Resumen de: US2025293279A1
A membrane electrode assembly includes a cathode portion including a cathode electrode and an anode portion disposed opposite the cathode portion and including an anode electrode. Additionally, the membrane electrode assembly includes a polymer electrolyte membrane extending between the cathode portion and the anode portion. Moreover, the membrane electrode assembly includes one or more metal oxides disposed therein with the metal oxides configured to react with hydrogen peroxide within the membrane electrode assembly. Additionally, the membrane electrode assembly includes one or more metal cations disposed therein with the metal cations configured to react with hydroxyl radicals disposed within the membrane electrode assembly.
Resumen de: AU2024269568A1
The present invention relates to a novel material comprising an organic binder consisting of a thermoplastic polymer, selected from the group consisting of polyethylene, polypropylene, polystyrene, acrylonitrile-butadiene-styrene, poly vinyl halide or poly vinylidene halide or mixtures thereof, a hydrophilic inorganic filler and a porosity agent. This material can be used for the manufacture of a film which, after treatment, will provide a membrane suitable for use as a diaphragm in an alkaline electrolyser, allowing the production of hydrogen.
Resumen de: AU2024214359A1
Feedwater preparation system in a water electrolyser adapted to produce hydrogen and oxygen in one or more pressurised electrolyser stacks (2) using alkaline water and comprising a product gas conditioning system that has a safety valve out-blow material stream pipe (11) which is connected to a feedwater vessel (9), and/or has a depressurisation stream pipe (31) from a gas cleaning vessel which is connected to the feedwater vessel (9).
Resumen de: AU2024218032A1
A hydrogen generation system includes: a direct current (DC) power supply providing a driver signal, a reactive circuit coupled to the power supply and configured to generate a pulse drive signal from the driver signal, at least one reaction chamber coupled to the reactive circuit and receiving the pulse drive signal wherein the chamber is configured to generate hydrogen from feedstock material utilizing the pulse drive signal, a gas analyzer coupled to the at least one reaction chamber and configured to detect the generated hydrogen, and a control unit coupled to the reactive circuit and to the gas analyzer and configured to control the reactive circuit based on the detected hydrogen. The reaction chamber includes a plurality of positively charged elements and a plurality of negatively charged elements. The elements are composed of non-dis similar metallic material.
Resumen de: AU2024226531A1
This hydrogen carrier production system includes: a hydrogen production device which produces hydrogen; a hydrogen tank in which hydrogen produced by the hydrogen production device is stored; and a plurality of hydrogen carrier production devices in which hydrogen stored in the hydrogen tank is converted to different types of hydrogen carriers.
Resumen de: EP4617231A1
A hydrogen absorption/discharge device includes an absorption/discharge part, a first electrode located at a first end portion side of the absorption/discharge part, a second electrode located at a second end portion side of the absorption/discharge part, and buffer layers located respectively between the first electrode and the first end portion of the absorption/discharge part and between the second electrode and the second end portion of the absorption/discharge part; the absorption/discharge part includes a material that allows permeation of hydrogen and hydride-ion conduction; and the second end portion faces the first end portion.
Resumen de: GB2639297A
An apparatus for the photolysis of a solid target material comprising a chamber arranged to receive the target material, at least one emitter arranged to emit an electromagnetic radiation signal at or towards the target material, an electric field generator configured to generate an electric field within the chamber and a controller configured to control the electric field such that the EM radiation signal emitted is incident upon the target. Preferably the chamber is a vacuum chamber. Preferably the electric field strength is targeted on the excited bonds present in the target material. Preferably there are a plurality of electromagnetic radiation emitters, more preferably there is a radial array of emitters, alternatively the plurality of emitters may be arranged about the circumference of the chamber.
Resumen de: EP4618104A2
A solid or liquid fuel to plasma to electricity power source that provides at least one of electrical and thermal power comprising (i) at least one reaction cell for the catalysis of atomic hydrogen to form hydrinos, (ii) a chemical feel mixture comprising at least two components chosen from: a source of H<sub>2</sub>O catalyst or H<sub>2</sub>O catalyst; a source of atomic hydrogen or atomic hydrogen; reactants to form the source of H<sub>2</sub>O catalyst or H<sub>2</sub>O catalyst and a source of atomic hydrogen or atomic hydrogen; one or more reactants to initiate the catalysis of atomic hydrogen; and a material to cause the feel to be highly conductive, (iii) a fuel injection system such as a railgun shot injector, (iv) at least one set of electrodes that confine the fuel and an electrical power source that provides repetitive short bursts of low-voltage, high-current electrical energy to initiate rapid kinetics of the hydrino reaction and an energy gain due to forming hydrinos to form a brilliant-light emitting plasma, (v) a product recovery system such as at least one of an augmented plasma railgun recovery system and a gravity recovery system, (vi) a fuel pelletizer or shot maker comprising a smelter, a source of hydrogen and a source of H<sub>2</sub>O, a dripper and a water bath to form fuel pellets or shot, and an agitator to teed shot into the injector, and (vii) a power converter capable of converting the
Resumen de: EP4618204A2
Method of manufacturing of a membrane with surface fiber structure, in particular for use in an electrolyzer or fuel cell, by inserting the polymer membrane into the vacuum chamber equipped with a magnetron sputtering system with a cerium oxide target in which an atmosphere of O2 and inert gas is formed and igniting the plasma which leads to simultaneous plasma etching of the membrane surface and deposition of cerium oxide onto the surface of etched membrane resulting in formation of fibers. The membrane is made of polymer and on at least one of its sides features porous surface made of fibers, the cross-sectional dimensions of which are lower than their length and which are integral and inseparable part of membrane body.
Resumen de: AU2023379054A1
2. The invention relates to a filter for treating process fluid such as that which in particular arises during hydrogen electrolysis, preferably for separating hydrogen and/or oxygen from process water, having a first filter element (10) and a second filter element (12), which encloses the first filter element (10) with the formation of a flow space (14) with a predefinable radial spacing, wherein each filter element (10, 12) has a filter medium (16, 18) through which the process fluid can flow in a flow-through direction (24) from the outside to the inside or preferably from the inside to the outside, wherein, seen in the flow-through direction (24), the one filter medium (16) forms a first degassing stage, which is used to enlarge gas bubbles through coalescence and to remove same from the process fluid through separation caused by buoyancy, and the subsequent further filter medium (18) forms a second degassing stage, which is used to remove very finely distributed gas bubbles remaining in the process fluid, again through coalescence and the separation of same through rising caused by buoyancy.
Resumen de: EP4617405A1
The present invention provides a gas-liquid diffuser for hydrogen production by alkaline water electrolysis. The gas-liquid diffuser is arranged between an electrode plate and a diaphragm to form a gas-liquid diffusion layer, is made of a woven web or a mesh plate, and is formed to have a plurality of flow channels alternately arranged on both sides of the gas-liquid diffuser; and in a direction perpendicular to the flow channels, the cross section of the gas-liquid diffuser is in a wavy shape formed by the plurality of flow channels. By using the gas-liquid diffuser, contact resistance is effectively reduced, electrolysis efficiency is improved, stress concentration at a contact position is lowered, diaphragm is prevented from being crushed, flow resistance of a fluid is reduced, formation of a retention and backflow in an internal flow field is avoided, the risk of hydrogen and oxygen interpenetration is lowered, and it is useful to increase the contact area between an electrode surface and an alkaline electrolyte.
Resumen de: MX2025009748A
A hydrogen generating cell comprising an input electrode plate pair, an output electrode plate pair, an additional X plate electrode positioned adjacent the output electrode plate pair, and a plurality of intermediate electrode plates disposed between the input and output electrode plate pairs. A plasma torch is spaced apart from and inductively coupled to the input electrode plate pair. A pulsed DC voltage is applied to the plasma torch and X-plate, while a lower voltage pulsed DC voltage is applied to the input and output electrode plate pair to cause generation of hydrogen gas from an aqueous solution in which the cell is immersed.
Resumen de: AT528039A1
Die vorliegende Erfindung betrifft eine Elektrolysevorrichtung (100) für eine Erzeugung eines Brennstoffs (B) in Elektrolysezellen wenigstens eines Elektrolysestapels (110), aufweisend einen Luftzuführabschnitt (122) zur Zufuhr von Zuluft (ZL) zu einer Luftseite (120) des Elektrolysestapels (110) und einen Luftabführabschnitt (124) zur Abfuhr von Abluft (AL) von der Luftseite (120) des Elektrolysestapels (110), weiter aufweisend einen Wasserzuführabschnitt (132) zur Zufuhr von Wasser (W) zu einer Brennstoffseite (130) des Elektrolysestapels (110) und einen Brennstoffabführabschnitt (134) zur Abfuhr von Brennstoffgemisch (BG), aufweisend Brennstoff (B) und Wasser (W), von der Brennstoffseite (130) des Elektrolysestapels (110), wobei der Brennstoffabführabschnitt (134) eine Kondensatorvorrichtung (140) aufweist für eine Kühlung des Brennstoffgemischs (BG) unter eine Kondensationstemperatur von Wasser (W), für ein Kondensieren und Abtrennen des Wassers (W) von dem Brennstoff (B), wobei im Brennstoffabführabschnitt (134) stromaufwärts der Kondensatorvorrichtung (140) ein Brennstoffgemisch-Zuluft-Wärmetauscher (150) in wärmeübertragendem Kontakt mit dem Luftzuführabschnitt (122) angeordnet ist für eine Übertragung von Wärme vom Brennstoffgemisch (BG) in die Zuluft (ZL).
Resumen de: WO2025186606A1
An integrated system for power generation and method thereof is disclosed, for generating and utilizing hydrogen gas or oxyhydrogen gas for enhancing fuel efficiency, thereby providing energy efficient power generation. An electricity generation system (402) generates and store an electric current in a battery for processing a gas generator (100) i.e., hydrogen (H2) or oxyhydrogen (HHO) gas generator. In the gas generator (100) an Automatic Transmit Power Control power supply (102) stabilizes power transmission, providing constant current by a current source (104) to an electrolysis setup (106) for generating hydrogen (H2) gas or oxyhydrogen (HHO) gas. A thermostat regulates temperature, and a demister separates steam from the generated gas. A burner (200) combusts the generated gas. A steam boiler (302) converts water into high pressure steam using the generated gas. A steam turbine (304) converts the high-pressure steam into mechanical energy. An electricity generator (306) converts mechanical energy into electrical energy.
Resumen de: WO2025186621A1
An apparatus, a system and a method for generating and storing hydrogen gas are disclosed. In one arrangement, an apparatus comprises a wind turbine, a solar array comprising at least one solar panel, an electrolyser unit having an electrolyser peak capacity and powered by the wind turbine and/or the solar array, and a pipeline configured to receive and store hydrogen from the electrolyser unit and having a length at least equal to 500 meters per 10MW of the electrolyser peak capacity. In another arrangement a method comprises generating energy at the wind turbine and the solar array comprising at least one solar panel, receiving the generated energy at the electrolyser unit, generating hydrogen gas with the generated energy by the electrolyser unit, and receiving and storing the generated hydrogen gas in a pipeline.
Resumen de: WO2025185857A2
Disclosed is a process for producing hydrogen and a reactor used for this process. The reactor contains a first reaction space for oxidizing metal fuel selected from silicon, magnesium, iron, titanium, zinc, aluminum or alloy containing two or more of these metals with an oxidant and a second reaction space separated from the first reaction space for dehydrogenating hydrogen-containing chemicals into hydrogen and dehydrogenated products. The reactor contains a plurality of feed lines axially and/or radially and/or tangentially passing through the reactor jacket for feeding the inlet zone of the first reaction space with inert gas and/or metal fuel and/or oxidant as a result of which a vortex is formed at the interior of the reactor jacket, which vortex moves towards the direction of the outlet zone of the first reaction space or the reactor contains at least one electrolysis cell that is placed partially or in total within the first reaction space or is placed downstream a tube located within the first reaction space for performing electrolysis of the hot hydrogen-containing chemical within said electrolysis cell. With the reactor and the process of this invention hydrogen is generated from hydrogen-containing chemicals, such as water and metal fuel is used to generate thermal energy to promote the dehydrogenation reaction.
Resumen de: US2025283230A1
A method for producing an electrolysis cell includes a joining step of joining a frame portion of a protective sheet member provided between a membrane electrode assembly and a fluid-supply-side current collector to a portion of the membrane electrode assembly on the outer side of the covered portion where an electrolyte membrane is covered with an electrode catalyst layer to form a joint, and a joined body stacking step of stacking the membrane electrode assembly and the protective sheet member joined together on the fluid-supply-side current collector with the protective sheet member facing the fluid-supply-side current collector.
Resumen de: WO2025186440A1
The present invention relates to electrical energy storage apparatus, such as rechargeable electrical energy storage devices such as batteries. We describe an electrochemical cell comprising: a chamber containing an electrolyte and a porous membrane dividing the chamber into a first compartment and a second compartment. The cell includes a first electrode, associated with the first compartment; and a second electrode, associated with the second compartment. The first compartment contains a first triphasic gas storage material in contact with the first electrode; and the second compartment contains a second triphasic gas storage material in contact with the second electrode. The first compartment further contains hydrogen gas, and the second compartment contains oxygen gas. In preferred examples, the first and/or the second triphasic gas storage material is a material selected from a polymer of intrinsic microporosity, a metal-organic framework, a zeolite or a porous silicate.
Resumen de: US2025282614A1
A process for cracking ammonia to form hydrogen is described comprising the steps of (i) passing ammonia through one or more catalyst-containing tubes in a furnace to crack the ammonia and form hydrogen, wherein the one or more tubes are heated by combustion of a fuel gas mixture to form a flue gas containing nitrogen oxides capable of reacting with ammonia in the flue gas to form ammonium nitrate, and (ii) cooling the flue gas to below 170° C., characterised by maintaining an amount of steam in the flue gas according to the following equation to prevent solid ammonium nitrate formation: (I) where, yH2O is the mol % of steam in the flue gas, P*H2O is the equilibrium vapor pressure of water in an aqueous solution of ammonium nitrate, and p is the minimum operating pressure of the flue gas.
Resumen de: US2025281781A1
A gist of the present invention provides a flame extinction device which is excellent in flame propagation suppressive effect and in shock wave propagation suppressive effect, and a hydrogen production device including the flame extinction device. A flame extinction device (1) includes: a flame propagation suppression section (3) having a porous portion on the first pipe (10) side and/or the second pipe (22) side when seen from a connective piping section (20); and a pressure reduction section (2) that reduces a risen internal pressure at an end part of a third pipe (23) which is not orthogonal to any of the first pipe (10) and the second pipe (22).
Resumen de: US2025283226A1
An electrochemical reactor for capturing carbon dioxide and producing bicarbonate and hydrogen is described herein. The electrochemical reactor is useful for, among other things, converting biogas to a bicarbonate and hydrogen feedstock for biomethanation. The reactor comprises at least one reactor unit comprising an electrolyzer cell and at least one alkaline water electrolysis (AWE) cell adjacent to the electrolyzer cell. The electrolyzer cell comprises an anode spaced from a cathode by an ion exchange membrane between the anode and the cathode; and the electrolyzer cell is adapted and arranged to allow a flow of a neutral liquid electrolyte to contact the anode and the cathode. The ion exchange membrane can be a cation exchange membrane (CEM), or an anion exchange membrane (AEM). The AWE cell comprises a second anode spaced from a second cathode by a porous diaphragm.
Resumen de: US2025214034A1
Hydrogen gas purifier electrochemical cells, systems for purifying hydrogen gas, and methods for purifying hydrogen gas are provided. The cells, systems, and methods employ double membrane electrode (DMEA) electrochemical cells that enhance purification while avoiding the complexity and cost of conventional cells. The purity of the hydrogen gas produced by the cells, systems, and methods can be enhanced by removing at least some intermediate gas impurities from the cells. The purity of the hydrogen gas produced by the cells, systems, and methods can also be enhanced be introducing hydrogen gas to the cells to replenish any lost hydrogen. Water electrolyzing electrochemical cells and methods of electrolyzing water to produce hydrogen gas are also disclosed.
Resumen de: US2025283232A1
An electrolysis cell of an electrolysis device includes a membrane electrode assembly in which an electrolyte membrane is interposed between a first electrode and a second electrode. The membrane electrode assembly is positioned between a first separator and a second separator. The electrolysis device further includes a seal member and a protection member. The protection member surrounds the outer periphery of the second electrode. The protection member includes a first portion and a second portion. The first portion is interposed between the electrolyte membrane and the seal member. The second portion is interposed between the electrolyte membrane and the second separator.
Resumen de: AU2025201306A1
A water processing system includes an ultrafiltration membrane device (UF membrane device), a reverse osmosis membrane device (RO membrane device), an electric deionization device (EDI device), and an information processing device (edge computer). The information processing device controls operations of the ultrafiltration membrane device, the reverse osmosis membrane device, and the electric deionization device based on information on a water electrolysis device that obtains hydrogen by subjecting water to electrolysis. Water that is processed by the electric deionization device is supplied to the water electrolysis device. The water electrolysis device is able to obtain hydrogen by subjecting supplied water to electrolysis. A water processing system includes an ultrafiltration membrane device (UF membrane device) , a reverse osmosis membrane device (RO membrane device) , an electric deionization device (EDI device , and an information processing device (edge computer) . The information processing device controls operations of the ultrafiltration membrane device, the reverse osmosis membrane device, and the electric deionization device based on information on a water electrolysis device that obtains hydrogen by subjecting water to electrolysis. Water that is processed by the electric deionization device is supplied to the water electrolysis device. The water electrolysis device is able to obtain hydrogen by subjecting supplied water to electrolysis. eb w a t e r p r o c e s
Resumen de: US2025286385A1
A sea-land collaboration-based multi-energy coupling low-carbon new energy system includes a low-carbon power generation unit, a green fuel synthesis unit and an energy storage device which are arranged on a sea and an island, a green fuel comprehensive utilization unit and a carbon capture device which are arranged on the island and/or on land, and a multi-energy flow coupling-based sea-land collaborative low-carbon intelligent control center. The system generates power using abundant and stable solar energy and wind energy on the sea and the island, prepares hydrogen and ammonia using seawater, and the green fuel synthesis unit prepares green fuels using the prepared hydrogen and carbon dioxide produced by the system, such that the use of coal and natural gas in the green fuel comprehensive utilization unit is reduced; meanwhile, produced carbon dioxide is used as raw materials to prepare green fuels again.
Resumen de: US2025283595A1
A circular economy polygeneration system includes an electrolyzer operable to provide hydrogen and oxygen based on water. The system includes a hydrogen firing furnace operable to burn hydrogen and produce a first flue gas including water and nitrogen. The system also includes an oxy-firing furnace operable to burn hydrocarbon fuel with oxygen provided by the electrolyzer to produce a second flue gas comprising water and carbon dioxide. Moreover, the system includes a first condenser configured to produce nitrogen and a first stream of water based on the first flue gas. The system further includes a second condenser configured to produce carbon dioxide and a second stream of water based on the second flue gas. The first and second stream of water are used by the electrolyzer to provide the hydrogen and oxygen. Additionally, the system includes a carbon capture system operable to capture carbon dioxide produced by the second condenser.
Resumen de: US2025283230A1
A method for producing an electrolysis cell includes a joining step of joining a frame portion of a protective sheet member provided between a membrane electrode assembly and a fluid-supply-side current collector to a portion of the membrane electrode assembly on the outer side of the covered portion where an electrolyte membrane is covered with an electrode catalyst layer to form a joint, and a joined body stacking step of stacking the membrane electrode assembly and the protective sheet member joined together on the fluid-supply-side current collector with the protective sheet member facing the fluid-supply-side current collector.
Resumen de: US2025283231A1
Methods and apparatuses for converting carbon dioxide to useful compounds are disclosed. The method involves reducing bicarbonate solution in an electrolyzer. Bicarbonate solution is supplied to the cathode. The direct reduction of bicarbonate at the cathode may be coupled with an oxidation reaction at the anode. The oxidation reaction may provide a source of protons (H+) to cathode for the reduction of bicarbonate. The oxidation reaction may be a hydrogen oxidation reaction (HOR). Hydrogen gas (H2) may be supplied to the anode. In some embodiments, a source of gas may be supplied to the bicarbonate solution to form a pressurized solution before supplying the solution to the cathode.
Resumen de: MX2025002871A
The present invention relates to the electrochemical production of hydrogen and lithium hydroxide from Li+-containing water using a LiSICon membrane. The problem addressed by the present invention is that of specifying a process which is operable economically even on an industrial scale. The process shall especially exhibit a high energy efficiency and achieve a long service life of the membrane even when the employed feed contains impurities harmful to LiSICon materials. A particular aspect of the process is that the cell simultaneously separates off the lithium via the membrane and effects electrolysis of water. An essential aspect of the process is that the electrochemical process is performed in a basic environment, more precisely at pH 9 to 13. The pH is adjusted by addition of a basic compound to the feed.
Resumen de: MX2025002822A
The problem addressed by the present invention is that of specifying a process for producing lithium hydroxide which is very energy efficient. The process shall especially operate without consumption of thermal energy. The process shall be able to handle, as raw material, Li-containing waters generated during digestion of spent lithium-ion batteries. The LiOH produced by the process shall have a high purity sufficient for direct manufacture of new LIB. The process shall achieve a high throughput and have small footprint in order that it can be combined with existing processes for workup of used LIB/for production of new LIB to form a closed, continuous production loop. The process according to the invention is an electrolytic membrane process operating with a LiSICon membrane. It is a special aspect of the process that the electrolysis is operated up to the precipitation limit of the lithium hydroxide.
Resumen de: US2025283392A1
The present application is related to a geological carbon sequestration and hydrogen production structure and method based on the spontaneous reaction of water, CO2, and active minerals, belonging to the field of carbon sequestration and hydrogen production technology. The method comprises the following steps: (1) CO2 collection; (2) selecting a site for carbon sequestration and hydrogen production; (3) constructing a space for carbon sequestration and hydrogen production; (4) CO2 mineralization sequestration and simultaneous hydrogen production; (5) hydrogen collection. The method permanently mineralizes and sequesters CO2 while using the water-CO2-active minerals reaction for simultaneous geological hydrogen production. It not 10 only reduces the economic cost of CO2 geological sequestration but also opens a new pathway for in-situ geological hydrogen production, achieving green and low-carbon hydrogen energy production. The geological carbon sequestration and hydrogen production structure is designed to have low sequestration costs and enable large-scale simultaneous geological hydrogen production.
Resumen de: US2025282613A1
Contemplated systems and methods for hydrogen production use a solar heliostat system as an energy source to produce hydrogen during daytime, and employ molten salt as an energy source to produce hydrogen during nighttime.
Resumen de: MX2025002826A
The problem addressed by the present invention is that of specifying a process for electrochemical production of LiOH from Li<sup>+</sup>-containing water using an electrochemical cell having a LiSICon membrane which is operable economically even on an industrial scale. The process shall especially have a high energy efficiency and achieve a long service life of the membrane even when the employed feed contains impurities damaging to LiSICon materials. The problem is solved by adjusting the flow conditions in the anodic compartment of the electrochemical cell such that the anolyte flows along the membrane at a certain minimum flow rate.
Resumen de: US2025283236A1
A method for sealing an electrolyzer cell may include applying a sealant between two layers of an electrolyzer cell and compressing the two layers towards each other. The method may further include flowing fluid through a flow field in the electrolyzer cell. The method may further include controlling a temperature of the fluid flowing through the flow field and controlling a pressure applied to the sealant by the compressing the two layers towards each other. The method may further include conforming the sealant to the two layers.
Resumen de: US2025283237A1
A method can include: processing precursors, electrochemically oxidizing an anolyte and reducing a catholyte in an electrolyzer, and cooperatively using the oxidized anolyte and reduced catholyte in a downstream process. The electrolyzer can include an anode, a cathode, and a separator. The anode can include an anolyte, an electrode, an anolyte reaction region. The cathode can include a catholyte, an electrode, a catholyte reaction region.
Resumen de: US2024154496A1
A system includes a flow-through electric generator and an electrolytic cell. The flow-through electric generator includes a turbine wheel, a rotor, and a stator. The turbine wheel is configured to receive natural gas from a natural gas pipeline and rotate in response to expansion of the natural gas flowing into an inlet of the turbine wheel and out of an outlet of the turbine wheel. The rotor is coupled to the turbine wheel and configured to rotate with the turbine wheel. The flow-through electric generator is configured to generate electrical power upon rotation of the rotor within the stator. The electrolytic cell is configured to receive a water stream and the electrical power from the flow-through electric generator. The electrolytic cell is configured to perform electrolysis on the water stream using the received electrical power to produce a hydrogen stream and an oxygen stream.
Resumen de: WO2024094264A2
A hydrogen generation system comprising a hydrogen electrolyser, a power converter connected to the electrolyser, and a control system configured to control the power converter to supply power to the electrolyser The system further includes a monitoring system configured to monitor the operation of the generation system, wherein the monitoring system is configured to: determine a plurality of operational parameters of the electrolyser, and, generate one or more performance metrics based on the determined operational parameters, the one or more performance parameters including: the electrical capacitance of the electrolyser, and/or the equivalent series resistance of the electrolyser. Also disclosed is a method for determining operational performance of a hydrogen generation system including an electrolyser.
Resumen de: EP4613913A1
A method for sealing an electrolyzer cell may include applying a sealant between two layers of an electrolyzer cell and compressing the two layers towards each other. The method may further include flowing fluid through a flow field in the electrolyzer cell. The method may further include controlling a temperature of the fluid flowing through the flow field and controlling a pressure applied to the sealant by the compressing the two layers towards each other. The method may further include conforming the sealant to the two layers.
Resumen de: US2025276895A1
The gas generation system decomposes water in contact with the photocatalyst by sunlight to generate a mixed gas composed of oxygen gas and hydrogen gas. The gas generation system includes a housing having a light-transmission wall in which an accommodation space for accommodating water and a photocatalyst is formed. The light-transmission wall transmits the sunlight S that has directly or indirectly reached at least a part of the wall portion forming the accommodation space. The gas generation system includes an irradiation device that causes an artificial light L having a peak wavelength that is absorbed by the photocatalyst to emit light by supply of electric power, and irradiates the light-transmission wall with the emitted artificial light L, and a switch that selectively switches supply or stop of supply of electric power to the irradiation device.
Resumen de: MX2025005140A
Cell for forming an electrolyser comprising at least one diaphragm or membrane having a first side and a second side opposite the first side, a first cell plate, arranged on the first side of the diaphragm, provided with a first electrode, provided with an inlet channel for supplying or draining electrolyte to or from the electrode, provided with a first discharge channel for discharging oxygen from the electrode, at least one second cell plate, arranged on the second side of the diaphragm, provided with a second electrode and provided with a second discharge channel for discharging hydrogen from the electrode wherein the at least one first and second cell plate are made of a polymer material.
Resumen de: EP4613912A1
The present invention relates to a cathode material for a solid oxide electrolytic cell and its preparation and use. The cathode material for the solid oxide electrolytic cell has a molecular formula of LaxSr1-xFe0.8CuyNi0.2-yO3-δ, wherein 0.1≤x≤0.9, 0.01≤y<0.2, and 0≤δ≤0.5. An electrolytic cell prepared by using the cathode material can efficiently convert CO2 and H2O into synthesis gas through electrochemical catalysis. Furthermore, the electrolytic cell can achieve continuous and stable operation of high-temperature electrolysis of water vapor and/or carbon dioxide at a temperature of 800°C and an electrolysis current density of 0.5 A/cm<2> or more, thereby having good prospects for industrial application.
Resumen de: EP4613700A1
Disclosed is a process for producing hydrogen and a reactor used for this process. The reactor contains a first reaction space for oxidizing metal fuel selected from silicon, magnesium, iron, titanium, zinc, aluminum or alloy containing two or more of these metals with an oxidant and a second reaction space separated from the first reaction space for dehydrogenating hydrogen-containing chemicals into hydrogen and dehydrogenated products.With the reactor and the process of this invention hydrogen is generated from hydrogen-containing chemicals, such as water and metal fuel is used to generate thermal energy to promote the dehydrogenation reaction.
Resumen de: WO2025182682A1
A method for operating a water electrolysis apparatus that comprises an electrolytic bath for electrolyzing water, a hydrogen separator to which hydrogen generated in the electrolytic bath is guided, an oxygen separator to which oxygen generated in the electrolytic bath is guided, and a vent line for discharging gas from the hydrogen separator or the oxygen separator and a vent valve provided to the vent line, the method comprising: a step for halting electrolysis of water in the electrolytic bath; and a step for determining whether or not a first index indicating the amount of increase in the concentration of oxygen in gas in the hydrogen separator or the concentration of hydrogen in gas in the oxygen separator has exceeded a first threshold after the electrolysis has been halted. When the first index exceeds the first threshold, the pressure in the hydrogen separator or the oxygen separator is lowered to a first prescribed value by opening the vent valve.
Resumen de: WO2024097986A2
Disclosed herein are devices, systems, and methods of using aluminum, activated with a liquid metal catalyst stored inside of one or multiple shipping containers or shipping container-like boxes to produce hydrogen and direct heat on demand.
Resumen de: WO2025182228A1
The present invention provides: an operation method for an electrolysis device that is able to quickly reach a rated load; a control device for an electrolysis device; and an electrolysis system. Provided is an operation method for an electrolysis device (100) that is provided with a temperature adjuster (30), which adjusts the temperature of an electrolytic solution supplied to an electrolytic cell (40), the electrolytic cell (40), which electrolyzes the electrolytic solution supplied thereto via the temperature adjuster (30), and a gas-liquid separator (20), which separates a gas and a liquid produced by the electrolytic cell (40), wherein in a state in which the electrolysis device (100) is stopped, warm water is supplied to the temperature adjuster (30).
Resumen de: EP4613914A1
A water electrolysis system (100) includes a plurality of water electrolysis stacks (101) connected in series to a DC power supply, a plurality of gas storage tanks (e.g., a hydrogen gas tank (102), a low-pressure hydrogen gas tank (102a)) for storing a gas generated in the water electrolysis stacks, a first gas pressure adjustment mechanism (e.g., a hydrogen gas tank pressure adjustment valve (113)) for adjusting pressure of the gas generated in the entire plurality of water electrolysis stacks, a plurality of second gas pressure adjustment mechanisms (e.g., a water electrolysis stack hydrogen gas pressure adjustment valve (115), a water electrolysis stack low-pressure hydrogen gas pressure adjustment valve (115a)) for adjusting pressure of a gas generated in each of the water electrolysis stacks, and a control device (150) for controlling the first gas pressure adjustment mechanism and the second gas pressure adjustment mechanism.
Resumen de: JP2025130751A
【課題】 アンモニアを含む原料ガスを反応容器内で低い温度で分解させて水素ガスと窒素ガスとを含むガスを発生させるようにすると共に、アンモニアガスによって被処理物を炉内で窒化処理させる窒化装置の設備コストやランニングコストを低減させる。【解決手段】 炉20内で被処理物をアンモニアガスNH3により500~600℃の温度で窒化処理する窒化装置において、アンモニアを含む原料ガスを500~600℃で分解させる触媒xが収容された反応容器10を炉内に挿入させ、反応容器内で分解させて得た水素ガスH2と窒素ガスN2とを含むガスを炉内に直接供給するようにした。【選択図】 図2
Resumen de: US2025207273A1
A water electrolysis electrode includes a conductive substrate and a layered double hydroxide layer. The conductive substrate has a surface including nickel having a plane orientation. The layered double hydroxide layer includes a layered double hydroxide including two or more transition metals. The layered double hydroxide layer is disposed on the surface.
Resumen de: JP2025130721A
【課題】電磁波の照射により効率よく酸素を発生し得る酸素発生剤を提供する。【解決手段】本発明の一態様によれば、酸素発生剤が提供される。この酸素発生剤は、300MHz以上20GHz以下の周波数を有する電磁波の照射により、300℃以上770℃以下の温度環境下において酸素元素を離脱する特性を有する複合酸化物を含む。【選択図】図1
Resumen de: JP2025129457A
【課題】現在における二酸化炭素レーザーによって水素を生じさせる方法は産出の複雑度とコストが増やされる問題とエネルギー消耗の問題がある。【解決手段】本発明の低炭素水素の製造方法は、廃シリコンスラリーを乾燥させる工程(a)と、乾燥した廃シリコンスラリーを粉砕と選別し、重量百分率(wt%)が40から95の酸化ケイ素が得られ、そのうち金属ケイ素は酸化ケイ素含有量の5wt%から40wt%を占める工程(b)と、酸化ケイ素とアルカリ金属水溶液を混合反応させ、反応温度を100℃から150℃の間に制御するすることによって水素が得られる工程(c)とを備える。【選択図】図1
Resumen de: US2025270710A1
A water electrolysis system includes: a water electrolysis device for electrolyzing water; a gas-liquid separator for performing gas-liquid separation of a mixed fluid of hydrogen gas and water, the mixed fluid being led out from the water electrolysis device; a dehumidifier for dehumidifying the hydrogen gas separated from the mixed fluid by the gas-liquid separator; a delivery path for delivering the hydrogen gas dehumidified by the dehumidifier; a humidifier for humidifying the hydrogen gas delivered through the delivery path; and a compression device for compressing the hydrogen gas humidified by the humidifier.
Resumen de: JP2025129633A
【課題】固体高分子形の水電解セルを用いた水電解装置およびその周辺機器をコンテナ内に収容するにあたり、換気量を従来よりも抑える。【解決手段】水電解セルスタック13、酸素ガス用の気液分離を行うタンク21、水素ガス用気液分離機能を有するタンク52、水素ガスの除湿を行う除湿器62を、コンテナC1内に収容するにあたり、コンテナC1内の一側に寄せた領域Hに、水素ガス用気液分離機能を有するタンク52、水素ガスの除湿を行う除湿器62を配置する。領域Hは仕切り壁81に囲まれ、領域H内の雰囲気は換気扇83によってシステム外に放出される。仕切り壁81における下部は、コンテナC1内における領域H以外の空間と連通している。【選択図】図3
Resumen de: US2025283232A1
An electrolysis cell of an electrolysis device includes a membrane electrode assembly in which an electrolyte membrane is interposed between a first electrode and a second electrode. The membrane electrode assembly is positioned between a first separator and a second separator. The electrolysis device further includes a seal member and a protection member. The protection member surrounds the outer periphery of the second electrode. The protection member includes a first portion and a second portion. The first portion is interposed between the electrolyte membrane and the seal member. The second portion is interposed between the electrolyte membrane and the second separator.
Resumen de: WO2024126749A1
There is provided a multi-layered proton exchange membrane for water electrolysis, comprising: at least two recombination catalyst layers, each of the at least two recombination catalyst layers comprising a recombination catalyst and a first ion exchange material, wherein at least two recombination catalyst layers are separated by a region devoid of or substantially devoid of a recombination catalyst, and at least two reinforcing layers, each of the at least two reinforcing layers comprising a microporous polymer structure and a second ion exchange material which is at least partially imbibed within the microporous polymer structure.
Resumen de: WO2025179709A1
The present application relates to the technical field of catalysts and relates to a non-noble metal cathode hydrogen evolution catalyst for PEM water electrolysis and a use thereof. The present application provides a method for preparing a cathode hydrogen evolution catalyst. A nickel-molybdenum heteropoly acid having a specific structure is generated in situ on the surface of a porous carbon material carrier, and is used as a hydrogen evolution catalyst active component precursor, and an in-situ generated nickel-containing molybdenum sulfide active component is subjected to sulfidation treatment to prepare a non-noble-metal-supported cathode hydrogen evolution catalyst, wherein the in-situ generated nickel-containing molybdenum sulfide active component has a hydrogen adsorption free energy similar to that of Pt and catalytic hydrogen evolution activity, the dispersity is good, and the number of active sites is large, thereby reducing the costs of the catalyst; in addition, during the sulfidation treatment of the nickel-molybdenum heteropoly acid, nitrogen or phosphorus atoms in the carrier can be doped into the lattice of molybdenum disulfide, thereby reducing the hydrogen evolution Gibbs free energy of sulfur atoms on an MoS2 crystal basal surface, and more active sites are formed on a sulfur edge and a molybdenum edge, facilitating a hydrogen evolution reaction.
Resumen de: WO2025179506A1
The present disclosure relates to an electrode separator unit, a preparation method, an electrolytic cell unit, and a device for hydrogen production from a renewable energy. The electrode separator unit of the present disclosure comprises a membrane electrode assembly arranged in a center area of the electrode separator unit and comprises a sealing frame arranged around the outer peripheral wall of the membrane electrode assembly, wherein the inner peripheral wall of the sealing frame is fixedly connected to the outer peripheral wall of the membrane electrode assembly by means of material connection. In the solution of the present disclosure, by using the sealing frame and fixedly connecting the inner peripheral wall of the sealing frame to the outer peripheral wall of the membrane electrode assembly by means of material connection, no gaps generated by traditional packaging are present in the electrode separator unit. In addition, the contact area between the sealing frame and an adjacent functional component during fixed connection is increased, so that the clamping force for packaging an electrolytic cell device is more concentrated, and thus the sealing effect of the electrode separator unit is firmer, thereby further improving the hydrogen production efficiency. In addition, the present disclosure further reduces the number of parts, reduces the production cost, and improves the production efficiency.
Resumen de: KR20240032557A
According to the present invention, disclosed is a water electrolysis apparatus including a metal particle fluid electrode. The present invention comprises: a cathode; a first flow channel formed on the cathode; a cation exchange membrane (CEM) formed on the first flow channel; a second flow channel formed on the CEM; and an anode formed on the second flow channel, wherein the second flow channel includes metal particles and is used as a metal particle fluidic electrode.
Resumen de: US2025275533A1
Nanoplatelet forms of monolayer metal hydroxides are provided, as well as methods for preparing same. The nanoplatelets are suitable for use in antimicrobial compositions, for pressure treating lumber against wood rot, termites, and fungus, for water treatment for the removal of heavy metal contaminants, for the production of plasmonics devices, for the production of ore, or for the recovery of valuable metals in, e.g., fly ash ponds, mine tailings ponds, or other fluids containing the metal in ionic form. The nanoplatelet forms include copper hydroxide nanoplatelets.
Resumen de: US2025277318A1
The present disclosure is directed to a geothermal hydrogen production system, comprising; a primary liquid circuit circulating a liquid into a geothermal well and returning heated liquid from a well head of the geothermal well, the primary liquid circuit passing through a desalination plant; a first turbine driven by the heated liquid to produce a first mechanical output; and a second turbine driven by the heated liquid to produce a second mechanical output, wherein the first mechanical output drives an electrical generator, configured to power an electrolyser generating hydrogen via electrolysis of fresh water, and the second mechanical output drives an air compressor to provide at least one of a first, a second and a third compressed air supply, wherein the first compressed air supply drives a supply pump to supply salt water to the desalination plant, the second compressed air supply drives a start-up pump to initiate the primary liquid circuit, and the third compressed air supply drives a fresh water pump to deliver fresh water from the desalination plant to the electrolyser.
Resumen de: US2025277316A1
The present disclosure relates to an electrolyzer for generating hydrogen, the electrolyzer comprising: a housing comprising an electrolyte chamber; two electrodes for decomposition of electrolyte water, at least one of the electrodes being permeable to gases produced by the decomposition of electrolyte water, wherein the at least one permeable electrode has a first surface facing the electrolyte chamber and a second surface facing a first gas collection chamber; an electrolyte supply circuit for supplying electrolyte water to the electrolyte chamber; and a control unit and/or mechanical control for controlling a pressure drop across the at least one permeable electrode, between the electrolyte chamber and the first gas collection chamber.
Resumen de: US2025277317A1
Disclosed are electrolyzer systems and methods that combine forward osmosis with electrolysis to produce hydrogen from a water source such as seawater. The systems can operate with low energy input through immersion in the water source or by flowing the water source past osmotic membranes of a system to establish osmosis and simultaneous electrolysis.
Resumen de: CN119895081A
An electrolytic cell (1) for the electrolysis of chlor-alkali or alkaline water, comprising: two cell elements (2, 3), each cell element (2, 3) defining an electrode chamber (4, 5) by providing a rear wall (6) and side walls (7) of the electrode chamber (4, 5); electrodes (8, 9) respectively housed in each of the electrode chambers (4, 5); a sheet-like diaphragm (10) that extends in the height direction (H) and the width direction (W) of the electrolytic cell (1), is provided in a joint (11) between the two electrolytic cell elements (2, 3), and forms a partition wall (12) between the electrode chambers (4, 5); a plurality of support members (13) for supporting at least one electrode (8, 9) on a respective rear wall (6); wherein each support member (13) comprises: two support parts standing on the rear wall (6) and extending in the height direction (H) of the electrolytic cell (1); two feet (16, 17) connected to the respective supports (14, 15) at an angle and in planar contact with the rear wall (6); wherein the support portions of the support members (13) are connected to each other by means of an arch-shaped portion (18) bent outward toward the electrode (8) to be supported, and form an elastic bearing surface (19) for supporting the electrode (8); when the arch (18) deflects inwards, the bearing surface (19) increases.
Resumen de: US2024109772A1
A system and method for producing hydrogen, including steam reforming elemental sulfur to generate hydrogen gas and sulfur dioxide, to give a mixture including hydrogen gas, sulfur dioxide, elemental sulfur gas, and water vapor, removing the elemental sulfur gas to give a process gas including the hydrogen gas, sulfur dioxide, and water vapor, and isolating the hydrogen gas or a hydrogen gas rich stream.
Resumen de: AU2023331556A1
The invention relates to a photoelectric cell with a silicon carbide electrode (4) for photocatalytic production of hydrogen and to a production method for same. The cell has, on one side of the silicon carbide electrode (4), a window (2) for letting in light (5) and, on the other side of the silicon carbide electrode (4), an aqueous electrolyte (10) and a counter electrode (6). The cell is electrolyte-free on the side of the silicon carbide electrode (4) facing the window. The silicon carbide electrode (4) is preferably produced by coating a substrate (3) with silicon carbide (4).
Resumen de: WO2025180649A1
The invention relates to a method for operating a hydrogen production system (150, 450, 550, 650) having at least one wind turbine (110, 410, 510, 610) for supplying at least one electrolyzer (114, 414, 514, 614) of the hydrogen production system (150, 450, 550, 650) with electrical power, comprising determining a reference angular speed of the wind turbine (110, 410, 510, 610) based on at least one wind speed parameter predicted for the wind turbine (110, 410, 510, 610) for a future time window, regulating the wind turbine by setting a pitch angle during the future time window, wherein the pitch angle is determined based on the determined reference angular speed and the current angular speed of the wind turbine (110, 410, 510, 610), predicting power generatable by the wind turbine (110, 410, 510, 610) during the future time window based on the determined reference angular speed, controlling the at least one electrolyzer (114, 414, 514, 614) of the hydrogen production system (150, 450, 550, 650) by setting an at least almost constant rate of change of current during at least a portion of the future time window, wherein the rate of change of current is based on the predicted power.
Resumen de: WO2025180788A1
The invention relates to a method for controlling an electrolyzing plant (10), comprising: providing electric energy from an electric power network (32) with a network AC voltage; rectifying the network AC voltage by a rectifying device (50, 52, 54, 56, 58, 60, 62, 64); supplying water to the electrolyzing device (34, 36); providing an AC filter current flow by an active filter device (100), wherein the AC filter current flow is controlled such that it conforms to network regulations of the electric power network; measuring the network AC voltage by using a voltage sensor (128) which provides a respective voltage sensor signal; comparing the voltage sensor signal with a first reference voltage value providing a comparing result; depending on the comparing result, causing the active filter device (100) to emit electric energy to or to receive electric energy from the electric power network.
Resumen de: WO2025181491A1
An electrolyser system comprising at least one electrolyser cell comprising a first outlet for exhaust of off-gas from the first fluid volume at a relatively low pressure, a steam supply configured to supply steam at a relatively high pressure, means for mixing two fluids, a first heat exchanger; and a fuel supply. The means for mixing is configured to exhaust, at an intermediate pressure, an intermediate fluid comprising a mixture of steam from the supply and off-gas from the first fluid volume, and the system is configured to route said intermediate fluid to a first path of the first heat exchanger. The first heat exchanger is configured to transfer heat from the first path for the intermediate fluid to a second path for fuel from the fuel supply to separate water from the first product of the electrolyser reaction by condensing liquid water out of the intermediate fluid. The system is configured to route the first product of the electrolyser reaction out of the system at the intermediate pressure, and to route fuel from the second path of the first heat exchanger to a first inlet of the at least one electrolyser cell.
Resumen de: WO2025179327A1
The present invention relates to an electrolysis device (100) for producing a fuel (B) in electrolysis cells of at least one electrolysis stack (110), comprising an air supply portion (122) for supplying feed air (ZL) to an air side (120) of the electrolysis stack (110) and an air discharge portion (124) for discharging exhaust air (AL) from the air side (120) of the electrolysis stack (110), and also comprising a water supply portion (132) for supplying water (W) to a fuel side (130) of the electrolysis stack (110) and a fuel discharge portion (134) for discharging fuel mixture (BG), which comprises fuel (B) and water (W), from the fuel side (130) of the electrolysis stack (110), wherein: the fuel discharge portion (134) has a condenser device (140) for cooling the fuel mixture (BG) to below a condensation temperature of water (W), for condensing the water (W) and separating the water from the fuel (B); in the fuel discharge portion (134), upstream of the condenser device (140), a fuel-mixture/feed-air heat exchanger (150) is arranged in heat-transferring contact with the air supply portion (122) for transferring heat from the fuel mixture (BG) to the feed air (ZL).
Resumen de: WO2025180734A1
The invention relates to a method (100) for controlling the capacity utilisation of electrolysis units of an electrolysis system, wherein the electrolysis system has a control device and a plurality of electrolysis units, each of which can be selected by the control device; comprising providing current individual hydrogen production rates when there are cell voltage values individual to the selected electrolysis units depending on a common controlled variable, selecting (106) a number of electrolysis units from the plurality of electrolysis units taking into account a settable target hydrogen production rate or a settable target total electrical power consumption; and adapting (110) the common controlled variable depending on a deviation of a current total hydrogen production rate of the number of selected electrolysis units from the settable target hydrogen production rate or depending on a deviation of a current total electrical power consumption of the number of selected electrolysis units from the settable target total electrical power consumption. The common controlled variable is a target cell voltage value common to the number of selected electrolysis units, and the number of selected electrolysis units are operated at respective individual cell voltage values which are continuously adjusted to the common target cell voltage value (112).
Resumen de: WO2025181199A1
The present disclosure relates to a heat management method in a methanol-generating unit remarkable in the reactor (100) of the methanol-generating unit comprises a cooling device and wherein the steam (5, 7) recovered from said cooling device has a pressure that is suitable for being fed into the one or more solid oxide electrolyser cells (400), so as to provide a hydrogen-rich effluent (15) that is used to enhance the efficacy of the separation unit necessary for the methanol production.
Resumen de: WO2025181164A1
The invention relates to an electrochemical cell unit comprising the following, in the following order across its thickness: a hydrogen electrode (200) comprising a support electrode layer (203) and a functional electrode layer (204) stacked one on top of the other; a solid electrolyte (300) comprising a thin layer (302) having a first surface (305) and a second surface (306); and an oxygen electrode (400), characterised in that the solid electrolyte (300) comprises a frame (303) which extends from the first face (305) of the thin layer (302) and forms a cavity (304) in which the hydrogen electrode (200) is at least partially arranged. The invention relates to the optimisation of a solid oxide cell, including solid oxide fuel cells and solid oxide electrolyser cells.
Resumen de: AU2023433484A1
The present invention discloses an electrode plate of an electrolysis apparatus and an electrolysis apparatus to which the electrode plate is applied. A direct current power supply is connected to the electrolysis apparatus and an electrolyte is injected into the electrolysis apparatus, to convert electric energy into chemical energy. The electrode plate includes a silicon-based electrode plate made of a doped conductive silicon material. The silicon-based electrode plate is electrically connected to the direct current power supply, and a flow channel is disposed on at least one surface of the silicon-based electrode plate, so that the electrolyte is input into the electrolysis apparatus through the silicon-based electrode plate, to implement an electrochemical reaction and output a reaction product. In the present invention, on a basis of maintaining good mechanical support and sealing function, material and process costs of the electrode plate of the electrolysis apparatus are significantly reduced, an overpotential of the electrochemical reaction for producing the reaction product is reduced, and an electrolysis reaction rate per unit area in the electrolysis apparatus is increased. Therefore, an operating voltage is effectively reduced at a same electrochemical reaction rate, and energy conversion efficiency of the electrochemical reaction is finally significantly improved.
Resumen de: CN119866395A
A membrane electrode assembly (MEA) for generating hydrogen gas in a water electrolyser is provided. The MEA comprises a polymer electrolyte membrane (REM); a cathode comprising a cathode catalyst on a first side of the REM; an anode comprising an anode catalyst on a second side of the REM; and a platinum-ruthenium (Pt-Ru) catalyst on a second side of the REM to electrochemically convert hydrogen to hydrogen cations in use. The Pt-Ru catalyst is in electrical contact with the anode and in contact with the REM ions.
Resumen de: CN119866392A
A coating method for an electrolytic cell assembly is provided. The method includes coating at least a portion of the component with an acidic solution of platinum cations, and reducing the coated platinum cations with a reducing agent to form a layer of platinum metal on the component.
Resumen de: US2025276895A1
The gas generation system decomposes water in contact with the photocatalyst by sunlight to generate a mixed gas composed of oxygen gas and hydrogen gas. The gas generation system includes a housing having a light-transmission wall in which an accommodation space for accommodating water and a photocatalyst is formed. The light-transmission wall transmits the sunlight S that has directly or indirectly reached at least a part of the wall portion forming the accommodation space. The gas generation system includes an irradiation device that causes an artificial light L having a peak wavelength that is absorbed by the photocatalyst to emit light by supply of electric power, and irradiates the light-transmission wall with the emitted artificial light L, and a switch that selectively switches supply or stop of supply of electric power to the irradiation device.
Resumen de: US2025276903A1
Process for producing syngas comprising the steps of:a) burning methane or natural gas with oxygen and optionally with water steam for producing flue gas comprising CO2 and H2O according to the following reaction:CH4+2O2→CO2+2H2O1b) cooling the flue gas coming from a) by heat exchange with a water stream which is thereby vapourised;c) condensing and removing water from the flue gas, coming from step b), thereby obtaining a mixture consisting essentially of CO2;d) carrying out an electrolysis of a steam stream in a solid oxide electrolytic cell (SOEC), whereby steam is split into oxygen gas and hydrogen gas according to the following reaction scheme:H2O(g)→H2+1/2O22e) separating and drying hydrogen gasf) carrying out a reverse water gas shift reaction between CO2 coming from step c) with H2 coming from step e) according to the following scheme:CO2+H2→CO+H2O.3
Resumen de: US2025276905A1
Method for recovering waste heat created in the production of ammonia, the method comprises the steps of(a) providing an ammonia synthesis gas including the steps of electrolysis of water or steam for the preparation of hydrogen and of adding a stream of nitrogen into the hydrogen;(b) converting the ammonia synthesis gas to ammonia;(c) recovering at least a part of waste heat from the electrolysis in step (a);(d) upgrading the waste heat from step (c) by heat recovered from one or more compressor stages discharge and/or waste heat created in the conversion of the ammonia synthesis gas in step (b) and/or waste heat from a turbine condenser utilizing steam generated in step (b); and(e) distributing the upgraded waste heat from step (d) to a downstream heat utilizing step.
Resumen de: US2025279726A1
An electrolysis plant includes an electrolyzer and a circuit assembly which has an input for connecting to an external DC source and an output connected to the electrolyzer. The circuit assembly has a transformer with an inverter connected on the primary side and a rectifier connected on the secondary side, such that a direct current can be supplied to the electrolyzer. There is also described a plant network with a electrolysis plant and a renewable energy plant that is directly connected to the electrolysis plant.
Resumen de: AU2024291100A1
The invention relates to an energy supply system (20) for coupling to a wind turbine (30) used in island mode, wherein the wind turbine (30) is configured to operate an electrolysis system (11) for producing green hydrogen using wind energy, wherein the energy supply system (20) has a solar energy source (21), comprising a photovoltaic module (22) and/or a solar thermal collector (23), which is configured to supply the electrolysis system (21), in particular an enclosure (12) and water-conducting lines of electrolysis units of the electrolysis system (11), with thermal energy in the event of the absence of wind energy. The invention also relates to a corresponding method for supplying solar energy to a wind turbine (30) used in island mode.
Resumen de: AU2024318321A1
The invention relates to an electrolysis system (10) comprising a plurality of electrolysis devices (34, 36) which are connected to a power supply line (30), the electrolysis devices (34, 36) having a power supply unit (38, 40) and an electrolysis module (12, 14, 16, 18, 20, 22, 24, 26) coupled to the power supply unit, the power supply units of the electrolysis devices comprising a transformer (42, 44, 46, 48) and a rectifier unit (50, 52, 54, 56, 58, 60, 62, 64), the transformer having a primary winding (66, 68, 70, 72) and a secondary winding (74, 76, 78, 80, 82, 84, 86, 88) connected to an AC voltage side of the rectifier unit. According to the invention, the primary winding of the transformer of at least a first of the electrolysis devices (40) is designed to be adjustable in stages, and the rectifier unit of said electrolysis device is designed to be operated in an uncontrolled manner, the rectifier unit of the power supply unit of at least a second of the electrolysis devices being designed to be operated in a controlled manner depending on the electrical energy that can be provided by the energy source.
Resumen de: AU2024230333A1
The present invention relates to a method for purifying an oxygen stream polluted by water, hydrogen and potentially nitrogen, said method comprising bringing the oxygen stream to be purified into contact with a zeolitic adsorbent material comprising at least one metal, in zero-valent metal form, or in oxidized form or in reduced form, and recovering purified oxygen streams. The invention also relates to the use of a zeolitic adsorbent material comprising at least one transition metal for the purification of oxygen, and to the use in industrial processes of oxygen thus purified.
Resumen de: AU2024230439A1
The present invention relates to a method for purifying a hydrogen stream polluted by water, oxygen and optionally nitrogen, said method comprising bringing the hydrogen stream to be purified into contact with a zeolite adsorbent material comprising at least one metal chosen from the metals from columns 3 to 12 of the periodic table of the elements, in zero-valent metal form, or in oxidized form or in reduced form, and recovering a purified hydrogen stream. The invention also relates to the use of a zeolite adsorbent material comprising at least one metal from columns 3 to 12 of the periodic table of the elements for the purification of hydrogen, and to the use of hydrogen thus purified in industrial processes.
Resumen de: AU2024224275A1
A process for the reaction of aluminium with water comprising the steps of adding aluminium metal to an aqueous solution comprising potassium hydroxide at a concentration of between 0.1M and 0.4M and a surfactant; agitating the mixture of previous step; and collecting generated hydrogen. A composition for use in such a process for reacting aluminium with water, comprising potassium hydroxide and a surfactant.
Resumen de: AU2024209628A1
The invention provides devices, systems, and methods for providing hydrogen gas mixtures to a subject. The invention allows hydrogen gas mixtures to be provided at a rate that does not restrict normal or even elevated breathing.
Resumen de: WO2025183649A1
The invention relates to a pure hydrogen gas production system (A) for use in hydrogen production technologies, including applications such as energy storage, fuel cells, and industrial chemical processes. The system (A) is characterized by including at least one top cover (10) that encloses the upper portion of the system and protects its internal components from external factors, and at least one bottom cover (20) that encloses the lower portion of the system, ensuring the stable and secure positioning of the electrolysis cell. It also features a water inlet (30) that allows the introduction of water containing potassium hydroxide into the system (A), at least one anode (60) functioning as the positive electrode, and at least one cathode (70) functioning as the negative electrode during the electrolysis process. Conductive plates (100) are included to ensure efficient transmission of electrical current to the electrolysis cell, along with at least one sealing element (101) positioned between the conductive plates (100) to ensure the liquid- tightness of the electrolysis cell. Furthermore, an anion exchange membrane (90) with high selectivity and permeability is positioned within the void (102) of the conductive plates (100). This membrane purifies the HHO gas generated by the electric current passing between the anode (60) and the cathode (70) during electrolysis, separating water molecules and extracting pure hydrogen gas.
Resumen de: WO2025183215A1
The present invention provides a catalyst-layer-equipped electrolyte membrane and an application of the same, said catalyst-layer-equipped electrolyte membrane comprising: an anode catalyst layer containing an ionomer and an anode catalyst component that is composed of iridium-containing manganese dioxide, the molar ratio of iridium to manganese in the anode catalyst component being 0.011-0.182, and the logarithm log(amount of ionomer/amount of anode catalyst component) of the ratio of the amount of the ionomer to the amount of the anode catalyst component being −1.40 to −0.46; a proton exchange membrane; and a cathode catalyst layer.
Resumen de: WO2025183169A1
A laminate according to the present invention comprises a porous metallic body on an electrolyte membrane. Fine metal particles are included at least in pores and/or in the electrolyte membrane-side surface of the porous metallic body. The average pore size of the porous metallic body is preferably 0.5-100 μm. The average particle size of the fine metal particles is preferably 5-200 nm. The thickness of the porous metallic body is preferably 1-500 μm. In addition, a fine metal particle layer is preferably provided between the electrolyte membrane and the porous metallic body. The porous metallic body is preferably a metal foam or a metal fiber mat.
Resumen de: WO2025183341A1
The present invention relates to a reverse electrodialysis-based water electrolysis apparatus capable of producing hydrogen and oxygen with a small amount of electricity consumption and generating electricity in an eco-friendly manner by introducing an exchange membrane having an electrode layer bonded to the surface thereof. The reverse electrodialysis-based water electrolysis apparatus of the present invention may be economically feasible by producing hydrogen and oxygen with a small amount of electricity consumption, and can reduce environmental pollution by generating electricity in an eco-friendly manner. In addition, hydrogen can be produced by using seawater, thereby securing economic feasibility.
Resumen de: WO2025182228A1
The present invention provides: an operation method for an electrolysis device that is able to quickly reach a rated load; a control device for an electrolysis device; and an electrolysis system. Provided is an operation method for an electrolysis device (100) that is provided with a temperature adjuster (30), which adjusts the temperature of an electrolytic solution supplied to an electrolytic cell (40), the electrolytic cell (40), which electrolyzes the electrolytic solution supplied thereto via the temperature adjuster (30), and a gas-liquid separator (20), which separates a gas and a liquid produced by the electrolytic cell (40), wherein in a state in which the electrolysis device (100) is stopped, warm water is supplied to the temperature adjuster (30).
Resumen de: WO2025183309A1
One embodiment of the present invention provides a system and method for producing hydrogen and biogas, capable of shortening the hydrogen production start time of a microbial electrolysis cell through techniques of determining the voltage application time at each step, monitoring electrochemically active microbial populations, and inhibiting methane conversion bacteria for hydrogen production, in order to shorten the stabilized culture period of the microbial populations through a single-chamber microbial electrolysis cell system.
Resumen de: WO2025182936A1
This apparatus for producing carbon dioxide is provided with: an anode which is provided on one side of an electrolyte membrane and generates protons from hydrogen; a cathode which is provided on the other side of the electrolyte membrane and generates hydrogen; a first liquid chamber which is provided between the anode and the electrolyte membrane and to which a first electrolyte solution that has absorbed carbon dioxide is supplied; and a second liquid chamber which is provided between the electrolyte membrane and the cathode and to which a second electrolyte solution is supplied. The anode is supplied with a gas that has a hydrogen concentration of less than 99 vol%.
