Resumen de: US2025243592A1
A water electrolysis electrode includes a conductive substrate and a layered double hydroxide layer. The layered double hydroxide layer is disposed on a surface of the conductive substrate. The layered double hydroxide layer includes two or more transition metals. The layered double hydroxide layer includes a chelating agent.
Resumen de: US2025243590A1
The invention relates to a novel frame for a PEM electrolysis cell and for a PEM electrolysis cell stack. The subject matter of the invention is the frame, a PEM electrolysis cell and stack-type PEM electrolysis devices, which comprise the frame according to the invention, preassembled components and methods for producing preassembled components and stack-type PEM electrolysis devices. The frame, PEM electrolysis cell and stack-type PEM electrolysis devices according to the invention are suitable for generating high-pressure hydrogen in combination with the use of thin proton exchange membranes. The invention is based on a novel frame- and sealing-concept. The invention also relates to a cover for stack-type PEM electrolysis devices.
Resumen de: US2025243589A1
To provide a water electrolysis cell which reduces the concentration of hydrogen reaching the oxygen generating electrode side before the concentration increases with a simple configuration. An electrolyte membrane, a catalyst layer, and a separator for flowing a fluid are provided. A water electrolytic cell for generating hydrogen and oxygen by supplying water and applying a voltage, wherein a hydrogen reaction catalyst for promoting a reaction between hydrogen and oxygen is provided at a site where oxygen generated and residual water flow on the surface of the separator on the oxygen generating electrode side.
Resumen de: US2025243594A1
An embodiment may provide a metal-positive ion-MXene nanosheet hybrid composite. According to the embodiment, by providing a hybrid composite composed of metal particles/positive ions/MXene nanosheets, there is a feature that may provide a hydrogen evolution reaction catalyst having excellent electrochemical performance with a high current value and low overvoltage.
Resumen de: AU2023408768A1
A method of hydrogen production includes providing a solution and immersing a device in the solution. The device includes a substrate having a surface, an array of conductive projections supported by the substrate and extending outward from the surface of the substrate, and a plurality of catalyst nanoparticles disposed over the array of conductive projections. The solution includes dissolved sodium chloride (NaCl).
Resumen de: US2025242312A1
The present disclosure is directed to a molybdenum iron composition that includes 55 to 60 weight percent MoFe2, 33 to 37 weight percent Mo5.08Fe7.92, and 5 to 10 weight percent MoO3 based on the total weight of the composition. The composition is in the form of nanosheets. A nanocomposite membrane including the molybdenum iron composition is also provided. The nanocomposite membrane includes 0.01 to 0.5% molybdenum iron composition by weight uniformly distributed in a polyvinylidene fluoride polymeric matrix based on a total weight of the nanocomposite membrane. The nanocomposite membrane of the present disclosure finds application in filtration of a contaminated feed mixture and for generating hydrogen.
Resumen de: US2025244729A1
A simulation system and method for hydrogen production by water electrolysis. The simulation system for hydrogen production by water electrolysis includes: a first simulation unit used for simulating a hydrogen production power system to obtain hydrogen production electrical parameters; a controller unit used for outputting a control instruction to control hydrogen production process parameters in a hydrogen production chemical system; a second simulation unit used for simulating the hydrogen production chemical system according to the hydrogen production electrical parameters and the control instruction so as to obtain a hydrogen production result; and a data interaction unit, the first simulation unit, the controller unit, and the second simulation unit being capable of performing data interaction by means of the data interaction unit. Joint simulation of complete chemical and electrical processes for hydrogen production by water electrolysis can be realized.
Resumen de: US2025246642A1
The present invention provides an oxygen evolution reaction catalyst, wherein the oxygen evolution reaction catalyst is an oxide material comprising iridium, tantalum and ruthenium: wherein the oxygen evolution catalyst comprises a crystalline oxide phase having the rutile crystal structure; wherein the crystalline oxide phase has a lattice parameter a of greater than 4.510 Å.
Resumen de: US2025246660A1
Described is a long-lasting, heavy-duty ion exchange membrane comprising a fluorinated ionomer, a CexM1-xOy nanoparticle, and optional additives; where x is 0.2-0.9, y is 1-3, and M is Zr, Gd, Pr, Eu, Nd, La, Hf, Tb, Pd, Pt, or Ni. Optional additives may include reinforcement layers, which may be embedded in the ion exchange membrane. Such membranes are formed from ion exchange polymer dispersions and are useful to form membrane assemblies for fuel cell or water electrolysis applications. The present membranes and membrane assemblies have improved chemical stability and durability in such applications.
Resumen de: US2025243057A1
The present invention discloses a zero-carbon-emission device and process for generating hot air or high-temperature steam or producing pure water, including a gas storage unit, a gas conduct device, a reaction chamber, and a heating conduct device, where the gas storage unit is configured to store hydrogen and oxygen or air respectively; the gas storage unit is connected to the reaction chamber through the gas conduct device respectively, and the gas conduct device is configured to convey the oxygen or the air and the hydrogen of the gas storage unit to the reaction chamber; the reaction chamber is further provided with a hot and moist air outlet, and the hot and moist air outlet is connected to the heating conduct device; and the reaction chamber is provided with a plurality of layers of pipes that are connected in sequence.
Resumen de: GB2637456A
An electrolyser system (10) comprising a heat storage unit (14) and an electrolyser (16) is described. The heat storage unit (14) comprises at least one heat source infeed. The electrolyser (16) comprises at least one electrolyser cell (20), a steam inlet and at least one off-gas outlet. The off-gas outlet is connected to the heat source infeed to heat the heat storage unit (14). The heat storage unit (14) is configured to use its stored heat to produce steam for feeding into the steam inlet and for generating electrical power, either one at a time or both at the same time. The invention also provides a system comprising an intermittent or variable electricity source (12) and an electrolyser system (10) as defined above. The intermittent or variable electricity source (12) can be configured to power the electrolyser (16) and to heat the heat storage unit (14) via a heating element, either both at the same time or individually.
Resumen de: EP4592425A1
The present invention discloses an electrolyser system (100) and a method for operating the electrolyser system. The electrolyser system (100) comprises an electrolyser stack (101) further comprising a cathode compartment and an anode compartment separated by a diaphragm. A catholyte inlet (102) of the stack (101) is configured for supplying catholyte to the cathode compartment of the stack (101) and an anolyte inlet (103) configured for supplying anolyte to the anode compartment of the stack (101). A catholyte outlet (104) transports gas-electrolyte mixture from the cathode compartment to a hydrogen separator (106) and an anolyte outlet (105) transports gas-electrolyte mixture from the anode compartment to an oxygen separator (107). A pressure control unit (110) is configured to establish a predefined differential pressure (Δp) between the cathode compartment and the anode compartment of the stack (101) by maintaining the pressure at the cathode compartment greater than the pressure at the anode compartment.
Resumen de: US2025214034A1
Hydrogen gas purifier electrochemical cells, systems for purifying hydrogen gas, and methods for purifying hydrogen gas are provided. The cells, systems, and methods employ double membrane electrode (DMEA) electrochemical cells that enhance purification while avoiding the complexity and cost of conventional cells. The purity of the hydrogen gas produced by the cells, systems, and methods can be enhanced by removing at least some intermediate gas impurities from the cells. The purity of the hydrogen gas produced by the cells, systems, and methods can also be enhanced be introducing hydrogen gas to the cells to replenish any lost hydrogen. Water electrolyzing electrochemical cells and methods of electrolyzing water to produce hydrogen gas are also disclosed.
Resumen de: EP4592426A2
This organic hydride generation system 1 is provided with: an electrolytic bath 2; a main power supply unit 56 that supplies power to the electrolytic bath 2; an auxiliary power supply unit 58 that supplies power to the electrolytic bath 2 independently of the main power supply unit 56; a detection unit 38 that detects the voltage of the electrolytic bath 2, the potential of an anode electrode 12, or the potential of a cathode electrode 16; and a control unit 10 that controls the supply of power to the electrolytic bath 2 on the basis of detection results of the detection unit 38. The control unit 10 controls the auxiliary power supply unit 58 to supply power to the electrolytic bath 2, when the voltage or potential is detected to be changed to a prescribed value during the operation stoppage of the organic hydride generation system 1 in which the power from the main power supply unit 56 is not supplied to the electrolytic bath 2.
Resumen de: WO2025125243A1
The invention relates to a method for producing an electrode (10) for use in alkaline electrolysis of water, the method comprising: providing a metal substrate (12); providing a coating material (26) comprising powder (28) consisting of a catalyst material (20), and comprising non-metal particles (24); and coating at least a portion of the substrate with the coating material. The invention also relates to electrodes produced in this way.
Resumen de: EP4593128A2
Provided herein is a method for producing a cement material, said method comprising steps of: a. reacting sulfur dioxide and water to form a first acid, the first acid comprising at least one sulfur-containing anion; b. reacting the first acid and a first cement precursor to form a second cement precursor; wherein the second cement precursor comprises the at least one sulfur-containing anion; and c. converting the second cement precursor to the cement material. Also provided is a system for producing a cement material.
Resumen de: AU2023327787A1
The invention provides an electrolytic cell, comprising: a working electrode; a counter electrode; a liquid electrolyte in contact with a working surface of the working electrode; an acoustically transmissive substrate comprising at least a piezoelectric substrate portion; one or more conductive electrodes coupled to the piezoelectric substrate portion and configured to propagate a high frequency acoustic wave having a frequency of at least 1 MHz across the acoustically transmissive substrate when electrically actuated; and one or more power supplies configured (i) to apply a potential between the working electrode and the counter electrode sufficient to electrolytically react a species in the liquid electrolyte, thereby producing an electrolytic reaction product proximate the working electrode, and (ii) to electrically actuate the one or more conductive electrodes, wherein the working electrode is either located on the acoustically transmissive substrate or spaced apart from the acoustically transmissive substrate by the liquid electrolyte, and wherein propagation of the high frequency acoustic wave across the acoustically transmissive substrate in operation of the electrolytic cell stimulates the liquid electrolyte, thereby increasing the production efficiency of the electrolytic reaction product.
Resumen de: MX2025004437A
Electrochemical cell system (100) which comprises an electrochemical cells arrangement (10), a control unit (20) configured to operate the electrochemical cells arrangement (10) only as electrolytic cells or only as fuel cells, a heat unit (40), external to the electrochemical cells arrangement (10), which is thermally coupled to the electrochemical cells arrangement (10) and which is configured to alternately store heat from the electrochemical cells arrangement (10) to the heat unit (40) and supply heat from the heat unit (40) to the electrochemical cells arrangement (10), and a transfer arrangement (30) configured to alternately transfer heat from the electrochemical cells arrangement (10) to the heat unit (40) and from the heat unit (40) to the electrochemical cells arrangement (10).
Resumen de: US2025018339A1
Disclosed are a method and an apparatus for carbon capture coupled hydrogen production. The method includes: capturing low-concentration CO2 by a solution of an alkali metal hydroxide to obtain a low-concentration CO2 absorption solution; capturing high-concentration CO2 by a first portion of the low-concentration CO2 absorption solution to obtain a high-concentration CO2 absorption solution; and performing electrolysis by a second portion of the low-concentration CO2 absorption solution as a catholyte solution, using the high-concentration CO2 absorption solution as an anolyte, and using a non-ionic diaphragm as a diaphragm. According to the method, capture of CO2 in a wide concentration range can be realized; electrolysis is performed by a non-ionic diaphragm, to implement regeneration of an absorption solution coupled hydrogen production; capture costs of CO2 in a wide concentration range can be reduced; additional products of H2 and O2 can be obtained; and hydrogen production costs can be reduced.
Resumen de: WO2024133283A1
An alkaline water electrolyzer (200) comprising an electronic controller (Cont), a stack (Stck) of electrolysis cells each comprising an anode and a cathode, the electrolyzer being configured to contain an electrolyte made of an anolyte (AnKOH) and a catholyte (CathKOH), the electrolyzer comprising a system (Sys) controlled by the electronic controller (Cont) configured to maintain a concentration of an impurity in the electrolyte within a target range by measuring a characteristic representative of the concentration of the impurity in the electrolyte and, in response to the measured concentration of the impurity, add a quantity of the impurity into the electrolyte.
Resumen de: WO2025153178A1
A control system (30) for a hydrogen plant (100) is provided. The hydrogen plant includes: a first set of units (11,12…1n) comprising at least one hydrogen electrolyzer for producing hydrogen as a main product and heat as a byproduct; and a second set of units (21,22…2n) comprising at least one desalination unit partially operated with the heat from the at least one hydrogen electrolyzer for producing distilled water from raw water, and the at least one water desalination unit being configured to provide at least part of the distilled water to the at least one hydrogen electrolyzer. The control system is configured to control operation of the hydrogen plant including controlling electrical energy consumption of the at least one electrolyzer and the at least one desalination unit by adjusting at least one of: 1) electrical power supplied to the at least one hydrogen electrolyzer to produce the hydrogen and the heat; 2) flowrate of the at least part of the distilled water to the at least one hydrogen electrolyzer from the at least one desalination unit; and 3) heat transferred from the at least one hydrogen electrolyzer to the at least one desalination unit.
Resumen de: WO2025153632A1
The disclosure concerns a hydroprocessing of a hydrocarbon feedstock (1) in which the acid gas stream with hydrogen sulphide (11) that is generated is cracked to generate a stream (13) comprising hydrogen and elemental sulphur. The disclosure relates also to an installation for removing one or more organic sulphur compounds from a hydrocarbon feedstock (1).
Resumen de: WO2025154892A1
The present invention relates to a stepwise system and method for producing lime and hydrogen using by-product gypsum and the system includes: a lime production unit that reacts the by-product gypsum with a hydroxide of an alkali metal to produce lime and alkali metal sulfate, an electrolysis unit that electrolyzes the aqueous solution of the generated alkali metal sulfate to produce alkali metal hydroxide and hydrogen, and a circulation unit that provides the produced alkali metal hydroxide back to the lime production unit.
Resumen de: WO2025154484A1
The purpose of the present invention is to improve the safety of a hydrogen production plant. This hydrogen production plant (1) comprises: a solid oxide electrolysis cell (SOEC) (10) which produces a hydrogen-containing gas; and a discharge stack (30) into which the hydrogen-containing gas produced by the SOEC (10) is introduced and which discharges the introduced hydrogen-containing gas to air. The discharge stack (30) has a spray unit (32) which supplies, to the hydrogen-containing gas introduced therein, cooling water for cooling the hydrogen-containing gas.
Resumen de: US2025236961A1
A device (1) for performing electrolysis of water is disclosed. The device comprising: a semiconductor structure (10) comprising a surface (11) and an electron guiding layer (12) below said surface (11), the electron guiding layer (12) of the semiconductor structure (10) being configured to guide electron movement in a plane parallel to the surface (11), the electron guiding layer (12) of the semiconductor structure (10) comprising an InGaN quantum well (14) or a heterojunction (18), the heterojunction (18) being a junction between AlN material and GaN material or between AlGaN material and GaN material; at least one metal cathode (20) arranged on the surface (11) of the semiconductor structure (10); and at least one photoanode (30) arranged on the surface (11) of the semiconductor structure (10), wherein the at least one photoanode (30) comprises a plurality of quantum dots (32) of InxGa(1-x)N material, wherein 0.4≤x≤1. Also a system comprising such device is disclosed.
Resumen de: US2025236978A1
A hydrogen generation system includes a plurality of cell stack assemblies, each including a plurality of cells. The cell stack assemblies are electrically connected in series. The cell stack assemblies each receive water and electricity and generate hydrogen as a result of an electrochemical reaction within the cells. The hydrogen is intended for use outside of the system and may be stored or transported to another location. A plurality of conduits carry water into and water, oxygen and hydrogen away from the cell stack assemblies. The conduits each include a dielectric section near the respective cell stack assembly to reduce or eliminate shunt currents between the cell stack assemblies. The dielectric sections may also serve to electrically isolate the cell stack assemblies from grounded portions of the system, such as a supporting frame.
Resumen de: US2025236967A1
A membrane in an electrochemical cell may be electrically and/or mechanically coupled to a flow-field plate using a conductive adhesive. Various types of adhesives with conductive particles may be used. The adhesive may be selected such that in the fluid phase it is able to diffuse through one or more porous layers of the electrochemical cell, such as a liquid/gas diffusion layer. In some cases, the use of conductive adhesive may increase the level of inter-component electrical contact that may be achieved for a given level of compressive force applied between the components in the electrochemical cell.
Resumen de: US2025236972A1
Electrolyzer for production of hydrogen gas and comprising a stack of bipolar electrodes sandwiching ion-transporting membranes between each two of the bipolar electrodes. Each bipolar electrode comprises two metal plates welded together back-to-back forming a coolant compartment in between and having a respective anode surface and an opposite cathode surface, each of which is abutting one of the membranes. The plates are embossed with a major vertical channel and minor channels in a herringbone pattern for transport of oxygen and hydrogen gases. The embossed herringbone pattern is provided on both sides of the metal plates so as to also provide coolant channels in a herringbone pattern inside the coolant compartment.
Resumen de: US2025236969A1
A Ni-based porous electrode for water electrolysis including (a) a macroporous substrate having a specific thickness, porosity level, and a pore size; (b) a first layer of a metal or a metal alloy as defined herein covering the macroporous substrate; and (c) a second layer of Ni, a Ni—X alloy or a Ni—X—Y alloy covering the first layer. The Ni-based porous electrode is free from Pt-group metals and rare-earths. A process for the manufacturing of the Ni-based porous electrode. The use of the Ni-based porous electrode to catalyze the hydrogen evolution reaction (HER). A water electrolyzer comprising the Ni-based porous electrode.
Resumen de: US2025236962A1
Herein discussed is a hydrogen production system comprising a first reactor zone and a second reactor zone, wherein both reactor zones comprise an ionically conducting membrane, wherein the first zone is capable of reforming a hydrocarbon electrochemically and the second zone is capable of performing water gas shift reactions electrochemically, wherein the electrochemical reforming reactions involve the exchange of an ion through the membrane to oxidize the hydrocarbon and wherein electrochemical water gas shift reactions involve the exchange of an ion through the membrane and include forward water gas shift reactions, or reverse water gas shift reactions, or both. In an embodiment, the membrane is mixed conducting. In an embodiment, the membrane comprises an electronically conducting phase and an ionically conducting phase.
Resumen de: US2025236960A1
Described is a system and method for green hydrogen production via electrolysis. The system includes a steam boiler unit configured to produce a discharged waste water stream, an electrolysis unit configured to produce hydrogen and oxygen from the discharged waste water stream; and a hydrogen storage unit for storing a portion of the hydrogen produced by the electrolysis unit as a product.
Resumen de: US2025236964A1
Electrochemical cells having recombination layers are disclosed herein. One example of such a cell includes a membrane configured to be positioned between an anode flow field and a cathode flow field of the electrochemical cell. The cell further includes a recombination layer configured to be positioned between the anode flow field and at least a portion of the membrane. The recombination layer includes a catalyst configured to assist in a formation of water from hydrogen gas and oxygen gas produced within the electrochemical cell, therein mitigating any hydrogen gas crossover from a cathode side to an anode side of the electrochemical cell.
Resumen de: US2025236541A1
Methods, systems and devices for removing iodide from an aqueous solution including submerging an iodophilic electrode in an aqueous solution containing iodide, applying a current to the electrode, and electrochemically oxidizing the iodide to iodine within the electrode. The electrode may include an iodophilic material and an electrically conductive material. It may also include a binder. The iodophilic material may be a starch, chitosan, carboxycellulose, cationic polymer, or an anion exchange membrane material, for example. After oxidizing the iodide to iodine within the electrode, the electrode may be submerged in a second solution and a current may be applied to reduce the iodine and release it from the electrode in the form of iodide into the second solution.
Resumen de: US2025236542A1
Provided is an apparatus and a method of desalinating saltwater and transporting hydrogen ions using Ion Concentration Polarization (ICP), the apparatus including: a channel part including a channel allowing saltwater to be introduced thereinto, an ion-selective membrane connected to the channel, and a cathode and an anode for applying a voltage to both ends of the channel; a desalination part configured to obtain fresh water from the saltwater with ionic substances removed from the saltwater by ion concentration polarization in a first region adjacent to the anode of the ion-selective membrane; and a hydrogen gas production part configured to concentrate the ionic substances in a second region adjacent to the cathode of the ion-selective membrane and to reduce hydrogen ions (H+) contained in the ionic substances.
Resumen de: US2025235819A1
An environmental control system employs an electrolysis cell utilizing an anion conducting membrane. A power supply is coupled across the anode and cathode of the electrolysis cell to drive reactions to reduce oxygen and/or carbon dioxide in an output gas flow. A cathode enclosure may be coupled with the electrolysis cell and provide an input gas flow and receive the output gas flow. A first electrolysis cell may be utilized to reduce the carbon dioxide concentration in an output flow that is directed to a second electrolysis cell, that reduces the concentration of oxygen. The oxygen and/or carbon dioxide may be vented from the system and used for an auxiliary purpose. An electrolyte solution may be configured in a loop from a reservoir to the anode, to provide a flow of electrolyte solution to the anode. Moisture from the cathode may be collected and provided to the anode.
Resumen de: WO2024163636A1
The present disclosure relates to methods of sequestering CO2 comprising a first cathodic chamber, performing a first alkaline process, a first anodic chamber, performing a first acidic process, and dechlorinating a solution by contacting the solution with a dechlorinating agent. Also provided herein are systems comprising a first cathodic chamber and a first anodic chamber.
Resumen de: WO2025155611A1
Improved electrocatalysts for promoting a hydrogen evolution reaction (HER) or an oxygen evolution reaction (OER) from alkaline fresh water and seawater are disclosed. By incorporating metals, such as tungsten and rare earth elements, into the nickel molybdenum nitride framework, Ni1-xMoxN, the disclosed electrocatalysts demonstrate improved catalytic activity and stability compared to the original Ni&Ni0.2Mo0.8N catalysts, particularly under high-current alkaline conditions, in water electrolysis for hydrogen and oxygen production.
Resumen de: CN119895081A
An electrolytic cell (1) for the electrolysis of chlor-alkali or alkaline water, comprising: two cell elements (2, 3), each cell element (2, 3) defining an electrode chamber (4, 5) by providing a rear wall (6) and side walls (7) of the electrode chamber (4, 5); electrodes (8, 9) respectively housed in each of the electrode chambers (4, 5); a sheet-like diaphragm (10) that extends in the height direction (H) and the width direction (W) of the electrolytic cell (1), is provided in a joint (11) between the two electrolytic cell elements (2, 3), and forms a partition wall (12) between the electrode chambers (4, 5); a plurality of support members (13) for supporting at least one electrode (8, 9) on a respective rear wall (6); wherein each support member (13) comprises: two support parts standing on the rear wall (6) and extending in the height direction (H) of the electrolytic cell (1); two feet (16, 17) connected to the respective supports (14, 15) at an angle and in planar contact with the rear wall (6); wherein the support portions of the support members (13) are connected to each other by means of an arch-shaped portion (18) bent outward toward the electrode (8) to be supported, and form an elastic bearing surface (19) for supporting the electrode (8); when the arch (18) deflects inwards, the bearing surface (19) increases.
Resumen de: MX2025002822A
The problem addressed by the present invention is that of specifying a process for producing lithium hydroxide which is very energy efficient. The process shall especially operate without consumption of thermal energy. The process shall be able to handle, as raw material, Li-containing waters generated during digestion of spent lithium-ion batteries. The LiOH produced by the process shall have a high purity sufficient for direct manufacture of new LIB. The process shall achieve a high throughput and have small footprint in order that it can be combined with existing processes for workup of used LIB/for production of new LIB to form a closed, continuous production loop. The process according to the invention is an electrolytic membrane process operating with a LiSICon membrane. It is a special aspect of the process that the electrolysis is operated up to the precipitation limit of the lithium hydroxide.
Resumen de: EP4588566A1
The present disclosure relates to a method of preparing a NiMo-MoO<sub>3-x</sub> porous nanorod catalyst based on a metal-organic framework and a non-precious metal alloy catalyst prepared thereby. The method of preparing a non-precious metal alloy catalyst according to the present disclosure can prepare an alloy catalyst that combine alloys and oxides and form nanorods having porosity and high surface area, and possess excellent HER performance close to that of commercial platinum catalysts.
Resumen de: EP4589053A1
An electrode, including: a substrate that has a surface composed of at least one of nickel, nickel oxide, and nickel hydroxide; and scale-like protruding parts provided on the surface of the substrate.
Resumen de: EP4588957A1
A block copolymer including one or more segments containing an ionic group (hereinafter referred to as an "ionic segment(s)") and one or more segments containing no ionic group (hereinafter referred to as a "nonionic segment(s)"), wherein the ionic segment has an aromatic hydrocarbon polymer having a number-average molecular weight of more than 40,000 and 50,000 or less, and wherein the block copolymer satisfies the relation of: Mn3 / (Mn1 + Mn2) > 1.5, wherein Mn1 represents the number-average molecular weight of the ionic segment, Mn2 represents the number-average molecular weight of the nonionic segment, and Mn3 represents the number-average molecular weight of the block copolymer. Provided is a block copolymer and a polymer electrolyte material produced using the same, wherein the block copolymer has excellent proton conductivity even under low-humidity conditions, has excellent mechanical strength and physical durability, and has an excellent in-process capability.
Resumen de: AU2023342927A1
An electrochemical cell is disclosed having a porous metal support, a gas transport layer on the porous metal support, and an electrode layer on the gas transport layer. The gas transport layer is electrically conductive and has an open pore structure comprising a pore volume fraction of 20% by volume or higher and wherein the electrode layer has a pore volume fraction lower than the pore volume fraction of the gas transport layer. Also disclosed is a stack of such electrochemical cells and a method of producing such an electrochemical cell.
Resumen de: GB2637436A
Provided are a battery management system and method, and a related device. Battery units are controlled to be connected or disconnected in a power supply circuit by using collected operation parameters of the battery units, so that the safety in a battery operation process is improved. The battery management system comprises N first nodes, a second node, and M control switches. The first node is used for generating a first signal and sending the first signal to the second node, wherein the first signal comprises operation parameters of the battery unit corresponding to the first node in the power supply circuit. The second node is used for generating a second signal on the basis of the N first signals from the N first nodes and sending the second signal to the control switches. The control switch is used for controlling, on the basis of the second signal, the battery unit corresponding to the control switch to be connected or disconnected in the power supply circuit.
Resumen de: AU2023405114A1
The invention relates to an electrolysis system (1) comprising an electrolyser (3) for producing hydrogen (H
Resumen de: WO2024114990A1
A hydrogen production apparatus (11) for an intermittent power source (2) and/or an electrical grid, comprising: a hydrogen production unit (19) for producing hydrogen gas (12), a first compressor unit (21) for compressing the produced hydrogen gas, a tank (25) for storing the gas compressed by the first compressor unit (21), the tank comprising a first and a second outlet (28, 29), a second compressor unit (30) fluidly connected to the second outlet of the tank (25) for compressing hydrogen gas supplied from the tank, the second compressor unit comprising an outlet (33), and a dispensing unit (34) fluidly connected to both the first outlet of the tank and the outlet of the second compressor unit for dispensing gas from the hydrogen production apparatus. By storing hydrogen gas in the tank, hydrogen gas can be dispensed from the hydrogen production apparatus even in times of low hydrogen production such as low wind speeds.
Resumen de: CN119908039A
Disclosed is an electrochemical cell having: a porous metal support; at least one layer of a first electrode on the porous metal support; a first electron blocking electrolyte layer of rare earth doped zirconia on the at least one layer of the first electrode; and a second bulk electrolyte layer of rare earth doped cerium oxide on the first electron blocking electrolyte layer. The first electron blocking electrolyte layer of rare earth doped zirconia may have a thickness of 0.5 mu m or more, and the second bulk electrolyte layer of rare earth doped ceria may have a thickness of 4 mu m or more.
Resumen de: EP4588561A1
Provided is a composite including molybdenum disulfide and molybdenum trioxide, in which the molybdenum disulfide includes a 3R crystal structure, and the percentage content of a molybdenum trioxide-equivalent value (B) calculated from the molybdenum content determined by XRF analysis of the composite relative to the total mass of the composite is 5 to 90 mass%. Also provided is a catalytic ink including the composite and a solvent. Also provided is a method for producing the composite, including a calcination step of heating molybdenum trioxide in the presence of a sulfur source at a temperature of 400°C or less.
Resumen de: NZ793935A
The present invention describes a processes, systems, and catalysts for the conversion of carbon dioxide and water and electricity into low carbon or zero carbon high quality fuels and chemicals. In one aspect, the present invention provides an integrated process for the conversion of a feed stream comprising carbon dioxide to a product stream comprising hydrocarbons between 5 and 24 carbon atoms in length.
Resumen de: AU2023359480A1
The invention relates to a bipolar plate for an electrolytic cell, the plate comprising, on at least one of its main faces: a first zone running circumferentially; a second zone running circumferentially so as to be bordered on the outside by the first zone; a third zone running circumferentially so as to be bordered on the outside by the second zone, the various zones being arranged on the periphery of the associated main face. The invention also relates to the corresponding cell, electrolyzer cell and assembly method.
Resumen de: WO2023246668A1
Disclosed in the present invention is an ammonia decomposition reactor having an ammonia preheating function. The reactor comprises a heat exchanger body and a reactor body; the heat exchanger body wraps the outer side of the reactor body; heat exchange tubes on the heat exchanger body are arranged in heat exchange housings; one end of each heat exchange tube is communicated with an ammonia heat exchange inlet, and the other end of the heat exchange tube is communicated with an ammonia heat exchange outlet; a heating agent inlet and a heating agent outlet on the heat exchanger body are respectively communicated with the heat exchange housings; catalyst tubes on the reactor body are arranged in a reaction housing; the ammonia heat exchange outlet on the heat exchanger body is communicated with an ammonia inlet on the reactor body; the ammonia inlet is communicated with an ammonia decomposition gas outlet by means of the catalyst tubes; and the ammonia decomposition gas outlet is communicated with the heating agent inlet on the heat exchanger body. According to the present invention, the reactor is compact in structure, high-temperature gas of an ammonia decomposition gas in the reactor is used as a heat medium of a heat exchanger, and heat is provided for ammonia for preheating, so that ammonia entering the reactor is in a high-temperature state, and the ammonia decomposition reaction in the reactor is more sufficient.
Resumen de: WO2025149217A1
The present invention relates to an alkaline electrolysis device comprising: - at least one electrolysis cell having a reactor chamber, which has a hydrogen-side reactor-chamber region, containing the aqueous electrolyte, for breaking down the aqueous electrolyte into gaseous hydrogen and has an oxygen-side reactor-chamber region, containing the aqueous electrolyte, for breaking down the aqueous electrolyte into gaseous oxygen; - a hydrogen separator, which is connected to the hydrogen-side reactor-chamber region, for separating the gaseous hydrogen from the aqueous electrolyte introduced into the hydrogen separator; and - an oxygen separator, which is connected to the oxygen-side reactor-chamber region, for separating the gaseous oxygen from the aqueous electrolyte introduced into the oxygen separator; wherein the hydrogen separator comprises a first hydrogen-separator outlet for removing the aqueous electrolyte having a first hydrogen concentration, and a second hydrogen-separator outlet for removing the aqueous electrolyte having a second hydrogen concentration that is lower than the first hydrogen concentration; and wherein the first hydrogen-separator outlet and the second hydrogen-separator outlet can be or are connected to the reactor chamber.
Resumen de: MX2025000634A
A water electrolysis system including a container; a plurality of microcells located inside the container; the microcells are centered around a central axis of the container; a first bracket located on a first side of the microcells; a second bracket located on a second side of the microcells; a plurality of magnets mounted on the first and the second brackets, the magnets are placed in parallel to the microcells; a liquid inside the container. The first and the second brackets are adapted to be connected to a motor. The first and the second brackets rotate during the electrolysis process. The magnets on the first bracket produce a first magnetic field and the magnets on the second bracket produce a second magnetic field; and the first and the second magnetic fields have opposite polarity.