Resumen de: WO2025181688A1
The present disclosure provides system and method for synthesis of green ammonia and other nitrogenous fertilizers derived from it including urea and nitric acid (as well as others that may be produced by any combination/reaction of these) by coupling renewable energy and Carnot battery with Solid-Oxide Electrolyser Cell (SOEC) and Direct Air Capture (DAC). 5 The system provides a solution for round-the-clock renewable energy using Carnot battery that provides both heat and power to run SOEC. The heat from Carnot battery is used by DAC to capture carbon dioxide from air. A nitrogen-oxygen generator may produce nitrogen using continuous power from Carnot battery. Ammonia may be produced by using hydrogen from SOEC, and nitrogen from the nitrogen-oxygen generator. Urea may be produced using 0 carbon dioxide from DAC and ammonia. Ammonia and oxygen from SOECs and nitrogen- oxygen generator may be used for synthesis of nitric acid, and other nitrogenous fertilizers. The process heat from ammonia and nitric acid synthesis is recycled back to the Carnot battery.
Resumen de: WO2025182682A1
A method for operating a water electrolysis apparatus that comprises an electrolytic bath for electrolyzing water, a hydrogen separator to which hydrogen generated in the electrolytic bath is guided, an oxygen separator to which oxygen generated in the electrolytic bath is guided, and a vent line for discharging gas from the hydrogen separator or the oxygen separator and a vent valve provided to the vent line, the method comprising: a step for halting electrolysis of water in the electrolytic bath; and a step for determining whether or not a first index indicating the amount of increase in the concentration of oxygen in gas in the hydrogen separator or the concentration of hydrogen in gas in the oxygen separator has exceeded a first threshold after the electrolysis has been halted. When the first index exceeds the first threshold, the pressure in the hydrogen separator or the oxygen separator is lowered to a first prescribed value by opening the vent valve.
Resumen de: JP2025128540A
【課題】形成時のクラックを少なくすることができ、さらに、水電解の高効率化・高耐久化が可能な電極触媒層を提供する。【解決手段】イオン交換膜型水電解用の電極触媒層は、触媒、導電性粒状物質、高分子電解質、及び、繊維状物質を有する。電極触媒層の厚み方向に沿った断面において、電極触媒層の厚みを3等分して得られる3つの領域を、電極触媒層の一方の表面側から順に領域1、領域2、領域3とし、領域1、領域2、領域3の空隙率をそれぞれ、V1、V2、V3とした場合に、V1<V2<V3を満たす。【選択図】図2
Resumen de: JP2025128597A
【課題】中性領域の水溶液中で安定且つ高い酸化触媒活性を示す水の酸化触媒を提供する。【解決手段】本実施形態に係る水の酸化触媒は、Fe-Ni系触媒を含み、前記Fe-Ni系触媒は、主成分であるNi(OH)2と、Fe元素と、アルカリ金属元素及びアルカリ土類金属元素のうちの少なくともいずれか一方の源とを、を含むことを特徴とする。【選択図】なし
Resumen de: WO2024137217A1
A new multilayer ion-exchange membrane comprising an ion-exchange membrane layer, a catalyst layer coated on a first surface of the ion exchange membrane, a first polyelectrolyte multilayer coated on the catalyst layer, and optionally a second polyelectrolyte multilayer coated on a second surface of the ion-exchange membrane for electrolysis applications has been developed.
Resumen de: CN120202324A
The invention relates to a stack module having at least one solid oxide electrolysis stack comprising a plurality of stacked solid oxide electrolysis cells, in which the stack module comprises two gas inlet connections and two gas outlet connections. According to the invention, at least one solid oxide electrolysis stack is encapsulated in a metal container, with two gas inlet connections and two gas outlet connections connected to the metal container. The invention further relates to a solid oxide electrolyzer having at least one stacked module and to a method for replacing a stacked module of a solid oxide electrolyzer.
Resumen de: EP4610397A1
The in-vehicle hydrogen generation unit represents a hydrogen production system designed specifically for Fuel Cell Electric Vehicles (FCEVs), marking a significant leap in sustainable transportation. During the electrolysis process, the byproduct oxygen is emitted into the atmosphere. Furthermore, the byproduct water generated during power generation using hydrogen is efficiently recycled back into the electrolysis system, creating a closed-loop and resource-efficient cycle. Notably, the electrolysis unit incorporates an integrated cooling system to maintain optimal operating temperatures during the electrolysis reaction.
Resumen de: EP4610400A1
A serially connected stack group is configured by serially connecting a plurality of water electrolysis stacks and at least one overcurrent interruption means, a series-parallel stack unit is configured by parallelly connecting at least three serially connected stack groups, and a water electrolysis stack group configured by serially connecting a plurality of the series-parallel stack units, is connected to a DC power supply.
Resumen de: GB2700064A
A system comprises an anaerobic digester 110 configured to process carbohydrate to produce carbon dioxide gas 112 and a digestate 114, wherein the digestate comprises a mixture of ethanol and water; a separator 120, such as a centrifuge, configured to separate the mixture of ethanol and water from the digestate; a distillation apparatus 130 configured to distil and separate the ethanol and the water; an electrolyser 140 configured to electrolyse the distilled water in order to produce hydrogen 142 and oxygen; and a reactor 150 configured to convert the carbon dioxide gas and hydrogen to produce methane or methanol. A solid residue is formed when the mixture of ethanol and water is removed from the digestate, wherein a furnace (180, Fig. 3) can be arranged to receive and burn the solid residue to produce carbon dioxide gas, which can then be provided to the reactor. The reactor may be a hydrogenator. The distillation apparatus may comprise a heat pump. Figure 1
Resumen de: EP4611202A1
The invention relates to a method for controlling an electrolyzing plant (10), comprising:- providing electric energy from an electric power network (32) with a network AC voltage;- rectifying the network AC voltage by a rectifying device (50, 52, 54, 56, 58, 60, 62, 64);- supplying water to the electrolyzing device (34, 36);- providing an AC filter current flow by an active filter device (100), wherein the AC filter current flow is controlled such that it conforms to network regulations of the electric power network;- measuring the network AC voltage by using a voltage sensor (128) which provides a respective voltage sensor signal;- comparing the voltage sensor signal with a first reference voltage value providing a comparing result;- depending on the comparing result, causing the active filter device (100) to emit electric energy to or to receive electric energy from the electric power network.
Resumen de: CN120202324A
The invention relates to a stack module having at least one solid oxide electrolysis stack comprising a plurality of stacked solid oxide electrolysis cells, in which the stack module comprises two gas inlet connections and two gas outlet connections. According to the invention, at least one solid oxide electrolysis stack is encapsulated in a metal container, with two gas inlet connections and two gas outlet connections connected to the metal container. The invention further relates to a solid oxide electrolyzer having at least one stacked module and to a method for replacing a stacked module of a solid oxide electrolyzer.
Resumen de: MX2025002906A
The disclosure pertains to a plant for the production of ammonia. The ammonia is produced from hydrogen obtained by electrolysis of water. The electrolysis is powered by a renewable source of energy, complemented with power obtained from the plant during periods of low or no availability of the renewable energy. To this end, the plant is configured such that it can be operated in a charge configuration (obtaining and storing power) and a discharge configuration (employing said power).
Resumen de: DK202430100A1
The present invention relates to boiling water reactors arranged to receive a synthesis gas for producing raw gas products, such as a raw methanol product, particularly for transient operation, such as where the synthesis gas is at least partly provided by producing hydrogen by electrolysis of water or steam. Embodiments of the invention include a boiling water reactor, a method of revamping an existing boiling water reactor, and a process for producing raw gas product, such as raw methanol product, utilizing the boiling water reactor.
Resumen de: MX2025008939A
The present disclosure relates to methods of sequestering CO<sub>2 </sub>comprising a first cathodic chamber, performing a first alkaline process, a first anodic chamber, performing a first acidic process, and dechlorinating a solution by contacting the solution with a dechlorinating agent. Also provided herein are systems comprising a first cathodic chamber and a first anodic chamber.
Resumen de: MX2025008965A
The present application relates to a flow field for use in an electrolysis cell comprising one or more sheets of porous material with a corrugated structure. The electrolysis cell comprises a membrane, an anode, a cathode, an anode reinforcement layer, a cathode reinforcement layer, an anode flow field, a cathode flow field, and a bipolar plate assembly comprising an embedded hydrogen seal. The anode flow field comprises one or more porous sheets having at least one straight edge and at least one of the porous sheets has the form of a corrugated pattern with a plurality of peaks and valleys whose axes are generally aligned with one straight edge of the sheet. The anode flow field geometry simultaneously provides resiliency, for efficient mechanical compression of the cell, and well-distributed mechanical support for the anode reinforcement layer adjacent to the anode flow field.
Resumen de: MX2025009748A
A hydrogen generating cell comprising an input electrode plate pair, an output electrode plate pair, an additional X plate electrode positioned adjacent the output electrode plate pair, and a plurality of intermediate electrode plates disposed between the input and output electrode plate pairs. A plasma torch is spaced apart from and inductively coupled to the input electrode plate pair. A pulsed DC voltage is applied to the plasma torch and X-plate, while a lower voltage pulsed DC voltage is applied to the input and output electrode plate pair to cause generation of hydrogen gas from an aqueous solution in which the cell is immersed.
Resumen de: US2025257489A1
A water electrolysis system includes: a water electrolysis stack that generates oxygen gas and hydrogen gas by electrolyzing water; a gas-liquid separator that separates the hydrogen gas from water; a hydrogen compression stack that compresses the hydrogen gas; a gas tank that stores an inert gas and is connected to a hydrogen flow path that connects the water electrolysis stack and the hydrogen compression stack; a supply valve that, when opened, supplies the inert gas to the hydrogen flow path; and a supply control unit that opens the supply valve in a case where the concentration of the oxygen gas that has flowed into the hydrogen flow path exceeds an oxygen concentration threshold determined in advance.
Resumen de: WO2024163636A1
The present disclosure relates to methods of sequestering CO2 comprising a first cathodic chamber, performing a first alkaline process, a first anodic chamber, performing a first acidic process, and dechlorinating a solution by contacting the solution with a dechlorinating agent. Also provided herein are systems comprising a first cathodic chamber and a first anodic chamber.
Resumen de: JP2025127400A
【課題】簡易な設備によって低コストで安定的に水素の生成が可能な水素の生成方法及び水素生成用鉄材を提供する。【解決手段】溶融鉄にフラーレンを含むナノカーボン材料を加えて生成した鉄材10と、pH2以下の水溶液20をタンク1内に収容して水素を生成する水素の生成方法。【選択図】図1
Resumen de: FR3159658A1
L’invention concerne un dispositif de surchauffe comprenant une chambre de combustion (10) comprenant une entrée de carburant, une entrée de comburant et une entrée de chaleur pour recevoir une chaleur à une température moyenne (Tm) comprise entre 150°C et 500°C, la chambre de combustion étant adaptée pour brûler le carburant pour chauffer et produire une chaleur (Th) à une haute température supérieure à 600°C. Application à la réalisation d’installations industrielles nécessitant une énergie thermique à haute température. Figure 1
Resumen de: CN120556077A
本发明公开了一种具有受阻路易斯酸碱对性质的核壳结构金属氧化物体相催化剂,所述催化剂由基底和活性组分构成,所述基底为导电基底,所述活性组分为Fe‑OH和Ni‑O双金属受阻路易斯酸碱对位点。该催化剂成本低廉,具有高效催化性能和稳定性。
Resumen de: CN120550470A
本发明公开了一种新型碱性电解槽外部过滤装置及方法,包括与电解槽形状、体积相适配的网罩结构,网罩结构包括支撑框架结构、过滤网结构,支撑框架结构设置在电解槽空间外围,过滤网结构敷设于支撑框架结构上,在电解槽外部形成空间过滤结构;智能动态清理系统包括清理动作组件和联动防护模块,清理动作组件对网罩结构清洁。本过滤装置通过与电解槽形状、体积相适配的网罩结构,利用桁架支撑柱与桁架梁形成稳定的空间框架,其间距设计既保障了电解槽外围的操作空间,又通过蜂巢六边形支撑网层与过滤网层的层叠结构,在确保过滤强度的同时,实现对电解液杂质的精准拦截,兼顾结构稳定性与过滤效率。
Resumen de: CN120556061A
本公开实施例提供一种基于调峰波谷发电的电解制氢合成氨系统,包括燃煤锅炉、汽轮机、发电机、脱硝装置、电解水装置、空分装置和合成氨装置;燃煤锅炉的蒸汽出口与汽轮机相连,燃煤锅炉的烟气出口与脱硝装置的第一入口相连;发电机的第一端与汽轮机相连,发电机的第二端分别与电解水装置和空分装置相连;发电机用于在火电厂调峰波谷时为电解水装置和空分装置供电;合成氨装置的第一入口与电解水装置的阴极出口相连,其第二入口与空分装置的氮气出口相连,其出口与脱硝装置的第二入口相连。该系统促进可再生能源与化石能源的互补利用,减少对传统化石燃料的依赖,推动能源结构向绿色低碳转型,实现能源结构优化,降低火电厂运营成本。
Resumen de: CN120556068A
本发明公开了一种兼具阳极甲醇氧化和阴极析氢的铁钴复合氧化物双功能催化剂及其制备方法和应用。包括以下步骤:S1,基底预处理;S2,前驱体溶液配制:将溶有硝酸钴六水合物的异丙醇溶液缓慢加入溶有硫酸亚铁七水合物的去离子水中,形成均一过渡金属盐前驱体溶液;S3,将泡沫镍完全浸入前驱体溶液中静置反应;S4,后处理。根据本发明,具有最优钴铁摩尔比的FeCoOx‑2催化剂在1.38V(vs.RHE)超低电位下即可产生100mA cm‑2电流密度,并在80小时恒电流测试中电位仅上升93mV,作为阳极MOR和阴极HER的双功能催化剂时,仅需要378秒就可以产生20mL氢气,产氢速率为53μL s‑1。
Resumen de: CN120556076A
本发明属于甲醇电解制氢技术领域,提供了一种RuSe2‑Pt双功能催化剂的制备方法。本发明通过在高比表面积碳上生长RuSe2,为硒化钌提供生长面积,同时高比表面积碳可以增强RuSe2‑Pt双功能催化剂的导电性;然后通过高比表面积碳上生长的RuSe2作为Pt的载体,提供种子位点,有利于Pt的负载,同时具有亲氧特性的RuSe2作为载体通过配体效应在低电位提供含氧物质,通过d带中心的下移来降低醇类氧化反应过程中产生的CO的吸附能力,提高Pt的利用率,进而增强RuSe2‑Pt双功能催化剂的催化性能;并且,RuSe2与Pt的协同效应和电子相互作用,可以调控Pt纳米颗粒周围电子密度,提高电催化性能。
Resumen de: CN120560033A
本发明公开了一种基于改进灰狼优化算法的PEM电解水制氢多变量模型预测控制方法及制氢系统,属于氢能制备控制领域。针对PEM制氢系统多变量耦合引起的控制超调与权重矩阵随机性问题,提出IGWO‑MPC双环控制架构:构建涵盖电流密度、温度、压力的全局模型,解析电解槽电压、温度及功率;采用加权最小二乘法对非线性效率进行抗差线性化,建立状态空间模型;通过改进灰狼算法动态优化MPC权重矩阵,结合收敛因子自适应调整策略,抑制多物理场耦合失稳。该方法突破传统经验赋权局限,使温度波动降低56.8%,产氢量提升4.89%,电解效率稳定于78%‑80%,有效提升大规模清洁能源制氢系统的控制精度与运行效率。
Resumen de: CN120556085A
本申请属于高熵电催化剂技术领域,具体涉及NF负载的高熵氧化物/MXene双功能电催化剂、制备方法及应用。本申请采用一步酒精燃烧法,将高熵氧化物和MXene负载在泡沫镍上,将得到的预产物Ⅱ在通风橱中使用明火点燃,反应燃烧完成后获得NF负载的高熵氧化物/MXene双功能催化剂。本申请的制备方法简单便捷,实用性强,易于合成,对环境友好,并且原料来源广、成本低。所制备的NF负载的(FeCoNiZnCe)Ox@MXene催化剂具有优异的HER、OER和UOR性能,可应用于电解水制氢领域,还可以进一步用于电催化尿素氧化领域,进一步扩大其应用范围。
Resumen de: CN120550804A
本发明提供了一种高效催化氨分解制氢的Ru/MgO‑La2O3催化剂及其制备方法和应用,属于氨分解制氢技术领域。该催化剂以贵金属Ru为活性组分,以MgO‑La2O3复合氧化物为载体,通过共沉淀法和浸渍法制备而成。所述催化剂中Ru的负载量为1‑20wt%,通过优化载体与金属‑载体相互作用,显著提升了Ru的分散性和氨分解反应活性。制备方法包括:将钌前驱体与MgO‑La2O3载体混合,经干燥、煅烧及还原处理,得到高分散的Ru/MgO‑La2O3催化剂。与现有贵金属基催化剂相比,本发明通过复合载体调控Ru的电子结构,使其在低温(350‑550 oC)下展现出优异的氨分解活性与稳定性,在450 oC时氨转化率可达99.5%,且在高温和高空速条件下仍保持高效全转化。该方法获得Ru/MgO‑La2O3催化剂在同等条件下优于大部分报道的催化剂,并且催化剂制备工艺简单、成本可控,适用于规模化生产,为氢能储运领域提供了高效经济的技术方案。
Resumen de: CN120550827A
本发明提供了Pr2TeO2在光催化制氢中的应用,属于光催化材料技术领域。本发明将Pr2TeO2作为光催化分解水制氢的催化剂,Pr2TeO2具有高度有序的晶体结构和较少的结构缺陷,晶体的有序性能减少电子在晶格中的散射,从而增强载流子的迁移率;同时Pr2TeO2拥有相对较窄的带隙,能够有效地吸收可见光,从而提高光催化效率,在光催化分解水制氢方面具有较大的优势。实施例的结果显示,本发明将Pr2TeO2作为光催化分解水制氢的催化剂,在模拟太阳光的照射下,Pr2TeO2连续五个小时的平均产氢速率可达52.14μmol·g‑1·h‑1,是TiO2产氢速率(5.04μmol·g‑1·h‑1)的十倍以上。
Resumen de: CN120556091A
本发明涉及电制氢技术领域,具体涉及一种海上风电的电解海水制氢装置及系统,该系统包括处理器和存储器,处理器用于处理存储在存储器中的指令实现以下步骤:对风电功率数据进行分类;确定功率强度权重和当前电量权重,并对并网功率进行调整;根据当前时刻下的风电功率数据和并网功率修正值,以及海上风电的电解海水制氢设备的电制氢装置的最大运行功率和最小运行功率,对海上风电的电解海水制氢设备的蓄电池进行充放电调整。本发明通过量化的功率强度权重和当前电量权重,自适应地设置了并网功率修正值,从而提高了并网功率调整的合理性,并通过增加的蓄电池的充放电调整,实现了电资源的循环利用,在一定程度上减少了弃风能源的浪费。
Resumen de: CN120556059A
本发明公开了一种节能型海水制氢装置,包括:电解槽、氧分离器和氢分离器;电解槽内设置有阳极组件和阴极组件,阳极组件包括阳极片和第一集气筒,阴极组件包括阴极片和第二集气筒;并且阴极片的表面负载有活性组分,所述活性组分包括镍、钼中的一种或多种;第一集气筒和所述第二集气筒的侧壁内部设置有叶片,叶片第一集气筒和所述第二集气筒旋转,使所述第一集气筒和第二集气筒内的电解液形成旋转上升的涡流,并将所述第一集气筒和第二集气筒外部的电解液均匀的从开口吸入。本发明可以提高制氢效率,实现功能减排,同时还可有效分离制的氧气和氢气。
Resumen de: CN120550583A
本发明涉及气液分离技术领域,具体是一种电解水制氢系统的气液分离装置,包括柜体相对两侧均固定连接有连接管,且两个连接管分别靠近柜体顶底两端,两个所述连接管之间设置有多个弯管,且多个弯管分别固定连接于柜体两相对内侧壁处,所述柜体相对两侧的多个弯管交错布置,冷却机组与所述柜体顶部固定连接,多个分离机构均位于所述柜体内部。本发明中,通过将气体利用连接管输送,使气体通过多个分离机构,使气体在经过分离机构时被分离机构冷却,使气体降温其中水汽凝结成液滴,而后利用收集机构对分离机构中冷凝出的液滴进行清理,从而便于分离气体中的水分。
Resumen de: CN120556056A
本发明涉及制氢技术领域,特别涉及一种水电解制氢电解槽,包括有端板、连杆一、连杆二、氧气管、氢气管和注水管等;两个端板之间固接有若干个连杆一;还包括有、注水管和电解单元;两个端板之间固接有若干个连杆二;两个端板上共同贯穿有氧气管、氢气管和注水管;氧气管上等距开有若干个通孔一;氢气管上等距开有若干个通孔二;注水管上等距开有若干个通孔三。本发明可在不拆解隔膜的情况下,完成对隔膜的清理,无需对各个组件进行拆解和重组,大幅减少人工成本;本发明将隔膜集成在隔板内,在发现隔膜损坏时,可将损坏的隔膜从隔板内取出,进行更换,无需将所有部件拆卸下来,提高更换效率。
Resumen de: CN120550829A
本发明公开了一种溶剂热法合成ZnSe/NiCo2O4光催化剂的方法,属于光催化析氢技术领域。本发明以NiCo2O4作为助催化剂合成ZnSe/NiCo2O4光催化剂,NiCo2O4作为一种半导体能够与ZnSe形成有效的二元异质结,使得光生载流子的分离效率显著提高,并且NiCo2O4具有多价态的共存镍和钴离子,可以提供更丰富的活性位点和优异的电化学性能,进而提升了ZnSe的光催化性能,相比于纯ZnSe,ZnSe/NiCo2O4光催化剂的析氢过电位明显降低,载流子分离效率提高,活性位点增加,光催化析氢活性显著提升。
Resumen de: CN120553668A
本发明公开了一种非晶镍钴铁磷酸盐阳极催化剂的制备方法及应用,属于碱性电解水制氢技术领域,包括以下步骤:(1)将过渡金属盐溶于溶剂中,搅拌,得到金属盐溶液;(2)将磷酸盐溶于溶剂中,搅拌,得到磷酸盐溶液;(3)将磷酸盐溶液加入金属盐溶液进行反应,用去离子水和乙醇洗涤,离心分离,干燥,得到非晶镍钴铁磷酸盐阳极催化剂;该非晶镍钴铁磷酸盐阳极催化剂的制备方法及应用,通过全水相绿色合成体系实现了工艺安全性提升和环境友好性优化,所得催化剂在AEM电解槽中展现优异性能,在2A/cm²电流密度下槽电压仅需1.87V,具有显著的工业化应用前景。
Resumen de: CN120553640A
本发明提出了一种基于多相反应耦合渣金电解高温高纯氢气制取系统及方法,其核心技术在于利用1600‑1800℃高温铁基熔体作为反应介质,将水蒸气通过底吹元件通入熔体发生热化学强制分解反应(Fe+H2O→FeO+H2↑)并可通过控制熔体氧活度制取高纯度氢气,同时通过氧活度检测装置可以实时调控反应条件;脱氧产物FeO则通过外加电场进行电化学还原(FeO→Fe+1/2O2)实现铁基介质的再生,形成可持续的氧转移循环。该系统创新性地采用光伏、风电等绿色电力作为能量来源,既满足了水分解吸热和熔渣电解的能耗需求,又实现了全过程零碳排放,有效打通了钢铁冶金与清洁能源生产的物质‑能量耦合通道,为钢铁行业低碳转型和绿氢规模化制备提供了具有工业可行性的技术方案。
Resumen de: CN120556083A
本发明属于电催化材料技术领域,具体公开了原位碳包覆硫化钴/硫化钴锌复合材料及制备方法和应用,制备方法包括如下步骤:将钴硝酸盐水合物和锌硝酸盐水合物和六亚甲基四胺溶解于脱碳水制备前驱体;前驱体进行硫化退火得到中间体产物;中间体用盐酸超声制得复合材料。本发明采用上述的原位碳包覆硫化钴/硫化钴锌复合材料及制备方法和应用,通过水热、煅烧、刻蚀,成功制备出具有多孔结构的原位碳包覆的硫化钴/硫化钴锌复合材料,改善了比表面积,提高了催化性能,由于碳包覆硫化钴/硫化钴锌复合材料在碱性电解质中避免被腐蚀,从而实现良好的耐久性和导电性。
Resumen de: CN120566564A
基于光伏发电的制氢控制方法、系统、设备及存储介质,涉及光伏制氢领域。方法包括:基于光伏发电系统的发电特性数据,将光伏发电系统的运行区域划分为稳定运行区域和波动运行区域;基于稳定运行区域的第一输出功率确定水电解制氢系统的基础运行参数,以及基于波动运行区域的第二输出功率确定动态调节参数;基于水电解制氢系统的运行数据计算能量转换效率,当能量转换效率低于目标效率时,确定影响能量转换效率的关键参数;根据关键参数生成目标调控策略,并控制水电解制氢系统按照目标调控策略进行运行。实施本申请提供的技术方案,使得水电解制氢系统在光伏发电波动工况下仍能保持稳定的运行状态,有效提高了系统的能量转换效率。
Resumen de: CN120556062A
本发明提供一种SOEC电解制氢耦合高温热储能系统,通过设置热储能子系统,能够储存并在需要时释放高温热能,且在第一换热器中,热能通过储热颗粒与水进行高效热交换,从而大幅减少原本需要用于电加热的电能消耗,有效解决SOEC电解制氢能耗居高不下的问题,从而减轻因电加热导致的系统复杂性问题。同时,第二换热器回收电解过程中氢气和氧气的冷却热能,并将其转化为水蒸气循环使用,有效解决了SOEC电解制氢热能利用不充分的问题,使得系统整体的热能转换效率得到显著提升。
Resumen de: CN120556058A
本发明涉及制氢设备的技术领域,特别是涉及一种制氢设备的极板固定装置,其能够方便对多个极板进行检查并能够快捷的拆下指定的极板,操作更架简单方便;包括多个极板;还包括两个下横板、两个上横板、门型框架、多个插销孔、多个插杆、两个横杆和多个锁定螺栓,两个上横板位于两个下横板的上方,门型框架的下端通过一个横杆与两个下横板的左端插装连接,门型框架的上端通过另一个横杆与两个上横板的左端插装连接,多个锁定螺栓穿过门型框架与两个下横板和两个上横板螺接,多个极板的左右侧壁的上端和下端均设置插销孔,多个插杆分别穿过两个下横板和两个上横板的插孔插装在多个插销孔中,将多个极板平行安装在两个下横板和两个上横板之间。
Resumen de: CN120562204A
本发明属于海洋工程与氢能装备技术领域。本发明融合多学科前沿技术。利用高精准度的分布式传感网络与专业监测模块采集数据,通过区块链技术保障数据真实可靠;借助多物理场耦合模型和先进求解器,精准捕捉平台运行中的复杂物理过程。结合仿生控制、深度强化学习算法,实现动态响应预测与多目标优化。构建综合评估体系并依托数字孪生形成预警决策闭环。该方法突破传统评估局限,有效提升浮式制氢平台在多变海况下运行的安全性与制氢效率,为海上氢能产业发展提供关键技术支撑。
Resumen de: CN120556072A
本发明属于电解水制氢技术领域,具体涉及一种碳氧共掺杂管状多孔氮化硼载体负载单原子催化剂的制备方法及应用。本发明通过控制前驱体的沉淀速率形成了碳氧共掺杂管状多孔氮化硼,碳氧共掺杂管状多孔氮化硼具有纳米管状结构,Ru以单原子的形式分散在晶格中。这保证了结构的稳定性和表面活性位点的充分暴露。更重要的是,单原子与载体的相互作用可以通过电荷转移有效调节催化相材料电子状态,从而提高反应动力学。本发明解决了单原子催化剂在酸性条件下催化活性及稳定性较差,以及目前工业化电解水装置中使用贵金属基催化剂导致成本高昂的问题。
Resumen de: CN120553779A
本发明公开了一种利用纳米气泡辅助胶体磨宏量制备超分散镍铁水滑石粉体催化剂的方法,首先将预先通入纳米气泡的混合金属盐溶液和混合碱溶液在胶体磨机中搅拌,再通入纳米气泡老化,老化后离心取固态沉淀,固态沉淀经清洗,干燥即得NiFe‑LDHs材料。本发明利用胶体磨,在短时间内剧烈搅拌引发晶体的爆发成核,并通过纳米气泡发生器将带有负电荷的纳米气泡注入到反应物浆料中,快速实现浆料均匀分散的同时避免NiFe‑LDHs在老化过程中发生静电力聚集,最终获得超分散的NiFe‑LDHs粉体,实现催化剂的快速批量制备,所制备的超分散NiFe‑LDHs具有优异的电催化活性,在电解水制氢等领域具有广阔的应用前景。
Resumen de: CN120553754A
一种三元稀土共改性钒酸铋材料的制备方法,包括以下步骤;步骤1,将硝酸铋溶解于硝酸中,得到铋源溶液;将与Bi(NO3)3·5H2O等摩尔量的NH4VO3加入到离子水中完全溶解,得到钒源溶液;步骤2,在室温下将步骤1所制钒源溶液加入到铋源溶液中,期间持续搅拌,形成悬浊液;调节pH调整至7‑8,完成前驱体溶液的预处理过程;步骤3,将步骤2中悬浊液转移至水热反应釜中反应,离心、洗涤沉淀、干燥后得到钒酸铋材料;步骤4,对步骤3中洗涤完成的钒酸铋材料通过煅烧法或离子浸渍法引入稀土元素,得到三元稀土共改性钒酸铋材料。本发明有效解决了钒酸铋光生载流子运输效率低和电子空穴对复合率高的问题。并提高了钒酸铋的可见光催化能力。
Resumen de: CN120556071A
本发明公开了一种涂覆无析出相高熵氧化物颗粒制备电催化用电极的方法,该方法包括:一、金属氧化物粉末混合均匀;二、混合金属氧化物粉末加入去离子水混合均匀;三、将加水混合金属氧化物粉末液压成型;四、将块状金属氧化物高温固相反应;五、块状高熵氧化物研磨粉碎;六、高熵氧化物粉末颗粒涂覆,得到电催化用高熵氧化物电极。本发明综合液压成型及高温固相反应,利用液压成型中的高压强将固体氧化物粉末进行压制成型,便于后续高温固相反应中各原子的相互扩散与充分反应,有效避免了杂质相的析出,有利于获得无析出相的高熵氧化物,优化了电子结构,提高了表面催化活性,进一步涂覆成高熵氧化物电极,实现电催化性能的大幅提升。
Resumen de: CN120556057A
本发明公开了一种电解水制氢阴离子交换膜电解槽,包括槽体、设置在槽体内的耐碱腐蚀阳极电极、耐碱腐蚀阴极电极、阴离子交换膜和驱动机构,驱动机构包括双轴电机、摆动组件和往复运动组件,其中摆动组件实现耐碱腐蚀阳极电极的摆动,往复运动组件实现耐碱腐蚀阴极电极的往复运动。本申请中,双轴电机驱动摆动组件和往复运动组件同时运行,使得耐碱腐蚀阳极电极发生摆动,耐碱腐蚀阴极电极发生往复性运动,使得电极附近的电解液产生流动和扰动,这种动态变化打破了电极表面附近电解液的浓度边界层,加速了电解液中离子向电极表面的迁移以及反应产物从电极表面的扩散,从而提高了传质速率,使得电解反应能够更高效地进行。
Resumen de: CN120550839A
本发明涉及光催化的技术领域,公开了一种三元催化材料及其制备方法与应用、水分解制氢的方法以及氨分解制氢的方法。一种三元催化材料,所述三元催化材料包括氮化碳基体、氧化铁和硫化镉;其中,氧化铁和硫化镉以团簇形式生长于氮化碳基体上;氧化铁和硫化镉团簇的平均粒径为40‑80nm。该三元催化材料具有良好的催化活性,能够提高光催化产氢性能。
Resumen de: CN120550509A
本发明提供了一种气液分离装置,所述气液分离装置被设置适于依靠重力使水电解产生的混合物气液分离,所述气液分离装置包括罐体,所述罐体在竖直方向上的下部设置有液体容纳区域,所述气液分离装置还包括:设置于所述罐体内部的隔板,所述隔板的外周和所述罐体的内壁相贴合,所述液体容纳区域通过所述隔板分隔形成若干水平分布的子区域,所述子区域在任意一水平方向上设置有至少两个。该气液分离装置,通过在罐体内设置隔板,隔板将罐体内的液体容纳区域分隔形成若干子区域,液体容纳区域内的水在晃荡时,经隔板上的通孔在子区域之间流动,增加了对水的阻尼,进而降低液体容纳区域内晃荡的水位,以及水对罐体内壁壁面的砰击压力。
Resumen de: CN120556075A
本发明公开了一种镍钼合金纳米析氢催化剂的制备方法及应用,属于非贵金属析氢催化剂技术领域,包括:(1)将镍盐和钼酸盐溶解在混合溶剂中得到混合溶液,加入氨水并加热,将得到的产物分别用去离子水和乙醇洗涤,离心分离后进行干燥,得到钼酸镍前驱体;(2)将钼酸镍前驱体在还原气氛下还原,冷却后研磨,得到镍钼合金粉末析氢催化剂;该镍钼合金纳米析氢催化剂的制备方法及应用,通过调控化学计量比和利用双金属协同效应优化电子结构,在三电极体系中表现出较高的析氢反应活性,其性能接近商业Pt/C催化剂;作为AEM电解槽阴极时,在2 V槽压下实现>2 A/cm²的制氢电流密度,其性能与商业铂碳析氢催化剂相当。
Resumen de: CN120556090A
本申请提供的基于多参数动态调节的制氢控制方法和装置、设备及介质,涉及设备运行控制技术领域。在本申请中,首先,确定目标电解槽是否处于低电流密度状态;其次,在目标电解槽处于低电流密度状态时,对目标电解槽的电解液进行浓度检测,得到当前浓度值;然后,在当前浓度值大于参考浓度值时,沿着稀释后的电解液的浓度值接近参考浓度值的方向,对目标电解槽的电解液进行稀释操作,并对目标电解槽的电解液进行循环速度的增加操作,以实现对目标电解槽中电解液的动态调节。基于上述内容,可以改善现有技术中存在的低负荷下能效下降、气体纯度不足及设备腐蚀等问题,能够提高设备在低负荷下运行的安全性、可靠性和寿命。
Resumen de: CN120550821A
本发明公开一种用于高效光催化水分解析氢的单团簇多酸/三维有序大孔硫化镉耦合催化剂的简易制备方法。以室温浸渍法将Sb9在3DCdS上实现单团簇均匀分散,该耦合材料的制备方法简单,反应条件温和,成本低廉。在可见光驱动下6小时内水分解析氢产量可达206.2μmol是单独3DCdS的9倍。该材料的高比表面积和稳定的大孔结构为反应暴露了更多的活性中心,搭载的Sb9有效地抑制了载流子复合,进一步提升了催化剂在光催化中的催化活性,具有较好地应用前景。
Resumen de: AU2024211141A1
The invention provides an electrolyser system (10) comprising a heat storage unit (14) and an electrolyser (16). The heat storage unit (14) comprises at least one heat source infeed. The electrolyser (16) comprises at least one electrolyser cell (20), a steam inlet and at least one off-gas outlet. The off-gas outlet is connected to the heat source infeed to heat the heat storage unit (14). The heat storage unit (14) is configured to use its stored heat to produce steam for feeding into the steam inlet and for generating electrical power, either one at a time or both at the same time. The invention also provides a system comprising an intermittent or variable electricity source (12) and an electrolyser system (10) as defined above. The intermittent or variable electricity source (12) can be configured to power the electrolyser (16) and to heat the heat storage unit (14) via a heating element, either both at the same time or individually.
Resumen de: US2025276895A1
The gas generation system decomposes water in contact with the photocatalyst by sunlight to generate a mixed gas composed of oxygen gas and hydrogen gas. The gas generation system includes a housing having a light-transmission wall in which an accommodation space for accommodating water and a photocatalyst is formed. The light-transmission wall transmits the sunlight S that has directly or indirectly reached at least a part of the wall portion forming the accommodation space. The gas generation system includes an irradiation device that causes an artificial light L having a peak wavelength that is absorbed by the photocatalyst to emit light by supply of electric power, and irradiates the light-transmission wall with the emitted artificial light L, and a switch that selectively switches supply or stop of supply of electric power to the irradiation device.
Resumen de: CN120556089A
本发明涉及了一种Pt/Ru/RuO2异质结构金属气凝胶材料及其制备方法。该方法通过两步简单工艺实现:首先以硼氢化钠为还原剂,在水溶液中还原三氯化钌和氯铂酸钾,获得前驱体水凝胶;随后将水凝胶经冷冻干燥、退火处理,得到最终产物Pt/Ru/RuO2异质结构的金属气凝胶。该制备策略对传统硼氢化钠还原法进行改良,操作简便且耗时短,所使用的药品不仅无毒无害,成本也极为低廉。性能测试表明,Pt/Ru/RuO2异质结构金属气凝胶在电催化析氢(HER)和析氧(OER)反应中表现卓越:在10 mA·cm‑2的高电流密度下,HER和OER的过电位分别仅需17 mV和1840 mV;更值得注意的是,在该电流密度下连续测试24小时后,材料性能基本无衰减,展现出优异的稳定性。凭借上述优势,该材料在电解水等能源转化领域具有广阔的应用前景。
Resumen de: US2025263846A1
To provide a water electrolysis stack capable of suppressing deterioration in sealability. A water electrolysis stack configured by laminating a plurality of water electrolysis cells to generate hydrogen by supplying water to the water electrolysis cell and applying electric power, wherein a laminated member for improving sealing property, which is a member that does not introduce water therein, is laminated at a predetermined position of the water electrolysis cell to be laminated.
Resumen de: US2025266534A1
A water electrolysis system includes: a water electrolysis device including a membrane electrode assembly formed by sandwiching an electrolyte membrane between an anode and a cathode, the water electrolysis device being configured to generate oxygen gas at the anode by supplying water to the cathode and electrolyzing the water; and a water supply device configured to supply, to the anode, water generated in association with power generation of a fuel cell stack.
Resumen de: CN120550825A
本发明公开了一种采用溶剂热法合成Mn0.43Cd0.57S/Cu2MoS4光催化剂的方法,属于催化剂技术领域。本发明先以氧化亚铜为模板制备硫化钼铜,结合溶剂热法,合成了纯度高、结晶度好的硫化钼铜,然后以乙酸锰、乙酸镉、氢氧化钠和硫代乙酰胺为原料制备硫化镉锰,并在水热反应前加入硫化钼铜,通过构建异质结成功改性了硫化镉锰,合成了Mn0.43Cd0.57S/Cu2MoS4光催化剂,提高了硫化镉锰的光催化产氢速率。并且,本发明制备的Mn0.43Cd0.57S/Cu2MoS4光催化剂的产氢速率可达8233μmol/(g·h),为纯硫化镉锰产氢速率的2.08倍,硫化镉锰负载1%铂产氢速率的1.24倍。
Resumen de: CN120556063A
本发明公开了一种电解水制氢电极的综合处理设备,涉及电解水制氢电极的综合处理设备技术领域,包括外壳,所述外壳中空,所述外壳底部内壁安装有伺服电机,所述伺服电机与丝杆连接,所述外壳内侧的顶部设有洗涤室和吹扫室,所述洗涤室底部通过转动部密封,所述丝杆上滑动连接有连接座,所述连接座内嵌有升降杆,所述升降杆顶部安装有夹持件。本发明能够确保出水口始终对准电极,极大提高了电极洗涤效率,同时在转动部的作用下能够实现洗涤室与其他部件的隔离,避免影响其他设备;同时通过转动齿轮与驱动齿轮的配合将洗涤室打开,能够快速将电极转移至吹扫室内,实现电极的快速处理,极大提高了电极的处理效率。
Resumen de: CN120550815A
本发明属于钨合金技术领域,本发明具体公开了一种钨合金催化剂及其制备方法,本发明以钨粉、铁粉、钴粉、锰粉、氧化钇粉和氧化钛粉作为原料,以石墨烯作为活化剂,将其共混,而后经过碳酸氢铵、氢氧化铷特殊的造孔以及硝酸的侵蚀,而后包覆锡化物(热处理变成氧化锡),最后经过三次热处理,第一次热处理消除合金内部内应力,第二次热处理诱导亚稳金属间化合物生成,最后经过高温烧结,得到了具有优异的催化活性的钨合金催化剂,能够用于催化制氢。
Resumen de: CN120550747A
本发明公开一种基于等离子体炬直接加热与催化裂解的氨裂解器及其运行方法,包括等离子体炬、加热炉、氨催化装置、换热器、多个通气通道和管道;等离子体炬在启动阶段使用氮气放电,在工作阶段使用裂解气放电,产生的高温气体与氨气混合形成氨氮氢混合气,通入氨催化装置中,在催化剂作用下分解形成裂解气,高温氮氢混合气在换热器中与氨气换热提高能量利用效率;第一通气通道内设有第二通气通道、换热器,第二通气通道设有加热炉,第一第二通气通道内的介质吸收加热炉损失的热量;本发明的氨裂解器能够使用等离子体炬所产生的高温气体直接加热氨,加热效率高,装置紧凑,并且提高了能量利用效率。
Resumen de: WO2024257430A1
The present invention reduces unburned ammonia when ammonia is used as fuel. A combustor (10) comprises: a burner (11) that injects fuel containing ammonia into a combustion space (S); and a refractory material (12) that defines at least a portion of the combustion space (S). The refractory material (12) blocks passage of combustion gas, and the refractory material (12) contains a catalyst (C), which decomposes ammonia into hydrogen and nitrogen, on a surface (1b) that defines at least a portion of the combustion space (S).
Resumen de: CN120550837A
本发明提供了一种耐海水腐蚀NiP/Cu催化剂及其制备方法和应用,属于新能源技术领域。本发明提供的耐海水腐蚀NiP/Cu催化剂的制备方法,包括:在铜基体表面进行电镀制备镍磷涂层,得到耐海水腐蚀NiP/Cu催化剂;所述电镀的电压为4.5~5.5V,电镀的时间为2.5~3.5min,电镀的温度为25~35℃;所述电镀所采用的电镀液中镍和磷的物质的量之比为1:(0.25~0.75)。本发明通过对电镀的电压、时间和温度进行优化,并调整电镀液中镍和磷的物质的量之比能够改善镍磷涂层的质量,从而提高了NiP/Cu催化剂的耐海水腐蚀性能。
Resumen de: CN120550869A
本申请的实施例公开了CQDs@HOF‑101复合微晶及其制备方法与应用,涉及光催化材料技术领域,旨在解决现有光催化材料光利用率较低的技术问题。所述CQDs@HOF‑101复合微晶的制备方法,包括以下步骤:将HOF‑101小分子1,3,6,8‑四(4‑羧基苯)芘均匀溶解在极性非质子溶剂中后,通过有机滤膜与碳点一同装入玻璃小瓶中,将小瓶开盖放置于装有醇类溶剂的烧杯中,待所述醇类溶剂进入有机溶剂中,并长出晶体后,离心得到沉淀,将所述沉淀进行洗涤,获得CQDs@HOF‑101晶体。
Resumen de: CN120556064A
本发明公开了一种高适用性的电解水制氢电极后处理方法,本发明操作简易、可行性高,可直接兼容至现有工艺,利用超声波处理、气体吹扫、机械震荡等方式,对现有电极直接新增一步处理工艺,改善电极表面形貌和催化剂结合状态,优化处理后电极的活性和稳定性,减小催化剂脱落刺穿隔膜和阻塞管道的风险;本发明适用性强,不受电极原有合成工艺及材料成分限制,对所有一体化电极均有效果;选用某一后处理方式后,结合本发明的参数确定流程,可针对特定电极厘清最佳操作参数范围,实现批量化处理;本发明成本低,环境友好,相对电极合成环节无复杂工艺流程,不产生污染性气体、液体,所收集废料经处理后可以重复利用。
Resumen de: CN120556070A
一种用于波动工况下电解海水制氢的催化剂及其制备方法,属于非贵金属催化剂及氢能制取领域。所述方法为:将基体置于刻蚀溶液中,通过刻蚀得到催化剂前驱体;催化剂前驱体合成后的洗涤与干燥;将催化剂前驱体放置于含有硫源的溶液中静置,取出后洗涤干燥即可。本发明通过#imgabs0#刻蚀和硫化将Fe和S分别均匀分布在Ni基底上获得新型高性能海水电解催化剂。电解过程中,界面元素自氧化形成#imgabs1#和NiFe LDH实现催化剂活性提高的同时抑制了海水中#imgabs2#对催化剂的腐蚀。由刻蚀得到的催化剂具有明显的树枝结构,在氧化电流下被氧化形成纳米片状的层状氢氧化物。
Resumen de: CN120556073A
本发明公开了一种含有氧缺陷的氧化钨负载铂纳米团簇催化剂的制备方法,包括如下步骤:将氯化钨分散在无水乙醇中,超声搅拌后使其充分溶解,将其转移至聚四氟水热釜中,反应结束后倒去上清液,将产物用去离子水和无水乙醇离心洗涤后放置干燥箱中干燥,得到氧化钨;将氧化钨溶解在去离子水中,搅拌一段时间,将铂的金属前驱体盐溶解分散后缓慢滴加至上述溶液中,搅拌进行反应;反应结束后将上述溶液离心,将得到的固体干燥,得到固体产物;将固体产物在惰性氛围下煅烧,得到最终产物。本发明实现了高效稳定的电解水析氢催化剂的制备;本发明所得催化剂为氧化钨负载的Pt纳米团簇电催化剂,该催化剂分散均匀,是一种良好的电解水析氢催化剂。
Resumen de: WO2025176298A1
Present invention relates to a method for the synthesis of ammonia, where a hydrogen (1) from an electrolyser (G) and a nitrogen (2) from a nitrogen production unit (D) are fed to a nitrogen-hydrogen mixture compression unit (A) and from there said mixture (3) is fed to an ammonia synthesis unit (B). Heat from steam-hydrogen steam from a electrolyser (G), heat generated during compression of the nitrogen-hydrogen mixture in the compressor stages of the nitrogen-hydrogen mixture compression unit, and heat released during the synthesis reaction in the ammonia synthesis unit, is used to generate steam for an electrolysis in the electrolyser. Liquid ammonia is separated from the circulation gas entering the separation unit from the steam generation unit using condensation at temperatures at an ambient environment temperature.
Resumen de: WO2025176414A1
The invention relates to a method for operating an electrolysis plant (1, 20) comprising an electrolyzer (11) for generating hydrogen (H2) and oxygen (O2) as product gases. Water is supplied as a reactant and is split into hydrogen (H2) and oxygen (O2) on a proton-conducting membrane (21) made of a fluorine-free polymer (24), said polymer (24) comprising a non-functional polymer material having a functional hydrophilic group, wherein a product gas flow (5) is formed in a phase mixture comprising water (H2O) and a respective product gas, and a product gas flow is fed to a gas separator (3, 13) connected downstream of the electrolyzer (11). The release of an ionic decomposition product of the functional hydrophilic group of the membrane (21) is determined over the operating time, the time curve of the concentration of said decomposition product is determined, and a measurement of the operational degradation of the proton-conducting membrane (21) as a result of a release of the ionic decomposition product of the hydrophilic group is determined. The invention additionally relates to a corresponding electrolysis plant (1, 20) and to a measuring system for carrying out the method.
Resumen de: WO2025176273A1
The various embodiments of the present invention disclose an electrolyser and a method for electrolysis of water. The system (100) comprises at least an electrolyser stack (101) producing a first gas-first electrolyte mixture at a first compartment of the stack (101), and a second gas-second electrolyte mixture at a second compartment of the stack (101). A first separator (103) receives the first gas-first electrolyte mixture via a first outlet (107) and separates a first electrolyte from a first gas. A second separator (104) receives the second gas-second electrolyte mixture via a second outlet (108) and separates a second electrolyte from a second gas. A first inlet (105c) transports at least the first electrolyte into the stack (101) and a second inlet (106c) transports at least the second electrolyte into the stack (101). A first suction line (105a) connects a first pump (109) and the first separator (103) and a first head line (105b) connects the first pump (109) and the first inlet (105c) of the stack (101). A second suction line (106a) connects a second pump (110) and the second separator (104), and a second head line (106b) connects the second pump (110) and the second inlet (106c) of the stack (101). An interconnect line (111) connecting the first head line (105b) and the second suction line (106a) is configured to supply a portion of the first electrolyte, at a predetermined mixing rate, from the first head line (105b) to the second suction line (106a). The predeter
Resumen de: WO2025177010A1
An apparatus for carrying out a chemical reaction, which includes a heat source configured to circulating a fluid and a fluidised reactor unit. The reactor unit includes a heat exchanger unit configured to receive the heated fluid to provide heat to the reactor unit, a fluidised bed, and an internally located particle separator.
Resumen de: US2025270123A1
A process for treating PFAS containing waste materials comprising vaporizing the PFAS containing waste materials during a reaction with fuel, oxygen and water, and then oxidizing the gaseous reaction product of those materials along with fuel, oxygen and water to break the fluorine bonds and oxidize the remaining components to carbon dioxide and water. In one embodiment the process further comprises the steps of electrolyzing the water exiting the process to produce hydrogen and oxygen, purifying both the hydrogen and oxygen streams, and then feeding the purified hydrogen and oxygen to hydrogen fuel cells to generate power.
Resumen de: US2025270722A1
Methods are for storing electricity and producing liquefied natural gas (LNG) or synthetic natural (SNG) and using carbon dioxide and for producing electricity, natural gas (NG) or SNG. The methods involve, starting from a water flow, producing an oxygen gas flow and a hydrogen gas flow by electrolysis in an electrolytic cell. A first hydrogen gas flow portion and a second hydrogen gas flow portion are obtained. The first hydrogen gas flow portion is allocated to a methanation step in the presence of carbon dioxide gas. A condensed recirculation water vapor flow is obtained to be allocated to the methanation step and performing methanation. The second hydrogen gas flow portion is allocated to a cooling and liquefaction step. A liquid hydrogen flow is obtained, which is stored in a liquid hydrogen tank.
Resumen de: US2025270151A1
A plant, such as a hydrocarbon plant, or synfuels plant, is provided, with effective use of various streams, in particular carbon dioxide and hydrogen. A method for producing a product stream, such as a hydrocarbon product stream, is also provided. The plant and method of the present invention provide overall better utilization of carbon dioxide and hydrogen, while avoiding build-up of inert components.
Resumen de: US2025270723A1
The invention relates to an electrolyser for generating hydrogen (H2) and oxygen (O2) as product gases, said electrolyser including an electrolysis module and a gas separator which is designed for phase separation of the product gas from water, the electrolysis module being connected to the gas separator via a product flow line for the product gas, and a return line, which connects the gas separator to the electrolysis module, being provided for the separated water. The gas separator is designed and positioned at a height difference (Δh) above the electrolysis module in such a way that, in the event of a standstill, the electrolysis module can be automatically flooded with water, driven solely by the height difference (Δh). The invention also relates to a method for operating an electrolyser including an electrolysis module, wherein, in a standstill mode, the electrolysis current is stopped, and a safety deactivation is initiated.
Resumen de: US2025270117A1
A water processing system includes an ultrafiltration membrane device (UF membrane device), a reverse osmosis membrane device (RO membrane device), an electric deionization device (EDI device), and an information processing device (edge computer). The information processing device controls operations of the ultrafiltration membrane device, the reverse osmosis membrane device, and the electric deionization device based on information on a water electrolysis device that obtains hydrogen by subjecting water to electrolysis. Water that is processed by the electric deionization device is supplied to the water electrolysis device. The water electrolysis device is able to obtain hydrogen by subjecting supplied water to electrolysis.
Resumen de: US2025273961A1
A carbon-free energy supply system generates hydrogen from electricity generated by a floating offshore photovoltaic power generation plant, synthesizes energy carriers using the hydrogen as a raw material, stores the energy carriers, converts the energy carriers into a predetermined energy form to supply the energy to each of the supply destination facilities. The floating offshore plant is composed of multiple photovoltaic panels, each of which is substantially hexagonal in plan view, by connecting the photovoltaic panels in a honeycomb structure in plan view. Each photovoltaic panel functions as a floating body, panel housings of the adjacent photovoltaic panels are capable of swinging relative to each other in a vertical direction, and each photovoltaic panel can be submerged and floated to a predetermined depth by pouring water into and draining water from the panel housing.
Resumen de: AU2025217260A1
Embodiments of the invention relate to systems and methods for producing hydrogen gas and/or liquid fuels using electrolysis. Embodiments of the invention relate to systems and methods for producing hydrogen gas and/or liquid fuels using electrolysis. ug u g m b o d i m e n t s o f t h e i n v e n t i o n r e l a t e t o s y s t e m s a n d m e t h o d s f o r p r o d u c i n g h y d r o g e n g a s a n d o r l i q u i d f u e l s u s i n g e l e c t r o l y s i s
Resumen de: US2025270108A1
Disclosed herein is a method for producing a palladium (Pd) decorated two-dimensional (2D) transition metal dichalcogenide (TMD) composite. The method includes steps of, (a) providing 2D TMD nanosheets; (b) dispersing the 2D TMD nanosheets in water to form a dispersion; (c) mixing the dispersion with palladium acetate to form a mixture; and (d) subjecting the mixture to sonication to deposit Pd nanoparticles on the 2D TMD nanosheets thereby forming the Pd decorated 2D TMD composite. Also disclosed herein is a method of producing hydrogen from an aqueous solution. The method includes electrolyzing the aqueous solution in an electrochemical cell characterizing in having an electrode made from the present Pd decorated 2D TMD composite.
Resumen de: US2025262610A1
According to the embodiments of the present disclosure, an ammonia decomposition catalyst may be prepared by performing heat treatment on alumina, a lanthanum compound and a cerium compound in a reducing gas atmosphere to form a composite oxide on an alumina support, and supporting an active metal including ruthenium on the composite oxide.
Resumen de: JP2024028790A
To provide a hydrogen generation system that generates hydrogen from raw water.SOLUTION: A hydrogen generation system includes pure water generating means for generating pure water from raw water, hydrogen generating means for generating hydrogen from the pure water generated by the pure water generating means, and hydrogen storage means for storing hydrogen generated by the hydrogen generating means.SELECTED DRAWING: Figure 1
Resumen de: WO2025178924A1
A system and method to precipitate calcium hydroxide at low temperatures (T < 40 °C) using an electrolytic reactor with hydrodynamic separation. The calcium can be supplied by any calcium bearing material such as calcium carbonate or basalt rock, or from industrial wastes such as brine or steel slag. The solid feedstock undergoes dissolution, whereas the brine may be utilized as is. Once in solution, the feed stream is directed towards an electrolyzer reactor which comprises a cathode, an anode, and a membrane separator. At the cathode, or in a separate precipitation chamber, an alkaline catholyte solution containing calcium hydroxide (portlandite) and magnesium hydroxide (brucite) precipitates, and hydrogen gas is produced.
Resumen de: WO2025179041A1
Particular embodiments described herein provide for a synthetic fuel creation system. The synthetic fuel creation system includes a syngas creation station to create syngas, a crude creation station to create heavy syncrude, and a crude cracking station to convert the heavy syncrude into synthetic fuel. The synthetic fuel creation system can use an electrocatalysis system to create the syngas and the electrocatalysis system can include an anode, a cathode, oxygen evolution reaction catalysts, hydrogen/carbon monoxide evolution reaction catalysts, and an electrolyte, where the hydrogen/carbon monoxide evolution reaction catalysts include a graphitic carbon nitride.
Resumen de: WO2025178748A1
A system and a method are disclosed. The system includes a plurality of reversible energy conversion devices, a cryotank configured to store a liquefied fuel comprising hydrogen therein, a liquefier, and a fueling station for hydrogen-based vehicles. The cryotank, the liquefier, the plurality of reversible energy conversion devices, and the fueling station are fluidly connected. Each reversible energy conversion devices is individually controlled and is configured to reversibly convert hydrogen gas into electricity and convert electricity to hydrogen gas. The system also includes at least one interconnect configured to be connected with to a power grid, a data center, or an energy storage.
Resumen de: WO2025177951A1
Problem The present invention provides a diaphragm for alkaline water electrolysis in which an inorganic compound for imparting hydrophilicity is not likely to fall off from an organic polymer porous membrane. Solution In this diaphragm for alkaline water electrolysis, a thin film that is derived from a titanium alkoxide and/or a zirconium alkoxide is adhered to an organic polymer porous membrane. The organic polymer porous membrane is a polysulfone-based porous membrane or a polyphenylsulfone-based porous membrane, and is supported by a wet nonwoven fabric that has polyphenylene sulfide fibers as constituent fibers. The organic polymer porous membrane supported by the wet nonwoven fabric is immersed in a diluent that is obtained by dissolving a solute, which is composed of a titanium alkoxide and/or a zirconium alkoxide, in a solvent and has a concentration of 0.1-20 vol%. Thereafter, in a situation where the solute is not precipitated, a heat treatment is performed so as to obtain a diaphragm for alkaline water electrolysis, in which a thin film that is derived from a titanium alkoxide and/or a zirconium alkoxide is adhered to the organic polymer porous membrane.
Resumen de: WO2025175829A1
Disclosed in the present invention is a system for preparing a hydrogen and oxygen mixed combustible gas from water, comprising a water tank, a first storage tank, a second storage tank and an electrochemical reactor. The water tank is connected to a feeding port of the electrochemical reactor via a water pipe. The electrochemical reactor is provided with a first gas outlet and a second gas outlet, the first gas outlet being connected to the first storage tank via a pipe, and the second gas outlet being connected to the second storage tank via a pipe. The first storage tank and the second storage tank are separately connected to a main discharge pipe via pipes, and a discharge port of the main discharge pipe is connected to a fuel gas storage tank. The electrochemical reactor is connected to a control apparatus. The present invention has the beneficial effects of effectively reduced production cost, capability of having the properties of combustibility, high calorific value, combustibility in an oxygen-deficient state and the like, and no pollution after combustion such that the hydrogen and oxygen mixed combustible gas is a novel efficient and environment-friendly clean energy.
Resumen de: WO2025175519A1
Provided in the present application are a two-dimensional 1T-phase molybdenum disulfide nano material, a preparation method therefor, and the use thereof. The two-dimensional 1T-phase molybdenum disulfide nano material satisfies the following conditions: the monolayer ratio of the molybdenum disulfide is 97% or above, the content of the 1T-phase molybdenum disulfide represented by X-ray photoelectron spectroscopy is 90% or above, and the surface has defects. The monolayer ratio of the two-dimensional molybdenum disulfide nano material being 97% or above indicates that the proportion of monolayer molybdenum disulfide nanosheets in the nano material is very high; the mass content of the 1T-phase molybdenum disulfide being 90% or above indicates that the nano material has good metallicity; and meanwhile, the presence of defects on the surface of the nano material indicates that the nano material has good dispersibility in solvents and also has good electrocatalytic performance, especially having excellent electrocatalytic hydrogen evolution performance under an industrial current density; the catalytic performance of the nano material is better than that of commercial Pt/C and even can be kept stable for 100 h without deterioration; thus, the nano material is one of the most superior non-precious-metal hydrogen evolution catalysts at present.
Resumen de: US2025270461A1
A process for producing syngas with a H2/CO ratio of from 0.5 to 3.5, comprising:a) generating steam by burning hydrogen and oxygen in the presence of steam in a H2 burner,b) quenching the effluents from step a);c) conducting an electrolysis on steam from step b) in a solid oxide electrolytic cell (SOEC) thereby obtaining hydrogen and oxygen,d) cooling wet hydrogen gas coming from step c) and removing water by condensation;e) carrying out a reverse water gas shift reaction with hydrogen gas coming from step d) with CO2, coming from an external source, thereby obtaining syn gas;f) cooling wet syngas coming from step e) and removing water by condensation thereby obtaining dry syngas.
Resumen de: US2025270717A1
Disclosed herein is a method for producing a platinum (Pt) decorated single-layer transition metal dichalcogenide (TMD) composite. The method includes steps of, (a) mixing single-layer TMD nanosheets with a reducing agent, K2PtCl4, and water to form a mixture, wherein the reducing agent and the K2PtCl4 are present in a molar ratio of 3:2 in the mixture; and (b) irradiating the mixture of step (a) for about 0.1-2 hrs to allow the growth of Pt nanoparticles on the single-layer TMD nanosheets thereby forming the Pt decorated single-layer TMD composite. Also disclosed herein is a method of producing hydrogen from an aqueous solution. The method includes electrolyzing the aqueous solution in an electrochemical cell characterizing in having an electrode made from the present Pt decorated single-layer TMD composite.
Resumen de: US2025270721A1
The invention provides a high-capacity, dry-charged, ready-for-instant-activation-by-adding-water, recyclable and safe electrochemical device and a method for producing hydrogen and electrical energy on demand, based on electrochemical interactions of magnesium, water and sulfuric acid, with an automatic control of the electrolyte's temperature, acidity and level inside the device.
Resumen de: US2025270710A1
A water electrolysis system includes: a water electrolysis device for electrolyzing water; a gas-liquid separator for performing gas-liquid separation of a mixed fluid of hydrogen gas and water, the mixed fluid being led out from the water electrolysis device; a dehumidifier for dehumidifying the hydrogen gas separated from the mixed fluid by the gas-liquid separator; a delivery path for delivering the hydrogen gas dehumidified by the dehumidifier; a humidifier for humidifying the hydrogen gas delivered through the delivery path; and a compression device for compressing the hydrogen gas humidified by the humidifier.
Resumen de: US2025270124A1
A process for treating waste materials and generating electrical power from simultaneously comprising reacting the waste materials during a reaction with fuel, oxygen and water, and then oxidizing the gaseous reaction product of those materials along with fuel, oxygen and water. In one embodiment the process further comprises the steps of electrolyzing the water exiting the process to produce hydrogen and oxygen, purifying both the hydrogen and oxygen streams, and then feeding the purified hydrogen and oxygen to hydrogen fuel cells to generate power.
Resumen de: GB2638622A
A hydrogen production facility 10 and associated method of use is disclosed, comprising a plurality of electrolyser stacks 12. The stacks 12 are for electrolyzing water, generating a hydrogen-aqueous solution mixture. A hydrogen separator 2 arrangement is described for producing a flow of hydrogen from the hydrogen-aqueous solution mixture. The hydrogen separator 2 arrangement comprises a plurality of first stage hydrogen collector separators 20,22, where the first stage hydrogen collector separators are fluidly coupled to a respective sub-set of the plurality of electrolyser stacks. The plurality of first stage hydrogen collector separators 20,22 are also fluidly coupled to a downstream hydrogen buffer vessel 28. The hydrogen separator 2 arrangement may comprise one or more hydrogen coalescing devices 16. A pressure balancing line 24 can also be provided between oxygen 22 and hydrogen separators 20 - it may also extend between hydrogen 28 and oxygen buffer 30 vessels.
Resumen de: GB2638621A
A hydrogen production facility 10 and associated method of use is disclosed, comprising a plurality of electrolyser stacks 12. The stacks 12 are for electrolyzing water, generating a hydrogen-aqueous solution mixture. A hydrogen separator 2 arrangement is described for producing a flow of hydrogen from the hydrogen-aqueous solution mixture. The hydrogen separator 2 arrangement comprises a plurality of first stage hydrogen collector separators 20,22, where the first stage hydrogen collector separators are fluidly coupled to a respective sub-set of the plurality of electrolyser stacks. The plurality of first stage hydrogen collector separators 20,22 are also fluidly coupled to a downstream hydrogen buffer vessel 28. The hydrogen separator 2 arrangement may comprise one or more hydrogen coalescing devices 16. A pressure balancing line 24 can also be provided between oxygen 22 and hydrogen separators 20 - it may also extend between hydrogen 28 and oxygen buffer 30 vessels.
Resumen de: US2024194916A1
A hydrocarbon feed stream is exposed to heat in an absence of oxygen to the convert the hydrocarbon feed stream into a solids stream and a gas stream. The gas stream is separated into an exhaust gas stream and hydrogen. The carbon is separated from the solids stream as a carbon stream. Electrolysis is performed on a water stream to produce an oxygen stream and hydrogen. The oxygen and a portion of the carbon are combined to generate power and a carbon dioxide stream. At least a portion of the carbon stream, cement, and water are mixed to form a concrete mixture. The concrete mixture can be used to produce ready-mix concrete and precast concrete. Carbon dioxide used for curing the concrete can be sourced from the carbon dioxide stream produced by power generation.
Resumen de: AU2023389305A1
The present invention relates to an alkaline anion exchange membrane precursor (pAAEM) comprising a blend of at least one first polymer (P1) comprising repeating units derived from acrylonitrile and at least one second polymer (P2) comprising repeating units derived from a vinyl lactam, and an alkaline anion exchange membrane (AAEM) obtained therefrom.
Resumen de: US2024133066A1
An electrolysis cell system includes a cathode portion configured to output a cathode exhaust stream, an anode portion configured to output an anode exhaust stream, a sensor configured to detect a concentration in an exhaust stream and to output sensor data, wherein the sensor is either a hydrogen concentration sensor configured to detect a hydrogen concentration in the cathode exhaust stream or a water concentration sensor configured to detect a water concentration of the anode exhaust stream, and a controller. The controller is configured to receive the sensor data from the sensor and, based on the sensor data, control at least one of (a) an air pressure adjustment device to adjust a pressure of air entering the anode portion or (b) a steam pressure adjustment device to adjust a pressure of steam entering the cathode portion.
Resumen de: WO2025173338A1
This pretreatment method comprises, prior to incorporating a mesh plate (80) into a cell, exposing the mesh plate (80) to ultrasonic waves while the mesh plate (80) is immersed in water. Hydrophilicity of the mesh plate (80) is thereby improved. Stagnation of gas in the mesh plate (80) when an electrochemical reaction is performed in a cell can therefore be suppressed. The efficiency of an electrochemical reaction in a cell can be improved as a result.
Resumen de: WO2024086793A1
The present disclosure provides a catalyst, methods of manufacturing the catalyst, and methods for using the catalyst for ammonia decomposition to produce hydrogen and nitrogen. The catalyst may comprise an electrically conductive support with a layer of one or more metal oxides adjacent to the support and at least one active metal adjacent to the layer. Methods are disclosed for deposition of metal oxide and active metal, drying and heat treatment. The method of using the catalyst may comprise bringing ammonia in contact with the catalyst in a reactor. The catalyst may be configured to be heated to a target temperature in less than about 60 minutes, by passing an electrical current through the catalyst. The method of using the catalyst may comprise bringing the catalyst in contact with ammonia at about 450 to 700 °C, to generate a reformate stream with a conversion efficiency of greater than about 70%.
Resumen de: EP4606931A1
The present disclosure relates to a hydrogen production control system and method, and a storage medium. The hydrogen production control system includes a safety controller, a first valve and a second valve respectively connected to the safety controller, a hydrogen-production controller, a third valve and a fourth valve respectively connected to the hydrogen-production controller, an oxygen-side gas-liquid separation apparatus respectively in communication with the first valve and the third valve, and a hydrogen-side gas-liquid separation apparatus respectively in communication with the second valve and the fourth valve, where the hydrogen-production controller is configured to control a pressure in the oxygen-side gas-liquid separation apparatus through the third valve, and control a liquid level in the hydrogen-side gas-liquid separation apparatus through the fourth valve; and the safety controller is configured to: when a hydrogen production parameter is greater than or equal to a preset parameter alarm threshold, adjust the pressure in the oxygen-side gas-liquid separation apparatus through the first valve, and/or adjust the liquid level in the hydrogen-side gas-liquid separation apparatus through the second valve. In this way, system safety is effectively ensured, and production efficiency is improved.
Resumen de: EP4606932A1
The various embodiments of the present invention disclose an electrolyser and a method for electrolysis of water. The system (100) comprises at least an electrolyser stack (101) producing a first gas-first electrolyte mixture at a first compartment of the stack (101), and a second gas-second electrolyte mixture at a second compartment of the stack (101). A first separator (103) receives the first gas-first electrolyte mixture via a first outlet (107) and separates a first electrolyte from a first gas. A second separator (104) receives the second gas-second electrolyte mixture via a second outlet (108) and separates a second electrolyte from a second gas. A first inlet (105c) transports at least the first electrolyte into the stack (101) and a second inlet (106c) transports at least the second electrolyte into the stack (101). A first suction line (105a) connects a first pump (109) and the first separator (103) and a first head line (105b) connects the first pump (109) and the first inlet (105c) of the stack (101). A second suction line (106a) connects a second pump (110) and the second separator (104), and a second head line (106b) connects the second pump (110) and the second inlet (106c) of the stack (101). An interconnect line (111) connecting the first head line (105b) and the second suction line (106a) is configured to supply a portion of the first electrolyte, at a predetermined mixing rate, from the first head line (105b) to the second suction line (106a). The predeter
Resumen de: KR20250128257A
본 발명의 일 실시예는 니켈 폼 기판; 상기 니켈 폼 기판의 표면에 형성된 NiSe 나노 와이어 코어부; 및 상기 NiSe 나노 와이어 코어부의 표면에 형성된 Mo3Se4 쉘부;를 포함하는 것을 특징으로 하는 Mo3Se4-NiSe 코어-쉘 나노 와이어 어레이를 제공한다.
Resumen de: GB2638623A
A hydrogen production facility 10 and associated method of use is disclosed, comprising a plurality of electrolyser stacks 12. The stacks 12 are for electrolyzing water, generating a hydrogen-aqueous solution mixture. A hydrogen separator 2 arrangement is described for producing a flow of hydrogen from the hydrogen-aqueous solution mixture. The hydrogen separator 2 arrangement comprises a plurality of first stage hydrogen collector separators 20,22, where the first stage hydrogen collector separators are fluidly coupled to a respective sub-set of the plurality of electrolyser stacks. The plurality of first stage hydrogen collector separators 20,22 are also fluidly coupled to a downstream hydrogen buffer vessel 28. The hydrogen separator 2 arrangement may comprise one or more hydrogen coalescing devices 16. A pressure balancing line 24 can also be provided between oxygen 22 and hydrogen separators 20 - it may also extend between hydrogen 28 and oxygen buffer 30 vessels.
Resumen de: US2024133063A1
An electrolyzer system includes a vaporizer configured to store a first volume of liquid water and to vaporize water to humidify a cathode inlet stream of an electrolyzer cell module, a cold water tank positioned at a height greater than that of the first volume of liquid water and configured to store a second volume of water, and a valve configured to open and close. The water from the cold water tank is allowed to flow through the valve into the vaporizer when the valve is open.
Resumen de: CN120536972A
本发明属于电解槽领域,具体涉及一种构建酸性反应微环境的阴极催化剂及其制备方法和应用、电解槽以及电解非纯水制氢方法。阴极催化剂制备包括:将#imgabs0#酸氧化物前驱体配置成溶液;将Pt/C催化剂分散于上述溶液中;加热缓慢蒸发,得到固体并进行干燥得到前驱体@Pt/C。在管式炉中,将前驱体@Pt/C进行退火处理得到阴极催化剂酸氧化物@Pt/C。本发明提出一种微环境pH调节策略,通过在Pt/C中引入#imgabs1#酸氧化物制备得到阴极催化剂,采用该催化剂制备得到的电解槽应用于电解水制氢,能够构建强酸性局部环境,从而:提升产氢反应动力学;抑制阳离子在阴极的沉积/沉淀;延缓质子交换膜的化学降解。
Resumen de: JP2023145445A
To provide a composite composition with a silicon suboxide that more strongly elicits a hydrogen generation ability of silicon fine particles.SOLUTION: One composite composition of the present invention comprises silicon fine particles and a silicon sub-oxide (SiOX, where x is 1/2, 1, and 3/2) covering at least a portion of a surface of the silicon fine particles and/or a mixed composition of the silicon sub-oxide and silicon dioxide.SELECTED DRAWING: Figure 1
Resumen de: CN120536955A
一种用于酸性铁离子循环辅助电解制氢体系的膜电极的制备方法及其在低电耗制氢中应用,它涉及电解水制氢领域。方法:一、基底的预处理;二、制备催化剂墨水;三、制备阴极和阳极;四、热压组装。用于酸性铁离子循环辅助电解制氢体系的膜电极作为工作电极在装有含Fe离子的酸性电解液的质子交换膜电解槽中低电耗制氢,通过Fe2+/Fe3+循环促进阳极反应动力学,降低阳极氧化电位,从而显著降低电解水能耗,提高制氢效率;本发明制备方法简便,所制膜电极电阻小、界面结合牢固,具有优异的电化学性能,适合酸性体系下PEM电解槽的低电耗制氢,具备广阔的应用前景。
Resumen de: CN120545418A
本申请提供一种氢电池多功能舱用电解水供氧系统及氧气后处理方法,涉及电解水制氧技术领域。氢电池多功能舱用电解水供氧系统包括电解水装置、过滤机构、净化机构、纯化机构以及干燥机构。其中,电解水装置用于电解水制取氢气和氧气;过滤机构用于过滤电解水装置产生的氧气;净化机构具有承载有净化液的净化腔,净化液为双氧水,净化腔用于接收过滤后的氧气并利用净化液对其进行净化;纯化机构用于接收并分解净化的氧气中的过氧化氢,以输出纯化后的氧气;干燥机构用于干燥纯化后的氧气至第一预设湿度并控制氧气的温度至预设温度。其能够输出纯度、湿度以及温度同时满足相关要求的氧气,可在降低成本的基础上有效提升氧气的使用效率。
Resumen de: CN120532395A
本发明公开了一种基于氢化钙氧化还原反应的高效环保氢气生成装置,属于制氢技术领域,包括可相对转动的上瓶体和下瓶体,上瓶体的顶面设置有氢气导管,氢气导管上设置有充气阀门和压力表,氢气导管的顶部设置有用于连接气球的气球接口,下瓶体的底部设置有可拆卸的密封盖,密封盖上设置有用于放置反应物的盛放框,盛放框的上部设置有水囊,上瓶体的内部设置有刺破机构,上瓶体和下瓶体的连接处设置有防护机构。本发明通过集成式设计,体积小、重量轻、安全性高,在成本、重量、安全性上均满足海上无人探空需求,且环保处理简便。
Resumen de: CN120536962A
本发明公开一种具备分布均匀活性组分的全解水整体电极,所述全解水整体电极的表面原位生长有与基底紧密结合的硫化物或磷化物;所述基底为金属泡沫;所述分布均匀活性组分的前驱体溶液是含有润湿剂的含硫或含磷化合物;所述原位生长为喷涂法结合退火处理。
Resumen de: CN120536943A
本申请公开了一种便于装配和内漏测试的电解槽。阴极室设有第一双极板和一体成型的阴极碱液输配层,第一双极板上以直通的方式开设有延伸至第一端部或者第二端部外侧的氢气出口;阳极室设有第二双极板和一体成型的阳极碱液输配层,第二双极板上以直通的方式开设有延伸至第一端部或者第二端部外侧的氧气出口;氢侧通道从第一端部或者第二端部的外侧以直通的方式贯通第一双极板,氧侧通道从第一端部或者第二端部的外侧以直通的方式贯通第二双极板。本申请提供的便于装配和内漏测试的电解槽,降低了装配难度,省时省力,减小了接触电阻,便于在运行前进行阴极侧和阳极侧的内漏测试,降低电解槽在运行时氢氧互传的风险。
Resumen de: CN120536956A
本发明公开了一种整体式多孔催化电极及其制备方法和应用。所述方法包括以下步骤:(1)将多孔金属骨架依次置于无水乙醇、盐酸、去离子水中清洗;(2)将步骤(1)得到的多孔金属骨架浸渍在含钼的溶液中,浸渍温度为10~95℃,浸渍时间为0.5~72h;(3)将多孔金属骨架从浸渍液中取出并烘干;(4)将步骤(3)得到的产物进行焙烧处理,焙烧温度为200~1200℃,焙烧时间为0.5~12h;(5)将步骤(4)得到的产物进行活化处理,活化温度为200~1200℃,活化时间为0.5~12h,得到整体式多孔催化电极。本发明制备方法在常压条件下进行,操作简单安全、制备成本低,适合催化电极的放大制备及工业化生产。
Resumen de: CN120533105A
本发明公开了一种应用于氢破炉的供氢循环系统及控制方法,系统包括氨气供应单元、氨分解装置、纯化单元、第一氢气供应单元、第二氢气供应单元、氢破炉和尾气回收单元。氨气经分解后形成氢氮混合气,经纯化后分别通过两路供应单元进入氢破炉,其中第一供应单元提供高纯氢气,第二供应单元提供氮气比例大于25%的混合气,实现氢气浓度的灵活调节。系统通过尾气回收单元将氢破炉排出气体中的氢气提纯后循环利用,显著提高氢气利用率。本发明将氨分解制氢与氢破工艺有机结合,通过多路气体供应和浓度调控,可适应不同材料的氢破需求,同时实现尾气中氢气的回收利用,既降低了氢气排放风险,又提高了系统能量利用效率,具有运行能耗低、适应性强的特点。
Resumen de: CN120536973A
本发明具体涉及一种自支撑非贵金属催化剂的制备及其在PEM中的应用,属于电催化技术领域。本发明将钴源、锆源制成金属靶材,采用脉冲激光沉积法将金属靶材沉积到处理后的衬底上,最后在空气中退火处理,制备出一种可以规模生产的PEM电解水非贵金属电催化剂。实验结果表明,本发明制备的自支撑非贵金属电解水催化剂在常温下具有高稳定性和催化活性,且非贵金属钴锆较贵金属铱钌价格低廉,储量丰富,对于降低工业化PEM电解水催化剂成本具有良好的指导作用。
Resumen de: CN120535001A
本发明提供了一种具有压缩应变的二维多孔氧化物纳米片的制备方法和应用,属于电化学技术领域。本发明通过将甘露糖、赖氨酸以及金属盐研磨混合,之后将混合物焦耳热处理,发生非酶棕色化反应,即可制备压缩应变的氧化物多孔纳米片。其材料具有丰富的多孔结构,并将稀土元素和过渡金属共掺杂,诱导CeO2中的晶格压缩应变及产生丰富的氧空位,在晶格压缩应变和增加氧空位浓度的协同作用下,有效提高了催化剂的稳定性和HER活性。
Resumen de: CN120532529A
本发明提供了一种基于静电纺丝法制备Ru基纳米粒子催化剂的方法,属于纳米材料制备领域本发明基于静电纺丝技术,对贵金属催化剂进行合理的设计、制备和优化,提高了析氧反应催化剂活性和稳定性同时提高Ru原子的利用率,降低了Ru基纳米粒子催化剂的制备成本,能够广泛应用于OER电催化研究中去。包括如下步骤:步骤一、在聚丙烯腈中引入RuP2的前驱体,之后加入N,N‑二甲基甲酰胺来配制纺丝液,再通过静电纺丝法制备Ru‑PAN纳米纤维膜;步骤二、将活化后的Ru‑PAN纳米纤维膜,在煅烧后获得RuP2纳米粒子负载在N掺杂的CNFs上的纳米复合材料,即Ru基纳米粒子催化剂。
Resumen de: CN120536963A
本发明公开了一种选择性暴露特定晶面调控IrRuMOx基氧析出电催化剂构型的方法,包括以下步骤:酸化和热处理碳粉制备成碳材料硬模板;缓慢注入预反应混合溶液并进行搅拌;有机配体和硝酸盐进行溶剂热反应;对反应产物烘干处理后研磨成粉并热处理;酸处理和水洗获得纳米棒结构的IrRuMOx氧析出电催化剂。本发明利用碳材料模板提供的纳米限域生长环境,限制IrRuM(OH)前驱体在热处理过程中的径向生长;在热处理过程中,有机配体选择性吸附于IrRuMOx特定晶面,有效抑制该方向的晶体生长,引导形成沿特定晶向的高度有序纳米结构,选择性暴露特定活性晶面显著加快四电子转移过程,有利于提升氧析出反应活性。
Resumen de: CN120536980A
本发明涉及一种用于控制碱性电解槽的温度的系统,其中,所述系统包括至少一个电解槽、氧气分离器、氢气分离器、碱液冷却器、碱液循环泵,所述氧气分离器和氢气分离器位于所述电解槽的下游,从所述氧气分离器和氢气分离器分离出来的碱液流动到所述碱液冷却器,所述碱液循环泵将来自所述碱液冷却器的碱液回流到所述电解槽中以实现电解液的循环,所述系统还包括控制器,所述控制器被构造成根据提供给所述电解槽的波动电源负荷、所述电解槽的温度和回流到所述电解槽中的碱液的流量来控制所述电解槽中的碱液的温度。
Resumen de: CN120536944A
本发明涉及制氢技术领域,具体公开一种整合质子传导固体氧化物电解池和透氧膜的高效制氢系统,包括质子传导固体氧化物电解池和透氧组件;所述质子传导固体氧化物电解池包含有氧电极、电解质、燃料电极、燃料电极流道和氧电极流道;所述透氧组件具有透氧膜流道和透氧膜,所述氧电极流道与透氧膜流道被所述透氧膜分隔,所述氧电极流道中的水蒸气被电解时,以在所述氧电极中产生氧气,并在所述燃料电极产生纯净的氢气;在氧分压差的作用下,所述氧电极流道中的氧气能通过所述透氧膜,并进入所述透氧膜流道;该整合质子传导固体氧化物电解池和透氧膜的高效制氢系统可以高效制氢,降低电能损耗。
Resumen de: CN120532273A
本发明公开了一种电解水制氢两塔无损耗纯化干燥装置及其时序控制方法。将三通阀的输入口接高压氢气,三通阀的第一输出口与第一回氢阀的第一端连通;三通阀的第二输出口与第二回氢阀的第一端连通;第一回氢阀的第二端与第一干燥罐的第一端连通;第一干燥罐的第二端与第二干燥罐的第一端连通;第二干燥罐的第二端与第二回氢阀的第二端连通;第二回氢阀的第三端与第二冷却器的第一端连通,第二冷却器的第二端与气水分离罐的第一端连通;气水分离罐的第二端与流量调节阀的第一端连通;流量调节阀的第二端与第一冷却器的第一端连通,第一冷却器的第二端与第一回氢阀的第三端连通。本发明可以延长分子筛的再生间隔周期,从而降低综合制氢能耗。
Resumen de: CN120532716A
本发明属于膜电极喷涂技术领域,具体涉及一种PEM电解水制氢膜电极的梯度喷涂制备工艺。所述制备工艺包括以下步骤:配置浆料:制备PEM膜电极阳极催化层第一浆料和第二浆料,阴极催化层第一浆料和第二浆料,阳极催化层喷涂:第一层将PEM膜电极阳极催化层第一浆料超声喷涂质子交换膜上,随后将第二浆料超声喷涂质子交换膜上,两次喷涂的流速相同;依次顺序重复进行喷涂;阴极催化层喷涂:第一层将PEM膜电极阴极催化层第一浆料超声喷涂到质子交换膜上;随后将第二浆料超声喷涂到质子交换膜上,两次喷涂的流速相同;依次顺序重复进行喷涂。本发明制备的PEM电解水制氢膜电极能有效降低结构孔隙率,以减少气体传质阻力,提升质子传导效率,提高催化剂利用率。
Resumen de: CN120536976A
本发明公开了一种海水直接制氢抗高盐抗腐蚀电解催化剂及其制备方法,该催化剂包括阳极催化剂TiN‑IrO2和阴极催化剂TiN‑MoS2;制备方法:(1)先将钛箔依次进行超声清洗,取出,洗涤,烘干,然后在钛箔上沉积TiN,得到TiN基底;(2)将TiN基底浸渍在IrCl3·3H2O和HCl的混合溶液中,搅拌,取出,焙烧,得到阳极催化剂TiN‑IrO2;(3)将TiN基底浸渍在Na2MoO4·2H2O和硫脲的混合溶液中,水热反应,取出,洗涤,真空烘干,得到阴极催化剂TiN‑MoS2。本发明电解催化剂成本低、抗高盐、抗腐蚀性强,实现了海水直接制氢的高效性和稳定性,成功克服了现有技术在海水直接制氢领域的高成本、制备复杂、稳定性不足、选择性差以及预处理需求等缺陷,为海水直接制氢提供了高效解决方案。
Resumen de: CN120531941A
本发明公开了一种具有产氢功能的气管导管及其制备方法,其制备方法具体包括以下步骤:S1:将产氢粒子分散到三羟甲基氨基甲烷盐酸盐溶液中,然后加入盐酸多巴胺,遮光搅拌8~12h,制得含有产氢粒子和聚多巴胺的混合溶液;S2:将气管导管套囊浸没在步骤S1的混合溶液中,并在35~37℃下遮光搅拌8~12h,然后取出置于30~40℃烘箱内干燥,从而在气管导管套囊表面制得产氢涂层,进而得到所述具有产氢功能的气管导管。本发明能有效消除气管导管套囊作用部位的活性氧,减小患者气道黏膜损伤。
Resumen de: CN120532551A
本发明涉及一种基于铜卟啉共价有机框架与石墨相氮化碳的Z型有机异质结光催化剂及其制备方法与应用,将碱化g‑C3N4与CuP‑Ph COF超声分散于有机溶剂中,分散均匀后进行回流反应,将反应产物经冷却、过滤、洗涤、干燥,得到g‑C3N4@CuP‑Ph COF复合光催化剂,即基于铜卟啉共价有机框架与石墨相氮化碳的Z型有机异质结光催化剂。该光催化剂通过共价有机框架中的Cu与碱化g‑C3N4中的氰基/亚氨基形成稳定配位键,构建平面共价键合的半导体异质结。与现有技术相比,本发明具有通过构建平面共价键合的半导体异质结,实现高效的光催化制氢性能等优点。
Resumen de: CN120536968A
本发明公开了一种基于电活化与钼酸电解液改性协同的电解水制氢方法,包括:催化剂的制备、电解液的配置等多个步骤。通过上述方式,本发明一种基于电活化与钼酸电解液改性协同的电解水制氢方法,不仅可以通过对催化剂进行电活化,使得制备的电极能够得到非晶态和纳米晶态的镀层,从而有效的提升了催化剂的催化活性,而且价格低廉,可以有效的控制成本,同时降低了电解能耗,提升了电解水制氢效率。
Resumen de: CN120534930A
本发明属于制氢技术领域,尤其涉及一种镁基储氢材料的制备及水解放氢方法。本发明通过将镁锭加热熔化,并加入带有磁性金属元素的中间合金进行合金化处理得到具有磁性的镁合金粉体,进而对该粉体进行氢化、半固态化处理,得到半固态的镁基储氢材料,该材料在水解放氢装置上与水发生水解反应。通过水解放氢装置上设置磁铁,依靠磁场控制固体颗粒聚集状态,加快固相与液相的分离速度,经过水解、脱水、干燥,对外输出纯净的氢气。制备成半固态浆料便于储存、运输、水解反应,可防止镁基固体颗粒暴露在空气中发生氧化,也加速水解制(放)氢过程,另外水解制氢装置还可将半固态浆料转变为全固态颗粒料,方便用于热解产氢。还可适用于复杂运动条件下的持续工作。
Resumen de: US2025270710A1
A water electrolysis system includes: a water electrolysis device for electrolyzing water; a gas-liquid separator for performing gas-liquid separation of a mixed fluid of hydrogen gas and water, the mixed fluid being led out from the water electrolysis device; a dehumidifier for dehumidifying the hydrogen gas separated from the mixed fluid by the gas-liquid separator; a delivery path for delivering the hydrogen gas dehumidified by the dehumidifier; a humidifier for humidifying the hydrogen gas delivered through the delivery path; and a compression device for compressing the hydrogen gas humidified by the humidifier.
Resumen de: WO2024132579A1
A process for producing a synthesis gas product comprising hydrogen from an endothermic cracking reaction of an ammonia feedstock stream, comprising the following steps: - Providing an ammonia feedstock stream, - Performing a catalytic conversion by catalytically converting the ammonia feedstock stream by cracking endothermically said ammonia feedstock stream into a synthesis gas product comprising hydrogen, - Performing heat exchanges step by performing heat exchanges between the synthesis gas product and the catalytic conversion of the ammonia feedstock stream, said heat exchanges step comprising the following steps: • Discharging the synthesis gas product in a synthesis gas product circulation duct, said duct being arranged for the heat exchanges between the discharged synthesis gas product and the catalytic conversion of the ammonia feedstock stream, • Recovering heat from the discharged synthesis gas product, • Directing the recovered heat to the catalytic conversion of the ammonia feedstock stream.
Resumen de: CN120532544A
本发明属催化能源转化技术领域,具体为一种三维自支撑多元过渡金属催化剂及其制备方法和应用。本发明催化剂,采用化学镀的方法将催化层原位沉积于多孔网状泡沫海绵基底,并结合酸刻蚀、浸渍修饰等表面处理技术进行优化改性得到;具体以Co为基础金属,掺杂入过渡金属X,记为Co‑X;并修饰以少量铂系金属中的一种或两种。本发明兼顾催化剂制造成本和催化效率,利用多元素的协同效应,分别有效地促进催化过程中各步基元反应的进行,表现出优异的内禀催化活性和稳定性,能实现高效的硼氢化物水解制氢,如可用作硼氢化钠水介质氢燃料电池中的制氢启动控制器,实现氢气的随时随地供应,具有广阔应用前景。
Resumen de: CN120536969A
本发明公开了一种基于酸处理法的钌基合金催化剂的制备方法,包括:基底预处理、前驱体的制备、钌基合金催化剂的制备等步骤。通过上述方式,本发明一种基于酸处理法的钌基合金催化剂的制备方法,通过多种金属元素相互作用产生协同效应,具有更多的活性位点和更强的导电性,大大提高了催化剂在具有高腐蚀性的高浓度碱性电解质中的析氢活性、稳定性和耐受性,还降低了对单一贵金属的依赖,进一步降低成本,提高资源的利用效率。
Resumen de: CN120536957A
本申请涉及电解水制氢技术领域,具体涉及一种气体扩散层及其制备方法、质子交换膜电解池。本申请提供一种气体扩散层,气体扩散层包括基底层和多个阵列柱,多个阵列柱按阵列排布在基底层的一侧表面上;所述阵列柱具有底部和端部,相较于所述端部,所述底部更靠近所述基底层设置;其中,水对所述底部的润湿性高于水对所述端部的润湿性。本申请提供的气体扩散层可以对传输方向相反的液态水和气态氧分别进行有效传输,其能够降低液态水和气态氧的相互干扰,降低传质损失,进而得以有效提高质子交换膜电解池的电解效率。
Resumen de: CN120536949A
本发明公开了一种基于叶脉脉络结构的新型PEM电解槽流道结构,包括流道结构,所述流道结构呈叶脉脉络分布的进水主通道和排水分支流道,所述进水主通道沿电解槽长度方向延伸并位于流道结构中央,所述排水分支流道由进水主通道向外分支延伸,进而形成对称双向流道结构,以使流体在流道结构中均匀横向分布。本发明显著优化了流体在电解槽中的横向均匀分布,减少了流动死区。此外,结构还强化了气液分离能力,便于气泡逸出,降低了极板表面气泡覆盖,从而提高了反应效率,特别适用于对气体管理要求较高的PEM电解应用。
Resumen de: CN120536942A
本发明公开了一种可以动态吹扫的电解水制氢装置,涉及电解水制氢技术领域,该可以动态吹扫的电解水制氢装置包括箱体,所述箱体内壁上安装有电解室,所述箱体一侧安装有气液分离罐,所述电解室阳极输出端与气液分离罐通过管道相连,所述空气压缩机输出端与气液分离罐通过空压风管道相连,所述空压风管道上安装有电磁阀,所述电磁阀与电解室电性连接,启动空气压缩机,压缩空气通过空压风管道进入气液分离罐内进行吹扫,可以根据电解室的工作功率相应控制空压风管道上电磁阀的工作状态,从而控制压缩空气的吹扫流量和吹扫频率,实现动态吹扫功能。
Resumen de: US2025250687A1
A water electrolysis system includes a flow rate adjusting valve for relatively changing a first flow rate which is a flow rate of water flowing through a first flow path portion extending from a first water lead-out unit, and a second flow rate which is a flow rate of water flowing through a second flow path portion extending from a second water lead-out unit.
Resumen de: CN120536979A
本发明公开了一种二氧化铈掺杂磷化镍钴负载到碳化钛Mxene复合电催化材料及其制备方法,属于电催化材料技术领域。本发明通过简单的原位生成法,采用LiF+HCl作为刻蚀剂成功合成单/少层的Ti3C2TxMXene,Ti3C2TxMXene表面端基官能团能吸引金属活性成分;通过水热法和热磷化工艺制备NiCoP纳米颗粒负载到少层Ti3C2TxMXene材料上,其中,CeO2 NPs附着在NiCoP上以及Ti3C2TxMXene片层上,得到双功能CeO2‑NiCoP/Ti3C2TxMXene复合电催化材料。该制备方法简单高效;所制备得到的复合电催化材料可表现出优异的HER和OER的催化活性以及稳定性。
Resumen de: CN120536948A
本发明适用于电解槽技术领域,尤其涉及一种氯碱或烷基水电解的电解槽用槽宽垫片及其生产方法;所述氯碱或烷基水电解的电解槽用槽宽垫片包括:阳极垫片以及阴极垫片,所述阳极垫片与阴极垫片呈对称分布安装在电解槽的单元槽密封面上,阳极垫片与阴极垫片之间安装有离子膜;所述的氯碱或烷基水电解的电解槽用槽宽垫片既能保证密封层与法兰面接触的弹性密封性,同时又具备较好的绝缘性能,且后期在发生损伤时可以对阴极密封层或阳极密封层进行修复达到再用目的;包覆层直接接触具有腐蚀性的电解液,不会产生腐蚀,保证了电解槽运行过程中不会因为基板原因而产生停车后果。
Resumen de: CN120532543A
本发明提供一种新型的液‑液相分离微米颗粒(LLPS MPs)及其制备方法与应用。所述液‑液相分离(LLPS)体系,是通过水溶液中带正电荷的聚电解质和带负电荷的无机盐或有机盐的静电吸引作用驱动形成的微米液滴。使用多金属氧酸盐(POM)通过静电吸引作用对其进行稳定并沉淀出具有脊状结构的LLPS MPs。本发明选用具有光催化水氧化活性的{(B‑α‑PW9O34)Co3(OH)(H2O)2(O3PC(O)(C3H6NH3)PO3)}2Co14‑(Co7‑POM)沉积出微米颗粒,使其具有增强的光催化水氧化活性,同时通过简单易行的固‑液分离实现其可回收利用。
Resumen de: CN120536936A
本发明涉及能源技术领域,提供一种电解制氢方法及装置,该方法包括:浓度为0.01M以上的酸的水溶液或者浓度为0.01M以上的碱的水溶液冷冻至固态得固态电解质;所述固态电解质在低温下进行电解以连续产生氢气,所述低温使所述固态电解质在所述电解过程中保持固态;所述电解采用的正极与所述固体电解质的接触区域记为第一区域,所述电解采用的负极与所述固体电解质的接触区域记为第二区域,在垂直于所述第一区域的方向上或者在垂直于所述第二区域的方向上,所述第一区域和所述第二区域的投影面部分重叠。本发明通过设计正负极的接触方式,使该固态电解质可以实现低温下连续电解制氢,填补低温电解制氢方法的行业空白。
Resumen de: CN120536867A
本发明公开了一种硫化钼涂层及其制备方法和应用,所述涂层为金属相,所述涂层包括钛层、硫化钼层,所述钛层的厚度为50~200nm,所述硫化钼层的厚度为2~6μm。制备方法为采用磁控溅射镀膜的方法,向基材上沉积二硫化钼涂层;沉积二硫化钼涂层的过程中,舱室反应真空度为0.5Pa~1Pa,脉冲磁控功率为1~3kW,沉积时间为30~60min。本发明的涂层,具有钛层和硫化钼层,涂层具有丰富的边缘活性位点,可应用于电解水制氢。制备方法操作简单,重复性好,实现了半导体相与金属相之间的调控。
Resumen de: CN120536967A
本发明涉及微波辅助合成晶面调控二氧化铈负载钌催化剂的制备及其应用,其特征在于,以不同温度水热结合高温煅烧合成具有不同晶面的二氧化铈前驱体,通过超快微波准固态方法将金属钌负载在不同晶面的二氧化铈上,得到金属钌负载于不同晶面的二氧化铈催化剂材料。本发明所述制备方法具有简单、快速、环保和价格低廉的特点,该棒状Ru/CeO2(111)和块状Ru/CeO2(200)在碱性电解液中的过电位为50mV时,电流密度分别为3.2mA cm‑2和10.9mA cm‑2。
Resumen de: CN120532491A
本发明涉及一种(Mo,C)共掺杂型氧化钛光催化剂的制备方法,以TiCl4、CaC2、Na2MoO4为原料,通过调节C4‑/Ti4+的摩尔比和WMoO3/WTiO2重量比进行掺杂,形成(Mo,C)共掺杂型纳米氧化钛光催化剂,有效提高了TiO2的光催化制氢性能,在300W氙灯光照射下析氢性能达到10~12mmol/g.h,为共掺杂型锐钛矿氧化钛光催化剂的制备提供了新的途径,具有广泛的应用前景。
Resumen de: CN120536960A
本发明公开了一种碱性电解水电极,包括由镍板制成的电极本体,所述电极本体上贯穿有若干供气体通过的网孔,各所述网孔沿所述电极本体的主延展方向均匀布置,所述电极本体的一侧主延展面为第一面,另一侧主延展面为第二面;所述电极本体上设置有若干凸出于所述第一面的产气凸台,所述产气凸台一体成型于所述电极本体上,以使所述产气凸台上均布有若干所述网孔,各所述产气凸台沿所述电极本体的主延展面阵列均布。该碱性电解水电极能够提高碱性电解水工艺的电解处理效率,优化整体工艺效果。本发明还公开一种用于上述碱性电解水电极的碱性电解水电极制造方法。
Resumen de: CN120536978A
本发明属于电解水制氢催化剂技术领域,具体为一种水电解催化用高熵硫化物/石墨烯复合材料及其制备方法,以导电性较好、表面较粗糙的泡沫镍为基底,采用电沉积方法使钼源、铁源、钴源、镍源在NF(泡沫镍)表面原位生长成纳米花球状形貌的(MoFeCoNi)OH/NF材料;然后通过高能球磨作用将超声处理下来的(MoFeCoNi)OH与G充分混合得到(MoFeCoNi)OH/G材料,最后通过将硫蒸汽与(FeCoNiMo)OH/G充分接触并反应生成(MoFeCoNi)S/G电解水催化材料。本发明优化了多金属硫化物电子结构,提高了催化剂在HER过程中的活性及稳定性,提高了电解水性能;且催化剂采用的原料成本较低,操作周期短,重复性高,易规模化生产。
Resumen de: CN120536977A
本发明公开了一种海水直接制氢的电解槽非贵金属双组份催化剂及其制备方法和应用,属于海水电解制氢技术领域。双组份催化剂包括阳极催化剂和阴极催化剂;阳极为NiFe‑LDH@CoMoO4(Ni:Fe=3:1,Co:Mo=1:1),阴极为CoMoS3(Co:Mo=1:2),通过水热法、电化学沉积和硫化法制备。催化剂在盐度20‑35g/L海水中运行,电压1.8‑2.3V,电流密度0.8‑1.6A/cm2,H2产率2.0‑2.3L/min,效率85‑90%,寿命>6000小时,Cl2副产物<0.05%。本发明无需预处理,使用非贵金属,成本低,抗腐蚀性强,适用于绿色氢能生产。
Resumen de: CN120532519A
本发明属于压电光催化剂领域,具体涉及一种含有硫空位的CuSe/MgIn2S4‑Vs复合催化剂及其制备方法和应用。首先合成MgIn2S4‑Vs,其次合成CuSe,最后采用浸渍法制备CuSe/MgIn2S4‑Vs异质结复合催化剂。该催化剂在太阳光的照射下,通过引入超声波振动,用于压电光催化产H2或H2O2。本发明催化剂合成方法简单易行,绿色无污染,所制备出的催化剂具有丰富的活性位点,较高的活性和优异的稳定性等特点。
Resumen de: CN120545417A
本发明涉及氢气发生装置技术领域,公开了一种自动投料式氢气发生装置,包括罐体、盖体、集气组件以及激发组件,罐体构造有容纳反应物的腔体,敞口处设置有放置固体反应物的承载件;盖体可拆卸的连接于所述罐体并封闭所述罐体的敞口;激发组件所述激发组件装配在所述盖体内,包括由上至下布置的激发板和顶动活塞,所述激发板上朝向所述固体反应物的一侧设置有挤压凸起,顶动活塞向上移动时推动所述激发板压缩所述弹簧且所述激发板转动一预设角度;所述集气组件设置于所述盖体。上述技术方案的有益效果为:固体反应物具有多个且独立封装,激发组件能够自动陆续将所有的固体反应物依次的投入罐体内参与反应,使得罐体内能够持续的供应气体。
Resumen de: CN119604997A
The invention relates to: a bipolar plate (1); and an electrochemical cell (12) comprising a plurality of such bipolar plates (1, 1 '). The bipolar plate (1) comprises a first half plate (1a) and a second half plate (1b) which are fixedly connected with each other, the bipolar plate (1) is provided with a plurality of fluid channel openings (2), and the fluid channel openings comprise fluid inlet openings (2a, 2c and 2e) and fluid outlet openings (2b, 2d and 2f); on both sides of the bipolar plate (1) there are a first distributor field (3) for distributing the fluid, an active field (4) and a second distributor field (5) for distributing the fluid. At least one seal (6, 6 ') is also present on each side of the bipolar plate (1), the seals (6, 6') being positioned one above the other in at least one transition region (7) between the fluid channel opening (2) and the adjacent distributor field (3, 5) as seen perpendicularly to the plane of expansion of the bipolar plate (1) and being reinforced by embossing structures (9a, 9b).
Resumen de: CN120536966A
本发明公开了一种介孔类绣球花负载型低贵金属催化剂的制备方法及应用,以Pluronic F127为软模版制备F127溶液;将铌草酸铵盐通过醇盐水解制备五氧化二铌的前驱体分散液;将两种溶液混合,通过溶剂热法、离心、干燥收集固体、煅烧,得到介孔类绣球花五氧化二铌,将其和氯铱酸混合;加热还原,抽滤,洗涤,干燥,煅烧,得到介孔类绣球花负载型低贵金属催化剂。不同于传统的贵金属催化剂,本发明制备的产品具有较高比表面积和较大的孔隙率。高度开放的结构,确保了活性组分的均匀分散,大大提升了电催化活性和稳定性,有效的降低贵金属用量,铱用量仅有铱黑催化剂用量的60%。介孔结构加快膜电极的传质效率,在0.6mg/cm2铱载量下,实现1Acm2@1.69V,大大提升贵金属利用率,实现高效电解水制氢。
Resumen de: US2025262610A1
According to the embodiments of the present disclosure, an ammonia decomposition catalyst may be prepared by performing heat treatment on alumina, a lanthanum compound and a cerium compound in a reducing gas atmosphere to form a composite oxide on an alumina support, and supporting an active metal including ruthenium on the composite oxide.
Resumen de: WO2024129246A1
Herein discussed is a method of producing hydrogen comprising: (a) providing an electrochemical reactor having an anode, a cathode, and a membrane between the anode and the cathode, wherein the membrane conducts both electrons and protons, wherein the anode and cathode are porous; (b) introducing a first stream to the anode, wherein the first stream comprises ammonia or a cracked ammonia product; and (c) extracting a second stream from the cathode, wherein the second stream comprises hydrogen, wherein the first stream and the second stream are separated by the membrane.
Resumen de: CN120519895A
本发明提供了一种Ru基合金化异质结电解水制氢催化剂的制备方法,属于纳米材料和电化学技术领域。本发明使用的三元熔盐辅助的焦耳热快速煅烧工艺,可以在空气气氛下低成本,高效率制备二维多孔Ru基合金化异质结电解水制氢催化剂。该电解水制氢催化剂具有优异的结构和组分优势,其二维多孔结构的优势在于可以提升催化剂活性位点的数量并有利于反应过程中氢气的脱出。其合金化异质结的组分优势在于合金化以及丰富的异质界面可以增加Ru活性位点的种类并激发不同组分的协同效应。进而优化Ru对中间产物的吸附能析氢反应动力学,展现出优异的碱性电解水析氢性能。
Resumen de: CN120519911A
本发明提供了一种Ru‑RuO2纳米片的制备方法及其应用,属于纳米材料制备技术领域。本发明首先将L‑脯氨酸、三氯化钌三水合物、尿素加入到乙醇中,超声溶解后加热反应形成胶状物液体,然后在空气气氛下进行焦耳热处理得到Ru‑RuO2纳米片。该方法无需表面活性剂、模板剂、还原气氛和复杂的煅烧工艺,可以效率高、低能耗实现多孔异质结Ru‑RuO2纳米片的制备,具有工业化应用前景。这种原位煅烧形成的二维多孔异质结具有丰富的界面结构,可以充分发挥双组分的协同效应,显著提升了其在酸性电解水应用中的活性和稳定性。
Resumen de: CN120515408A
本发明提供了一种锂促进钌基氨分解催化剂及其制备方法,属于热催化技术领域。本发明所述制备方法的步骤如下:将LiNO3和Al(NO3)3·9H2O混合,得到第一混合溶液,之后将其与NaOH溶液滴加至Na2CO3溶液中生成沉淀,保持沉淀pH稳定,得到锂铝复合氢氧化物前驱体,将该前驱体进行焙烧,得到锂铝复合氧化物;将所述锂铝复合氧化物分散于乙醇中,之后滴加钌前驱体溶液,得到第二混合溶液,之后对其进行真空蒸发处理,最后进行还原处理,得到所述锂促进钌基氨分解催化剂。本发明所述催化剂在氨分解反应中表现出良好的活性和稳定性。
Resumen de: CN120519884A
本发明公开了一种模板法合成NiFeCu阵列催化剂的方法及NiFeCu阵列催化剂,涉及催化剂技术领域,包括如下步骤:对泡沫铜进行清洗,除去表面氧化物和污染物;将浓度为0.1‑0.2mol/L的过硫酸铵溶液和浓度为1mol/L的NaOH溶液按照体积比1:1混合均匀,得到混合液一,将清洗后的泡沫铜置于混合液一中反应20‑60min,得到Cu(OH)2/CuF阵列模板;将Cu(OH)2/CuF阵列模板置于含有草酸、镍源与铁源的混合液二中反应30‑120min,得到具有纳米棒阵列结构的NiFeCu阵列催化剂;应用于OER工作电极时,经活化形成NiFeCuOX阵列催化剂,无需类似粉体催化剂所需要的nafion粘结剂,可保证电解液与催化剂的有效接触和氧气的快速释放,大幅提升电化学性能。
Resumen de: CN120515993A
本发明属于能源技术领域,具体涉及一种铝基制氢材料及其制备工艺。本发明提供的铝基制氢材料包括铝粉、复合活化剂、活化金属和盐;所述复合活化剂是由三氧化二锑、五氧化二钒和改性碳纳米管制备得到的复合材料。本发明采用三氧化二锑、五氧化二钒和改性碳纳米管制备得到复合材料作为复合活化剂,使氧化铝膜结构疏松、开裂,破坏氧化膜的完整性,加速电子转移,提高铝基制氢材料的产氢效率;采用镍和钴对酸化后的碳纳米管进行改性,通过在碳纳米管中吸附镍来降低氢气的生成能垒,提升产氢效率,通过在碳纳米管中吸附钴来促进铝粉表面的氧化膜溶解,提高铝粉的反应活性。
Resumen de: CN120515400A
本发明涉及光催化材料技术领域,具体为一种活性碳基高效光催化材料及其制备方法:包括以下步骤:S1:基料准备,基料选取活性炭,活性炭进行磨粉处理,制得粉料,待用;S2:基料预处理,对粉料进行预处理,制得主料,待用。本发明中,在光催化材料的制备过程中,通过对活性炭的形态改变处理,在处理中将活性炭磨粉后制成浆料,之后对浆料进一步处理后进行静电纺丝处理,之后重新制成颗粒材料用于制备光催化材料,经过静电纺丝的处理可以使得活性炭形成丰富的纤维孔洞结构,在其内部形成连贯的微孔,有效提升了光催化材料的表面面积,进而有效提升了光催化材料的净化效果。
Resumen de: CN120519912A
本发明公开了一种铁银共掺杂氧化镍自支撑电极及其制备方法与应用,属于电极材料技术领域,制备方法包括以下步骤:将泡沫镍依次进行裁剪处理、超声清理处理和干燥处理,干燥处理后备用;将Fe(NO3)3·9H2O、AgNO3和CO(NH2)2溶解于乙醇和去离子水中,搅拌后放入水热釜;将泡沫镍插入聚四氟模具底座,所述泡沫镍保持垂直状态;在110℃下保持15小时,冷却至室温,洗涤、干燥后在马弗炉中350℃下退火2h得到铁银共掺杂氧化镍自支撑电极材料;该电极可用于碱性条件下电解甲醛溶液的阴阳两极析氢,是一种双功能电极,具有较好的经济性和环保性。
Resumen de: CN120519900A
本发明公开了一种钨掺杂镍/钴双金属硫化物(W‑NiCo2S4)的制备方法,以泡沫镍(Ni foam)为载体,通过水热法结合后续硫化处理,构建W掺杂的CoNi2S4纳米结构。W的引入有效调控了催化剂的电子结构,增强了其导电性和结构稳定性,并显著提升其在电催化硫化物氧化反应(SOR)中的催化活性与抗硫中毒能力。本发明制备的催化剂在碱性电解质中均表现出优异的电催化性能和长期稳定性,合成过程操作性强,适用于硫化氢分解制氢等能源转化领域,表现出极好的工业应用前景。
Resumen de: CN120519877A
本发明涉及气压设备的端板技术领域,公开了一种自动平衡气压的端板,其技术方案要点是包括端板主体、气压平衡盖板;所述端板主体的边沿与目标设备的其他结构固定密封连接,所述端板主体上贯穿的设置有气体出口;所述端板主体的顶面中部设置有凹陷的气压平衡槽,所述气压平衡盖板密封的盖设在所述气压平衡槽的顶端口沿;所述气体出口和所述气压平衡槽之间设置有气体通道;所述气压平衡槽内设置有支撑机构,所述支撑结构在所述端板主体和所述气压平衡盖板之间形成可供气体流通的气压平衡腔,所述气压平衡腔与所述气体通道之间连通。
Resumen de: CN120519878A
本发明涉及绿电制氢的技术领域,特别是涉及一种用于大规模绿电应用场景的水电解制氢装置,其能够将极板上的气泡振动脱落,减少气泡占用极板的时间,提高电解制氢效率;包括电解箱、进水管、阴极板、阳极板和电化学工作站;还包括振动板一、振动板二、出气管一、出气管二和摆动机构,振动板一弹性安装在电解箱的腔室左端,阳极板安装在振动板一的端面上,振动板二弹性安装在电解箱的腔室右端,阴极板安装在振动板二的端面上,阴极板和阳极板相对布置,摆动机构安装在电解箱的腔室中,摆动机构驱动振动板一和振动板二往复振动,出气管一和出气管二安装在电解箱上,出气管一的输入端位于阳极板的上方,出气管二的输入端位于阴极板的上方。
Resumen de: CN120519868A
本发明公开了纸基电极耦合热电驱动光电催化制氢装置,包括电化学工作站,所述电化学工作站内设有电解槽,且电解槽内设有电解液,所述电解槽内设有热电模块,所述热电模块的顶部设有纸基电极,所述热电模块通过导热硅胶与纸基电极粘合,所述纸基电极的截面形状为L型,所述电解槽右侧设有回环部,所述回环部内设有光阴极和参比电极,所述光阴极通过导线和电化学工作站的负极连接,且电化学工作站的正极通过导线与热电模块连接,所述参比电极通过导线与电化学工作站连接;本发明通过纸基电极和热电模块的结合来利用太阳光中的红外光,能够解决光电催化系统不能有效利用红外光的问题,实现太阳光的全谱利用,提高光电催化效率。
Resumen de: CN120518864A
本发明提供一种聚合物及其制备方法和应用,所述制备方法包括以下步骤:步骤一、将多巴和/或多巴胺与有机溶剂混合,加入有机碱、硅烷化合物,得到第一中间产物;步骤二、将第一中间产物与有机溶剂混合,加入pH调节剂,搅拌反应,得到第二中间产物;步骤三、将二苯砜类化合物与有机溶剂混合,加入第二中间产物,搅拌反应,得到第三中间产物;步骤四、将第三中间产物与有机溶剂混合,加入铵盐,得到第四中间产物;步骤五、将第四中间产物、双酚A与有机溶剂混合,加入无机碱,搅拌反应,得到所述聚合物。将所述聚合物用于制备碱性水电解复合膜,能够改善复合膜与电解液的浸润性,减少隔膜的表面电阻,提高隔膜的电解效率和机械稳定性。
Resumen de: CN120519889A
本发明涉及电化学催化和电沉积技术领域,具体公开了一种低铱负载的铱钴磷纳米颗粒析氢电催化剂及其制备方法,所述析氢催化剂由基底负载铱、钴、磷金属制得,所述催化剂中的铱、钴、磷金属为铱钴磷纳米颗粒结构,颗粒尺寸为10‑300nm,铱、钴、磷元素分布均匀,铱含量可低至0.32wt%。所述催化剂在1.0M KOH溶液中,于10mA/cm2电流密度下过电位可低至31.3mV,Tafel斜率可低至40.6mV/dec,析氢性能优异,成本显著降低,适合大规模工业应用,具有良好的市场应用前景。
Resumen de: CN120519874A
本发明属于氢能技术领域,具体涉及一种实验用小型质子交换膜电解水制氢测试平台,包括:电解池(槽)以及辅助系统,所述辅助系统包括电解水加热装置、循环装置、氢气分离收集装置、氧气分离收集装置、水体净化回收装置、电解电源供应装置。本发明制备的实验用小型质子交换膜电解水制氢测试平台结构简便,易于组装并适应于光伏波动工况,克服了传统实验室用质子交换膜电解水制氢系统的不足之处,提高了设备操作的灵活性和实验控制的可行性。其次,装置可接入实际光伏波动工况下的电源输入,实现制氢系统与波动性能源的耦合制氢,具有重要的实际意义。
Resumen de: CN120519887A
本发明涉及一种析氧电催化材料及其制备方法与应用,属于电解水制氢技术领域。针对现有贵金属基OER催化剂成本高昂、性能差及稳定性不足的技术难题,本发明提出一种负载在导电沸石分子筛骨架上的二氧化铱颗粒的新型OER电催化剂,通过将导电金属离子植入沸石分子筛骨架,并结合金属‑载体协同效应,实现了高活性、高稳定性的OER性能。
Resumen de: CN120515488A
本发明涉及一种负载型镍催化剂及制备方法、氨气分解制氢的方法,属于催化剂技术领域,所述负载型镍催化剂包括分子筛载体以及负载在所述分子筛载体上的镍离子,其中:所述分子筛载体为SOD分子筛,在所述SOD分子筛中,碱金属、铝和硅的摩尔比为(1‑4):1:1;以所述负载型镍催化剂的总质量为100%计,所述镍离子的含量为0.5‑20%。本发明提供的负载型镍催化剂具有丰富的微孔结构、晶化时间短且成本低的优点,能够降低氨气分解所需的温度以及氨气完全分解的温度,极大程度的降低了生产成本,具有巨大应用潜力。
Resumen de: CN120519898A
本发明属于光电催化领域,公开了一种亚硫酸盐和硫化镉/二氧化钛(CdS/TiO2)协同光电解合成2,5‑呋喃二甲酸和氢气的方法。本发明通过引入亚硫酸盐作阳极牺牲剂和光/电生活性物质,与光催化剂CdS/TiO2协同促进5‑羟甲基糠醛光电解合成高附加值2,5‑呋喃二甲酸和绿氢,该方法不仅有利于解决光催化剂不稳定及电解水制氢能耗高的问题,而且合成反应在接近中性的温和条件下进行,避免了强碱和高温高压氧的使用,光电能量利用率高,反应可控,操作简单,成本低,具有潜在的应用前景。
Resumen de: CN120515449A
本申请属于催化剂制备技术领域,具体涉及一种Ni/D‑TiOSO4纳米催化剂及其制备方法和应用。该催化剂包括D‑TiOSO4纳米片和分散在D‑TiOSO4纳米片上的Ni纳米粒子;该D‑TiOSO4纳米片为富含氧缺陷的TiOSO4纳米片;Ni纳米粒子的平均粒径为2.9 nm‑3.6 nm,所述Ni的含量为3.4 wt%‑15.0 wt%。本发明提供的Ni/D‑TiOSO4纳米催化剂表现出优异的催化性能、100%的H2选择性以及出色的稳定性,并且于298 K下添加0.1 M NaOH后,TOF显著提升至414.1 min‑1,具有良好的应用前景。
Resumen de: US2023272543A1
A modular system for hydrogen generation includes a plurality of cores and a hub. Each core includes an electrolyzer and a power supply. The power supply is operable to manage electrical power to the electrolyzer of the core and is redundant to the power supply of at least another one of the plurality of cores. The hub includes a water module, a heat exchange module, and a switchgear module. The water module includes a water source in fluid communication with the electrolyzer of each one of the plurality of cores, the heat exchange module includes a heat exchanger in thermal communication with the electrolyzer of each one of the plurality of cores, and the switchgear module includes a switch activatable to electrically isolate the power supply of each one of the plurality of cores.