Resumen de: CN119546546A
The invention relates to a method for producing hydrogen by photodissociation of water, comprising at least one step of contacting an aqueous solution with oxidized nanodiamonds under solar, natural or artificial illumination (or light).
Resumen de: WO2025150454A1
Provided is an operation method for a dehumidifier device for dehumidifying hydrogen gas produced by a hydrogen production device. The dehumidifier device comprises; a dehumidifier; a discharge line for discharging hydrogen gas dehumidified by the dehumidifier from the dehumidifier; a dew point measurement line connected to the discharge line; a dew point meter provided on the dew point measurement line; and an inlet valve and an outlet valve provided on opposite sides of the dew point meter on the dew point measurement line. The method includes: a stop step of stopping discharge of the hydrogen gas from the dehumidifier to the discharge line; and a maintenance step of maintaining a state in which a dew point meter installation part including at least a installation place of the dew point meter on the dew point measurement line is filled with dry gas when the discharge of the hydrogen gas from the dehumidifier to the discharge line is stopped.
Resumen de: WO2025148994A1
The present invention provides a direct electrolysis seawater hydrogen production method that effectively inhibits precipitation. In the present invention, natural seawater is used as an electrolyte; an alternating current is applied to an electrode; the polarity of the electrode is periodically and alternately converted between a cathode state and an anode state by utilizing the periodic change of the voltage of the alternating current; and when the electrode is in the anode state, OH- generated by means of a hydrogen evolution reaction in the cathode state is consumed to inhibit precipitation and a catalytic activity decrease of the electrode. The present invention further provides a solution electrolysis hydrogen production method that generates a precipitate under alkaline conditions.
Resumen de: US2025230560A1
An electrolyzer cell comprises a first half cell comprising a housing at least partially enclosing a cell interior, a first electrode coated with a first catalyst coating, wherein the first electrode is coupled to the housing in the cell interior without welding, a second electrode coupled to the housing in the cell interior without welding, and a separator positioned between the first electrode and the second electrode, wherein a voltage is applied between the first electrode and the second electrode.
Resumen de: AU2025204790A1
SYSTEM AND METHOD FORO CARBON DIOXIDE REACTOR CONTROL A system preferably including a carbon dioxide reactor. A method for carbon dioxide reactor control, preferably including selecting carbon dioxide reactor aspects based on a desired output composition, running a carbon dioxide reactor under controlled process conditions to produce a desired output composition, and/or altering the process conditions to alter the output composition. SYSTEM AND METHOD FORO CARBON DIOXIDE REACTOR CONTROL A system preferably including a carbon dioxide reactor. A method for carbon dioxide reactor control, preferably including selecting carbon dioxide reactor aspects based on a desired output composition, running a carbon dioxide reactor under controlled process conditions to produce a desired output composition, and/or altering the process conditions to alter the output composition. un u n s y s t e m p r e f e r a b l y i n c l u d i n g a c a r b o n d i o x i d e r e a c t o r m e t h o d f o r c a r b o n d i o x i d e r e a c t o r c o n t r o l , p r e f e r a b l y i n c l u d i n g s e l e c t i n g c a r b o n d i o x i d e r e a c t o r a s p e c t s b a s e d o n a d e s i r e d o u t p u t c o m p o s i t i o n , r u n n i n g a c a r b o n d i o x i d e r e a c t o r u n d e r c o n t r o l l e d p r o c e s s c o n d i t i o n s t o p r o d u c e a d e s i r e d o u t p u t c o m p o s i t i o n , a n d o r a l t e r i n g t h e p r o c e s s c o n d i t i o n s t o a l t e r t h e
Resumen de: US2025230563A1
The present invention relates to an electrocatalyst comprising a Cu substrate coated with a 3D TiO2/Cu microrods array decorated with nanoparticles of a noble metal, preferably Ru nanoparticles, an electrochemical cell comprising said electrocatalyst and their use for hydrogen production via hydrogen evolution reaction (HER) in basic conditions. The present invention also refers to an in-situ process for the preparation of said electrocatalyst and simultaneous production of hydrogen. The present invention also refers to a process for producing hydrogen which utilizes the electrochemical cell comprising the electrocatalyst according to the invention.
Resumen de: US2025230040A1
Methods and systems for splitting one or more of water and carbon dioxide are disclosed. Exemplary methods can operate under substantially isothermal conditions. The methods can include use of a material including two or more spinel phases in a solid solution. The solid solution can include oxygen, aluminum, and one or more transition metals.
Resumen de: US2025230108A1
A hydrocarbon generation system includes a hydrocarbon generator, an electrolyzer, a water vapor supply line, and a heat exchanger. The hydrocarbon generator generates hydrocarbon through an exothermic reaction between a carbon oxide gas and hydrogen. The electrolyzer generates hydrogen from water vapor of raw materials, the generated hydrogen being supplied to the hydrocarbon generator. The water vapor supply line generates the water vapor of the raw materials by evaporating liquid water of the raw materials and supplies the generated water vapor to the electrolyzer. The heat exchanger uses heat of a reaction generated in the hydrocarbon generator to evaporate the liquid water of the raw materials in the water vapor supply line via heat transfer oil.
Resumen de: US2025230790A1
A system and method by which energy from ocean waves is converted into hydrogen, and that hydrogen is used to manifest electrical and mechanical energies by an energy consuming device. A portion of the generated electrical power is communicated to water electrolyzers which produce oxygen and hydrogen from water as gases. At least a portion of the generated hydrogen gas is transferred to a transportation ship via a hose-carrying, remotely operated (or otherwise unmanned) vehicle, and subsequently transferred to an energy-consuming module or infrastructure, where a portion of the hydrogen is consumed in order to manifest a generation of electrical energy, a mechanical motion, and/or a chemical reaction.
Resumen de: AU2024287197A1
A method for optimizing and controlling collaborative operation of an integrated energy system containing a complete hydrogen energy chain, comprising: building a complete hydrogen energy chain in an integrated energy system, and modeling the built complete hydrogen energy chain considering waste heat utilization of an electrolytic cell, a hydrogen-fired turbine, and a fuel cell and economic benefits achieved by hydrogen production by-products; considering system operation flexibility, hydrogen pipeline expansion, and equipment waste heat utilization based on a traditional power system model, a refined model of the complete hydrogen energy chain, a heat-related equipment model, and performing single objective and multi-objective optimization during solving; and optimizing a connection configuration between the complete hydrogen energy chain and the integrated energy system according to a solved result, and regulating and controlling output quantities of various types of energy between the complete hydrogen energy chain and the integrated energy system. A method for optimizing and controlling collaborative operation of an integrated energy system containing a complete hydrogen energy chain, comprising: building a complete hydrogen energy chain in an integrated energy system, and modeling the built complete hydrogen energy chain considering waste heat utilization of an electrolytic cell, a hydrogen-fired turbine, and a fuel cell and economic benefits achieved by hydrogen produc
Resumen de: AU2024210539A1
In this water electrolysis system, an alternating current (AC)-side connection end of a power converter is connected to an AC power system, at least one electrolytic stack and a series circuit configured by connecting the at least one electrolytic stack to a circuit breaker is connected to a direct current (DC)-side connection end of the power converter, before disconnecting the electrolytic stack from the series circuit, a controller reduces the power flowing to the DC-side connection end while controlling the speed at which the power converter reduces the power flowing to the DC-side connection end to a speed at which a difference from the reference value of the voltage amplitude of the AC power system is less than a predetermined value, and when the circuit breaker reaches a power sufficient to disconnect the internal DC circuit, the controller disconnects the circuit breaker connected to the DC circuit to disconnect the electrolytic stack from the series circuit.
Resumen de: US2025230555A1
A method of generating hydrogen including applying a potential of −0.1 volts (V) to −1.0 V to an electrochemical cell, and the electrochemical cell is at least partially submerged in an aqueous solution. Further, on the application of the potential, the aqueous solution is reduced, thereby forming hydrogen. The electrochemical cell includes an electrocatalyst and a counter electrode. The electrocatalyst includes a substrate and vanadium-doped manganese spinel oxide microspheres (MnVxCo2-xO4) particles. The value of x is ≤0.4, the MnVxCo2-xO4 particles have a spherical shape, the MnVxCo2-xO4 particles have an average diameter of less than 100 nanometers (nm), and the MnVxCo2-xO4 particles are dispersed on the substrate to form the electrocatalyst.
Resumen de: US2024395434A1
A reactor block to extract hydrogen from water includes a first opening configured to receive gasified water, a second opening, and a reactor plate. A channel is formed in the reactor plate and disposed in a fluid path between the first opening and the second opening and a radioactive coating is applied to the channel. The second opening is configured to eject hydrogen generated by radiolysis of at least a portion of the gasified water received at the first opening and passed through the channel to the second opening.
Resumen de: CN119604997A
The invention relates to: a bipolar plate (1); and an electrochemical cell (12) comprising a plurality of such bipolar plates (1, 1 '). The bipolar plate (1) comprises a first half plate (1a) and a second half plate (1b) which are fixedly connected with each other, the bipolar plate (1) is provided with a plurality of fluid channel openings (2), and the fluid channel openings comprise fluid inlet openings (2a, 2c and 2e) and fluid outlet openings (2b, 2d and 2f); on both sides of the bipolar plate (1) there are a first distributor field (3) for distributing the fluid, an active field (4) and a second distributor field (5) for distributing the fluid. At least one seal (6, 6 ') is also present on each side of the bipolar plate (1), the seals (6, 6') being positioned one above the other in at least one transition region (7) between the fluid channel opening (2) and the adjacent distributor field (3, 5) as seen perpendicularly to the plane of expansion of the bipolar plate (1) and being reinforced by embossing structures (9a, 9b).
Resumen de: AT527859A1
Elektrolyseur zur alkalischen Wasserstoffelektrolyse, umfassend eine Gleichspannungsquelle, insbesondere einen Gleichrichter (1) mit einem elektrischen Plus-Pol (2) und einem elektrischen Minus-Pol (3), sowie Medienzuleitungen (4) für ein Elektrolysemedium und Medienableitungen (5) für Produktmedien, wobei zwischen dem Plus-Pol (2) und dem Minus-Pol (3) mehrere, über elektrische Verbindungsleitungen (9) in Serie geschaltete Elektrolyseblöcke (6) angeschlossen sind, wobei die Elektrolyseblöcke (6) jeweils eine Vielzahl elektrisch in Serie geschalteter und bündig mechanisch verspannter Elektrolysezellen (7) aufweisen, wobei die Medienzuleitungen (4) und die Medienableitungen (5) jeweils seriell durch die Elektrolyseblöcke (6) verlaufen und sich innerhalb jedes einzelnen Elektrolyseblocks (6) auf individuelle Zellzuleitungen (4‘, 4‘‘) und individuelle Zellableitungen (5‘, 5‘‘) der Elektrolysezellen (7) verteilen.
Resumen de: JP2025106288A
【課題】水素を生成する方法を提供する。【解決手段】水素を生成する方法は、燃料を含む第1のストリームを装置に導入すること、水を含む第2のストリームを装置に導入すること、第2のストリーム中の水を水素に還元すること、および水素を装置から抽出することを含む。第1のストリームおよび第2のストリームは、装置内で互いに接触しない。【選択図】図6B
Resumen de: US2023373882A1
The invention relates to a process, catalysts, materials for conversion of renewable electricity, air, and water to low or zero carbon fuels and chemicals by the direct capture of carbon dioxide from the atmosphere and the conversion of the carbon dioxide to fuels and chemicals using hydrogen produced by the electrolysis of water.
Resumen de: WO2025146950A1
The present invention relates to a system for producing hydrogen while interworking with a nuclear power plant, the system comprising: a water electrolysis facility for producing hydrogen and oxygen by using vapor supplied from a nuclear power plant; and a power supply controller for selecting at least one reactor module from multiple reactor modules for hydrogen production by the water electrolysis facility, and selecting at least one from multiple generators or power grids such that power is supplied therefrom to the water electrolysis facility. According to an embodiment, power and hydrogen can be simultaneously produced. Particularly, hydrogen can be produced continuously in an economical and effective manner by selecting an optimal reactor module from multiple reactor modules for hydrogen production and by selecting an optimal power supply source from various power sources.
Resumen de: AU2023359478A1
The invention relates to a method for joining a stack of elements together, the method comprising the steps of: individually joining subassemblies of the elements together; joining the subassemblies together by arranging a joint between each subassembly to form the stack of elements; applying consecutive phases of heating and cooling to the stack of elements while applying at least one clamping action to the stack of elements between two different phases of heating and cooling.
Resumen de: CN118461072A
The invention discloses an electrolytic hydrogen production system and a control method thereof. The electrolytic hydrogen production system comprises a plurality of electrolytic cells, the control method comprises the following steps: acquiring a state code of each electrolytic cell; the state code reflects the state information of the electrolytic cell; and controlling the hydrogen production capacity of each electrolytic cell according to each state code. According to the technical scheme, intelligent control over the electrolytic hydrogen production system is achieved, the hydrogen production capacity of all the electrolytic cells is reasonably distributed, and therefore the electrolytic hydrogen production system is in the optimal operation state all the time, and the stability of the electrolytic hydrogen production system and the electrolytic hydrogen production efficiency can be improved.
Resumen de: AU2023285998A1
The present invention provides a portable 12-volt system for cooking/heating, utilising hydrogen gas. The said stove runs from a 12-volt battery supply, hydrogen is not stored - the gas is only produced on demand. The concept developed is a one-off functional prototype to demonstrate proof of concept. The proof of concept demonstrates the ability to produce hydrogen gas flames from a 12-volt power source, to be used as a cooking or heating output. The accompanied drawings are the latest iteration post physical prototype development. The present invention provides a portable 12-volt system for cooking/heating, utilising hydrogen gas. The said stove runs from a 12-volt battery supply, hydrogen is not stored - the gas is only produced on demand. The concept developed is a one-off functional prototype to demonstrate proof of concept. The proof of concept demonstrates the ability to produce hydrogen gas flames from a 12-volt power source, to be used as a cooking or heating output. The accompanied drawings are the latest iteration post physical prototype development. ec h e p r e s e n t i n v e n t i o n p r o v i d e s a p o r t a b l e - v o l t s y s t e m f o r c o o k i n g h e a t i n g , u t i l i s i n g h y d r o g e n g a s h e s a i d s t o v e r u n s f r o m a - v o l t b a t t e r y s u p p l y , h y d r o g e n i s n o t s t o r e d - t h e e c g a s i s o n l y p r o d u c e d o n d e m a n d h e c o n c e p t d e v e l o p e d i s a o n e - o f f f u n c t i o n a
Resumen de: US2025223539A1
A method for optimal production of methane from a storage horizon configured as an underground bioreactor, the method including obtaining environmental data for a renewable energy facility that produces hydrogen and obtaining process data from an industrial facility that produces carbon dioxide. The method further includes injecting the produced hydrogen, the produced carbon dioxide, and a selection of microbes, the selection defined by a set of microbe parameters, into the bioreactor. The bioreactor produces a quantity of methane that is controlled by, at least in part, a set of operation parameters. The method further includes determining, with a composite artificial intelligence model, a predicted methane production from the bioreactor based on the environmental data, the process data, the set of microbe parameters, and the set of operation parameters and adjusting, automatically, the set of operation parameters and the set of microbe parameters to optimize methane production.
Resumen de: AU2023417560A1
A small scale high-pressure electrolyzer for generating hydrogen and oxygen is provided comprising one or more units each comprising a plurality of high-pressure electrolytic cells, wherein the electrolytic cells of each unit are electrically connected in series, as well as a central electrolyt header, functionally connected to each electrolytic cell for the supply of liquid electrolyt to the cell; a central hydrogen header connected to each electrolytic cell for the discharge of generated hydrogen from the cell; a central oxygen header connected to each electrolytic cell for the discharge of generated oxygen from the cell; a direct current power source for the power supply to each unit of serially connected electrolytic cells; wherein the units of serially connected electrolytic cells are electrically connected in parallel.
Resumen de: DK202370641A1
0083 Disclosed is an electrolysis cell element (1) comprising, a support structure (2) comprising an inner aperture (3), and a bipolar plate (4) being suspended in the inner aperture (3). The support structure (2) comprises a structure core (5) and a coating (6), wherein the coating (6) includes a thermoplastic material at least partly enclosing the structure core (5) and wherein the bipolar plate (4) is suspended in the inner aperture (3) by means of the coating (6). 0084 An electrolysis cell stack (10) and use of an electrolysis cell stack (10) is also disclosed.
Resumen de: AU2023303893A1
An estimation system for estimating current efficiency of an electrolyser comprises a data processing system (105) for computing heat loss of the electrolyser based on specific heat capacity of electrolyte, a flow rate of the electrolyte in a cathode side of the electrolyser, a flow rate of the electrolyte in an anode side, a temperature difference (T1c - T0c) between electrolyte circulation outlet and inlet of the cathode side, and a temperature difference (T1a - T0a) between electrolyte circulation outlet and inlet of the anode side. The current efficiency is estimated based on a difference between electric power supplied to the electrolyser and the computed estimate of the heat loss, and on a product of thermoneutral voltage of electrolysis cells of the electrolyser and electric current supplied to the electrolyser.
Resumen de: CN119497764A
The present invention relates to a method for operating a high temperature solid oxide electrolysis system suitable for converting a fuel stream into a product stream and a system for implementing the method. The method includes drying the moist purge gas and using the waste purge gas as a regeneration gas in the drying unit.
Resumen de: JP2024023781A
To provide a hydrogen production cell of which a thickness per cell is reduced as compared with a conventional one.SOLUTION: A hydrogen side current collector 12 and an oxygen side current collector 13 are arranged on both sides of an electrolyte membrane 11. A separator 14 with a flat surface is arranged outside the hydrogen side current collector 12. A flow passage forming plate 15 and a separator 16 are arranged outside the oxygen side current collector 13. Since a flow passage dedicated for collecting water and a hydrogen gas generated when electrolysis is performed is not formed between the hydrogen side current collector 12 and the separator 16, the thickness of the cell itself can be reduced. These reaction fluids generated during the electrolysis are discharged from the inside of the hydrogen side current collector 12.SELECTED DRAWING: Figure 3
Resumen de: US2025223163A1
A highly crystalline mesoporous sulphur functionalized carbon nitride and a process for producing the same. The process including the steps of: providing a carbon nitride precursor material; mixing the carbon nitride precursor material with a metal salt to form a first mixture; and, thermally treating the first mixture to produce the crystalline carbon nitride.
Resumen de: WO2025147215A1
The present disclosure relates to a bipolar hydrogen production system and a method for producing hydrogen gas from the bipolar hydrogen production system. The system comprises a silver-based anodic catalyst deposited on an anode electrode, a cathode electrode, and an alkaline electrolyte containing an organic compound with aldehyde functional group extracted from lignocellulosic biomass waste or an aldehyde-containing chemical compound extracted from chemical waste.
Resumen de: WO2025146950A1
The present invention relates to a system for producing hydrogen while interworking with a nuclear power plant, the system comprising: a water electrolysis facility for producing hydrogen and oxygen by using vapor supplied from a nuclear power plant; and a power supply controller for selecting at least one reactor module from multiple reactor modules for hydrogen production by the water electrolysis facility, and selecting at least one from multiple generators or power grids such that power is supplied therefrom to the water electrolysis facility. According to an embodiment, power and hydrogen can be simultaneously produced. Particularly, hydrogen can be produced continuously in an economical and effective manner by selecting an optimal reactor module from multiple reactor modules for hydrogen production and by selecting an optimal power supply source from various power sources.
Resumen de: US2025223707A1
Provided is a power generation system (100) comprising: a gas turbine (10) for combusting air compressed by a compressor (11) and a fuel gas using a combustor (12) to generate combustion gas and drive a turbine (13) and a compressor connected to the turbine using the combustion gas; a heat storage structure (30) heated by the combustion gas with which the turbine is driven; a boiler (40) for generating steam using heat stored in the heat storage structure (30); and a solid oxide electrolytic cell (50) having a hydrogen electrode (51), an oxygen electrode (52), and an electrolyte layer (53) positioned between the hydrogen electrode and the oxygen electrode, the solid oxide electrolytic cell (50) supplying steam generated by the boiler (40) to the hydrogen electrode (51) to generate hydrogen through steam electrolysis.
Resumen de: US2025223714A1
Provided are a proton conductor 2 obtained by molding a solid electrolyte ceramic using hydrogen ions or ions containing hydrogen as charge carriers into a flat plate shape or a curved surface shape; a pair of hydrogen permeable electrode bodies 31 and 32 that have hydrogen permeability and conductivity and are formed of a solid that is airtight to gases other than hydrogen, and are arranged so as to sandwich the hydrogen ion conductive solid; a pair of media 41 and 42 arranged so as to sandwich the proton conductor 2 and the pair of hydrogen permeable electrode bodies 31 and 32; and a power supply 5 that applies a voltage between the pair of hydrogen permeable electrode bodies 31 and 32 to induce a current.
Resumen de: US2025223713A1
An electrochemical cell for a high-pressure electrolyzer contains a closed cell frame made of a high-pressure-resistant first material; an electrochemical reaction region, which is arranged completely inside the cell frame and contains an anodic half-cell and a cathodic half-cell; a gap, which spatially separates the reaction region from the cell frame; and a second material introduced into the gap. The second material is an electrical insulator, and the second material has a lower diffusion coefficient with respect to the entry of foreign ions into the reaction region. A plurality of the electrochemical cells are used to form a cell stack and the cell stack is used to form a high-pressure electrolyzer.
Resumen de: US2025223546A1
Microorganisms and bioprocesses are provided that convert gaseous substrates, such as renewable H2 and waste CO2 producer gas, or syngas into high-protein biomass that may be used directly for human nutrition, or as a nutrient for plants, fungi, or other microorganisms, or as a source of soil carbon, nitrogen, and other mineral nutrients. Renewable H2 used in the processes described herein may be generated by electrolysis using solar or wind power. Producer gas used in the processes described herein may be derived from sources that include gasification of waste feedstock and/or biomass residue, waste gas from industrial processes, or natural gas, biogas, or landfill gas.
Resumen de: US2025223547A1
Microorganisms and bioprocesses are provided that convert gaseous substrates, such as renewable H2 and waste CO2 producer gas, or syngas into high-protein biomass that may be used directly for human nutrition, or as a nutrient for plants, fungi, or other microorganisms, or as a source of soil carbon, nitrogen, and other mineral nutrients. Renewable H2 used in the processes described herein may be generated by electrolysis using solar or wind power. Producer gas used in the processes described herein may be derived from sources that include gasification of waste feedstock and/or biomass residue, waste gas from industrial processes, or natural gas, biogas, or landfill gas.
Resumen de: AU2024211141A1
The invention provides an electrolyser system (10) comprising a heat storage unit (14) and an electrolyser (16). The heat storage unit (14) comprises at least one heat source infeed. The electrolyser (16) comprises at least one electrolyser cell (20), a steam inlet and at least one off-gas outlet. The off-gas outlet is connected to the heat source infeed to heat the heat storage unit (14). The heat storage unit (14) is configured to use its stored heat to produce steam for feeding into the steam inlet and for generating electrical power, either one at a time or both at the same time. The invention also provides a system comprising an intermittent or variable electricity source (12) and an electrolyser system (10) as defined above. The intermittent or variable electricity source (12) can be configured to power the electrolyser (16) and to heat the heat storage unit (14) via a heating element, either both at the same time or individually.
Resumen de: AU2023331556A1
The invention relates to a photoelectric cell with a silicon carbide electrode (4) for photocatalytic production of hydrogen and to a production method for same. The cell has, on one side of the silicon carbide electrode (4), a window (2) for letting in light (5) and, on the other side of the silicon carbide electrode (4), an aqueous electrolyte (10) and a counter electrode (6). The cell is electrolyte-free on the side of the silicon carbide electrode (4) facing the window. The silicon carbide electrode (4) is preferably produced by coating a substrate (3) with silicon carbide (4).
Resumen de: EP4582594A1
The present invention discloses a water electrolysis device including a metal particle fluidic electrode. The water electrolysis device of the present invention includes a cathode; a first fluid channel formed on the cathode; a cation exchange membrane (CEM) formed on the first fluid channel; a second fluid channel formed on the cation exchange membrane; and an anode formed on the second fluid channel, wherein the second fluid channel includes metal particles and is used as a metal particle fluidic electrode.
Resumen de: EP4582593A1
A membrane electrode assembly 6 for a water electrolysis cell includes a polymer electrolyte membrane 1 having a first main surface 1A and a second main surface 1B, a first electrode catalytic layer 2 disposed to the first main surface 1A of the polymer electrolyte membrane 1, a second electrode catalytic layer 3 disposed to the second main surface 1B of the polymer electrolyte membrane 1, an annular outer peripheral film 4 disposed to surround an outer peripheral surface of the polymer electrolyte membrane 1, and a first adhesive film 5A having a substrate layer 51 and an adhesive agent layer 52. The first main surface 1A of the polymer electrolyte membrane 1 has a first annular non-covered section 1AN that is not covered with the first electrode catalytic layer 2 along an outer periphery of the first main surface, and the adhesive agent layer 52 of the first adhesive film 5Ais adhered to the first annular non-covered section 1AN of the polymer electrolyte membrane 1 and to a main surface 4A of the outer peripheral film 4 at the same side as the first main surface 1A of the polymer electrolyte membrane 1.
Resumen de: CN119866395A
A membrane electrode assembly (MEA) for generating hydrogen gas in a water electrolyser is provided. The MEA comprises a polymer electrolyte membrane (REM); a cathode comprising a cathode catalyst on a first side of the REM; an anode comprising an anode catalyst on a second side of the REM; and a platinum-ruthenium (Pt-Ru) catalyst on a second side of the REM to electrochemically convert hydrogen to hydrogen cations in use. The Pt-Ru catalyst is in electrical contact with the anode and in contact with the REM ions.
Resumen de: EP4582589A1
The present application belongs to the technical field of electrolytic hydrogen production, and particularly relates to a direct air electrolytic hydrogen production system. The system comprises an energy supply module, an electrolytic hydrogen production module, an electrolyte recycling module and a moisture vapor self-trapping module, wherein the energy supply module is connected to the electrolytic hydrogen production module; the electrolytic hydrogen production module comprises an electrolyzer; and the electrolyte recycling module is connected to the electrolytic hydrogen production module and the moisture vapor self-trapping module separately. The system may realize direct air electrolytic hydrogen production, while its energy consumption for electrolysis is comparable to that of industrial pure water electrolysis for hydrogen production, without additional energy consumption for desalination/purification of impure water solutions or for harvesting moisture from the air. The system greatly broadens the range of hydrogen energy sources without time and space limitation, providing technical support for future distributed hydrogen energy arrangement.
Resumen de: GB2636962A
An electrolyser system (10) and a method of operating an electrolyser system (10), the electrolyser system (10) comprising an electrolyzer (16) and a metal hydride or adsorption-desorption compressor (24), where the electrolyser (16) has at least one electrolyser cell with a steam input (22) and at least one gas output. The method comprises supplying steam through a first side of the electrolyser cell at the steam input (22), operating the electrolyser (16) to split part of the steam into hydrogen and oxygen in the at least one electrolyser cell, venting a mixture of the hydrogen and the remaining steam from the first side of the electrolyser cell at the at least one gas output (18), passing the mixture into the metal hydride or adsorption-desorption compressor (24), and cryo-adsorbing the hydrogen of the mixture in the metal hydride or 15 adsorption-desorption compressor (24) to compress the hydrogen and desorbing the compressed hydrogen from the metal hydride or adsorption-desorption compressor (24). The electrolyser system (10) is connected to a source of cold waste gas to operate the cryo-adsorption.
Resumen de: CN119866392A
A coating method for an electrolytic cell assembly is provided. The method includes coating at least a portion of the component with an acidic solution of platinum cations, and reducing the coated platinum cations with a reducing agent to form a layer of platinum metal on the component.
Resumen de: EP4582592A1
An alkaline water electrolysis apparatus includes: a separation membrane including a first main surface and a second main surface opposite to the first main surface; a first electrode including a third main surface and a fourth main surface opposite to the third main surface, the third main surface being provided to face the first main surface of the separation membrane; and a first bipolar plate including a fifth main surface, the fifth main surface being provided in contact with the fourth main surface of the first electrode, wherein the first electrode consists of a first metal porous body having a three-dimensional mesh structure.
Resumen de: AU2023405114A1
The invention relates to an electrolysis system (1) comprising an electrolyser (3) for producing hydrogen (H
Resumen de: CN115976552A
The invention provides an electrolytic bath which comprises a cathode end plate, a cathode insulating layer, an electrolytic unit, an anode insulating layer and an anode end plate which are sequentially arranged in the same direction, and the electrolytic unit comprises small electrolytic chambers which are arranged in series; from the cathode insulating layer to the anode insulating layer, each small electrolysis chamber comprises a cathode plate, a cathode sealing ring, a cathode gas diffusion layer, a diaphragm, an anode gas diffusion layer, an anode sealing ring and an anode plate which are sequentially arranged, and the cathode plates and the anode plates at the series connection parts between the small electrolysis chambers are combined to form a bipolar plate; the cathode plate comprises a cathode surface, the anode plate comprises an anode surface, the bipolar plate comprises a cathode surface and an anode surface, the cathode surface and the anode surface are provided with a concave area and an outer frame area, the outer frame area surrounds the concave area, the concave area is respectively provided with two confluence runners, and a branch runner is arranged between the two confluence runners; and the two ends of the branch flow channel are communicated with the confluence flow channel. According to the scheme, uniform diffusion of the electrolyte is realized.
Resumen de: AU2023374771A1
Cell for forming an electrolyser comprising at least one diaphragm or membrane having a first side and a second side opposite the first side, a first cell plate, arranged on the first side of the diaphragm, provided with a first electrode, provided with an inlet channel for supplying or draining electrolyte to or from the electrode, provided with a first discharge channel for discharging oxygen from the electrode, at least one second cell plate, arranged on the second side of the diaphragm, provided with a second electrode and provided with a second discharge channel for discharging hydrogen from the electrode wherein the at least one first and second cell plate are made of a polymer material.
Resumen de: US2022235426A1
Methods and systems for producing steel or similar molten-iron-containing materials in melting or smelting furnaces utilizing pre-reduced iron ore, known also as direct reduced iron (DRI) or sponge iron, wherein the emission of CO2 and other greenhouse gases is significantly low. Such methods and systems are based on producing DRI in a direct reduction furnace with a reducing gas comprising hydrogen; melting at least a portion of the DRI in a melting furnace in order to generate hot gases; producing steam and/or hot water using the heat contained in the hot gases. From the steam and/or hot water hydrogen is produced by electrolysis, at least a portion of which is fed to the direct reduction furnace as a component of the reducing gas to produce the DRI.
Resumen de: TW202507200A
A power generator is described that provides at least one of electrical and thermal power comprising (i) at least one reaction cell for reactions involving atomic hydrogen hydrogen products identifiable by unique analytical and spectroscopic signatures, (ii) a molten metal injection system comprising at least one pump such as an electromagnetic pump that provides a molten metal stream to the reaction cell and at least one reservoir that receives the molten metal stream, and (iii) an ignition system comprising an electrical power source that provides low-voltage, high-current electrical energy to the at least one stream of molten metal to ignite a plasma to initiate rapid kinetics of the reaction and an energy gain. In some embodiments, the power generator may comprise: (v) a source of H2 and O2 supplied to the plasma, (vi) a molten metal recovery system, and (vii) a power converter capable of (a) converting the high-power light output from a blackbody radiator of the cell into electricity using concentrator thermophotovoltaic cells or (b) converting the energetic plasma into electricity using a magnetohydrodynamic converter.