Resumen de: CN120519879A
本发明公开了一种光伏电即时电解水制备绿氢的装备,包括多个电解箱本体,所述电解箱本体的上端安装有封盖,多个电解箱本体之间相互架设,所述电解箱本体的一侧固定有固定盒,所述固定盒内设有调节机构,所述调节机构的上端安装有固定盒,所述调节机构上安装有升降机构,所述升降机构上安装有转动机构。本发明避免了传统系统中直流电转换环节的能量损耗,使太阳能能够更直接、高效地用于电解水,提高了能源利用效率,另外可以极大地提升电解液的循环效率和与电极的接触面积,促进了电解反应的进行,显著提高了电解效率,另外,方便快速布设和扩展,满足不同规模的绿氢生产需求,有助于降低绿氢的生产成本,提高绿氢的生产效率。
Resumen de: CN120519891A
本发明属于电解催化剂技术领域,尤其涉及一种钌纳米催化剂及其制备方法和应用。钌纳米催化剂的制备方法,包括以下步骤:(1)将氯化钌水溶液与氧化石墨烯水溶液混合,搅拌均匀,冷冻干燥;(2)将步骤(1)得到的样品置于两片碳纸之间进行焦耳热闪烧退火,所得黑色气凝胶即为钌纳米催化剂。本发明提供了一种高载量超细钌纳米催化剂,包括还原氧化石墨烯基底以及负载在所述基底上兼具高载量与超细特点的钌纳米颗粒。本发明中,还原氧化石墨烯基底呈膨松状,为钌纳米颗粒提供锚定位点,纳米颗粒呈高密度,细小且均匀的分散在基底上,结构清晰。
Resumen de: CN120515337A
本发明公开一种化学方便制氢器及应用,包括外体结构、制氢层室、氢气无水调温净化层室、过滤层室、穿刺注液件、呼吸道吸入应用装置或气管肺部和非呼吸道腔体输入应用装置、制氢化学反应固体物料、可刺破液储液袋和/或设置于穿刺注液件的外源制氢反应用液;制氢层室发生化学反应并制备氢气;制氢结构层室通过穿刺注液件的参与和/或易开盖外体结构的设置获得制氢反应用液的供给,通过固体物料和用液可控性持续供给的结构和机制实现制氢流量和安全性的控制及持续循环制氢。本发明使化学制氢器的应用如同食用方便食品和口服用药一样方便,本发明还包括制氢过程药物介入使制氢过程伴随药蒸气产生的技术和结构基础。
Resumen de: JP2023106855A
To provide a hydrogen system operation planning device which can accurately create an operation plan that achieves an efficient operation in a hydrogen system.SOLUTION: A hydrogen system operation planning device 200 that plans an operation of a hydrogen system comprising a hydrogen manufacturing deice for manufacturing hydrogen by using electric power, includes: a classification part 210 into which a DR command related to a demand of the power in the hydrogen system is input, and which classifies the input DR command into a first DR group and a second DR group having a priority lower than that of the first DR group; a first plan part 220 that creates a first operation plan so as to reflect the DR command classified into the first DR group; and a second plan part 230 that creates a second operation plan by reflecting contents of the DR command classified into the second DR group upon the first operation plan so that the command of the DR command classified into the first DR group is more prioritized than the content of the DR command classified into the second DR group.SELECTED DRAWING: Figure 2
Resumen de: CN120517544A
本发明涉及海上风电技术领域,尤其涉及一种风电场制氢储运系统,包括风电制氢平台和穿梭储氢船,风电制氢平台能够将风能转化为电能并进行电解水制氢,多个风电制氢平台间隔分布在海上并通过场内输氢管连接组成风电制氢场,风电制氢场上外接有场外输氢管,场外输氢管漂浮在海上,穿梭储氢船能够与场外输氢管连通并对来自风电制氢场的氢气进行储存,多个穿梭储氢船交替往返于风电制氢场和码头进行氢气运输。该风电场制氢储运系统能够通过风电制氢场进行分布式制氢,并借助穿梭储氢船进行集中式储运,大幅降低了氢的转运技术难度、转运能量损失和转运泄露爆炸风险。
Resumen de: CN120521160A
本发明涉及氢气管路检测技术领域,尤其涉及一种制氢站电解水系统管路氢泄漏检测设备,包括有复合式气体检测仪和探头;复合式气体检测仪上通过连接管连接有探头。本发明实现了通过刮板刮除输氢管上侧表面结块的污垢,实现对输氢管上侧表面的清理,避免结块的污垢阻碍第一万向滚珠和第二万向滚珠滚动,影响第一半圆筒和第二半圆筒向左移动;通过膨胀的第一气囊和第二气囊对从第一喷口和第二喷口中喷出的气流进行阻挡,实现对泄漏氢气的引导,避免泄漏的氢气和泄漏的氧气共同流向输氢管和输氧管之间的位置,导致上述两种泄漏的气体相互混合在一起,危害检测人员的人生安全。
Resumen de: CN120519880A
本发明涉及电催化技术领域,公开了一种用于碱性电解槽的高润湿性复合多孔陶瓷电极的制备方法,包括隔膜和催化剂层两个部分,所述的隔膜由聚砜、钇掺杂氧化锆纳米颗粒、聚丙烯网格组成,所述的催化剂层由过渡金属Ni、Fe、Co组成,该复合多孔陶瓷电极多孔骨架支撑复合膜的制备、过渡金属催化剂层的涂附工艺,该复合多孔陶瓷电极能够在强碱环境、高温下稳定工作,并且提供较高的电流密度,具有很高的制氢效率,该制备工艺能够将隔膜与催化剂层一体化,降低接触电阻,同时能够减少贵金属在制氢方面的使用,易于广泛推广。
Resumen de: CN120520706A
本发明公开了一种能量转换装置,属于能量转换技术领域,包括电解水设备、燃烧室、蒸汽室、气缸、氢气存储罐、氧气存储罐;电解水设备的氢气出口通过连接管一与氢气存储罐的进气口连接,电解水设备的氧气出口通过连接管二与氧气存储罐的进气口连接,氢气存储罐的出气口通过连接管三与燃烧室的进气喷口一连接,氧气存储罐的出气口通过连接管四与燃烧室的进气喷口二连接,燃烧室设有电子点火器;蒸汽室顶端通过连接管五与气缸进气口连通;气缸外壁包裹有冷却箱;燃烧室底侧设有排水口。本发明的优点在于:本发明能量梯级利用率高,闭环清洁运行,燃烧速度快,启动迅速,在能量转化过程中可以实现相应的功能,从而达到能量的充分利用。
Resumen de: CN120515470A
本发明公开了一种高结晶度melon基氮化碳光催化剂及其制备方法和应用,属于光催化材料制备技术领域。本发明采用分阶段控温聚合工艺,通过精准调控含氮前驱体的脱氨动力学过程,在高温条件下成功构建具有有序层状堆垛结构的高结晶度氮化碳材料。该光催化剂在可见光区展现出优异的宽谱响应特性,配合铑‑铬双金属及碳包覆四氧化三钴(Co3O4@C)复合助催化剂体系时,其光催化全分解水性能明显优于传统无定形氮化碳材料。本发明为规模化制备高效稳定光解水催化剂提供了新策略,在清洁能源生产领域具有重要应用价值。
Resumen de: CN120519908A
本申请属于高熵电催化剂技术领域,具体涉及一种高价金属掺杂镍铁锌铈钴(氧)氢氧化物双功能催化剂、制备方法及应用。本申请采用一步水热法,在室温下配成含有镍、铁、锌、铈、钴等金属盐溶液,并将其充分搅拌超声均匀,放入高压釜中,加入泡沫镍浸渍,水热、洗涤、干燥得到负载在泡沫镍(NF)上的高价金属掺杂的镍铁锌铈钴(氧)氢氧化物材料。由于多种金属之间的协同效应加速了电荷转移,尤其是Cr的引入,可以调节电子结构,增强导电性,暴露丰富的活性位点,可获得优异的电催化活性。本申请的制备方法温和可控,实用性强,且重现性好,对环境友好,具有较优异的双功能电催化性能,可应用于电解水制氢领域,还可以进一步用于尿素氧化领域。
Resumen de: CN120519894A
本发明涉及了一种基于微波技术的PtFe/NF纳米片快速制备方法,该方法以氯铂酸和硝酸铁和泡沫镍为原料,以乙醇‑水混合溶液为溶剂,通过微波反应器实现PtFe/NF纳米片的高效合成。该制备工艺具有操作简便、绿色环保、反应速率快等显著优势,所制得的PtFe/NF纳米片在碱性淡水及碱性海水电解制氢领域展现出良好的应用前景,有望为氢能制备技术提供创新型解决方案。
Resumen de: CN120519937A
本发明公开了一种减少镁合金支架表面氢气析出的方法,涉及生物医用材料表面改性技术领域,包括以下步骤:表面纳米化处理:采用超声表面滚压技术,在镁合金支架表面制备厚度5‑20μm的纳米晶层,晶粒尺寸控制在20‑100nm,表面粗糙度Ra≤0.5μm,使表面活性位点密度降低30%‑50%;复合涂层沉积。该减少镁合金支架表面氢气析出的方法,通过表面纳米化处理降低表面活性位点密度,复合涂层提供物理屏障,微弧氧化陶瓷层增强耐腐蚀性,稀土元素掺杂调控电化学反应,四重机制协同作用,使镁合金支架的析氢速率显著降低,在模拟体液中测试,平均析氢速率≤0.05mL/(cm2·d),优于现有单一涂层技术的抑制效果。
Resumen de: CN120519886A
本发明公开了一种Cu1.8S/C复合材料、其制备方法及应用,属于电解制氢技术领域。其技术方案包括将Cu块作为阳极靶材放置在电弧反应室内的水冷铜台上,石墨棒作为阴极,点弧前抽真空,随后,向反应室内依次通入氩气和甲烷,点弧,停弧之后抽出残余气体,将炉内的纳米颗粒在氩气气氛下钝化,在反应室顶部和侧壁收集黑色粉末,该粉末即为Cu/C纳米颗粒;将上述Cu/C纳米颗粒和S粉在550℃及氩气保护下进行热处理,得到Cu1.8S/C纳米复合材料。本发明应用于电解制氢方面,解决硫化铜类化合物较低的载流子迁移速率问题,具有高效的载流子迁移、耐久性好及催化效率高的特点。
Resumen de: CN120515443A
本发明属于压电光催化剂领域,具体涉及一种用于光催化产氢及还原CO2的CuCo2S4/Co0.2Cd0.8S复合催化剂。本发明以铜钴硫(CuCo2S4)为助催化剂通过简单的水热法制备富有硫空位的CuCo2S4/Co0.2Cd0.8S‑Vs复合催化剂,CuCo2S4稳定性优良,微观结构明显易于观察,且CuCo2S4的引入没有改变Co0.2Cd0.8S‑Vs的晶体结构,制备的复合催化剂的结晶度和纯度较高,于太阳光照射和超声波振动协同作用下,进行压电光催化产H2,或压电光催化还原CO2产CO和CH4;具有高催化活性和较好的稳定性。
Resumen de: CN120519876A
本申请公开了一种膜电极的制备方法、膜电极及电解槽,制备方法包括:将氧化锡锑ATO负载的氧化铱催化剂作为电解水制氢的阳极催化剂,配制成析氧电极浆料;将40%铂炭(Pt/C)催化剂作为电解水制氢的阴极催化剂,配制成析氢电极浆料;预处理质子交换膜(Nafion,N117),在搅拌的条件下,分别用80℃~85℃的5wt%双氧水和5wt%的硫酸处理至少1小时,之后用去离子水反复冲洗,干燥质子交换膜,并用热压机将质子交换膜压作平整处理;将阴极和阳极催化剂浆料分别喷涂在转印膜PTFE上;将上述涂有催化层的转印膜PTFE和质子交换膜热压在一起,自然冷却后取下PTFE膜,得到膜电极。本申请的技术方案提升了膜电极的性能和稳定性。
Resumen de: CN120515745A
本发明提供了一种用于水电解制氢PEM膜电极修复的清洗装置,属于PEM膜电极清洗技术领域。其技术方案为:包括溶剂槽,溶剂槽内两侧侧壁上均设置有转轴,两个转轴之间设置有用于放置PEM膜电极的夹持机构,溶剂槽外侧面上设置有电机,相应侧转轴设置在电机的输出轴上;夹持机构包括一对分别同轴设置在两个转轴内侧端的圆盘,两侧圆盘之间沿同一圆周设置有若干组支撑部,支撑部包括弧形长板,弧形长板上设置有若干组固定块,相邻两个固定块之间形成弧形夹槽。本发明的有益效果为:本装置通过创新的结构设计和自动化控制,不仅提高了PEM膜电极的清洗效果和完整性,还增强了装置的通用性、操作简便性和稳定性,具有显著的技术优势和经济效益。
Resumen de: CN120515454A
本发明提供了一种高暴露活性位点异金属多酸团簇催化剂的制备方法,将无催化活性位点的镍(Ni)取代POM(NiW)通过精准热活化改性,成功合成了高暴露活性位点的350‑HNiW材料。在水分解产氢的光催化反应中,350‑HNiW的产氢速率可达55mmol·g‑1·h‑1。催化剂的改性方法非常简单,只需要通过计算热稳定性差异,在管式炉中进行精准加热活化。催化剂经历从无催化活性到高催化活性的过程,从而高效分解水产氢。
Resumen de: CN120519896A
本发明公开了一种三金属尖晶石氧化物/高价金属氧化物复合OER电催化剂及其制备方法。所述方法先通过胶体磨一步合成缺陷丰富的三金属LDH纳米片,然后利用离子交换法将高价过渡金属氧酸根离子插入LDH层间,最后采用低温热氧化法使LDH向尖晶石结构拓扑转化同时产生更多的缺陷,制得复合氧化物电催化剂。本发明基于层状双氢氧化物层间阴离子的可调性质,结合成核晶化隔离法、离子交换法和热氧化技术,制备了具有超薄纳米片结构和丰富的表面缺陷的复合氧化物电催化剂,其具有远高于贵金属的OER催化性能。
Resumen de: CN120519883A
本发明涉及酸性析氧反应催化剂领域,公开了一种Ru基析氧催化剂及其制备方法和应用。制备方法为:制备CoMn‑ZIF‑L前驱体骨架;将CoMn‑ZIF‑L前驱体骨架在惰性气氛下煅烧,得到载体;将载体分散在溶剂中,然后加入RuCl3溶液中反应,将反应产物分离、洗涤、干燥后在空气氛围下煅烧,得到所述Ru基析氧催化剂。本发明以MOF骨架载体限域、原子掺杂配位重构、界面稳定性强化为协同调控路径,制备出基于沸石咪唑酯骨架结构前驱体的叶状薄片钴锰尖晶石作为新型载体,最终实现高Ru利用率、强界面相互作用、快传质效率的三重突破。
Resumen de: CN120515459A
本发明涉及光催化析氢技术领域,公开了一种光诱导高分散AgNi/CM‑C3N4催化剂的制备方法及应用,制备方法为:将CM‑C3N4分散在银盐和镍盐的混合水溶液中,通过超声搅拌直至分散均匀,将混合悬浮液置于氙灯光源下,将得到的沉淀物干燥后研磨,即得到AgNi/CM‑C3N4光催化剂。本发明使用的光诱导法操作简单,抑制颗粒团聚,得到的催化剂光催化析氢活性得到明显提升。
Resumen de: CN120515376A
本公开涉及氢气制备技术领域,特别是集成式本生反应器及热化学硫碘循环制氢工艺,包括内衬抗腐蚀材料的反应容器,反应容器上部设有通入本生反应原料的喷射器,中部设有硫酸相出口,底部设有氢碘酸相出口;喷射器包括夹套管和设于其内的内管,内管为本生反应原料的液相流道,夹套管为本生反应原料的气相流道,高压的本生反应原料通过喷射器形成雾状气液混合物,实现了气体和液体在带压下的瞬间均匀混合,消除了气液相的传质阻力,极大的缩短了反应所需的时间,同时在加压状态下,打破SO2的5%溶解度限制,实现了一次性完全溶解,解决了系统硫元素的完全闭环循环难题。
Resumen de: CN120515441A
本发明公开了一种基于金属载体的整体式催化剂、制备方法及应用;该方法包括:对金属载体进行碱/酸超声清洗、干燥后,通过梯度氧化处理在载体表面形成氧化层,最后采用浸渍法、3D打印涂覆或电弧喷涂法负载催化层;本发明通过碱刻蚀去除表面杂质,结合梯度氧化工艺在金属载体表面形成特殊氧化层结构,显著增强了催化剂与载体的界面结合强度,优化了传质/传热性能。该方法工艺简单、易于规模化生产,所制备的催化剂在氨分解制氢反应中表现出优异的催化活性和高温稳定性,特别适用于高温条件下的高效制氢应用。
Resumen de: CN120519915A
一种电解槽测试系统及压力分程控制方法,属于电解水制氢测试技术领域,解决如何提高电解槽制氢时测试系统的稳定性,减少产气量波动对压力的影响的问题,本发明通过并联大小阀门的方式分程调控阀门总开度,能够合理的调控电解槽的产物以及保证整个测试系统的工况压力稳定性,避免单个阀门进行控制时无法达到工况需求;并联双阀门的分程控压方法既能确保不同电流拉载工况下气量变化时测试系统的稳定性和安全性,还能够稳定工况下阴阳极压差从而确保电解槽的质子交换膜的使用寿命。
Resumen de: CN120519899A
本发明提供了一种海水电解制氢膜电极制备及双极板、阳极集电器的处理方法,一种海水电解制氢膜电极制备方法,包括以下步骤:步骤1:通过静电纺丝制备纳米纤维,将制备的纳米纤维进行分切为短纤维,然后和粘结剂混合,加入溶剂,分散均匀得到纤维浆料;步骤2:将纤维浆料涂布在质子交换膜表面,干燥形成纳米纤维层;步骤3:称取阳极催化剂、粘结剂和溶剂混合,分散均匀得到阳极催化剂浆料;本发明的有益效果是:在制备时采用静电纺丝技术将全氟磺酸树脂和功能性聚合物混合制备成纳米纤维,且降低分切成均匀的尺寸,形成有序的多孔结构。
Resumen de: CN120515343A
本发明涉及能源技术领域,特别涉及一种光‑热化学链制氢系统,包括进气单元水蒸气单元、光‑热固定床反应器和石英气液分离单元,光‑热固定床反应器包括旋转石英管反应器、位于旋转石英管反应器上方的高能流太阳能模拟器和位于旋转石英管反应器下方的加热组件,进气单元和水蒸气单元分别与旋转石英管反应器的进气端管道连接,石英气液分离单元与旋转石英管反应器的出气端管道连接。本发明通过旋转石英管反应器转动,使得反应器中全部氧载体材料均能够受到光的照射,在短时间内实现光催化和光热催化,并通过调整光源功率实现对温度的精准调控,实现超纯氢气≥99%及高选择性合成气制备,提高了系统能量效率,降低制氢成本,具有广阔的应用前景。
Resumen de: CN120521294A
本申请涉及燃气热水器领域,尤其涉及一种燃气热水器、燃气热水器控制方法、装置及介质,包括:氢气产生装置、燃气加热装置、进气三通阀和溶气罐;氢气产生装置包括纯水提供装置和电解水装置,纯水提供装置与电解水装置连接;电解水装置进气三通阀连接;燃气加热装置包括热交换器,所述热交换器包括出水口;进气三通阀与出水口连接,进气三通阀与溶气罐连接。由此可见,电解水装置产生的氢气通过进气三通阀流入溶气罐,经过加热的市政水通过进气三通阀流入溶气罐中,从而使得在溶气罐中氢气充分溶解于经过加热的市政水,进而防止氢气发生逃逸,有效提高氢气的利用率。
Resumen de: CN120515339A
本发明公开了一种氨裂解催化剂搭载结构及微反应器,搭载结构包括多个搭载体,多个搭载体沿第一方向依次叠合设置,搭载体均布有沿第一方向贯通设置的多个过气孔,相邻两个搭载体上的过气孔至少有一部分在第一方向上错位设置,相邻两个搭载体相互叠合的至少一面均布有多个流道槽,对应的搭载体上的过气孔设于流道槽内,相邻两个搭载体上相互靠近的过气孔通过流道槽连通,过气孔和流道槽分别设有氨裂解催化剂。既能保证反应气体在经过搭载体时留有充分的时间在搭载体表面的氨裂解催化剂作用下进行反应,又能够保证一定的气体通量,使得反应完的气体及时排出,同时减小搭载结构的体积,又能减少反应气体沿程路径,从而降低逆反应的产生。
Resumen de: CN120519914A
双极膜强化电解水制氢电解槽,涉及电解水制氢技术领域,包括集成底座,集成底座上设有双极膜电解模块、水路循环模块、散热模块、纯化干燥模块;双极膜电解模块包括电解箱,电解箱焊接在集成底座上;电解箱内焊接有分隔竖板,分隔竖板上固定有电场发生器;分隔竖板上开设有连通口,连通口的两侧固定设有前段电解管和后段电解管;前段电解管上开设有阳离子排出口,阳离子排出口内固定有阳离子交换膜;前段电解管内还固定设有水平界面膜;后段电解管上开设阴离子排出口,阴离子排出口内固定有阴离子交换膜;后段电解管内还固定设有竖直界面膜。本发明解决了电解水制氢中存在的高能耗、低纯度、散热难、耗水多、系统庞杂、控制僵化及安全风险等问题。
Resumen de: DE102024201557A1
Die Erfindung betrifft ein Verfahren zum Betrieb einer Elektrolyseanlage (1, 20) umfassend einen Elektrolyseur (11) zur Erzeugung von Wasserstoff (H2) und Sauerstoff (O2) als Produktgase, wobei Wasser als Edukt zugeführt wird und an einer protonenleitenden Membran (21) aus einem fluorfreien Polymer (24) zu Wasserstoff (H2) und Sauerstoff (O2) gespalten wird, wobei das Polymer (24) ein nicht-funktionelles Polymermaterial mit einer funktionellen hydrophilen Gruppe aufweist, wobei ein Produktgasstrom (5) in einem Phasengemisch umfassend Wasser (H2O) sowie ein jeweiliges Produktgas gebildet wird, und wobei ein Produktgasstrom einem dem Elektrolyseur (11) nachgeschalteten Gas-Separator (3, 13) zugeführt wird, und bei dem die Freisetzung eines ionischen Abbauproduktes der funktionellen hydrophilen Gruppe der Membran (21) über die Betriebszeit bestimmt wird, wobei dessen zeitlicher Verlauf der Konzentration ermittelt wird, wobei ein Maß für die betriebsbedingte Degradation der protonenleitenden Membran (21) infolge einer Freisetzung des ionischen Abbauprodukts der hydrophilen Gruppe ermittelt wird.Die Erfindung betrifft weiterhin eine entsprechende Elektrolyseanlage (1, 20) sowie eine Messsystem zur Durchführung des Verfahrens.
Resumen de: US2025263850A1
A polymer electrolyte membrane (PEM) electrolytic cell assembly, and a method for making the assembly, are provided. An exemplary method includes forming a functionalized zeolite templated carbon (ZTC), including forming a CaX zeolite, depositing carbon in the CaX zeolite using a chemical vapor deposition (CVD) process to form a carbon/zeolite composite, treating the carbon/zeolite composite with a solution including hydrofluoric acid to form a ZTC, and treating the ZTC to add catalyst sites, forming the functionalized ZTC. The method further includes incorporating the functionalized ZTC into electrodes, forming a membrane electrode assembly (MEA), and forming the PEM electrolytic cell assembly. The method further includes coupling the PEM electrolytic cell assembly to a heat source.
Resumen de: WO2025172046A1
The invention relates to a method for operating an electrolyzer (1) comprising an anode chamber (3) and a cathode chamber (5), in which water (H2O) is supplied as a reactant and hydrogen (H2) and oxygen (O2) are generated as product gases. On the anode side, the oxygen product gas, which also contains hydrogen as a foreign gas, is generated in a product flow out of the anode chamber (3) and is introduced into a horizontal anode-side collecting line (7) having a surrounding wall (11) and is removed via the collecting line (7), wherein water (H2O) is sprayed onto an inner surface of the surrounding wall (11) of the collecting line (7) so that the surrounding wall (11) is wetted with water and the inner surface is inerted. The invention additionally relates to an electrolyzer (1), in particular for carrying out the method.
Resumen de: WO2025172702A1
An apparatus comprising an electrolyser subsystem (20), a Haber Bosch subsystem (22), and an Ostwald subsystem (24), and a method for producing nitric acid. Fluid passageways are configured to: route hydrogen produced by the electrolyser subsystem (20) to the Haber Bosch subsystem (22) via a first path (26) for use in a Haber process at the Haber Bosch subsystem (22) to produce ammonia; route at least a portion of the ammonia produced by the Haber Bosch subsystem (22) to the Ostwald subsystem (24) via a second path (28) for use in an Ostwald process at the Ostwald subsystem (24) to produce nitric acid; and route at least a portion of steam produced using heat from the Ostwald subsystem (24) to the electrolyser subsystem (20) via a third path (30) for use as at least a part of an infeed gas for the electrolyser subsystem (20).
Resumen de: US2025263845A1
The invention relates to a method and an apparatus for the production of hydrogen from a hydrogen-containing substance by splitting the hydrogen-containing substance into its components, wherein the hydrogen-containing substance is stimulated by means of an electromagnetic wave generator. The electromagnetic wave generator emits energy at the resonant frequency of an atomic bond of the hydrogen-containing substance. According to the invention, it is provided that the splitting of the hydrogen-containing substance takes place in an electromagnetic resonator.
Resumen de: US2025263322A1
Methods, systems and devices for PFAS destruction including adding a sulfite salt to an aqueous solution containing PFAS and then irradiating the aqueous solution with light at 222 nm. The method may include adding a base to the aqueous solution in an amount sufficient to raise a pH of the aqueous solution including PFAS to about 10 or more. It may also include adding a halide salt such as a bromide salt or an iodine salt, and further adding a carbonate. Greater than 90%, or greater than 99%, of the PFAS in the solution may be destroyed by irradiating the aqueous solution in this way.
Resumen de: US2025263302A1
The present invention describes an improved catalytic reactor system with an improved catalyst that transforms CO2 and low carbon H2 into low-carbon syngas with greater than an 80% CO2 conversion efficiency, resulting in the reduction of plant capital and operating costs compared to processes described in the current art. The inside surface of the adiabatic catalytic reactors is lined with an insulating, non-reactive surface which does not react with the syngas and effect catalyst performance. The improved catalyst is robust, has a high CO2 conversion efficiency, and exhibits little or no degradation in performance over long periods of operation. The low-carbon syngas is used to produce low-carbon fuels (e.g., diesel fuel, jet fuel, gasoline, kerosene, others), chemicals, and other products resulting in a significant reduction in greenhouse gas emissions compared to fossil fuel derived products.
Resumen de: US2025263361A1
The present invention relates to a process for producing dimethyl ether (DME) and hydrogen (H2) from methane, comprising the steps of: a) providing a gaseous feed stream comprising methane; b) reacting said gaseous feed stream with at least one halogen reactant (X2), under reaction conditions effective to produce an effluent stream comprising methyl halide (MeX), and hydrogen halide (HX); c) separating from the effluent stream obtained in step b): (i) a methyl halide (MeX) stream; and, (ii) a hydrogen halide (HX) stream; d) reacting the methyl halide (MeX) stream separated in step c) with a solid metal oxide (MO(s)) under reaction conditions effective to produce metal halide (MX) and dimethyl ether (DME); and e) decomposing by means of electrolysis said hydrogen halide (HX) stream separated in step c) under conditions effective to produce a gaseous hydrogen (H2) stream and a stream comprising halogen reactant (X2).
Resumen de: US2025263849A1
A method of electrolysing hydrogen bromide comprising the steps i) brominating a hydrocarbon such that hydrogen bromide is produced, ii) providing an electrolytic cell comprising an anode, a cathode, and a membrane sandwiched between the anode and the cathode, iii) feeding a first composition comprising hydrogen bromide and water to the anode, iv) feeding a second composition comprising hydrogen bromide and water to the cathode, and v) operating the electrolytic cell to produce hydrogen at the cathode, wherein the hydrogen bromide fed in step iii) and/or the hydrogen bromide fed in step iv) is hydrogen bromide produced in step i).
Resumen de: US2025263294A1
Ammonia, methanol, Fischer Tropsch products, and derivatives thereof are made by using hydrogen and oxygen supplied from an electrolyzer that is at least partially powered by renewable power, resulting in green process and systems that produce green products disclosed herein. A process using biomass and renewable energy includes producing an unshifted syngas from biomass and oxygen in a gasification unit, introducing water into an electrolyzer to produce an oxygen product and a hydrogen product, and introducing the oxygen product to the gasification unit. The electrolyzer is powered by renewable energy, and the oxygen product supplies at least a portion of the oxygen to the gasification unit.
Resumen de: US2025262590A1
Proposed is a system for capturing and recycling carbon dioxide and producing hydrogen for a cement manufacturing facility. The system includes a preheater provided with multiple stages of cyclones arranged in series in a vertical direction and configured to receive and preheat a cement raw material, a calciner configured to calcine the cement raw material preheated by the preheater, a kiln configured to burn the cement raw material calcined in the calciner, an exhaust line connected to the cyclones and configured to discharge an exhaust gas respectively discharged from the calciner and the kiln to the outside, a reactor configured to capture carbon dioxide in the exhaust gas, to collect a reactant containing the captured carbon dioxide, and to separate a carbon dioxide reactant and a waste solution in the reactant, and a hydrogen generator configured to generate hydrogen gas by receiving the separated carbon dioxide from the reactor.
Resumen de: US2025262610A1
According to the embodiments of the present disclosure, an ammonia decomposition catalyst may be prepared by performing heat treatment on alumina, a lanthanum compound and a cerium compound in a reducing gas atmosphere to form a composite oxide on an alumina support, and supporting an active metal including ruthenium on the composite oxide.
Resumen de: US2025267782A1
A system which facilitates the joining of metal or ceramic objects via heat in an oxygen-depleted atmosphere comprising: a plasma flame generator (torch), regulator, gas purifier, in-situ hydrogen generator, liquid pumps, battery, and electrical power supply. The electrical system is self-contained and is intended to provide equal or greater functionality to that of existing TIG/Plasma arc welders but in a portable form-factor free from reliance on expensive and cumbersome high pressure compressed gas bottles.
Resumen de: US2025263349A1
The invention relates to a process, catalysts, materials for conversion of renewable electricity, air, and water to low or zero carbon fuels and chemicals by the direct capture of carbon dioxide from the atmosphere and the conversion of the carbon dioxide to fuels and chemicals using hydrogen produced by the electrolysis of water.
Resumen de: US2025266688A1
A system network includes at least two electrolysis systems, a power supply source, and a central supply line. The central supply line is connected to the secondary side of a transformer. The primary side of the transformer can be fed with energy from the power supply source. The transformer is designed for an operating frequency above the mains frequency of the public power grid, and so a higher-frequency AC grid is formed, to which the electrolysis systems are connected via the central supply line.
Resumen de: US2025266470A1
Electro-energy or electro-synthetic cells whose architectures allow them to be readily stacked into a cell stack. The cells include polymeric cell frames that incorporate within them, functional materials, such as an inter-electrode separator, electrodes, metallic bipolar plates, and the like. For example, an electro-energy or electro-synthetic cell includes a polymeric cell frame, a first electrode and a second electrode, and an inter-electrode separator positioned between the first electrode and the second electrode. A compressive component is positioned adjacent to the first electrode. The compressive component may be a metallic bipolar plate compressive component and/or a metallic porous transport layer compressive component. In one example the polymeric cell frame is sealed to the metallic bipolar plate by a polymer-to-metal join. In another example at least one polymeric structural locating component locates the metallic bipolar plate against the polymeric cell frame. A cell stack includes a plurality of the cells.
Resumen de: US2025266534A1
A water electrolysis system includes: a water electrolysis device including a membrane electrode assembly formed by sandwiching an electrolyte membrane between an anode and a cathode, the water electrolysis device being configured to generate oxygen gas at the anode by supplying water to the cathode and electrolyzing the water; and a water supply device configured to supply, to the anode, water generated in association with power generation of a fuel cell stack.
Resumen de: AU2024219118A1
The present application relates to a flow field for use in an electrolysis cell comprising one or more sheets of porous material with a corrugated structure. The electrolysis cell comprises a membrane, an anode, a cathode, an anode reinforcement layer, a cathode reinforcement layer, an anode flow field, a cathode flow field, and a bipolar plate assembly comprising an embedded hydrogen seal. The anode flow field comprises one or more porous sheets having at least one straight edge and at least one of the porous sheets has the form of a corrugated pattern with a plurality of peaks and valleys whose axes are generally aligned with one straight edge of the sheet. The anode flow field geometry simultaneously provides resiliency, for efficient mechanical compression of the cell, and well-distributed mechanical support for the anode reinforcement layer adjacent to the anode flow field.
Resumen de: AU2024307301A1
A method and arrangement of performing electrolysis by an electrolyzer includes an operational mode and a partial operational mode. During the operational mode operational power from a main power source (202) to a first (808) and second set of stacks (806). In response to detecting a power insufficient for the first and the second set of stacks (806) to perform electrolysis without impurities, the electrolyzer is set to a partial operational mode, wherein the first set of stacks (808) perform electrolysis without impurities and the second set of stacks (806) do not perform electrolysis.
Resumen de: KR20250125006A
본 발명은 수전해 스택에 관한 것으로서, 직렬로 적층되는 복수의 스택 유닛과, 상기 복수의 스탯 유닛의 양단에 형성되는 엔드플레이트를 포함하여 구성되고, 상기 스택유닛은, 육각형 형상으로 형성되는 복수의 MEA를 포함하고, 상기 복수의 MEA는 인접하는 MEA와 서로 교대로 어긋나게 배치되고, 상기 엔드플레이트는 상기 복수의 MEA의 배치형상에 상응하는 형상을 가지는 것을 특징으로 하며, 복수의 MEA를 병렬로 배치하여 수전해 스택의 용량을 증가시킬 수 있고, MEA를 육각형으로 형성하여 MEA간의 간격이 일정하게 이격되어 MEA간에 전압, 전류 차가 일정하게 유지되어 효율이 높고, 장수명을 기대할 수 있으며, 육각형으로 형성된 복수의 MEA를 2열로 배치하되 서로 교대로 어긋나게 배치하여, 1.5열의 배치에 가깝게 배치할 수 있으므로, 스택유닛이 차지하는 면적을 작게하여 콤팩트하게 제조할 수 있다.
Resumen de: KR20250125005A
본 발명은 수전해 스택에 관한 것으로서, 복수의 장착구멍이 형성된 애노드측 플레이트와, 상기 애노드측 장착구멍에 상응하는 위치에 형성된 복수의 장착구멍을가지는 캐소드측 플레이트와, 상기 장착구멍에 상응하는 구멍을 가지며 상기 애노드측 플레이트와 상기 캐소드측 플레이트가 연결되는 수전해 스택바디와, 상기 장착구멍에 착탈가능하게 삽입되는 복수의 셀 모듈을 포함하여 구성되고, 상기 셀 모듈은, MEA를 포함하며 기둥형상으로 형성되는 MEA유닛과, 애노드측 유닛과, 캐소드측 유닛을 포함하여 구성되고, MEA유닛을 애노드측 플레이트와 캐소드측 플레이트에 착탈하게 구성함과 동시에 MEA유닛을 기둥형으로 복수개가 착탈가능하게 구성함으로써 스택의 용량을 용이하게 증가시킬 수 있고 스택에 용이하게 착탈가능하게 구성하여 조립이 용이하고 경제적인 수전해 스택을 제공할 수 있다. 또한, 기둥형상으로 병렬로 조립하여 고압의 압력을 사용하더라도 MEA가 손상되지 않을 뿐만 아니라 기둥형상의 MEA지지체가 애노드측 플레이트와 캐소드측 플레이트에 단단하게 체결되어 축하중을 지지할 수 있으므로 고압 압력에도 견딜 수 있는 수전해 스택을 제공할 수 있다.
Resumen de: KR20250125178A
본 발명은 수소 생산 원료인 암모니아를 가열하여 분해 반응을 수행하기 위한, 시스템의 준비(start-up), 시스템 질소 퍼징 및 버너 공기공급, 분해반응기 승온, 암모니아 공급, 분해가스 생성확인 및 시스템 정지(shut-down)를 순차적으로 수행하는 정제된 수소를 생산하는 암모니아를 이용한 수소 생산 시스템 및 그 제어방법에 관한 것이다.
Resumen de: WO2025174971A1
A method can include coupling sulfur dioxide depolarized electrolysis (e.g., electrochemical oxidation of sulfur dioxide to sulfuric acid with electrochemical reduction of water to hydrogen) with the contact process to facilitate formation of high concentration sulfuric acid with concurrent hydrogen production. The sulfuric acid and hydrogen can optionally be used cooperatively for downstream processes (e.g., metal extraction from ore, fertilizer production, hydrocarbon processing, etc.).
Resumen de: WO2025173338A1
This pretreatment method comprises, prior to incorporating a mesh plate (80) into a cell, exposing the mesh plate (80) to ultrasonic waves while the mesh plate (80) is immersed in water. Hydrophilicity of the mesh plate (80) is thereby improved. Stagnation of gas in the mesh plate (80) when an electrochemical reaction is performed in a cell can therefore be suppressed. The efficiency of an electrochemical reaction in a cell can be improved as a result.
Resumen de: WO2025173297A1
A water splitting device for generating hydrogen when irradiated with light, said water splitting device comprising: an electrolytic bath that is filled with an electrolytic solution; and a water splitting cell that is immersed in the electrolytic solution and comprises a laminate in which an anode, a hole transport layer, a Perovskite battery cell, an electron transport layer, and a cathode have been laminated in the given order, and an electrically insulating protective material which covers the outer periphery of the laminate.
Resumen de: WO2025171442A1
The invention is directed to methods of electrolysis and cells used for the same. The method comprising generating and delivering a humidified gas stream or liquid water to an electrolysis cell comprising an anode side, a cathode side and an ion permeable membrane located between them wherein the anode side has a first catalytic layer and the cathode side has a second electrolytic layer, contacting the humidified gas stream or liquid water with the first catalytic layer and contacting a portion of the ion- permeable membrane on the cathode side with liquid water, applying a voltage such that oxygen gas is generated at the anode and hydrogen gas is generated at the cathode. The invention is also related to an electrolytic cell for performing the methods and a kit that allows for retrofitting existing cells to perform the methods.
Resumen de: US2025263859A1
A method of producing hydrogen and/or bromine by electrolysing hydrogen bromide using a fluoropolymer membrane having a glass transition temperature Tg≥110° C. in an electrolysis of hydrogen bromide, wherein the hydrogen bromide stems from a sulfuric acid synthesis.
Resumen de: US2025263853A1
A control device includes a controller that controls a first power supplier structured to supply power to an electrolytic bath for generating an organic compound and a second power supplier different from the first power supplier and structured to supply power to the electrolytic bath. The controller controls the second power supplier based on a change in a voltage between a cathode electrode and an anode electrode provided in the electrolytic bath to a specified voltage, a change in a potential of the cathode electrode to a specified potential ECA1, or a change in a potential of the anode electrode to a specified potential EAN1.
Resumen de: US2025263847A1
A system and method to precipitate calcium hydroxide at low temperatures (T<40° C.) using an electrolytic reactor with hydrodynamic separation. The calcium can be supplied by any calcium bearing material such as calcium carbonate or basalt rock, or from industrial wastes such as brine or steel slag. The solid feedstock undergoes dissolution, whereas the brine may be utilized as is. Once in solution, the feed stream is directed towards an electrolyzer reactor which comprises a cathode, an anode, and a membrane separator. At the cathode, or in a separate precipitation chamber, an alkaline catholyte solution containing calcium hydroxide (portlandite) and magnesium hydroxide (brucite) precipitates, and hydrogen gas is produced.
Resumen de: US2025263844A1
A system for hydrogen recovery includes a dryer having an inlet that may be fluidly connected to a hydrogen outlet of a hydrogen generator, a hydrogen using device having an inlet fluidly connected to a dry hydrogen outlet of the dryer, and one or more conduits fluidly connecting a wet hydrogen outlet from the dryer and an impure hydrogen exhaust outlet of the hydrogen using device to the inlet of the dryer.
Resumen de: US2025263848A1
Particular embodiments described herein provide for a synthetic fuel creation system. The synthetic fuel creation system includes a syngas creation station to create syngas, a crude creation station to create heavy syncrude, and a crude cracking station to convert the heavy syncrude into synthetic fuel. The synthetic fuel creation system can use an electrocatalysis system to create the syngas and the electrocatalysis system can include an anode, a cathode, oxygen evolution reaction catalysts, hydrogen/carbon monoxide evolution reaction catalysts, and an electrolyte, where the hydrogen/carbon monoxide evolution reaction catalysts include a graphitic carbon nitride.
Resumen de: US2025263846A1
To provide a water electrolysis stack capable of suppressing deterioration in sealability. A water electrolysis stack configured by laminating a plurality of water electrolysis cells to generate hydrogen by supplying water to the water electrolysis cell and applying electric power, wherein a laminated member for improving sealing property, which is a member that does not introduce water therein, is laminated at a predetermined position of the water electrolysis cell to be laminated.
Resumen de: WO2025171924A1
Method for producing a hydrogen product from ammonia, comprising the steps of: - Providing an ammonia feed stream; - Passing the ammonia feed stream to at least one ammonia pre-cracking reactor for producing a partly converted ammonia feed stream comprising ammonia, hydrogen and nitrogen by a pre-cracking reaction, said pre-cracking reactor comprising a pre-cracking catalyst bed comprising from 20 wt% to 60 wt% of nickel, preferably from 25 wt% to 50 wt% of nickel as a pre-cracking catalytically active material, - Passing the partly converted ammonia feed stream to an ammonia cracking reactor for producing an effluent gas stream comprising hydrogen and nitrogen and optionally also unconverted ammonia by a cracking reaction, said cracking reactor comprising a cracking catalyst bed comprising from 10 wt% to 20 wt% of nickel as a cracking catalytically active material.
Resumen de: US2025116022A1
A method of operating a solid oxide electrolysis cell (SOEC) system at partial load, the SOEC system including a plurality of branches each including at least one SOEC stack, includes determining a thermally neutral target voltage and cycling an ON phase and an OFF phase for each of the branches such that the SOEC system operates at an average operating power equal to a chosen percentage of the operating power at the thermally neutral target voltage. In the ON phase, the SOEC stacks in a given branch operate at the thermally neutral target voltage, and in the OFF phase, the SOEC stacks in the given branch are unloaded to an open circuit voltage and operate at 0% of rated power. The frequency of OFF phases for each branch is determined such that stronger or healthier branches have a lower frequency of OFF cycles than weaker or less healthy branches.
Resumen de: US2023243054A1
A separator for alkaline electrolysis comprising a porous support (10) and a first (20b) and second (30b) porous layer provided on respectively one side and the other side of the porous support, characterized in that the porous support has a thickness (d1) of 150 μm or less and the total thickness (d2) of the separator is less than 250 μm. Also a method is disclosed wherewith such a separator may be prepared.
Resumen de: MX2025001242A
The invention relates to a method for heating a furnace comprising radiant tubes and being able to thermally treat a running steel strip comprising the steps of: i. supplying at least one of said radiant tubes with H<sub>2</sub> and O<sub>2</sub> such that said H<sub>2</sub> and said O<sub>2</sub> get combined into heat and steam, ii. recovering said steam from said at least one of said radiant tubes, iii. electrolysing said steam so as to produce H<sub>2</sub> and O<sub>2</sub>, iv. supplying at least one of said radiant tubes with said H<sub>2</sub> and O<sub>2</sub> produced in step iii, such that they get combined into heat and steam.
Resumen de: CN119677896A
In one embodiment, discussed herein is a method of producing hydrogen, the method comprising: (a) providing an electrochemical reactor having an anode, a cathode, and a membrane between the anode and the cathode, where the membrane is both electronically and ionically conductive; (b) introducing a first stream to the anode, wherein the first stream comprises ammonia; (c) introducing an oxidizing agent to the anode; and (d) introducing a second stream to the cathode, wherein the second stream comprises water and provides a reducing environment to the cathode; wherein the hydrogen is generated from water in an electrochemical manner; wherein the first stream and the second stream are separated by the membrane; and wherein the oxidant and the second stream are separated by the membrane.
Resumen de: US2025250685A1
The water electrolysis system includes: a first cooling device that cools a gas containing a predetermined gas component generated by electrolysis of water to a first cooling temperature that is higher than or equal to a boiling point of the gas component so that the first impurity having a boiling point higher than the first cooling temperature can be separated; a gas-liquid separation device that separates the first impurity from the gas; and a second cooling device that cools the gas from which the first impurity is separated to a second cooling temperature that is lower than the boiling point of the gas component, and liquefies the gas component so that the second impurity having a boiling point lower than the second cooling temperature can be separated as a gas.
Resumen de: WO2024081205A1
A composition that produces hydrogen includes a nanoparticle or plurality of nanoparticles; an external source of electrons such as an electrogenic bacterium or a plurality of electrogenic bacteria and a carbon source; and an aqueous medium. The nanoparticles and the aqueous medium are combined in a mixture; upon exposure to electromagnetic radiation with a wavelength in the absorption profile of the nanoparticles, the nanoparticles generate an electron that can reduce a proton in the aqueous medium; and the source of electrons is capable of reducing the nanoparticles. The nanoparticles may comprise cadmium chalcogenide or water-soluble cadmium chalcogenide quantum dots. The electrogenic bacterium or bacteria may comprise Shewanella oneidensis, a Geobacter species or any bacterium capable of extracellular electron transfer. The electromagnetic radiation has a wavelength of between approximately 400 and 1100 nanometers, or preferably 530 nm. The aqueous medium may be wastewater and the carbon source may comprise lactate.
Resumen de: AU2023390125A1
Catalyst ink formulas for the preparation of CCMs are described. The catalyst ink formulas comprise a catalyst, an ionomer, a solvent, and a porogen soluble in the solvent. The catalyst ink formula may also comprise an additive, such as an electron conductive polymer. The anode catalyst coating layer or both the anode and the cathode catalyst coating layers prepared from the catalyst ink formula comprises uniformly distributed nanopores that allow easy gas removal and uniform water feed distribution, which will avoid or reduce the direct energy losses for the electrolyzers. Catalyst coated membranes and methods of making a catalyst coated membranes are also described.
Resumen de: AU2023359480A1
The invention relates to a bipolar plate for an electrolytic cell, the plate comprising, on at least one of its main faces: a first zone running circumferentially; a second zone running circumferentially so as to be bordered on the outside by the first zone; a third zone running circumferentially so as to be bordered on the outside by the second zone, the various zones being arranged on the periphery of the associated main face. The invention also relates to the corresponding cell, electrolyzer cell and assembly method.
Resumen de: AU2023359478A1
The invention relates to a method for joining a stack of elements together, the method comprising the steps of: individually joining subassemblies of the elements together; joining the subassemblies together by arranging a joint between each subassembly to form the stack of elements; applying consecutive phases of heating and cooling to the stack of elements while applying at least one clamping action to the stack of elements between two different phases of heating and cooling.
Resumen de: WO2024081426A2
The present disclosure relates to circuits for connecting components of a hydrogen plant to a power grid to power the components in an efficient manner. In one implementation, power-side alternate current (AC) to direct current (DC) converters may be connected to a source power grid without the need for an isolation transformer by providing separate buses between the power-side AC-DC converters and load-side DC-DC converters instead of a shared DC bus between the converters. Other implementations for connecting components of a hydrogen plant to a power grid may include an adjustable transformer, such as a tappable transformer or an autotransformer, to connect any number of auxiliary loads of the plant to the power grid. The adjustable transformer may provide for various types of auxiliary load devices to connect to the power provided by the transformer at the same time, including both three-phase devices and one-phase devices.
Resumen de: US2025236972A1
Electrolyzer for production of hydrogen gas and comprising a stack of bipolar electrodes sandwiching ion-transporting membranes between each two of the bipolar electrodes. Each bipolar electrode comprises two metal plates welded together back-to-back forming a coolant compartment in between and having a respective anode surface and an opposite cathode surface, each of which is abutting one of the membranes. The plates are embossed with a major vertical channel and minor channels in a herringbone pattern for transport of oxygen and hydrogen gases. The embossed herringbone pattern is provided on both sides of the metal plates so as to also provide coolant channels in a herringbone pattern inside the coolant compartment.
Resumen de: EP4603447A1
Method for producing a hydrogen product from ammonia, comprising the steps of:- Providing an ammonia feed stream;- Passing the ammonia feed stream to at least one ammonia pre-cracking reactor for producing a partly converted ammonia feed stream comprising ammonia, hydrogen and nitrogen by a pre-cracking reaction, said pre-cracking reactor comprising a pre-cracking catalyst bed comprising from 20 wt% to 60 wt% of nickel, preferably from 25 wt% to 50 wt% of nickel as a pre-cracking catalytically active material,- Passing the partly converted ammonia feed stream to an ammonia cracking reactor for producing an effluent gas stream comprising hydrogen and nitrogen and optionally also unconverted ammonia by a cracking reaction, said cracking reactor comprising a cracking catalyst bed comprising from 10 wt% to 20 wt% of nickel as a cracking catalytically active material.
Resumen de: EP4603183A1
According to the embodiments of the present disclosure, an ammonia decomposition catalyst may be prepared by performing heat treatment on alumina, a lanthanum compound and a cerium compound in a reducing gas atmosphere to form a composite oxide on an alumina support, and supporting an active metal including ruthenium on the composite oxide. According to further embodiments, the present disclosure provides a catalyst with improved dispersibility which is particularly suitable for ammonia decomposition.
Resumen de: EP4603181A1
The invention provides a novel and efficient catalyst for HER composed of Ru nanoparticles dispersed over a support consisting of titanium oxynitride and high surface area carbon material, such as graphene oxide, (TiON-C) with a particularly low Ru loading of only 6 wt.%. In an alkaline electrolyte, the Ru/TiON-C composite significantly surpasses the HER performance of the Ru/C analog. More importantly, Ru/TiON-C is both intrinsically (nearly 3 times higher turnover frequency) and practically (4 times higher mass activity) better performing HER catalyst than the commercial Pt/C benchmark.
Resumen de: CN120505661A
本发明涉及一种可平衡晶格氧消耗与填充的铈钨共掺杂钌氧化物催化剂及其制备方法和应用。本发明通过同时利用AEM‑OER催化剂的桥梁作用和CeOx对晶格氧空位填充的促进作用,在W‑RuO2稳定框架下激活LOM反应,从而平衡晶格氧的消耗与填充,能够实现RuO2在OER中的稳定性和高活性的双重优化,有效克服了单纯利用W掺杂来提高RuO2稳定性的技术以牺牲活性为代价、单纯利用Ce掺杂来激活RuO2晶格氧的以牺牲稳定性为代价的缺陷,实现了晶格氧消耗与补充的动态平衡,使得LOM机制的OER反应稳定运行,突破了传统活性和稳定性无法兼顾的技术瓶颈。
Resumen de: WO2024257430A1
The present invention reduces unburned ammonia when ammonia is used as fuel. A combustor (10) comprises: a burner (11) that injects fuel containing ammonia into a combustion space (S); and a refractory material (12) that defines at least a portion of the combustion space (S). The refractory material (12) blocks passage of combustion gas, and the refractory material (12) contains a catalyst (C), which decomposes ammonia into hydrogen and nitrogen, on a surface (1b) that defines at least a portion of the combustion space (S).
Resumen de: CN120502351A
本发明公开了一种光催化纳米复合材料及其制备方法与应用,属于纳米复合材料技术领域,先合成CuInS2量子点粉末,在CuInS2量子点粉末的表面覆上一层碳,再通过硅烷偶联剂改性引入氨基,然后将改性碳复合CuInS2量子点粉末负载到管状氮化碳粉末上形成的。管状氮化碳粉末的管状结构有利于CuInS2量子点分散在其表面或内部,使CuInS2量子点粉末的活性位点充分暴露,CuInS2量子点粉末的带隙能约为1.53eV,在受到光照射时,会产生电子和空穴对,可以促进光生电子和空穴的分离从而提高催化剂的活性,而碳层致密地包覆在CuInS2量子点粉末上能形成物理屏障,阻止过氧化物与硫离子直接接触。
Resumen de: US2025266534A1
A water electrolysis system includes: a water electrolysis device including a membrane electrode assembly formed by sandwiching an electrolyte membrane between an anode and a cathode, the water electrolysis device being configured to generate oxygen gas at the anode by supplying water to the cathode and electrolyzing the water; and a water supply device configured to supply, to the anode, water generated in association with power generation of a fuel cell stack.
Resumen de: US2025263846A1
To provide a water electrolysis stack capable of suppressing deterioration in sealability. A water electrolysis stack configured by laminating a plurality of water electrolysis cells to generate hydrogen by supplying water to the water electrolysis cell and applying electric power, wherein a laminated member for improving sealing property, which is a member that does not introduce water therein, is laminated at a predetermined position of the water electrolysis cell to be laminated.
Resumen de: CN120505632A
本申请涉及一种使用特斯拉阀流道的无隔膜电解槽,包括有电解槽本体,所述电解槽本体的侧壁开设有进液口,所述电解槽本体的内部相对于所述进液口的位置设置有中间层流道,所述电解槽本体的内部位于所述中间层流道的两侧分别设置有阴极室和阳极室,所述阴极室与所述中间层流道相对连通,所述阳极室与所述中间层流道相对连通,所述中间层流道为单向流道。本申请具有在不使用昂贵且易污染的离子交换膜的前提下,通过合理的电解液流道和电极的设计,利用电解液的流动分隔开阳极和阴极产出的气体,从而避免因阴阳极产气混合而爆炸的风险。
Resumen de: CN120511673A
本发明公开了风光模拟绿电制氢测试平台的控制系统,包括工业网电电源,工业网电电源连接有配电系统,配电系统分别连接有风光模拟电源系统、能源管理系统、模块化整流电源系统和制氢自动控制系统,能源管理系统连接储能系统,模块化整流电源系统连接电解槽组。本发明还公开了风光模拟绿电制氢测试平台的控制方法,包括以下步骤:通过工业网电电源给配电系统、风光模拟电源系统和能源管理系统依次上电,能源管理系统进行能量调度,能源管理系统和制氢自动控制系统给模块化整流电源系统发送电源控制命令,模块化整流电源系统比对控制命令中的给定参数,根据比对结果执行相应电源控制命令。本发明可以形成多种模型的电源输入。
Resumen de: CN120504436A
本发明涉及富氢水机技术领域,具体为一种便于更换物理式制氢机滤芯的设备,包括机体底板、腔体、滤芯安装筒、滤芯,所述腔体内部设有五组圆形滑道,后侧中心处具有螺杆,圆形滑道中设有内推板,内推板具有五组伸出臂,每组伸出臂端部都具有伸出圆板,内推板中心具有中心孔,内推板具有五组安装孔一,每组伸出圆板都具有安装孔二,伸出圆板安装在圆形滑道内,安装孔一内分别设有传动齿轮轴,中心孔内设有驱动齿轮轴,传动齿轮轴一端具有齿轮一,另一端具有链轮一,驱动齿轮轴一端具有齿轮二,另一端具有圆形卡板,驱动齿轮轴中心处具有螺纹孔一,螺纹孔一安装在螺杆上;本发明可进行更换滤芯,保证滤芯的顺利脱离与安装。
Resumen de: CN120505651A
本发明公开的碱性电解槽用流道密封双极板,通过设置相互交错的多通道氢碱、氧碱气道孔,氢碱、氧碱气道槽,碱液阴极、阳极进液孔和的碱液阴极、阳极进液槽,可为各电解小室提供多个交错分布碱液流通分配通道,使碱液快速充满各个电解小室,确保了各处碱液浓度的均匀一致性,电解小室内的气液两相流场分布更加均匀,上升的气泡能以最快的速度在最近的出口快速排出,降低了气体集聚,消除了电解小室气体死区,降低了碱液电阻电压降,从而降低了碱性电解槽的电解能耗,提高了电解效率;同时通过设置相应流道密封结构,杜绝了各电解小室中氢气、氧气的互串,从而提高了碱性电解槽的氢气、氧气纯度,保障碱性电解槽高安全性、长寿命稳定运行。
Resumen de: CN120505656A
本发明提供了一种电解水催化剂浆料及其制备方法与膜电极及电化学装置和电解水制氢方法。该制备方法包括:将催化剂、树脂、溶剂混合,得到中间溶液;将造孔剂加入所述中间溶液中搅拌,得到电解水催化剂浆料;造孔剂包括碳材料,搅拌的转速小于等于1000转/分钟,所述搅拌的时间小于等于30min。本发明还提供了上述制备方法得到的电解水催化剂浆料,由该电解水催化剂浆料制成的膜电极,包含该膜电极的电化学装置和电解水制氢的方法。上述电解水催化剂浆料可以通过添加造孔剂获得多孔催化层、同时避免造孔剂去除过程引起的催化剂流失,提高膜电极的催化性能和耐久性。
Resumen de: CN120505653A
本发明公开了利用废金属屑制备铁基电化学催化剂的方法及电化学催化剂,具体过程为:将废金属屑进行酸浸,得到浸出液;用树脂吸附浸出液中的金属离子,得到饱和树脂;用硝酸对饱和树脂进行解吸,得到无杂溶液;在无杂溶液中加入过量的还原剂进行还原,得到固液混合物;将固液混合物进行离心分离,得到沉淀,将沉淀清洗干净、烘干,得到铁基催化剂粉末;将预处理后的泡沫镍在无杂溶液中电镀,得到催化剂基底;将铁基催化剂粉末涂覆至催化剂基底上,真空烘干,得到铁基电化学催化剂。本发明制备方法利用废金属屑作为原料,大大降低了制备成本,同时对废金属屑进行了回收利用且本发明制备得到的电催化剂在析氧反应中表现出优异的催化效果。
Resumen de: CN120505669A
本发明公开的一对多碱性电解水制氢监测系统,包括若干个碱液循环泵,每个碱液循环泵均管线连接有碱性电解槽,每个碱性电解槽的阴极端共同连接有氢中氧分析组件,每个碱性电解槽的阳极端共同连接有氧中氢分析组件,每个碱性电解槽和氧中氢分析组件之间均管线连接有监测组件,每个监测组件均与氧中氢分析组件连接,每个碱液循环泵共同连接有碱液冷却器,碱液冷却器分别和氢中氧分析组件、氧中氢分析组件连接,每个监测组件均数据连接有控制器。本发明还公开了一对多碱性电解水制氢监测方法。本发明的一对多碱性电解水制氢监测系统及监测方法,解决了无法对每台电解槽的氧中氢含量进行监测的问题。
Resumen de: CN120505642A
本发明公开的用于撬装碱性水电解制氢系统的辅助设备,包括箱体,箱体内设置有用于供电的配电柜间,配电柜间通过线路与设置在箱体内的水处理设备间、空压机设备间和输出设备间分别连接;箱体相对配电柜间位置设有连接外部电源的电源输入口;箱体相对水处理设备间位置设有水源输入口;箱体相对空压机设备间位置设有空气输入口;箱体相对输出设备间位置设有仪表气输出口、原料水输出口、碱液输出口和吹扫气输出口。本发明将纯水制备系统、配碱系统、压缩空气系统、氮气系统进行集成,提高了空间利用率,降低了辅助设备的占用空间。
Resumen de: CN120508033A
本发明公开了千方级碱性水电解制氢系统远程运维平台和运维方法,包括设备层、云平台、平台层和应用层,设备层包括千方级制氢设备,千方级制氢设备中安装有监测设备运行的传感器,以及控制设备运行的PLC控制器,云平台设置有公有云或私有云,平台层设置有私有云服务器或本地服务器,应用层设置有本地显示终端和移动显示终端,云平台和平台层都部署有Web组态软件,设备层、云平台和平台层通过无线物联网络连通,云平台与本地显示终端、移动显示终端也分别通过无线物联网络连通,平台层与本地显示终端通过有线专用网络连通,PLC控制器采集传感器传递的数据信号,传递至云平台和平台层,平台层镜像还原千方级制氢电解水制氢系统的现场。
Resumen de: CN120505640A
本发明公开的具有三角形沟槽流道结构的质子交换膜电解槽,包括自上而下依次设置的阳极极板、阳极气体扩散层、膜电极、阴极气体扩散层与阴极极板,阳极极板与阳极气体扩散层之间设有阳极液体流道,阴极极板与阴极气体扩散层之间设有阴极液体流道。本发明的三角形沟槽流道结构的质子交换膜电解槽,促使反应水沿着竖直方向进入气体扩散层,提高到达催化层发生反应的液态水含量,同时减少气体扩散层中氧气的积累,提高了电解槽的产氢效率。
Resumen de: CN120505647A
本发明属于电解水制氢领域,涉及一种梯度孔结构电极及其制备方法与应用,该制备方法包括如下步骤:1)在电极基底表面依次涂敷不同粒径的聚苯乙烯,然后低温烧结将聚苯乙烯固定在电极基底表面,得到固定有聚苯乙烯分子模板的电极基底;2)采用化学镀法在固定有聚苯乙烯分子模板的电极基底表面上电镀金属镀层,得到含有金属镀层的固定有聚苯乙烯分子模板的电极基底;3)对步骤2)得到的含有金属镀层的固定有聚苯乙烯分子模板的电极基底进行去模板和去金属基底处理,得到梯度孔结构电极。本发明通过梯度孔构建了高效三相反应界面,降低气泡屏蔽效应,降低了过电位和电解水能耗,提高了电解水制氢效率。
Resumen de: CN120502800A
本发明属于电解槽设备技术领域,公开了碱性制氢电解槽的紧固方法,组装完电解槽的零部件结构后,通过液压拉伸器以间隔的方式对拉紧螺栓的顶部进行拉伸预紧,以防止电解槽的各部件窜动;预紧完成后再对电解槽进行多次冷紧和热紧,完成对电解槽的紧固。预紧、冷紧和热紧过程中,液压拉伸器的泵站按照3~8MPa/次的差值进行升压,对拉紧螺栓进行拉伸紧固,将电解槽的零部件压紧,尽可能将缝隙消除,并挤压密封垫圈使其产生形变,提升电解槽的密封效果。本发明的技术方案,增强了对大型碱性制氢电解槽的紧固效果,使电解槽的长期使用状态更加稳定。
Resumen de: CN120505660A
本发明公开了一种固体氧化物电解池片阳极材料及其制备方法和应用,所述固体氧化物电解池片阳极材料包括LSCF颗粒以及在LSCF颗粒表面沉积生长的LNO颗粒,简称为LSCF‑LNO材料;LSCF的化学式为La0.6Sr0.4Co0.2Fe0.8O3,LNO的化学式为La2NiO4,所述LSCF‑LNO材料上LNO的质量是LSCF质量的10%‑50%。本发明充分利用LSCF的优良电子导电率以及LNO的优良氧离子传输性能,并通过两步合成法在以LSCF为主体在其表面形成LNO颗粒增强材料氧表面交换传输能力并增大反应三相界面和氧离子传输通道,以提高高温固体氧化物电解池电化学性能。
Resumen de: CN120505643A
本发明涉及氢能制备技术领域,具体是涉及一种基于光伏发电的集装箱电解水制氢系统,包括有电解结构、正极板和负极板,所述电解结构夹设于所述正极板和所述负极板之间;所述制氢系统还包括用以夹紧所述电解结构的夹紧机构,所述夹紧机构包括有固定设置的正极压板及可沿正极压板轴向移动的负极压板;所述夹紧机构还包括有缩进控制单元,用于在电解结构产生泄漏时缩小正极压板和负极压板之间间距恢复电解结构的密封性。本发明通过压力传感器实时监测电解结构的夹紧力,当发生泄漏导致夹紧力下降时,能够自动触发缩进控制单元,实现极板间距的调整,恢复电解结构的密封性,无需人工干预,大大提高了制氢系统的可靠性和响应速度。
Resumen de: CN120505665A
本发明属于电解水制氢技术领域,公开了碱性水电解槽用PPS复合纤维隔膜及其制备方法,该方法包括采用PPS树脂通过熔喷工艺制备PPS非织造布;将PPS非织造布置于硝酸溶液中进行硝化处理;对硝化后的PPS非织造布进行热压处理得到PPS纤维膜;将PPS纤维膜置于硝酸锌‑二甲基咪唑‑甲醇混合溶液中进行原位生长,得到PPS复合纤维隔膜。本发明采用的硝化、热压和原位自生相结合的方式,不仅在疏水的PPS纤维膜上引入亲水基团提升了其亲水性,还通过纤维间的热交联提高了PPS纤维膜的拉伸强度,同时利用原位自生的具有三维网状结构的ZIF‑8提高了PPS纤维膜的隔气性,本发明制备工艺简单、操作简便,能够满足工业碱性水电解制氢的需求。
Resumen de: CN120505667A
本发明公开的电解水制氢纯化系统及方法,包括通过氢气管路连接的气水分离器、氢气冷却器、集水器和水封,气水分离器与脱氧器相连,每个氢气冷却器上均连接有一个干燥器;脱氧器、干燥器下部分别接有温度变送器;脱氧器、干燥器内的加热部件上接有温度传感器,通过控制内加热部件温度调节加热器功率,在氢气再生管路和成品氢气管路前装有薄膜调节阀,可根据主氢气流量和系统压力调节再生氢气和系统氢气流量,节省人力的同时也能提高系统运行效率在脱氧器和干燥器接口处分别设置一路安全阀放空管线;当系统出现异常情况时,可通过安全阀管线快速排出容器中的氢气,保证整个纯化系统的安全可靠运行。
Resumen de: CN120505638A
本申请涉及一种海水供水碱性电解水制氢装置,涉及电解制氢的领域,包括有膜电极组件,所述膜电极组件的两侧设置有气体收集腔室,所述气体收集腔室背离所述膜电极组件的一侧设置有进液组件,所述进液组件与所述气体收集腔室之间设置有气化部件,所述气化部件能够将通过其的液体气化进入到所述膜电极组件的内部。本申请具有减少电极的腐蚀,钙镁离子堵塞电极的情况的效果。
Resumen de: CN120505650A
本发明公开了多级环形质子交换膜电解槽双极板流场结构,包括板体,板体的中心位置同心设置有多级环形流道,多级环形流道是以双极板中心点为圆心,相邻环形流道之间均采用通道脊分隔;沿直径方向设置有中央通道,中央通道贯穿所有环形流道并且与每一个环形流道互通,中央通道以一级环形流道圆心沿直径方向呈轴对称分布;中央通道的一端为进水口,中央通道的另一端为出水口;板体的四周边沿间隔开有若干螺栓孔,板体一侧面设有电源接口。本发明属于质子交换膜电解水制氢技术领域,避免在转弯处发生速度和电流密度的突变,能够显著降低流场中的压力分布,减少蠕动本送水做功,提高电解槽性能。
Resumen de: CN120505635A
本发明申请公开了一种PEM电解槽,涉及电解槽技术领域,PEM电解槽,包括端板组件、极板组件和膜电极,其中极板组件、膜电极上设有与端板组件的分流通道分别连通的阳极侧进出水通道、阴极侧进出水通道。本申请的PEM电解槽所包含的部件少,结构简单,加工成本较低,可以保证具备良好的密封性,同时其可以从两侧的端板分别进水,则进水量更大,具备良好的散热性能,能够均匀分配反应物、生产物,提高了电解效率。
Resumen de: CN120504346A
本发明提供了一种溴掺杂的二维镍铁氧化物的制备方法及其应用,属于纳米材料制备技术领域。本发明通过将琥珀酸,乙二醇与金属盐,溴盐在混合溶液中反应,结合焦耳热快速升降温技术,形成了溴离子掺杂的二维多孔结构,该方法合成工艺简单,制备的催化剂在碱性海水电解中实现了较低的过电位优异的稳定性,显著提升了OER反应效率,为海水制氢技术提供了高效、耐用的电化学催化剂。
Resumen de: CN120505670A
本发明公开了一种用于碱水电解制氢的高效低耗长寿命碱液循环系统,包括阴极侧和阳极侧,对于阳极侧,碱水电解制氢装置连接催化转化模块,催化转化模块连接至气液分离模块,气液分离模块液体依次通过碱液循环模块、碱液循环换热器和碱液过滤器连接至电解槽;对于阴极侧,碱水电解制氢装置连接气液分离模块,所述气液分离模块液体的液体输出端依次通过碱液循环模块、碱液循环换热器和碱液过滤器连接至电解槽;阳极侧和阴极侧分别设置相应的碱液控制模块。本发明提高了碱性电解水系统宽负荷波动范围下的适应性,消除了氧自由基对系统设备的腐蚀以及降低了碱液循环泵的功耗,提升了碱水电解制氢系统的经济性。
Resumen de: CN120502331A
本发明公开了一种Ni/Al1.8Ce0.2Ox催化剂及其制备方法和在热催化氨分解制氢中的应用,将可溶性Ni盐、Al盐、Ce盐均匀分散在水中得混合液,再加入络合剂,通过溶胶凝胶法得到络合物前体,然后热解得到氧化物前体,再然后氧化物前体超声分散于水中,加入碱液进行刻蚀,得到刻蚀氧化物前体,最后刻蚀氧化物前体于H2/Ar气氛下焙烧,得到Ni/Al1.8Ce0.2Ox催化剂,用于热催化氨分解制氢。本发明的催化剂具有结构稳定、金属Ni高度分散的特点,通过碱刻蚀处理后,有效抑制了载体对金属Ni的包覆作用,溶出的金属Ni呈金字塔状形貌,具有更多不饱和配位的活性位点,催化剂的催化活性与稳定性显著提高。
Resumen de: JP2024102507A
To provide a water electrolysis stack capable of improving durability.SOLUTION: A water electrolysis stack has a cell laminate in which a plurality of water electrolysis cells are laminated. In the cell laminate, inter-cell regions are formed in adjacent water electrolysis cells, and gas flows in the inter-cell regions during water electrolysis.SELECTED DRAWING: Figure 6
Resumen de: CN120505657A
本发明公开了一种钨/氮化钒异质结电催化材料及其制备方法,将氯化钒、氯化钨和草酸溶解在乙醇中,其中氯化钒和氯化钨的摩尔比为(0.5‑3):(1‑3),得到混合液;将混合液的pH值调至1‑4后进行水热处理,得到反应液,将反应液中的产物洗涤后干燥,得到粉体;按(200‑600)mg:(0.5‑1.2)mol的比例,将粉体和碳源在氩气气氛下煅烧处理,得到钨/氮化钒异质结电催化材料,简单易行,原料成本低,绿色无污染,在碱性环境中电催化析氢活性高,稳定性强。
Resumen de: US2024044285A1
The present invention relates, in general, to systems and methods for generating hydrogen from ammonia on-board vehicles, where the produced hydrogen is used as fuel source for an internal combustion engine. The present invention utilizes an electric catalyst unit operating in series with a plate-type heat exchange catalyst unit. The electric catalyst unit is used to initiate an ammonia cracking process on-board during a cold start or low load operating condition of the internal combustion engine, where the ammonia cracking process occurs in the heat exchange catalyst unit once exhaust gas from the internal combustion engine has been heated to a threshold temperature suitable to perform the ammonia cracking process.
Resumen de: US2025250688A1
An electrolysis system includes: an electrolysis cell configured to generate hydrogen by high-temperature steam electrolysis; a steam generation unit that has a refrigerant heat exchange unit configured to perform heat exchange between heat of a heat storage unit and a refrigerant, generates a steam by heating raw material water via the refrigerant subjected to the heat exchange in the refrigerant heat exchange unit, and supplies the steam to the electrolysis cell; a heat storage supply unit that has the heat storage unit and configured to supply heat of the heat storage unit to the refrigerant heat exchange unit; and a control unit configured to control the heat storage supply unit such that an amount of heat input to the refrigerant heat exchange unit is smaller during a system startup or during a high-temperature standby than during a normal operation.
Resumen de: CN120505666A
本发明公开了一种用于碱性电解水制氢的PPS隔膜改性制备方法,包括:预处理、多巴胺亲水处理等步骤。通过上述方式,本发明一种用于碱性电解水制氢的PPS隔膜改性制备方法,有效提升了PPS隔膜的亲水性,并且优化隔膜孔径分布,更加高效的发挥气体阻隔与离子传导作用,且本方法操作流程简单、成本较低,有利于推动PPS隔膜在高性能碱性电解水制氢系统中的广泛应用。
Resumen de: CN120202324A
The invention relates to a stack module having at least one solid oxide electrolysis stack comprising a plurality of stacked solid oxide electrolysis cells, in which the stack module comprises two gas inlet connections and two gas outlet connections. According to the invention, at least one solid oxide electrolysis stack is encapsulated in a metal container, with two gas inlet connections and two gas outlet connections connected to the metal container. The invention further relates to a solid oxide electrolyzer having at least one stacked module and to a method for replacing a stacked module of a solid oxide electrolyzer.
Resumen de: US2025257489A1
A water electrolysis system includes: a water electrolysis stack that generates oxygen gas and hydrogen gas by electrolyzing water; a gas-liquid separator that separates the hydrogen gas from water; a hydrogen compression stack that compresses the hydrogen gas; a gas tank that stores an inert gas and is connected to a hydrogen flow path that connects the water electrolysis stack and the hydrogen compression stack; a supply valve that, when opened, supplies the inert gas to the hydrogen flow path; and a supply control unit that opens the supply valve in a case where the concentration of the oxygen gas that has flowed into the hydrogen flow path exceeds an oxygen concentration threshold determined in advance.
Resumen de: US2025257482A1
Some embodiments relates generally to the production of a desalinated, filtrated or other way treated water simultaneously with generation of renewal energy source, in particular hydrogen, using osmotic and/or gauge pressure driven filtration processes and systems. The co-generation of hydrogen 11 from water 8 produced during pressure driven water desalination/filtration processes, such as reverse osmosis, forward osmosis, pressure retarded osmosis or ultrafiltration. A small part of feed, raw saline solution and/or permeate involved in a desalination/filtration processes is subjected to electrolysis thereby splitting the water to produce hydrogen. This is achieved by the provision of novel RO type semi-permeable membranes and UF type membrane that incorporate electrodes 9, 10 within the membrane to allow splitting of the water via electrolysis.
Resumen de: US2025256975A1
Embodiments of the disclosure pertain to the conditioning of the purge gas stream in an NH3 synthesis plant comprising a water electrolysis unit to produce a H2 stream, ammonia synthesis loop, and a treatment section for treating purge gas at 10-70 bar(a) using scrubbing and membrane separation.
Resumen de: WO2025168743A1
The present disclosure provides an improved ammonia-producing plant and process for the simultaneous production of hydrogen and ammonia as end products, by integrating a hydrogen separation unit into an ammonia-producing plant. More in particular, the present disclosure provides an ammonia production plant comprising (a) a reforming section, (b) a purification section, downstream of the reforming section, and (c) an ammonia synthesis section, downstream of the purification section, wherein the plant further comprises (d) a hydrogen separation unit, wherein the hydrogen separation unit has an inlet for a hydrogen-containing gas stream, a first outlet for a pure hydrogen gas, particularly for providing the pure hydrogen to a hydrogen network, and a second outlet for a tail gas, particularly wherein the inlet of the hydrogen separation unit is in fluid communication with a hydrogen-containing gas stream in the purification section and/or in the ammonia synthesis section, and/or with a hydrogen-containing gas stream between the purification section and the ammonia synthesis section of the ammonia production plant, and, particularly, wherein the second outlet is in fluid communication with the reforming section and/or with the purification section of the ammonia production plant.
Resumen de: WO2025169081A1
PRODUCTION OF HYDROGEN USING METHANOL The present disclosure relates generally to processes for producing hydrogen. In particular, the disclosure relates to a process comprising: providing a first feed stream comprising H2 and CO2; contacting the first feed stream with a hydrogenation catalyst (e.g., in a hydrogenation reaction zone) to hydrogenate at least a portion of the CO2 to form a first product stream comprising methanol; storing at least a portion of the methanol of the first product stream; providing a second feed stream comprising at least a portion of the stored methanol; in a methanol dehydrogenation reaction zone, dehydrogenating at least a portion of the methanol of the second feed stream to form a second product stream comprising H2 and CO2; providing a third feed stream comprising at least a portion of H2 of the second product stream; in a hydrogen reaction zone, reacting hydrogen of the third feed stream with one or more co-reactants to provide a third product stream comprising one or more products including reacted hydrogen atoms from hydrogen of the third feed stream.
Resumen de: US2025257022A1
The present invention relates to a process for producing methanol (MeOH) and hydrogen (H2) from methane, comprising the steps: a) providing a gaseous feed stream comprising methane; b) reacting said gaseous feed stream with at least one halogen reactant (X2), under reaction conditions effective to produce an effluent stream comprising methyl halide (MeX), hydrogen halide (HX); c) separating from the effluent stream obtained in step b): (i) a methyl halide (MeX) stream, optionally comprising unreacted methane; and, (ii) a hydrogen halide (HX) stream; d) reacting the methyl halide (MeX) stream separated in step c) with a solid metal hydroxide (MOH(s)) under reaction conditions effective to produce metal halide (MX) and methanol (MeOH); and, e) decomposing by means of electrolysis said hydrogen halide (HX) stream separated in step c) under conditions effective to produce a gaseous hydrogen (H2) stream and a stream comprising halogen reactant (X2).
Resumen de: US2025257489A1
A water electrolysis system includes: a water electrolysis stack that generates oxygen gas and hydrogen gas by electrolyzing water; a gas-liquid separator that separates the hydrogen gas from water; a hydrogen compression stack that compresses the hydrogen gas; a gas tank that stores an inert gas and is connected to a hydrogen flow path that connects the water electrolysis stack and the hydrogen compression stack; a supply valve that, when opened, supplies the inert gas to the hydrogen flow path; and a supply control unit that opens the supply valve in a case where the concentration of the oxygen gas that has flowed into the hydrogen flow path exceeds an oxygen concentration threshold determined in advance.
Resumen de: US2025257487A1
A method of producing hydrogen and/or bromine by electrolysing hydrogen bromide using a fluoropolymer membrane having a glass transition temperature Tg≥110° C. in an electrolysis of hydrogen bromide, wherein the hydrogen bromide stems from a bromination of a hydrocarbon.
Resumen de: US2025257488A1
An electrolysis system includes at least one electrolyzer for generating hydrogen and oxygen as products, and at least two downstream compressors for compressing at least one of the products produced in the electrolyzer. A method of operating the electrolysis system in a part-load operation of the electrolyzer that is optimized in terms of efficiency and is also cost-effective. During the part load operation of the electrolyzer, a first group of compressors is operated in part-load operation, while the compressor(s) of a second group can be switched on or off individually for full-load operation.
Resumen de: US2025257484A1
An electrode suitable for carrying out oxygen evolution reaction in the electrolysis of water in alkaline conditions. The electrode includes a ceramic material having a stability factor (SF) between 1.67≤SF≤2.8 and which is calculated by formula (II), where rO is the ionic radius of oxide ion (O2−), rB,av is the weighted average ionic radius of a transition metal, nA,Av is the weighted average oxidation state of a rare earth or alkaline earth metal, rA,av is the weighted average ionic radius of a rare earth or alkaline earth metal. An alkaline electrolysis stack includes the electrode, as well as a method for the electrolysis of water in alkaline conditions using the alkaline electrolysis stack.
Resumen de: US2025257483A1
Clean version of Abstract A catalyst and anode for hydrogen production by electrolysis as well as a preparation method, activation method and use thereof are provided. The anode for hydrogen production by electrolysis includes a catalyst which is nickel iron barium hydrotalcite with a nano hexagonal sheet structure and a thickness of 100-200 nm. The catalyst can be prepared by a one-step solvothermal reaction method. Alkaline-earth metal ions are evenly doped in the nickel iron barium hydrotalcite and are in atomic level dispersion, so that the anode for hydrogen production by electrolysis based on the catalyst, when being applied to a process for hydrogen production by electrolysis of an aqueous solution containing chlorine ions, not only can maintain good catalytic performance, but also has greatly improved chlorine ion corrosion resistance, leading to significant improvement of working stability and service life.
Resumen de: US2025257477A1
A method of electrolysing hydrogen bromide comprising the steps i) synthesizing sulfuric acid such that hydrogen bromide is produced, ii) providing an electrolytic cell comprising an anode, a cathode, and a membrane sandwiched between the anode and the cathode, iii) feeding a first composition comprising hydrogen bromide and water to the anode, iv) feeding a second composition comprising hydrogen bromide and water to the cathode, and v) operating the electrolytic cell to produce hydrogen at the cathode.
Resumen de: US2025257476A1
A method can include coupling sulfur dioxide depolarized electrolysis (e.g., electrochemical oxidation of sulfur dioxide to sulfuric acid with electrochemical reduction of water to hydrogen) with the contact process to facilitate formation of high concentration sulfuric acid with concurrent hydrogen production. The sulfuric acid and hydrogen can optionally be used cooperatively for downstream processes (e.g., metal extraction from ore, fertilizer production, hydrocarbon processing, etc.).
Resumen de: US2025257475A1
The invention relates to a method for operating an electrolysis plant which has an electrolyzer for generating hydrogen and oxygen as product gases, wherein water is fed as educt water to the electrolyzer and split into hydrogen and oxygen at an ion-exchange membrane. Prior to splitting, the educt water is brought into a thermodynamic state close to the boiling point of the water in terms of the pressure and temperature and is fed in this state to the membrane. Educt water is brought to a boil at the membrane and converted into the gas phase, wherein the water in the gas phase is split at the membrane. There is also described an electrolysis plant having an electrolyzer for generating hydrogen and oxygen as product gases.
Resumen de: US2025259714A1
A determination method determines whether or not target molecules including elemental hydrogen are electrolytic hydrogen-containing molecules which include: hydrogen molecules produced by water electrolysis; or molecules produced using the hydrogen molecules as a raw material. In the determination method, the method includes determining that the target molecules are the electrolytic hydrogen-containing molecules when an abundance ratio of deuterium to light hydrogen in the target molecules is less than or equal to a predetermined threshold which is smaller than an abundance ratio of deuterium to light hydrogen in nature.
Resumen de: WO2024126749A1
There is provided a multi-layered proton exchange membrane for water electrolysis, comprising: at least two recombination catalyst layers, each of the at least two recombination catalyst layers comprising a recombination catalyst and a first ion exchange material, wherein at least two recombination catalyst layers are separated by a region devoid of or substantially devoid of a recombination catalyst, and at least two reinforcing layers, each of the at least two reinforcing layers comprising a microporous polymer structure and a second ion exchange material which is at least partially imbibed within the microporous polymer structure.
Resumen de: KR20250122697A
본 발명에 의한 수소발생 촉매 전극용 백금-탄소나노튜브 복합체는 탄소나노튜브 표면에 백금이 도입되며, 백금 함량이 20 중량% 이하인 것을 특징으로 한다.
Resumen de: US2025250686A1
A water electrolysis device includes a water electrolysis module that generates hydrogen by water vapor electrolysis. The water electrolysis device includes: a blower configured to supply hydrogen to the water electrolysis module; a recycle passage configured to supply generated hydrogen generated by the water electrolysis module from the water electrolysis module to an intake port of the blower; a condenser configured to condense water vapor contained in the generated hydrogen; and a temperature increasing portion configured to increase a temperature of the generated hydrogen between the condenser and the blower.
Resumen de: WO2025169719A1
This water electrolysis system comprises: a water electrolysis cell stack; a water separator that is connected to the water electrolysis cell stack and separates water discharged from the water electrolysis cell stack from gas; a water circulation path that is provided with a water circulation pump and circulates the water separated by the water separator; a water supply path that is separate from the water circulation path, is provided with a water supply pump, and supplies the water to the water electrolysis cell stack; an ion exchange resin provided in the water circulation path; and a heat exchanger that is provided on the upstream side of the ion exchange resin in the water circulation path, and that cools the water in the water circulation path on the basis of the temperature of the water supplied from the water supply path to the water electrolysis cell stack.
Resumen de: WO2025168858A1
The present invention relates to a high-efficiency hydrogen electrolyser consisting of a single casing containing four inner cavities having identical cubic capacity which are intercommunicated at the top to share a common gas outlet and which may also be intercommunicated at mid-height to share filler material. At the bottom of each cavity there is a solid bar longitudinally arranged such that the upper bar serves as a cathode and the lower bar serves as an anode, resulting in the optimisation of the electrolysis system by adding acidified water and providing DC power supply.
Resumen de: WO2025166879A1
The present invention belongs to the technical field of OER electrocatalysts. Provided are a method for constructing a nitrogen-doped bimetallic nanofiber membrane electrocatalyst on the basis of an electrostatic spinning method and the use of the nitrogen-doped bimetallic nanofiber membrane electrocatalyst. The electrocatalyst is prepared from a mixed high-molecular polymer of a metal salt, N,N-dimethylformamide and polyacrylonitrile by means of the coordinated and confined pyrolysis transformation of a one-dimensional porous carbon nanomaterial. The method comprises: S1, preparing a FeCo-NCNF precursor solution; S2, transferring the resulting FeCo-NCNF precursor solution into a plastic injector with a stainless steel needle to perform electrostatic spinning, so as to obtain a nanofiber membrane; and S3, subjecting the obtained nanofiber membrane to high-temperature carbonization and phosphorization in sequence, so as to obtain a nitrogen-doped bimetallic nanofiber membrane electrocatalyst. In the present invention, the nitrogen-doped bimetallic nanofiber membrane electrocatalyst prepared by using the method has the advantages of a large specific surface area, a porous structure, a high nitrogen content, a great number of active sites, etc., and therefore the catalytic performance of the electrocatalyst is improved.
Resumen de: US2025257415A1
A hydrogen-rich blast furnace ironmaking system based on mass-energy conversion, comprising a water electrolysis system (2). The water electrolysis system (2) is separately connected to a hydrogen storage tank (3) and an oxygen storage tank (4); a gas outlet of the hydrogen storage tank (3) is connected to a hydrogen compressor (5); an outlet of the hydrogen compressor (5) is connected to a hydrogen buffer tank (6); the hydrogen buffer tank (6) is connected to a hydrogen injection valve group (7); the hydrogen injection valve group (7) is connected to a hydrogen preheating system (8); and the hydrogen preheating system (8) is connected to a tuyere of a blast furnace body (1) or a hydrogen injector at the lower portion of the furnace body.
Resumen de: US2025257374A1
The invention described herein presents compositions and methods for a multistep biological and chemical process for the capture and conversion of carbon dioxide and/or other forms of inorganic carbon into organic chemicals including biofuels or other useful industrial, chemical, pharmaceutical, or biomass products. One or more process steps utilizes chemoautotrophic microorganisms to fix inorganic carbon into organic compounds through chemosynthesis. An additional feature described are process steps whereby electron donors used for the chemosynthetic fixation of carbon are generated by chemical or electrochemical means, or are produced from inorganic or waste sources. An additional feature described are process steps for recovery of useful chemicals produced by the carbon dioxide capture and conversion process, both from chemosynthetic reaction steps, as well as from non-biological reaction steps.
Resumen de: AU2024301470A1
The present invention relates to an electrolysis system (100) comprising a renewable power generation plant (1), an electrolysis plant (3), a transformer station (27) and an AC bus bar (5), wherein the renewable power generation plant (1) is connected to the public electricity grid at a point of connection (POC) via the AC bus bar (5) and comprises a power plant controller (7) and a self-controlled converter (9) that is connected to the AC bus bar (5). The electrolysis plant (3) comprises an electrolysis active power controller (11) and a converter arrangement (13) that is connected to the AC bus bar (5), and wherein the electrolysis active power controller (11) is configured for controlling active power (P) of the electrolysis plant (3) at the AC bus bar (5) and the power plant controller (7) is configured for controlling reactive power (Q) at the point of connection (POC).
Resumen de: WO2024129246A1
Herein discussed is a method of producing hydrogen comprising: (a) providing an electrochemical reactor having an anode, a cathode, and a membrane between the anode and the cathode, wherein the membrane conducts both electrons and protons, wherein the anode and cathode are porous; (b) introducing a first stream to the anode, wherein the first stream comprises ammonia or a cracked ammonia product; and (c) extracting a second stream from the cathode, wherein the second stream comprises hydrogen, wherein the first stream and the second stream are separated by the membrane.
Resumen de: WO2024112460A1
Herein discussed is a method of co-producing carbon monoxide and hydrogen comprising: (a) providing an electrochemical reactor having an anode, a cathode, and a mixed-conducting membrane between the anode and the cathode; (b) introducing a first stream to the anode, wherein the first stream comprises a fuel; (c) introducing a second stream to the cathode, wherein the second stream comprises carbon dioxide and water, wherein carbon monoxide is generated from carbon dioxide electrochemically and hydrogen is generated from water electrochemically. In an embodiment, the anode and the cathode are separated by the membrane and are both exposed to reducing environments during the entire time of operation.
Resumen de: EP4600283A1
The subject disclosure relates to a crosslinked copolymer that has outstanding ion exchange capacity, exhibits high ion conductivity and water content under diverse temperature conditions, and features high density, low hydrogen permeability, and excellent thermal and oxidative stability, making it well-suited as an anion exchange membrane for water electrolysis to produce high-purity hydrogen and oxygen
Resumen de: AU2023397261A1
The invention relates to an electrolysis system (1) with a pressure electrolyzer (3) for generating hydrogen (H
Resumen de: EP4600408A1
An anode for electrolysis in which electrolysis performance is less likely to deteriorate even when electric power having a large output fluctuation, such as renewable energy, is used as a power source and in which excellent catalytic activity is stably maintained for a long period of time is provided. The anode for electrolysis 10 includes a conductive substrate 2 in which at least a surface of the conductive substrate 2 is formed of nickel or a nickel-based alloy; and a first layer 4 formed on the surface of the conductive substrate 2, the first layer 4 being capable of functioning as a catalyst layer containing a lithium-containing nickel cobalt oxide represented by a composition formula LixNiyCo2O4 (0.05 ≤ × ≤ 1.0, 1.0 ≤ y ≤ 2.0, 1.0 ≤ z ≤ 2.0, and x + y + z = 2 to 3).
Resumen de: US2025250695A1
A platform technology that uses a novel membrane electrode assembly, including a cathode layer, an anode layer, a membrane layer arranged between the cathode layer and the anode layer, the membrane conductively connecting the cathode layer and the anode layer, in a COx reduction reactor has been developed. The reactor can be used to synthesize a broad range of carbon-based compounds from carbon dioxide and other gases containing carbon.
Resumen de: WO2024076575A1
A method can include: processing precursors, electrochemically oxidizing sulfur dioxide, processing sulfuric acid and hydrogen, and/or any suitable steps. An electrolyzer can include an anode, a cathode, and a separator. The anode can include an anolyte, an electrode, an anolyte reaction region, and/or any suitable components. The cathode can include a catholyte, an electrode, a catholyte reaction region, and/or any suitable components.
Resumen de: EP4600236A1
A hydrocarbon generation system (1) includes a hydrocarbon generator (2, 21, 22), an electrolyzer (3), a water vapor supply line (4), and a heat exchanger (51). The hydrocarbon generator generates hydrocarbon through an exothermic reaction between a carbon oxide gas and hydrogen. The electrolyzer generates hydrogen from water vapor of raw materials, the generated hydrogen being supplied to the hydrocarbon generator. The water vapor supply line generates the water vapor of the raw materials by evaporating liquid water of the raw materials and supplies the generated water vapor to the electrolyzer. The heat exchanger uses heat of a reaction generated in the hydrocarbon generator to evaporate the liquid water of the raw materials in the water vapor supply line via heat transfer oil.
Resumen de: EP4600203A1
The present disclosure provides an improved ammonia-producing plant and process for the simultaneous production of hydrogen and ammonia as end products, by integrating a hydrogen separation unit into an ammonia-producing plant. More in particular, the present disclosure provides an ammonia production plant comprising (a) a reforming section, (b) a purification section, downstream of the reforming section, and (c) an ammonia synthesis section, downstream of the purification section, wherein the plant further comprises (d) a hydrogen separation unit, wherein the hydrogen separation unit has an inlet for a hydrogen-containing gas stream, a first outlet for a pure hydrogen gas and a second outlet for a tail gas, particularly wherein the inlet of the hydrogen separation unit is in fluid communication with a hydrogen-containing gas stream in the purification section and/or in the ammonia synthesis section, and/or with a hydrogen-containing gas stream between the purification section and the ammonia synthesis section of the ammonia production plant, and, particularly, wherein the second outlet is in fluid communication with the reforming section and/or with the purification section of the ammonia production plant.
Resumen de: EP4600407A2
An electrolysis system (10) includes: an electrolysis cell (20) configured to generate hydrogen by high-temperature steam electrolysis; a steam generation unit (30) that has a refrigerant heat exchange unit configured to perform heat exchange between heat of a heat storage unit and a refrigerant, generates a steam by heating raw material water via the refrigerant subjected to the heat exchange in the refrigerant heat exchange unit, and supplies the steam to the electrolysis cell; a heat storage supply unit (50) that has the heat storage unit and configured to supply heat of the heat storage unit to the refrigerant heat exchange unit; and a control unit (70) configured to control the heat storage supply unit such that an amount of heat input to the refrigerant heat exchange unit is smaller during a system startup or during a high-temperature standby than during a normal operation.
Resumen de: KR20200094876A
The present invention relates to a solid oxide fuel cell and a solid oxide electrolysis cell. According to the present invention, the solid oxide fuel cell and the solid oxide electrolysis cell comprises, respectively; a flat tubular unit cell (100) having a plurality of tubular through-holes (111a, 111b) for transferring fuel gas formed in a longitudinal direction; an upper cap (200) coupled to one longitudinal end of the flat tubular unit cell (100) and blocking one end of the flat tubular unit cell (100) from the outside while communicating the plurality of tubular through-holes (111a, 111b) with each other; a cell lower slit (300) coupled to the other longitudinal end of the flat tubular unit cell (100), having an opening part (320) opening the plurality of tubular through-holes (111a, 111b) formed therein, and having an insertion groove (330) formed on a lower surface; and a manifold (400) coupled to the cell lower slit (300), having spaces (420, 430) formed therein to communicate with the plurality of tubular through-holes (111a, 111b), including a reaction gas inlet (450) through which the fuel gas is supplied and a reaction gas outlet (460) through which the fuel gas reacting with air is discharged, and dividing the spaces (420, 430) and the plurality of tubular through-holes (111) into halves to form the flow of fuel gas in a U-shape. Accordingly, since a flat tubular unit cell and a flat planar unit cell are divided into halves, respectively, inflow and outflow of t
Resumen de: WO2024074817A1
An ammonia cracker module for converting ammonia into hydrogen is provided. The ammonia cracker module includes: (i) a heat exchange reactor including: (a) a first reaction zone including: a first working fluid flowpath; a first reactant flowpath; and one or more heat exchange interfaces positioned between the first working fluid flowpath and first reactant flowpath; (b) a second reaction zone including: a second working fluid flowpath; a second reactant flowpath; and one or more heat exchange interfaces positioned between the second working fluid flowpath and second reactant flowpath; (c) a catalyst positioned to contact reactant fluid flowing through the first and second reactant flowpaths to convert ammonia flowing through the first and second reactant flowpaths into hydrogen; and (ii) a heating system including: a first heat source, configured to heat working fluid to create a first heated working fluid to enter the first working fluid flowpath; and a second heat source, configured to receive a first thermally depleted working fluid from the first working fluid flowpath and output a second heated working fluid to the second working fluid flowpath when the cracker module is in use. A method of producing hydrogen using an ammonia cracker is also provided.
Resumen de: US2025250688A1
An electrolysis system includes: an electrolysis cell configured to generate hydrogen by high-temperature steam electrolysis; a steam generation unit that has a refrigerant heat exchange unit configured to perform heat exchange between heat of a heat storage unit and a refrigerant, generates a steam by heating raw material water via the refrigerant subjected to the heat exchange in the refrigerant heat exchange unit, and supplies the steam to the electrolysis cell; a heat storage supply unit that has the heat storage unit and configured to supply heat of the heat storage unit to the refrigerant heat exchange unit; and a control unit configured to control the heat storage supply unit such that an amount of heat input to the refrigerant heat exchange unit is smaller during a system startup or during a high-temperature standby than during a normal operation.
Resumen de: CN120400870A
The present disclosure relates to a water electrolysis cell, and a stack of water electrolysis cells stacked with water electrolysis cells. Provided is a water electrolysis cell in which the concentration of hydrogen reaching the oxygen-generating electrode side is reduced to the concentration before the concentration is increased, with a simple configuration. The water electrolysis cell is provided with an electrolyte membrane, a catalyst layer, and a diaphragm through which a fluid flows, and generates hydrogen and oxygen by supplying water and applying a voltage thereto, in which a hydrogen reaction catalyst for promoting a reaction between hydrogen and oxygen is provided at a site where the generated oxygen and the remaining water flow on the surface of the diaphragm on the oxygen generation electrode side.
Resumen de: CN120400877A
The invention provides a water electrolysis system capable of ensuring cooling of a water electrolysis cell and suppressing deterioration of durability of the water electrolysis cell. A water electrolysis system for obtaining hydrogen from a hydrogen electrode by supplying water to an oxygen electrode of a water electrolysis cell and applying a voltage to the water electrolysis cell, the water electrolysis system having a cooling fluid path for supplying a cooling fluid different from the water supplied to the oxygen electrode to the water electrolysis cell through a flow path different from a flow path through which the water is supplied to the oxygen electrode.
Resumen de: US2025250698A1
Disclosed herein are a catalyst for a hydrogen evolution reaction, a water electrolysis electrode including the same, and a method of manufacturing the same, wherein the catalyst can be manufactured at room temperature, and catalyst diversity can be given through an alloy structure including ruthenium and two or more metals. According to the present disclosure, the catalyst can be manufactured at room temperature due to characteristics of an electroplating manufacturing method, and the catalyst diversity can be given through the alloy structure that includes ruthenium and two or more metals.
Resumen de: JP2025116859A
【課題】シート状チタン多孔質を高効率で、かつ歩留まり良く製造可能な方法を提供すること。【解決手段】この製造方法は、少なくとも一つの貫通孔を有する少なくとも一つのステージ、少なくとも一つのステージを囲み、少なくとも一つのステージから離隔するフレーム、および少なくとも一つのステージとフレームを互いに連結する少なくとも一つの連結部を備える治具上に、少なくとも一つの貫通孔および少なくとも一つのステージとフレーム間の隙間を覆うように、チタン多孔質体を含むマザーシートを配置すること、マザーシートを治具上に吸着すること、ならびに隙間に沿って、ファイバレーザから射出されるレーザ光をマザーシート上で走査することによってマザーシートを切断することを含む。【選択図】図6B
Resumen de: US2025250694A1
A membrane electrode assembly includes a cathode portion disposed on one end and an anode portion disposed on an opposite end from the cathode portion. The membrane electrode assembly also includes a cathode ionomer layer disposed adjacent the cathode portion and an anode ionomer layer disposed adjacent the anode portion. Further, the membrane electrode assembly may include one or more support layers disposed between the cathode ionomer layer and the anode ionomer layer. Additionally, the anode ionomer layer includes a plurality of gas recombination catalysts in a graded dispersion such that a portion of the anode ionomer layer disposed closer to the anode portion includes a higher concentration of gas recombination catalysts than a portion of the anode ionomer layer disposed closer to the cathode portion.
Resumen de: WO2024142618A1
A gasket device (1) comprises a gasket (2) and a spacer (3). The spacer (3) supports separators (101, 102) which are members facing each other and an electrolyte membrane (104) between the separators (101, 102) and the electrolyte membrane (104) such that the separators (101, 102) and the electrolyte membrane (104) face each other via spaces (100a, 100b). The gasket (2) surrounds the space (100a) or the space (100b) between the separator (101) or the separator (102) and the electrolyte membrane (104). Moreover, the spacer (3) surrounds the gasket (2) from the outer side between the separators (101, 102) and the electrolyte membrane (104). The gasket (2) and the spacer (3) are in contact with each other in the expanding direction of the spaces (100a, 100b).
Resumen de: WO2025165039A1
The present invention relates to a high-efficiency hydrogen production system by a direct air capture method using renewable energy. According to an embodiment of the present invention, the high-efficiency hydrogen production system comprises: a direct air capture device in which a chemical reaction occurs when an alkaline liquid mixture containing a specific component, such as potassium hydroxide or sodium hydroxide, is brought into contact with air, to capture carbon dioxide from the air; an electrolysis tank into which pure water and the sodium carbonate or potassium carbonate solution generated in the process of the chemical reaction for capturing carbon dioxide in the direct air capture device are introduced and then electrolyzed by using renewable energy including solar or wind power generation energy, to generate a gas containing hydrogen and a liquid containing potassium hydroxide or sodium hydroxide and separate and extract the generated gas and liquid; a gas storage tank in which the gas separated and extracted from the electrolysis tank is stored; and a liquid storage tank in which the remaining liquid after the gas is separated and extracted from the electrolysis tank is stored and potassium hydroxide or sodium hydroxide contained in the liquid is reintroduced into the direct air capture device.
Resumen de: CN120202324A
The invention relates to a stack module having at least one solid oxide electrolysis stack comprising a plurality of stacked solid oxide electrolysis cells, in which the stack module comprises two gas inlet connections and two gas outlet connections. According to the invention, at least one solid oxide electrolysis stack is encapsulated in a metal container, with two gas inlet connections and two gas outlet connections connected to the metal container. The invention further relates to a solid oxide electrolyzer having at least one stacked module and to a method for replacing a stacked module of a solid oxide electrolyzer.
Resumen de: CN120391000A
An electrochemical cell system (100) comprising: an electrochemical cell arrangement (10); a control unit (20) configured to operate the electrochemical cell arrangement (10) only as an electrolytic cell or as a fuel cell; a heating unit (40) located outside the electrochemical cell arrangement (10), the heating unit being thermally coupled to the electrochemical cell arrangement (10) and the heating unit being configured to alternately store heat from the electrochemical cell arrangement (10) to the heating unit (40) and supply heat from the heating unit (40) to the electrochemical cell arrangement (10); and a transfer arrangement (30) configured to alternately transfer heat from the electrochemical cell arrangement (10) to the heating unit (40) and from the heating unit (40) to the electrochemical cell arrangement (10).
Resumen de: US2025250687A1
A water electrolysis system includes a flow rate adjusting valve for relatively changing a first flow rate which is a flow rate of water flowing through a first flow path portion extending from a first water lead-out unit, and a second flow rate which is a flow rate of water flowing through a second flow path portion extending from a second water lead-out unit.
Resumen de: WO2025163393A1
A hydrogen production facility is disclosed, comprising: a plurality of electrolysis systems to electrolyze water using lye; and a mutualized lye circulation system coupled with the plurality of electrolysis systems to circulate the lye among the plurality of electrolysis systems to facilitate electrolyzing the water, the lye circulation system comprising one or more pumps, wherein a number of the one or more pumps is less than a number of electrolysis systems of the plurality of electrolysis systems. A hydrogen production facility comprising first and second modular structures is also disclosed.
Resumen de: WO2025164180A1
This composite comprises a molybdenum compound and a noble metal. The molybdenum compound is at least one compound selected from the group consisting of molybdenum sulfide and molybdenum carbides, and the noble metal is at least one metal selected from the group consisting of platinum and palladium.
Resumen de: WO2025162752A1
A method is disclosed for producing an electrode (4) having a noble metal catalyst for alkaline water electrolysis. The method comprises: (S1) providing the electrode substrate (1); (S2) providing a matrix material (2) and a catalyst material (3) as starting materials for the coating; (S3) mixing the matrix material (2) and the catalyst material (3); and, (S4) coating the substrate (1) with the mixture of matrix material (2) and catalyst material (3) by means of high-velocity oxygen fuel spraying (HVOF). A correspondingly produced electrode (4), an electrochemical cell (10) comprising said electrode, and an electrolyser (20) are also specified.
Resumen de: US2025250685A1
The water electrolysis system includes: a first cooling device that cools a gas containing a predetermined gas component generated by electrolysis of water to a first cooling temperature that is higher than or equal to a boiling point of the gas component so that the first impurity having a boiling point higher than the first cooling temperature can be separated; a gas-liquid separation device that separates the first impurity from the gas; and a second cooling device that cools the gas from which the first impurity is separated to a second cooling temperature that is lower than the boiling point of the gas component, and liquefies the gas component so that the second impurity having a boiling point lower than the second cooling temperature can be separated as a gas.
Resumen de: US2025250703A1
A water electrolyzer includes a water electrolysis cell, a voltage applicator, a pressure regulating valve, and a controller. The water electrolysis cell includes a diaphragm or an electrolyte membrane, an anode, and a cathode. The anode is provided in one of two spaces separated by the diaphragm, or on one of two main surfaces of the electrolyte membrane. The cathode is provided in the other one of the two spaces separated by the diaphragm, or on the other one of the two main surfaces of the electrolyte membrane. The voltage applicator applies voltage between the anode and the cathode. In start-up of the water electrolyzer, the controller controls the voltage applicator to increase current flowing through the water electrolysis cell, and then controls the pressure regulating valve to increase set pressure of the pressure regulating valve.
Resumen de: US2025250687A1
A water electrolysis system includes a flow rate adjusting valve for relatively changing a first flow rate which is a flow rate of water flowing through a first flow path portion extending from a first water lead-out unit, and a second flow rate which is a flow rate of water flowing through a second flow path portion extending from a second water lead-out unit.
Resumen de: US2025250688A1
An electrolysis system includes: an electrolysis cell configured to generate hydrogen by high-temperature steam electrolysis; a steam generation unit that has a refrigerant heat exchange unit configured to perform heat exchange between heat of a heat storage unit and a refrigerant, generates a steam by heating raw material water via the refrigerant subjected to the heat exchange in the refrigerant heat exchange unit, and supplies the steam to the electrolysis cell; a heat storage supply unit that has the heat storage unit and configured to supply heat of the heat storage unit to the refrigerant heat exchange unit; and a control unit configured to control the heat storage supply unit such that an amount of heat input to the refrigerant heat exchange unit is smaller during a system startup or during a high-temperature standby than during a normal operation.
Resumen de: US2025250698A1
Disclosed herein are a catalyst for a hydrogen evolution reaction, a water electrolysis electrode including the same, and a method of manufacturing the same, wherein the catalyst can be manufactured at room temperature, and catalyst diversity can be given through an alloy structure including ruthenium and two or more metals. According to the present disclosure, the catalyst can be manufactured at room temperature due to characteristics of an electroplating manufacturing method, and the catalyst diversity can be given through the alloy structure that includes ruthenium and two or more metals.
Resumen de: US2025250696A1
Hydrogen is produced using high temperature heat from a progressive heat collection system that utilizes sun and air for collection and transfer of heat. Thermal energy from the sun superheats the water into steam and also powers a Stirling engine based electrical generator for operating a high temperature steam electrolyzer.
Resumen de: US2025250695A1
A platform technology that uses a novel membrane electrode assembly, including a cathode layer, an anode layer, a membrane layer arranged between the cathode layer and the anode layer, the membrane conductively connecting the cathode layer and the anode layer, in a COx reduction reactor has been developed. The reactor can be used to synthesize a broad range of carbon-based compounds from carbon dioxide and other gases containing carbon.
Resumen de: US2025250594A1
Compositions and methods for a hybrid biological and chemical process that captures and converts carbon dioxide and/or other forms of inorganic carbon and/or CI carbon sources including but not limited to carbon monoxide, methane, methanol, formate, or formic acid, and/or mixtures containing CI chemicals including but not limited to various syngas compositions, into organic chemicals including biofuels or other valuable biomass, chemical, industrial, or pharmaceutical products are provided. The present invention, in certain embodiments, fixes inorganic carbon or CI carbon sources into longer carbon chain organic chemicals by utilizing microorganisms capable of performing the oxyhydrogen reaction and the autotrophic fixation of CO2 in one or more steps of the process.
Resumen de: US2025250164A1
The invention relates to a photocatalytic unit for the production of hydrogen from water, comprising: (i) a photoreactor comprising a plurality of tubes, wherein said tubes internally comprise a photocatalyst, and are adapted for internally conducting a stream of water vapor; and absorbing external solar radiation focused on said tubes; and (ii) a plurality of solar reflectors adapted for concentrating incident solar radiation on the tubes of the photoreactor. Advantageously, the tubes of the photoreactor are arranged in a plane substantially perpendicular to the ground, and the solar reflectors w are arranged at both sides of said plane. The invention also relates to a solar plant for generating hydrogen comprising, at least, one photocatalytic unit according to any of the embodiments herein described, and a water vapor stream source connected to the photocatalytic unit.
Resumen de: US2025250694A1
A membrane electrode assembly includes a cathode portion disposed on one end and an anode portion disposed on an opposite end from the cathode portion. The membrane electrode assembly also includes a cathode ionomer layer disposed adjacent the cathode portion and an anode ionomer layer disposed adjacent the anode portion. Further, the membrane electrode assembly may include one or more support layers disposed between the cathode ionomer layer and the anode ionomer layer. Additionally, the anode ionomer layer includes a plurality of gas recombination catalysts in a graded dispersion such that a portion of the anode ionomer layer disposed closer to the anode portion includes a higher concentration of gas recombination catalysts than a portion of the anode ionomer layer disposed closer to the cathode portion.
Resumen de: CN119604469A
The present invention relates to a method for manufacturing an electrocatalyst for alkaline water electrolysis, said method comprising the steps of: (i) generating an aqueous electrolyte comprising suspended graphene and graphite nanoplatelets having lt in an electrochemical cell; the present invention relates to an electrolytic cell having a thickness of 100 nm, where the electrolytic cell comprises: a graphite negative electrode, (b) a graphite positive electrode, (c) an aqueous electrolyte comprising ions in a solvent, the ions comprising cations and anions, where the anions comprise sulfate anions; and wherein the method comprises the step of passing an electric current through the electrolysis cell to obtain exfoliated graphene and graphite nanosheet structures in the aqueous electrolyte in an amount greater than 5 g/l; (ii) forming an electroplating bath (2) comprising suspended graphene and graphite nanoplatelets in an amount greater than 2 g/l, said acidic electroplating bath comprising an aqueous solution of nickel sulfate and an electroplating solution comprising suspended graphene and graphite nanoplatelets in an amount greater than 5 g/l (thickness lt; 100 nm) of an aqueous electrolyte of step (i); and (iii) electrodepositing a combined layer of Ni or Ni alloy with graphene and graphite particles from the electroplating bath on a support to form an electrocatalyst.
Resumen de: US2025250165A1
Processes of photocatalytically generating molecular hydrogen (H2) and systems for carrying out the processes. Liquid water is contacted with an amount of a ID and/or 2D carbon-doped nanofilament-based photocatalyst material composition and a hole scavenger chemical, optionally under an inert gas purge, at temperature of 100° C. or less, generating gaseous molecular hydrogen by irradiating the liquid water, the hole scavenger chemical, and the photocatalyst for about 1 to 300 hours with at least one sun illumination (UV-Vis light (250-650 nm)).
Resumen de: US2025250187A1
The present disclosure describes a process for producing a reducing liquid comprising providing a liquid; providing a reducing gas and/or a metasilicate; and infusing the reducing gas and/or the metasilicate to the liquid, for the reducing gas and/or metasilicate to react with the liquid to produce a reducing liquid that has an oxidation reduction potential (ORP) value of about −100 mV or more negative. Further described is the process for preparing a reducing gas, which includes the steps of preparing an activator, introducing the activator into an electrolytic reactor, adding water, and applying a direct current to produce the reducing gas. Also described is a system for producing a reducing liquid.
Resumen de: US2025253377A1
The invention relates to an electrochemical cell assembly including a first end plate assembly, a stack of cell repeat units, and a second end plate assembly. The stack is held in a compressed state between the first end plate assembly and the second end plate assembly. The first end plate assembly and/or the second end plate assembly each include an end plate. The electrochemical cell assembly includes an insulation plate located between the end plate and the stack. At least one through-hole is provided in the insulation plate and a sealing insert is provided in the at least one through-hole of the insulation plate, the sealing insert defining a fluid pathway along the stacking direction. The invention also relates to an end plate assembly and a method of manufacturing an electrochemical cell assembly.
Resumen de: WO2025165433A2
An integrated energy system comprising a power plant including at least one nuclear reactor and electrical power generation system, the at least one nuclear reactor being configured to generate steam, and the electrical power generation system being configured to generate electricity, a desalination system configured to receive at least a portion of the electricity and steam to produce brine, an electrolysis process configured to process the brine into Sodium Hydroxide (NaOH), a Sodium Formate (HCOONa) production process configured to receive the Sodium Hydroxide (NaOH) to produce Sodium Formate (HCOONa), a Hydrogen (H2) extraction reactor configured to receive the Sodium Formate (HCOONa) and produce Hydrogen (H2), and a fuel cell configured to receive the Hydrogen (H2).
Resumen de: WO2025165427A1
Herein discussed is a method of carbon capture comprising providing a reactor having an anode, a cathode, and an electrolyte between and in contact with the anode and the cathode, wherein the electrolyte conducts oxide ions and electrons; introducing a carbonaceous gas to the anode; introducing steam and hydrogen (H2) or carbon dioxide (CO2) and carbon monoxide (CO) to the cathode, wherein steam or CO2 is the dominant component; producing carbon dioxide (CO2) at the anode, wherein the CO2 partial pressure is greater than 18 kPa in the anode exhaust; and producing H2 or CO or both at the cathode. In an embodiment, the anode exhaust has a pressure of from 1 atm to 5 atm. In an embodiment, the CO2 content in the anode exhaust is from 20vol% to 100vol%.
Resumen de: WO2025165039A1
The present invention relates to a high-efficiency hydrogen production system by a direct air capture method using renewable energy. According to an embodiment of the present invention, the high-efficiency hydrogen production system comprises: a direct air capture device in which a chemical reaction occurs when an alkaline liquid mixture containing a specific component, such as potassium hydroxide or sodium hydroxide, is brought into contact with air, to capture carbon dioxide from the air; an electrolysis tank into which pure water and the sodium carbonate or potassium carbonate solution generated in the process of the chemical reaction for capturing carbon dioxide in the direct air capture device are introduced and then electrolyzed by using renewable energy including solar or wind power generation energy, to generate a gas containing hydrogen and a liquid containing potassium hydroxide or sodium hydroxide and separate and extract the generated gas and liquid; a gas storage tank in which the gas separated and extracted from the electrolysis tank is stored; and a liquid storage tank in which the remaining liquid after the gas is separated and extracted from the electrolysis tank is stored and potassium hydroxide or sodium hydroxide contained in the liquid is reintroduced into the direct air capture device.
Resumen de: WO2025163482A1
Process for the production of syngas from carbonaceous waste material and CO2 comprising the following stages: a stage a) comprising the reaction R1 in which the carbonaceous material is reacted with carbon dioxide to obtain carbon monoxide according to the following reaction scheme: R1 CO2 + C = 2 CO; a stage b) of producing H2 and adding it to the carbon monoxide obtained in stage a) to obtain syngas, wherein stage b) comprises at least one of the following stages: bl) the carbon monoxide from the previous stage is reacted with water vapour to obtain carbon dioxide and hydrogen according to the following reaction scheme: R2 CO + H2O = CO2 + H2 b2) producing hydrogen by means of electrolysis of water, which is added to the carbon monoxide from stage a). The invention also relates to the unit in which stages a) and bl) are conducted as well as the related apparatus comprising the aforementioned unit.
Resumen de: WO2025163136A1
A method for controlling a green hydrogen production system (100; 100'), comprising geographically distributed power generating nodes (10, 300; 300') each having at least one node center (320; 320.1, 320.2, 320.3, 320.4) and at least one electrolyzer (13) for generating green hydrogen within the system from the produced electrical energy, wherein each the power generating node (10, 300; 300') comprises multiple PV units (12; 312) and multiple wind turbine generators (WTG) (11; 301...316) as power generating units and wherein the multiple wind turbine generators units (WTG) (11; 301...316) are located in geographically dispersed sites surrounding the node center(s) (320; 320.1, 320.2, 320.3, 320.4), wherein the installed capacity (IC) of the electrolyzer (13) and all other energy consuming devices in the system is smaller than the sum of maximum capacities (MG) of all PV units (12; 312) and wind turbine generators (11; 301...316) available for operation together, wherein the method comprises at least the following steps: a) an energy demand value (EDV) of electrical power required for constantly operating the electrolyzer and other consumers is defined wherein EDV < IC; b) weather conditions in proximity of the power generating units and in windward direction of the PV units (312) are constantly monitored; c) based on weather conditions acquired from monitoring, an expected energy yield value (EEY) is calculated separately for each type of power generating unit and/or for each
Resumen de: WO2025162555A1
The present disclosure relates to a method for producing a purified oxygen-containing stream, the method comprising: heating a Solid Oxide Electrolyzer Cells (SOEC) unit to a SOEC operating temperature; providing a water source or a steam source at a water source or steam source temperature; heating the water source or the steam source to produce a steam stream at a steam stream temperature; providing a sweep gas at a sweep gas temperature; feeding the steam stream and the sweep gas to the SOEC unit to produce an oxygen-containing stream and a hydrogen-containing stream; cooling the oxygen-containing stream to a temperature in the range of about 20°C to about 100°C, preferably about 40°C to about 60°C, more preferably about 44°C to about 55°C, and even more preferably about 50°C; and, after the cooling step, purifying the oxygen-containing stream to produce the purified oxygen-containing stream The present disclosure also relates a system for producing a purified oxygen-containing stream.
Resumen de: WO2025162564A1
A control system for a hydrogen production system is proposed. The hydrogen production system includes a plurality of electrolyzers and a plurality of converter modules each of which is coupled to one or more of the plurality of electrolyzers. The control system includes: a plurality of local controllers each of which is coupled with one or more of the plurality of converter modules and one more of the plurality of the electrolyzers; and a system controller in communication with the plurality of local controllers. The system controller is configured to receive an external dispatch value and electrolyzer state information regarding states of the plurality of electrolyzers, and to determine internal dispatch values for one or more electrolyzer from the plurality of electrolyzers based on the external dispatch value and the electrolyzer state information. A least one local controller from the plurality of local controllers associated with the one or more electrolyzers is configured to receive the internal dispatch values from the system controller, and to control operations of the one or more electrolyzers according to the internal dispatch values.
Resumen de: WO2025163032A1
The invention relates to an electrolysis device (10) for generating hydrogen from water using an electric current, having a cell stack (11) comprising a plurality of cell stack elements (12) in the form of electrolysis cells; a first pressure sensor (28) for detecting a first hydrogen-side pressure; a second pressure sensor (29) for detecting a second hydrogen-side pressure; and a control device (30) which checks whether the electrolysis device (10) has a leak on the basis of the first pressure measured by the first pressure sensor (28), the second pressure measured by the second pressure sensor (29), and the electric current applied to the electrolysis device (10) for the electrolysis process.
Resumen de: WO2025162963A1
The invention relates to a system consisting of a plurality of electrolysis devices (10), which are accommodated in a frame or shelf (19), for generating hydrogen from water using an electric current. Each electrolysis device (10) has at least the following: a cell stack (11) consisting of a plurality of cell stack elements (12) in the form of electrolysis cells; end plates (14, 15) lying opposite each other, wherein the cell stack (11) consisting of the cell stack elements (12) is provided and compressed between the end plates (14, 15); at least one water supply connection (16) which is formed on the end plates (14, 15) and via which water can be supplied to the respective electrolysis device (10); and at least one water discharge connection (17) which is formed on the end plates (14, 15) and via which water and oxygen can be discharged from the respective electrolysis device (10). At least one pre-separator (20) for oxygen is installed on the frame or shelf (19) and/or in the frame or shelf (19) and/or in the immediate vicinity of the frame or shelf (19) in order to separate oxygen from the water discharged from the electrolysis devices (10).
Resumen de: WO2025163031A1
Aspects of the present disclosure relate to a hydrogen production facility. The hydrogen production facility includes one or more electrolyser stacks to electrolyze water using an electrolyte and generate a hydrogen-aqueous solution mixture and an oxygen-aqueous solution mixture, the one or more electrolyser stacks comprising a plurality of membranes. The facility also includes a hydrogen separator to produce a flow of hydrogen from the hydrogen-aqueous solution mixture and an oxygen separator to produce a flow of oxygen from the oxygen-aqueous solution mixture. The hydrogen separator comprises a hydrogen gas-liquid separation device and a hydrogen coalescing device. The oxygen separator comprises an oxygen gas-liquid separation device and an oxygen coalescing device.
Resumen de: WO2025163034A1
A hydrogen production facility is disclosed, comprising a plurality of electrolyser stacks arranged for electrolyzing water using an electrolyte and for generating at least a hydrogen-aqueous solution mixture; and a hydrogen separator arrangement for producing a flow of hydrogen from the hydrogen-aqueous solution mixture; wherein the hydrogen separator arrangement comprises a plurality of first stage hydrogen collector separators, the first stage hydrogen collector separators being fluidly coupled to a respective sub-set of the plurality of electrolyser stacks; and wherein the plurality of first stage hydrogen collector separators are fluidly coupled to a downstream hydrogen buffer vessel. A related method is further disclosed.