Resumen de: AU2024200214A1
MAGNETOHYDRODYNAMIC ELECTRIC POWER GENERATOR A power generator that provides at least one of electrical and thermal power comprising (i) at least one reaction cell for the catalysis of atomic hydrogen to form hydrinos identifiable by unique analytical and spectroscopic signatures, (ii) a reaction mixture comprising at least two components chosen from: a source of H20 catalyst or H20 catalyst; a source of atomic hydrogen or atomic hydrogen; reactants to form the source of H20 catalyst or H20 catalyst and a source of atomic hydrogen or atomic hydrogen; and a molten metal to cause the reaction mixture to be highly conductive, (iii) a molten metal injection system comprising at least one pump such as an electromagnetic pump that causes a plurality of molten metal streams to intersect, (iv) an ignition system comprising an electrical power source that provides low-voltage, high-current electrical energy to the plurality of intersected molten metal streams to ignite a plasma to initiate rapid kinetics of the hydrino reaction and an energy gain due to forming hydrinos, (v) a source of H2 and 0 2 supplied to the plasma, (vi) a molten metal recovery system, and (vii) a power converter capable of (a) converting the high power light output from a blackbody radiator of the cell into electricity using concentrator thermophotovoltaic cells or (b) converting the energetic plasma into electricity using a magnetohydrodynamic converter.
Resumen de: US2023023539A1
A method for generating hydrogen and oxygen using an electrolyzer, including at least one anode chamber having an anode and at least one cathode chamber having a cathode, wherein the at least one anode and the at least one cathode are energized by a modulated current and the generation of hydrogen and oxygen takes place within the electrolyzer using a defined pulse pattern sequence, which is formed from at least one pulse pattern.
Resumen de: KR20250102672A
본 발명은 수소발생전극 촉매의 산화를 억제하는 수전해 시스템에 관한 것으로, 본 발명에 따르면, 수소발생전극 및 전해질을 포함하는 수소발생부와, 산소발생전극 및 전해질을 포함하는 산소발생부와, 상기 수소발생부와 산소발생부 사이에 위치하는 분리막과, 상기 수소발생부와 산소발생부의 전극들에 전원을 공급하는 전원공급장치를 포함하는 수전해 시스템에서, 수소발생부의 전해질로서 알카라인 전해질 또는 중성 전해질에 저가의 소재인 아황산염을 포함하는 첨가제를 첨가함으로써, 분리막을 통해 크로스오버된 산소 분자 또는 상기 수소발생부의 전해질 내에 용존하는 산소 분자와 아황산염이 우선 반응하여 수소발생전극의 산화를 억제하여, 이로 인한 수소발생전극 촉매의 열화를 감소시켜 수소 생산 효율 및 수소발생전극의 수명을 증가시킬 수 있다.
Resumen de: WO2025143640A1
Disclosed is a hydrogen gas purification method for increasing the recovery rate and purity of purified hydrogen gas. According to one aspect, provided is a hydrogen gas purification method comprising purifying a mixed gas produced by an electrolysis method and containing chlorine gas and hydrogen gas.
Resumen de: WO2024240539A1
The invention discloses a gas generator (20) for a tool comprising an electrolytic cell (30) for producing oxyhydrogen gas with a hollow cell body (31) and an electrode pair (32) with a first electrode (33) and a second electrode (35). Said first electrode (33) and said second electrode (35) are separated by a non-conductive separator (37) in said hollow cell body (31). A gas extraction tube (55) is arranged in the hollow cell body (31). Furthermore, said invention disclose a usage of such a gas generator in a tool and a tool with such a gas generator.
Resumen de: KR20250101425A
본 발명은 태양-수소 변환 효율이 향상된 무선 광전지-전기화학 시스템에 관한 것으로서, 태양광을 이용하여 발전하는 태양전지부, 태양전지부에 연결된 애노드 전극부, 및 태양전지부에 연결된 캐소드 전극부를 포함하며, 애노드 전극부는 CuNiFe-LDH를 포함하도록 구성되고, 캐소드 전극부는 NiFe2O4를 포함하도록 구성된다. 또한, 태양전지부는 비정질 실리콘(a-Si:H)/a-Si:H/미세결정 실리콘(μc-Si:H)의 삼원접합 박막 태양전지를 포함하여 구성될 수 있다. 본 발명에 따른 무선 광전지-전기화학 시스템은 우수하고 안정적인 작동 및 유망한 효율과 내구성을 보이면서도 높은 수소 생산량을 나타낼 수 있다. 구체적인 예로서, 비정질 실리콘(a-Si:H)/a-Si:H/미결정 실리콘(μc-Si:H) 삼원접합 박막 태양전지에 CuNiFe-LDH/Ni 섬유 종이(NFP) 양극 및 NiFe2O4/NFP 음극을 결합하여, 11.08%의 태양광-수소(STH) 효율을 달성하였다.
Resumen de: WO2024150467A1
Provided is a solid electrochemical device comprising: a solid electrolyte which has a first main surface and a second main surface that is opposite from the first main surface; a first electrode which has a third main surface and a fourth main surface that is opposite from the third main surface and which is provided such that the third main surface faces the first main surface; a first current collector which has a fifth main surface and a sixth main surface that is opposite from the fifth main surface and which is provided such that the fifth main surface faces the fourth main surface; and a first interconnector which has a seventh main surface and which is provided such that the seventh main surface faces the sixth main surface, wherein the seventh main surface of the first interconnector is a flat surface, the first current collector includes a first porous metal body that has a three-dimensional network structure, and the fifth main surface has a plurality of first through-holes that are formed so as to extend along a first direction from the fifth main surface to the sixth main surface.
Resumen de: AU2024233949A1
An electrolysis cell according to the present disclosure is provided with: a first separator; a second separator; an anion exchange membrane disposed between the first separator and the second separator; a negative electrode disposed between the first separator and the anion exchange membrane; and a positive electrode disposed between the second separator and the anion exchange membrane. The first separator has a flow path for supplying an electrolyte solution to the negative electrode, and hydrogen and hydroxide ions are produced at the negative electrode by consuming at least some of the electrolyte solution supplied from the flow path. The second separator does not have a flow path for supplying the electrolyte solution to the positive electrode, and oxygen and water are produced at the positive electrode from the hydroxide ions that have come from the negative electrode through the anion exchange membrane, in a state where the electrolyte solution is not supplied to the positive electrode.
Resumen de: WO2025143203A1
The present disclosure addresses the problem of providing a solid polymer electrolyte membrane which is capable of suppressing occurrence of curl and suppressing crossover of hydrogen. The present disclosure also addresses the problem of providing: a membrane electrode assembly; a water electrolysis device; and a method for producing a membrane electrode assembly. A solid polymer electrolyte membrane according to the present disclosure comprises: a first layer that contains a first fluorine-containing polymer which has an ion exchange group and a platinum-containing material; and a second layer that contains a second fluorine-containing polymer which has an ion exchange group. The concentration of the platinum-containing material in the second layer is lower than the concentration of the platinum-containing material in the first layer, and the ion exchange capacity of the first fluorine-containing polymer is higher than the ion exchange capacity of the second fluorine-containing polymer. This solid polymer electrolyte membrane further has a reinforcement body that is disposed closer to the first layer-side surface of the solid polymer electrolyte membrane than the center position of the solid polymer electrolyte membrane in the thickness direction.
Resumen de: WO2025143143A1
Provided is a solid polymer electrolyte membrane which is capable of suppressing an increase in electrolytic voltage after water electrolysis is performed for a certain period, and in which pinholes are hardly generated. This solid polymer electrolyte membrane includes: a fluorine-containing polymer having an ion exchange group; a platinum-containing material; aggregates of cerium oxide particles; and a woven fabric. The average particle diameter of the aggregates is 0.1-10 μm.
Resumen de: WO2025142931A1
Resumen de: WO2025142740A1
A methanol production method comprising: a step (A) for acquiring a synthesis gas comprising at least carbon dioxide and hydrogen; a step (B) for reacting the synthesis gas in the presence of a catalyst to obtain a methanol mixture; a step (C) for distilling the methanol mixture to separate out each of methanol, a distillation waste liquid, and distillation wastewater; and a step (D) for subjecting the distillation waste liquid and/or the distillation wastewater to an organic matter decomposition treatment to obtain a decomposition gas and treated water.
Resumen de: AU2023300562A1
Bipolar plates (1) adapted for use in an electrolyser cell stack (4) and wherein each plate comprises a plate midplane (2) whereby the plate (1) comprises spaced apart uniform spacers (7) extending in opposed directions from the midplane (2). All spacers (7) are arranged along concentric circles (8) in the midplane (2) with spacers (7) alternatingly protruding in opposite directions relative to the midplane (2) along each concentric circle (8) and an even number of spacers (7) are provided in each circumferential circle (8), apart from an innermost circle (9) which comprises a single spacer (7).
Resumen de: WO2025142261A1
In order to provide a water electrolysis device and an operation controlling method for the water electrolysis device which, when the operation is stopped, are capable of reducing energy consumption and suppressing deterioration of an electrolyte membrane due to hydrogen peroxide generated in a cathode-side hydrogen flow passage when the operation is stopped, this operation controlling method for a water electrolysis device having at least one water electrolysis cell which is divided into an anode-side oxygen flow passage 5 and a cathode-side hydrogen flow passage 6 by an electrolyte membrane, electrolyzes pure water supplied to the oxygen flow passage 5, and discharges hydrogen from the hydrogen flow passage 6 comprises: supplying pure water to the oxygen flow passage 5 during the operation of the water electrolysis device; when the operation of the water electrolysis device is stopped, stopping the supply of pure water to the oxygen flow passage 5, and supplying pure water to the hydrogen flow passage 6 for a prescribed period of time and discharging the same to the outside; and then stopping the supply of pure water to the hydrogen flow passage 6.
Resumen de: AU2025204349A1
Abstract: A system for extracting hydrogen gas from a liquid hydrogen carrier may include a hydrogen gas reactor, a catalyst for facilitating extraction of the hydrogen gas from the liquid hydrogen carrier, and a reservoir for containing the liquid hydrogen carrier and a spend liquid hydrogen carrier. The system may be configured to regulate a flow of liquid hydrogen carrier in and out of the hydrogen gas reactor, to move a catalyst relative to a volume of the liquid hydrogen carrier, and to provide a continuous flow of the hydrogen gas, in response to a demand for the hydrogen gas. Abstract: A system for extracting hydrogen gas from a liquid hydrogen carrier may include a hydrogen gas reactor, a catalyst for facilitating extraction of the hydrogen gas from the liquid hydrogen carrier, and a reservoir for containing the liquid hydrogen carrier and a spend liquid hydrogen carrier. The system may be configured to regulate a flow of liquid hydrogen carrier in and out of the hydrogen gas reactor, to move a catalyst relative to a volume of the liquid hydrogen carrier, and to provide a continuous flow of the hydrogen gas, in response to a demand for the hydrogen gas. un b s t r a c t : s y s t e m f o r e x t r a c t i n g h y d r o g e n g a s f r o m a l i q u i d h y d r o g e n c a r r i e r m a y i n c l u d e a h y d r o g e n g a s r e a c t o r , a c a t a l y s t f o r f a c i l i t a t i n g e x t r a c t i o n o f t h e h y d r o g e n g a s f r o m t h e l i q u i d h y
Resumen de: DE102024126314A1
Elektrolysesystem (20) zur Gewinnung von Wasserstoff, mit mindestens einer Elektrolysevorrichtung (23), die zur Gewinnung des Wasserstoffs aus Prozesswasser mit Hilfe von elektrischem Strom eingerichtet, mit einem von dem Prozesswasser durchströmten Prozesswasserkreislauf (21), in den zusätzlich zu der mindestens einen Elektrolysevorrichtung (23) ein Wärmetauscher (24) eingebunden ist, der ferner in einen Kühlwasserkreislauf (22) eingebunden ist, und der eingerichtet ist, das Prozesswasser dadurch bedarfsweise zu kühlen, dass Wärme des Prozesswassers über den Wärmetauscher (24) auf durch den Kühlwasserkreislauf strömendes Kühlwasser übertragbar ist, wobei dem Prozesswasserkreislauf (21) ferner mindestens eine Heizeinrichtung (26) zugeordnet ist, die eingerichtet ist, das Prozesswasser bedarfsweise zu erwärmen.
Resumen de: US2025214034A1
Hydrogen gas purifier electrochemical cells, systems for purifying hydrogen gas, and methods for purifying hydrogen gas are provided. The cells, systems, and methods employ double membrane electrode (DMEA) electrochemical cells that enhance purification while avoiding the complexity and cost of conventional cells. The purity of the hydrogen gas produced by the cells, systems, and methods can be enhanced by removing at least some intermediate gas impurities from the cells. The purity of the hydrogen gas produced by the cells, systems, and methods can also be enhanced be introducing hydrogen gas to the cells to replenish any lost hydrogen. Water electrolyzing electrochemical cells and methods of electrolyzing water to produce hydrogen gas are also disclosed.
Resumen de: US2025214037A1
Embodiments of the present disclosure are directed to systems and methods of removing carbon dioxide from a gaseous stream using magnesium hydroxide and then regenerating the magnesium hydroxide. In some embodiments, the systems and methods can further comprise using the waste heat from one or more gas streams to provide some or all of the heat needed to drive the reactions. In some embodiments, magnesium chloride is primarily in the form of magnesium chloride dihydrate and is fed to a decomposition reactor to generate magnesium hydroxychloride, which is in turn fed to a second decomposition reactor to generate magnesium hydroxide.
Resumen de: US2025215602A1
Apparatus is provided for treating an electrode in an electrochemical cell. The electrode is treated to evolve catalytic oxide layers on the electrode surface, which make the electrode suitable for use in hydrogen production. The apparatus includes a signal generator, a switching arrangement, and a filtering stage including a differential choke and the common mode choke, to supply power to the electrochemical cell for commercial scale treatment and production of electrodes.
Resumen de: US2025215591A1
Electrolysis techniques and system implementations are disclosed comprising a plurality of reactors, each comprising electrolysis electrodes and configured to carry out a sequence of phases of an electrolysis process phase-shifted with respect to a sequence of phases of the electrolysis process carried out by at least another one of said plurality of reactors, one or more power sources for driving the electrolysis processes carried out by the plurality of reactors, and a control system configured to monitor changes in a power capacity of at least one of the one or more power sources and based thereon perform at least one of the following: (i) activate or deactivate one or more of the electrolysis processes carried out by the plurality of reactors, (ii) adjust a time duration of at least one of the phases of the electrolysis process; (iii) adjust the power supplied to at least one of the plurality of reactors from the one or more power sources; and/or (iv) adjust, remove or introduce, at least one phase of the electrolysis process.
Resumen de: US2025215588A1
Described are a gas-permeable electronically conductive plate for use as porous transport layer for an electrolyzer and a process for preparing said gas-permeable electronically conductive plate. a building unit for an electrolyzer, and an electrolyzer.
Resumen de: US2025215587A1
The present invention relates to a non-combustion heat source preferably integrated with a net-positive electricity hydrogen production system and integral feedforward control system maximizing value creation by enabling superior high-radiant heat transfer and energy efficiency while minimizing carbon dioxide footprint. The feedforward control system further enhances broad system performance including determining optimal combustion emissivity and waste heat recovery operations.
Resumen de: US2025215590A1
An object of the present invention is to provide an electrolyte membrane having a good durability when performing water electrolysis. The gist of the present invention is an electrolyte membrane including: a first electrolyte layer having a first main surface and a second main surface; and a second electrolyte layer provided on the first main surface of the first electrolyte layer; wherein the first electrolyte layer has a thickness of 40 μm or more and 250 μm or less, and contains a polymer electrolyte; and wherein the second electrolyte layer contains a polymer electrolyte and carbon particles.
Resumen de: US2025215576A1
Systems and methods for increased oxygen output from an electrolyzer system are provided. The electrolyzer system includes a water storage tank. The electrolyzer system also includes an electrolyzer in fluid communication with the water storage tank and configured to produce oxygen and hydrogen from water e.g., (H2O). The electrolyzer system also includes one or more pressure isolating components configured to increase the oxygen output pressure of the system by pressure isolating the water storage tank from the electrolyzer stack.
Resumen de: US2025219549A1
A system comprises at least one transformer for galvanically isolating the system from an electrical power grid and adapting an input voltage level associated with an alternating current received from the electrical power grid. A converter unit connected to the transformer is configured to convert the alternating current into a direct current output between a positive pole and a negative pole. The converter unit comprises at least one modular multilevel converter comprising at least two converter branches. Each branch comprises a converter cell and an inductor. One branch is connected from an AC line of the transformer to the positive pole and another branch is connected from the AC line to the negative pole. An electrolyser unit may be arranged between the positive and negative poles, and a control unit may be configured to control the direct current output based on a reference value.
Resumen de: US2025219421A1
An HVDC system comprising an AC/DC converter sub-system electrically connected to a renewable energy equipment and a VSC sub-system is provided. A method comprises operating the renewable energy equipment to function as a voltage source to energize an HVDC link between the AC/DC converter sub-system and the VSC sub-system; operating the VSC sub-system as a voltage source to energize an electrical load electrically connected thereto; if it is determined the power production rate of the renewable energy equipment is not within a designated parameter, operating the equipment to follow the VSC sub-system such that controlling the AC electric power output influences the power production rate. If it is within the designated parameter, operating the VSC sub-system to follow the renewable energy equipment such that the VSC sub-system adjusts the properties of its AC electric output to match the properties of the electric power generated by the renewable energy equipment.
Resumen de: US2025215331A1
Production of fuels from low carbon electricity and from carbon dioxide by the use of a solid oxide electrolysis cell (SOEC) and Fischer-Tropsch is shown. Fischer-Tropsch is an exothermic reaction that can be used to produce steam. Steam produced from the Liquid Fuel Production (LFP) reactor system, where the Fischer-Tropsch reaction occurs, is used as feed to the SOEC. The higher temperature steam improves the efficiency of the overall electrolysis system. The integration of the LFP steam improves the efficiency of the electrolysis because the heat of vaporization for the liquid water does not have to be supplied by the electrolyzer.
Resumen de: WO2025140933A1
A method of transporting hydrogen comprising: forming an alcohol from hydrogen and carbon dioxide; transporting said alcohol; breaking down said alcohol to form carbon dioxide and hydrogen; using said hydrogen as a fuel; and capturing said carbon dioxide to transport for reuse in generating more alcohol.
Resumen de: WO2025140991A1
Systems and methods for increased oxygen output from an electrolyzer system are provided. The electrolyzer system includes a water storage tank. The electrolyzer system also includes an electrolyzer in fluid communication with the water storage tank and configured to produce oxygen and hydrogen from water e.g., (H2O). The electrolyzer system also includes one or more pressure isolating components configured to increase the oxygen output pressure of the system by pressure isolating the water storage tank from the electrolyzer stack.
Resumen de: WO2025141013A1
The invention relates to a plant for treating gases containing hydrogen sulphide (H2S), the plant comprising: - a Claus-type sulphur recovery unit (1), the sulphur recovery unit (1) receiving, as input: a first stream comprising a gas containing H2S and a second stream comprising a gas that comprises O2; - a high-temperature steam electrolysis unit receiving, as input, a first stream comprising water vapour and supplying, as output, a second stream comprising O2 gas and a third stream comprising H2 gas. The invention is characterised in that the plant further comprises a water vapour forming unit (3) comprising means for recovering the heat from the sulphur recovery unit (1), this heat being used to produce at least some of the water vapour of the first stream received by the electrolysis unit.
Resumen de: WO2025141005A1
The invention relates to a catalyst for the decomposition of ammonia into hydrogen and nitrogen, wherein the catalyst comprises at least ruthenium, mesoporous cerium oxide and at least one oxide selected from among cobalt, nickel and iron oxides, preferably nickel oxide, and to a method for producing hydrogen from ammonia comprising the following steps in this order: activating at least one catalyst according to the invention at a temperature ranging from 300°C to 600°C under a stream of a reducing gas; bringing the activated catalyst into contact with a gas to be treated comprising ammonia at a temperature ranging from 200°C to 800°C, and at a pressure ranging from atmospheric pressure to 100 bar.
Resumen de: KR20250100494A
본 발명은 암모니아를 전기분해하여 수소를 추출하는 수소 추출 시스템, 상기 수소 추출 시스템의 외부에 장착되어 가스 누출을 감지하는 가스 감지기, 상기 가스 감지 시스템과 연동되어 가스 누출 여부를 표시하는 가스 누출 표시기, 및 상기 가스 감지 시스템으로부터 가스 누출 신호를 전달받아 수소 추출 시스템의 작동을 비상 정지시키는 제어기를 포함하는 비상 감지 시스템에 관한 것이다.
Resumen de: KR20250100495A
본 발명은 암모니아 전기분해를 이용한 수소 생산 시스템에 있어서, 상기 수소 생산 시스템은 암모니아가 공급되는 혼합기; 상기 혼합기로부터 전달받은 암모니아를 수소와 질소로 전기분해하는 전해 셀; 및 상기 수소 및 상기 질소에 포함된 암모니아를 분리하는 하나 이상의 유체 분리기를 포함하며, 상기 유체 분리기 내의 미반응 암모니아 기체를 물에 용해시켜 외부로 배출하는 암모니아 제거 장치가 구비되어 안정성이 향상된 수소 생산 시스템에 관한 것이다.
Resumen de: WO2025143640A1
Disclosed is a hydrogen gas purification method for increasing the recovery rate and purity of purified hydrogen gas. According to one aspect, provided is a hydrogen gas purification method comprising purifying a mixed gas produced by an electrolysis method and containing chlorine gas and hydrogen gas.
Resumen de: WO2025143151A1
Provided are a solid polymer electrolyte membrane having superior chemical durability, a membrane electrode assembly, and a water electrolysis device. The solid polymer electrolyte membrane according to the present disclosure comprises: a first membrane that contains a fluorine-containing polymer having an ion exchange group, and cerium oxide; and a second membrane that contains a fluorine-containing polymer having an ion exchange group and has a cerium oxide concentration lower than that of the first membrane. When the ratio of the thickness of the first membrane to the total thickness of the first membrane and the second membrane at an end part of the solid polymer electrolyte membrane is defined as ratio X, and the ratio of the thickness of the first membrane to the total thickness of the first membrane and the second membrane at the center of the solid polymer electrolyte membrane is defined as ratio Y, ratio X is greater than ratio Y.
Resumen de: WO2025143145A1
The present invention provides: a solid polymer electrolyte membrane which is excellent in terms of low gas permeability; a membrane electrode assembly; and a water electrolysis device. A solid polymer electrolyte membrane according to the present disclosure comprises: a first membrane which contains a fluorine-containing polymer that has an ion exchange group, and a platinum-containing material; and a second membrane which contains a fluorine-containing polymer that has an ion exchange group, and which has a lower concentration of the platinum-containing material than the first membrane. If a ratio X is the ratio of the thickness of the first membrane to the total thickness of the thickness of the first membrane and the thickness of the second membrane at an end of the solid polymer electrolyte membrane, and a ratio Y is the ratio of the thickness of the first membrane to the total thickness of the thickness of the first membrane and the thickness of the second membrane at the central part of the solid polymer electrolyte membrane, the ratio X is greater than the ratio Y.
Resumen de: WO2025143156A1
Provided is a solid polymer electrolyte membrane that resists tearing and, when employed in a water electrolysis device, resists the generation of pinholes. The solid polymer electrolyte membrane contains an ion-exchange group-bearing fluoropolymer and a woven fabric composed of a warp and a weft. When the solid polymer electrolyte membrane is observed from the direction normal to a surface of the solid polymer electrolyte membrane, the standard deviation on the area of regions delimited by the warp and the weft is 0.10 × 104 to 2.0 × 104 μm2.
Resumen de: WO2024041751A1
The invention relates to a method and a device for producing a cracked gas (7) comprising hydrogen and nitrogen from an ammonia-rich input (1) that is more than 50% ammonia by volume, wherein ammonia present in the ammonia-rich input (1) is cracked in a cracker furnace (C) with catalytic assistance at a cracking pressure above 5 bar and a cracking temperature of at least 500°C in order to obtain the cracked gas (7) comprising hydrogen and nitrogen. The invention is characterised in that the ammonia-rich input (1) undergoes catalytically assisted pre-cracking (V), during which some of the ammonia present in the input (1) is separated into hydrogen and nitrogen and an input (5) comprising ammonia for the cracker furnace (C) is obtained.
Resumen de: GB2636681A
An electrolyser system (10) is described. The system (10) comprises at least one electrolyser (20), where the electrolyser (20) comprises at least one steam inlet (41) and at least one off-gas outlet (38; 39). A turbocharger (62) is also present for compressing off-gas from the electrolyser (20). The turbocharger (62) comprises a drive fluid inlet, a drive fluid outlet, a compression fluid inlet, a compressed fluid outlet, a compressor (13) and a turbine (12). The turbine (12) is configured to drive the compressor (13). The drive fluid outlet of the turbocharger (62) is fluidically connected to the at least one steam inlet (41) of the electrolyser (20). The at least one off-gas outlet (38; 39) of the electrolyser (20) is fluidically connected to the compression fluid inlet of the turbocharger (62). The system (10) can further comprise a steam source fluidically connected to the drive fluid inlet of the turbocharger (62) for powering the turbine (12) using pressurised steam.
Resumen de: GB2636885A
An electrolyser 10 which provides a hydrogen gas containing stream and a separate oxygen gas containing stream from an aqueous electrolyte is described. The electrolyser comprises a hollow locating member 32 defining a fluid conduit for receiving an electrolyte, where the hollow locating member has at least one opening 42. A fluid pump 26 is pumps electrolyte into and through the fluid conduit of the hollow locating member 32. The electrolyzer cell 12 has a stacked arrangement on the locating member 32. The stacked arrangement comprises at least one electrolysis cell 12. Each cell 12 comprises an anode 14 having a first side 11 and a second opposed side 13; and a cathode 16 having a first side 15 and a second opposed side 17, in which the first side of the anode 11 is positioned adjacent the first side of the cathode 15. A reaction chamber is defined between the first side of the anode and the first side of the cathode, in which the reaction chamber 18 is in fluid communication with the at least one opening 42 of the hollow locating member 32. Each cell 12 further comprise a magnet 30 positioned adjacent the second side of the anode 13; a first gas collection chamber 34a positioned adjacent the second side of the anode 13, in which the first gas collection chamber 34a is in fluid communication with the reaction chamber 18; and a second gas collection chamber 34b positioned adjacent the second side of the cathode 17, in which the second gas collection chamber 34b is in fluid c
Resumen de: AU2023327787A1
The invention provides an electrolytic cell, comprising: a working electrode; a counter electrode; a liquid electrolyte in contact with a working surface of the working electrode; an acoustically transmissive substrate comprising at least a piezoelectric substrate portion; one or more conductive electrodes coupled to the piezoelectric substrate portion and configured to propagate a high frequency acoustic wave having a frequency of at least 1 MHz across the acoustically transmissive substrate when electrically actuated; and one or more power supplies configured (i) to apply a potential between the working electrode and the counter electrode sufficient to electrolytically react a species in the liquid electrolyte, thereby producing an electrolytic reaction product proximate the working electrode, and (ii) to electrically actuate the one or more conductive electrodes, wherein the working electrode is either located on the acoustically transmissive substrate or spaced apart from the acoustically transmissive substrate by the liquid electrolyte, and wherein propagation of the high frequency acoustic wave across the acoustically transmissive substrate in operation of the electrolytic cell stimulates the liquid electrolyte, thereby increasing the production efficiency of the electrolytic reaction product.
Resumen de: GB2636726A
A hydrogen boiler comprises a self-producing hydrogen system, the hydrogen is produced by electrolysis. A cut off sensor 7.18 is attached to the system to prevent hydrogen leaks and a pressure regulator to keep the gas flow constant. A pressure cut off 7.13 turns off the hydrogen production when the tank is full. A flashback arrestor 8.6 prevents furnace flashback to the main oxyhydrogen production tank 2. The system may be powered by solar panels or standard AC power. The hydrogen is combusted in a furnace 3, which includes a heat exchanger 3.15 connected to the central heating system; heated water is then circulated to the radiators and hot water system. Water produced by the combustion of hydrogen is recovered and returned to the electrolyser. The system may also provide additional hot water systems 9 or a hot air system using a second electrolyser and furnace.
Resumen de: DK202370622A1
The invention relates to method for recovering carbon capture solvent from reactant streams in a power-to-X plant for methanol production, said power-to-X plant comprising an electrolyzer, a unit capturing COₓ with a carbon capture solvent, a syngas compressor and a methanol reactor, wherein the electrolyzer creates a H₂ stream and wherein the unit capturing COₓ creates a stream of COₓ. The carbon capture solvent is returned to the unit capturing COₓ.
Resumen de: EP4574255A1
In a method of preparing an ammonia decomposition catalyst according to embodiments of the present disclosure, a mixture of a metal oxide including lanthanum and a heterogeneous metal and aluminum oxide is prepared, the mixture was subj ected to steam treatment to form a carrier, and an active metal is supported on the carrier to prepare an ammonia decomposition catalyst. The ammonia decomposition catalyst according to embodiments of the present disclosure is prepared by the above-described preparation method.
Resumen de: DK202370621A1
The invention relates to a method for and a plant capable of abruptly shifting the electricity consumption in a Power-to-X methanol production facility. The facility comprising: - An electrolysis unit - A carbon capture unit - A compressor for compressing a stream of H₂ and a stream of COₓ into a syngas for methanol production - A methanol reactor having an operational pressure and comprising a catalyst for production of methanol - A recirculation system for recirculating unreacted H₂ and/or COₓ - A rerouting system for rerouting the stream of COₓ Where the ratios in changes in the streams are within range 0.2 to 5 for a time period t, where t is between 0.3 and 30 seconds.
Resumen de: DK202330403A1
An alkaline electrolyser comprising a stack (17) of electrolytic cells (1) is used for producing hydrogen gas (8). Purified hydrogen gas and purified oxygen gas is used for purging the corresponding cathode and anode compartments (5, 6) for preventing buildup of dangerous gas mixtures by gas crossover during stop, before starting, or when running production low.
Resumen de: KR20250098043A
본 발명에 따른 수소 생산 및 저장 장치는, 특정 에너지로 물을 전기분해하여 수소와 산소를 생산하기 위한 수전해 모듈; 상기 수전해 모듈에 의해 생산된 상기 수소를 압축하기 위한 고압 압축 모듈; 상기 고압 압축 모듈에 의해 압축된 수소를 저장하기 위한 수소 고압 탱크 모듈; 및 상기 수전해 모듈에 의해 생산된 수소를 일시적으로 저장한 후, 상기 고압 압축 모듈에 의해 압축되도록 하여, 압축 과정에서 발생되는 압력 차에 의한 상기 수전해 모듈의 손상을 방지하기 위한 수소 완충 탱크 모듈;을 포함하는 것을 특징으로 할 수 있다.
Resumen de: WO2025064007A1
A method for producing a hydrogen product having a carbon intensity less than about 0.45 kg C02e / kg H2 is provided. The method includes the steps of converting water to oxygen and the hydrogen product through an electrolysis process, providing at least some, and substantially all, of the required energy for the electrolysis process from a biomass power plant, and processing one or more flue gas streams from the biomass power plant in a carbon capture unit to reduce CO2emissions. The energy produced from the biomass power plant may comprise one or more of electricity, steam used as process steam in the electrolysis process, steam used as thermal energy in the electrolysis process, and steam used to power a mechanical drive for one or more compressors, pumps, or other motors generating shaft torque in the electrolysis process.
Resumen de: KR20250097071A
본 발명은 광 산란 기반 수상 태양광 수전해 시스템에 관한 것이다. 일 실시예에 따르면, 수상에 설치되는 광 산란 기반 수상 태양광 수전해 시스템에 있어서, 무기 나노입자를 포함하는 광 가이드 부재와 상기 광 가이드 부재의 전면측, 후면측, 좌면측 및 우면측 중 적어도 하나의 측면에 배치된 태양전지로 이루어진 광 가이드 투명 태양전지;를 포함하는 태양전지 모듈부; 및 상기 태양전지 모듈부와 전기적으로 연결되고, 태양광 에너지를 제공받아 수소 및 산소를 생산하는 수전해 모듈부;를 포함하는, 광 산란 기반 수상 태양광 수전해 시스템이 제공될 수 있다.