Resumen de: DE102024103045A1
Verfahren zur Steuerung eines Systems zur Erzeugung von grünem Wasserstoff, wobei mehrere Photovoltaikanlagen (12) und mehrere Windenergieanlagen als Stromerzeugungseinheiten zur Erzeugung von elektrischer Energie und mindestens ein Elektrolyseur zur Erzeugung von grünem Wasserstoff genutzt werden, wobei die installierte Leistung (IC) des Elektrolyseurs und aller anderen energieverbrauchenden Vorrichtungen in dem Kraftwerk kleiner ist als die Leistung der Summe der maximalen Leistung (MC) der Photovoltaikanlagen (12) und der Windenergieanlagen zusammen, mit folgenden Schritten:a) Definition eines Energiebedarfswerts (EBW) der für den Elektrolyseur und andere Verbraucher erforderlichen elektrischen Leistung, wobei EBW < IC ist;b) Überwachung der Wetterverhältnisse in der Nähe der Stromerzeugungseinheiten und in Luv der Photovoltaikanlagen (12);c) Berechnung eines erwarteten Energieertragswerts (EEW) für jeden Typ von Stromerzeugungseinheit basierend auf den Wetterverhältnissen;d) Zuweisen einer individuellen Arbeitslast für die Photovoltaikanlagen (12) und die Windenergieanlagen, die nach dem folgenden Priorisierungsschema ausgewählt wird:i. wenn der erwartete Energieertragswert EEW(PV) der Photovoltaikanlagen (12) allein ausreicht, um den Energiebedarfswert EBW zu erfüllen, werden alle Photovoltaikanlagen (12) mit Volllast betrieben und alle Windenergieanlagen im Leerlauf betrieben oder abgeschaltet;ii. Wenn der erwartete Energieertragswert EEW(PV) der Photovolt
Resumen de: DE102024109660A1
Eine Membranelektrodenanordnung umfasst einen Kathodenabschnitt, der an einem Ende angeordnet ist, und einen Anodenabschnitt, der an einem dem Kathodenabschnitt gegenüberliegenden Ende angeordnet ist. Die Membranelektrodenanordnung umfasst auch eine Kathoden-Ionomerschicht, die neben dem Kathodenabschnitt angeordnet ist, und eine Anoden-Ionomerschicht, die neben dem Anodenabschnitt angeordnet ist. Ferner kann die Membranelektrodenanordnung eine oder mehrere Trägerschichten enthalten, die zwischen der Kathoden-Ionomerschicht und der Anoden-Ionomerschicht angeordnet sind. Zudem enthält die Anoden-Ionomerschicht eine Vielzahl von Gasrekombinationskatalysatoren in einer abgestuften Dispersion, sodass ein Abschnitt der Anoden-Ionomerschicht, der näher am Anodenabschnitt angeordnet ist, eine höhere Konzentration an Gasrekombinationskatalysatoren enthält als ein Abschnitt der Anoden-Ionomerschicht, der näher am Kathodenabschnitt angeordnet ist.
Resumen de: WO2025162027A1
Disclosed in the present application are an electrode plate frame and an electrolytic bath, which relate to the technical field of electrolytic hydrogen production and are used for solving the problem of leakage at the joint of an electrode plate frame and an external pipeline. The electrode plate frame comprises an annular frame body, one or more fluid inlets/outlets being formed in the outer circumferential surface of the annular frame body, and mounting holes being formed in the positions on the outer circumferential surface of the annular frame body around each fluid inlet/outlet, such that each fluid inlet/outlet and the corresponding mounting holes form a flange structure to be connected to an external pipeline. Compared with the existing practice of welding a pipeline at fluid inlet/outlets, the fluid inlets/outlets in the annular frame body of the present application do not need welding and have no welding spot, thereby preventing generation of stress corrosion, further preventing the phenomenon of galvanic corrosion caused by a welding material being different from materials of a pipeline and an electrode plate frame during welding, and reducing the risk of leakage at the joint of the electrode plate frame and the external pipeline.
Resumen de: WO2025161658A1
A system and method for co-producing green sodium carbonate and ammonium chloride by using renewable energy sources. The system comprises a renewable energy source power generation subsystem, a water electrolysis subsystem, an air separation subsystem, an ammonia synthesis subsystem, a tail-gas pretreatment subsystem, a waste-salt pretreatment subsystem and a sodium carbonate synthesis subsystem. By utilizing renewable wind and solar energy to generate electricity for electrolytic hydrogen production and air separation, the impact of renewable energy power generation on a power grid and the difficulty in balancing the fluctuating power supply of the power grid are solved, on-site consumption of green power is achieved, the green power is converted on site into green products with economic value added, and stable operation of a green electricity-green hydrogen-green chemical production line is achieved; and industrial waste salts and the industrial emissions of carbon dioxide tail gas are used as green raw materials for sodium carbonate, and are integrated with carbon tail gas and industrial waste salts discharged by industrial enterprises in the vicinity, and resource utilization of waste is conducted, thereby reducing carbon emissions and also realizing a green circular economy.
Resumen de: AU2024239221A1
This hydrogen production system is provided with: a solid oxide electrolytic cell (SOEC) that electrolyzes water vapor; a power supply device that applies a voltage equal to or greater than a thermal neutral voltage to the SOEC; and a water vapor generation device that generates at least a portion of water vapor to be supplied to the SOEC by heating water using surplus heat generation of the SOEC.
Resumen de: US2025250686A1
A water electrolysis device includes a water electrolysis module that generates hydrogen by water vapor electrolysis. The water electrolysis device includes: a blower configured to supply hydrogen to the water electrolysis module; a recycle passage configured to supply generated hydrogen generated by the water electrolysis module from the water electrolysis module to an intake port of the blower; a condenser configured to condense water vapor contained in the generated hydrogen; and a temperature increasing portion configured to increase a temperature of the generated hydrogen between the condenser and the blower.
Resumen de: WO2025164073A1
Provided is a hydrogen production system (100) which comprises: an electrolysis module (19) that supplies steam to a hydrogen electrode and produces hydrogen through steam electrolysis; a steam supply unit (20) that supplies steam to a hydrogen electrode (11); an air supply unit (70) that supplies air to an oxygen electrode (12); a hydrogen supply pipe (43) that supplies hydrogen to the oxygen electrode (12); a power supply unit (18) that supplies power to the electrolysis module (19); and a control device (80) that controls the hydrogen production system (100). The control device (80) controls the power supply unit (18) so as to start supplying power to the electrolysis module (19) in response to the temperature of the electrolysis module (19) exceeding Temp4 that is lower than the ignition temperature of hydrogen.
Resumen de: WO2025163609A1
The present invention provides a multipurpose integrated passive system (20) for converting green energy comprising a renewable energy conversion module (1) to generate electricity, a water and gas management module (3) to supply water to the water electrolyser (4), a water electrolyser (4) connected with one or more potassium hydroxide (KOH) tank (4a, 4b), is configured to split water into hydrogen gas and oxygen gas and said gases are separately directed into the storage assembly (5). The storage assembly (5) include a plurality of gas storage tanks (5a, 5b) for separately storing the gases and a plurality of valves for controlling the flow of said gases, a burner assembly (6) include a hydrogen burner (7), wherein the hydrogen gas from the gas storage tank (5a) is delivered to the hydrogen burner (7), and a controller (2) configured to ensures to safety and efficiency of the multipurpose integrated passive system (20).
Resumen de: WO2025162048A1
The present application belongs to the technical field of hydrogen production by water electrolysis, and particularly relates to an oxygen evolution reaction catalyst, a preparation method therefor, and the use thereof. The present application uses the hydrolysis effect of metal positive ions in a hydrolysable metal salt solution to make a weakly-acidic heterogeneous soaking system, which slowly acts on the surface of a metal substrate, thereby partially etching the surface of the metal substrate while removing metal oxides on the surface; on the surface of the substrate, metal ions generated by the etching bind to metal ions generated by hydrolysis, so as to form an LDH catalyst structure, ensuring a relatively high catalytic activity thereof. Moreover, under an interface-confined effect, a compact transition layer structure is slowly formed at the interface between the metal substrate and the catalyst layer; as a bridge of the metal substrate and the catalyst layer, said transition layer has the same structure as that of the LDH, but exhibits a more compact appearance and totally covers the surface of the metal substrate, so as to firmly anchor the LDH catalytic structure layer onto the surface of the metal substrate, thereby allowing the OER catalyst to have high activity and high stability under the condition of an industrial-level current density.
Resumen de: WO2025162959A1
The disclosure refers to a computer-implemented method for heating up electrolytic units. The method comprises determining whether some electrolytic units of an electrolysis plant require heating up to have them at a temperature within a predetermined range in a future time span; controlling the electrolytic units to power them up based on first electric power available in a current time span; heating up the electrolytic units to have them at the temperature within the predetermined range in the at least one future time span; and repeating the steps such that the heating up is determined for one or more time spans that occur at the same time and/or later than the future time span, thereby repeatedly controlling the temperature of the electrolytic units to be at a temperature within the predetermined range in the future time spans.
Resumen de: EP4596758A1
A water electrolysis device (1) includes a water electrolysis module (2) that generates hydrogen by water vapor electrolysis. The water electrolysis device includes: a blower (7, 8) configured to supply hydrogen to the water electrolysis module; a recycle passage configured to supply generated hydrogen generated by the water electrolysis module from the water electrolysis module to an intake port of the blower; a condenser (6) configured to condense water vapor contained in the generated hydrogen; and a temperature increasing portion (18) configured to increase a temperature of the generated hydrogen between the condenser and the blower.
Resumen de: EP4596757A1
A hydrogen production facility is disclosed, comprising a plurality of electrolyser stacks arranged for electrolyzing water using an electrolyte and for generating at least a hydrogen-aqueous solution mixture; and a hydrogen separator arrangement for producing a flow of hydrogen from the hydrogen-aqueous solution mixture; wherein the hydrogen separator arrangement comprises a plurality of first stage hydrogen collector separators, the first stage hydrogen collector separators being fluidly coupled to a respective sub-set of the plurality of electrolyser stacks; and wherein the plurality of first stage hydrogen collector separators are fluidly coupled to a downstream hydrogen buffer vessel. A related method is further disclosed.
Resumen de: EP4596756A1
Aspects of the present disclosure relate to a hydrogen production facility. The hydrogen production facility includes one or more electrolyser stacks to electrolyze water using an electrolyte and generate a hydrogen-aqueous solution mixture and an oxygen-aqueous solution mixture, the one or more electrolyser stacks comprising a plurality of membranes. The facility also includes a hydrogen separator to produce a flow of hydrogen from the hydrogen-aqueous solution mixture and an oxygen separator to produce a flow of oxygen from the oxygen-aqueous solution mixture. The hydrogen separator comprises a hydrogen gas-liquid separation device and a hydrogen coalescing device. The oxygen separator comprises an oxygen gas-liquid separation device and an oxygen coalescing device.
Resumen de: EP4596760A1
The disclosure refers to a computer-implemented method for heating up electrolytic units. The method comprises determining whether some electrolytic units of an electrolysis plant require heating up to have them at a temperature within a predetermined range in a future time span; controlling the electrolytic units to power them up based on first electric power available in a current time span; heating up the electrolytic units to have them at the temperature within the predetermined range in the at least one future time span; and repeating the steps such that the heating up is determined for one or more time spans that occur at the same time and/or later than the future time span, thereby repeatedly controlling the temperature of the electrolytic units to be at a temperature within the predetermined range in the future time spans.
Resumen de: EP4596755A1
A hydrogen production facility is disclosed, comprising: a plurality of electrolysis systems to electrolyze water using lye; and a mutualized lye circulation system coupled with the plurality of electrolysis systems to circulate the lye among the plurality of electrolysis systems to facilitate electrolyzing the water, the lye circulation system comprising one or more pumps, wherein a number of the one or more pumps is less than a number of electrolysis systems of the plurality of electrolysis systems. A hydrogen production facility comprising first and second modular structures is also disclosed.
Resumen de: MX2025004437A
Electrochemical cell system (100) which comprises an electrochemical cells arrangement (10), a control unit (20) configured to operate the electrochemical cells arrangement (10) only as electrolytic cells or only as fuel cells, a heat unit (40), external to the electrochemical cells arrangement (10), which is thermally coupled to the electrochemical cells arrangement (10) and which is configured to alternately store heat from the electrochemical cells arrangement (10) to the heat unit (40) and supply heat from the heat unit (40) to the electrochemical cells arrangement (10), and a transfer arrangement (30) configured to alternately transfer heat from the electrochemical cells arrangement (10) to the heat unit (40) and from the heat unit (40) to the electrochemical cells arrangement (10).
Resumen de: CN119866558A
The invention relates to a power plant (1) comprising two units (A) and (B), a first unit (A) and a second unit (B), located in two separate industrial sites, having:-the first unit (A) comprising a synthesis device (8) capable of producing methane or methanol (15) from hydrogen (2) and carbon dioxide (4) originating from the second unit (B), and-a second unit (B) comprising fuel cell means (5) that can be supplied with electric current (1) by methane or methanol (15) originating from the first unit (A) and an anode gas stream (6) comprising carbon dioxide, said fuel cell means being combined with collecting means (7) for collecting carbon dioxide (17) in the anode stream (6) intended for the first unit (A).
Resumen de: CN119948208A
Disclosed are a membrane suitable for alkaline water electrolysis and an alkaline water electrolysis device comprising the same. A method for producing hydrogen and a method for producing a membrane for alkaline water electrolysis are also disclosed.
Resumen de: WO2024073537A2
A hydrogen-rich hydrocarbon fuel gas can be separated into a methane fuel stream and a hydrogen product stream. The methane fuel stream can be fed to a methane fuel fired furnace, combustion of the methane fuel stream can produce a carbon-dioxide-rich flue gas, and a carbon capture process can be performed on the carbon-dioxide-rich flue gas. The hydrogen product stream can be fed to a hydrogen fired furnace or elsewhere. Combustion of the hydrogen product stream in a hydrogen fired furnace can generate a flue gas the is low in carbon dioxide. Electrolysis of water obtained from the hydrogen fired furnace flue gas can produce hydrogen for a desired use, such as fuel for the hydrogen fired furnace, and can produce oxygen for enriching the fuel gas fed to the methane fuel fired furnace.
Resumen de: EP4596493A1
Provided is a method for producing a tantalum nitride material including a nitriding step of heating a precursor containing a lithium tantalum composite oxide in the presence of a nitrogen compound.
Resumen de: EP4596659A1
The present invention aims to provide a liquid fuel production system and a method for producing liquid fuel capable of reducing the amount of hydrogen gas used.The liquid fuel production system 1 includes: an electrolytic reduction device 2 for obtaining a mixed gas and an oxygen gas by an electrolytic reduction of carbon dioxide and water; a carbon dioxide separation device 3 for separating the carbon dioxide from the mixed gas; a water separation device 4 for separating water from the mixed gas; a cryogenic separation device 5 for separating the mixed gas into ethylene, hydrogen, and a residual off-gas; a first reaction device 6 for obtaining a first mixture by oligomerization of ethylene obtained in the cryogenic separation device; a first separation device 7 for separating light hydrocarbons from the first mixture; a second reaction device 8 for obtaining a second mixture containing liquid fuel by hydrocracking and hydroisomerizing the first mixture; and a second separation device 9 for separating the second mixture into at least liquid fuel, cracked gas, and heavy hydrocarbons.
Resumen de: EP4596759A1
In order to improve robustness of a water electrolysis system, there is provided an insulating piping configured by a double tube including an inner tube (130) that connects a water electrolysis stack and an auxiliary machine and through which a fluid flows, and an outer tube (12) provided on an outer side of the inner tube (130) via the inner tube (130) and an outer tube inner space (14); in which the outer tube (12) has an insulating property, the water electrolysis stack and the auxiliary machine are insulated from each other in the inner tube (130), and a dry gas (13) having a humidity of less than or equal to a predetermined value is enclosed in an outer tube inner space (14) that is the space at a pressure of the fluid flowing inside the inner tube (130) and a pressure higher than an atmospheric pressure.
Resumen de: US2024059557A1
An exemplary hydrogen production apparatus 100 according to the present invention includes a grinding unit 10 configured to grind a silicon chip or a silicon grinding scrap 1 to form silicon fine particles 2, and a hydrogen generator 70 configured to generate hydrogen by causing the silicon fine particles 2 to contact with as well as disperse in, or to contact with or dispersed in water or an aqueous solution. The hydrogen production apparatus 100 can achieve reliable production of a practically adequate amount of hydrogen from a start material of silicon chips or silicon grinding scraps that are ordinarily regarded as waste. The hydrogen production apparatus thus effectively utilizes the silicon chips or the silicon grinding scraps so as to contribute to environmental protection as well as to significant reduction in cost for production of hydrogen that is utilized as an energy source in the next generation.
Resumen de: CN119317736A
An electrolyte membrane including a composite catalyst layer is provided. The membrane has a thickness of less than or equal to 100 mu m and is a single adhesive polymer membrane comprising a plurality of ion conducting polymer layers. The composite catalyst layer comprises particles of an unsupported composite catalyst dispersed in an ion conducting polymer, and the layer has a thickness in the range of from 5 mu m to 30 mu m and including 5 mu m and 30 mu m. Also provided are a catalyst coated film (CCM) incorporating the electrolyte membrane, and a method of manufacturing the electrolyte membrane.
Resumen de: JP2024102507A
To provide a water electrolysis stack capable of improving durability.SOLUTION: A water electrolysis stack has a cell laminate in which a plurality of water electrolysis cells are laminated. In the cell laminate, inter-cell regions are formed in adjacent water electrolysis cells, and gas flows in the inter-cell regions during water electrolysis.SELECTED DRAWING: Figure 6
Resumen de: CN119465247A
The invention discloses a molybdenum phosphide carbon nanosphere loaded noble metal Pt as an efficient hydrogen evolution reaction catalyst and a preparation method thereof. The preparation method of the electrochemical catalyst comprises the following steps: firstly preparing a molybdenum phosphorus carbon nanosphere precursor by a hydrothermal method, then carrying out heat treatment in a hydrogen-argon mixed gas atmosphere, and finally loading noble metal platinum by a hydrothermal method to obtain the MoP/C-Pt catalyst. According to the MoP/C-Pt catalyst prepared through the method, molybdenum phosphide carbon nanospheres serve as a carrier, Pt nano-particle aggregation is obviously inhibited through the interaction between metal and the carrier, the problems that in the electrochemical hydrogen evolution reaction, the precious metal utilization rate of the catalyst is low, and stability is poor are effectively solved, in addition, MoP has special Mo delta + and P delta-active sites, and the stability of the catalyst is improved. According to the present invention, the carbon carrier is introduced, such that the water decomposition can be catalyzed under the low potential, the conductivity of the catalyst is enhanced due to the introduction of the carbon carrier, and the catalyst can provide the excellent electro-catalysis performance especially in the acidic and alkaline electrolyte. The preparation method is simple and can be widely applied to industrial production.
Resumen de: KR20250117771A
원자력 발전 및 수소 생산을 위한 복합 운용 시스템 및 방법을 제공한다. 원자력 발전 및 수소 생산을 위한 복합 운용 시스템은 원자력 발전 및 수소 생산을 위한 복합 운용 시스템으로서, 제2 차 계통; 수전해를 수행하는 수전해부; 전력수요 변동량 정보를 제공받는 전력 그리드; 터빈 운전정보와 상기 수전해부의 운전정보를 제공하는 원자력 발전소 주제어부; 및 상기 전력수요 변동량 정보와 상기 운전정보를 기반으로, 원자력 발전과 수소 생산이 복합적으로 수행되도록 하기 위한 통합 운전제어부를 포함한다.
Resumen de: MX2025005140A
Cell for forming an electrolyser comprising at least one diaphragm or membrane having a first side and a second side opposite the first side, a first cell plate, arranged on the first side of the diaphragm, provided with a first electrode, provided with an inlet channel for supplying or draining electrolyte to or from the electrode, provided with a first discharge channel for discharging oxygen from the electrode, at least one second cell plate, arranged on the second side of the diaphragm, provided with a second electrode and provided with a second discharge channel for discharging hydrogen from the electrode wherein the at least one first and second cell plate are made of a polymer material.
Resumen de: US2023373882A1
The invention relates to a process, catalysts, materials for conversion of renewable electricity, air, and water to low or zero carbon fuels and chemicals by the direct capture of carbon dioxide from the atmosphere and the conversion of the carbon dioxide to fuels and chemicals using hydrogen produced by the electrolysis of water.
Resumen de: US2025250686A1
A water electrolysis device includes a water electrolysis module that generates hydrogen by water vapor electrolysis. The water electrolysis device includes: a blower configured to supply hydrogen to the water electrolysis module; a recycle passage configured to supply generated hydrogen generated by the water electrolysis module from the water electrolysis module to an intake port of the blower; a condenser configured to condense water vapor contained in the generated hydrogen; and a temperature increasing portion configured to increase a temperature of the generated hydrogen between the condenser and the blower.
Resumen de: CN120400872A
The invention provides a high-performance PEM water electrolysis hydrogen production membrane electrode preparation method, and relates to the technical field of non-noble metal catalyst loading and nanostructure skeleton construction, and the method comprises the following steps: 1, modifying a proton exchange membrane by using a vacuum coating method, and constructing a nanostructure skeleton on the surface of a membrane electrode; and 2, loading a non-noble metal catalyst on the surface of the proton exchange membrane with the nano-structure skeleton constructed in the step 1. The preparation method has the beneficial effects that the nano-structure framework constructed on the surface of the proton exchange membrane can play a surface modification role, the surface hydrophilicity of the proton exchange membrane is enhanced, the roughness degree is improved, and the combination between the proton exchange membrane and a catalyst is enhanced; the nanostructure skeleton provides more loading sites for the non-noble metal catalyst, and the coupling of the nanostructures of the nanostructure skeleton and the non-noble metal catalyst further improves the overall specific surface area, thereby being beneficial to improving the performance and improving the stability of the membrane electrode.
Resumen de: CN120398299A
The invention discloses a gas and fertilizer producing device, and relates to the technical field of sewage recycling, the gas and fertilizer producing device comprises a feeding container, a membrane bioreactor, a liquid fertilizer container, an alkali liquor storage device, a porous hydrophobic membrane, an electrolyzer, an electrolytic positive electrode and an electrolytic negative electrode, a reaction tank is formed in the membrane bioreactor; the reaction tank is connected with the feeding container to enable sewage in the feeding container to flow into the reaction tank, the liquid fertilizer container is connected with the reaction tank to enable effluent of the reaction tank to flow into the liquid fertilizer container, the alkali liquor storage device forms an alkali liquor tank, and water in the reaction tank spontaneously flows into the alkali liquor tank through a porous hydrophobic membrane in the form of water vapor. The electrolytic tank is communicated with the alkali liquor tank, so that an alkali solution in the alkali liquor tank flows into the electrolytic tank, and water in the alkali solution in the electrolytic tank is electrolyzed to form oxygen and hydrogen. According to the gas and fertilizer producing device, harmlessness and recycling of sewage can be achieved while the sewage is treated, recycling of resources is achieved, the resources are saved, and the environment is protected.
Resumen de: CN120400869A
The invention discloses a PEM water electrolysis hydrogen production system and a control method, and belongs to the technical field of electrolysis hydrogen production. The PEM water electrolysis hydrogen production system provided by the invention comprises a water purifier, a temperature control water tank, a circulating water tank, a heat exchanger, an electrolytic bath, a first steam-water separator and a control system, a three-way valve and a first water pump are arranged on a pipeline between the circulating water tank and the heat exchanger; a liquid outlet of the electrolytic bath is communicated with a liquid inlet of the circulating water tank and a liquid inlet of the first steam-water separator through pipelines respectively; an air outlet of the first steam-water separator is communicated with the circulating water tank through a pipeline; a liquid outlet of the circulating water tank, the first water pump and a liquid outlet of the first steam-water separator are communicated with the three-way valve; the control system is used for controlling opening and closing of the first solenoid valve and the second solenoid valve, valve opening of the three-way valve, rotating speed of the first water pump and current of the electrolytic bath. The system can be quickly started, and meanwhile the risk that the electrolytic cell is damaged due to large-current starting is avoided.
Resumen de: CN120400923A
The invention discloses a high-performance low-noble-metal hydrogen evolution catalyst as well as a preparation method and application thereof, and relates to the technical field of water electrolysis hydrogen production. The preparation method of the high-performance low-noble-metal hydrogen evolution catalyst comprises the following steps: placing the porous conductive carrier in a first electrolyte containing nickel ions to carry out first-step electrochemical deposition, so that metal nickel is deposited on the surface of the porous conductive carrier; the porous conductive carrier with the metal nickel deposited on the surface is placed in air to be subjected to oxidation treatment, and a nickel oxide layer is formed on the surface of the metal nickel; and the porous conductive carrier with the nickel oxide layer is placed in a second electrolyte for second-step electrochemical deposition, metal platinum nanoparticles are deposited on the surface of the nickel oxide layer, and the second electrolyte contains soluble platinic acid or platinate. The hydrogen evolution catalyst prepared by adopting two-step electrochemical deposition has relatively high catalytic activity, and is simple in process, low in cost and suitable for batch industrial production.
Resumen de: CN120394054A
The invention relates to a hydrogen evolution reaction catalyst, in particular to a titanium dioxide phase junction material, a preparation method thereof and application of the titanium dioxide phase junction material in an electrolytic water hydrogen evolution reaction, and the preparation method comprises the following steps: S1, putting a foam titanium substrate into an alkaline solution to carry out a hydrothermal reaction, and washing and drying a reaction product; s2, calcining the reaction product obtained in the step S1 for the first time to obtain a titanium oxide; and S3, carrying out secondary calcination on the titanium oxide obtained in the step S2, and carrying out doping induced phase change to obtain the titanium dioxide phase junction material. Compared with the prior art, the preparation method has the advantages that the problems that heterojunction has interface defects and phase junction is difficult to prepare in a hydrogen evolution reaction catalyst based on titanium dioxide in the prior art are solved, and the preparation of the phase junction catalytic material which is simple in technological process and capable of effectively saving energy is realized; the catalyst can be used for catalytic hydrogen evolution reaction under electrolyte conditions with different pH values.
Resumen de: CN120400874A
The invention relates to the technical field of water electrolysis hydrogen production, and discloses an AEM single-reactor water electrolysis hydrogen production system with a high fluctuation response characteristic and a method thereof, and the AEM single-reactor water electrolysis hydrogen production system comprises a data acquisition module and an evaluation management module. According to the system, water supply data, power supply data and electrolysis data at all time points are obtained through the multi-dimensional acquisition module and classified to form a data set, the intelligent control module analyzes the running state of AEM water electrolysis hydrogen production equipment in real time, a monitoring data set is generated, the problem that an electrolytic bath is overheated or insufficient in cooling is effectively solved, and the service life of the system is prolonged. The matching degree of the electrode reaction rate and the ion transmission capacity is rapidly judged, then the estimated yield and energy conversion efficiency of hydrogen production are analyzed, the energy efficiency index is generated, the yield and energy consumption are accurately balanced, the multi-dimensional monitoring response speed is high, and the monitoring accuracy is high. The intelligent control module judges the cavitation state, the heat balance state, the electrode reaction rate and the fluctuation of the energy conversion efficiency in the AEM single-reactor water electr
Resumen de: CN120400864A
The invention relates to the technical field of photovoltaic cooling hydrogen production, and particularly provides a multi-source synergistic spray cooling concentrating frequency division photovoltaic hydrogen production system and a regulation and control method. Accurate separation of solar spectrums is achieved through jacketed pipe frequency division and a reaction pipe, visible light wave bands are converted into electric energy through a photovoltaic module, infrared wave bands are subjected to photo-thermal conversion through a catalytic reaction pipe, surplus heat energy is directly used for the activation process of hydrogen production through water electrolysis, and gradient utilization of solar energy is achieved. And precise temperature control is realized, and the temperature of the photovoltaic panel is stabilized in an optimal interval in combination with a closed-loop temperature control strategy. The wind-solar complementary power supply and the waste heat cascade recovery device synergistically improve the energy utilization rate, and the multifunctional integrated electric control system realizes hydrogen-electricity-heat multi-target scheduling through a dynamic game optimization algorithm and a digital twin simulation platform. The working temperature of a solar cell is stabilized in the optimal efficiency interval, meanwhile, heat energy loss of a traditional system is converted into hydrogen production effective energy, and an efficient and stable sol
Resumen de: CN120400880A
The invention discloses a modularized electrolytic cell, and belongs to the technical field of electrolytic hydrogen production. The electrolytic bath comprises a plurality of detachable electrolytic units, an anode chamber and a cathode chamber in each electrolytic unit are provided with independent tabs, liquid inlets and liquid outlets, the liquid inlets supply liquid through electromagnetic valves, and the tabs supply power through control switches; and the electromagnetic valve and the control switch are electrically connected to a central control unit. According to the design of the modularized electrolysis unit, flexible and accurate adjustment of power supply and liquid supply can be achieved, meanwhile, mounting and dismounting are convenient, and maintenance is easier and more convenient.
Resumen de: CN120398011A
The invention discloses a rapid preparation process of a novel nano material. The rapid preparation process comprises the following steps: step 1, pretreating raw materials; 2, mixing and pipe sealing; step 3, gradient temperature rise; the preparation method has the advantages that by optimizing the raw material combination, the reaction time is greatly shortened, the preparation efficiency is remarkably improved, meanwhile, the conductivity of FePSe3 is greatly improved through introduced carbon doping, the overpotential of the oxygen evolution reaction is successfully reduced to 524 mV at 100 mAcm <-2 > and is reduced by 23% compared with pure FePSe3 (677 mV), and the material can be used for preparing the high-current-density composite material under the industrial-grade high-current density, such as gt; the overpotential growth rate of 100mAcm <-2 > is remarkably lower than that of pure FePSe3, the energy consumption and equipment cost of hydrogen production by electrolysis of water can be greatly reduced, efficient synthesis of FePSe3 and innovative application of FePSe3 in OER are realized through raw material optimization and process improvement, the method has remarkable technical progress and commercial value, and the method is simple in process, low in energy consumption and suitable for industrial production. And a new way is provided for large-scale preparation of the high-performance OER catalyst.
Resumen de: CN120398134A
The invention provides a polyacid derivative, a preparation method thereof and an electrolytic water hydrogen evolution catalyst, and belongs to the field of electrocatalytic hydrogen evolution materials, and the molecular formula of the polyacid derivative is Co (NH3) 6 2 (MnMo9O32). The preparation method comprises the following steps: mixing an aqueous solution of ammonium 9-molybdenum manganate octahydrate with an aqueous solution of cobalt hexammine trichloride, reacting at 70-90 DEG C for 2-5 hours, filtering, washing, and freeze-drying to obtain Co (NH3) 6 2 (MnMo9O32). According to the present invention, the polyacid derivative is adopted as the precursor, and the hydrothermal reaction and the H2-Ar atmosphere calcination are combined so as to achieve the efficient preparation of the electrolytic water hydrogen evolution catalyst Co4S3-MnS-MoS2 (at) CC, such that the electro-catalytic performance of the catalyst is significantly improved;
Resumen de: CN120400906A
The invention aims at providing an oxygen-containing anion modified oxygen evolution electrode for AEMWE and a preparation method of the oxygen-containing anion modified oxygen evolution electrode, and belongs to the technical field of hydrogen production through electrolysis of water. Introducing a second cation and an oxygen-containing anion through dipping treatment; and finally, carrying out cyclic voltammetry electrochemical activation treatment to obtain the oxygen evolution electrode modified by the oxygen-containing anion. The invention provides an AEMWE anode gas diffusion electrode preparation route which is rapid, controllable, simple in method and relatively mild in synthesis condition, the oxygen evolution electrode prepared by the method has high activity and long-term durability under ampere-level current density, and has low cell pressure and long-term stability under AEMWE industrial conditions; the catalyst cost and the hydrogen production energy consumption are effectively reduced. The preparation method is suitable for cheap iron-based metal materials, different oxygen-containing anions can be introduced, and the preparation method has huge potential application value and wide application prospects.
Resumen de: CN120414394A
The invention discloses a hydrogen blast type power transmission line deicing device, and belongs to the technical field of power transmission line deicing, the hydrogen blast type power transmission line deicing device comprises a cavity fixedly connected with a power transmission line, and the cavity is internally provided with a first cavity and a second cavity; a rainwater collecting conduit and an ignition wire are arranged in the first cavity, and an openable and closable sealing cover is arranged at the bottom outlet; a water electrolysis module and a controller module are arranged in the second cavity; when the power transmission line is frozen, the water electrolysis module electrolyzes rainwater to generate oxygen and hydrogen, the oxygen and the hydrogen are filled into the first cavity to be stored, the controller starts the ignition wire to ignite the oxygen and the hydrogen in the first cavity, the oxygen and the hydrogen in the first cavity are exploded, generated high pressure pushes the sealing cover, and the power transmission line is frozen. A huge impact force is generated, so that ice attached to the power transmission line is peeled off, and the purpose of deicing the power transmission line is achieved; compared with traditional mechanical deicing and manual deicing, the labor cost, the maintenance cost and the operation cost are reduced.
Resumen de: CN120400909A
The invention discloses a tree-flower-shaped nickel-based amorphous composite material as well as a preparation method and application thereof, and belongs to the field of seawater electro-catalysis. The tree-flower-shaped nickel-based amorphous composite material comprises a NiM amorphous alloy wire, wherein M is composed of a transition metal element and a non-metal element; the NiM amorphous alloy wire comprises a NiM amorphous alloy wire and NiBPNOx nanoflowers, the outermost layer of the NiBPNOx nanoflowers is of an amorphous NiOx structure, the NiBPNOx nanoflowers are combined on the surface of the NiM amorphous alloy wire, and x refers to the content of oxygen elements. According to the structure, an amorphous alloy wire serves as a precursor, the outer layer of the amorphous alloy wire is wrapped with a NiBPNOx nanoflower structure, and the whole structure is of a tree-flower-shaped structure. The prepared tree-flower-shaped nickel-based amorphous composite material has the characteristics of high corrosion resistance, large surface area and high activity, and has excellent and stable hydrogen production performance in seawater electrocatalysis as an electrocatalyst. In addition, the preparation method provided by the invention is convenient and rapid, has strong industrialization, and provides good technical basis and material guarantee for seawater electrolysis hydrogen production application.
Resumen de: JP2025112925A
【課題】触媒層中に複数の空洞を形成できる技術を提供する。【解決手段】複数の触媒粒子、アイオノマー、溶媒、および臨界ミセル濃度以上の界面活性剤を混合し、界面活性剤の分子81によりミセル80が形成された触媒インクを調製する。そして、当該触媒インクを電解質膜の表面に塗布する。このようにして製造された触媒層から界面活性剤を除去することにより、触媒層中に複数の空洞を形成できる。【選択図】図4
Resumen de: JP2025112835A
【課題】電解スタックへの負荷変動を抑制して電解スタックの長期劣化を抑制できるようにする。【解決手段】再生可能エネルギー電源PSで得られる電力及び水素需要がともに所定の閾値よりも低い状況において、電力貯蔵部14から電解スタック16に電力を供給して水素の生成を行い、得られた水素を水素貯蔵部20に貯蔵する。【選択図】図1
Resumen de: CN120400929A
The invention relates to the technical field of hydrogen production, in particular to a wind power coupling proton exchange membrane water electrolysis hydrogen production method. According to the technical scheme, the method for producing hydrogen by electrolyzing water through the wind power coupled proton exchange membrane comprises the following steps: S1, acquiring a wind power signal in real time, and dividing the wind power signal into a low-frequency component and a high-frequency component according to a preset frequency division band; s2, dynamically distributing the low-frequency component to at least one target sub-pile in a plurality of PEM electrolytic cell sub-piles for operation; s3, absorbing the fluctuation energy of the high-frequency component through a hybrid energy storage module; and S4, based on a model prediction control MPC algorithm, optimizing the operation state of each sub-reactor, and enabling each sub-reactor to operate within 40-100% of the load in the efficient interval of the rated power of each sub-reactor. Through collaborative optimization of frequency-band-divided power distribution, multi-pile dynamic operation and an intelligent control strategy, comprehensive improvement of the hydrogen production efficiency, the equipment service life and the energy utilization rate is achieved in a wind power fluctuation scene.
Resumen de: CN120400870A
The present disclosure relates to a water electrolysis cell, and a stack of water electrolysis cells stacked with water electrolysis cells. Provided is a water electrolysis cell in which the concentration of hydrogen reaching the oxygen-generating electrode side is reduced to the concentration before the concentration is increased, with a simple configuration. The water electrolysis cell is provided with an electrolyte membrane, a catalyst layer, and a diaphragm through which a fluid flows, and generates hydrogen and oxygen by supplying water and applying a voltage thereto, in which a hydrogen reaction catalyst for promoting a reaction between hydrogen and oxygen is provided at a site where the generated oxygen and the remaining water flow on the surface of the diaphragm on the oxygen generation electrode side.
Resumen de: CN120400900A
The invention relates to a rare earth metal-containing multi-element composite catalytic material for hydrogen production by water electrolysis and a preparation method and application thereof, and discloses a rare earth metal-containing multi-element composite catalytic material for hydrogen production by water electrolysis and a preparation method and application thereof. The catalytic material comprises a quaternary metal compound, wherein the quaternary metal compound at least comprises a first metal, a second metal, a third metal and a rare earth metal; the first metal is selected from iron; the second metal is selected from at least one of copper and cobalt; the third metal is selected from at least one of tungsten and molybdenum; the rare earth metal is selected from at least one of cerium and lanthanum. The catalytic material disclosed by the invention is low in manufacturing cost, simple to prepare and high in oxygen evolution catalytic activity and stability.
Resumen de: CN120398648A
The invention provides a high-efficiency electric energy storage and zero-carbon emission technology for producing, storing and transporting dimethyl ether based on coupling of green hydrogen and a coal gasification process. Green hydrogen is prepared from renewable energy electrolyzed water and coupled with the coal gasification process to generate synthesis gas, then methanol is synthesized, and dimethyl ether is generated through dehydration. Dimethyl ether is stored in a liquid form and transported in a long distance, and is transported in a gas form during short-distance transportation. Efficient electric energy storage and zero carbon emission are achieved, and high economic and environmental benefits are achieved.
Resumen de: CN120400868A
The invention discloses a high-adaptability photovoltaic electrolytic hydrogen production system and an operation strategy, and belongs to the field of renewable energy hydrogen production. According to the system, water electrolysis hydrogen production is directly driven by a photovoltaic array, and efficient green hydrogen production is achieved in combination with dynamic power distribution and intelligent control. The system comprises a hydraulic supporting assembly, a viscous damper, energy flow testing equipment, a photovoltaic array, a universal spindle, an MPPT controller, a DC/DC converter, a dynamic power divider, a PEM electrolytic bath, a super capacitor, a high-pressure hydrogen storage tank and a water vapor treatment auxiliary device. The photovoltaic array adopts an adjustable angle design to maximally receive solar radiation, the MPPT controller optimizes output power through a perturbation and observation method, the DC/DC converter realizes voltage matching, and the dynamic power divider intelligently distributes electric power according to illumination intensity. The system is stable and efficient in operation, is particularly suitable for an illumination fluctuation environment, and provides a reliable solution for large-scale green hydrogen production.
Resumen de: CN120393678A
The invention provides an energy consumption optimization system and method based on a hydrogen purification process, and relates to the technical field of water electrolysis hydrogen production. The energy consumption optimization system based on the hydrogen purification process comprises a crude hydrogen input pipeline, a first waste heat recovery pipeline, a second waste heat recovery pipeline, a deoxidizing and cooling unit, a first hydrogen cooling and drying unit, a second hydrogen cooling and drying unit, a third hydrogen cooling and drying unit, a hydrogen conveying pipeline before cooling and a pure hydrogen output pipeline. The crude hydrogen input pipeline is communicated with the deoxidizing and cooling unit; the first waste heat recovery pipeline and the second waste heat recovery pipeline are communicated among the deoxidizing and cooling unit, the first hydrogen cooling and drying unit, the second hydrogen cooling and drying unit and the third hydrogen cooling and drying unit. The hydrogen purification device has the beneficial effects that the energy loss in the hydrogen purification process can be reduced, and the energy utilization efficiency is improved.
Resumen de: CN120400876A
The invention belongs to the field of hydrogen production through water electrolysis, and discloses an organic matter oxidative coupling hydrogen production electrolytic bath which comprises a frame assembly, a hydrogen production assembly is locked and connected in the frame assembly, and external electrolyte is introduced into the hydrogen production assembly through the frame assembly for electrolytic hydrogen production; the hydrogen production assembly comprises a middle polar plate arranged on the frame assembly, the two sides of the middle polar plate abut against and are attached to a plurality of left polar plates and right polar plates which are symmetrically arranged respectively, and an electrolysis cavity used for electrolysis hydrogen production is formed between every two adjacent polar plates; an electrolyte inlet is formed in the bottom end of the side wall of the outer frame and communicates with an inner cavity of the electrolysis cavity. An outlet assembly used for discharging electrolysis products is arranged at the top end of the frame assembly and communicates with the top end of the electrolysis cavity. The device is compact in structure, reasonable in design, convenient to use and low in processing and maintenance cost, can provide effective equipment support for organic matter oxidation coupling hydrogen production, is beneficial to improving the hydrogen production efficiency and the product discharge efficiency, and guarantees stable operation of t
Resumen de: CN120400902A
The invention provides a platinum-carbon catalyst taking hollow carbon nanospheres as a carrier and a preparation method of the platinum-carbon catalyst. The method comprises the following steps: adding a polymer monomer into a nano template dispersion liquid with a uniform size; then adding a proper amount of platinum salt into the solution to obtain a mixed solution, and stirring to react for 0.5-30 hours to obtain a reaction product; and annealing the reaction product, and then removing the nano template to obtain the platinum-carbon catalyst. The obtained platinum-carbon catalyst takes the hollow carbon nanospheres as a carrier and has a larger specific surface area, the platinum catalyst is loaded on the surfaces of the carbon nanospheres and can be in better contact with an electrolyte, and the obtained catalyst has good electrochemical activity and shows excellent electro-catalytic hydrogen evolution performance and oxygen reduction performance; and the related preparation method is simple and reliable, is suitable for preparation of an electrocatalytic hydrogen evolution electrode and an oxygen reduction electrode, and has a good application prospect in the fields of proton exchange membrane electrolytic cells, hydrogen fuel cells and the like.
Resumen de: CN120400897A
The invention discloses a supported water electrolysis catalyst, a preparation method thereof and a water electrolysis membrane electrode, and belongs to the technical field of water electrolysis hydrogen production. The preparation method comprises the following steps: obtaining a mixture, wherein the mixture comprises titanium dioxide, a reducing agent and chlorine salt; the mixture is calcined in a reducing atmosphere, so that at least part of titanium dioxide on the surface layer of the titanium dioxide is reduced into titanium, a carrier with a titanium layer on the surface is obtained, and the atom proportion of zero-valent titanium in the titanium element of the carrier measured through XPS is 40%-60%; and mixing the carrier with a soluble iridium source liquid phase to carry out replacement reaction, so that at least part of titanium replaces iridium ions into iridium nanoparticles and forms the iridium nanoparticles on the surface of the carrier. According to the preparation method, the supported water electrolysis catalyst with high catalytic activity and high structural stability can be prepared on the basis of low precious metal consumption.
Resumen de: CN120400875A
The invention provides a PEM hydrogen production bipolar plate, a preparation method thereof and an electrolytic bath, and the preparation method of the PEM hydrogen production bipolar plate comprises the following steps: (1) uniformly mixing polytetrafluoroethylene, bisphenol A epoxy resin and a solvent to obtain polytetrafluoroethylene slurry; (2) applying polytetrafluoroethylene slurry to the surface of the flow channel of the cleaned bipolar plate, and then performing heating treatment to form a polytetrafluoroethylene coating on the surface of the flow channel of the bipolar plate; and (3) carrying out laser ablation to remove the polytetrafluoroethylene coating on the surface of the runner ridge of the runner, then carrying out electroplating, and forming a metal coating on the surface of the runner ridge to obtain the PEM hydrogen production bipolar plate. The bipolar plate provided by the invention is simple in preparation process and low in cost, not only effectively reduces the use amount of noble metal, but also avoids oxidation corrosion of the region of the flow channel where the noble metal layer is not formed, prolongs the service life of the bipolar plate, and has excellent electrical properties.
Resumen de: CN120402794A
The invention discloses an efficient hydrogen production and hydrogen refueling station system coupled with an SOEC hydrogen production device. The efficient hydrogen production and hydrogen refueling station system comprises a photovoltaic unit, an SOEC electrolytic bath, a combustor, a water supply unit, a waste heat recovery unit, an ammonia hydrogen production unit and a hydrogen refueling unit. The photovoltaic unit supplies power to the SOEC electrolytic bath and the ammonia hydrogen production unit, and an anode outlet of the SOEC electrolytic bath is connected with the combustor. The ammonia hydrogen production unit comprises a liquid ammonia tank, an evaporator and an ammonia decomposition reactor, decomposed gas is purified by a temperature swing adsorption device, part of the gas enters a combustor for combustion, and part of the gas is output by a filling machine after being compressed and refrigerated. The waste heat recovery unit recovers waste heat of the combustor and the electrolytic cell, is used for preheating water of the water supply unit and supplying the water to the SOEC electrolytic cell, and meanwhile provides heat energy for the ammonia decomposition reactor. High-temperature SOEC electrolytic hydrogen production and ammonia decomposition hydrogen production are coupled, and waste heat gradient utilization is combined, so that the energy utilization rate of the system is remarkably increased, the hydrogen filling efficiency is optimized, the electro
Resumen de: FR3158721A1
Le projet a pour but de fournir à l’industrie des moteurs à explosion, un procédé alternatif à l’utilisation des carburants fossiles. Nous proposons à l’industrie un système de production in situ de l’hydrogène, pour donner suite à l’application de la réaction sodium eau (equation1)
Resumen de: CN120400881A
The invention provides a water electrolysis hydrogen production system and a load control method in order to solve the problems that in the prior art, a load adjustment method of an existing water electrolysis hydrogen production device is greatly influenced by load changes, adjustment is not easy for operators, pressure fluctuation of a hydrogen outer pipe is large, and waste is caused by frequent emptying of a hydrogen production system. The system comprises a plurality of electrolytic cells, a load control subsystem and a hydrogen storage tank, wherein the hydrogen storage tank is connected with external hydrogen using equipment through an outer pipe. The load control subsystem is connected with each electrolytic bath and the outer pipe, and ensures that the real-time pressure p of the outer pipe is within the range from the outer pipe pressure lower limit value SPL to the outer pipe pressure upper limit value SPH by adjusting the number m of the electrolytic baths in operation and the real-time loads of the electrolytic baths in real time, so that the adverse effect on the system and hydrogen utilization equipment caused by too high or too low pressure is avoided, and the service life of the hydrogen utilization equipment is prolonged. Safe and stable operation of the system is guaranteed, the electrolytic bath can be reasonably utilized, resource allocation is optimized, the hydrogen production efficiency is improved, and the intelligent control level of the system is in
Resumen de: CN120400893A
The invention discloses a two-dimensional material loaded graphene quantum dot catalyst as well as a preparation method and application thereof, and belongs to the technical field of electro-catalytic materials. Firstly, citric acid is used as a carbon source, thiourea is used as a nitrogen source, and graphene quantum dots are synthesized through a hydrothermal method. And then taking iron nitrate nonahydrate, cobalt nitrate hexahydrate, citric acid and urea as precursors, and growing the ferrocobalt layered double-metal hydroxide on the foamed nickel through a hydrothermal method. And finally, combining the ferrocobalt layered double hydroxides with the graphene quantum dots through secondary hydrothermal treatment so as to form the CoFe-LDH (at) N-GQDs/NF composite catalyst. The CoFe-LDH-coated N-GQDs/NF composite catalyst is used for hydrogen evolution by water electrolysis, and the overpotential of the catalyst is 95 mV when the current density is 10 mA/cm < 2 >; a time current curve shows that the catalyst still has good stability after being continuously tested for 100 hours.
Resumen de: WO2025042413A1
A method of running a water electrolyzer that can operate on seawater without a significant voltage rise. In some embodiments, the method includes the use of specific ionomers in the catalyst layer. In some embodiments, the method involves using a Break-In Procedure. In some embodiments, the method can include periodic interruption of the voltage to the AEM electrolyzer.
Resumen de: CN120400859A
The invention discloses a marine seawater desalination hydrogen production device with a self-cleaning function, which comprises a photovoltaic photo-thermal system for converting solar energy into electric energy and heat, the electric energy is used for driving a water electrolysis hydrogen production system and an electrochemical hydrogen compression system, and the heat is used for supplying heat to a photovoltaic-membrane separation seawater desalination system; the photovoltaic-membrane separation seawater desalination system absorbs seawater by using a capillary core, desalinates seawater by using heat of a photovoltaic photo-thermal system, and has a capillary core salt self-cleaning function in a non-desalinated seawater state; the fresh water collection system is used for installing the photovoltaic-membrane separation seawater desalination system and collecting fresh water; the water electrolysis hydrogen production system is used for electrolyzing the collected fresh water to produce low-pressure hydrogen; the electrochemical hydrogen compression system is used for purifying and compressing low-pressure hydrogen; and the heat exchange system is used for energy recovery and heat exchange. Through light-heat-electricity coupling driving, automatic salt cleaning in the seawater desalination process and energy gradient utilization in the high-pressure hydrogen output process can be achieved.
Resumen de: CN120400927A
The invention provides a high-selectivity composite diaphragm for seawater electrolysis hydrogen production and a preparation method of the high-selectivity composite diaphragm, and relates to the technical field of hydrogen energy and seawater resource utilization. The composite diaphragm comprises a matrix layer, a functional layer and a protective layer. The modifier is added to improve the interior of the diaphragm and the surface structure of the diaphragm, the ion selectivity of the diaphragm is improved by adding the ion selective material, efficient screening of Cl <->/OH <-> is achieved, and the Cl <-> rejection rate is larger than 99%; by reducing the contact angle of the diaphragm, the resistance of ions passing through the diaphragm is reduced, and the effect of reducing the surface resistance of the diaphragm is achieved; the matrix layer and/or the functional layer are/is optimally designed, the micro-nano fiber structure of the matrix layer provides mechanical support, and the bubble point pressure is larger than 5 bar; and an adhesive is added into the functional layer to enhance the interlayer binding force and prevent the coating from falling off. Therefore, the technical problems that an existing diaphragm is insufficient in chloride ion blocking capacity and low in ionic conductivity are solved, and the diaphragm is suitable for efficient and safe electrolytic hydrogen production by directly utilizing seawater.
Resumen de: TW202500506A
Provided are: a carbon nanotube molded body containing carbon nanotubes, wherein the specific surface area of the carbon nanotube molded body is 700 m2/g or more, the pore distribution of the carbon nanotube molded body is 3-15 nm, the tensile strength of the carbon nanotube molded body is 45 MPa or more, and the Young's modulus of the carbon nanotube molded body is 1600 MPa or more; and a method for producing the carbon nanotube molded body. Also provided are: an electrode for electrochemical water splitting that contains the carbon nanotube molded body and platinum supported on the carbon nanotube molded body and a method for producing the same; and an electrochemical water splitting device provided with the electrode for electrochemical water splitting.
Resumen de: CN120400888A
The invention discloses a preparation method of a photoresponsive composite catalyst. The method comprises the following steps: S1, obtaining a nickel salt solution, a molybdenum salt solution and a ferric salt solution; s2, mixing the nickel salt solution, the molybdenum salt solution and the iron salt solution to obtain a mixed solution; s3, the pretreated foamed nickel is obtained; s4, immersing the pretreated foamed nickel into the mixed solution, and carrying out hydrothermal reaction and washing and drying treatment to obtain a Ni-Mo-Fe precursor; and S5, the Ni-Mo-Fe precursor is subjected to Joule pyrolysis treatment, and NiFe/FMO is obtained. The invention further discloses a light external field assisted seawater electrolysis hydrogen production device which comprises a light field module and an electrolysis system. The light field module is formed by matching a 300W xenon lamp with an AM1.5 optical filter; and the electrolysis system is a three-electrode electrolysis system or a membrane electrode electrolytic bath. The photoresponsive electrocatalyst is designed, and a light field module is introduced to induce the cathode surface to generate a photo-generated asymmetric electric field, so that an OH <-> rapid diffusion channel is formed, and calcium and magnesium are inhibited from precipitating on the cathode surface. And meanwhile, the temperature of the electrolyte is effectively increased through the photothermal effect induced by the light external fie
Resumen de: CN120398088A
The invention provides a novel green hydrogen ammonia production cooling system and an ammonia production method. The system comprises a cooling nitrogen production module, a water electrolysis hydrogen production cooling module and an ammonia synthesis module, the cooled nitrogen preparation module is used for compressing nitrogen, air and the nitrogen-adsorbed gas to obtain compressed gas; cooling the compressed gas to obtain cooled gas; the water electrolysis hydrogen production cooling module is cooled through cooling gas; and the ammonia gas synthesis module is used for proportionally mixing the mixed gas prepared by the water electrolysis hydrogen production cooling module with the dried nitrogen, and synthesizing and collecting ammonia gas. In the embodiment of the invention, the nitrogen serves as one of synthesis raw materials of the ammonia gas and also serves as a coolant of the water electrolysis hydrogen production cooling module to cool each part in the water electrolysis hydrogen production cooling module, so that the traditional water cooling is replaced, the waste of water resources is reduced, the production process of the ammonia gas is simplified, and the synthesis cost of the green ammonia is reduced.
Resumen de: CN120400928A
According to the photovoltaic hydrogen production multi-electrolytic cell cluster control method provided by the invention, through efficient data acquisition, accurate data analysis, personalized control strategy formulation and intelligent cluster coordination control, optimal management of a multi-electrolytic cell cluster in a photovoltaic hydrogen production process is realized. Specifically, the system collects photovoltaic power grid energy data and operating parameters (such as current, voltage and temperature) of each electrolytic cell in real time, and analyzes and evaluates the working state of each electrolytic cell through deep data analysis, so that a control strategy is customized for each electrolytic cell. Besides, the system also adopts an optimized equipment proportion configuration scheme including specific proportion relations between the transformer and the rectifier cabinet, between the rectifier cabinet and the electrolytic bath, between the electrolytic bath and the gas-liquid separation device and between the gas-liquid separation device and the purification device, so that the operation cost and the capital expenditure are reduced, and the occupied area is reduced.
Resumen de: CN120413819A
The invention provides an energy storage system based on an anion exchange membrane electrolysis water hydrogen production and Ni-H2 battery. The energy storage system comprises an AEM water electrolysis device and a Ni-H2 battery device, a cathode of the AEM water electrolysis device is connected with a cathode of the Ni-H2 battery device, and the Ni-H2 battery device is charged by the AEM water electrolysis device. According to the system, a closed loop (hydrogen production-storage-utilization) for hydrogen production and storage is realized, and the energy conversion efficiency is improved.
Resumen de: CN120398297A
According to the seawater desalination and power generation system based on the wind-hydrogen energy, firstly, the wind power generator is used for capturing wind energy and converting the wind energy into electric energy, and then the converted electric energy is directly supplied through the micro-grid or stored through the power storage device; and then the electric energy transmitted by the micro-grid or the electric energy of the electricity storage device is converted into an electrolysis range which can be accepted by the electrolytic bath through the electric energy adjusting device, and the electric energy is used for electrolyzing the seawater through the electrolytic bath to generate hydrogen and oxygen. And the electrolyzed hydrogen is converted into electric energy and domestic direct water through a hydrogen fuel cell power generation system by a hydrogen storage tank or a hydrogen storage transport ship. The full-process coverage from clean energy to fresh water production is realized, the energy utilization rate and economical efficiency of the whole system are also remarkably improved, the purposes of high efficiency, energy conservation, environmental protection and no pollution are achieved, the operation cost is effectively reduced, and an innovative and feasible technical path is provided for solving global water resource and energy crisis.
Resumen de: CN120415132A
The invention discloses an LC resonance type double-staggered three-port photovoltaic direct electrolytic hydrogen production power supply system which structurally comprises a photovoltaic cell, one end of the photovoltaic cell is connected with one end of an inversion full bridge, and the other end of the photovoltaic cell is connected with an energy storage cell and then connected with the other end of the inversion full bridge; the other end of the energy storage battery is connected with one end of the energy storage side interlaced inductor, the other end of the energy storage side interlaced inductor is connected to midpoints of two bridge arms of the inverter full bridge, the midpoints of the two bridge arms of the inverter full bridge serve as alternating current output ends to be connected to the LC resonant cavity, and the rear stage of the LC resonant cavity is connected to the primary side of the high-frequency transformer. A secondary side of the high-frequency transformer is connected to midpoints of two bridge arms of the rectification full bridge, the rectification full bridge supports the capacitor C2 and is arranged at two ends of the rectification full bridge, one end of the output side interleaved inductor is connected to the midpoints of the two bridge arms of the rectification full bridge, and the other end of the output side interleaved inductor is connected with one end of the electrolytic cell. And two ends of the inverter full bridge are connected i
Resumen de: CN120398448A
The invention discloses a low-carbon cement production method for co-producing high-value chemicals, which adopts actual ingredients for cement production to produce cement clinker, fully considers the influence of impurity components in cement raw materials on follow-up synthesis, preheats the raw materials in a preheating separator I and a preheating separator II step by step, avoids advanced decomposition, and improves the production efficiency. The maximum in-situ reaction of in-situ CO2 and H2 is ensured, and harmful elements such as sulfur and chlorine are converted into the oxygen-enriched gas in advance and do not enter the subsequent synthesis step, so that the gas purification cost is reduced; a part of hydrogen is recycled, so that the problem that the conversion rate of the reverse water-gas shift reaction is relatively low is solved, CO2 is converted into carbon monoxide to the greatest extent, and subsequent synthesis of high-value chemicals is facilitated. According to the invention, low-carbon production of the cement clinker can be realized, CO2 generated by carbonate decomposition is completely converted into high-value chemicals, carbon emission in the cement industry can be reduced by more than 50%, gas and heat generated in each step are fully utilized, and utilization of resources and heat is realized to the greatest extent.
Resumen de: CN120400915A
The invention discloses a preparation method and application of an electrocatalytic water decomposition electrode with a 3D structure, and the method comprises the following steps: S1, taking foamy copper as a raw material, and preparing a foamy copper/Cu nanowire substrate with the 3D structure through a chemical oxidation method, a calcination method and an electroreduction method in sequence; and S2, placing the foamy copper/Cu nanowire substrate prepared in the step S1 in a mixed electrolyte containing transition metal M < 2 + > salt and rare earth Ln < 3 + > salt through an electro-deposition method, and depositing lamellar M/Ln (OH) 3 on the surface of the foamy copper/Cu nanowire array so as to obtain the foamy copper/Cu nanowire (at) M/Ln (OH) 3 electrode material with a 3D structure. The method is green, environment-friendly, mild and controllable; the prepared catalytic material has a special structure: the catalyst can be directly used as a water decomposition electrode, has double functions of producing hydrogen and oxygen, and can realize efficient complete water decomposition.