Resumen de: AU2023369983A1
The present invention relates to stack module with at least one Solid Oxide electrolysis stack that comprises a plurality of stacked Solid Oxide electrolysis cells, wherein the stack module comprises two gas inlet connections and two gas outlet connections. According to the invention, the at least one Solid Oxide electrolysis stack is encapsulated in a metal container, wherein the two gas inlet connections and the two gas outlet connections are attached to the metal container. The invention further relates to Solid Oxide Electrolyzer with at least one stack module and a method of exchanging a stack module of a Solid Oxide Electrolyzer.
Resumen de: WO2024150467A1
Provided is a solid electrochemical device comprising: a solid electrolyte which has a first main surface and a second main surface that is opposite from the first main surface; a first electrode which has a third main surface and a fourth main surface that is opposite from the third main surface and which is provided such that the third main surface faces the first main surface; a first current collector which has a fifth main surface and a sixth main surface that is opposite from the fifth main surface and which is provided such that the fifth main surface faces the fourth main surface; and a first interconnector which has a seventh main surface and which is provided such that the seventh main surface faces the sixth main surface, wherein the seventh main surface of the first interconnector is a flat surface, the first current collector includes a first porous metal body that has a three-dimensional network structure, and the fifth main surface has a plurality of first through-holes that are formed so as to extend along a first direction from the fifth main surface to the sixth main surface.
Resumen de: AU2023369983A1
The present invention relates to stack module with at least one Solid Oxide electrolysis stack that comprises a plurality of stacked Solid Oxide electrolysis cells, wherein the stack module comprises two gas inlet connections and two gas outlet connections. According to the invention, the at least one Solid Oxide electrolysis stack is encapsulated in a metal container, wherein the two gas inlet connections and the two gas outlet connections are attached to the metal container. The invention further relates to Solid Oxide Electrolyzer with at least one stack module and a method of exchanging a stack module of a Solid Oxide Electrolyzer.
Resumen de: KR20250097060A
본 발명은 선박이나 화물차에 의한 운송이 가능하도록 상자 모양으로 제작되고, 도어에 의해 내부가 개폐되는 컨테이너; 상기 컨테이너의 내측에 전기분해에 필요한 물을 공급하도록 마련되는 급수기; 상기 컨테이너의 내측에 전기분해에 필요한 전해액을 분배 공급하도록 마련되는 전해액분배기; 상기 급수기로부터 공급되는 물과 상기 전해액분배기로부터 전해액을 각각 분배 공급받아 전기분해에 의한 수소와 산소를 발생시키고, 상기 컨테이너의 내측에 좌우로 배열되면서 상하로 적층되도록 설치되는 수소발생기; 상기 수소발생기의 전기분해에 필요한 전기에너지를 제공하도록 상기 컨테이너의 내측에 설치되는 파워서플라이; 상기 수소발생기로부터 발생되는 수소로부터 산소 및 수분을 제거하도록 상기 컨테이너의 내측에 설치되는 정제기; 및 상기 정제기에 의해 정제된 수소와 상기 수소발생기로부터 발생되는 산소를 각각 저장하도록 상기 컨테이너의 내측에 설치되는 수소탱크 및 산소탱크;를 포함하도록 한 멀티 스택 방식의 모듈형 수전해 장치에 관한 것이다. 본 발명에 따르면, 전기분해를 이용한 수소발생기를 사용하여 수소 발생에 필요한 각종 장치들을 필요로 하는 수소 발생 시스템을 제한된 공간에 효율
Resumen de: KR20250097212A
일 실시예에 따른 수전해 장치의 누출 방지 디바이스는 수전해 장치에 마련될 수 있고, 상기 수전해 장치는, 케이스, 상기 케이스 내에 수용되는 물 공급 및 순환 배관 및 상기 케이스 내에 수용되고 상기 물 공급 및 순환 배관에 연결되는 수전해 셀 또는 스택을 포함하고, 상기 수전해 장치의 누출 방지 디바이스는, 중력 방향을 기준으로 상기 케이스의 하단에 마련되는 누액수집기를 포함하고, 상기 누액수집기는 상기 중력 방향에 대해서 경사면을 포함할 수 있다.
Resumen de: KR20250097206A
일 실시예에 따른 수전해 장치의 동파 방지 시스템은, 케이스, 상기 케이스 내에 수용되는 물 공급 모듈, 상기 케이스 내에 수용되는 수전해 장치, 상기 케이스 내에 수용되어 상기 수전해 장치로부터 수소를 공급받는 수소 정제기 모듈, 상기 물 공급 모듈과 상기 수전해 장치 사이에 배치되어 상기 물 공급 모듈로부터 상기 수전해 장치로 물을 공급하는 물 공급 라인, 및 상기 물 공급 라인으로부터 분기되어 상기 물 공급 모듈로 연결되는 물 공급 바이패스 라인을 포함할 수 있다.
Resumen de: KR20250097397A
본 발명의 예시적인 실시예들에 따르면, 재생 에너지 전원 장치, 서브 전원 장치, 수전해 장치, 재생 에너지 전원 장치의 출력 전압을 측정하는 모니터링 장치 및 제어 장치를 포함하는 재생 에너지 기반의 수전해 시스템이 제공될 수 있다. 재생 에너지 전원 장치의 출력 전압에 따라 수전해 장치에 대한 전기 공급을 제어하는 방법이 제공될 수 있다.
Resumen de: BG113842A
The system and method for producing hydrogen and oxygen according to the invention optimize the production process, wherein the electrolysis of water is performed by superheated water vapor, and the decomposition of the water vapor is performed under the influence of a high-voltage field, which reduces the energy cost of producing hydrogen and oxygen. Also much of the input energy is recovered in two stages, in the first stage the recovery is done with separate economizers (5, 7) for the hydrogen and oxygen, which transfer their heat to the incoming hot water, and in the second stage the recovery is done in the purification and cooling of the hydrogen and oxygen. Recovery of the heat input for heating allows a significant reduction in the cost of hydrogen and oxygen production and a reduction in the cost of hydrogen and oxygen.
Resumen de: MA66617A1
The co-generation of hydrogen 11 from water 8 produced during pressure driven water desalination/filtration processes, such as reverse osmosis, forward osmosis, pressure retarded osmosis or ultrafiltration. A small part of feed, raw saline solution and/or permeate involved in a desalination/filtration processes is subjected to electrolysis thereby splitting the water to produce hydrogen. This is achieved by the provision of novel RO type semi-permeable membranes and UF type membrane that incorporate electrodes 9, 10 within the membrane to allow splitting of the water via electrolysis.
Resumen de: KR20250097287A
하기 식 (1)의 페로브스카이트 구조 촉매로서, ABO3 (1) 상기 식에서 A는 La, Sr로 이루어진 군으로부터 선택된 적어도 어느 하나이고, B는 Co, Fe, Ni, Ru 및 Mn로 이루어진 군으로부터 선택된 적어도 어느 하나이며, 상기 B에는 Ru가 일부 도핑된 것을 특징으로 하는 페로브스카이트 구조 촉매가 제공된다.
Resumen de: KR20250096033A
본 발명은 산화물 담체를 준비하고, 암모니아 분해촉매 합성을 위해 니켈과 마그네슘의 전구체 용액을 준비하고, 상기 전구체 용액을 상기 담체에 함침하고, 공기중에서 700 ~ 1000℃의 온도로 1 ~ 10시간 동안 열처리하여 상기 전구체 용액으로부터 니켈 마그네슘 산화물 고용체를 생성하여 상기 담체에 니켈 마그네슘 산화물 촉매층을 형성하고, 상기 니켈 마그네슘 산화물 촉매층이 형성된 담체를 환원분위기에서 500 ~ 900℃의 온도로 2 ~ 10시간 동안 열처리하여 상기 니켈 마그네슘 산화물 촉매층으로부터 금속 니켈 촉매를 석출시키는 단계를 포함하는 암모니아 분해촉매 제조방법을 제공한다.
Resumen de: CN115485066A
A catalytic material and a method of making the catalytic material are described. The use of the catalytic material in catalyzing ammonia decomposition processes is also described. The catalytic material comprises a metal oxide and a metal M selected from the group consisting of Ru, Fe, Co, Mo, and mixtures of two or more thereof, and is particularly active in the catalytic decomposition of ammonia, even at low temperatures.
Resumen de: AU2023376448A1
Provided is a positive electrode for electrolysis, which is unlikely to deteriorate in electrolysis performance even in cases where a power with large output fluctuation such as renewable energy is used as a power source, and in which excellent catalytic activity is maintained for a long period of time. A positive electrode 10 for electrolysis comprises: a conductive substrate 2 at least a surface of which is made of nickel or a nickel-based alloy; and a first layer 4 which is formed on the surface of the conductive substrate 2 and can function as a catalyst layer composed of a lithium-containing nickel cobalt oxide represented by a composition formula of Li
Resumen de: EP4574255A1
In a method of preparing an ammonia decomposition catalyst according to embodiments of the present disclosure, a mixture of a metal oxide including lanthanum and a heterogeneous metal and aluminum oxide is prepared, the mixture was subj ected to steam treatment to form a carrier, and an active metal is supported on the carrier to prepare an ammonia decomposition catalyst. The ammonia decomposition catalyst according to embodiments of the present disclosure is prepared by the above-described preparation method.
Resumen de: WO2025135565A1
The present invention relates to a composite water electrolysis system using nuclear power plant heat and electrical energy, and, to a composite water electrolysis system for receiving heat energy and electrical energy generated in each of a plurality of SMRs, the system comprising: a heat energy storage hub for storing the heat energy generated in each of the plurality of SMRs; an electrical energy storage hub for storing electrical energy generated in each of the plurality of SMRs; and a composite hydrogen production unit, which receives heat and electricity from the heat energy storage hub and the electrical energy storage hub so as to generate hydrogen and oxygen. According to one embodiment, technologies such as hydrogen production through high-temperature water electrolysis, low-temperature water electrolysis, and ammonia decomposition are diversified, hydrogen and oxygen produced through high-temperature water electrolysis are in a high-temperature state, and the waste heat energy discarded when hydrogen and oxygen are cooled to a low temperature in order to be stored can be used as an additional heat source of low-temperature water electrolysis and ammonia hydrogen decomposition devices.
Resumen de: KR20250096137A
선박의 질소공급시스템이 개시된다. 본 발명의 선박의 질소공급시스템은, 선박에 마련되며 암모니아를 공급받아 선내 수소 수요처로 공급될 수소를 생성하는 암모니아 개질부; 상기 암모니아 개질부에서 수소 생성 후 발생하는 테일가스(tail gas)를 상기 암모니아 개질부로부터 공급받아 질소를 분리하는 질소분리부; 및 상기 질소분리부에서 분리된 질소를 저장하는 질소버퍼탱크:를 포함하고, 상기 질소버퍼탱크의 질소는 선내 질소 수요처로 공급되는 것을 특징으로 한다.
Resumen de: AU2023391802A1
The present invention pertains to an ammonia decomposing catalyst and a method for producing same. More specifically, the present invention pertains to: an ammonia decomposing catalyst containing an MgAl
Resumen de: FR3157228A1
CATALYSEUR NOTAMMENT DE CRAQUAGE DE L’AMMONIAC, PROCEDE DE PREPARATION DU CATALYSEUR ET PROCEDE DE SYNTHESE D’HYDROGENE Catalyseur pour la décomposition de l’ammoniac en hydrogène et azote, ledit catalyseur comprenant au moins du ruthénium, de l’oxyde de cérium mésoporeux et au moins un oxyde choisi parmi les oxydes de cobalt, de nickel et de fer, de préférence l’oxyde de nickel et procédé pour produire de l’hydrogène à partir d’ammoniac comprenant les étapes suivantes dans cet ordre : activation d’au moins un catalyseur selon l’invention à une température allant de 300°C à 600°C, sous un flux d’un gaz réducteur ; mise en contact dudit catalyseur activé avec un gaz à traiter comprenant de l’ammoniac à une température allant de 200°C à 800°C, et à une pression allant de la pression atmosphérique à 100 bar. Figure pour l’abrégé : Fig. 3
Resumen de: JP2025095274A
【課題】予備処理を行わなくてもアルカリ水電解時の耐久性(耐金属溶出性)を確保することが可能なアルカリ水電解装置用部材を与える省Ni型のアルカリ水電解装置用ステンレス鋼材を提供する。【解決手段】質量基準で、C:0.100%以下、Si:1.00%以下、Mn:3.00~12.00%、Ni:7.00~9.00%、P:0.0030%以下、S:0.0030%以下、Cr:10.0~18.0%、N:0.01~0.25%、Cu:0.01~1.00%、Mo:0.01~1.00%、Al:0.005~0.080%、B:0.0001~0.0100%、Ca:0.0005~0.0100%、O:0.0100%以下を含み、残部がFe及び不純物からなるアルカリ水電解装置用ステンレス鋼材とする。【選択図】なし
Resumen de: WO2025132418A1
The invention relates to a water electrolysis installation (P) comprising a plurality of electrolysis clusters (Ci) operated at respective electrical power setpoints (Pi k). The installation comprises and a supervision unit (SU) for operating the installation (P) according to an electrical network flexibility signal (FSk), the supervision unit (SU) comprising a modulation controller (MOD) for modulating synchronously the electrical power drawn by the installation (P) from an electrical network (NET) according to a preset arrangement, a priority sequencer (SEQ) to establish the preset arrangement asynchronously to the modulation controller (MOD), and a regulator module (REG) to regulate the actual power (Pk) drawn by the installation.
Resumen de: WO2025132365A1
The invention relates to a device/method for capturing/converting CO2, comprising/using a CO2 capturing unit (2), a water electrolysis unit (5), an RWGS unit (8), an FT unit (13), a unit for converting by-products into syngas (28) and a hydrogen unit (20), in which a carbon dioxide separation unit (34) is arranged to: treat a first syngas (12) and a second syngas (29); produce a gaseous effluent depleted in carbon dioxide (18) and a gaseous effluent rich in carbon dioxide (35); and recycling the gaseous effluent rich in carbon dioxide (35) to the inlet of the RWGS section (8).
Resumen de: WO2025131874A1
The invention relates to a system (120) consisting of at least two catalyzers (100), in particular for use in electrochemical cell devices (10), preferably fuel cell devices (10), wherein the at least two catalyzers (100) are fluidically connected in series, and each of the at least two catalyzers (100) has a catalytically active material (108), each of which is provided on a main part (102). At least one first catalyzer (100a), which is arranged first in the flow direction, has a protective material (110), which is designed to bind chromium and is provided on the main part (102). According to the invention, the first catalyzer (100a) is designed to oxidize hydrogen, and a second catalyzer (100b), which is arranged after the first catalyzer (100a) in the flow direction, is designed to oxidize methane.
Resumen de: WO2025131721A1
The invention relates to a method for producing an electrolysis assembly comprising at least one housing with an interior, and with at least one stack assembly disposed in the interior of the housing, the stack assembly comprising a plurality of electrolytic cells stacked in a stacking direction, at least some of the electrolytic cells each comprising a membrane electrode assembly and an interconnector, and the membrane electrode assembly and the interconnector each having an oxygen side and a hydrogen side, wherein, in a preparation step for producing membrane electrode assemblies, at least one pasty layer is applied to each of the two surfaces of an electrolyte membrane, at least one of the layers on one surface being used to form a first electrode formed on the hydrogen side of the membrane electrode assemblies and at least one of the layers on the other surface being used to form a second electrode formed on the oxygen side of the membrane electrode assemblies, in a preparation step a seal material comprising glass and/or glass-ceramic is applied to the interconnectors, in an assembling step the prepared interconnectors and membrane electrode assemblies are stacked in alternation to form a stack, and in an assembling step the stack is joined under the action of thermal energy and of a mechanical clamping force which is applied to the stack inwardly in the stacking direction.
Resumen de: DE102023213299A1
Die Erfindung betrifft ein Verfahren zum Rückführen von Kathodenmedium (7) in einem Elektrolyseuraggregat (1), insbesondere einem PEM- oder AEM-Elektrolyseuraggregat (1), wobei zeitlich vor einem Wiedereinspeisen des einen Elektrolysezellenstapel (10) des Elektrolyseuraggregats (1) verlassenden Kathodenmediums (7) in ein Mediumreservoir (23) einer Mediumversorgung (20) des Elektrolyseuraggregats (1), ein im Kathodenmedium (7) vorliegender Wasserstoff (8) abgetrennt wird, und ferner zeitlich vor dem Wiedereinspeisen des Kathodenmediums (7) in das Mediumreservoir (23), in einem Verdünnschritt (V) des Rückführverfahrens dem Kathodenmedium (7) frisches Versorgungsmedium (3) zugeführt und derart eine Konzentration von Wasserstoff (8) im Kathodenmedium (7) verringert wird.
Resumen de: WO2025133594A1
An energy system (100) for supplying electricity to a load (108) and a method of using said system are provided, the system comprising renewable electricity generation capacity (102) comprising solar and wind generation capacity, a battery (110) with a maximum electricity storage capacity sufficient to meet the mean load for up to 1 hr, an electrolyser (112) configured for hydrogen gas production and capable of operating at from 0.3 to 0.8 times the maximum output of the renewable electricity generation capacity; and gas storage (114) configured to receive the hydrogen gas; wherein the renewable electricity generation capacity is in electrical communication with the electrolyser via the battery and wherein the system is configured to allow electrical communication to the load such that electrical output not consumed by the load is used to generate hydrogen gas.
Resumen de: WO2025132918A1
Disclosed is an electrolysis cell element (1) comprising, a support structure (2) comprising an inner aperture (3), and a bipolar plate (4) being suspended in the inner aperture (3). The support structure (2) comprises a structure core (5) and a coating (6), wherein the coating (6) includes a thermoplastic material at least partly enclosing the structure core (5) and wherein the bipolar plate (4) is suspended in the inner aperture (3) by means of the coating (6). An electrolysis cell stack (10) and use of an electrolysis cell stack (10) is also disclosed.
Resumen de: DE102023213301A1
Die Erfindung betrifft ein Verfahren zum Rückführen von Kathodenwasser (7) in einem Elektrolyseuraggregat (1), insbesondere einem PEM- oder AEM-Elektrolyseuraggregat (1), wobei zeitlich vor einem Wiedereinspeisen des einen Elektrolysezellenstapel (10) des Elektrolyseuraggregats (1) verlassenden Kathodenwassers (7) in eine Mediumversorgung (20) des Elektrolyseuraggregats (1), ein im Kathodenwasser (7) vorliegender Wasserstoff (8) abgetrennt wird, wobei in einer Wasserstoff-Abtrenneinrichtung (50) des Elektrolyseuraggregats (1), in einem ersten Abtrennschritt durch einen Überdruck in einem ersten Volumen (51) der Wasserstoff-Abtrenneinrichtung (50), Wasserstoff (8) aus dem wasserstoffreichen Kathodenwasser (7) abgetrennt wird, und in einem auf den ersten Abtrennschritt zeitlich folgenden zweiten Abtrennschritt durch eine Verweildauer des nun wasserstoffärmeren Kathodenwassers (7) in einem vom ersten Volumen (51) verschiedenen zweiten Volumen (52) der Wasserstoff-Abtrenneinrichtung (50), weiterer Wasserstoff (8) abgetrennt wird.
Resumen de: WO2025132855A1
A separator for alkaline water electrolysis comprising: - a porous support (100) and on at least one side of the support, in order: - an optional porous layer including a Polymer A (200), and - a non-porous layer including a Polymer B (300), characterized in that the separator is obtainable by coating on the porous support (100) or the optional porous layer (200) a Polymer B solution having a viscosity of at least 400 mPa.s, measured at 20°C and a shear rate of 100 s-1, and wherein the separator has a Bubble Point, measured according to ASTM F316, of at least 5 bar.
Resumen de: WO2025132806A1
A catalyst coated separator for alkaline water electrolysis (1) comprising a porous support (100) and on at least side of the support, in order: - an optional porous polymer layer (200), - a non-porous alkali-stable polymer layer (300), and - a catalyst layer (400).
Resumen de: WO2025132521A1
The present invention refers to an electrochemical system comprising: i. an electrolyte, preferably a liquid electrolyte, more preferably an aqueous electrolyte, comprising a stabilizing anion, wherein said electrolyte comprises > 10 mol/mol % of water; ii. a redox mediator electrode comprising Ga(0) or alloys thereof; iii. a cathode; iv. an anode; and v. a wavefunction generator to alternately polarize the electrical connection between the redox mediator electrode and the cathode or anode; wherein the redox mediator electrode is electrically connected with the cathode and the anode, provided that the anode and the cathode are not electrically connected with each other. The gallium-based redox mediator electrode permits the nearly complete reversibility between dissolution and electroplating of gallium, thus cathodic and anodic reactions can be carried out in an alternating manner by electrically connecting the redox mediator electrode with the cathode or the anode. The present invention also refers to a method for the electrochemical production of H2, and oxidized species, such as O2 and/or Cl2 or H+, with the electrochemical system of the invention. Therefore, the present invention may find application in fuel production, e.g. in combination with fuel cells or internal combustion engines, or in chemical reactions such as hydrogenation reactions, reversible H2 production and H2 oxidation, hydrotreating reactions, hydrocracking reactions, hydroisomerisation reactions, oil
Resumen de: WO2025131661A1
The invention relates to an electrolysis assembly comprising at least one housing with an interior and at least one stack assembly in the interior of the housing. The stack assembly comprises a plurality of electrolysis cells stacked in a stacking direction, and at least some of the electrolysis cells comprise a respective membrane electrode assembly and a respective interconnector, wherein the membrane electrode assembly and the interconnector each have an oxygen side and a hydrogen side, and at least some of the electrolysis cells have contact elements between the membrane electrode assembly and the interconnector, said contact elements being designed to be viscous in an operating state of the electrolysis assembly and solid in a rest state of the electrolysis assembly.
Resumen de: WO2025131585A1
The invention relates to a hydrogen production facility (222) comprising a hydrogen recirculation assembly (100, 200). The hydrogen production facility (222) comprises at least one main compressor (226, 426) which is fluidically connected to at least one electrolyzer (224, 424) via a main hydrogen flow fluid network (232), wherein the hydrogen recirculation assembly (100, 200) comprises a first fluid inlet (102, 202) which can be connected to a first hydrogen leakage point (240) of the hydrogen production facility (222) and which is connected to at least one collecting container (106, 206) of the hydrogen recirculation assembly (100, 200) via at least one first fluid connection (110, 210); a second fluid inlet (104, 204) which can be connected to a second hydrogen leakage point (242) of the hydrogen production facility (222) and which is connected to the collecting container (106, 206) via at least one second fluid connection (112, 212); at least one recirculation compressor (108, 208) which is connected to the collecting container (106, 206) via at least one third fluid connection (114), and at least one first fluid outlet (118, 218) which can be connected to a main hydrogen flow fluid network (232) of the hydrogen production facility (222) and which is connected to the recirculation compressor (108, 208) via at least one fourth fluid connection (116).
Resumen de: WO2025131681A1
The invention relates to an electrolysis assembly comprising a stack assembly. At least some of the interconnectors are designed in the form of substantially rectangular single-layer sheet-metal structures, the first face of which defines the hydrogen side of the interconnector and the second face of which defines the oxygen side of the interconnector, wherein the thickness of the interconnectors in the form of sheet-metal structures ranges from 0.3 to 0.8 mm, and at least some of the interconnectors have a reactant gas manifold opening in a first edge region in order to conduct reactant gas and a product gas manifold opening in a second edge region lying opposite the first edge region in order to conduct product gas. Between the membrane electrode assembly and the interconnector of at least some of the electrolysis cells is a reactant gas line structure designed to conduct reactant gas out of the reactant gas manifold structure along the hydrogen side of the membrane electrode assemblies and to the product gas manifold structure, and the reactant gas line structure has a plurality of flow channels, each of which is laterally delimited by means of two mutually spaced channel webs, at least some of the channel webs having, on average, an edge steepness of >= 85° at at least one surface which delimits a flow channel.
Resumen de: WO2025131626A1
The invention relates to an electrolysis assembly (10) comprising a stack assembly (16). The stack assembly (16) is equipped with precisely one reactant gas manifold structure (66) in order to provide reactant gas to the electrolysis cells (18) and precisely one product gas manifold structure (68) in order to discharge product gas from the electrolysis cells (18). The stack assembly (16) has a reactant gas opening for introducing reactant gas into the reactant gas manifold structure (66) and a product gas opening for discharging product gas out of the product gas manifold structure (68). The reactant gas manifold structure (66) and the product gas manifold structure (68) are formed within the stack assembly (16), in each case by means of manifold openings introduced into the interconnectors, wherein between the membrane electrode assembly and the interconnector of at least some of the electrolysis cells is a reactant gas line structure designed to conduct reactant gas out of the reactant gas manifold structure along the hydrogen side of the membrane electrode assemblies and to the product gas manifold structure, and at least some of the membrane electrode assemblies have an oxygen-permeable structure on the oxygen side, said oxygen-permeable structure being positioned and designed such that oxygen released on the oxygen side of the membrane electrode assembly can be discharged into the interior of the housing (12).
Resumen de: WO2025129214A1
The invention relates to an electrolyser for alkaline hydrogen electrolysis, comprising: a direct voltage source, in particular a rectifier (1) having an electrical positive pole (2) and an electrical negative pole (3); media inlet lines (4) for an electrolysis medium; and media outlet lines (5) for product media; wherein a plurality of electrolysis blocks (6) which are connected in series via electrical connecting lines (9) are connected between the positive pole (2) and the negative pole (3), wherein the electrolysis blocks (6) each have a number of electrolysis cells (7) which are electrically connected in series and are mechanically clamped so that they are flush with one another, wherein the media inlet lines (4) and the media outlet lines (5) each extend serially through the electrolysis blocks (6) and are distributed within each individual electrolysis block (6) to individual cell inlet lines (4', 4") and individual cell outlet lines (5', 5") of the electrolysis cells (7).
Resumen de: WO2025131283A1
The invention relates to a method, a system and the use thereof. According to the invention, hydrogen and oxygen are generated by means of a water-borne platform and, for example, the hydrogen and oxygen so produced are transported ashore and compressed and/or further compressed there.
Resumen de: WO2025135740A1
The present invention relates to a device for producing hydrogen from ammonia for a ship. According to the present invention, high-pressure hydrogen can be produced by using liquefied ammonia for a ship, and hydrogen can be economically produced by utilizing unconverted ammonia discharged from a decomposition reactor and off-gas discharged from a pressure swing adsorption device as a heat source for ammonia decomposition through a heat exchange network of the ship.
Resumen de: WO2025135743A1
The present invention provides a water electrolysis stack assembly and a hot box apparatus. In an embodiment, provided is a water electrolysis stack assembly including: a case including an upper surface part, a side surface part, and a gas outflow pipe formed in the side surface part; and a stack accommodated in an inner space of the case, wherein a surface pressure is applied to the stack by the upper surface part of the case.
Resumen de: WO2025135742A1
A control method of a high-temperature water electrolysis system, according to a first embodiment of the present invention, comprises the steps of: determining an operating temperature of a solid oxide water electrolysis stack in a high-temperature water electrolysis system including the solid oxide water electrolysis stack; selecting an operation mode of the solid oxide water electrolysis stack by comparing the operating temperature with a supply temperature of gas supplied to the solid oxide water electrolysis stack; determining a target voltage applied to the solid oxide water electrolysis stack according to the operation mode of the solid oxide water electrolysis stack; and applying the target voltage applied to the solid oxide water electrolysis stack in a step-up manner according to the operation mode of the solid oxide water electrolysis stack.
Resumen de: WO2025135726A1
The present invention provides a hydrogen vent system for discharging hydrogen generated in a high-temperature water electrolysis stack to the outside, comprising: a first pipe unit connected to the high-temperature water electrolysis stack and having a curved portion; a drain line which is connected to the first pipe unit and through which condensed water is drained; and a discharge unit which is connected to the first pipe unit and which releases hydrogen upward into the air, wherein a surge tank that maintains pressure and moves the condensed water to the drain line is disposed in the first pipe unit.
Resumen de: WO2025135328A1
The present invention relates to a water electrolysis system comprising: a hydrogen (H2) removal device; and an oxygen (O2) removal device, wherein the hydrogen (H2) removal device removes, from an oxygen (O2) stream, hydrogen (H2), and the oxygen (O2) removal device removes, from a hydrogen (H2) stream, oxygen (O2). By removing hydrogen (H2) and oxygen (O2) from the respective gas streams, the likelihood of explosion accidents during the movement of the gas streams is remarkably reduced, and the purity requirements of various industrial gases can be satisfied without a separate purification process.
Resumen de: WO2025135348A1
The present disclosure relates to a method for preparing a catalyst for an oxygen evolution reaction in a water electrolysis cell, and a water electrolysis cell membrane-electrode assembly and a water electrolysis cell, which comprise the catalyst prepared using same, and the method for preparing a catalyst for an oxygen evolution reaction in a water electrolysis cell comprises preparing a plurality of noble metal oxide seeds, and preparing a noble metal oxide aggregate by using the plurality of noble metal oxide seeds, thereby increasing the surface area thereof by means of pores between noble metal oxide particles, and thus performance and durability can be improved.
Resumen de: WO2025137083A1
An electrolyzer for gaseous production such as hydrogen gas includes an oscillating electrode driven at a natural frequency of the gaseous bubbles improves output by readily removing the gaseous bubble product from the electrode surface, thereby exposing greater electrode surface area for subsequent electrolysis reactions. A natural frequency of the gaseous product determines an oscillation frequency with which to drive the electrode accumulating the gaseous product, such as hydrogen bubbles, to agitate and release the bubbles which then rise to the surface of the liquid filled containment. Integrating oscillation logic for agitating the otherwise stationary electrode or cathode in a PEM water electrolyzer improves hydrogen production by readily evacuating the generated hydrogen to free up the electrode area for additional electrolysis reactions.
Resumen de: WO2025135565A1
The present invention relates to a composite water electrolysis system using nuclear power plant heat and electrical energy, and, to a composite water electrolysis system for receiving heat energy and electrical energy generated in each of a plurality of SMRs, the system comprising: a heat energy storage hub for storing the heat energy generated in each of the plurality of SMRs; an electrical energy storage hub for storing electrical energy generated in each of the plurality of SMRs; and a composite hydrogen production unit, which receives heat and electricity from the heat energy storage hub and the electrical energy storage hub so as to generate hydrogen and oxygen. According to one embodiment, technologies such as hydrogen production through high-temperature water electrolysis, low-temperature water electrolysis, and ammonia decomposition are diversified, hydrogen and oxygen produced through high-temperature water electrolysis are in a high-temperature state, and the waste heat energy discarded when hydrogen and oxygen are cooled to a low temperature in order to be stored can be used as an additional heat source of low-temperature water electrolysis and ammonia hydrogen decomposition devices.
Resumen de: WO2025135512A1
The present disclosure relates to: a catalyst for an oxygen evolution reaction of a water electrolysis cell; a method for manufacturing same; and a membrane-electrode assembly for a water electrolysis cell, and a water electrolysis cell, comprising same. More specifically, by manufacturing a catalyst for oxygen evolution reaction of a water electrolysis cell, having a structure in which active particles fill pores between nanoparticles of a carrier assembly manufactured in various forms or penetrate into the carrier assembly while being supported by the carrier assembly, performance is improved while reducing the amount of noble metal used. The active particles have stronger bonds than a form in which active particles are simply supported, and thus the active particles and the carrier assembly can have improved durability.
Resumen de: WO2025135513A1
The present disclosure relates to a catalyst for an oxygen evolution reaction of a water electrolysis cell, a manufacturing method therefor, a membrane-electrode assembly for a water electrolysis cell including same, and a water electrolysis cell. The catalyst for the oxygen evolution reaction of a water electrolysis cell includes a heterogeneous noble metal composite which has a nanowire shape and includes different first and second noble metal oxides in a node structure, whereby the catalyst can reduce the amount of the noble metals used while improving performance and can enhance performance and durability depending on the types and lengths of the noble metals forming the heterogeneous noble metal composite.
Resumen de: WO2025135428A1
The present technology relates to a water electrolysis system having a power supply control function capable of protecting a water electrolysis stack from instability of renewable energy power. The water electrolysis system comprises: a renewable energy production device for producing renewable energy; a renewable energy storage device for storing the produced renewable energy; a water electrolysis device for electrolyzing water by using at least one of the renewable energy and stored energy supplied from the renewable energy storage device; a gas storage device for storing gas produced by electrolysis in the water electrolysis device; and a power supply control device which controls power supply to the water electrolysis device so as to, if a gradient of power change of the renewable energy is greater than a preset power increase reference gradient, charge the renewable energy storage device by distributing at least a portion of the renewable energy, and if the gradient of power change of the renewable energy is less than a preset power decrease reference gradient, supplement the renewable energy by distributing at least a portion of the stored energy of the renewable energy storage device.
Resumen de: US2025205696A1
Described herein relates to a method that may be used for synthesizing a bifunctional electrocatalyst for electrochemical water splitting. The method may involve anodically converting an electrodeposited iron-nickel alloy film into an iron-nickel-oxygen nanofilm, followed by sequential phosphorization and/or selenylation treatments via chemical vapor deposition to form a quaternary iron-nickel phosphoselenide nanoporous film. This self-supported catalyst can facilitate both hydrogen evolution and oxygen evolution reactions, improving electrolysis efficiency. The inclusion of selenium may enhance electrical conductivity and stabilize catalytic performance, while the nanoporous structure can optimize mass transport. The film may be used as both anode and cathode in a two-electrode electrolyzer, enabling hydrogen production from pure water or seawater. Notably, the catalyst can demonstrate high turnover frequency and low overpotential, potentially surpassing conventional noble-metal-based catalysts. The system's stability under prolonged operation may underscore its potential for scalable hydrogen generation, reducing reliance on fossil fuels and advancing renewable energy applications.
Resumen de: US2025205656A1
An apparatus, includes: a first raw material supply unit 110 including a filter housing 111, a supply fan 112, a flow regulator 113, an electronic valve 114, and an air supply line 115, wherein the supply fan 112 is operated to suck in external air, in the process, the HEPA filter (not shown) mounted inside the filter housing 112 filters fine dust and adjusts the air supply flow rate from the flow regulator 113 to the appropriate flow rate and supplies through the supply line 115 to the ion generator 200; a second raw material supply unit 120 including a pressure regulator 122, a flow regulator 123, an electronic valve 124, and an air supply line 125.
Resumen de: US2025206621A1
A silica material has a substrate containing silicon dioxide, and has a sulfonate group on at least a surface of the substrate, or is obtained by bringing a sulfonating agent into contact with a substrate containing silicon oxide.
Resumen de: US2025207273A1
A water electrolysis electrode includes a conductive substrate and a layered double hydroxide layer. The conductive substrate has a surface including nickel having a plane orientation. The layered double hydroxide layer includes a layered double hydroxide including two or more transition metals. The layered double hydroxide layer is disposed on the surface.
Resumen de: US2025207278A1
An object of the present invention is to provide a water electrolysis method capable of maintaining a high electrolysis efficiency. The present invention proposes a water electrolysis method, including supplying water to an electrolysis cell whose interior is divided into an anode and a cathode by an electrolyte membrane, and electrolyzing the water, to generate oxygen at the anode and hydrogen at the cathode, wherein the electrolyte membrane includes: a first layer containing a polymer electrolyte; and a second layer containing carbon particles, and provided on the side of the cathode of the first layer.
Resumen de: US2025207279A1
A method for operating an electrolysis device, having a converter which is connected on an AC voltage side to an AC voltage grid via a decoupling inductance and draws an AC active power from the AC voltage grid, and an electrolyzer, which is connected to the converter on the DC voltage side, is provided. The method includes operating the electrolysis device, when a grid frequency corresponds to a nominal frequency of the ACT voltage grid and is substantially constant over a time period, with an electrical power which is between 50% and 100% of a nominal power of the electrolyzer, and operating the converter in a voltage-impressing manner, such that an AC active power drawn from the AC voltage grid is changed on the basis of a change and/or a rate of change of the grid frequency in the AC voltage grid.
Resumen de: US2025207277A1
A catalytic material comprising at least one group VIB metal at least partly in sulfide form, at least one group IVB metal at least partly in sulfide form, and an electrically conductive support wherein said group VIB metal is chosen from molybdenum and/or tungsten, said group IVB metal is chosen from titanium, zirconium and/or hafnium.
Resumen de: US2025207274A1
An electrode for water electrolysis cell includes a conductive base, a first layer, and a second layer. The conductive base includes a transition metal. The first layer is disposed on the conductive base, and includes two or more transition metals and oxygen. The second layer is disposed on the first layer and includes a layered double hydroxide (LDH) including two or more transition metals. The first layer is disposed between the conductive base and the second layer in a thickness direction of the first layer. The first layer includes a first transition metal that is the same as the transition metal included in the conductive base, and a second transition metal that is the same as the transition metal included in the second layer and different from the first transition metal. The first transition metal exists in the first layer at a concentration higher than a concentration of the first transition metal in the second layer.
Resumen de: US2025207266A1
A water electrolysis cell has: an oxygen generating electrode; a hydrogen generating electrode; and a membrane, and electrolyzes water to generate oxygen on the oxygen generating electrode and generate hydrogen on the hydrogen generating electrode. A control device includes: a potential-maintaining mode where the water electrolysis cell is supplied with electric current; and a complete stop mode where the water electrolysis cell is shut out from electric current supply, each of the modes is optionally implemented during an operation stop, wherein which of the modes is implemented is determined based on a duration time of the operation stop, a first deterioration rate of the water electrolysis cell when the complete stop mode is implemented, and a second deterioration rate of the water electrolysis cell when the potential-maintaining mode is implemented.
Resumen de: US2025210678A1
An electrochemical cell module includes a module housing and electrochemical cells located in the module housing and configured to generate power or hydrogen and to output an exhaust. The module also includes a vent housing attached to the module housing, an exhaust duct located in the vent housing, and a filter cartridge located in the exhaust duct. The exhaust duct contains an inlet that is configured to receive the exhaust from the module housing, and an outlet that is configured to direct the exhaust away from the module housing. The filter cartridge contains a particulate filter.
Resumen de: AU2023383044A1
An electrolysis system 1 is provided with an electrolysis cell 2 and a mediator reduction tank 4. The electrolysis cell 2 comprises: an anode electrode 10 which electrochemically oxidizes a mediator reduction body M
Resumen de: KR20250094950A
본 발명은, 스택 하우징의 면들을 각각 복수의 영역들로 구획하고, 각 영역마다 열선과 온도 센서가 구비됨으로써, 영역별 온도 측정 및 제어가 가능하여, 구조가 간단하면서도 온도 제어 및 관리가 용이하여 에너지 효율을 향상시킬 수 있다. 또한, 스택 하우징의 면들에 열선과 온도 센서가 구비되고, 스택에는 열선이나 온도 센서가 구비되지 않기 때문에, 상기 스택의 개수나 형상을 설계 변경하거나 상기 스택을 교체하더라도 상기 스택 하우징을 그대로 적용할 수 있으므로, 설치 편의성 및 확장성을 확보할 수 있다. 또한, 복수의 온도 센서들에서 측정된 영역별 온도에 따라 복수의 열선들을 선택적으로 작동시킬 수 있으므로, 상기 스택의 온도를 보다 정밀하게 제어할 수 있다. 또한, 미리 학습된 인공지능 알고리즘을 이용하여 복수의 온도 센서들로부터 측정된 영역별 온도에 따라 복수의 스택들의 온도를 도출하고, 상기 스택들의 온도에 따라 각 열선들의 작동 여부와 작동 시간을 포함한 개별 작동 데이터를 도출할 수 있으므로, 보다 신속하고 정밀하게 스택들의 온도를 제어할 수 있다.
Resumen de: WO2025135428A1
The present technology relates to a water electrolysis system having a power supply control function capable of protecting a water electrolysis stack from instability of renewable energy power. The water electrolysis system comprises: a renewable energy production device for producing renewable energy; a renewable energy storage device for storing the produced renewable energy; a water electrolysis device for electrolyzing water by using at least one of the renewable energy and stored energy supplied from the renewable energy storage device; a gas storage device for storing gas produced by electrolysis in the water electrolysis device; and a power supply control device which controls power supply to the water electrolysis device so as to, if a gradient of power change of the renewable energy is greater than a preset power increase reference gradient, charge the renewable energy storage device by distributing at least a portion of the renewable energy, and if the gradient of power change of the renewable energy is less than a preset power decrease reference gradient, supplement the renewable energy by distributing at least a portion of the stored energy of the renewable energy storage device.
Resumen de: KR20250094789A
본 발명은 수전해 시스템의 수명 예측 방법 및 장치에 관한 것이다. 본 발명에 따른 수전해 시스템의 수명 예측 방법은, 수전해 시스템에 설치된 센서들을 통해 측정된 과거의 각 시계열 데이터를 수집하는 단계; 인공신경망 모델을 이용하여 과거의 각 시계열 데이터로부터 수전해 스택의 성능 데이터를 산출하는 단계; 수전해 스택의 산출된 성능 데이터를 실제 성능 데이터와 비교하여 오차 값을 구하는 단계; 및 오차 값을 이용하여 인공신경망 모델의 파라미터를 조정하는 단계를 포함할 수 있다.
Resumen de: AU2023284373A1
The present invention relates to the technical field of hydrogen energy power generation, and provided is a hydrogen energy uninterruptible power system. Said system comprises a hydrogen production unit, a power storage unit, a power generation apparatus, and a control unit, wherein the hydrogen production unit is able to utilize electrolysis to prepare hydrogen and oxygen gases; the power storage unit can supply power to the hydrogen production unit, and can output power to the outside; the power generation apparatus can receive the hydrogen and oxygen gases output by the hydrogen production unit and generate power, and the power generation apparatus can output power to the outside or transfer power to the power storage unit; and the control unit communicates with the hydrogen production unit, the power storage unit, and the power generation apparatus by means of electrical signals.
Resumen de: CN119403758A
A process for dissociating ammonia into a dissociated hydrogen/nitrogen stream in a catalyst tube within a radiant tube furnace and an adiabatic or isothermal unit containing a catalyst, and a downstream purification process unit for purifying the dissociated hydrogen/nitrogen stream into a high purity hydrogen product.
Resumen de: EP4576285A1
An electrochemical cell module includes a module housing and electrochemical cells located in the module housing and configured to generate power or hydrogen and to output an exhaust. The module also includes a vent housing attached to the module housing, an exhaust duct located in the vent housing, and a filter cartridge located in the exhaust duct. The exhaust duct contains an inlet that is configured to receive the exhaust from the module housing, and an outlet that is configured to direct the exhaust away from the module housing. The filter cartridge contains a particulate filter.
Resumen de: US2024133066A1
An electrolysis cell system includes a cathode portion configured to output a cathode exhaust stream, an anode portion configured to output an anode exhaust stream, a sensor configured to detect a concentration in an exhaust stream and to output sensor data, wherein the sensor is either a hydrogen concentration sensor configured to detect a hydrogen concentration in the cathode exhaust stream or a water concentration sensor configured to detect a water concentration of the anode exhaust stream, and a controller. The controller is configured to receive the sensor data from the sensor and, based on the sensor data, control at least one of (a) an air pressure adjustment device to adjust a pressure of air entering the anode portion or (b) a steam pressure adjustment device to adjust a pressure of steam entering the cathode portion.
Resumen de: US2025197205A1
Disclosed is an apparatus for producing hydrogen gas from ammonia gas using a laser. A decomposition device for decomposing ammonia gas in order to produce hydrogen gas includes an ammonia inlet provided at an uppermost end of the decomposition device to allow ammonia gas to easily flow into the decomposition device, a hydrogen outlet configured to discharge the hydrogen gas produced by decomposition of the ammonia gas, and a nitrogen outlet configured to discharge nitrogen gas produced by the decomposition of the ammonia gas. Laser light in a preset first wavelength band is incident from an outside to a contact point of the ammonia inlet, the hydrogen outlet, and the nitrogen outlet, so that the ammonia gas is decomposed.
Resumen de: WO2025135740A1
The present invention relates to a device for producing hydrogen from ammonia for a ship. According to the present invention, high-pressure hydrogen can be produced by using liquefied ammonia for a ship, and hydrogen can be economically produced by utilizing unconverted ammonia discharged from a decomposition reactor and off-gas discharged from a pressure swing adsorption device as a heat source for ammonia decomposition through a heat exchange network of the ship.
Resumen de: US2024133063A1
An electrolyzer system includes a vaporizer configured to store a first volume of liquid water and to vaporize water to humidify a cathode inlet stream of an electrolyzer cell module, a cold water tank positioned at a height greater than that of the first volume of liquid water and configured to store a second volume of water, and a valve configured to open and close. The water from the cold water tank is allowed to flow through the valve into the vaporizer when the valve is open.
Resumen de: KR20250094156A
본 발명의 예시적인 실시예들에 따르면, 전기화학 장치 내지 스택에서 발생한 열을 효과적으로 회수할 수 있는 매니폴드가 제공된다.
Resumen de: WO2025127502A1
Provided according to exemplary embodiments of the present invention is an ammonia decomposition system capable of minimizing the generation of iron nitride, which is a by-product.
Resumen de: WO2025135726A1
The present invention provides a hydrogen vent system for discharging hydrogen generated in a high-temperature water electrolysis stack to the outside, comprising: a first pipe unit connected to the high-temperature water electrolysis stack and having a curved portion; a drain line which is connected to the first pipe unit and through which condensed water is drained; and a discharge unit which is connected to the first pipe unit and which releases hydrogen upward into the air, wherein a surge tank that maintains pressure and moves the condensed water to the drain line is disposed in the first pipe unit.
Resumen de: WO2025135743A1
The present invention provides a water electrolysis stack assembly and a hot box apparatus. In an embodiment, provided is a water electrolysis stack assembly including: a case including an upper surface part, a side surface part, and a gas outflow pipe formed in the side surface part; and a stack accommodated in an inner space of the case, wherein a surface pressure is applied to the stack by the upper surface part of the case.
Resumen de: EP4574749A1
Die Erfindung betrifft ein Verfahren sowie eine Anlage Verfahren zur Erzeugung eines Wasserstoffprodukts (12), bei dem ein erster Teil eines bereitgestellten Ammoniaks (F) überhitzt und in einem Spalteinsatz (1) einer brennerbefeuerten Spaltofenanordnung (S) zugeführt wird, um mit katalytischer Unterstützung zu einem Wasserstoff, Stickstoff und Ammoniak enthaltenden Spaltgas (3) umgesetzt zu werden, von dem zumindest ein Teil einer Trenneinrichtung (T) zugeführt wird, in der eine Wasserstofffraktion (6) sowie ein gegenüber dem Spaltgas (3) an Stickstoff angereichertes, Wasserstoff und Ammoniak enthaltendes Restgas (7) erhalten werden, von dem zumindest ein Teil zusammen mit einem zweiten Teil (14) des bereitgestellten Ammoniaks (F) zur Befeuerung der Spaltofenanordnung (S) eingesetzt wird. Kennzeichnend hierbei ist, dass der zweite Teil (14) des bereitgestellten Ammoniaks (F) vor seinem Einsatz zur Befeuerung der Spaltofeneinrichtung (S) überhitzt wird.
Resumen de: EP4575039A1
Die Erfindung betrifft ein Verfahren zur Herstellung einer Elektrolyseanordnung umfassend wenigstens ein Gehäuse mit einem Innenraum, und wenigstens einer im Innenraum des Gehäuses angeordneten Stackanordnung, wobei die Stackanordnung mehrere in eine Stapelrichtung gestapelte Elektrolysezellen umfasst, wobei zumindest einige der Elektrolysezellen jeweils eine Membran-Elektroden-Anordnung und einen Interkonnektor umfassen, und wobei die Membran-Elektroden-Anordnung und der Interkonnektor jeweils eine Sauerstoffseite und eine Wasserstoffseite aufweisen, wobei in einem Vorbereitungsschritt zur Herstellung einer Membran-Elektroden-Anordnungen auf den zwei Oberflächen einer Elektrolyt-Membran jeweils mindestens eine pastöse Schicht aufgebracht wird, wobei mindestens eine der Schichten auf jeweils einer Oberfläche zur Ausbildung einer auf der Wasserstoffseite der Membran-Elektroden-Anordnungen ausgebildeten ersten Elektrode und einer auf der Sauerstoffseite der Membran-Elektroden-Anordnungen ausgebildeten zweiten Elektrode dient, in einem Vorbereitungsschritt ein Dichtungsmaterial, umfassend Glas und/oder Glaskeramik auf die Interkonnektoren aufgebracht wird, in einem Montageschritt die vorbereiteten Interkonnektoren und Membran-Elektroden-Anordnungen abwechselnd zu einem Stapelverbund gestapelt werden, und in einem Montageschritt der Stapelverbund unter Einwirkung von thermischer Energie und einer auf den Stapelverbund in Stapelrichtung nach innen gerichteter mechanischer Spa
Resumen de: WO2025135742A1
A control method of a high-temperature water electrolysis system, according to a first embodiment of the present invention, comprises the steps of: determining an operating temperature of a solid oxide water electrolysis stack in a high-temperature water electrolysis system including the solid oxide water electrolysis stack; selecting an operation mode of the solid oxide water electrolysis stack by comparing the operating temperature with a supply temperature of gas supplied to the solid oxide water electrolysis stack; determining a target voltage applied to the solid oxide water electrolysis stack according to the operation mode of the solid oxide water electrolysis stack; and applying the target voltage applied to the solid oxide water electrolysis stack in a step-up manner according to the operation mode of the solid oxide water electrolysis stack.
Resumen de: EP4574255A1
In a method of preparing an ammonia decomposition catalyst according to embodiments of the present disclosure, a mixture of a metal oxide including lanthanum and a heterogeneous metal and aluminum oxide is prepared, the mixture was subj ected to steam treatment to form a carrier, and an active metal is supported on the carrier to prepare an ammonia decomposition catalyst. The ammonia decomposition catalyst according to embodiments of the present disclosure is prepared by the above-described preparation method.
Resumen de: EP4576478A1
The invention relates to a water electrolysis installation (P) comprising a plurality of electrolysis clusters (Ci) operated at respective electrical power setpoints (P<sup>i</sup><sub>k</sub>). The installation comprises and a supervision unit (SU) for operating the installation (P) according to an electrical network flexibility signal (FS<sub>k</sub>), the supervision unit (SU) comprising a modulation controller (MOD) for modulating synchronously the electrical power drawn by the installation (P) from an electrical network (NET) according to a preset arrangement, a priority sequencer (SEQ) to establish the preset arrangement asynchronously to the modulation controller (MOD), and a regulator module (REG) to regulate the actual power (P<sub>k</sub>) drawn by the installation.
Resumen de: CN119790190A
The invention relates to an electrolysis device (1) for producing hydrogen gas from an aqueous alkaline solution by electrochemical reaction, comprising an anode half-cell (2) and a cathode half-cell (3). The anode half-cell (2) and the cathode half-cell (3) are separated by a membrane (4), and the cathode half-cell (3) can be filled with the aqueous alkali. The anode half-cell (2) comprises an anode electrode (5) and the cathode half-cell (3) comprises a cathode electrode (6), the anode electrode (5), the cathode electrode (6) and the membrane (4) forming a membrane electrode unit (7). Furthermore, during normal operation of the electrolysis device (1), the initial filling amount of the alkaline solution in the cathode half-cell (3) can be varied exclusively by a diffusion process through the membrane electrode unit (7) and/or by an electrochemical reaction of the alkaline solution in the membrane electrode unit (7).
Resumen de: CN119678338A
The invention relates to a method for operating a renewable power plant (100) comprising at least one wind turbine (101) and an electrolyser system (110), the renewable power plant being connectable with an electrical grid (190) via a circuit breaker (123) located at a point of common coupling (PCC), wherein the renewable power plant comprises an internal grid (191) connecting the at least one wind turbine and the electrolyzer system with a point of common coupling, and wherein the method comprises detecting a low voltage at any one of the at least one wind turbine, and electrically disconnecting the electrolyzer system from the internal grid in response to detecting the low voltage.
Resumen de: WO2024178009A2
A hydrogen generating cell comprising an input electrode plate pair, an output electrode plate pair, an additional X plate electrode positioned adjacent the output electrode plate pair, and a plurality of intermediate electrode plates disposed between the input and output electrode plate pairs. A plasma torch is spaced apart from and inductively coupled to the input electrode plate pair. A pulsed DC voltage is applied to the plasma torch and X-plate, while a lower voltage pulsed DC voltage is applied to the input and output electrode plate pair to cause generation of hydrogen gas from an aqueous solution in which the cell is immersed.
Resumen de: EP4575040A1
A Ni-based porous electrode for water electrolysis comprising (a) a macroporous substrate having a specific thickness, porosity level, and a pore size; (b) a first layer of a metal or a metal alloy as defined herein covering the macroporous substrate; and (c) a second layer of Ni, a Ni-X alloy or a Ni-X-Y alloy as defined herein covering the first layer (b), wherein the Ni-based porous electrode is free from Pt-group metals and rare-earths; a process for the manufacturing of the Ni-based porous electrode; the use of the Ni-based porous electrode to catalyze the hydrogen evolution reaction (HER); and a water electrolyzer comprising the Ni-based porous electrode.
Resumen de: EP4575036A1
Die Erfindung betrifft eine Elektrolyseanordnung (10) mit einer Stackanordnung (16), wobei in der Stackanordnung (16) genau eine Eduktgas-Manifoldstruktur (66) zur Bereitstellung von Eduktgas an die Elektrolysezellen (18) und genau eine Produktgas-Manifoldstruktur (68) zum Abführen von Produktgas von den Elektrolysezellen (18) ausgebildet sind, wobei die Stackanordnung (16) eine Eduktgas-Öffnung zur Einleitung von Eduktgas in die Eduktgas-Manifoldstruktur (66) und eine Produktgas-Öffnung zur Ausleitung von Produktgas aus der Produktgas-Manifoldstruktur (68) aufweist, wobei die Eduktgas-Manifoldstruktur (66) und die Produktgas-Manifoldstruktur (68) innerhalb der Stackanordnung (16) jeweils mittels in den Interkonnektoren eingearbeiteten Manifoldöffnungen ausgebildet sind, wobei zwischen der Membran-Elektroden-Anordnung und dem Interkonnektor zumindest einiger Elektrolysezellen eine zur Leitung von Eduktgas aus der Eduktgas-Manifoldstruktur heraus entlang der Wasserstoffseite der Membran-ElektrodenAnordnungen und hin zur Produktgas-Manifoldstruktur ausgebildete Eduktgas-Leitungsstruktur angeordnet ist, und wobei zumindest einige Membran-ElektrodenAnordnungen auf ihrer Sauerstoffseite eine sauerstoffdurchlässige Struktur aufweisen, und wobei die sauerstoffdurchlässige Struktur derart angeordnet und ausgebildet ist, dass ein an der Sauerstoffseite der Membran-Elektroden-Anordnung freigesetzter Sauerstoff in den Innenraum des Gehäuses (12) ableitbar ist.
Resumen de: DE102023213299A1
Die Erfindung betrifft ein Verfahren zum Rückführen von Kathodenmedium (7) in einem Elektrolyseuraggregat (1), insbesondere einem PEM- oder AEM-Elektrolyseuraggregat (1), wobei zeitlich vor einem Wiedereinspeisen des einen Elektrolysezellenstapel (10) des Elektrolyseuraggregats (1) verlassenden Kathodenmediums (7) in ein Mediumreservoir (23) einer Mediumversorgung (20) des Elektrolyseuraggregats (1), ein im Kathodenmedium (7) vorliegender Wasserstoff (8) abgetrennt wird, und ferner zeitlich vor dem Wiedereinspeisen des Kathodenmediums (7) in das Mediumreservoir (23), in einem Verdünnschritt (V) des Rückführverfahrens dem Kathodenmedium (7) frisches Versorgungsmedium (3) zugeführt und derart eine Konzentration von Wasserstoff (8) im Kathodenmedium (7) verringert wird.
Resumen de: AU2023369983A1
The present invention relates to stack module with at least one Solid Oxide electrolysis stack that comprises a plurality of stacked Solid Oxide electrolysis cells, wherein the stack module comprises two gas inlet connections and two gas outlet connections. According to the invention, the at least one Solid Oxide electrolysis stack is encapsulated in a metal container, wherein the two gas inlet connections and the two gas outlet connections are attached to the metal container. The invention further relates to Solid Oxide Electrolyzer with at least one stack module and a method of exchanging a stack module of a Solid Oxide Electrolyzer.
Resumen de: WO2024204928A1
A solid oxide cell stack includes a plurality of interconnects, a first solid oxide cell disposed between the plurality of interconnects and including a first fuel electrode, a first electrolyte, and a first air electrode, and a second solid oxide cell disposed to be adjacent to the first solid oxide cell in a lateral direction between the plurality of interconnects and including a second fuel electrode, a second electrolyte, and a second air electrode, wherein an operating temperature of the first solid oxide cell is higher than an operating temperature of the second solid oxide cell.
Resumen de: KR20250093044A
본 발명의 예시적인 실시예들에 따르면, 수소 생산 시스템이 제공된다. 상기 수소 생산 시스템은, 스팀 공급부로부터 제공받은 제1 스팀을 전기 분해하여 수소 및 산소를 포함하는 제1 가스를 제공하도록 구성된 제1 고체산화물 수전해 셀을 포함하는 제1 SOEC 부; 물을 포함하는 냉매를 이용하여 상기 제1 가스를 냉각하고, 제2 스팀과 상기 수소 및 산소를 포함하는 제2 가스를 제공하도록 구성된 열교환부; 및 상기 제2 스팀을 전기 분해하여 산소 및 수소를 포함하는 제3 가스를 제공하도록 구성된 제2 고체산화물 수전해 셀을 포함하는 제2 SOEC 부; 를 포함하고, 상기 제1 스팀은, 상기 제1 고체산화물 수전해 셀의 작동 온도와 같거나, 상기 제1 고체산화물 수전해 셀의 작동 온도보다 높은 온도로 상기 제1 고체산화물 수전해 셀에 공급된다.
Resumen de: KR20250092966A
본 발명은 티타늄 다공막 제조방법과 관련된다. 본 발명은 실시예로, 본 발명의 소결체 상태의 티타늄 다공막을 피도금재로서 준비하는 제1단계, 샌드 블라스팅 공정 및 산세정액을 이용하여 상기 티타늄 다공막 표면에 형성된 산화막을 제거하는 제2단계, 상기 제2단계에서 표면처리된 티타늄 다공막의 표면에 백금을 도금하는 제3단계 및 상기 제3단계에서 얻어진 백금 도금 티타늄 다공막을 400-800℃로 열처리하는 제4단계를 포함하는 티타늄 다공막 제조방법을 제시한다.
Resumen de: WO2025041808A1
Provided is an electrode exhibiting high oxygen generating electrode catalytic activity as compared with conventional electrodes using manganese-based oxide as an oxygen generating electrode catalyst.
Resumen de: KR20250092308A
본 발명에 의하면, 메탄을 포함하는 메탄 원료가스에 대한 자열 개질 반응을 수행하여 수소를 포함하는 개질가스를 생산하는 자열 개질 반응기; 및 상기 자열 개질 반응기로 상기 자열 개질 반응에 필요한 산소를 공급하는 산소 공급부를 포함하며, 상기 산소 공급부는 물을 수소와 산소로 전기분해하는 수전해기에서 생성된 부생산소를 상기 자열 개질 반응기에 공급하는 부생산소 공급 시설을 구비하는 자열 개질 수소 생산 설비가 제공된다.
Resumen de: KR20250092336A
본 발명에 의하면, 수저해 시스템; 및 상기 수전해 시스템을 원자력 발전 시스템과 연계시키는 중간 열교환 시스템을 포함하며, 상기 수전해 시스템은, 저온 수전해 방식으로 전해수를 수소와 산소로 전기분해하여 수소를 생성하고 상기 원자력 발전 시스템으로부터 상기 전기분해에 필요한 전력을 공급받는 수전해기와, 상기 수전해기로부터 생성된 수소가스를 냉수와 열교환시켜서 냉각하는 수소가스 냉각기를 구비하며, 상기 전해수는 상기 수전해기에 순환 공급되며, 상기 중간 열교환 시스템은 전해수 열교환기와, 흡수식 냉동기와, 냉동기 열교환기를 구비하며, 상기 전해수 열교환기는 상기 전해수를 상기 원자력 발전 시스템에 구비되는 증기 발생기로 공급되는 급수와 열교환시켜서 상기 전해수를 냉각하고 상기 급수를 가열하며, 상기 냉수가 상기 흡수식 냉동기의 냉동기 냉수로서 상기 흡수식 냉동기와 상기 수소가스 냉동기 사이를 순환하고, 냉동기 온수가 상기 흡수식 냉동기와 상기 냉동기 열교환기 사이를 순환하며, 상기 냉동기 열교환기는 상기 냉동기 온수를 상기 원자력 발전 시스템에 구비되는 증기 발생기로 공급되는 급수와 열교환시켜서 상기 급수를 가열하는 원자력 발전 연계형 수소 생산 설비가 제공
Resumen de: WO2025127755A1
A hydrogen production apparatus of the present invention comprises: an ammonia decomposition reactor for decomposing ammonia to discharge a mixed gas including hydrogen, nitrogen, and unreacted ammonia; an ammonia remover for receiving the mixed gas, adsorbing and removing the unreacted ammonia included in the mixed gas, and discharging a first product gas including hydrogen and nitrogen and a first tail gas; and a nitrogen remover for receiving the first product gas, removing nitrogen included in the first product gas, and discharging a second product gas including hydrogen and a second tail gas, wherein the second product gas discharged from the nitrogen remover is resupplied to the nitrogen remover as a purge gas and a pressurizing gas. According to the hydrogen production apparatus of the present invention, high-purity hydrogen can be continuously produced in large quantities.
Resumen de: WO2025126639A1
Provided is a method for producing a hydrogen gas, which enables the production of a hydrogen gas with high energy efficiency. This method for producing a hydrogen gas includes: placing water between electrodes; and allowing pulsed discharge to occur between the electrodes to decompose water molecules, thereby generating the hydrogen gas. In the method, the frequency for the pulsed discharge is 190-196 kHz or a double vibration frequency thereof.
Resumen de: US2025198025A1
A method of operating an electrolyzer module includes providing a first air stream and steam into a stack of electrolyzer cells located in a hotbox and outputting a product stream containing hydrogen and steam, and an oxygen exhaust stream, providing the product stream to an internal product cooler (IPC) heat exchanger located in the hotbox to reduce the temperature of the product stream by transferring heat to the first air stream, and providing the product stream from the IPC to an external product cooler (EPC) heat exchanger located outside of the hotbox and inside of a cabinet housing the hotbox to further reduce the temperature of the product stream by transferring heat to a fluid stream.
Resumen de: KR20250092047A
제1 방향 및 제2 방향으로 연장되며 제3 방향으로 서로 마주보는 제1 면과 제2 면, 및 제2 방향으로 연장되며 제1 방향으로 서로 마주보는 제3 면 및 제4 면을 가지는 기판, 제1 면, 제2 면, 또는 제1 면 및 제2 면의 표면에 위치하는 채널, 채널로 개구되며 채널을 따라 이격되어 배치되는 복수개의 제1 개구들, 제1 개구들과 연결되며 기판을 관통하여 기판의 일 측으로 개구되는 제1 관통 유로, 채널로 개구되며 채널을 따라 이격되어 배치되는 복수개의 제2 개구들, 그리고, 제2 개구들과 연결되며 기판을 관통하여 기판의 일 측으로 개구되는 제2 관통 유로를 포함하며, 제1 개구들 또는 제2 개구들은 서로 이격 배치되고, 제1 관통 유로와 제2 관통 유로는 서로 이격 배치되는, 고분자 전해질 막-전극 어셈블리용 분리판을 제공한다.