Resumen de: CN120397993A
The invention belongs to the technical field of analysis and detection, and particularly relates to a preparation method of low-background low-tritium water. The preparation method of the low-background low-tritium water provided by the invention comprises the following steps: electrolyzing a water source by using an SPE electrolysis system to obtain hydrogen with low tritium content; mixing the low-tritium-content hydrogen and the low-tritium-content oxygen, combusting, and condensing to obtain low-tritium-content condensed water; distilling the condensed water with low tritium content to obtain distilled water with low tritium content; the distilled water with the low tritium content is repeatedly subjected to the steps of electrolysis, combustion, condensation and distillation, and the low-background low-tritium water is obtained. According to the principle that hydrogen isotope electrolysis difficulty programs are different in the water electrolysis process, hydrogen with the lower tritium content generated by water electrolysis is collected and mixed with oxygen to be ignited to generate water vapor, liquid water is obtained through condensation and collection, impurities are removed through distillation, and water with the tritium content as low as possible is obtained. The low-tritium water prepared according to the method provided by the invention has an extremely low background level.
Resumen de: CN120400926A
The invention relates to the field of diaphragms, and discloses diaphragm cloth for electrolytic hydrogen production, the diaphragm cloth comprises a polymer woven fabric diaphragm and a functional coating coated on the surface of the polymer woven fabric diaphragm, and the functional coating comprises a high-molecular polymer, a composite additive, modified chitosan and an organic solvent; the composite additive is prepared by grafting 2-chloroethyl isocyanate to the surface of a composite filler and then reacting with sodium p-hydroxybenzenesulfonate; zirconium oxychloride octahydrate is used as a precursor, Zr < 4 + > is fixed on the surface of a modified halloysite nanotube with a polydopamine base layer formed on the surface through evaporation, and then nano zirconium phosphate is formed on the surface of the modified halloysite nanotube after phosphoric acid reacts with Zr < 4 + >. The modified chitosan is prepared by modifying succinic anhydride carboxylated polyvinyl alcohol microspheres and a condensing agent, and by adding the composite additive and the modified chitosan, the diaphragm cloth is endowed with good hydrophilicity and air tightness, has excellent performance in alkaline water electrolysis and is high in mechanical strength.
Resumen de: CN120400878A
The invention discloses a coupling liquid organic hydrogen storage coal-fired boiler hydrogen-doped combustion power generation system and an operation method thereof. The system comprises a liquid organic working medium addition/dehydrogenation reaction system, a hydrogen production system and a boiler combustion power generation and water collection system. The hydrogen production system directly decomposes water recovered by the boiler combustion power generation and water collection system into hydrogen and oxygen, the hydrogen enters the liquid organic working medium addition/dehydrogenation reaction system, the liquid organic working medium addition/dehydrogenation reaction system combines the hydrogen with liquid organic matters to realize safe storage and transportation, and the hydrogen is released when needed; and the released hydrogen enters a boiler combustion power generation and water collection system and is used for realizing mixed combustion of the hydrogen and the pulverized coal, and meanwhile, boiler tail flue gas waste heat is supplied to a liquid organic working medium addition/dehydrogenation reaction system to provide heat required by dehydrogenation. According to the invention, the waste heat of the boiler is used for providing reaction heat for the liquid organic working medium dehydrogenation reactor, so that the utilization rate of energy is improved, water generated by combustion of hydrogen and pulverized coal is recovered, and the demand on exte
Resumen de: CN118086964A
The invention belongs to the technical field of water electrolysis hydrogen production, and particularly relates to a water oxidation catalyst and a preparation method and application thereof. According to the method, a weak acid heterogeneous soaking system is manufactured through the hydrolysis effect of metal cations in a hydrolyzable metal salt solution, a slow action is conducted on the surface of the metal substrate, and the surface of the metal substrate can be partially etched while metal oxides on the surface are removed; the etched metal ions and the hydrolyzed metal ions are combined on the surface of the substrate to form an LDH catalyst structure, so that relatively high catalytic activity of the LDH catalyst structure is ensured; meanwhile, under the interface confinement effect, a compact transition layer structure is slowly formed on the interface of the metal substrate and the catalyst layer. The transition layer is used as a bridge between the metal substrate and the catalyst layer, has the same structure as LDH, is more compact in morphology, and completely covers the surface of the metal substrate, so that the LDH catalytic structure layer is firmly anchored on the surface of the metal substrate, and the OER catalyst has high activity and high stability under the condition of industrial current density.
Resumen de: CN120400898A
The invention discloses a preparation method and application of a bifunctional medium-entropy alloy catalyst for brine electrolysis hydrogen production. Belongs to the field of nano material preparation. The preparation method of the medium-entropy alloy catalyst comprises the following steps: by taking a copper foil as a carrier, electroplating different precursor metal salts to quickly synthesize a nano-flower-shaped quaternary medium-entropy alloy nano material FeCoNiRu/Cu with a self-supporting structure; various metals are beneficial to the synergistic effect among atoms, and the nano three-dimensional spherical flower-shaped porous structure is beneficial to rapid mass transfer and release of hydrogen and oxygen; the preparation process of the medium-entropy alloy catalyst is simple, the electrolyte can be recycled, and the prepared sample shows excellent electro-catalysis water decomposition hydrogen production performance in a saline solution; the composite material has excellent electro-catalysis oxygen evolution performance and full water splitting performance and super-long stability under high current density; compared with traditional electrodes with foamed nickel, carbon paper, carbon cloth and the like as carriers, the electrode has excellent application and popularization prospects in seawater electrolysis or high-salinity brine electrolysis.
Resumen de: AU2023396734A1
The present invention relates to an ammonia decomposition catalyst and a method for producing same and, more specifically, to an ammonia decomposition catalyst containing alumina (Al
Resumen de: CN120394002A
The invention relates to a method for improving catalytic hydrogen production performance by introducing anion vacancies into an Au/semiconductor heterostructure through electrochemical treatment, and belongs to the technical field of catalytic energy. According to the method, gold nanoparticles are used and loaded on semiconductor particles through sputtering, finally, electrochemical treatment is carried out on the composite material, anion vacancies are introduced, and a sample (called a Vc-Au/semiconductor) heterostructure obtained after electrochemical treatment is formed. In the electro-catalysis process, local electron enrichment of anion vacancies can promote high catalytic activity of the catalyst in electro-catalysis hydrogen evolution (HER). When different semiconductors are replaced for loading gold nanoparticles and anion vacancies are introduced through electrochemical treatment, obvious HER activity enhancement is shown. The smooth implementation of the invention provides a universal, simple, convenient and efficient strategy for regulating and controlling the efficiency of the electro-catalytic hydrogen production reaction, solves the problems of high temperature and high energy consumption caused by introducing vacancies in a traditional heat treatment mode, and provides greater possibility for industrialization in the field of electro-catalytic hydrogen production.
Resumen de: CN120400863A
The invention discloses an electrolytic water tank for producing hydrogen by electrolyzing water, and relates to the technical field of electrolytic water tanks, a main body mechanism comprises an electrolytic water tank body, the bottom of the electrolytic water tank body is fixedly communicated with a drain pipe, the surface of the drain pipe is fixedly connected with a valve, and the surface of the electrolytic water tank body is provided with a cleaning mechanism; according to the electrolytic water tank for producing hydrogen by electrolyzing water, the cleaning mechanism is arranged, a first gear ring drives a scraping plate to scrape on the inner wall of the electrolytic water tank body, so that impurities attached to the inner wall of the electrolytic water tank body are cleaned, and meanwhile, an impact block is in contact with the surface of the electrolytic water tank body and impacts on the surface of the electrolytic water tank body; the electrolytic water tank body can generate vibration in the cleaning process, so that a scraper blade is assisted to better clean the inner wall of the electrolytic water tank body, the electrolytic water tank body is cleaned more thoroughly, the cleanliness of the interior of the electrolytic water tank body after cleaning is guaranteed, and the cleaning efficiency is improved.
Resumen de: CN120400871A
The PEM water electrolysis hydrogen production system comprises a hydrogen storage tank, a PEM electrolytic bath, a water supply system and a power conversion device, the pure water input end of the PEM electrolytic bath is connected with the water supply system, the power input end of the PEM electrolytic bath is connected with the power conversion device, and the hydrogen output end of the PEM electrolytic bath is connected with the hydrogen storage tank; and the power conversion device is configured to adjust the output current based on the real-time pressure of the hydrogen storage tank, so that the hydrogen production load of the PEM electrolytic bath is controlled, and the pressure of the hydrogen storage tank is stable. The PEM water electrolysis hydrogen production technology is applied to the hydrogen production, storage and adding integrated hydrogen energy supply station, the real-time pressure of the hydrogen storage tank is collected, the output current of the power conversion device is adjusted through the PID algorithm, the hydrogen production load of the PEM electrolytic cell is controlled, the pressure of the hydrogen storage tank is stable, and meanwhile frequent starting and stopping of the electrolytic cell are avoided.
Resumen de: CN120400879A
The invention provides a system and a method for thermoelectric coupling synergistic catalysis of PET waste plastic conversion and coupling hydrogen production. The system comprises a PET pretreatment unit, a PET depolymerization unit, a terephthalic acid separation unit, a thermoelectric coupling catalysis unit, a product separation device and an automatic control unit. According to the system and the method for conversion and coupling hydrogen production of the PET waste plastics through thermoelectric coupling concerted catalysis, the problems of high energy consumption, low selectivity, equipment complexity and the like in a traditional PET treatment technology are remarkably solved by innovatively combining thermoelectric coupling concerted catalysis. By synergistically coupling thermocatalysis and electrocatalysis technologies, respective thermodynamic and dynamic bottlenecks in a traditional single catalysis technology are solved. The traditional thermocatalytic method generally needs high-temperature and high-pressure conditions, resulting in high energy consumption.
Resumen de: CN120303448A
The invention relates to a method for joining together stacks of elements, comprising the steps of: joining together sub-assemblies of elements individually; joining the subassemblies together by arranging a joint between each subassembly to form an element stack; a successive heating phase and a cooling phase are applied to the component stack, while at least one clamping action is applied to the component stack between two different heating and cooling phases.
Resumen de: CN120344719A
The invention relates to a bipolar plate for an electrolytic cell, the plate comprising, on at least one of its main faces: a first region extending circumferentially; a second region extending circumferentially so as to border the first region on the outside; a third region extending circumferentially so as to border the second region on the outside, each region being arranged on a perimeter of an associated major face. The invention also relates to a corresponding cell, an electrolytic cell stack and a method of assembly.
Resumen de: SA523440970B1
An energy storage system 10 converts variable renewable electricity (VRE) to continuous heat at over 1000°C. Intermittent electrical energy heats a solid medium. Heat from the solid medium is delivered continuously on demand. An array of bricks incorporating internal radiation cavities 4601 is directly heated by thermal radiation. The cavities 4601 facilitate rapid, uniform heating via reradiation. Heat delivery via flowing gas establishes a thermocline which maintains high outlet temperature throughout discharge. Gas flows through structured pathways within the array, delivering heat which may be used for processes including calcination, hydrogen electrolysis, steam generation, and thermal power generation and cogeneration. Groups of thermal storage arrays 209 may be controlled and operated at high temperatures without thermal runaway via deep-discharge sequencing. Forecast-based control enables continuous, year-round heat supply using current and advance information of weather and V
Resumen de: CN120400918A
The invention discloses a bimetallic-doped and phosphatized nickel-based catalyst and a preparation method thereof. The preparation method comprises the steps of pretreatment, high-temperature reaction, phosphatization and the like. Through the mode, the bimetallic-doped and phosphorized nickel-based catalyst and the preparation method thereof have the advantages that molybdenum, vanadium and phosphorus elements are loaded on the surface of the nickel net substrate, the phosphorus element with extremely high electronegativity and the molybdenum and the vanadium loaded on the surface of the nickel net generate a strong synergistic effect, an electronic structure of active sites on the surface of the nickel net is effectively adjusted, and the catalytic activity of the catalyst is improved; the hydrogen evolution and oxygen evolution performance is effectively improved, the stability is excellent, the preparation process is simple, precious metal is not doped, the cost is low, and the application prospect in the alkaline water electrolysis hydrogen production industry is wide.
Resumen de: CN120400912A
The invention provides an alkaline electrolytic water hydrogen evolution reaction nickel-based electrode and a preparation method and application thereof, and belongs to the technical field of catalyst materials. The alkaline electrolytic water hydrogen evolution reaction nickel-based electrode has a monatomic-nanocluster-nanoparticle-support multilevel structure, the multilevel structure takes a metal nickel net as a support, nickel is loaded on the metal nickel net in the form of particles, molybdenum oxide is dispersed on the nickel particles in the form of clusters, and the metal nickel net is supported on the support. The preparation method comprises the following steps: preparing molybdenum oxide clusters, anchoring platinum on the molybdenum oxide clusters in the form of single atoms, loading nickel particles on a metal nickel net by utilizing a plasma spraying method, generating the molybdenum oxide clusters on the nickel particles through thermal annealing treatment, and then loading platinum single atoms on the molybdenum oxide clusters by utilizing an electrodeposition method, therefore, the nickel-based electrode for the hydrogen evolution reaction of the alkaline electrolyzed water is obtained. According to the invention, the hydrogen evolution reaction electrode with a multi-stage structure is prepared from a microreaction mechanism for the first time, the preparation cost is low, industrial production can be realized, and the hydrogen evolution reaction electro
Resumen de: CN120400877A
The invention provides a water electrolysis system capable of ensuring cooling of a water electrolysis cell and suppressing deterioration of durability of the water electrolysis cell. A water electrolysis system for obtaining hydrogen from a hydrogen electrode by supplying water to an oxygen electrode of a water electrolysis cell and applying a voltage to the water electrolysis cell, the water electrolysis system having a cooling fluid path for supplying a cooling fluid different from the water supplied to the oxygen electrode to the water electrolysis cell through a flow path different from a flow path through which the water is supplied to the oxygen electrode.
Resumen de: CN120400914A
The invention discloses a manganese-doped modified non-noble metal-based hydroxide oxygen evolution electrocatalyst and a preparation method and application thereof, and belongs to the technical field of water electrolysis hydrogen production catalysts, the catalyst is composed of a manganese-doped modified non-noble metal hydroxide active phase and a conductive substrate, the preparation method comprises the following steps: ultrasonically cleaning a conductive substrate with acid, deionized water and ethanol respectively; the preparation method comprises the following steps: dissolving 2, 5-dicarboxyl terephthalic acid and transition metal salt in N, N-dimethylformamide, and preparing and reacting to obtain a precursor solution; pouring into a reaction kettle, reacting with a conductive substrate, and growing a non-noble metal hydroxide active phase with a nano structure on the surface of the conductive substrate; putting into a reaction kettle, dissolving manganese metal salt into methanol, adding into the reaction kettle, and carrying out solvothermal reaction; the catalyst has the advantages of being high in fineness, not prone to agglomeration, high in oxygen evolution reaction activity and good in catalytic performance, and can keep high activity and long-term stability under the actual working condition reaction temperature condition.
Resumen de: WO2025158319A1
A method and an apparatus for a cooling of an electroyzer unit is described. The apparatus receives a temperature value associated with ambient air in proximal to the electrolyzer unit. The apparatus compares the temperature value with a predefined temperature threshold. The apparatus controls a supply of a liquid air stream from an air separation unit to a first heat exchanger unit based on the comparison. The apparatus control the first heat exchanger unit to mix the liquid air stream with the ambient air. The mixing of the liquid air stream and the ambient air causes transfer of heat therebetween. The apparatus controls a cooling of the electrolyzer unit based on the mixing.
Resumen de: WO2025159402A1
The present invention relates to a catalyst for an ammonia decomposition reaction and a hydrogen production method using same. More specifically, the present invention relates to: a catalyst for an ammonia decomposition reaction which, by containing cesium and cerium in a cobalt-molybdenum composite nitride, exhibits excellent catalytic activity in the ammonia decomposition reaction and thus enables an improved ammonia conversion rate, and which shows minimal degradation in activity even after high-temperature and long-duration reactions, offering excellent long-term stability; and a hydrogen production method using the catalyst.
Resumen de: WO2025159940A1
Described is a system and method for green hydrogen production via electrolysis. The system includes a steam boiler unit (204) configured to produce a discharged waste water stream (200), an electrolysis unit (300) configured to produce hydrogen (302) and oxygen (304) from the discharged waste water stream (200); and a hydrogen storage unit (708) for storing a portion of the hydrogen (302) produced by the electrolysis unit (300) as a product.
Resumen de: WO2025159042A1
The purpose of the present disclosure is to provide an electrolytic cell stack capable of increasing the amount of product generated by electrolysis while suppressing the temperature rise of the cell stack. An electrolytic cell stack (101) according to the present disclosure comprises: an electrolysis unit cell (105) that has a hydrogen electrode containing Ni, an oxygen electrode, and a solid electrolyte membrane and is formed in the circumferential direction of a base tube; and an interconnector that electrically connects a plurality of electrolysis unit cells arranged in the axial direction of the base tube. When the distance between the ends of the oxygen electrode, oriented in the axial direction of the base tube, in each electrolysis unit cell is defined as the width W of the electrolysis unit cell, and the area on the base tube in which the plurality of electrolysis unit cells are arranged is divided into a first end portion (10), a central portion (11), and a second end portion (12) along the axial direction, the widths W1, W3 of the electrolysis single cells (105b, 105c) positioned in the first end portion and/or the second end portion is 1.5 to 3 times greater than the width W2 of the electrolysis unit cell (105a) positioned in the central portion.
Resumen de: WO2025156736A1
Provided in the present application are a multi-electrolytic-cell series-parallel hydrogen production control method and a power generation system. The method in the present application comprises: acquiring electrolysis power parameters of a plurality of electrolytic cells and a real-time generation power of a power generation system; and then, on the basis of the plurality of electrolysis power parameters and the real-time generation power, controlling the plurality of electrolytic cells to sequentially and repeatedly execute electrolysis start-stop operations, wherein each electrolysis start-stop operation comprises: comparing the magnitude of a target round startup output power with the magnitude of a rated minimum electrolysis power of a target electrolytic cell; on the basis of a corresponding magnitude determination, performing subsequent control operations; and then in the subsequent control operations, performing a corresponding control operation by means of determining whether the target round startup output power exceeds a danger warning threshold power. Thus, the hydrogen production efficiency and flexibility of the plurality of electrolytic cells in the hydrogen production power generation system are improved, the stability of the hydrogen production power generation system is improved, and the service life of the hydrogen production power generation system is prolonged.
Resumen de: DE102024200876A1
Es wird ein Verfahren zur Herstellung einer Elektrode (4) mit einem Edelmetall-Katalysator für die alkalische Wasserelektrolyse angegeben. Das Verfahren umfasst, (S1), das Bereitstellen des Elektrodensubstrates (1), (S2), das Bereitstellen eines Matrixmaterials (2) und eines Katalysatormaterial (3) als Ausgangsmaterialien für die Beschichtung, (S3), das Vermischen des Matrixmaterials (2) und des Katalysatormaterials (3), und in (S4) Beschichten des Substrates (1) mit dem Gemisch aus Matrixmaterial (2) und Katalysatormaterial (3) mittels Hochgeschwindigkeitsflammspritzens (HVOF). Weiterhin werden eine entsprechend hergestellte Elektrode (4), eine diese Elektrode umfassende elektrochemische Zelle (10) und ein Elektrolyseur (20) angegeben.
Resumen de: DE102024102600A1
Ein hybrides System zur Herstellung von Wasserstoff (60) unter Nutzung einer variablen Energiequelle (50) und einer Mischflüssigkeit (10) ist offenbart. Das hybride System umfasst ein Osmose-System (110), das eingerichtet ist, um in einem Beladevorgang, die Mischflüssigkeit (10) in ein Permeat (20) und ein Konzentrat (30) zu trennen, und in einem Entladevorgang, das Konzentrat (30) mit der Mischflüssigkeit (10) unter Bereitstellung osmotischer Energie (12) zu vermischen. Das System umfasst weiter ein Wasserelektrolyse-System (120), das eingerichtet ist, um unter Nutzung des Permeats (20) Wasserstoff (60) elektrolytisch herzustellen, und eine Steuereinrichtung (130), die eingerichtet ist, um das Osmose-System (110) zwischen dem Beladevorgang und dem Entladevorgang zu schalten durch ein Steuern folgender Funktionen des Osmose-System (110): Bereitstellung von Energie der variablen Energiequelle (50) für den Beladevorgang, und Bereitstellung der osmotischen Energie (12) als Energiequelle für das Wasserelektrolyse-System (120).
Resumen de: DE102024102758A1
Elektrolysevorrichtung (10) zur Erzeugung von Wasserstoff aus Wasser mit Hilfe von elektrischem Strom, mit einem Zellstapel (11) aus mehreren als Elektrolysezellen ausgebildeten Zellstapelelementen (12), mit einem ersten Drucksensor (28) zur Erfassung eines ersten wasserstoffseitigen Drucks, mit einem zweiten Drucksensor (29) zur Erfassung eines zweiten wasserstoffseitigen Drucks, und mit einem Steuergerät (30), welches abhängig von dem vom ersten Drucksensor (28) gemessenen ersten Druck, abhängig von dem vom zweiten Drucksensor (29) gemessenen zweiten Druck und abhängig von dem an die Elektrolysevorrichtung (10) zur Elektrolyse angelegten elektrischen Strom überprüft, ob die Elektrolysevorrichtung (10) eine Undichtigkeit aufweist.
Resumen de: DE102024102527A1
System aus mehreren in einem Gestell oder Regal (19) aufgenommenen Elektrolysevorrichtungen (10) zur Erzeugung von Wasserstoff aus Wasser mit Hilfe von elektrischem Strom, wobei jede Elektrolysevorrichtung (10) zumindest folgendes aufweist: einen Zellstapel (11) aus mehreren als Elektrolysezellen ausgebildeten Zellstapelelementen (12); sich gegenüberliegende Endplatten (14, 15), wobei der Zellstapel (11) aus den Zellstapelelementen (12) zwischen den Endplatten (14, 15) ange-ordnet und verpresst ist; mindestens einen an den Endplatten (14, 15) ausgebildeten Wasserzuleitungsanschluss (16), über welchen der jeweiligen Elektrolysevorrichtung (10) Wasser zuführbar ist, und mindestens einen an den Endplatten (14, 15) ausgebildeten Wasserableitungsanschluss (17), über welchen von der jeweiligen Elektrolysevorrichtung (10) Wasser und Sauerstoff abführbar ist. Am Gestell oder Regal (19) und/oder im Gestell oder Regal (19) und/oder in unmittelbarer Nähe zum Gestell oder Regal (19) ist mindestens ein Vorabscheider (20) für Sauerstoff verbaut, um aus dem von den Elektrolysevorrichtungen (10) abgeführten Wasser Sauerstoff abzuscheiden.
Resumen de: US2025243592A1
A water electrolysis electrode includes a conductive substrate and a layered double hydroxide layer. The layered double hydroxide layer is disposed on a surface of the conductive substrate. The layered double hydroxide layer includes two or more transition metals. The layered double hydroxide layer includes a chelating agent.
Resumen de: US2025243590A1
The invention relates to a novel frame for a PEM electrolysis cell and for a PEM electrolysis cell stack. The subject matter of the invention is the frame, a PEM electrolysis cell and stack-type PEM electrolysis devices, which comprise the frame according to the invention, preassembled components and methods for producing preassembled components and stack-type PEM electrolysis devices. The frame, PEM electrolysis cell and stack-type PEM electrolysis devices according to the invention are suitable for generating high-pressure hydrogen in combination with the use of thin proton exchange membranes. The invention is based on a novel frame- and sealing-concept. The invention also relates to a cover for stack-type PEM electrolysis devices.
Resumen de: US2025243589A1
To provide a water electrolysis cell which reduces the concentration of hydrogen reaching the oxygen generating electrode side before the concentration increases with a simple configuration. An electrolyte membrane, a catalyst layer, and a separator for flowing a fluid are provided. A water electrolytic cell for generating hydrogen and oxygen by supplying water and applying a voltage, wherein a hydrogen reaction catalyst for promoting a reaction between hydrogen and oxygen is provided at a site where oxygen generated and residual water flow on the surface of the separator on the oxygen generating electrode side.
Resumen de: US2025243591A1
A water electrolysis system capable of suppressing a decrease in durability of a water electrolysis cell by ensuring cooling of a water electrolysis cell is provided. In a water electrolysis system for obtaining hydrogen from a hydrogen electrode by supplying water to an oxygen electrode of a water electrolysis cell and applying a voltage to the water electrolysis cell, a cooling fluid path for supplying a cooling fluid different from that supplied to an oxygen electrode is provided to the water electrolysis cell by a flow path different from a flow path for supplying water to an oxygen electrode.
Resumen de: US2025243594A1
An embodiment may provide a metal-positive ion-MXene nanosheet hybrid composite. According to the embodiment, by providing a hybrid composite composed of metal particles/positive ions/MXene nanosheets, there is a feature that may provide a hydrogen evolution reaction catalyst having excellent electrochemical performance with a high current value and low overvoltage.
Resumen de: US2025243139A1
An integrated energy system including a power plant is discussed herein. In some examples, the integrated energy system may include at least one nuclear reactor and electrical power generation system configured to generate steam and electricity, a water treatment plant configured to produce Sodium Hydroxide (NaOH) from salt water, a Sodium Formate (HCOONa) production plant configured to receive the Sodium Hydroxide (NaOH) to produce Sodium Formate (HCOONa), a Thermal Decomposition reactor configured to receive the Sodium Formate (HCOONa) and configured to receive at least a first portion of the steam or at least a second portion of the electricity from the power plant to indirectly heat the Thermal Decomposition reactor to produce Hydrogen (H2), Carbon Dioxide (CO2), and Carbon Monoxide (CO) from the Sodium Formate (HCOONa), and a Methanol (CH3OH) reaction chamber configured to receive the Hydrogen (H2), the Carbon Dioxide (CO2), and the Carbon Monoxide (CO) to produce Methanol (CH3OH).
Resumen de: US2025243057A1
The present invention discloses a zero-carbon-emission device and process for generating hot air or high-temperature steam or producing pure water, including a gas storage unit, a gas conduct device, a reaction chamber, and a heating conduct device, where the gas storage unit is configured to store hydrogen and oxygen or air respectively; the gas storage unit is connected to the reaction chamber through the gas conduct device respectively, and the gas conduct device is configured to convey the oxygen or the air and the hydrogen of the gas storage unit to the reaction chamber; the reaction chamber is further provided with a hot and moist air outlet, and the hot and moist air outlet is connected to the heating conduct device; and the reaction chamber is provided with a plurality of layers of pipes that are connected in sequence.
Resumen de: US2025242312A1
The present disclosure is directed to a molybdenum iron composition that includes 55 to 60 weight percent MoFe2, 33 to 37 weight percent Mo5.08Fe7.92, and 5 to 10 weight percent MoO3 based on the total weight of the composition. The composition is in the form of nanosheets. A nanocomposite membrane including the molybdenum iron composition is also provided. The nanocomposite membrane includes 0.01 to 0.5% molybdenum iron composition by weight uniformly distributed in a polyvinylidene fluoride polymeric matrix based on a total weight of the nanocomposite membrane. The nanocomposite membrane of the present disclosure finds application in filtration of a contaminated feed mixture and for generating hydrogen.
Resumen de: US2025244729A1
A simulation system and method for hydrogen production by water electrolysis. The simulation system for hydrogen production by water electrolysis includes: a first simulation unit used for simulating a hydrogen production power system to obtain hydrogen production electrical parameters; a controller unit used for outputting a control instruction to control hydrogen production process parameters in a hydrogen production chemical system; a second simulation unit used for simulating the hydrogen production chemical system according to the hydrogen production electrical parameters and the control instruction so as to obtain a hydrogen production result; and a data interaction unit, the first simulation unit, the controller unit, and the second simulation unit being capable of performing data interaction by means of the data interaction unit. Joint simulation of complete chemical and electrical processes for hydrogen production by water electrolysis can be realized.
Resumen de: US2025247039A1
Aspects of the present disclosure are directed to an electrolysis chamber. In some aspects, the electrolysis chamber includes a floor and sidewalls defining an interior region configured to contain an electrolyte solution; a cation pod and an anion pod disposed in the interior region, each of the cation pod and the anion pod including a gas containment cap terminating at a respective gas vent port; a pod divider extending from the gas containment caps partway toward the floor so as to separate at least a portion of the cation pod from the anion pod; a plurality of vertically stacked cation electrolysis mesh screens arranged within the cation pod; and a plurality of vertically stacked anion electrolysis mesh screens arranged within the anion pod.
Resumen de: US2025246642A1
The present invention provides an oxygen evolution reaction catalyst, wherein the oxygen evolution reaction catalyst is an oxide material comprising iridium, tantalum and ruthenium: wherein the oxygen evolution catalyst comprises a crystalline oxide phase having the rutile crystal structure; wherein the crystalline oxide phase has a lattice parameter a of greater than 4.510 Å.
Resumen de: US2025246660A1
Described is a long-lasting, heavy-duty ion exchange membrane comprising a fluorinated ionomer, a CexM1-xOy nanoparticle, and optional additives; where x is 0.2-0.9, y is 1-3, and M is Zr, Gd, Pr, Eu, Nd, La, Hf, Tb, Pd, Pt, or Ni. Optional additives may include reinforcement layers, which may be embedded in the ion exchange membrane. Such membranes are formed from ion exchange polymer dispersions and are useful to form membrane assemblies for fuel cell or water electrolysis applications. The present membranes and membrane assemblies have improved chemical stability and durability in such applications.
Resumen de: US2025246641A1
An electrocatalyst including a substrate and CoxNiyFe2O4 nanoparticles, where x+y=1. The CoxNiyFe2O4 nanoparticles are doped with 0.01 weight percentage (wt. %) to 1.0 wt. % selenium (Se), based on the total weight of the CoxNiyFe2O4 nanoparticles. Further, the CoxNiyFe2O4 nanoparticles have a polygonal shape, and the CoxNiyFe2O4 nanoparticles are dispersed on the substrate to form the electrocatalyst.
Resumen de: AU2023408768A1
A method of hydrogen production includes providing a solution and immersing a device in the solution. The device includes a substrate having a surface, an array of conductive projections supported by the substrate and extending outward from the surface of the substrate, and a plurality of catalyst nanoparticles disposed over the array of conductive projections. The solution includes dissolved sodium chloride (NaCl).
Resumen de: WO2025157768A1
The invention relates to a facility (1) for producing dihydrogen, the facility comprising a water purification device (2), a heating device (3) for converting the purified water into steam, and an electrolyser (4) configured to produce at least one stream of dihydrogen from the steam. The heating device (3) is preferably configured to recover waste heat. The invention also relates to a corresponding method.
Resumen de: US2025236517A1
A dehydrogenation reaction device includes a chemical hydride storage unit including a chemical hydride storage tank, a reaction unit including an acid aqueous solution storage tank, and a dehydrogenation reactor configured to generate hydrogen by reacting a chemical hydride with an acid aqueous solution, and a hydrogen storage unit including a hydrogen storage tank configured to store the hydrogen produced in the dehydrogenation reactor. The dehydrogenation reactor includes a body portion made of a metal and a reinforcement portion surrounding the outer surface of the body portion and including fiber reinforced plastic (FRP).
Resumen de: KR20210001132A
The present invention relates to a catalyst complex for a fuel cell, comprising: a support including carbon (C); platinum (Pt) supported on the support; and an iridium (Ir) compound supported on the support, wherein the iridium compound includes at least one of iridium oxide satisfying chemical formula 1, IrO_x and iridium-transition metal oxide satisfying chemical formula 2, IrMO_x (M is a transition metal and may be selected from Fe, Co, Cu, and Ni), and x is 1 to 2.
Resumen de: WO2024116062A1
The present invention relates to a symmetrical separator membrane for electrolysis of alkaline water and with homogeneous distribution of the pores.
Resumen de: KR20250115635A
본 발명은 성능 및 내구성 향상을 위한 수전해 고분자 전해질 막의 제조방법에 관한 것이다. 본 발명은, 물을 전기분해하여 수소를 생성하는 수전해 장치에 사용되는 수전해 비불소 탄화수소계 고분자 전해질 막의 제조방법으로서, 비불소 탄화수소계 고분자 용액을 캐스팅하여 고분자 전해질 막을 형성하는 제막 단계; 상기 형성된 고분자 전해질 막을 건조시키는 건조 단계; 및 상기 건조된 고분자 전해질 막을 어닐링하는 어닐링 단계를 포함하는 수전해 비불소 탄화수소계 고분자 전해질 막의 제조방법을 제공한다. 본 발명에 따르면, PEM 수전해용 고분자 전해질 막의 성능과 내구성을 효과적으로 향상시킬 수 있다.
Resumen de: JP2025112252A
【課題】本発明は、CoPが担持されたリン化コバルト炭素複合粒子を提供することを目的とする。【解決手段】細胞を、リンのオキソ酸及びその塩からなる群より選択されるリン源と共存させた状態で、コバルト化合物と有機溶媒とを含む処理液中で含浸処理する工程と、前記含浸処理後の細胞を焼成する工程と、を含み、前記リン源を構成するリンの量が、前記細胞の野生型に含まれるリンの量よりも多い、リン化コバルト炭素複合粒子の製造方法。【選択図】なし
Resumen de: WO2025154484A1
The purpose of the present invention is to improve the safety of a hydrogen production plant. This hydrogen production plant (1) comprises: a solid oxide electrolysis cell (SOEC) (10) which produces a hydrogen-containing gas; and a discharge stack (30) into which the hydrogen-containing gas produced by the SOEC (10) is introduced and which discharges the introduced hydrogen-containing gas to air. The discharge stack (30) has a spray unit (32) which supplies, to the hydrogen-containing gas introduced therein, cooling water for cooling the hydrogen-containing gas.
Resumen de: DE102024102394A1
Elektrolysevorrichtung (10) zur Erzeugung von Wasserstoff aus Wasser mit Hilfe von elektrischem Strom, mit einem Zellstapel (11) aus mehreren als Elektrolysezellen ausgebildeten Zellstapelelementen (12), mit sich gegenüberliegenden Endplatten (14, 15), wobei der Zellstapel (11) aus den Zellstapelelementen (12) zwischen den Endplatten (14, 15) angeordnet und verpresst ist, mit an den Endplatten (14, 15) ausgebildeten Wasserzuleitungsanschlüssen (16), Wasserableitungsanschlüssen (17) und Wasserstoffanschlüssen (18), wobei an beiden Endplatten (14, 15) jeweils sowohl mindestens ein Wasserzuleitungsanschluss (16), über welchen im Betrieb der Elektrolysevorrichtung (10) dem Zellstapel (11) von beiden Endplatten (14, 15) aus gleichzeitig Wasser zuführbar ist, als auch mindestens ein Wasserableitungsanschluss (17), über welchen im Betrieb der Elektrolysevorrichtung (10) von dem Zellstapel (11) über beide Endplatten (14, 15) gleichzeitig Wasser und Sauerstoff abführbar sind, ausbildet ist.
Resumen de: WO2025160516A1
A system and method of making hydrogen from water. A reaction vessel is provided with an outer shell, a central shaft, and concentric inner tubes separated by annular spaces. Water is delivered to the annular spaces by a water pump through an inlet defined in the reaction vessel. The water courses along a tortuous flow path. That path begins at an inner annular space around a central shaft. It ends at an outer annular space. The water emerges from the reaction vessel through an outlet associated with a manifold. A vibratory stimulus is applied to the reaction vessel and water. Water molecules are dissociated into hydrogen molecules and oxygen atoms. These reaction products are delivered through the manifold along an effluent flow path to a receiving pressure vessel before deployment to a sub-assembly for harnessing clean energy.
Resumen de: WO2025160419A1
An integrated energy system including a power plant is discussed herein. In some examples, the integrated energy system may include a power plant configured to generate steam, a hydrothermal decomposition reactor configured to receive at least a portion of the steam (H2O) from the power plant to react with Methane (CH4) within the hydrothermal decomposition reactor to produce Hydrogen (H2) and Carbon Dioxide (CO2), a first separation unit configured to separate the Hydrogen (H2) and the Carbon Dioxide (CO2), a Solid Oxide Stack configured to receive at least a portion of the Carbon Dioxide (CO2) and to produce Carbon Monoxide (CO), a second separation unit configured to separate the Carbon Dioxide (CO2) from the Carbon Monoxide (CO), and a methanol synthesis reactor configured to receive at least a portion of the Hydrogen (H2) and at least a portion of the Carbon Monoxide (CO) to produce Methanol (CH3OH).
Resumen de: WO2025159903A1
A system for separating a fluid in the operation of an electrochemical system includes: a cathode separator configured to separate a fluid into a first stream having hydrogen gas and a second stream having water and dissolved hydrogen; and a makeup water tank. The makeup water tank is configured to: receive the second stream from the cathode separator; operate at a pressure that is greater than atmospheric pressure and less than an operating pressure of the cathode separator; and separate at least a portion of the dissolved hydrogen from the water via a reduction in pressure from the cathode separator to the makeup water tank to provide a purified water stream and hydrogen gas. The hydrogen gas from the makeup water tank is configured to be transferred out of the makeup water tank and the purified water stream is configured to be transferred out the makeup water tank.
Resumen de: WO2025157947A1
The present invention discloses an electrolyser system and a method for operating the electrolyser system. The electrolyser system comprises an electrolyser stack further comprising a cathode compartment and an anode compartment separated by a diaphragm. A catholyte inlet of the stack is configured for supplying catholyte to the cathode compartment of the stack and an anolyte inlet configured for supplying anolyte to the anode compartment of the stack. A catholyte outlet transports gas-electrolyte mixture from the cathode compartment to a hydrogen separator and an anolyte outlet transports gas-electrolyte mixture from the anode compartment to an oxygen separator. A pressure control unit is configured to establish a predefined differential pressure between the cathode compartment and the anode compartment of the stack by maintaining the pressure at the cathode compartment greater than the pressure at the anode compartment.
Resumen de: GB2637456A
An electrolyser system (10) comprising a heat storage unit (14) and an electrolyser (16) is described. The heat storage unit (14) comprises at least one heat source infeed. The electrolyser (16) comprises at least one electrolyser cell (20), a steam inlet and at least one off-gas outlet. The off-gas outlet is connected to the heat source infeed to heat the heat storage unit (14). The heat storage unit (14) is configured to use its stored heat to produce steam for feeding into the steam inlet and for generating electrical power, either one at a time or both at the same time. The invention also provides a system comprising an intermittent or variable electricity source (12) and an electrolyser system (10) as defined above. The intermittent or variable electricity source (12) can be configured to power the electrolyser (16) and to heat the heat storage unit (14) via a heating element, either both at the same time or individually.
Resumen de: EP4592426A2
This organic hydride generation system 1 is provided with: an electrolytic bath 2; a main power supply unit 56 that supplies power to the electrolytic bath 2; an auxiliary power supply unit 58 that supplies power to the electrolytic bath 2 independently of the main power supply unit 56; a detection unit 38 that detects the voltage of the electrolytic bath 2, the potential of an anode electrode 12, or the potential of a cathode electrode 16; and a control unit 10 that controls the supply of power to the electrolytic bath 2 on the basis of detection results of the detection unit 38. The control unit 10 controls the auxiliary power supply unit 58 to supply power to the electrolytic bath 2, when the voltage or potential is detected to be changed to a prescribed value during the operation stoppage of the organic hydride generation system 1 in which the power from the main power supply unit 56 is not supplied to the electrolytic bath 2.
Resumen de: EP4593128A2
Provided herein is a method for producing a cement material, said method comprising steps of: a. reacting sulfur dioxide and water to form a first acid, the first acid comprising at least one sulfur-containing anion; b. reacting the first acid and a first cement precursor to form a second cement precursor; wherein the second cement precursor comprises the at least one sulfur-containing anion; and c. converting the second cement precursor to the cement material. Also provided is a system for producing a cement material.
Resumen de: EP4593125A1
A solid oxide electrochemical cell (400) includes a solid oxide electrolyte (5), a fuel-side electrode (7) located on a first side of the solid oxide electrolyte (5), and an air-side electrode (3) located on a second side of the solid oxide electrolyte (5). The air-side electrode (3) includes a strontium getter material, a current collector layer (34) and a functional layer (32) located between the current collector layer (34) and the second side of the solid oxide electrolyte (5).
Resumen de: EP4592425A1
The present invention discloses an electrolyser system (100) and a method for operating the electrolyser system. The electrolyser system (100) comprises an electrolyser stack (101) further comprising a cathode compartment and an anode compartment separated by a diaphragm. A catholyte inlet (102) of the stack (101) is configured for supplying catholyte to the cathode compartment of the stack (101) and an anolyte inlet (103) configured for supplying anolyte to the anode compartment of the stack (101). A catholyte outlet (104) transports gas-electrolyte mixture from the cathode compartment to a hydrogen separator (106) and an anolyte outlet (105) transports gas-electrolyte mixture from the anode compartment to an oxygen separator (107). A pressure control unit (110) is configured to establish a predefined differential pressure (Δp) between the cathode compartment and the anode compartment of the stack (101) by maintaining the pressure at the cathode compartment greater than the pressure at the anode compartment.
Resumen de: WO2025125243A1
The invention relates to a method for producing an electrode (10) for use in alkaline electrolysis of water, the method comprising: providing a metal substrate (12); providing a coating material (26) comprising powder (28) consisting of a catalyst material (20), and comprising non-metal particles (24); and coating at least a portion of the substrate with the coating material. The invention also relates to electrodes produced in this way.
Resumen de: CN119547229A
The invention relates to a bipolar plate (100) for a chemical energy converter (200, 300). The bipolar plate (100) comprises:-a plurality of channels (101) for conducting an operating medium of the energy converter (200, 300),-a plurality of supply openings (103) for supplying the plurality of channels (101) with an operating medium,-a plurality of distribution channels (105) for distributing the operating medium onto the plurality of channels (101), each distribution channel (105) of the plurality of distribution channels (105) extends between a corresponding supply opening (103) of the plurality of supply openings (103) and a corresponding channel (101) of the plurality of channels (101), and wherein the distribution channels (105) of the plurality of distribution channels (105) extend between the corresponding supply opening (103) of the plurality of supply openings (103) and the corresponding channel (101) of the plurality of channels (101). Each supply opening (103) of the plurality of supply openings (103) has an at least partially curved edge region at least on a distribution channel side facing a corresponding distribution channel (105) of the plurality of distribution channels (105).
Resumen de: KR20250115305A
본 발명은 알카라인 수전해 셀에 사용되는 고활성 산소 발생 전극의 제조방법에 관한 것으로, 본 발명에 따르면, 니켈 전극의 표면에 수증기를 노출시키는 간단한 방법으로 니켈 전극의 표면에 NiOOH 및 Ni(OH)2를 포함한 수산화물 층의 형성을 유도하였으며, 형성된 수산화물 층 중 특히 NiOOH는 산소 발생 반응(OER)의 활성을 향상시키고 과전위를 낮추며, 전하 이동 역학을 개선하여 니켈 전극의 산소 발생 반응 성능 및 장기안정성을 현저하게 향상시키므로, 상기 수산화물 층이 형성된 니켈 전극은 수전해 산소 발생 전극으로서 유용하게 사용될 수 있다.
Resumen de: CN120226171A
The present disclosure relates to an electrochemical cell stack comprising solid state electrochemical cells (20), an electrically conductive separator (30); and a sealing element (40). The separator comprises: a central portion (31) having an oppositely recessed support surface (32) supporting the solid oxide cell, and a contact surface (34) opposite the recessed support surface contacting an adjacent solid state electrochemical cell; and a boundary portion (36) providing a relatively elevated top (37) and upstanding side walls (38). A sealing element (40) extends between an elevated top surface of the boundary portion and an opposing support surface (39) of an adjacent bulkhead. The spacing distance between the concave support surface and the contact surface of the adjacent separator, defined by the combined height of the sealing element and the upstanding side wall, is matched to the thickness of the solid state electrochemical cell.
Resumen de: WO2025159402A1
The present invention relates to a catalyst for an ammonia decomposition reaction and a hydrogen production method using same. More specifically, the present invention relates to: a catalyst for an ammonia decomposition reaction which, by containing cesium and cerium in a cobalt-molybdenum composite nitride, exhibits excellent catalytic activity in the ammonia decomposition reaction and thus enables an improved ammonia conversion rate, and which shows minimal degradation in activity even after high-temperature and long-duration reactions, offering excellent long-term stability; and a hydrogen production method using the catalyst.
Resumen de: AU2023290620A1
The disclosure relates to systems and methods for continuous hydrogen production using photocatalysis. Specifically, the disclosure relates to systems and methods for continuous hydrogen production using photocatalysis of water utilizing semiconductor charge carriers immobilized on removable carriers in the presence of a reducing agent such as tertiary amines.
Resumen de: US2022306559A1
A method for upgrading biogas to methanol, including the steps of: providing a reformer feed stream comprising biogas; optionally, purifying the reformer feed stream in a gas purification unit; optionally, prereforming the reformer feed stream together with a steam feedstock in a prereforming unit; carrying out steam methane reforming in a reforming reactor heated by means of an electrical power source; providing the synthesis gas to a methanol synthesis unit to provide a product including methanol and an off-gas. Also, a system for upgrading biogas to methanol.
Resumen de: JP2025111401A
【課題】アルカリ水電解用隔膜として使用した場合に、イオン透過性、イオン透過持続性およびガス遮蔽性に優れた効果を奏する、織物およびその製造方法を提供する。【解決手段】ポリフェニレンスルフィドを主たる成分とするマルチフィラメントを有する織物であって、前記マルチフィラメントの平均単糸直径が0.2μm以上5.0μm以下であり、かつ単糸本数が5000本以上400000本以下である、織物。【選択図】なし
Resumen de: US2025214034A1
Hydrogen gas purifier electrochemical cells, systems for purifying hydrogen gas, and methods for purifying hydrogen gas are provided. The cells, systems, and methods employ double membrane electrode (DMEA) electrochemical cells that enhance purification while avoiding the complexity and cost of conventional cells. The purity of the hydrogen gas produced by the cells, systems, and methods can be enhanced by removing at least some intermediate gas impurities from the cells. The purity of the hydrogen gas produced by the cells, systems, and methods can also be enhanced be introducing hydrogen gas to the cells to replenish any lost hydrogen. Water electrolyzing electrochemical cells and methods of electrolyzing water to produce hydrogen gas are also disclosed.
Resumen de: MX2025004437A
Electrochemical cell system (100) which comprises an electrochemical cells arrangement (10), a control unit (20) configured to operate the electrochemical cells arrangement (10) only as electrolytic cells or only as fuel cells, a heat unit (40), external to the electrochemical cells arrangement (10), which is thermally coupled to the electrochemical cells arrangement (10) and which is configured to alternately store heat from the electrochemical cells arrangement (10) to the heat unit (40) and supply heat from the heat unit (40) to the electrochemical cells arrangement (10), and a transfer arrangement (30) configured to alternately transfer heat from the electrochemical cells arrangement (10) to the heat unit (40) and from the heat unit (40) to the electrochemical cells arrangement (10).
Resumen de: CN120384301A
The invention provides a CoP/Ni5P4/FeP nano material as well as preparation and application thereof, and the CoP/Ni5P4/FeP nano material takes a carbon material as a carrier and contains CoP, Ni5P4 and FeP. The adopted transition metal phosphide has good conductivity and electrochemical stability, negative phosphorus atoms with strong electrostatic affinity are arranged in the transition metal phosphide, and the transition metal phosphide can be used as a proton acceptor and is beneficial to catalyzing the hydrogen production process; abundant active sites can be designed by means of morphology regulation, element doping, defect engineering and the like, for example, the superficial area of the catalyst can be increased by constructing different forms of catalysts, so that more abundant catalytic active sites are created, and particularly, an electrolyte diffusion path can be shortened and the active sites can be more effectively exposed by adopting a nanosheet structure; meanwhile, the conductivity is enhanced, and the catalytic efficiency is improved.
Resumen de: CN120390787A
An integrated process for hydrogenating olefins is described in which a hydrogen stream is generated from electrolysis of water. A water source is from a first reaction step in which a first feed stream comprising oxidized hydrocarbons is reacted to produce a first reaction product stream comprising olefins and a second reaction product stream comprising water. The second reaction product stream is electrolyzed to produce an electrolyzer product stream comprising hydrogen. Hydrogen is used to hydrogenate olefins. A paraffin stream may be obtained from the hydrogenated effluent.
Resumen de: CN120387276A
The invention discloses an optimal configuration method for multiple sets of hydrogen production electrolytic cells, which belongs to the field of electrolytic hydrogen production control and comprises the following steps: building an ALK single-cell model considering electric heating characteristics; building an ALK group operation model considering the rotation value; building a PEM model considering start-stop characteristics; based on the ALK single-tank model, the ALK group operation model and the PEM model, an electrolytic cell hydrogen production system large model in which an ALK hydrogen production system and a PEM hydrogen production system are operated in a combined mode is constructed, and dispatching operation is conducted in a value rotation mode; designing a target function for the large model of the electrolytic cell hydrogen production system; performing target optimization on the large model of the electrolytic cell hydrogen production system by adopting a sequential traversal method; and carrying out optimal configuration on the electrolytic cell hydrogen production system. According to the method, under the condition that the injection power curve of the electrolytic hydrogen production system is given, different ALK electrolytic cell grouping schemes and different matching modes of the ALK electrolytic cell and the PEM electrolytic cell are compared, and a combination mode with the excellent efficiency, the high stability and the high economical efficienc
Resumen de: CN120390829A
The present invention provides a small high-voltage electrolyzer for generating hydrogen and oxygen, the small high-voltage electrolyzer comprising: one or more cells each comprising a plurality of high-voltage electrolysis cells wherein the electrolysis cells of the respective cells are electrically connected in series; and a central electrolyte header functionally connected to each of the electrolytic cells for supplying a liquid electrolyte to the cell; a central hydrogen header connected to each of the electrolytic cells for discharging the generated hydrogen from the cells; a central oxygen header connected to each of the electrolytic cells for discharging the generated oxygen from the cells; the direct-current power supply is used for supplying power to each unit of the electrolytic bath which is connected in series; wherein the cells of the electrolytic cells connected in series are electrically connected in parallel.
Resumen de: CN120384299A
The invention discloses a specially vulcanized CoFe prussian blue as well as preparation and application thereof. The porous three-dimensional graded non-noble metal sulfide catalyst is prepared by taking a ferrocobalt Prussian blue analogue as a template through calcination treatment and vulcanization. The catalyst is of a cubic porous structure, has high porosity and good conductivity, and has excellent hydrogen evolution and oxygen evolution electrocatalytic activity in an alkaline medium. The invention aims to provide a Prussian-blue-like electrocatalyst subjected to special vulcanization, the Prussian-blue-like electrocatalyst is used as a working electrode for an electrochemical test, the result shows that the Prussian-blue-like electrocatalyst has good electrocatalytic activity, the OER overpotential is as low as 237 mV and the HER overpotential is 156 mV when the Prussian-blue-like electrocatalyst is 10 mA cm <-2 >, and the Prussian-blue-like electrocatalyst also shows good stability in an alkaline solution.
Resumen de: CN120384303A
The invention belongs to the technical field of hydrogen production catalysts, and discloses a preparation method of a water electrolysis hydrogen production catalyst, and the prepared catalyst comprises the following components: La2O3, NiO, CoO, TiO2 and MoS2. The preparation method specifically comprises the following steps: mixing raw materials; performing high-temperature sintering and atomic diffusion; performing crushing; the preparation method comprises the following steps: uniformly mixing raw materials, screening, performing high-temperature sintering and atomic diffusion on the uniformly mixed raw materials through an atmosphere furnace in the steps of high-temperature sintering and atomic diffusion, and specifically, performing atomic diffusion: diffusing La < 3 + > in La2O3 into NiO, CoO and TiO2 crystal lattices. Through high-temperature sintering and temperature-controlled diffusion, during high-temperature sintering, a rare earth element La < 3 + > is diffused into crystal lattices of NiO, CoO and TiO2, electron holes are introduced, the conductivity is enhanced, the adsorption energy of a hydrogen intermediate is optimized, in addition, due to the addition of MoS2, sulfur vacancies at the edge of MoS2 can stabilize the hydrogen intermediate and reduce the reaction overpotential, so that the activity of the catalyst is remarkably improved.
Resumen de: CN120384845A
The invention relates to the field of new energy, in particular to an offshore hydrogen and ammonia production system based on multi-energy complementation of wind, light and tide. The system is composed of a wind power generation unit, a tidal power generation unit, a photovoltaic power generation unit, an electric energy conversion device, an air nitrogen-making device, a seawater hydrogen-making device, a hydrogen-nitrogen ammonia-making device, an automatic control device, a system structure framework and an electric pod type propeller. The system structure framework comprises a net rack, a bottom plate, side plates, a top plate, stand columns, stairs, guardrails, hatch covers and boat anchors. The bottom plate, the side plates and the top plate are combined into a hull structure, the photovoltaic power generation units are arranged on the upper portion, the guardrails are arranged on the periphery, the electric pod type propellers are installed below, and the net racks are fixed on the periphery. Power generation units are installed in the middles of the vertical chord members of the net rack, wind power generation units are arranged above the sea surface, and tidal power generation units are arranged below the sea surface. The seawater hydrogen production device generates hydrogen, the air nitrogen production device generates nitrogen, and ammonia gas is synthesized in the hydrogen-nitrogen ammonia production device by utilizing electric energy generated by the power ge
Resumen de: CN120384307A
The invention provides a modified alkaline electrolytic water hydrogen production diaphragm and a preparation method thereof. The modified diaphragm comprises a base membrane loaded with a Cu < 2 + > complexed chitosan alkali-resistant ion conduction unit, and the Cu < 2 + > complexed chitosan alkali-resistant ion conduction unit is obtained by loading chitosan through the base membrane and soaking in a Cu < 2 + > complexed solution for complexing. By introducing a copper-chitosan complex structure, a stable ionic conduction channel is constructed in an alkaline environment, and the alkali resistance and ionic conductivity of the membrane are effectively improved. According to the modified alkaline diaphragm for hydrogen production by electrolysis of water, the problems of insufficient alkali resistance, limited ion transmission capability and the like of a diaphragm material in the prior art are solved, and a new solution is provided for preparing the diaphragm for hydrogen production by electrolysis of alkaline water with long service life, high efficiency and low cost.
Resumen de: CN120384308A
The invention provides an alkaline electrolytic water hydrogen production diaphragm based on zirconium oxide modification, the alkaline electrolytic water hydrogen production diaphragm comprises a support layer and a hydrophilic modified coating on the support layer, the hydrophilic modified coating is obtained by coating the support layer with a casting liquid prepared from modified zirconium oxide particles, a film-forming polymer and an organic solvent and then carrying out non-solvent induced phase inversion, the modified zirconium oxide particles are prepared by adding micron-sized zirconium oxide and alkali liquor into a ball mill for ball milling, and the particle size of the zirconium oxide subjected to ball milling treatment is 20-100nm. According to the method, the structure of the micron-sized zirconium oxide particles is regulated and controlled by combining a ball milling-alkali etching synchronous process. Through combination of ball milling treatment and alkali etching treatment, the dispersion degree and the reaction opportunity of the zirconium oxide powder can be effectively improved, and the efficiency of the etching process is remarkably improved. The obtained modified zirconium oxide particles endow the diaphragm with excellent hydrophilicity, alkali resistance and OH <-> ion conduction performance, and the diaphragm has excellent performance when being used as an alkaline electrolytic water hydrogen production diaphragm.
Resumen de: CN120386292A
The invention relates to a scheduling method and device for a hydrogen production electrolytic cell array of a new energy hydrogen production system. The new energy hydrogen production system comprises new energy power generation equipment and a hydrogen production electrolytic cell array, the scheduling method comprises the following steps: on the basis of a day-ahead declared electric quantity curve, a day-ahead predicted electric energy price sequence, an intra-day electric quantity curve, a real-time electric energy price sequence, a hydrogen price coefficient, electric energy consumed by each liter of hydrogen generated by an electrolytic bath, and a day-ahead predicted electric quantity curve of new energy power generation equipment, performing scheduling on the basis of a day-ahead declared electric quantity curve; an objective function of the day-ahead electrolytic cell array start-stop state optimization model is determined, and the objective function represents the intraday total income of the new energy hydrogen production system; and based on the target function, determining the start-stop state of each electrolytic cell included in the hydrogen production electrolytic cell array in each preset time period of the next day, and correspondingly controlling the start-stop of each electrolytic cell according to the determined start-stop state.
Resumen de: CN120384297A
The invention relates to the field of preparation of catalysts, and particularly discloses a PEM water electrolysis hydrogen production catalyst material and a preparation method thereof, a manganese-cobalt-samarium metal composite oxide is used as a carrier, iridium oxide is loaded, and a unique catalyst composite material structure is formed. In the preparation process, by accurately adjusting the metal adding proportion and optimizing the technological parameters and the preparation sequence, the low iridium content is ensured, and the activity and stability of the catalyst are remarkably improved. The manganese-cobalt-samarium metal composite oxide has good conductivity, iridium oxide is crystallized on the substrate, electron binding can be effectively improved, binding sites are increased, and the oxygen adsorption capacity is optimized. The cost is effectively controlled while the catalyst composite material keeps high catalytic performance, and a solid foundation is laid for popularization and application.
Resumen de: KR20250114200A
본 발명은 수소생산장치에 관한 것이다. 구체적으로 본 발명의 일 실시예에 따르면, 암모니아가스 공급구 및 개질가스 배출구가 형성되는 본체부; 상기 암모니아가스 공급구에 연결되고, 상기 암모니아가스 공급구로부터 암모니아 가스가 유입되는 암모니아가스 매니폴드; 상기 암모니아가스 매니폴드에 연결되고, 상기 암모니아가스 매니폴드로부터 유입된 상기 암모니아가스가 개질가스로 개질되기 위한 개질공간이 형성되는 개질부; 상기 개질부를 둘러싸도록 배치되어 상기 개질부를 가열시킴으로써, 상기 암모니아가스를 개질시키는 가열부; 및 상기 개질부와 상기 개질가스 배출구에 연결되고, 상기 개질부로부터 유입되는 상기 개질가스가 상기 개질가스 배출구로 유동되기 위한 통로를 제공하는 개질가스 매니폴드를 포함하는, 수소생산장치가 제공될 수 있다.
Resumen de: CN120384305A
The invention discloses a CoMoSe4-P-coated NF electrocatalyst as well as a preparation method and application thereof, and belongs to the technical field of electrocatalytic materials. The preparation method specifically comprises the following steps: (1) ultrasonically dispersing foamed nickel in acetone, hydrochloric acid and absolute ethyl alcohol solutions in sequence, and drying; (2) mixing cobalt nitrate hexahydrate, ammonium molybdate tetrahydrate and selenium powder, dissolving in water, and stirring; (3) carrying out hydrothermal reaction on the foamed nickel and the mixed salt solution, washing, drying and calcining; and (4) calcining with a phosphorus source, cooling to room temperature, washing, and drying to obtain the product. The CoMoSe4-P-coated NF electrocatalyst is synthesized by a hydrothermal and high-temperature calcination combined method, has the characteristics of uniform and regular morphology, uniform element distribution and the like, has good electrochemical performance, can realize efficient electrocatalysis of fully-decomposed water, including an electrocatalytic oxygen evolution (OER) reaction and an electrocatalytic hydrogen evolution (HER) reaction, and can also be used for preparing the CoMoSe4-P-coated NF electrocatalyst. And the method also has the advantages of low cost, mild reaction conditions, good stability, small resistivity and the like.