Resumen de: KR20250091968A
본 발명의 예시적인 실시예들에 따르면, 스택의 열 취급을 용이하게 수행할 수 있는 분리판이 제공된다. 상기 분리판은, 제1 사이드에 위치하고, 제1 유체가 공급되도록 구성된 제1 공급구, 상기 제1 공급구와 연결되고, 상기 제1 유체가 상기 제1 사이드와 반대인 제2 사이드를 향해 유동하도록 구성된 제1 유로, 상기 제1 유로와 이격되고, 상기 제2 사이드로 유동한 상기 제1 유체가 상기 제1 사이드를 향해 유동하도록 구성된 제2 유로, 및 상기 제1 사이드에 위치하고, 상기 제2 유로와 연결되되, 상기 제1 유체가 배출되도록 구성된 제1 배출구를 포함하고, 상기 제2 유로는, 상기 제2 사이드에 인접하게 위치하고, 상기 제2 사이드로 유동한 상기 제1 유체가 상기 제2 유로로 유동하도록 구성된 관통구를 포함한다.
Resumen de: KR20250092007A
본 발명의 일 실시형태는 유체 입구와, 유체 출구 및 상기 유체 입구 및 상기 유체 출구와 연결된 유로의 적어도 일부를 형성하는 복수의 유선형 벽체를 포함하며, 상기 복수의 유선형 벽체 중 적어도 두 개는 일단과 타단을 연결한 직선이 서로 평행하지 않은 전기화학 디바이스용 분리판을 제공한다.
Resumen de: WO2025127730A1
According to exemplary embodiments of the present invention, a support is provided. The support is a support of a catalyst for ammonia decomposition, and the amount of acid sites of the support, as measured by NH3-temperature programmed desorption (NH3-TPD), is 0.006-0.010 mmol/g. Also, according to other exemplary embodiments of the present invention, provided are a method for manufacturing the support, and a catalyst for ammonia decomposition, comprising the support.
Resumen de: US2025201888A1
Disclosed are an insulating manifold for electrochemical reaction configured to receive gas from an external source, and an electrochemical reaction system in which there is no electrical contact between a stack and a manifold. The insulating manifold for the electrochemical reaction includes a plate-shaped base manifold having at least a first fluid conduit and a second fluid conduit extending therethrough vertically; a housing disposed on top of the base manifold and having a vertical wall and an open bottom surface, wherein a lower edge of the housing is coupled to a top of the base manifold; and upper and lower insulating plates respectively defining an upper surface and a lower surface of an inner space defined by the base manifold and the housing.
Resumen de: WO2025127526A1
According to exemplary embodiments of the present invention, a hydrogen production system is provided. The present invention comprises: a hydrogen generation unit configured to receive reduced iron from a reduced iron generation unit configured to generate reduced iron by reducing powdered iron ore in a reducing gas atmosphere, and to generate hydrogen from ammonia by bringing the reduced iron into contact with the ammonia; and a regeneration unit configured to receive the reduced iron from the hydrogen generation unit and to regenerate the reduced iron by reducing the reduced iron in a hydrogen gas atmosphere. According to other exemplary embodiments of the present invention, a method for producing hydrogen is provided.
Resumen de: WO2025127896A1
According to exemplary embodiments of the present invention, a hydrogen production system is provided. The hydrogen production system comprises: a dry quenching facility configured to cool coke using a cooling gas; a boiler configured to receive the cooling gas from the dry quenching facility and recover heat energy of the cooling gas to produce first steam and electric power; and a water electrolysis facility configured to receive the electric power from the boiler and electrolyze second steam to produce hydrogen. According to other exemplary embodiments of the present invention, a method for producing hydrogen is provided.
Resumen de: PL447183A1
Przedmiotem zgłoszenia jest wysokociśnieniowy elektrolizer alkaliczny wodoru i tlenu, będący urządzeniem, które jednocześnie wytwarza wodór i tlen na drodze procesu elektrolizy wody, po doprowadzeniu do anody i katody (elektrod) potencjału elektrycznego. Wysokociśnieniowy elektrolizer ma dwie niezależne od siebie pompy (12) umieszczone po jednej na dwóch przewodach zasilających elektrolitem alkalicznym, gdzie oba przewody zasilające połączone są po stronie tłocznej pomp (12) do dwóch stron hydro akumulatora (11), a w dalszym biegu przewodów zasilających jeden przewód podłączony jest do króćca zasilającego obiegu tlenowego (T), a drugi przewód do króćca zasilającego obiegu wodorowego (W) i w dalszym biegu przewód (W) połączony jest równolegle z obiegami omywającymi elektrolitem katody, a przewód (T) połączony jest równolegle z obiegami omywającymi anody pakietu elektrod katoda/anoda (2), gdzie sąsiadujące ze sobą obiegi katody i anody oddzielone są od siebie szczelnie membranami elektrolitycznymi (3).
Resumen de: KR20250090440A
본 발명은 수증기와 수소의 혼합물을 포함하는 연료와 공기를 입력 받아 전기분해를 통해 수소 및 수증기 혼합물을 생성하는 고체 산화물 전기분해 셀을 포함하고, 상기 고체 산화물 전기분해 셀에서 생성된 수소 및 수증기 혼합물의 일부는 제1분기에서 재순환하여 상기 연료에 혼합되고, 나머지는 분리기에서 수소와 수증기로 분리되고, 상기 분리기에서 분리된 수증기 중 일부는 제2분기에서 재순환되어 상기 연료에 혼합되는 고체 산화물 연료전지 셀 시스템에 관한 것이다.
Resumen de: KR20250090710A
일 실시예에 따른 수전해 설비의 전원 공급 장치는, 전원, 상기 전원으로부터 입력 전력을 제공받고 상기 수전해 설비로 출력 전력을 제공하는 전력변환기, 상기 전력변환기로부터 충전 전력을 제공 받고 상기 전력변환기로 방전 전력을 제공하는 배터리 및 상기 전력변환기 또는 배터리를 제어하는 제어기를 포함하고, 상기 제어기는 상기 출력 전력에 기반하여 상기 충전 전력 및 상기 방전 전력을 제어할 수 있다.
Resumen de: KR20250090996A
본 발명은 애노드 다공막 제조방법과 관련된다. 본 발명은 실시예로, 금속소재를 막대 형태로 제조하는 제1단계, 상기 제1단계에서 제조된 막대 형태의 금속소재와 상기 금속소재와 동일한 금속의 분말소재를 혼합하고 용매를 투입하여 슬러리를 제조하는 제2단계, 상기 제2단계에서 제조된 슬러리를 테이프캐스팅하여 그린시트를 제조하는 제3단계, 상기 제3단계에서 제조된 그린시트를 탈지하고 소결하여 소결된 다공막을 얻는 제4단계 및 상기 제4단계에서 얻어진 소결된 다공막을 압연처리하여 표면 조도를 감소시키도록 조절하는 제5단계를 포함하는 애노드 다공막 제조방법을 제시한다.
Resumen de: EP4574255A1
In a method of preparing an ammonia decomposition catalyst according to embodiments of the present disclosure, a mixture of a metal oxide including lanthanum and a heterogeneous metal and aluminum oxide is prepared, the mixture was subj ected to steam treatment to form a carrier, and an active metal is supported on the carrier to prepare an ammonia decomposition catalyst. The ammonia decomposition catalyst according to embodiments of the present disclosure is prepared by the above-described preparation method.
Resumen de: KR20250091080A
활성 영역(active area) 및 활성 영역을 둘러싸는 비활성 영역(inactive area)를 가지는 고분자 전해질 막; 고분자 전해질 막의 활성 영역의 제1 면 위에 위치하는 수소 발생 전극; 고분자 전해질 막의 활성 영역의 제2 면 위에 위치하는 산소 발생 전극; 고분자 전해질 막의 비활성 영역의 제1 면 위에 배치되며 제1 전극을 둘러싸는 제1 서브가스켓; 그리고 고분자 전해질 막의 비활성 영역의 제2 면 위에 배치되어 제2 전극을 둘러싸는 제2 서브가스켓;을 포함하며, 제1 서브가스켓은 수소 발생 전극을 수용하는 제1 윈도우, 및 제1 윈도우를 둘러싸며 고분자 전해질 막의 비활성 영역을 노출시키는 제1 물 공급 경로를 가지는, 수전해셀용 막-전극 어셈블리를 제공한다.
Resumen de: WO2024120594A1
A hydrogen generation system comprising a wind turbine installation including a wind energy generator (18) connected to a hydrogen electrolyser (30) by a power converter system (22) The power converter system (22) comprises a generator-side converter (24) and a electrolyser-side converter (26) which are coupled together electrically by a DC-link (28), and a converter controller (50) comprising a generator-side control module (50) coupled to the generator-side converter and a electrolyser-side control module (52) coupled to the electrolyser-side converter. The converter controller is configured to control the load torque on the wind energy generator and the electrical power fed to the electrolyser to implement a mechanical damping function associated with the wind turbine installation whilst maintaining a stable DC-link voltage. Beneficially, therefore, the wind turbine installation can implement active control of electromechanical damping systems whilst operating the electrolyser at an efficient operating point.
Resumen de: KR20250090704A
일 실시예에 따른 수전해 설비의 전원 공급 장치는, 전원, 상기 전원으로부터 입력 전력을 제공받고 상기 수전해 설비로 출력 전력을 제공하는 전력변환기 및 상기 전력변환기를 제어하는 제어기를 포함하고, 상기 전력변환기는 상기 입력 전력을 상기 수전해 설비의 작동 조건에 맞는 출력 전력으로 변환할 수 있다.
Resumen de: US2025198028A1
A method operating an electrolyzer system includes producing hydrogen by electrolysis of steam in at least one electrolyzer cell stack of the electrolyzer system using power received from an intermittent power source, detecting a reduction in a level of power received from the intermittent power source below a first threshold, decreasing a rate of producing hydrogen in response to the detected reduction in the level power below the first threshold, detecting a reduction in a level of power received from the intermittent power source below a second first threshold that is lower than the first threshold, and switching the electrolyzer system into a hot standby mode in which the electrolyzer system does not produce hydrogen and maintains the least one electrolyzer cell stack above a predetermined threshold temperature.
Resumen de: WO2025124766A1
The invention relates to an electrolytic cell (01) for the electrolysis of CO2, comprising a cathode side (02) and an anode side (03). The electrolytic cell (01) comprises a cathode plate (04), a gas chamber (06), a gas-diffusion layer (08), a catalyst layer (09), a water chamber (07) and an anode plate (05). The contacting of the catalyst layer (09) is optimized by using a plurality of current bridges (10). To this end, these current bridges (10) are electrically conductively connected to the cathode plate (04) and to the catalyst layer (09) while penetrating the gas-diffusion layer (08).
Resumen de: US2025198026A1
Disclosed herein are aspects of a composition comprising one or more metal-oxide nanoparticles and porous catalyst layers, comprising an electrically conductive core a surface layer comprising one or more surface active catalysts; and wherein the one or more metal-oxide nanoparticles are electrocatalytic toward oxygen gas evolution in alkaline conditions, alkaline-ionomer conditions, or a combination thereof. Aspects of a method of making such compositions for water oxidation alkaline and alkaline membrane electrolyzers are also disclosed herein. Also disclosed herein is an alkaline-exchange-membrane ionomer-based, hybrid liquid-alkaline, alkaline-ionomer electrolyzer comprising an anode, wherein the anode comprises (i) an ionomer and (ii) the composition disclosed herein and a liquid alkaline electrolyzer comprising an anode, wherein the anode comprises one or more catalysts having the composition disclosed herein, wherein the composition is produced as a powder or as a continuous electrode architecture on metal porous transport layers.
Resumen de: US2025198020A1
A hydrogen gas generation system comprises a reactor chamber, an elongate cathode, an ammonia inlet, a hydrogen gas outlet, and a collection outlet. The reactor chamber has an input end and an output end. A wall of the reactor chamber between the input end and the output end is an anode. The elongate cathode extends between the input end and the output end through an interior of the reactor chamber. The ammonia inlet is positioned to introduce a liquid ammonia into the reactor chamber such that the liquid ammonia flows in a direction from the input end to the output end. The hydrogen gas outlet at the output end, wherein a hydrogen gas generated in the reactor chamber exits the reactor chamber through the hydrogen gas outlet. The collection outlet is at the output end. Nitrogenous compounds exit the reactor chamber through the collection outlet.
Resumen de: WO2025129081A1
A method, comprising electrolyzing a CO2 input and water so as to form a first product comprising CO and H2, the electrolyzing optionally being performed over a Pd/C catalyst or a catalyst that comprises any one or more of gold, silver, iron, cobalt, nickel, copper, or zinc; and thermochemically processing the first product so as to give rise to a second product that comprises carbon nanofibers or nanotubes. A system, comprising: a first reaction zone, the first reaction zone configured to receive CO2 input and water, and the first reaction zone configured for electrolysis of the CO2 input and water to evolve a product that comprises CO; a second reaction zone, the second reaction zone configured to receive a product from the first reaction zone, the second reaction zone configured to support at least one of the Boudouard reaction (R1) and CO + H2 → C(s) + H2O (R2).
Resumen de: US2025198023A1
An electrolyzer for gaseous production such as hydrogen gas includes an oscillating electrode driven at a natural frequency of the gaseous bubbles improves output by readily removing the gaseous bubble product from the electrode surface, thereby exposing greater electrode surface area for subsequent electrolysis reactions. A natural frequency of the gaseous product determines an oscillation frequency with which to drive the electrode accumulating the gaseous product, such as hydrogen bubbles, to agitate and release the bubbles which then rise to the surface of the liquid filled containment. Integrating oscillation logic for agitating the otherwise stationary electrode or cathode in a PEM water electrolyzer improves hydrogen production by readily evacuating the generated hydrogen to free up the electrode area for additional electrolysis reactions.
Resumen de: US2025198014A1
An electrolyzer system includes a splitter configured to split a first air inlet stream into a bypass air stream and a second air inlet stream, a stack of electrolyzer cells configured receive steam and the second air inlet stream and output a product stream containing hydrogen and an oxygen exhaust stream, such that the bypass air stream is configured to bypass the stack, and a product cooler heat exchanger configured to cool the product stream using the first air inlet stream.
Resumen de: US2025196071A1
The present invention relates to a hydrogen ion conductive multilayer composite membrane comprising one or more inner reinforced membrane comprising a porous PTFE layer impregnated with an ionomer composition and outer reinforced membranes positioned on both sides of the inner reinforced membrane, wherein the outer reinforced membranes comprise a porous PTFE layer impregnated with an ionomer composition.
Resumen de: US2025202278A1
A power plant is configured to output power to a grid power system and comprises a hydrogen generation system configured to produce hydrogen, a gas turbine combined cycle power plant comprising a gas turbine engine configured to combust hydrogen from the hydrogen generation system to generate a gas stream that can be used to rotate a turbine shaft and a heat recovery steam generator (HRSG) configured to generate steam with the gas stream of the gas turbine engine to rotate a steam turbine, a storage system configured to store hydrogen produced by the hydrogen generation system, and a controller configured to operate the hydrogen generation system with electricity from the grid power system when the grid power system has excess energy and balance active and reactive loads on the grid power system using at least one of the hydrogen generation system and the gas turbine combined cycle power plant.
Resumen de: US2025201888A1
Disclosed are an insulating manifold for electrochemical reaction configured to receive gas from an external source, and an electrochemical reaction system in which there is no electrical contact between a stack and a manifold. The insulating manifold for the electrochemical reaction includes a plate-shaped base manifold having at least a first fluid conduit and a second fluid conduit extending therethrough vertically; a housing disposed on top of the base manifold and having a vertical wall and an open bottom surface, wherein a lower edge of the housing is coupled to a top of the base manifold; and upper and lower insulating plates respectively defining an upper surface and a lower surface of an inner space defined by the base manifold and the housing.
Resumen de: WO2025127896A1
According to exemplary embodiments of the present invention, a hydrogen production system is provided. The hydrogen production system comprises: a dry quenching facility configured to cool coke using a cooling gas; a boiler configured to receive the cooling gas from the dry quenching facility and recover heat energy of the cooling gas to produce first steam and electric power; and a water electrolysis facility configured to receive the electric power from the boiler and electrolyze second steam to produce hydrogen. According to other exemplary embodiments of the present invention, a method for producing hydrogen is provided.
Resumen de: WO2025127894A1
The present invention relates to a system for reducing fuel consumption and recovering CO2, comprising: a water electrolysis facility system for producing hydrogen and oxygen from water or steam; a combustion facility for combusting fuel by using the produced oxygen; and a CO2 recovery facility for recovering CO2 from an exhaust gas discharged from the combustion facility.
Resumen de: WO2025127730A1
According to exemplary embodiments of the present invention, a support is provided. The support is a support of a catalyst for ammonia decomposition, and the amount of acid sites of the support, as measured by NH3-temperature programmed desorption (NH3-TPD), is 0.006-0.010 mmol/g. Also, according to other exemplary embodiments of the present invention, provided are a method for manufacturing the support, and a catalyst for ammonia decomposition, comprising the support.
Resumen de: WO2025127755A1
A hydrogen production apparatus of the present invention comprises: an ammonia decomposition reactor for decomposing ammonia to discharge a mixed gas including hydrogen, nitrogen, and unreacted ammonia; an ammonia remover for receiving the mixed gas, adsorbing and removing the unreacted ammonia included in the mixed gas, and discharging a first product gas including hydrogen and nitrogen and a first tail gas; and a nitrogen remover for receiving the first product gas, removing nitrogen included in the first product gas, and discharging a second product gas including hydrogen and a second tail gas, wherein the second product gas discharged from the nitrogen remover is resupplied to the nitrogen remover as a purge gas and a pressurizing gas. According to the hydrogen production apparatus of the present invention, high-purity hydrogen can be continuously produced in large quantities.
Resumen de: WO2025127536A1
Disclosed are a catalyst electrode for ammonia electrolysis and a method for effectively producing same, wherein the ratio of oxides and hydroxides in the catalyst electrode for ammonia water electrolysis is improved by introducing a heat treatment step for heat treatment within a specific temperature range after an electroplating step, and as a result, poisoning by nitrogen oxides is suppressed such that durability is improved, and excellent ammonia water electrolysis performance is achieved.
Resumen de: US2025197205A1
Disclosed is an apparatus for producing hydrogen gas from ammonia gas using a laser. A decomposition device for decomposing ammonia gas in order to produce hydrogen gas includes an ammonia inlet provided at an uppermost end of the decomposition device to allow ammonia gas to easily flow into the decomposition device, a hydrogen outlet configured to discharge the hydrogen gas produced by decomposition of the ammonia gas, and a nitrogen outlet configured to discharge nitrogen gas produced by the decomposition of the ammonia gas. Laser light in a preset first wavelength band is incident from an outside to a contact point of the ammonia inlet, the hydrogen outlet, and the nitrogen outlet, so that the ammonia gas is decomposed.
Resumen de: US2025197314A1
A hydrocarbon production system includes: an impurity removal device that removes an impurity including any one or both of oxygen and a sulfur component from a mixed gas containing the impurity and carbon dioxide; a hydrocarbon production device, which includes a hydrocarbon synthesis catalyst for promoting a reaction for synthesizing hydrocarbon from carbon dioxide and hydrogen and synthesizes the hydrocarbon from the carbon dioxide contained in the mixed gas having the impurity removed by the impurity removal device and hydrogen; and a heat supply unit that supplies reaction heat generated in the hydrocarbon production device to the impurity removal device.
Resumen de: US2025196120A1
The present invention provides a method for producing a heterojunction photocatalyst having higher catalytic activity than that of conventional heterojunction photocatalysts, and a heterojunction photocatalyst. A method for producing a heterojunction photocatalyst having a solid state mediator between a hydrogen-evolution photocatalyst and an oxygen-evolution photocatalyst, which includes the following step 1: step 1: a step of joining the solid state mediator onto the oxygen-evolution photocatalyst by at least one method selected from the group consisting of a photoelectrodeposition method, an impregnation supporting method, and a precipitation method, in each of which an organic carboxylic acid compound and a solid state mediator or a precursor of the solid state mediator are used.
Resumen de: US2025196119A1
The present invention provides a heterojunction photocatalyst having higher catalytic activity than that of conventional junction photocatalysts. The heterojunction photocatalyst of the present invention is a heterojunction photocatalyst having a solid state mediator between a hydrogen-evolution photocatalyst and an oxygen-evolution photocatalyst, in which the solid state mediator and the hydrogen-evolution photocatalyst are joined to each other via an ionic polymer.
Resumen de: US2025197207A1
A method may provide a mechanical mill for reducing a size of particles; wherein the mechanical mill includes: a core for accelerating particles, the core including: a first disc and a second disc facing the first disc in an axial direction, wherein each of the first disc and the second disc includes a plurality of concentric rings and a plurality of concentric channels alternately interleaved with the plurality of concentric rings; and wherein the first disc, the second disc, or a combination thereof are rotated. A method may introduce water into the mechanical mill. A method may introduce soil particles into the mechanical mill. A method may activate the mechanical mill to accelerate the water and the soil particles. A method may thereby produce nanoparticles from the soil particles and producing hydrogen from a reaction between the nanoparticles and the water.
Resumen de: WO2025127526A1
According to exemplary embodiments of the present invention, a hydrogen production system is provided. The present invention comprises: a hydrogen generation unit configured to receive reduced iron from a reduced iron generation unit configured to generate reduced iron by reducing powdered iron ore in a reducing gas atmosphere, and to generate hydrogen from ammonia by bringing the reduced iron into contact with the ammonia; and a regeneration unit configured to receive the reduced iron from the hydrogen generation unit and to regenerate the reduced iron by reducing the reduced iron in a hydrogen gas atmosphere. According to other exemplary embodiments of the present invention, a method for producing hydrogen is provided.
Resumen de: WO2025127476A1
Provided is a membrane-electrode assembly for a water electrolysis cell, comprising: a polymer electrolyte membrane having an active area and an inactive area surrounding the active area; a hydrogen generation electrode positioned on a first surface of the active area of the polymer electrolyte membrane; an oxygen generation electrode positioned on a second surface of the active area of the polymer electrolyte membrane; a first sub-gasket which is disposed on a first surface of the inactive area of the polymer electrolyte membrane and which surrounds a first electrode; and a second sub-gasket which is disposed on a second surface of the inactive area of the polymer electrolyte membrane and which surrounds a second electrode, wherein the first sub-gasket has a first window that accommodates the hydrogen generation electrode, and a first water supply path that surrounds the first window and exposes the inactive area of the polymer electrolyte membrane.
Resumen de: WO2025127502A1
Provided according to exemplary embodiments of the present invention is an ammonia decomposition system capable of minimizing the generation of iron nitride, which is a by-product.
Resumen de: WO2025127054A1
The present disclosure provides at least one of an iridium-containing manganese oxide that exhibits high oxygen-generating electrode catalytic activity in a water electrolysis method, a catalyst that contains the same, an electrode that contains the catalyst, and a water electrolysis method that uses the electrode. With respect to the iridium-containing manganese oxide according to the present invention, the molar ratio of iridium to manganese is not less than 0.001 but 0.250 or less. In one embodiment, the manganese oxide is manganese dioxide that has a β-type crystal structure. In another embodiment, the ratio of the lattice constant in the a-axis direction to the lattice constant in the c-axis direction is not less than 1.420 but less than 1.521.
Resumen de: WO2025126547A1
The present invention addresses the problem of providing a hydrogen storage system in which the deterioration of a storage alloy can be suppressed. The present invention relates to a hydrogen storage system provided with a hydrogen production part for producing hydrogen and a storage tank, wherein the storage tank is provided with: a storage alloy which stores the produced hydrogen; a housing in which the storage alloy is housed; a first opening which is provided in the housing and into which a supply gas containing the produced hydrogen is sent from the hydrogen production part side; and a second opening which is provided in the housing separately from the first opening and from which the supply gas is sent out to the outside.
Resumen de: US2025198013A1
A method of preparing hydrogen based on micro-droplets includes: S1, mixing water and a regulator to obtain an aqueous solution, where the regulator is one or more of: a metal conductor, a nanomaterial, a conductive polymer, and an inorganic salt having a redox property; S2, inputting the aqueous solution to a micro-droplet generation device to generate the micro-droplets, where each of the micro-droplets has a size of less than or equal to 10 μm, and hydrogen radicals are spontaneously generated at a gas-liquid interface of each of the micro-droplets; S3, the hydrogen radicals being compounded with each other to generate the hydrogen; and S4, collecting the hydrogen or the hydrogen radicals.
Resumen de: US2025198012A1
The invention pertains to an electrolyser for producing hydrogen (H2) and oxygen (O2) as product gases. It includes an electrolysis module and a gas separator for phase separation of the product gas from water. The electrolysis module is connected to the gas separator via a product flow line, and a return line with a circulation pump connects the gas separator back to the electrolysis module for separated water. A bypass line with a valve allows water to be supplied from the gas separator to the electrolysis module during standstill. The invention also covers a method for operating the electrolyser, where in standstill mode, the electrolysis current is stopped, and a safety deactivation is initiated. Water is automatically driven into the electrolysis module due to a hydrostatic differential pressure (Δp) from a predefined height difference (Δh), flooding the electrolysis module.
Resumen de: US2025186304A1
A hydrogen generation device includes a tubular tank and a top lid combined with the tank. An immersion tube in which a hydrogen generating agent package is stuffed is placed in the tank. The hydrogen generating agent package is submerged in water after water is poured in the tank to generate hydrogen, which is released through a tank opening of the tank. The hydrogen generating agent package accommodates hydrogen generating agent powders including calcium oxide and aluminum powders, both of which are mixed and wrapped with a nonwoven fabric, as well as a little catalytic sodium carbonate added inside. For inhibition of free radicals and promotion of metabolism, the hydrogen generation device is further provided with a connector and a hose for a skin-care instrument, a nasal mask, an eye shield or an ear cleaner through which hydrogen is supplied as required.
Resumen de: WO2025124674A1
Alkaline electrolyser and a method for its operation including gas purging An alkaline electrolyser comprising a stack (17) of electrolytic cells (1) is used for producing hydrogen gas (8). Purified hydrogen gas and purified oxygen gas is used for purging the corresponding cathode and anode compartments (5, 6) for preventing buildup of dangerous gas mixtures by gas crossover during stop, before starting, or when running production low.
Resumen de: WO2025126639A1
Provided is a method for producing a hydrogen gas, which enables the production of a hydrogen gas with high energy efficiency. This method for producing a hydrogen gas includes: placing water between electrodes; and allowing pulsed discharge to occur between the electrodes to decompose water molecules, thereby generating the hydrogen gas. In the method, the frequency for the pulsed discharge is 190-196 kHz or a double vibration frequency thereof.
Resumen de: WO2025125243A1
The invention relates to a method for producing an electrode (10) for use in alkaline electrolysis of water, the method comprising: providing a metal substrate (12); providing a coating material (26) comprising powder (28) consisting of a catalyst material (20), and comprising non-metal particles (24); and coating at least a portion of the substrate with the coating material. The invention also relates to electrodes produced in this way.
Resumen de: WO2025125633A1
The present disclosure relates to apparatuses for producing hydrogen, and to top-down methods for producing nanoparticles. Different mechanical mills may be used to break down micron sized soil or sand particles and to react the particles with water, particularly sea water.
Resumen de: WO2025125439A1
A methanol plant and process for producing methanol are provided. A first SOE section is arranged to receive a carbon dioxide-rich feed and electrolyse it to a carbon monoxide-rich stream. A methanol loop is arranged to receive at least a portion of the carbon monoxide-rich stream and a hydrogen-rich stream and convert them to a crude methanol stream. A first H2O-rich stream is converted to a first steam stream by means of heat from the electrolysis process in the first SOE section. The first steam stream is used it as heat for the distillation of the crude methanol stream in the methanol distillation section.
Resumen de: WO2025125346A1
The present application relates to a water electrolyzer cell (26), related stack of water electrolyzer cells and process The cell (26) comprises a cell casing (34) defining an anodic compartment (36) and a cathodic compartment (38). The anodic compartment (36) comprises an anode chamber (50) and the cathodic compartment (38) comprises a cathode chamber (58). The cell casing (34) comprises a membrane (40) separating the anode chamber (50) from the cathode chamber (58). The anodic compartment (36) defines, within the cell casing (34), an anodic degassing cavity (52) located on top of the anode chamber (50). On the other side, the cathodic compartment (38) defines, within the cell casing (34), an cathodic degassing cavity (60) located on top of the cathode chamber (58). The cell casing (34) comprises a partition wall (42) tightly separating the anodic degassing cavity (52) from the cathodic degassing cavity (60).
Resumen de: WO2025125181A1
The invention relates to the synthesis of urea from ammonia and carbon dioxide, wherein the hydrogen required for ammonia synthesis is obtained both by steam reforming of feed natural gas (grey hydrogen) and by electrolysis of water using electricity from renewable energy sources (green hydrogen). As the proportion of green hydrogen increases, the amount of carbon dioxide formed in the synthesis gas during steam reforming is no longer sufficient for the synthesis of urea. Therefore, flue gas, which is formed during the combustion of a fuel gas composed of fuel natural gas and combustion air and which also contains carbon dioxide, is additionally used. The oxygen formed during the electrolysis of water is introduced into the flue gas, and the modified flue gas is fed to a secondary reformer; and/or the fuel natural gas is combusted together with combustion air and the oxygen formed during electrolysis. Excess nitrogen is preferably separated from the synthesis gas before it is used for the synthesis of ammonia.
Resumen de: WO2025125180A1
The invention relates to the synthesis of urea from ammonia and carbon dioxide, wherein the hydrogen required for ammonia synthesis is obtained both by steam reforming of feed natural gas (grey hydrogen) and by electrolysis of water using electricity from renewable energy sources (green hydrogen). As the proportion of green hydrogen increases, the amount of carbon dioxide formed in the synthesis gas during steam reforming is no longer sufficient for the synthesis of urea. Therefore, flue gas, which is formed during the firing of the steam reformer and also contains carbon dioxide, is additionally used. After reducing the nitrogen content, the flue gas is fed into the reforming process. The carbon dioxide from the synthesis gas and the flue gas is combined, separated using conventional carbon dioxide scrubbing, and used for the synthesis of urea.
Resumen de: WO2025128530A1
A method for producing hydrogen using a feed stream comprising ammonia is provided. The method can include the steps of: cracking a gaseous ammonia feed in an ammonia cracker to produce a cracked gas stream comprising hydrogen, nitrogen, and unreacted ammonia; cooling the cracked gas stream to a first temperature that is sufficient for condensing at least a portion of the unreacted ammonia to form a dual phase fluid; separating the dual phase fluid in an ammonia separator to produce a liquid ammonia stream and a top gas stream comprised predominately of hydrogen and nitrogen; removing additional ammonia from the top gas stream using a front-end purification system to form a purified top gas stream; further cooling the purified top gas stream to a second temperature that is sufficient for condensing at least a portion of the nitrogen within the top gas stream to form a dual-phase stream, wherein the second temperature is colder than the first temperature; introducing the dual-phase stream to a cryogenic hydrogen separator under conditions effective for separating hydrogen and nitrogen, thereby creating a liquid nitrogen stream and a hydrogen top gas; warming and vaporizing the liquid nitrogen stream to produce a gaseous nitrogen stream; warming the hydrogen top gas to produce a gaseous hydrogen product stream: and recycling the liquid ammonia stream produced by the ammonia separator to a point upstream the ammonia cracker.
Resumen de: WO2025126055A1
A system is described for the production of hydrogen and thermal power through a spontaneous electrochemical oxidation-reduction reaction, formed by at least one reactor (1) composed by a loading line (2) that introduces a reacting material into a reaction basin (6); at least one discharge body (12) for the hydroxide produced during the reaction, wherein the pH is transformed into a desired value by the introduction of an acidic solution through a loading line (13); at least one loading line (3) of water that is supplied into the reaction basin (6); at least one cathode body (5) made of porous material containing gaseous oxygen; at least one loading line (4) that allows the oxygen to be replenished at the cathode body (5); at least one porous material filter (7) for separating the gaseous hydrogen from solid residues produced during the reaction; and at least one discharge line (8) for the release of gaseous hydrogen. The system is configured to perform a process for the production of hydrogen and thermal power through an oxidation-reduction reaction between a material acting as an anode, a material acting as a cathode and a material acting as an electrolyte.
Resumen de: WO2025128535A1
A method for producing hydrogen using a feed stream comprising ammonia is provided. The method may include the steps of: cracking a gaseous ammonia feed comprising ammonia and at least 0.15% water vapor in an ammonia cracker to produce a cracked gas stream comprising hydrogen, nitrogen, unreacted ammonia, and water vapor; cooling the cracked gas stream to a separation temperature that is sufficient for condensing at least a portion of the unreacted ammonia and the water vapor to form a dual phase fluid; separating the dual phase fluid in a separator that is configured to produce an aqueous ammonia stream and a vapor stream, the vapor stream comprising predominantly of hydrogen and nitrogen; wherein the separation temperature is below 0°C.
Resumen de: WO2025127924A1
The present invention relates to an electrolyzer designed for the generation of hydrogen and oxygen through water electrolysis. The electrolyzer comprises a housing structure accommodating at least one electrolytic cell, which includes an anode, a cathode, and an ion-conducting membrane. A water inlet is provided to introduce water into the electrolytic cell, and an electrical power source is operatively connected to the anode and cathode to facilitate the electrolysis process. The electrolyzer also includes separate outlets for the efficient extraction of hydrogen and oxygen generated during electrolysis. A multi-parameter optical measurement system is integrated within the electrolyzer. This system features at least one optical fiber with multiple sensing points distributed along its length, each capable of detecting various operational parameters within the electrolyzer.
Resumen de: WO2025125277A1
The invention relates to an electrolysis system comprising an electrolysis stack (1) having multiple electrolytic cells (101) which each comprise a cathode chamber (102) and an anode chamber (103) and are designed to electrolytically split water in the anode chamber (103) into hydrogen and oxygen. The hydrogen generated in the cathode chamber (102) is fed to a first gas-liquid separator (9) through a cathode outlet (2) of the electrolysis stack (1) and via a medium line (7) connected thereto. A second gas-liquid separator (15) can be connected to the cathode outlet (2). Depending on the pressure in the electrolysis stack (1), the cathode outlet is connected to the first gas-liquid separator (9) or to the second gas-liquid separator (15).
Resumen de: WO2025124791A1
The invention relates to an offshore electrolysis system (100) comprising a wind turbine (1) having a tower (19), which is anchored to the seabed, and having an electrolysis plant (5), wherein the electrolysis plant (5) is connected to the wind turbine (1) by a supply line (11), and wherein the electrolysis plant (5) has an electrolyser (13) which is arranged in a container (9), wherein the container (9) is arranged below sea level (25). The invention also relates to a method for operating a corresponding offshore electrolysis system. In this method, water is broken down into hydrogen (H2) and oxygen by an electrolyser (13) of the electrolysis plant (5), which electrolyser is located below sea level (25), wherein the hydrogen (H2) produced is transported away via a product gas line (7).
Resumen de: US2025198025A1
A method of operating an electrolyzer module includes providing a first air stream and steam into a stack of electrolyzer cells located in a hotbox and outputting a product stream containing hydrogen and steam, and an oxygen exhaust stream, providing the product stream to an internal product cooler (IPC) heat exchanger located in the hotbox to reduce the temperature of the product stream by transferring heat to the first air stream, and providing the product stream from the IPC to an external product cooler (EPC) heat exchanger located outside of the hotbox and inside of a cabinet housing the hotbox to further reduce the temperature of the product stream by transferring heat to a fluid stream.
Resumen de: KR20250088864A
그린수소 생성장치 및 방법이 개시된다. 본 발명의 일 측면에 따르면, 제철소에서 발생하는 배가스에 물입자를 분무하는 미분무장치를 구비하고, 상기 배가스에 포함되어 있는 이산화탄소를 용해하여 포집하는 이산화탄소 포집장치; 상기 이산화탄소 포집장치로부터 전달된 이산화탄소 포집수를 가열하여 이산화탄소 가스와 액체로 분리시켜 이산화탄소를 농축 저장하는 이산화탄소 분리장치; 상기 농축 저장된 이산화탄소를 나노버블로 변환시키고 해수에 용해시켜 이산화탄소 수소이온수를 생성하는 이산화탄소 나노버블 발생장치; 및 상기 이산화탄소 수소이온수를 전극반응시켜 수소를 생산하는 전극장치;를 포함하는 그린수소 생성장치가 제공될 수 있다.
Resumen de: EP4570745A1
The present disclosure relates to apparatuses for producing hydrogen, and to top-down methods for producing nanoparticles. Different mechanical mills may be used to break down micron sized soil or sand particles and to react the particles with water, particularly sea water.
Resumen de: AU2023363865A1
Electrochemical cell system (100) which comprises an electrochemical cells arrangement (10), a control unit (20) configured to operate the electrochemical cells arrangement (10) only as electrolytic cells or only as fuel cells, a heat unit (40), external to the electrochemical cells arrangement (10), which is thermally coupled to the electrochemical cells arrangement (10) and which is configured to alternately store heat from the electrochemical cells arrangement (10) to the heat unit (40) and supply heat from the heat unit (40) to the electrochemical cells arrangement (10), and a transfer arrangement (30) configured to alternately transfer heat from the electrochemical cells arrangement (10) to the heat unit (40) and from the heat unit (40) to the electrochemical cells arrangement (10).
Resumen de: WO2025127536A1
Disclosed are a catalyst electrode for ammonia electrolysis and a method for effectively producing same, wherein the ratio of oxides and hydroxides in the catalyst electrode for ammonia water electrolysis is improved by introducing a heat treatment step for heat treatment within a specific temperature range after an electroplating step, and as a result, poisoning by nitrogen oxides is suppressed such that durability is improved, and excellent ammonia water electrolysis performance is achieved.
Resumen de: DK202330334A1
In an alkaline electrolyzer (12), especially for production of hydrogen gas, the separator (11) has larger pores in layers (8, 9) on its outer sides (7 A, 7C), facing the electrodes (13, 14), than in the bulk layer (10). In a practical embodiment, the separator (11) is composed of two diaphragms (7, 7 '), each with asymmetric pore structure, where the diaphragms (7, 7') are oriented such that largest pores are on the outer sides of the separator (11 ).
Resumen de: US2025188630A1
An oxynitride catalyst includes NiaMbNcOd, wherein M is Nb, Mn, or Co, a>0, b>0, c>0, d>0, and a+b+c+d=1. A hydrogen evolution device includes an anode and a cathode dipped in an electrolyte, and the anode includes the oxynitride catalyst. The oxynitride catalyst can be disposed on a support. The oxynitride catalyst may have a polyhedral structure.
Resumen de: AU2023285309A1
The present invention relates to a framing structure for an electrolyser subject to internal pressure, able to withstand corrosive environments and radial pressure forces. The present invention also relates to an electrolytic cell and electrolyser equipped with said framing structure, as well as its use in high-pressure water electrolysis applications.
Resumen de: EP4570958A2
A method of operating an electrolyzer module includes providing a first air stream and steam into a stack of electrolyzer cells located in a hotbox and outputting a product stream containing hydrogen and steam, and an oxygen exhaust stream, providing the product stream to an internal product cooler (IPC) heat exchanger located in the hotbox to reduce the temperature of the product stream by transferring heat to the first air stream, and providing the product stream from the IPC to an external product cooler (EPC) heat exchanger located outside of the hotbox and inside of a cabinet housing the hotbox to further reduce the temperature of the product stream by transferring heat to a fluid stream.
Resumen de: EP4570957A2
A method operating an electrolyzer system includes producing hydrogen by electrolysis of steam in at least one electrolyzer cell stack of the electrolyzer system using power received from an intermittent power source, detecting a reduction in a level of power received from the intermittent power source below a first threshold, decreasing a rate of producing hydrogen in response to the detected reduction in the level power below the first threshold, detecting a reduction in a level of power received from the intermittent power source below a second first threshold that is lower than the first threshold, and switching the electrolyzer system into a hot standby mode in which the electrolyzer system does not produce hydrogen and maintains the least one electrolyzer cell stack above a predetermined threshold temperature.
Resumen de: DE102023212702A1
Elektrolysesystem mit einem Elektrolysestack (1), der eine Vielzahl von elektrolytischen Zellen (101) umfasst, die jeweils einen Kathodenraum (102) und einen Anodenraum (103) aufweisen und die dazu ausgebildet sind, Wasser im Anodenraum (103) elektrolytisch in Wasserstoff und Sauerstoff aufzuspalten. Der im Kathodenraum (102) erzeugte Wasserstoff wird über einen Kathodenauslass (2) des Elektrolysestacks (1) und eine hieran angeschlossene Medienleitung (7) einem ersten Gas-Flüssig-Separator (9) zugeführt. Ein zweiter Gas-Flüssig-Separator (15) ist mit dem Kathodenauslass (2) verbindbar. Je nach Druck im Elektrolysestack (1) wird der Kathodenauslass mit dem ersten (9) oder mit dem zweiten Gas-Flüssig-Separator (15) verbunden.
Resumen de: DE102024125854A1
Verfahren zur Konditionierung einer Elektrolysevorrichtung (10), die zur Erzeugung von Wasserstoff aus Wasser mit Hilfe von elektrischem Strom eingerichtet ist, wobei die Elektrolysevorrichtung (10) vor dem Einbau in eine Wasserstoffproduktionsanlage zumindest einer chemischen Konditionierung über ein Durchspülen der Elektrolysevorrichtung (10) unterzogen wird.
Resumen de: GB2636333A
A system comprising two electrolysis subsystems for electrolysis of water to produce hydrogen, wherein the first subsystem produces waste thermal energy and the second uses this energy. One of the subsystems may use a low-temperature electrolysis technology and the other a high-temperature technology. Said low-temperature process may be anionic exchange membrane (AEM) electrolysis, alkaline electrolysis or a combination. The high-temperature process may be solid oxide electrolysis cell (SOEC) electrolysis. The waste thermal energy may be recovered into a heat exchange fluid and the system may also comprise a heater or a steam generator. Also claimed is a method for the system.
Resumen de: EP4570744A1
A method for producing hydrogen using a feed stream comprising ammonia is provided. The method can include the steps of: cracking a gaseous ammonia feed in an ammonia cracker to produce a cracked gas stream comprising hydrogen, nitrogen, and unreacted ammonia; cooling the cracked gas stream to a first temperature that is sufficient for condensing at least a portion of the unreacted ammonia to form a dual phase fluid; separating the dual phase fluid in an ammonia separator to produce a liquid ammonia stream and a top gas stream comprised predominately of hydrogen and nitrogen; removing additional ammonia from the top gas stream using a front-end purification system to form a purified top gas stream; further cooling the purified top gas stream to a second temperature that is sufficient for condensing at least a portion of the nitrogen within the top gas stream to form a dual-phase stream, wherein the second temperature is colder than the first temperature; introducing the dual-phase stream to a cryogenic hydrogen separator under conditions effective for separating hydrogen and nitrogen, thereby creating a liquid nitrogen stream and a hydrogen top gas; warming and vaporizing the liquid nitrogen stream to produce a gaseous nitrogen stream; warming the hydrogen top gas to produce a gaseous hydrogen product stream; and recycling the liquid ammonia stream produced by the ammonia separator to a point upstream the ammonia cracker.
Resumen de: EP4570743A1
A method for producing hydrogen using a feed stream comprising ammonia is provided. The method may include the steps of: cracking a gaseous ammonia feed comprising ammonia and at least 0.15% water vapor in an ammonia cracker to produce a cracked gas stream comprising hydrogen, nitrogen, unreacted ammonia, and water vapor; cooling the cracked gas stream to a separation temperature that is sufficient for condensing at least a portion of the unreacted ammonia and the water vapor to form a dual phase fluid; separating the dual phase fluid in a separator that is configured to produce an aqueous ammonia stream and a vapor stream, the vapor stream comprising predominantly of hydrogen and nitrogen; wherein the separation temperature is below 0°C.
Resumen de: EP4571906A1
The present invention relates to a hydrogen ion conductive multilayer composite membrane comprising one or more inner reinforced membrane comprising a porous PTFE layer impregnated with an ionomer composition and outer reinforced membranes positioned on both sides of the inner reinforced membrane, wherein the outer reinforced membranes comprise a porous PTFE layer impregnated with an ionomer composition.
Resumen de: EP4570960A1
Die Erfindung betrifft eine Elektrolysezelle (01) zur Elektrolyse von CO2 mit einer Kathodenseite (02) und einer Anodenseite (03). Dabei umfasst die Elektrolysezelle (01) eine Kathodenplatte (04), eine Gaskammer (06), eine Gasdiffusionsschicht (08), eine Katalysatorschicht (09), eine Wasserkammer (07) und eine Anodenplatte (05). Die Kontaktierung der Katalysatorschicht (09) wird durch die Verwendung mehrerer Strombrücken (10) optimiert. Hierzu sind diese (10) elektrisch leitend mit der Kathodenplatte (04) und der Katalysatorschicht (09) verbunden und durchdringen dabei die Gasdiffusionsschicht (08).
Resumen de: EP4570742A1
A method for producing hydrogen comprises a) performing water electrolysis to produce oxygen and a first hydrogen product stream; b) reforming a hydrocarbon stream with oxygen to produce a reformed stream containing CO<sub>x</sub> and hydrogen; c) optionally, subjecting said reformed stream to a water gas shift process to produce a shifted product stream containing additional hydrogen and carbon dioxide; and separating hydrogen from the shifted product stream to produce a second hydrogen product stream; and d) directing oxygen produced in step a), optionally after buffering, to step b). The method allows for producing constant, continuous and uninterrupted amounts of emission-free hydrogen accomodating external influences such as fluctuations with weather conditions, day-night cycles and seasons. Said process can be run continuously and is not reliant on only one energy source which might be fluctuating.
Resumen de: EP4570950A1
The present invention relates to an electrolyzer designed for the generation of hydrogen and oxygen through water electrolysis. The electrolyzer comprises a housing structure accommodating at least one electrolytic cell, which includes an anode, a cathode, and an ion-conducting membrane. A water inlet is provided to introduce water into the electrolytic cell, and an electrical power source is operatively connected to the anode and cathode to facilitate the electrolysis process. The electrolyzer also includes separate outlets for the efficient extraction of hydrogen and oxygen generated during electrolysis. A multi-parameter optical measurement system is integrated within the electrolyzer. This system features at least one optical fiber with multiple sensing points distributed along its length, each capable of detecting various operational parameters within the electrolyzer.
Resumen de: EP4570949A1
A hydrogen gas generation system comprises a reactor chamber, an elongate cathode, an ammonia inlet, a hydrogen gas outlet, and a collection outlet. The reactor chamber has an input end and an output end. A wall of the reactor chamber between the input end and the output end is an anode. The elongate cathode extends between the input end and the output end through an interior of the reactor chamber. The ammonia inlet is positioned to introduce a liquid ammonia into the reactor chamber such that the liquid ammonia flows in a direction from the input end to the output end. The hydrogen gas outlet at the output end, wherein a hydrogen gas generated in the reactor chamber exits the reactor chamber through the hydrogen gas outlet. The collection outlet is at the output end. Nitrogenous compounds exit the reactor chamber through the collection outlet.
Resumen de: WO2024184065A1
An offshore hydrogen production platform (100) is described comprising a support structure (101) and plurality of vertically spaced decks (110, 111, 112) arranged to be supported by the support structure (101). The plurality of vertically spaced decks (110,111, 112) comprise an uppermost deck (110), and wherein the uppermost deck (110) comprises a hydrogen production equipment (130). The offshore hydrogen production platform (100) further comprises an enclosure (113) arranged to encapsulate the hydrogen production equipment (130). Also described is a method of producing hydrogen using hydrogen production equipment (130) located on a uppermost deck (110) of an offshore hydrogen platform (100).
Resumen de: CN119677896A
In one embodiment, discussed herein is a method of producing hydrogen, the method comprising: (a) providing an electrochemical reactor having an anode, a cathode, and a membrane between the anode and the cathode, where the membrane is both electronically and ionically conductive; (b) introducing a first stream to the anode, wherein the first stream comprises ammonia; (c) introducing an oxidizing agent to the anode; and (d) introducing a second stream to the cathode, wherein the second stream comprises water and provides a reducing environment to the cathode; wherein the hydrogen is generated from water in an electrochemical manner; wherein the first stream and the second stream are separated by the membrane; and wherein the oxidant and the second stream are separated by the membrane.
Resumen de: EP4570955A1
The cell (26) comprises a cell casing (34) defining an anodic compartment (36) and a cathodic compartment (38), the anodic compartment (36) comprising an anode chamber (50) and the cathodic compartment (38) comprising a cathode chamber (58), the cell casing (34) comprising a membrane (40) separating the anode chamber (50) from the cathode chamber (58).The anodic compartment (36) defines, within the cell casing (34), an anodic degassing cavity (52) located on top of the anode chamber (50), the cathodic compartment (38) defining, within the cell casing (34), an cathodic degassing cavity (60) located on top of the cathode chamber (58). The cell casing (34) comprises a partition wall (42) tightly separating the anodic degassing cavity (52) from the cathodic degassing cavity (60).
Resumen de: EP4570954A1
The invention relates to a coated diaphragm (16) of an electrochemical device (8) for alkaline electrolysis. The diaphragm (16) comprises an alkaline membrane (18) coated on at least one side with a catalyst layer (20). The catalyst layer (20) is obtained by deposition of at least one metallic catalyst on the membrane (18) by physical vapor deposition, the metallic catalyst being chosen between Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zr, Nb, Mo, Hf, Ta, W and any combination thereof.
Resumen de: KR20250089313A
본 발명의 예시적인 실시예들에 따르면, 암모니아 분해용 촉매가 제공된다. 상기 암모니아 분해용 촉매는 세라믹 담지체; 및 상기 세라믹 담지체 상에 담지된 복합체로서, 상기 세라믹 담지체 상에 위치한 제1 산화물과, 상기 제1 산화물의 표면에 용출된 활성 금속 입자를 포함하는 복합체를 포함한다. 또한, 본 발명의 다른 예시적인 실시예들에 따르면, 암모니아 분해용 촉매를 제조하는 방법이 제공된다.
Resumen de: CN119907871A
An electrolytic cell (1) for producing hydrogen, comprising a stack of bipolar electrodes (9) that sandwich an ion transport membrane (2) between every two of the bipolar electrodes. Each bipolar electrode comprises two metal plates (9A, 9B) welded together back to back, forming a coolant compartment between them and having a respective anode surface and an opposite cathode surface, each metal plate abutting one of the membranes. The plates (9A, 9B) are embossed with primary vertical channels (10A, 10B) and secondary channels (11A, 11B) in a herringbone pattern for conveying oxygen and hydrogen. Embossed herringbone patterns are provided on both sides of the metal plates (9A, 9B) so as to also provide herringbone-pattern coolant channels (11B) within the coolant compartments.
Resumen de: EP4570949A1
A hydrogen gas generation system comprises a reactor chamber, an elongate cathode, an ammonia inlet, a hydrogen gas outlet, and a collection outlet. The reactor chamber has an input end and an output end. A wall of the reactor chamber between the input end and the output end is an anode. The elongate cathode extends between the input end and the output end through an interior of the reactor chamber. The ammonia inlet is positioned to introduce a liquid ammonia into the reactor chamber such that the liquid ammonia flows in a direction from the input end to the output end. The hydrogen gas outlet at the output end, wherein a hydrogen gas generated in the reactor chamber exits the reactor chamber through the hydrogen gas outlet. The collection outlet is at the output end. Nitrogenous compounds exit the reactor chamber through the collection outlet.
Resumen de: KR20250088138A
비스디아지린을 포함하는 광가교제, 그를 이용한 광촉매 개질 및 수소생산장치가 개시된다. 본 발명은 구조식 1로 표시되는 화합물이 개시된다. 구조식 1 에서, Z가 산소원자이면 Y는 원자가 결합이거나, 또는 Z가 탄소원자이면 Y는 산소원자이고, R1은 C1 내지 C6의 알킬렌기이고, Ar1 및 Ar2는 각각 C1 내지 C5의 알킬기가 치환 또는 비치환된 C6 내지 C20의 아릴렌기이고, X1 및 X2는 각각 불소원자, 염소원자, 브롬원자 또는 요오드 원자이고, n은 1 내지 100의 정수이다. 본 발명은 비스디아지린 광가교제의 글라이콜 개질을 통하여 비스디아지린 광가교제의 친수성 성질을 강화할 수 있는 효과가 있다.
Resumen de: CN119032199A
A hydrocarbon feed stream is exposed to heat (pyrolysis) in the absence of oxygen to convert the hydrocarbon feed stream into a solid stream and a gaseous stream. The solid stream comprises carbon. The gas stream comprises hydrogen. The gas stream is separated into an off-gas stream and a first hydrogen stream. The first hydrogen stream comprises at least a portion of the hydrogen in the gas stream. The carbon is separated from the solids stream to produce a carbon stream. The water stream is electrolyzed to produce an oxygen stream and a second hydrogen stream. At least a portion of the oxygen in the oxygen stream and at least a portion of the carbon in the carbon stream are combined to produce electrical energy and a carbon dioxide stream. At least a portion of the generated electrical energy is used to electrolyze the water stream.
Resumen de: CN119156365A
A process for manufacturing methanol having a deuterium content of less than 90 ppm based on the total hydrogen content, the process comprising the steps of: (a) providing hydrogen having a deuterium content of less than 90 ppm based on the total hydrogen content by water electrolysis using power generated at least in part from non-fossil renewable resources; (b) providing carbon dioxide; (c) reacting hydrogen and carbon dioxide in the presence of a catalyst to form methanol.
Resumen de: CN119278297A
The invention relates to a gas-permeable electron-conducting plate for use as a porous transport layer for an electrolytic cell and to a method for producing said gas-permeable electron-conducting plate, to a building unit for an electrolytic cell, and to an electrolytic cell.
Resumen de: JP2025090210A
【課題】より省電力で、水素を製造できる水素製造装置を提供すること。【解決手段】水素製造装置1は、アンモニアを貯留するアンモニアタンク2と、アンモニアタンク2から供給されるアンモニアを、窒素および水素に分解するプラズマリアクタ3と、プラズマリアクタ3から供給される、未分解のアンモニア、窒素および水素の混合物から、未分解のアンモニアおよび窒素と水素とを分離する第1分離膜5と、第1分離膜5により分離された未分解のアンモニアおよび窒素の混合物から、未分解のアンモニアおよび窒素を分離する第2分離膜6と、第2分離膜6により分離された未分解のアンモニアを、プラズマリアクタ3に供給するためのアンモニア戻りライン14とを備える。【選択図】図1
Resumen de: DK202330354A1
A method and system for operating a solid oxide cell (SOC) unit, the method comprising the steps of: i) providing a power supply unit (PSU) comprising a rectifier and converting an AC-current to a DC-current; ii) providing a solid oxide cell (SOC) unit comprising one or more SOC stacks, supplying steam to the one or more SOC stacks and serially connecting said one or more SOC stacks to said rectifier by providing said DC-current to the one or more SOC stacks, thereby powering the one or more SOC stacks for operation in electrolysis cell mode; and outputting hydrogen from said one or more SOC stacks; iii) interrupting said DC-current to the one or more of the SOC stacks, optionally interrupting said supply of steam to the one or more SOC stacks, and supplying a fuel source to the one or more SOC stacks, thereby switching the one or more SOC stacks from operation in electrolysis cell mode to operation in fuel cell mode; and outputting a DC-current from said one or more SOC stacks; iv) providing an electric heater and serially connecting said electric heater to said one or more SOC stacks operating in fuel cell mode, by directly providing said DC-current from said one or more SOC stacks to the electric heater. The invention provides also a system for carrying out the method.
Resumen de: AU2023376448A1
Provided is a positive electrode for electrolysis, which is unlikely to deteriorate in electrolysis performance even in cases where a power with large output fluctuation such as renewable energy is used as a power source, and in which excellent catalytic activity is maintained for a long period of time. A positive electrode 10 for electrolysis comprises: a conductive substrate 2 at least a surface of which is made of nickel or a nickel-based alloy; and a first layer 4 which is formed on the surface of the conductive substrate 2 and can function as a catalyst layer composed of a lithium-containing nickel cobalt oxide represented by a composition formula of Li
Resumen de: KR20250087871A
본 발명은 광전기화학 수전해 반응 시 희생제를 쓰지 않고도 높은 효율로 수소를 생산하는 넓은 광흡수 영역을 가지는 친환경 광전기화학 수전해 촉매 및 이의 제조방법에 관한 것이다.