Resumen de: AU2023327787A1
The invention provides an electrolytic cell, comprising: a working electrode; a counter electrode; a liquid electrolyte in contact with a working surface of the working electrode; an acoustically transmissive substrate comprising at least a piezoelectric substrate portion; one or more conductive electrodes coupled to the piezoelectric substrate portion and configured to propagate a high frequency acoustic wave having a frequency of at least 1 MHz across the acoustically transmissive substrate when electrically actuated; and one or more power supplies configured (i) to apply a potential between the working electrode and the counter electrode sufficient to electrolytically react a species in the liquid electrolyte, thereby producing an electrolytic reaction product proximate the working electrode, and (ii) to electrically actuate the one or more conductive electrodes, wherein the working electrode is either located on the acoustically transmissive substrate or spaced apart from the acoustically transmissive substrate by the liquid electrolyte, and wherein propagation of the high frequency acoustic wave across the acoustically transmissive substrate in operation of the electrolytic cell stimulates the liquid electrolyte, thereby increasing the production efficiency of the electrolytic reaction product.
Resumen de: CN120167017A
A process for co-production of carbon monoxide and hydrogen is discussed herein, the process comprising: (a) providing an electrochemical reactor having an anode, a cathode, and a hybrid conductive membrane positioned between the anode and the cathode; (b) introducing a first stream into the anode, wherein the first stream comprises a fuel; (c) introducing a second stream into the cathode wherein the second stream comprises carbon dioxide and water wherein carbon monoxide is electrochemically generated from carbon dioxide and hydrogen is electrochemically generated from water. In an embodiment, the anode and the cathode are separated by the membrane, and both are exposed to a reducing environment during the entire operating time.
Resumen de: CN120366804A
The invention belongs to the technical field of water electrolysis hydrogen production, and relates to a light-heat-electricity coupled photovoltaic hydrogen production system which comprises a collecting lens, a solar Si battery, a semiconductor chilling plate and a proton exchange membrane electrolytic tank, the cold end of the semiconductor chilling plate is attached to the solar Si battery in a heat conduction mode, and the hot end of the semiconductor chilling plate is attached to the proton exchange membrane electrolytic tank in a heat conduction mode. The solar Si battery is electrically connected with a DC-DC converter; the DC-DC converter is electrically connected to a proton exchange membrane electrolytic tank, a gas outlet of the proton exchange membrane electrolytic tank is communicated with a hydrogen storage tank and an oxygen storage tank, and a water supply port of the proton exchange membrane electrolytic tank is communicated with a constant-temperature water tank; the cold end of the semiconductor chilling plate actively refrigerates, so that the photovoltaic working temperature is reduced, the hot carrier recombination effect is inhibited, the photoelectric conversion efficiency is improved, and the photovoltaic power generation efficiency is remarkably improved. And by utilizing the advantage of rapid heat dissipation of the semiconductor chilling plate, the system can support a higher concentration ratio, and the photovoltaic output power density is impro
Resumen de: CN120376691A
The invention discloses a hydrogen production and hydrogenation device and solid-state hydrogen storage type fuel cell device coupling system, which comprises a hydrogen production and hydrogenation device and a solid-state hydrogen storage type fuel cell device, the hydrogen production and hydrogenation device comprises a solar photovoltaic panel, a storage battery, an electrolysis mechanism, a heater and a first solid-state hydrogen storage module, the solar photovoltaic panel is connected with the storage battery, and the storage battery is connected with the electrolysis mechanism. The storage battery is connected with the electrolysis mechanism and the heater so as to supply power, the electrolysis mechanism is used for producing hydrogen and filling the hydrogen into the first solid hydrogen storage module for storage, and the heater is used for heating the first solid hydrogen storage module so as to improve the hydrogen storage pressure of the first solid hydrogen storage module; and the first solid hydrogen storage module is used for hydrogenating the solid hydrogen storage type fuel cell device. The system has the advantages of being simple in structure, low in cost and good in convenience.
Resumen de: CN120366823A
The invention discloses a preparation method of a phosphate radical intercalation NiCoFe-LDH catalyst and application of the phosphate radical intercalation NiCoFe-LDH catalyst in hydrogen production through water electrolysis, and belongs to the technical field of hydrogen production through electrolysis. The method comprises the following steps: carrying out electrochemical adsorption and electrochemical oxidation treatment on a NiCoFe-LDH material in a phosphating solution, so as to obtain the phosphate radical intercalation NiCoFe-LDH catalyst. The phosphating solution is a sodium hypophosphite monohydrate solution. According to the preparation method, phosphate radicals are successfully introduced between LDH material layers in a manner of taking the phosphate radicals as a precursor for the first time and an electrochemical oxidation manner, so that the phosphate radical intercalation nickel-cobalt-iron-based hydrotalcite with a nanosheet structure is prepared; the material is stable in structure and low in overpotential in the water electrolysis hydrogen production process, stable operation can be conducted for 400 h when the current density is 400 mA. Cm <-2 >, and the potential retention rate reaches 95% or above; the preparation method is simple, the used reagents are low in cost and rich in source, and the catalyst is suitable for macroscopic preparation and has popularization and application prospects.
Resumen de: CN120365957A
The invention relates to a process method for preparing green methanol by combining biomass with a combined heat and power generation technology. The method comprises the following steps: biomass pretreatment, gasification, waste heat utilization, desulfurization and dust removal, compression synthesis, methanol rectification, production of green electricity from byproducts through the combined heat and power generation technology, production of hydrogen and oxygen as energy supplementation through a water electrolysis device, and the like. The system comprises a pretreatment unit, a gasification unit, a waste heat utilization unit, a purification unit, a synthesis and rectification unit and an energy and by-product treatment unit. By means of reasonable process design and system integration, efficient conversion from biomass to methanol is achieved, the raw material utilization rate and the energy comprehensive utilization efficiency are improved, the product quality is guaranteed, pollutant emission is reduced, the green and environment-friendly requirements are met, and good industrial application prospects are achieved.
Resumen de: CN120366829A
The invention discloses an iron phosphide catalyst for separating hydrogen isotopes from PEM electrolyzed water and a preparation method of the iron phosphide catalyst, and the preparation method of the iron phosphide catalyst comprises the following steps: step 1, adding ferric salt and carbon black into a solvent according to a certain proportion, dispersing, and evaporating the solvent to obtain a uniform mixture of the ferric salt and the carbon black; 2, heating the mixture obtained in the step 1 at a high temperature, and introducing hydrogen-argon mixed gas to obtain an intermediate product Fe/C; and 3, carrying out high-temperature phosphorization on Fe/C and red phosphorus under the protection of argon to obtain the iron phosphide catalyst. The non-noble metal iron phosphide catalyst is synthesized to replace a traditional noble metal platinum carbon catalyst, the cost is reduced, and the hydrogen isotope separation factor is remarkably increased to 6-8; the cathode iron phosphide catalyst disclosed by the invention is high in stability, the performance of the cathode iron phosphide catalyst is almost not attenuated after long-time electrolytic reaction, an electric pile can stably run for about more than 2000 hours under the condition that the current density is 0.5 A/cm < 2 >, and the cathode iron phosphide catalyst has a very high industrial application value.
Resumen de: CN120366839A
The invention discloses a Ru/Ni-3DONMC catalyst as well as a preparation method and application thereof, and relates to the technical field of new energy materials and electrochemical catalysis. According to the invention, self-designed ordered SiO2 microspheres are self-assembled as a template, a nitrogen-doped carbon carrier with a three-dimensional ordered hierarchical pore structure is constructed, and a composite catalytic system with a multi-stage active center is successfully prepared by combining a bimetallic precursor adsorption impregnation and thermal reduction process. The catalyst disclosed by the invention shows excellent bifunctional catalytic performance in an alkaline medium; only 16 mV overpotential is needed in a hydrogen evolution reaction under the current density of 10 mA cm <-2 >, and the Tafel slope is as low as 40.54 mV/dec; and in a hydroxide reaction, the material has high limiting current density of 2.55 mA cm <-2 > and excellent mass activity. And it is powerfully proved that the intrinsic catalytic activity and long-term operation stability of the hydrogen-electricity reaction can be effectively improved through a monatomic-nanocluster cooperative regulation strategy.
Resumen de: CN120366837A
The invention relates to the technical field of catalyst preparation, in particular to an oxide nanosheet and a preparation method and application thereof. According to the preparation method provided by the invention, the reaction materials are mixed according to a specific molar ratio and calcined to a molten salt state, the obtained oxide nanosheet has good sheet structure characteristics, relatively high crystallinity and a stable crystal phase, the catalytic performance of the material is effectively enhanced, the potential of practical application in hydrogen production through water electrolysis is achieved, and the preparation method is suitable for industrial production. The catalytic activity can be further enhanced after boric acid modification; the process is simple, and large-scale preparation is facilitated. In the test provided by the invention, the IrOx nanosheet prepared by the invention has a stable rutile crystal phase structure, is relatively high in crystallinity and stable in crystal phase, and has certain performance in a water electrolysis device; the IrOx-H3BO3 modified by boric acid also has a rutile crystal phase structure, is relatively high in crystallinity and stable in crystal phase, and has better performance in a water electrolysis device compared with IrOx.
Resumen de: CN120366824A
The invention discloses a synthesis method of an iron-doped cobalt phosphide catalyst for hydrogen production through electrolysis of untreated seawater, and the method comprises the following steps: doping Fe into a cobalt-based catalyst precursor through a solution gel-vapor deposition method, and further phosphorizing in the vapor deposition process to form a Fe/Co2P structure; the high-performance seawater direct electrolysis oxygen desorption catalyst with a specific structure is obtained, and Fe doping is utilized to improve the catalytic activity of Co2P and inhibit dissolution of Co < 2 + >. The preparation method is simple and efficient, the electrode material has excellent OER activity and extremely high chlorine resistance in untreated natural seawater, only 1.866 V potential is needed when the current density in untreated neutral seawater reaches 100 mA. Cm <-2 >, and stable electrolysis can be carried out for more than 100 h. The catalyst has the advantages of low synthesis cost, high stability, good catalytic activity and the like, and provides a brand new material research and development thought for hydrogen production by electrolysis of alkalization-free seawater.
Resumen de: CN120366802A
The invention discloses an intermittent electrolysis supercritical water hydrogen production and electrochemical measurement system and method. The measurement system comprises a supercritical water electrolyzer, a direct current power supply device, a first supercritical water storage tank and a second supercritical water storage tank, wherein the bottom of the electrolysis supercritical water generator is provided with a heating device, the top of the supercritical water electrolyzer is provided with an outlet, the outlet is divided into two paths, one path is connected with the first supercritical water storage tank, and the other path is connected with the second supercritical water storage tank; the supercritical water electrolyzer is connected with the direct-current power supply device; and the supercritical water electrolyzer adopts a three-electrode system. The measuring system provided by the invention adopts a three-electrode system, and can accurately measure the electrochemical behavior of supercritical water electrolysis. The supercritical water reactor can better adapt to different electrochemical reduction oxidation systems, the cathode is subjected to an electrocatalytic hydrogen evolution reaction, the anode completes an organic matter oxidation reaction, and hydrogen production and organic matter treatment are synchronously achieved.
Resumen de: CN120366816A
The invention provides an oxygen evolution reaction catalyst, a preparation method thereof, a water electrolysis hydrogen production anode material and application, and belongs to the technical field of electrocatalysis and nanometer materials. The preparation method of the oxygen evolution reaction catalyst comprises the following steps: (1) growing a compact nickel sulfide nano material on a nickel substrate in situ through a hydrothermal method, a thermal injection method or a chemical vapor deposition method to obtain a nickel sulfide/nickel composite material; and (2) growing a ferro-nickel hydroxide nano material on at least one part of the surface of the nickel sulfide/nickel composite material by a hydrothermal method or an electrodeposition method to obtain the oxygen evolution reaction catalyst. The oxygen evolution reaction catalyst obtained by the preparation method has high efficiency and high stability, and is suitable for efficient and stable actual industrial hydrogen production by electrolysis of water.
Resumen de: CN120366835A
The invention discloses a NiMo nitride-based catalyst and a preparation method and application thereof, and belongs to the technical field of electrolyzed water hydrogen production catalysts.The NiMo nitride-based catalyst is characterized in that foamed nickel serves as a substrate, NiMo nitride microcrystals grow on the surface of the foamed nickel in situ, at least one noble metal elementary substance of ruthenium, osmium and iridium is loaded on the surface of the NiMo nitride microcrystals, and the NiMo nitride-based catalyst is prepared. The NiMo nitride-based catalyst is obtained. The microtopography of the NiMo nitride-based catalyst provided by the invention is an in-situ growth micron-sized nickel-molybdenum nitride microcrystal square column, a noble metal simple substance is attached to the surface of the microcrystal square column, and various catalytic active sites of the noble metal simple substance and the nickel-molybdenum nitride are distributed and constructed on a foamed nickel matrix, so that the catalytic efficiency of the catalyst is remarkably improved.
Resumen de: CN120366810A
The invention belongs to the technical field of water electrolysis hydrogen production membrane electrodes, and particularly relates to a membrane electrode with a continuous gradient distribution structure and a preparation method and application thereof. The composition design, the preparation process and the spraying technology of the catalyst slurry are innovatively combined, and accurate regulation and control of ionomer and porosity distribution in the membrane electrode are realized. The content of the ionomer in the membrane electrode can be in continuous gradient change by accurately regulating and controlling the liquid inlet components and the spraying rate, specifically, the content of the ionomer is gradually reduced layer by layer or the content of the ionic liquid is gradually increased layer by layer, so that a membrane electrode structure with the ionomer or porosity in gradient distribution is obtained. Compared with the prior art, the developed gradient distribution structure can effectively expose catalytic sites, so that the ion/electron transport resistance is reduced, the mechanical stability of the membrane electrode is also remarkably improved, and the key problems of low catalyst utilization rate, insufficient durability, low hydrogen production efficiency and the like of the traditional membrane electrode are effectively solved.
Resumen de: CN120368758A
The invention relates to a plate heat exchanger and a water electrolysis hydrogen production test system, and belongs to the technical field of water electrolysis hydrogen production batteries. The plate heat exchanger comprises a first end plate, a second end plate and a heat exchange piece, the heat exchange piece is arranged between the first end plate and the second end plate, a cold side flow channel is formed between the heat exchange piece and the first end plate, and a hot side flow channel is formed between the heat exchange piece and the second end plate; the heat exchanger comprises a plurality of heat exchange pieces, the two sides of each heat exchange piece are each provided with a plurality of flow channel structures arranged at intervals, each flow channel structure comprises a flow channel body and slope structures at the two ends, and the slope structures obliquely extend from the flow channel bodies to the surfaces of the heat exchange pieces. The plate heat exchanger is simple in structure, small in occupied area and high in pressure resistance, and the occupied area and the test cost of a water electrolysis hydrogen production test system are reduced. The invention further provides a water electrolysis hydrogen production testing system which comprises the plate heat exchanger.
Resumen de: CN120380198A
The invention relates to a method for the regeneration of an electrolyser, which is designed to produce hydrogen and oxygen by means of electrical energy and which comprises an electrolytic cell (1), the electrolytic cell (1) having a cathode chamber (2) and an anode chamber (3) which are separated from one another by a selective permeable membrane (6). The membrane (6) is coated on the side facing the cathode chamber (2) with a cathode electrode (7) and on the side facing the anode chamber (3) with an anode electrode (8), a voltage being applied between the cathode electrode and the anode electrode during the operation of the electrolyzer, the anode electrode (8) being made of a porous material, and the anode electrode (8) being made of a porous material. And the anode chamber (3) is filled with water or an aqueous electrolyte during the operation of the electrolyzer. In order to carry out the method, the following steps are carried out: reducing the voltage between the anode electrode (8) and the cathode electrode (7) to 0 V; -reducing the pressure in the anode chamber (3) to less than 2 bar (0.2 MPa); -removing water or aqueous electrolyte from the anode chamber (3); introducing hydrogen into the anode chamber (3); -refilling the anode chamber (3) with water or an aqueous electrolyte.
Resumen de: CN120366818A
The invention discloses a medium-entropy NiMoCoN catalyst and a preparation method thereof. The active component of the catalyst is NiMoCoN; wherein in the compound NiMoCoN, the atomic percent of each element is as follows: 23 to 31 at.% of Ni, 15 to 33 at.% of Mo, 26 to 48 at.% of Co and 10 to 19 at.% of N. The NiMoCoN catalyst disclosed by the invention has lower overpotential, lower Tafel slope, lower electrochemical impedance and long-term stability when being used as a water electrolysis hydrogen production catalyst; when the material is applied to alkaline liquid (1.0 M KOH), the hydrogen evolution overpotential under the current density of 10mA. Cm <-2 > can be as low as 94mV, and the material can stably work for more than 100 hours under the condition of 300mA. Cm <-2 >; in an acidic electrolyte (0.5 M H2SO4), the hydrogen evolution overpotential can be as low as 141mV under the current density of 10mA. Cm <-2 >, and the hydrogen evolution overpotential can stably work for more than 100 hours under the condition of 300mA. Cm <-2 >.
Resumen de: CN120377356A
The invention discloses an island electricity-hydrogen-water-heat combined supply system driven by wind, light and wave energy and an operation method, and belongs to the field of renewable energy utilization and island energy supply. The system comprises a reversible solid oxide battery module, a fresh water preparation module, a wind, light and wave energy power generation module, an air conveying module, a hydrogen conveying module and a system scheduling module, and can supply electricity, heat, water, hydrogen and the like to an island at the same time. When the renewable energy electric power is surplus, the rSOC module operates in an electrolysis mode, and the surplus renewable energy electric power is converted into hydrogen and water vapor; and when the renewable energy power is insufficient, the rSOC module operates in a power generation mode, and the hydrogen stored in the electrolysis mode is utilized to generate power. In addition, the rSOC operates at 600-1000 DEG C, and high-temperature waste heat of the rSOC can be efficiently recycled in a stepped mode. Therefore, electricity-hydrogen-water-heat poly-generation can be achieved, and the comprehensive utilization efficiency of island energy and the energy supply stability are remarkably improved.
Resumen de: CN120361830A
The invention belongs to the technical field of fuel oil production systems, and particularly relates to a system and a method for producing fuel oil from biomass through methanol. Biomass pyrolysis or gasification is adopted for power generation, obtained green electricity is used for electrolyzing water to prepare green hydrogen and green oxygen, green hydrogen and carbon monoxide and carbon dioxide obtained after biomass pyrolysis or gasification are synthesized into green methanol, and green oxygen can assist in biomass power generation; the synthesized methanol is further used for synthesizing propylene, and then propylene oligomerization is continued to obtain a long-carbon-chain hydrocarbon product; by-product water generated in the process of preparing methanol through carbon dioxide hydrogenation and preparing propylene through methanol passes through a water treatment system and is used as a raw material to return to the electrolyzed water unit, carbon dioxide generated in each process is used as a raw material to return to the unit of preparing methanol through carbon dioxide hydrogenation, and excessive carbon dioxide can obtain carbon monoxide through water gas reverse transformation; carbon monoxide can be used as a raw material for preparing methanol through hydrogenation, and can also be used as heat energy or used for power generation, so that a full-green process fuel oil fuel product synthesis technology is realized. Methanol preparation through carbon diox
Resumen de: CN120377383A
The invention provides an oil and gas field water-wind-light multi-energy fluctuating source network methanol electrolysis hydrogen production system, and relates to the technical field of oil and gas fields, the system comprises a processor, a water-wind-light power generation module, a frequency domain decomposition module, an electrolytic cell module, a methanol hydrogen storage and regeneration module, an energy storage device and a bidirectional inverter; the water-wind-light power generation module automatically adjusts the operation mode of power generation equipment based on the acquired meteorological data and hydrological data, and realizes power distribution through complementary power generation in the anti-fluctuation aspect; the frequency domain decomposition module divides the fluctuation input current according to frequency based on a wavelet packet decomposition algorithm and performs matching; the bidirectional inverter is used for converting direct current into alternating current, transmitting the alternating current to a power grid and transmitting redundant electric energy to the energy storage equipment for storage. The invention solves the problems of low efficiency, high energy consumption, short service life and insufficient safety of an electrolytic cell and an electrolytic hydrogen production method in the prior art under the condition of high fluctuation input of renewable energy sources.
Resumen de: CN120364722A
The invention provides a control method for synthesizing ammonia through hydrogen production by water electrolysis. When ammonia is synthesized through hydrogen and nitrogen, the reaction temperature is controlled through the following steps that S1, a CMAC model and a fuzzy PID controller are constructed; s2, acquiring a current temperature, calculating a difference value and a difference value change rate between the current temperature and a target temperature, and dynamically judging a current control state according to the difference value, the difference value change rate and parameters of the CMAC model; s4, inputting the difference value and the difference value change rate into a fuzzy PID controller to calculate a first control parameter u1; s4, inputting the difference value and the difference value change rate into the CMAC model to calculate a second control parameter u2; and S5, calculating a control parameter u through the following formula: u = p1 * u1 + (1-p1) u2, and determining values of p1 and p2 according to the current control state. The device is used for controlling the reaction temperature when hydrogen and nitrogen are synthesized.
Resumen de: FR3158519A1
Installation (1) de production de dihydrogène comprenant un dispositif (2) de purification d’eau, un dispositif (3) de chauffage de l’eau ainsi purifiée pour former de la vapeur d’eau et un électrolyseur (4) configuré pour former au moins un flux de dihydrogène à partir de la vapeur d’eau. Le dispositif de chauffage (3) étant de préférence configuré pour récupérer de la chaleur fatale. Procédé correspondant. Figure pour l’abrégé : Fig. 1
Resumen de: CN120361672A
The embodiment of the invention relates to the technical field of green chemical engineering, and provides a system and method for hydrogen production by coupling synthesis ammonia, and the system comprises a hydrogen production module, a hydrogen deoxidation module, an adsorption module and a synthesis ammonia module which are communicated in sequence; the nitrogen supply module, the regeneration module and the adsorption module are sequentially communicated; when one of the regeneration module and the adsorption module comprises a first adsorption tower, the other comprises a second adsorption tower; the hydrogen purification module, the nitrogen supply module and the ammonia synthesis module are all connected with the first adsorption tower and the second adsorption tower in a breakable/closable manner; the nitrogen supply module is used for supplying nitrogen, and the regeneration module is used for desorbing and regenerating the first adsorption tower or the second adsorption tower by using the nitrogen and supplying the nitrogen to the adsorption module; the hydrogen production module provides hydrogen to be purified, and the hydrogen deoxidation module purifies the hydrogen to be purified and then provides the purified hydrogen to the adsorption module; hydrogen and nitrogen are purified by the adsorption module and then are supplied to the ammonia synthesis module, so that the energy consumption and the system investment cost are at least reduced.
Resumen de: CN120366840A
The invention belongs to the technical field of hydrogen evolution catalysts, and particularly relates to a phosphorus-doped/nickel-molybdenum bimetallic mulberry-shaped synaptic sphere catalyst constructed by a one-step deposition method based on foamed nickel and application of the phosphorus-doped/nickel-molybdenum bimetallic mulberry-shaped synaptic sphere catalyst. A nickel source, a molybdenum source and a phosphorus source are used as reactants, a complexing agent is introduced to construct an electrodeposition system, foamed nickel is used as a carrier, the phosphorus-doped/nickel-molybdenum bimetallic mulberry-like synaptic sphere catalyst is obtained through electrodeposition, and the catalyst has extremely low hydrogen evolution overpotential (64 mV) under the current density of 10 mA cm <-2 >, is good in stability and easy to prepare, and can be used as a catalyst for preparing the mulberry-like synaptic sphere catalyst. The method has the characteristics of low cost and no pollution.
Resumen de: CN120366828A
The invention relates to the technical field of electro-catalysis, and provides a bifunctional CoMo/CoMoP-CF catalyst as well as a preparation method and application thereof. Comprising the following steps: respectively carrying out ultrasonic cleaning on foamy copper by using acid, ethanol and deionized water to obtain pretreated foamy copper; the foamy copper serves as a cathode, a platinum sheet serves as an anode, mercury/mercuric oxide serves as a reference electrode, the foamy copper, the platinum sheet and the mercury/mercuric oxide are immersed in the first electrolyte, electro-deposition is conducted under the constant-voltage condition, and CoMo-CF is obtained; and immersing CoMo-CF serving as a cathode, a platinum sheet serving as an anode and mercury/mercuric oxide serving as a reference electrode into the second electrolyte, and carrying out electro-deposition under a constant voltage condition to obtain the CoMo/CoMoP-CF catalyst. The CoMo/CoMoP-CF catalyst prepared by the invention shows relatively low hydrogen evolution overpotential and excellent catalytic activity in electro-catalytic hydrogen evolution, also shows relatively low overpotential and excellent catalytic activity in glucose oxidation reaction, and is a bifunctional catalyst applied to electro-catalytic hydrogen evolution and glucose oxidation.
Resumen de: WO2025154892A1
The present invention relates to a stepwise system and method for producing lime and hydrogen using by-product gypsum and the system includes: a lime production unit that reacts the by-product gypsum with a hydroxide of an alkali metal to produce lime and alkali metal sulfate, an electrolysis unit that electrolyzes the aqueous solution of the generated alkali metal sulfate to produce alkali metal hydroxide and hydrogen, and a circulation unit that provides the produced alkali metal hydroxide back to the lime production unit.
Resumen de: CN120377324A
The invention relates to the technical field of hydrogen production, in particular to a micro-grid hydrogen production system based on dynamic optimization control and a multi-mode energy scheduling method. Comprising a renewable energy power generation unit which comprises at least two distributed power supplies with different power generation characteristics; the multi-stage hydrogen production device is configured to receive the electric energy output of the renewable energy power generation unit and perform proton exchange membrane water electrolysis hydrogen production; the hybrid energy storage system comprises a super capacitor bank and a lithium ion battery pack which are connected in parallel to the direct current bus through a bidirectional DC/DC converter; the dynamic optimization controller is internally provided with a multi-time-scale coordination algorithm and is used for acquiring meteorological prediction data, load demand data and an energy storage SOC state in real time; the multi-mode scheduling module comprises three working modes including an island operation mode, a grid-connected operation mode and an emergency standby mode; according to the scheme, hydrogen production economy, equipment durability and power supply reliability can be considered at the same time.
Resumen de: CN120366836A
The invention discloses a preparation method and application of a wood-derived carbon supported metal sulfide catalyst with a modified hierarchical pore structure, relates to a preparation method and application of a hydrogen evolution catalyst, and aims to solve the technical problems that the electrochemical performance of the existing molybdenum disulfide and nickel-based sulfide catalyst is low, and the density of active sites of a wood-derived carbon carrier is low. The method comprises the following steps: immersing wood chips into a mixed solution of H3PO4 and ZnCl2, stirring, and carbonizing in a tubular furnace to obtain wood derived carbon with a modified hierarchical pore structure; and carrying out hydrothermal reaction on the modified wood-derived carbon and a mixed solution of sodium molybdate, nickel nitrate and thiourea to obtain the modified hierarchical pore structure wood-derived carbon supported metal sulfide catalyst. When hydrogen is produced by electrolyzing water in an alkaline electrolyte, the overpotential current density can reach 10mAcm <-2 > only by 101-157mV. The method can be used in the field of water electrolysis hydrogen production.
Resumen de: CN120367755A
The invention discloses an offshore wind power consumption and utilization system based on sharing integration, which comprises a wind power generation subsystem, a hydrogen production unit, a natural gas extraction unit, a floating platform, a land power centralized control station and a land energy storage station, and is characterized in that the wind power generation subsystem is electrically connected with the land power centralized control station and the floating platform; the floating platform is also connected with the hydrogen production unit and the natural gas extraction unit; the wind power generation subsystem comprises a seabed anchoring assembly and a wind turbine assembly connected with the seabed anchoring assembly, and the seabed anchoring assembly is connected with the corresponding offshore wind turbines in the wind turbine assembly through cables so that the multiple offshore wind turbines can be adjusted based on the wind direction to form polygonal distribution. The invention aims to effectively improve the offshore wind power generation efficiency.
Resumen de: CN120366813A
The invention provides a method for preparing a carbon-coated nickel-molybdenum nitride material through nitrogen-containing organic solvent steam modification, which is characterized by comprising the following steps of: loading a nickel-molybdenum composite oxide precursor layer on a nickel base through a liquid phase deposition method, heating the material subjected to liquid phase deposition to 400-800 DEG C in an argon atmosphere, and carrying out heat preservation for 2-3 hours, so as to obtain the carbon-coated nickel-molybdenum nitride material. Then inert gas is used as carrier gas to carry nitrogen-containing organic matter solvent volatile steam at a certain temperature to enter a tubular furnace, carbon and nitrogen species generated by decomposition of the organic matter solvent steam are used for reduction, nitrogen doping and carbon coating on the nickel molybdenum oxide precursor layer growing on the nickel base under the high-temperature condition, and the carbon-coated nickel molybdenum nitride material is prepared. The method provided by the invention is simple and easy to implement, and the prepared cathode material has excellent electrocatalytic hydrogen evolution activity and tolerance in alkaline electrolyzed water.
Resumen de: CN120377402A
The invention relates to the technical field of electric energy storage systems, in particular to an offshore wind-solar hydrogen storage ammonia-alcohol-based constructed network control system and a broadband oscillation prevention and control method. Comprising an offshore hydrogen-ammonia-alcohol base, an offshore wind power base, an offshore photovoltaic base, an inverter station, an offshore wind-light base energy storage power station, a booster station, a network-forming type energy storage phase modulation power station and a broadband oscillation control and prevention device, so that the network-forming type energy storage control research of the offshore wind-light hydrogen-ammonia-alcohol multi-energy complementary base can be carried out under low-short-circuit-ratio access and isolated network operation. Voltage, frequency and short-circuit capacity adjustment and inertia supporting are achieved, oscillation prevention and control can be carried out, and the purposes of power grid supporting optimization adjustment and oscillation treatment are achieved; meanwhile, multi-energy complementation is achieved, the energy utilization rate is increased, hydrogen ammonia alcohol can be prepared through green energy, and carbon emission is reduced. Therefore, the problems of poor frequency stability, weak voltage supporting capability, serious weak power grid oscillation and the like in the prior art are solved.
Resumen de: CN120366808A
The invention discloses AEM water electrolysis hydrogen production equipment which comprises a first end plate and a second end plate, the at least two small reaction chambers are arranged between the first end plate and the second end plate; each group of small reaction chambers comprises a cathode current-conducting plate, a cathode gas diffusion layer, an AEM film layer, an anode gas diffusion layer, a photocatalyst layer and an anode current-conducting plate which are arranged in sequence; wherein the anode current-conducting plate comprises a light-transmitting current-conducting plate; a light source assembly is attached to the side face of the anode current-conducting plate. Light output by the light source assembly to the side edge of the anode current-conducting plate enters the anode current-conducting plate and is transmitted to the photocatalyst layer through the anode current-conducting plate. On the basis that the anode current-conducting plate in the AEM water electrolysis hydrogen production equipment adopts the polar plate with light-transmitting and conductive functions, light can be guided into the anode current-conducting plate of each small reaction chamber, so that the working efficiency of the whole AEM water electrolysis hydrogen production equipment is improved.
Resumen de: US2025018339A1
Disclosed are a method and an apparatus for carbon capture coupled hydrogen production. The method includes: capturing low-concentration CO2 by a solution of an alkali metal hydroxide to obtain a low-concentration CO2 absorption solution; capturing high-concentration CO2 by a first portion of the low-concentration CO2 absorption solution to obtain a high-concentration CO2 absorption solution; and performing electrolysis by a second portion of the low-concentration CO2 absorption solution as a catholyte solution, using the high-concentration CO2 absorption solution as an anolyte, and using a non-ionic diaphragm as a diaphragm. According to the method, capture of CO2 in a wide concentration range can be realized; electrolysis is performed by a non-ionic diaphragm, to implement regeneration of an absorption solution coupled hydrogen production; capture costs of CO2 in a wide concentration range can be reduced; additional products of H2 and O2 can be obtained; and hydrogen production costs can be reduced.
Resumen de: WO2024133283A1
An alkaline water electrolyzer (200) comprising an electronic controller (Cont), a stack (Stck) of electrolysis cells each comprising an anode and a cathode, the electrolyzer being configured to contain an electrolyte made of an anolyte (AnKOH) and a catholyte (CathKOH), the electrolyzer comprising a system (Sys) controlled by the electronic controller (Cont) configured to maintain a concentration of an impurity in the electrolyte within a target range by measuring a characteristic representative of the concentration of the impurity in the electrolyte and, in response to the measured concentration of the impurity, add a quantity of the impurity into the electrolyte.
Resumen de: CN120366801A
The invention discloses a flowing type electrolysis supercritical water hydrogen production system and method. The system comprises a supercritical water generator, an electrolysis supercritical water reactor, a first after-reaction supercritical water storage tank, a second after-reaction supercritical water storage tank, a pressure monitoring device and a temperature monitoring device. Wherein the pressure monitoring device and the temperature monitoring device are arranged inside the electrolysis supercritical water reactor, and an outlet of the electrolysis supercritical water reactor is divided into two paths which are respectively connected with the first after-reaction supercritical water storage tank and the second after-reaction supercritical water storage tank. The electrolysis supercritical water generator is arranged, supercritical water is dissociated through an electrochemical means, and the supercritical water is converted into hydrogen and oxygen. The mode of electrolyzing the supercritical water can be carried out at higher temperature and pressure, and the method has remarkable advantages in the aspects of thermodynamics and dynamics. In addition, hydrogen generated in the supercritical water can be mutually dissolved with the supercritical water in any proportion instead of being separated out in the form of bubbles, and stable operation of the electrolysis process is facilitated. Under the conventional implementation working condition, the actual electric
Resumen de: CN120366807A
The invention discloses an integrated system and method combining photovoltaic power generation, continuous water taking from air and electrolytic hydrogen production. The system comprises a photovoltaic power generation module, a continuous multi-adsorption-bed module, a thermoelectric temperature control module, a condensation water collection module and an electrolytic hydrogen production module. The photovoltaic power generation module is connected with the thermoelectric temperature control module and the electrolytic hydrogen production module, the thermoelectric temperature control module is connected with the continuous multi-adsorption-bed module and the condensation water collection module, the continuous multi-adsorption-bed module is connected with the condensation water collection module, and the condensation water collection module is connected with the electrolytic hydrogen production module. According to the invention, the continuous device design is adopted, and the adsorption-desorption period of the continuous multi-adsorption-bed module is optimized, so that efficient water extraction from air is realized; the photovoltaic power generation module is arranged, all-weather operation of the photovoltaic power generation module is achieved, and more efficient active heating/cooling is achieved through double-end utilization of the thermoelectric temperature control module and heat transfer optimization of the condensation water collection module; and by arrang
Resumen de: CN120366805A
The invention provides a self-heating electrolytic tank and an electrolysis system, and relates to the technical field of electrolysis, the self-heating electrolytic tank comprises an air electrode, a fuel electrode and a self-heating electrolyte; the self-heating electrolyte is composed of a single-phase mixed ion or electronic conductive material or is formed by compounding an ion conductive material and an electronic conductive material, the self-heating electrolyte conducts ions and electrons at the same time, the ions comprise oxygen ions, hydrogen ions or hydroxyl ions, and the electrons comprise oxygen ions, hydrogen ions or hydroxyl ions. The electrons generate Joule heat when flowing through the electrolyte to maintain an electroendothermic reaction. The self-heating electrolysis system comprises the self-heating electrolytic tank, and further comprises a heat exchanger I and a heat exchanger II. According to the invention, Joule heat generated when electrons flow through the electrolyte is utilized to maintain the electrolysis endothermic reaction, so that spontaneous heating in the electrolysis process is realized, an external heater is not needed, and efficient thermal circulation is realized, thereby improving the energy efficiency of the system and prolonging the service life of the electrolytic tank.
Resumen de: CN120366845A
The invention provides an electrolytic cell series-connection group structure of a PEM electrolytic hydrogen production system and an electrolytic cell pipeline system. The electrolytic cell series-connection group structure comprises at least three PEM electrolytic cell modules, a switching end plate and a group control assembly. The upper end face of the switching end plate is fixedly connected with the lower end plate of one PEM electrolytic cell module, and the lower end face of the switching end plate is fixedly connected with the upper end plate of the other PEM electrolytic cell module; the grouped control assembly is connected with the PEM electrolytic cell modules and used for controlling whether two adjacent PEM electrolytic cell modules are connected in series in the PEM electrolytic hydrogen production system or not and controlling whether any one PEM electrolytic cell module is short-circuited or not. According to the flexible grouping technology provided by the invention, flexible connection and efficient grouping of a plurality of electrolytic cell modules can be realized.
Resumen de: WO2025154484A1
The purpose of the present invention is to improve the safety of a hydrogen production plant. This hydrogen production plant (1) comprises: a solid oxide electrolysis cell (SOEC) (10) which produces a hydrogen-containing gas; and a discharge stack (30) into which the hydrogen-containing gas produced by the SOEC (10) is introduced and which discharges the introduced hydrogen-containing gas to air. The discharge stack (30) has a spray unit (32) which supplies, to the hydrogen-containing gas introduced therein, cooling water for cooling the hydrogen-containing gas.
Resumen de: US2025236964A1
Electrochemical cells having recombination layers are disclosed herein. One example of such a cell includes a membrane configured to be positioned between an anode flow field and a cathode flow field of the electrochemical cell. The cell further includes a recombination layer configured to be positioned between the anode flow field and at least a portion of the membrane. The recombination layer includes a catalyst configured to assist in a formation of water from hydrogen gas and oxygen gas produced within the electrochemical cell, therein mitigating any hydrogen gas crossover from a cathode side to an anode side of the electrochemical cell.
Resumen de: WO2025154892A1
The present invention relates to a stepwise system and method for producing lime and hydrogen using by-product gypsum and the system includes: a lime production unit that reacts the by-product gypsum with a hydroxide of an alkali metal to produce lime and alkali metal sulfate, an electrolysis unit that electrolyzes the aqueous solution of the generated alkali metal sulfate to produce alkali metal hydroxide and hydrogen, and a circulation unit that provides the produced alkali metal hydroxide back to the lime production unit.
Resumen de: WO2025155611A1
Improved electrocatalysts for promoting a hydrogen evolution reaction (HER) or an oxygen evolution reaction (OER) from alkaline fresh water and seawater are disclosed. By incorporating metals, such as tungsten and rare earth elements, into the nickel molybdenum nitride framework, Ni1-xMoxN, the disclosed electrocatalysts demonstrate improved catalytic activity and stability compared to the original Ni&Ni0.2Mo0.8N catalysts, particularly under high-current alkaline conditions, in water electrolysis for hydrogen and oxygen production.
Resumen de: US2025235819A1
An environmental control system employs an electrolysis cell utilizing an anion conducting membrane. A power supply is coupled across the anode and cathode of the electrolysis cell to drive reactions to reduce oxygen and/or carbon dioxide in an output gas flow. A cathode enclosure may be coupled with the electrolysis cell and provide an input gas flow and receive the output gas flow. A first electrolysis cell may be utilized to reduce the carbon dioxide concentration in an output flow that is directed to a second electrolysis cell, that reduces the concentration of oxygen. The oxygen and/or carbon dioxide may be vented from the system and used for an auxiliary purpose. An electrolyte solution may be configured in a loop from a reservoir to the anode, to provide a flow of electrolyte solution to the anode. Moisture from the cathode may be collected and provided to the anode.
Resumen de: US2025236969A1
A Ni-based porous electrode for water electrolysis including (a) a macroporous substrate having a specific thickness, porosity level, and a pore size; (b) a first layer of a metal or a metal alloy as defined herein covering the macroporous substrate; and (c) a second layer of Ni, a Ni—X alloy or a Ni—X—Y alloy covering the first layer. The Ni-based porous electrode is free from Pt-group metals and rare-earths. A process for the manufacturing of the Ni-based porous electrode. The use of the Ni-based porous electrode to catalyze the hydrogen evolution reaction (HER). A water electrolyzer comprising the Ni-based porous electrode.
Resumen de: US2025236972A1
Electrolyzer for production of hydrogen gas and comprising a stack of bipolar electrodes sandwiching ion-transporting membranes between each two of the bipolar electrodes. Each bipolar electrode comprises two metal plates welded together back-to-back forming a coolant compartment in between and having a respective anode surface and an opposite cathode surface, each of which is abutting one of the membranes. The plates are embossed with a major vertical channel and minor channels in a herringbone pattern for transport of oxygen and hydrogen gases. The embossed herringbone pattern is provided on both sides of the metal plates so as to also provide coolant channels in a herringbone pattern inside the coolant compartment.
Resumen de: US2025236967A1
A membrane in an electrochemical cell may be electrically and/or mechanically coupled to a flow-field plate using a conductive adhesive. Various types of adhesives with conductive particles may be used. The adhesive may be selected such that in the fluid phase it is able to diffuse through one or more porous layers of the electrochemical cell, such as a liquid/gas diffusion layer. In some cases, the use of conductive adhesive may increase the level of inter-component electrical contact that may be achieved for a given level of compressive force applied between the components in the electrochemical cell.
Resumen de: US2025236978A1
A hydrogen generation system includes a plurality of cell stack assemblies, each including a plurality of cells. The cell stack assemblies are electrically connected in series. The cell stack assemblies each receive water and electricity and generate hydrogen as a result of an electrochemical reaction within the cells. The hydrogen is intended for use outside of the system and may be stored or transported to another location. A plurality of conduits carry water into and water, oxygen and hydrogen away from the cell stack assemblies. The conduits each include a dielectric section near the respective cell stack assembly to reduce or eliminate shunt currents between the cell stack assemblies. The dielectric sections may also serve to electrically isolate the cell stack assemblies from grounded portions of the system, such as a supporting frame.
Resumen de: US2025236961A1
A device (1) for performing electrolysis of water is disclosed. The device comprising: a semiconductor structure (10) comprising a surface (11) and an electron guiding layer (12) below said surface (11), the electron guiding layer (12) of the semiconductor structure (10) being configured to guide electron movement in a plane parallel to the surface (11), the electron guiding layer (12) of the semiconductor structure (10) comprising an InGaN quantum well (14) or a heterojunction (18), the heterojunction (18) being a junction between AlN material and GaN material or between AlGaN material and GaN material; at least one metal cathode (20) arranged on the surface (11) of the semiconductor structure (10); and at least one photoanode (30) arranged on the surface (11) of the semiconductor structure (10), wherein the at least one photoanode (30) comprises a plurality of quantum dots (32) of InxGa(1-x)N material, wherein 0.4≤x≤1. Also a system comprising such device is disclosed.
Resumen de: US2025236542A1
Provided is an apparatus and a method of desalinating saltwater and transporting hydrogen ions using Ion Concentration Polarization (ICP), the apparatus including: a channel part including a channel allowing saltwater to be introduced thereinto, an ion-selective membrane connected to the channel, and a cathode and an anode for applying a voltage to both ends of the channel; a desalination part configured to obtain fresh water from the saltwater with ionic substances removed from the saltwater by ion concentration polarization in a first region adjacent to the anode of the ion-selective membrane; and a hydrogen gas production part configured to concentrate the ionic substances in a second region adjacent to the cathode of the ion-selective membrane and to reduce hydrogen ions (H+) contained in the ionic substances.
Resumen de: US2025236541A1
Methods, systems and devices for removing iodide from an aqueous solution including submerging an iodophilic electrode in an aqueous solution containing iodide, applying a current to the electrode, and electrochemically oxidizing the iodide to iodine within the electrode. The electrode may include an iodophilic material and an electrically conductive material. It may also include a binder. The iodophilic material may be a starch, chitosan, carboxycellulose, cationic polymer, or an anion exchange membrane material, for example. After oxidizing the iodide to iodine within the electrode, the electrode may be submerged in a second solution and a current may be applied to reduce the iodine and release it from the electrode in the form of iodide into the second solution.
Resumen de: KR20250112431A
본 발명의 실시예에 따르면, 배터리로부터 공급되는 전력을 활용하여 물탱크에 저장되었던 물에 대한 전기 분해를 수행하는 전기 분해기; 및 상기 전기 분해기에 의해 생성된 수소를 운송 수단의 엔진 연소실과 연결되는 흡기 통로에 공급하는 수소 공급 장치를 포함하는, 운송 수단의 수소 발생 시스템이 제공된다.
Resumen de: KR20250112723A
원자력 발전소 수소생산 시스템 및 방법을 제공한다. 원자력 발전소의 수소생산 시스템으로서, 전력그리드; 증기를 생성하는 증기발생부; 상기 증기를 기반으로 동작하는 터빈; 상기 전력그리드와 연동되는 스위치야드; 상기 증기를 수요처로 이송하는 이송배관; 상기 터빈의 동작을 기반으로 동작하는 발전기; 상기 증기로부터 추기된 추기 증기를 수요처로 이송하는 추기배관; 상기 스위치야드로부터 공급되는 전기를 통해, 수소를 생산하는 저온 수전해부; 및 상기 스위치야드로부터 공급되는 전기와, 상기 추기 증기를 기반으로, 수소를 생산하는 고온 수전해부를 포함하고, 상기 수소생산 시스템은, 기 설정된 조건에 따라, 상기 저온 수전해부만 운전되는 제1 운전과, 상기 고온 수전해부만 운전되는 제2 운전과, 상기 저온 수전해부와 상기 고온 수전해부가 복합 운전되는 제3 운전이 각각 수행 가능하다.
Resumen de: US2025236517A1
A dehydrogenation reaction device includes a chemical hydride storage unit including a chemical hydride storage tank, a reaction unit including an acid aqueous solution storage tank, and a dehydrogenation reactor configured to generate hydrogen by reacting a chemical hydride with an acid aqueous solution, and a hydrogen storage unit including a hydrogen storage tank configured to store the hydrogen produced in the dehydrogenation reactor. The dehydrogenation reactor includes a body portion made of a metal and a reinforcement portion surrounding the outer surface of the body portion and including fiber reinforced plastic (FRP).
Resumen de: US2025236968A1
A method and an apparatus for a cooling of an electroyzer unit is described. The apparatus receives a temperature value associated with ambient air in proximal to the electrolyzer unit. The apparatus compares the temperature value with a predefined temperature threshold. The apparatus controls a supply of a liquid air stream from an air separation unit to a first heat exchanger unit based on the comparison. The apparatus control the first heat exchanger unit to mix the liquid air stream with the ambient air. The mixing of the liquid air stream and the ambient air causes transfer of heat therebetween. The apparatus controls a cooling of the electrolyzer unit based on the mixing.
Resumen de: WO2024163636A1
The present disclosure relates to methods of sequestering CO2 comprising a first cathodic chamber, performing a first alkaline process, a first anodic chamber, performing a first acidic process, and dechlorinating a solution by contacting the solution with a dechlorinating agent. Also provided herein are systems comprising a first cathodic chamber and a first anodic chamber.
Resumen de: WO2025153632A1
The disclosure concerns a hydroprocessing of a hydrocarbon feedstock (1) in which the acid gas stream with hydrogen sulphide (11) that is generated is cracked to generate a stream (13) comprising hydrogen and elemental sulphur. The disclosure relates also to an installation for removing one or more organic sulphur compounds from a hydrocarbon feedstock (1).
Resumen de: WO2025153178A1
A control system (30) for a hydrogen plant (100) is provided. The hydrogen plant includes: a first set of units (11,12…1n) comprising at least one hydrogen electrolyzer for producing hydrogen as a main product and heat as a byproduct; and a second set of units (21,22…2n) comprising at least one desalination unit partially operated with the heat from the at least one hydrogen electrolyzer for producing distilled water from raw water, and the at least one water desalination unit being configured to provide at least part of the distilled water to the at least one hydrogen electrolyzer. The control system is configured to control operation of the hydrogen plant including controlling electrical energy consumption of the at least one electrolyzer and the at least one desalination unit by adjusting at least one of: 1) electrical power supplied to the at least one hydrogen electrolyzer to produce the hydrogen and the heat; 2) flowrate of the at least part of the distilled water to the at least one hydrogen electrolyzer from the at least one desalination unit; and 3) heat transferred from the at least one hydrogen electrolyzer to the at least one desalination unit.
Resumen de: WO2025154357A1
This electrolysis cell comprises: an ion exchange membrane; a power feeder which is provided on the surface of the ion exchange membrane and composed of a plurality of fibers formed in a sheet shape; a binder layer that covers the surface of each of the fibers; and an electrode catalyst layer that contains catalyst particles at least partially protruding from the surface of the binder layer. At least a part of the catalyst particles protrudes from the surface of the binder layer. Consequently, the surface area of the exposed portion of the catalyst particles is increased, and thus the contact area with an electrolyte can be increased.
Resumen de: US2025236962A1
Herein discussed is a hydrogen production system comprising a first reactor zone and a second reactor zone, wherein both reactor zones comprise an ionically conducting membrane, wherein the first zone is capable of reforming a hydrocarbon electrochemically and the second zone is capable of performing water gas shift reactions electrochemically, wherein the electrochemical reforming reactions involve the exchange of an ion through the membrane to oxidize the hydrocarbon and wherein electrochemical water gas shift reactions involve the exchange of an ion through the membrane and include forward water gas shift reactions, or reverse water gas shift reactions, or both. In an embodiment, the membrane is mixed conducting. In an embodiment, the membrane comprises an electronically conducting phase and an ionically conducting phase.
Resumen de: US2025236960A1
Described is a system and method for green hydrogen production via electrolysis. The system includes a steam boiler unit configured to produce a discharged waste water stream, an electrolysis unit configured to produce hydrogen and oxygen from the discharged waste water stream; and a hydrogen storage unit for storing a portion of the hydrogen produced by the electrolysis unit as a product.
Resumen de: WO2025154724A1
A method for producing a hydrocarbon according to the present invention comprises: a step for making a metal and carbon dioxide react in water to produce a carbonate of the metal and hydrogen; and a step for making the hydrogen and carbon dioxide react in the water containing the carbonate of the metal to produce a hydrocarbon. The metal is at least one selected from the group consisting of iron, magnesium, zinc, and manganese.
Resumen de: JP2022111667A
To provide an intermediate for producing a dissimilar-metal doped cerium oxide, a method for producing the same, and a dissimilar-metal doped cerium oxide using the same, wherein the dissimilar-metal doped cerium oxide is excellent in uniformity of particle size distribution of a dissimilar-metal doped cerium oxide, and improves productivity by increasing a yield, and is excellent in flowability and can improve productivity and reaction efficiency when used as a catalyst.SOLUTION: An intermediate for producing a dissimilar-metal doped cerium oxide has a water content of 7.0 wt.% or less, wherein dissimilar metal is one or two or more metal selected from the group consisting of manganese, cobalt, iron and nickel.SELECTED DRAWING: None
Resumen de: KR20250111786A
본 발명의 일 실시예는, 선박에 탑재되며, 증기 또는 열을 생산하는 원자로와, 원자로의 출력을 조절가능한 출력조절부와, 원자로에서 생산되는 증기를 공급받아 발전가능하며, 선박에 전기를 공급하는 제1발전부와, 원자로에서 생산되는 열을 공급받아 발전가능하며, 선박에 전기를 공급하는 제2발전부 및 출력조절부와 전기적으로 연결되며, 제1발전부 및 제2발전부의 구동을 제어하는 제어부를 포함하며, 제어부는 원자로의 출력 크기와 미리 설정되는 출력값을 비교하여, 제1, 2발전부를 선택적으로 구동시키는 것을 특징으로 하는, 선박 발전 시스템 및 선박 발전 방법을 제공한다.
Resumen de: WO2024086793A1
The present disclosure provides a catalyst, methods of manufacturing the catalyst, and methods for using the catalyst for ammonia decomposition to produce hydrogen and nitrogen. The catalyst may comprise an electrically conductive support with a layer of one or more metal oxides adjacent to the support and at least one active metal adjacent to the layer. Methods are disclosed for deposition of metal oxide and active metal, drying and heat treatment. The method of using the catalyst may comprise bringing ammonia in contact with the catalyst in a reactor. The catalyst may be configured to be heated to a target temperature in less than about 60 minutes, by passing an electrical current through the catalyst. The method of using the catalyst may comprise bringing the catalyst in contact with ammonia at about 450 to 700 °C, to generate a reformate stream with a conversion efficiency of greater than about 70%.
Resumen de: CN119895081A
An electrolytic cell (1) for the electrolysis of chlor-alkali or alkaline water, comprising: two cell elements (2, 3), each cell element (2, 3) defining an electrode chamber (4, 5) by providing a rear wall (6) and side walls (7) of the electrode chamber (4, 5); electrodes (8, 9) respectively housed in each of the electrode chambers (4, 5); a sheet-like diaphragm (10) that extends in the height direction (H) and the width direction (W) of the electrolytic cell (1), is provided in a joint (11) between the two electrolytic cell elements (2, 3), and forms a partition wall (12) between the electrode chambers (4, 5); a plurality of support members (13) for supporting at least one electrode (8, 9) on a respective rear wall (6); wherein each support member (13) comprises: two support parts standing on the rear wall (6) and extending in the height direction (H) of the electrolytic cell (1); two feet (16, 17) connected to the respective supports (14, 15) at an angle and in planar contact with the rear wall (6); wherein the support portions of the support members (13) are connected to each other by means of an arch-shaped portion (18) bent outward toward the electrode (8) to be supported, and form an elastic bearing surface (19) for supporting the electrode (8); when the arch (18) deflects inwards, the bearing surface (19) increases.
Resumen de: AU2023342927A1
An electrochemical cell is disclosed having a porous metal support, a gas transport layer on the porous metal support, and an electrode layer on the gas transport layer. The gas transport layer is electrically conductive and has an open pore structure comprising a pore volume fraction of 20% by volume or higher and wherein the electrode layer has a pore volume fraction lower than the pore volume fraction of the gas transport layer. Also disclosed is a stack of such electrochemical cells and a method of producing such an electrochemical cell.
Resumen de: CN119908039A
Disclosed is an electrochemical cell having: a porous metal support; at least one layer of a first electrode on the porous metal support; a first electron blocking electrolyte layer of rare earth doped zirconia on the at least one layer of the first electrode; and a second bulk electrolyte layer of rare earth doped cerium oxide on the first electron blocking electrolyte layer. The first electron blocking electrolyte layer of rare earth doped zirconia may have a thickness of 0.5 mu m or more, and the second bulk electrolyte layer of rare earth doped ceria may have a thickness of 4 mu m or more.
Resumen de: WO2024114990A1
A hydrogen production apparatus (11) for an intermittent power source (2) and/or an electrical grid, comprising: a hydrogen production unit (19) for producing hydrogen gas (12), a first compressor unit (21) for compressing the produced hydrogen gas, a tank (25) for storing the gas compressed by the first compressor unit (21), the tank comprising a first and a second outlet (28, 29), a second compressor unit (30) fluidly connected to the second outlet of the tank (25) for compressing hydrogen gas supplied from the tank, the second compressor unit comprising an outlet (33), and a dispensing unit (34) fluidly connected to both the first outlet of the tank and the outlet of the second compressor unit for dispensing gas from the hydrogen production apparatus. By storing hydrogen gas in the tank, hydrogen gas can be dispensed from the hydrogen production apparatus even in times of low hydrogen production such as low wind speeds.
Resumen de: US2024109772A1
A system and method for producing hydrogen, including steam reforming elemental sulfur to generate hydrogen gas and sulfur dioxide, to give a mixture including hydrogen gas, sulfur dioxide, elemental sulfur gas, and water vapor, removing the elemental sulfur gas to give a process gas including the hydrogen gas, sulfur dioxide, and water vapor, and isolating the hydrogen gas or a hydrogen gas rich stream.
Resumen de: AU2023405114A1
The invention relates to an electrolysis system (1) comprising an electrolyser (3) for producing hydrogen (H
Resumen de: GB2637436A
Provided are a battery management system and method, and a related device. Battery units are controlled to be connected or disconnected in a power supply circuit by using collected operation parameters of the battery units, so that the safety in a battery operation process is improved. The battery management system comprises N first nodes, a second node, and M control switches. The first node is used for generating a first signal and sending the first signal to the second node, wherein the first signal comprises operation parameters of the battery unit corresponding to the first node in the power supply circuit. The second node is used for generating a second signal on the basis of the N first signals from the N first nodes and sending the second signal to the control switches. The control switch is used for controlling, on the basis of the second signal, the battery unit corresponding to the control switch to be connected or disconnected in the power supply circuit.
Resumen de: EP4588561A1
Provided is a composite including molybdenum disulfide and molybdenum trioxide, in which the molybdenum disulfide includes a 3R crystal structure, and the percentage content of a molybdenum trioxide-equivalent value (B) calculated from the molybdenum content determined by XRF analysis of the composite relative to the total mass of the composite is 5 to 90 mass%. Also provided is a catalytic ink including the composite and a solvent. Also provided is a method for producing the composite, including a calcination step of heating molybdenum trioxide in the presence of a sulfur source at a temperature of 400°C or less.
Resumen de: EP4589053A1
An electrode, including: a substrate that has a surface composed of at least one of nickel, nickel oxide, and nickel hydroxide; and scale-like protruding parts provided on the surface of the substrate.
Resumen de: EP4588562A1
An ammonia dehydrogenation catalyst, a method for producing same, and a method for producing hydrogen using same are disclosed. The disclosed ammonia dehydrogenation catalyst comprises: a zeolite having an intracrystalline cation; and an alkali metal and ruthenium impregnated on the zeolite.
Resumen de: EP4588957A1
A block copolymer including one or more segments containing an ionic group (hereinafter referred to as an "ionic segment(s)") and one or more segments containing no ionic group (hereinafter referred to as a "nonionic segment(s)"), wherein the ionic segment has an aromatic hydrocarbon polymer having a number-average molecular weight of more than 40,000 and 50,000 or less, and wherein the block copolymer satisfies the relation of: Mn3 / (Mn1 + Mn2) > 1.5, wherein Mn1 represents the number-average molecular weight of the ionic segment, Mn2 represents the number-average molecular weight of the nonionic segment, and Mn3 represents the number-average molecular weight of the block copolymer. Provided is a block copolymer and a polymer electrolyte material produced using the same, wherein the block copolymer has excellent proton conductivity even under low-humidity conditions, has excellent mechanical strength and physical durability, and has an excellent in-process capability.
Resumen de: EP4589054A1
An object of the present invention is to provide a polymer electrolyte membrane with excellent low gas permeability and chemical durability and to provide a membrane electrode assembly, a method for producing a membrane electrode assembly and a water electrolyzer. The polymer electrolyte membrane of the present invention includes a fluorinated polymer having ion exchange groups, a platinum-containing material, cerium oxide and a woven fabric.
Resumen de: MX2025002822A
The problem addressed by the present invention is that of specifying a process for producing lithium hydroxide which is very energy efficient. The process shall especially operate without consumption of thermal energy. The process shall be able to handle, as raw material, Li-containing waters generated during digestion of spent lithium-ion batteries. The LiOH produced by the process shall have a high purity sufficient for direct manufacture of new LIB. The process shall achieve a high throughput and have small footprint in order that it can be combined with existing processes for workup of used LIB/for production of new LIB to form a closed, continuous production loop. The process according to the invention is an electrolytic membrane process operating with a LiSICon membrane. It is a special aspect of the process that the electrolysis is operated up to the precipitation limit of the lithium hydroxide.
Nº publicación: EP4588566A1 23/07/2025
Solicitante:
HANWHA SOLUTIONS CORP [KR]
YONSEI UNIV UNIV INDUSTRY FOUNDATION UIF [KR]
Hanwha Solutions Corporation,
Yonsei University, University-Industry Foundation(UIF)
Resumen de: EP4588566A1
The present disclosure relates to a method of preparing a NiMo-MoO<sub>3-x</sub> porous nanorod catalyst based on a metal-organic framework and a non-precious metal alloy catalyst prepared thereby. The method of preparing a non-precious metal alloy catalyst according to the present disclosure can prepare an alloy catalyst that combine alloys and oxides and form nanorods having porosity and high surface area, and possess excellent HER performance close to that of commercial platinum catalysts.