Resumen de: CN120158774A
本公开阳极催化剂材料技术领域,具体涉及一种阴离子交换膜水电解阳极催化剂材料及制备方法,所述阴离子交换膜水电解阳极催化剂材料的制备方法,包括以下步骤:步骤一:将铁源、镍源与双模板剂混合,得到混合溶液;步骤二:向步骤一的混合溶液中加入沉淀剂进行共沉淀反应,控制反应体系的pH值为8‑12,反应温度为60‑100℃,反应时间为6‑24小时,得到共沉淀产物;步骤三:将所述共沉淀产物在空气或氧气气氛中煅烧处理,以1‑10℃/分钟的升温速率升温至500‑600℃,保温2‑5小时,冷却至室温后得到阳极催化剂材料。上述技术方案在兼顾高催化活性、优良的传质性能以及高比表面积方面达到了平衡。
Resumen de: CN120158779A
本发明提供一种具有优良成膜性的交联型苯并噁嗪水电解用质子交换膜及其制备方法与应用。本发明质子交换膜的制备方法包括步骤:苯并噁嗪齐聚物溶于溶剂中,加入异氰酸酯类化合物,混合均匀,成膜得到交联型苯并噁嗪水电解用质子交换膜。本发明质子交换膜具有良好的成膜性、韧性和机械强度,质子导电率高,成本低;应用于质子交换膜水电解表现出优异的性能,具有巨大的应用前景。
Resumen de: CN120155230A
本发明涉及光催化剂技术领域,且公开了一种钨和金修饰g‑C3N4制氢复合催化剂及其制备方法和应用。本发明所述催化剂为钨和金以及聚合物半导体的复合材料,由超薄g‑C3N4纳米片、高度分散的W单原子和Au纳米团簇组成。本发明还公开了制备所述催化剂的方法,具体包括:步骤一:制备黄色g‑C3N4块体;步骤二:制备白色g‑C3N4薄片;步骤三:混合CN和Na2WO4原材料;步骤四:制备负载有W单原子的g‑C3N4薄片;步骤五:混合g‑C3N4薄片和HAuCl4;步骤六:制备负载有Au纳米团簇和W单原子的g‑C3N4薄片。本发明还公开了将所述催化剂应用于光催化水分解制氢的方法。本发明系统解决g‑C3N4基光催化剂存在的活性位点密度低、光生载流子分离效率差及光谱响应范围窄等共性难题,实现高效光催化水分解制氢。
Resumen de: CN120158770A
本发明涉及催化剂技术领域,特别是涉及一种氟掺杂氧化铱催化剂及其制备方法和应用。将氮化碳前体焙烧,得到氮化碳载体,将所述氮化碳载体分散于水中,得到氮化碳载体分散液;将氮化碳载体分散液与铱盐溶液、氟源混合,干燥后得到催化剂前驱体;将催化剂前驱体煅烧,得到氟掺杂氧化铱催化剂。催化剂的颗粒尺寸小、原子利用率高;氟原子的掺杂可以优化反应过程中质子脱附步骤,加快酸性氧析出OER反应动力学,实现本征活性提升。本发明制备的氟掺杂二氧化铱催化剂在OER反应中具有优异的反应活性。
Resumen de: CN120155192A
本发明提供一种钴包覆硫化镉光催化产氢材料及其制备方法和应用,涉及光催化材料技术领域,钴包覆硫化镉光催化产氢材料的制备方法,具体包括如下步骤:S1、以硫代乙酰胺、乙酸镉二水合物为原料,采用溶剂热法制得CdS纳米颗粒;S2、以乙酸钴四水合物和步骤S1制得的CdS纳米颗粒为原料,采用离子吸附方法制得钴包覆硫化镉光催化产氢材料。与现有技术相比,本发明提供一种钴包覆硫化镉光催化产氢材料及其制备方法和应用,有效抑制了硫化镉在光照条件下的自氧化过程,减少了硫离子的溶出,显著提高了材料的光化学稳定性,延长了其使用寿命。
Resumen de: CN120158766A
本发明公开了一种二氧化钼负载铂催化剂的制备方法及其应用,属于纳米催化剂技术领域,制备方法:将乙酰丙酮铂和乙酰丙酮钼溶解在有机溶剂中,滴涂在碳纸上并加热,将所得负载前驱体样品的碳纸固定在焦耳加热装置中完成快速碳热冲击反应制得。本发明可有效分散金属铂,以暴露更多的反应活性位点,同时利用金属铂与二氧化钼载体之间的相互作用,降低金属铂对氢的吸附能力,增强催化体系活性和稳定性,提升电解水制氢催化活性,并显著降低金属铂的使用量。
Resumen de: CN120155131A
一种氨制氢技术领域的高效的自热型氨分解制氢反应器,包括燃烧尾气出口、保温层壳体、反应层壳体、螺旋折流板、燃烧室壳体、螺旋助燃气管、保温层、反应层、燃烧室、斜向开口、氨分解入口、氨燃烧入口、助燃气入口、分解气出口、挡板座、尾气连通口、分解气汇集管、分解气汇集室,反应层壳体嵌套于保温层壳体内,两者之间形成保温层,燃烧室壳体嵌套于反应层壳体内,两者之间形成反应层。本发明采用氨为主要燃料,用氢作为引燃料,氨氢在燃烧室中掺混燃烧为氨分解反应提供热量,从而实现自热式的氨分解制氢。本发明采用了三层嵌套式的结构,具有结构紧凑、能量利用率高等优点。
Resumen de: CN120158775A
本申请涉及催化材料技术领域,特别是涉及一种Ni/Fe3O4复合材料、电极及其制备方法、碱性电解槽及电解水制氢的方法。Ni/Fe3O4复合材料包括二次颗粒,二次颗粒包括堆积的一次颗粒,一次颗粒包括内核和设于内核表面的外壳,内核包括四氧化三铁,外壳包括镍单质。该Ni/Fe3O4复合材料以四氧化三铁为内核,在内核的表面包覆镍单质外壳,使该Ni/Fe3O4复合材料的导电性能较好;将其作为催化材料制备碱性电解槽中的电极,并用于电解水制氢,可降低水电解反应的活化能,从而降低水电解反应的过电位,进而提升制氢效率,且无需升高电解槽运行温度,可降低能耗,以及基本不会破坏隔膜以及不腐蚀槽体。
Resumen de: CN120158755A
本发明公开了一种制备萘醌衍生物并产氢气的方法和电解池,属于储能技术领域。所述电解池包括端板I、集流体I(正极)、电极装置、集流体II(负极)和端板II依次固定叠合;电极装置包括正极单元、膜电极和负极单元依次叠合;正极单元内设有正电极和正极电解液;负极单元内设有负电极且不设置负极电解液;膜电极包括质子交换膜、催化剂层和气体扩散层;质子交换膜的第一面和正极单元接触,质子交换膜的第二面上设有催化剂层,催化剂层和气体扩散层叠合,气体扩散层和所述负极单元接触。本发明方法将有机活性分子电化学氧化与产氢耦合,可更加快速且便捷地获得大量的有机活性分子和高纯氢气。
Resumen de: CN120161007A
本发明涉及电化学测试相关技术领域,且公开了一种电催化析氢性能测试装置,包括反应箱体,反应箱体的侧面设置有检测箱体,反应箱体和检测箱体之间固定连接有连接管,检测箱体的内壁上转动连接有齿轮,齿轮上固定连接有光线发射器,齿轮的底部啮合连接有齿条,齿条的侧面上固定连接有一号弹簧阻尼装置,检测箱体的顶部内壁上固定连接有检测板,检测板内部设置有红外检测板和光线接收装置,连接管包括装置外壳,装置外壳上开设有通气孔,装置外壳的内侧面上开设有通气槽;氢气在检测箱体中推动齿条运动,改变了齿轮上光线发射器照射角度,利用红外检测板检测氢气浓度,光线接收装置检测气体生成量,达到检测装置析氢性能的目的。
Resumen de: CN120155197A
本发明涉及光催化析氢领域一种富硫空位多孔二硫化钼与硫化锌镉构建Ⅱ型异质结光催化剂的制备及其应用。本发明的目的是提供一种制备工艺简便、成本低廉且具有高效光催化析氢性能的Ⅱ型异质结光催化剂,以提升光催化析氢效率,缓解当前能源危机下对清洁能源的迫切需求。所采用的方法:以二氧化硅为模板,通过氢氟酸的刻蚀作用,生成富硫空位多孔二硫化钼,将其与醋酸锌、氯化镉、硫脲和聚乙烯吡咯烷酮一同作为原料,采用水热合成方法,制备的一种富硫空位多孔二硫化钼与硫化锌镉构建Ⅱ型异质结光催化剂可适用于光催化析氢领域且具有较高的催化活性和稳定性。
Resumen de: CN120157927A
本发明属于新材料技术领域,涉及以聚砜树脂为粘结剂的层状双氢氧化物膜,所述的层状双氢氧化物膜是以聚砜树脂为粘结剂将层状双氢氧化物颗粒或层状双氢氧化物纳米片连接成连续薄膜得到的。还涉及一种以聚砜树脂为粘结剂的层状双氢氧化物膜制备方法及应用。本发明层状双氢氧化物膜采用具有阴离子导电性的LDH为主体,其可以在碱溶液中表现出明显低于商品Zirfon膜的面电阻,因此本发明隔膜用于水电解时,可以表现出更高的电解效率。本发明的成膜方法是基于化工分离领域分离膜制备中常用的相转化原理,故其规模化制备便于以分离膜相转化制备的成熟工业设备为基础通过工艺参数改变而达成,易于实现批量化制备。
Resumen de: CN120158754A
本发明属于电解槽技术领域,尤其涉及一种阴阳极网改进型电解槽;所述阴阳极网改进型电解槽包括:框架,在框架两侧分别对称安装有阳极网以及阴极网,所述阴极网包括多个排列分布安装的极网筋片,极网筋片表面开设有定位孔;同时所述极网筋片一侧上下分布开设有多个矩形槽,矩形槽内部放置有极网筋条柱;所述框架、阳极网以及阴极网之间形成阳极室以及阴极室;所述的阴阳极网改进型电解槽在极网筋片一侧开设矩形槽,便于快速对位校准放置极网筋条柱,使得整个阴极网组装效率高效,且由于极网筋条柱横截面积更小,再加上横置稳定放置在矩形槽内部,在受到流动的电解液产生的冲击力时,波动幅度较小,不容易使整个阴阳极网产生较大的波动。
Resumen de: CN120157186A
本发明公开了一种钼酸铁电催化剂的制备方法及其在析氧反应中的应用,制备方法包括以下步骤:(1)将铁源、钼源、镍盐和硫脲分别溶于溶剂中,然后混合在一起混合均匀得到混合溶液;(2)将混合溶液进行水热反应,反应结束后,洗涤,干燥,获得所述钼酸铁电催化剂。本发明采用一步水热的方法,制备方法简单有效,制备成本较低,设计合理,并且镍的掺入调节了Fe和Mo的d带中心位置,优化了反应中间体的吸附能,降低反应能垒,合适的d带中心使催化剂表面更易吸附反应物,同时利于产物的脱附,从而加速OER动力学,提升了OER性能,实现了催化剂高催化活性和高稳定性。
Resumen de: CN120161101A
本发明公开了一种AEM水电解膜电极失效诊断方法。本发明包括:在AEM水电解膜电极正常运行时输入不同交流振幅的载波,进行载波分析,确定交流振幅大小,得到正常状态下电化学交流阻抗和总谐波失真的标准谱图;监测AEM水电解膜电极运行,发生性能变化后进入诊断模式,输入载波,进行电化学交流阻抗测试的同时进行总谐波失真测试,对输出的电化学交流阻抗信号进行傅里叶变换处理,得到电化学交流阻抗谱;对输出的谐波信号进行处理,得到总谐波失真谱;根据总谐波失真谱,结合电化学交流阻抗谱,与步骤一得到的标准谱图比较,识别AEM水电解膜电极失效类型。本发明能有效诊断AEM水电解膜电极发生温度变化、电解液计量变化以及阴阳极压力变化的失效模式。
Resumen de: CN120158760A
本申请实施例提供一种用于制氢储氢系统的控制方法、装置及存储介质。方法包括:实时获取电解槽的工作电流和电解槽的阴极侧所产生的氢气流经充氢管路时的实时压力;根据工作电流和实时压力确定电解槽的阴极侧所产生的实时水量;根据实时压力和实时水量对制氢储氢系统进行充氢排水控制,实现间歇式排水和高压充氢,有效地提高排水操作的压力并使得单次充氢压力更稳定,缩短单次排水的时间和单次充氢时间,降低氢气的泄漏量,有效提升充氢效率。
Resumen de: CN120158776A
本申请公开了一种ZIF‑L衍生的碱性电解水析氧催化剂及其制备方法与应用,涉及新能源电解水催化技术领域,该方法包括:将钴盐溶液与2‑甲基咪唑溶液混合得到紫色混合溶液;在紫色混合溶液中放入泡沫镍进行陈化,得到钴基金属有机框架ZIF‑L@NF;将钴基金属有机框架加入硼氢化钠溶液中进行冰水浴,得到硼掺杂的钴基金属有机框架B‑ZIF‑L@NF;将B‑ZIF‑L@NF在惰性气氛中进行低温退火,得到碱性电解水析氧催化剂B‑ZIF‑L‑X@NF。解决了现有技术中电解水的催化剂存在活性位点被掩蔽,催化效率低的问题。实现了改变过渡金属中心的电子云分布,优化其局域电子结构,促进高价活性位点的生成,进而提高催化效率。
Resumen de: CN120157158A
本发明属于电解海水制氢技术领域,公开了一种通过化学刻蚀阳极催化剂提高电解海水性能的通用方法。针对现有技术中阳极催化剂选择性差,催化活性不足等问题,本发明提出采用化学刻蚀工艺对非贵金属基催化剂进行改性。刻蚀后催化剂表面形成多孔粗糙结构,比表面积显著增大,暴露出丰富的活性位点,有效降低析氧反应能垒。实验表明,改性后的催化剂在模拟海水中电解性能显著提升,10mA cm‑3电流密度下过电位提升了70mV。该方法工艺简便、成本低、普适性强,可适配多种非贵金属催化剂体系,为高效、低成本电解海水制氢技术的规模化应用提供了创新解决方案。
Resumen de: CN120158756A
本发明公开了一种方形带压碱性电解槽,涉及电解水制氢技术领域,包括:固定连接的左端板、电解槽主体和右端板;电解槽主体包括若干个堆叠的电解小室;电解小室包括:方形双极板,方形双极板设置有安装工艺孔和供碱液循环的进出口,方形双极板的两侧分别设置有凹槽,凹槽中固定有金属支撑网,方形双极板的两侧金属支撑网分别固定有阴极电极和阳极电极,阴极电极和阳极电极之间设置有隔膜。本申请通过设置金属支撑网,增大了方形双极板与电极之间的有效接触面积,减小了电解槽的欧姆阻抗,进而提高了制氢效率;金属支撑网还使得流场分布更加均匀,有效改善了气体在电解槽内部的积聚现象,提高了运行稳定性。
Resumen de: CN120163278A
本发明涉及一种PEM电解水制氢多槽混联优化方法吗,包括以下步骤:S1、获取光伏发电的数据,并进行数据预处理;S2、采用K‑means聚类算法将光伏发电白天数据根据天气模式分为晴天和非晴天,计算不同天气的平均功率;S3、构建调度策略;S4、采用改进粒子群优化PSO算法进行全局搜索和优化,找到最优的PEM调度策略;S5、记录每个PEM电解槽运行时间以及状态切换次数,并评估生成的PEM调度策略;本发明通过K‑means聚类算法将天气对光伏发电的影响与PEM电解槽分配调度相结合,设计最优耦合控制策略,多目标优化和运行时间管理,显著减少PEM电解槽的切换次数,降低设备磨损和维护成本,提高PEM电解水制氢的效率。
Resumen de: CN120158768A
本发明提供了一种Cdot@Ni2P复合电催化产氢材料及其制备方法。本发明首先将碳量子点与氯化镍充分复合,随后通过次磷酸钠与复合物焙烧得到Cdot@Ni2P复合电催化产氢材料。本发明相比现有技术最大的特点在于:应用于电催化产氢领域的新型催化剂,制备工艺简单、高效,制得的Cdot@Ni2P复合电催化产氢材料性能良好、晶体结构完善,且具有较高的催化产氢性能和优异的循环使用性能,易回收再利用。
Resumen de: CN120158762A
本发明涉及电化学能源转化领域,公开一种负载钌团簇的氮掺杂碳基复合催化材料及其制备方法和应用。包括步骤:步骤1,以吡咯和对甲苯磺酸钠的混合水溶液为电解液,导电碳基底材料为工作电极,采用恒电位沉积方法在聚吡咯负载于导电基底碳材料上,得含氮碳材料;步骤2,将所述含氮碳材料浸渍于钌前驱体溶液,取出干燥后煅烧,再经酸洗、干燥得到所述负载钌团簇的氮掺杂碳基复合催化材料。本发明的负载钌团簇的氮掺杂碳基复合催化材料具有突起状波浪形貌,钌团簇锚定于材料表面等优点,展现出优异的电催化析氧反应性能,可作为质子交换膜电解水的析氧阳极材料。
Resumen de: US2025186304A1
A hydrogen generation device includes a tubular tank and a top lid combined with the tank. An immersion tube in which a hydrogen generating agent package is stuffed is placed in the tank. The hydrogen generating agent package is submerged in water after water is poured in the tank to generate hydrogen, which is released through a tank opening of the tank. The hydrogen generating agent package accommodates hydrogen generating agent powders including calcium oxide and aluminum powders, both of which are mixed and wrapped with a nonwoven fabric, as well as a little catalytic sodium carbonate added inside. For inhibition of free radicals and promotion of metabolism, the hydrogen generation device is further provided with a connector and a hose for a skin-care instrument, a nasal mask, an eye shield or an ear cleaner through which hydrogen is supplied as required.
Resumen de: AU2023359480A1
The invention relates to a bipolar plate for an electrolytic cell, the plate comprising, on at least one of its main faces: a first zone running circumferentially; a second zone running circumferentially so as to be bordered on the outside by the first zone; a third zone running circumferentially so as to be bordered on the outside by the second zone, the various zones being arranged on the periphery of the associated main face. The invention also relates to the corresponding cell, electrolyzer cell and assembly method.
Resumen de: AU2023359478A1
The invention relates to a method for joining a stack of elements together, the method comprising the steps of: individually joining subassemblies of the elements together; joining the subassemblies together by arranging a joint between each subassembly to form the stack of elements; applying consecutive phases of heating and cooling to the stack of elements while applying at least one clamping action to the stack of elements between two different phases of heating and cooling.
Resumen de: EP4566988A1
The invention relates to a process for the production of hydrogen gas (4) from ammonia, thereby obtaining an effluent gas (6) comprising hydrogen gas (4). Said process comprising the following steps:- providing an ammonia feedstock stream (8);- performing at least one electrical heating and conversion step, said step comprising:heating in at least one electric heater (12) the ammonia feedstock stream (8) so as to produce a heated gas stream (14); andperforming in at least one adiabatic reactor (16) an endothermic cracking reaction of the heated gas stream (14), said adiabatic reactor (16) comprising at least one catalyst bed (18) performing said endothermic cracking reaction of the ammonia feedstock stream (8) into said effluent gas (6).
Resumen de: KR20250087120A
본 발명은 금 원자 이온으로 산소 결함이 채워진 금/산화아연 접합구조체의 광촉매에 관한 것으로, 본 발명에 따른 산소 결함이 발생한 산화아연 광촉매(VO-ZnO)의 산소 결함 자리에 금 나노입자가 광증착된 광촉매(Au/VO-Au:ZnO)는 자외선 뿐만 아니라 가시광선 조사 하에서도 광촉매 효율이 현저히 향상되는 효과가 있다.
Resumen de: US2025188631A1
An embodiment water electrolysis catalyst includes iridium oxide including a rutile phase and iridium-nickel oxide including a hexagonal phase. An embodiment method of preparing a water electrolysis catalyst includes preparing a mixture including an iridium precursor, a nickel precursor, and cysteamine hydrochloride, drying the mixture, grinding the dried mixture, and firing a ground product, wherein the water electrolysis catalyst includes iridium oxide including a rutile phase and iridium-nickel oxide including a hexagonal phase.
Resumen de: CN119497764A
The present invention relates to a method for operating a high temperature solid oxide electrolysis system suitable for converting a fuel stream into a product stream and a system for implementing the method. The method includes drying the moist purge gas and using the waste purge gas as a regeneration gas in the drying unit.
Resumen de: CN120138702A
本发明涉及电解水催化剂技术领域,公开了一种催化材料及其制备方法、电解水析氢催化电极和电解水析氢的方法,所述催化材料包括载体以及负载在载体上的活性金属组分;其中,所述载体为含有S空位的过渡金属硫化物,且至少部分所述过渡金属硫化物为1T相;所述活性金属组分选自VIII族金属和IB族金属中的至少一种。所述催化材料具有优异的HER催化性能,催化稳定性好。
Resumen de: CN120138703A
本发明属于催化剂制备技术领域,涉及清洁能源的高效制备,具体涉及利用稀土元素形成的二元合金催化剂作用于乙醇辅助下的节能制氢体系。本发明采用湿化学合成法,将钯与镧的金属前驱体以及六羰基钼与正辛酸溶剂均匀混合,油浴反应一段时间后,分离沉淀并依次洗涤、干燥,即可获得二元合金催化剂。随后我们在H型电解槽中探究了乙醇对传统电解水制氢体系的改善和促进作用,证明了乙醇辅助制氢为高效节能的制氢方式。本发明所述的催化剂制备方法简单,步骤少,操作简便。相比于Pd金属烯催化剂和商业Pd黑有着更为优异的催化活性和稳定性。所述的制氢方式更为高效,极大降低了能耗。
Resumen de: CN120138674A
本发明提供了一种碱性电解水用多腔室透明电解槽,涉及电解槽领域,采用的方案是:包括:阳极端板组件,所述阳极端板组件包括阳极端板和阳极导电环,所述阳极端板采用透明且不导电材料;阴极端板组件,所述阴极端板组件包括阴极端板和阴极导电环,所述阴极端板采用透明且不导电材料,所述阴极端板与所述阳极端板之间贯穿有对拉螺栓;复合极板,所述复合极板设置在相邻的两个所述电解室之间,所述复合极板包括阳极极框和阴极极框,所述阳极极框和所述阴极极框采用透明且不导电材料,所述阳极极框和所述阴极极框之间设置有导电板。本发明能够从端部和外周部分直观看到内部流场和电极的变化情况。
Resumen de: CN120138690A
本发明公开一种A位高熵化设计的电解水阳极催化剂及其制备方法,属于电解水催化剂制备技术领域。所述催化剂的化学式为(La0.25Sm0.25Eu0.25Ce0.25)NiO3。制备过程为按照设计的化学计量比分别称量La2O3、Sm2O3、Eu2O3、CeO2、Ni2O3粉末,采用湿法球磨、搅拌、造粒、高温烧结、过筛、等离子喷涂,制备得到的催化剂具有过电位低和稳定性好等优势,有望广泛应用在电解水制氢气的阳极催化剂材料。
Resumen de: CN120138697A
本发明公开了一种钌掺杂的钴金属氧化物纳米片电催化剂及其制备方法和应用,涉及电催化剂技术领域,制备方法为:称取钴盐和均苯三甲酸共同溶解在甲醇溶液中,经过一次超声混合处理后得到混合液A;将含钌盐的甲醇溶液滴入混合液A中,经过二次超声混合处理后得到混合液B,将混合液B经过水热反应后得到钌钴金属有机骨架前驱体;将钌钴金属有机骨架前驱体经过煅烧处理。与现有技术相比,本发明制备的钌掺杂的钴金属氧化物纳米片电催化剂在碱性电解水反应中展现出优异的析氢电催化活性和稳定性,该催化剂的性能优于商业铂碳催化剂,且能够在100小时的持续测试中保持稳定的电位输出,无明显衰减。
Resumen de: CN120138706A
本发明属于电催化技术领域,具体涉及一种含有界面暴露CrOx团簇助催化剂的光电极及其制备方法和应用。通过简单的滴涂法和碱刻蚀方法制备了具有EJI结构的CrOx团簇作为高效助催化剂,这极大的简便了新型助催化剂(团簇、基团、量子点)的制备方法。本发明将电催化剂中界面暴露的结构应用在OEC当中,使OEC的催化活性进一步提升,从而提高了光阳极的性能。In2S3中In原子原位引入到CrOx当中,调控了CrOx团簇界面电子状态,促进了光生空穴的转移,降低了表面过电势,提升了表面OER动力学过程。
Resumen de: CN120132723A
本发明公开了一种硼氢化物多相流动制氢反应器及方法,反应器包括壳体,壳体底端设置有排放管道,排放管道两侧设置有碱性硼氢化物溶液入口,壳体内设置有装有催化剂颗粒的反应管束,反应管束上方设置有百叶窗分离器,壳体上部设置有取样口通道和溶液排出管道,反应管束连接有冷却水管道。与传统的制氢反应器相比,该多相流动制氢反应器可以更加高效稳定,通过控制冷却水的温度来控制反应器温度,使产氢速率可控性更强。利用泡沫截断器来减少氢气泡的形成程度,再经过分离器达到气液分离效果,以获得更加纯净的氢气。
Resumen de: CN120138657A
本发明公开了一种碱性水电解制氢系统、气液分离装置及其应用,该装置包括:分离塔和自下而上依次设置于分离塔内部的气液分离分布器、洗涤载体、洗涤水分布器、除沫滤网和冷却器;分离塔的下部开设有流体入口和流体出口,分离塔的顶部设置有气体出口;气液分离分布器用于对导入至分离塔内的气液混合流体进行气液分离;从洗涤水分布器中喷出的洗涤水在洗涤载体表面分布,以使从气液分离分布器中分离出的气体中携带的液体与洗涤载体表面分布的洗涤水逆向接触并去除气体中携带的液体;除沫滤网用于清除气体中携带的液体;冷却器用于对气体和气体中携带的液体冷却,使得冷却后析出的液体在重力作用下回落至分离塔中,进而提高气液分离效率和分离纯度。
Resumen de: CN120138664A
本发明涉及一种便携式轻量化水电解制氧设备,包括:壳体,顶部设有横槽和放置槽;电解装置,安装在壳体内部,用于电解产生氧气;氧气管和氢气管,一端均与电解装置连接,另一端均贯穿壳体;气体纯化装置,与氧气管一端连接,用于对电解产生的氧气纯化处理;移动板,横向滑动设置在横槽内;活动板,竖向滑动设置在移动板一侧;放置板,安装在活动板顶部,与放置槽活动适配,内设有槽口,用于放置移动电源;定位组件,设在放置板底部,用于对移动电源进行限位固定。本发明提供的便携式轻量化水电解制氧设备通过转动杆、横移板和定位板等多个部件的配合实现了对移动电源的固定限位,保证了在充电状态下移动电源的稳定性。
Resumen de: CN120132760A
本发明公开了一种PEM电解水制氢用贵金属催化剂活化装置,涉及催化剂活化技术领域,包括活化加工罐,所述活化加工罐内顶壁的中心转动设置有转动轴,所述转动轴的底部设置有搅拌组件,所述活化加工罐的顶部固定安装有导流箱,所述转动轴的顶端贯穿活化加工罐并转动安装在导流箱内,所述转动轴上设置有多个叶片;本发明在加热贵金属催化剂的过程中会产生的水蒸气以及有机物烟气,此时烟气以及水蒸气会通过曲型管进入导流箱内,并推动叶片带动转动轴以及搅拌件转动,方便对大量贵金属催化剂颗粒进行搅拌,使得可均匀受热,此外,搅拌件的运动可由催化剂活化时产生的烟气作为动力源,不仅节省了电能,还可避免不必要的维护和维修成本。
Resumen de: CN120132750A
本发明公开了一种旋流振荡耦合超声压电制氢装置与方法,采用旋流超声耦合反应器进行压电催化制氢,将分散有压电催化剂和助催化剂的固液混合体系沿切向高速通入旋流超声耦合反应器内,通过旋流耦合超声进行压电催化制氢;本发明的旋流耦合超声的压电制氢方法,旋流耦合超声提供驱动力、强化传质及旋流脱气三个方面显著强化超声制氢的效率;超声振动棒在旋流超声耦合反应器内充当中心固棒的作用,在压电制氢反应过程中稳定流场、降低能耗;二者共同作用,实现了“1+1>2”的效果。
Resumen de: CN120143011A
本发明公开了一种检测PEM水电解不同失效情况的电化学谱学方法。本发明的检测方法包括:选取测试振幅;通过可提供非线性谱学分析的电化学工作站向PEM水电解制氢系统在恒电流模式下施加激励信号;对PEM水电解制氢系统进行稳态V‑I测试、电化学阻抗和总谐波失真测试;通过所述电化学工作站的信号采集单元采集响应信号,对响应信号进行分析,将信号从时域转换到频域,获得相应的检测谱图;将故障谱图与标准谱图分析对比,根据不同的PEM失效情况对应总谐波失真在不同频域范围内的不同变化,确定失效类型。本发明能有效地区分PEM水电解制氢系统发生氢氧串气、压力变化、温度变化、进液量变化时所造成的PEM失效。
Resumen de: CN120138686A
本发明属于光电化学水分解光电极材料制备技术领域,具体为一种改善氮化钽光阳极背接触的方法。该方法使用电化学抛光技术对铌箔基底进行处理,去除铌箔基底表面污染物和复杂的原生氧化膜的同时,提高了铌箔基底表面平整度,促进了氮化钽结晶过程,提升了在铌箔表基底面制备的氮化钽光阳极薄膜的质量;然后,将电化学抛光后的铌箔衬底进行高温氮化,让铌箔基底正面生成与氮化钽光阳极薄膜晶格匹配的NbNx晶相,为氮化钽光阳极薄膜的生长提供晶核位点,从而改善了氮化钽光阳极薄膜与铌箔基底的背接触增加了氮化钽薄膜结晶性,提高了氮化钽光阳极的水分解效率。与现有技术相比,本发明处理方式简单、成本低,且可以拓展应用在其他金属衬底上。
Resumen de: CN120138658A
本发明公开了一种具有铥掺杂的质子导体固体氧化物电解池氧电极的单电池及其制备方法与应用。本发明将Tm元素按一定量掺入Ba(ZrCoFe)O3,煅烧后得到BaZrxCoyFezTm1‑x‑y‑zO3(BZCFTm,x=0.1‑0.2,y=0.2‑0.4,z=0.2‑0.4)。本发明涉及一种质子导体固体氧化物电解池氧电极,在电解水以及乙烷脱氢过程中,此电极表现出了非常出色的电化学性能。当工作温度设定为650℃,并且施加电压为1.3V时,其电解水时达到‑1618mA cm‑2的电流密度,电解乙烷时则达到‑225mA cm‑2的电流密度。
Resumen de: CN120132721A
本发明公开了一种旋流振荡驱动压电催化海水直接制氢系统及方法,将分散有压电催化材料颗粒和过硫酸盐的海水高速通入多个并联的旋流器中,形成三维旋转流场,各旋流器内的压电催化材料颗粒在跟随三维旋转流场进行跟随旋转运动的过程中,受到旋流振荡机械应力的作用发生形变,压电催化材料颗粒的压电效应被激发并作用于海水,压电催化海水直接制氢;本发明的旋流振荡驱动压电催化海水直接制氢系统及方法,不仅能够低能效、高效率的制备氢气,且其压电催化海水直接制氢系统反应全过程中无氧气产生,极大提高了制氢系统的安全性;且整个制氢系统流程简单,减少了氢气和氧气分离、洗涤、冷却等繁琐流程。
Resumen de: CN120136029A
本发明公开了一种高效型光解水制氢系统及其装置,涉及光解水制氢技术领域,旨在解决传统光解水制氢技术存在光解效率低的问题,包括框架,所述框架的内壁设置有多组反应管,相邻的两组所述反应管之间相互连通,所述框架的内壁固定连接有多个固定架,所述反应管分别与所述固定架固定连接,所述框架内部设置有中转仓,位于最前侧的一组所述反应管分别与所述中转仓的内部连通,所述中转仓的外壁固定连接有与其内部连通的流通管,所述框架的内壁固定连接有连接件,所述连接件的另一端与所述中转仓的外壁固定连接,所述框架的外壁固定连接有多个支架,所述支架的底部固定连接有环形的底座。本发明具有有效提升光解水制氢效率和效果的优点。
Resumen de: CN120138665A
本发明属于CO2电催化还原技术领域,更具体的说是涉及一种无膜电催化CO2还原解耦水分解装置及方法。装置包括左腔室电解池、右腔室电解池和蠕动泵;所述蠕动泵连接左腔室电解池和右腔室电解池的底部;所述左腔室电解池和右腔室电解池的上部通过管道连接;所述左腔室电解池设有CO出口和CO2入口,所述右腔室电解池设有O2出口;所述左腔室电解池内设有阳极和阴极;所述右腔室电解池底部设有助催化剂。该工艺在分离的电解和催化电池中产生CO和O2,并支持在无膜系统中连续运行,提高了离子传导性,减少了内阻,增强了电解效率,在无膜电解槽中可实现高效率和高速率的CO2还原反应。
Resumen de: CN120136251A
本发明属于电化学技术领域,具体涉及一种高效低能耗电化学产羟基自由基的方法,采用三电极体系进行电化学水氧化生成羟基自由基,其中,以钛基铁单原子电极为工作电极;所述的电化学水氧化的电压为1.9~2.3V,反应时间为1~3h。与现有技术相比,本发明解决现有技术中需要施加较高的电压(~3V)以实现电化学产生羟基自由基的问题;本方案采用由钛基铁单原子电极构成的三电极体系,实现了高效低能耗电化学产羟基自由基。
Resumen de: CN120138675A
本发明公开了一种电沉积制备负载铂单原子电极的方法及电极。首先通过在电解质溶液中对泡沫镍进行阳极刻蚀,并用碱清洗刻蚀后的泡沫镍。之后将刻蚀后的泡沫镍置于含有镍、铁离子前驱体溶液生长NiFe LDH薄膜。负载NiFe LDH的泡沫镍电极于含有氯铂酸根的碱性溶液中进行阴极沉积即可制备负载铂单原子(Pt SAs)的NiFe LDH电极。该方法借助阴极还原的方法,在室温下即可快速制备均匀负载铂单原子的NiFe LDH催化剂。电沉积负载Pt SAs的NiFe LDH存在特殊配位结构,增强了其复合材料的电催化析氢和析氧反应的活性。该制备方法有望在各类LDH电极中引入铂单原子并进一步增强电极的电催化活性。
Resumen de: CN120138680A
本发明公开了一种稀土元素掺杂锆基钙钛矿结构的高性能固体氧化物电解池氧电极材料。本发明将稀土元素Yb元素掺杂进锆基钙钛矿Ba(Zr,Co,Fe)O3,得到一种高性能固体氧化物电解池氧电极材料BaZrxCoyFezYb1‑x‑y‑zO3‑δ(BZCFYb,x=0.1‑0.2,y=0.4‑0.6,z=0.2‑0.3)。本发明的固体氧化物电池氧电极材料具有高的电解水性能和稳定性。在氧电极中通入30%的H2O气氛,在650℃,1.4V的电流密度下电压为2000mA/cm2,运行稳定性达到100h。
Resumen de: CN120132882A
本发明公开了一种纳米线氧化镍‑氮化铜负载石墨烯复合材料的制备方法,包括:(1)、将可溶性铜盐和镍盐按比例溶于超纯水中,配置成混合盐溶液A;(2)、将载体石墨烯超声分散于超纯水;(3)、在磁力搅拌下将石墨烯分散液缓慢滴加到A溶液中形成B溶液;(4)、缓慢向B溶液滴加碱液,形成C溶液;(5)、将C溶液转移至反应釜,100~180℃反应6~12h,过滤洗涤,收集产品,烘干;(6)、将样品置于马弗炉中350℃煅烧2h,反应结束,收集样品;(7)、以氨气为氨源,将(6)中样品放置于管式炉中,在300~400℃氨气气氛下煅烧0.5~5h进行部分氮化处理。本发明采用简单的水热合成法和后煅烧氮化处理,成功制备出氧化镍‑氮化铜负载石墨烯复合材料。
Resumen de: CN120138669A
本申请实施例涉及电解槽领域,提供一种电解槽及其制造方法、电解模组,电解槽包括:围成内腔的边框包括顶边框、底边框、第一和第二边框;与边框连接的双极板将内腔分为阳、阴极腔;第一收集框,位于阳极腔内且固定于双极板靠近顶边框的一端,且和双极板围成第一空腔;阳极网,位于第一收集框远离双极板的一侧;第二收集框,位于阴极腔内且固定于双极板靠近顶边框的一端,且和双极板围成第二空腔;阴极网,位于第二收集框远离双极板的一侧;第一边框和第二边框均具有中空腔室,第一边框和第二边框中一者朝向阳极腔的内壁开设与第一空腔连通的第一出料口,另一者朝向阴极腔的内壁开设与第二空腔连通的第二出料口,至少有利于提升电解槽的电解效率。
Resumen de: CN120146677A
本发明公开了一种水电解制氢用多孔传输层性能及性价比综合评价方法,该方法包括:一、基于水电解制氢用多孔传输层的各项性能指标数据,构建水电解制氢用多孔传输层的评价指标矩阵;二、依据评价指标矩阵对指标数据进行标准化处理,将指标数据的绝对值转化为相对值;三、计算指标Xj下第i个评价对象占该指标的比重;四、计算第j个指标Xj的熵值;五、确定各项指标的权重;六、计算每个评价对象的综合性能评价值;七、基于每个评价对象的综合性能评价值和单价计算获得评价对象的性价比值。本发明依据多孔传输层的多项性能指标和单价,采用熵值赋权法对多孔传输层进行了全面评价,评价结果具有较高的应用价值和可靠性。
Resumen de: CN120138715A
本发明涉及一种基于不锈钢的天然海水电解高效催化剂的设计方法和催化剂及其应用,包括以下步骤:以不锈钢网为载体,将所述载体置于高浓度碱性溶液中,通过施加长时间氧化电压对不锈钢表面进行氧化处理形成非晶态镍铁混合氧化物层,并进一步将表面形成氧化层的不锈钢浸渍到含金属M盐的溶液中,通过脉冲电沉积形成负载与不锈钢氧化层的M盐的纳米团簇,并通过改变脉冲电沉积的沉积电流及脉冲次数调控纳米团簇的负载量及团簇尺寸。与现有技术相比,本发明通过对商用不锈钢表面改性处理及贵金属纳米团簇负载实现优异的海水电解阳极催化抗腐蚀性能,经改性处理的不锈钢材料在真实海水电解工业电流密度工况下实现长期稳定运行。
Resumen de: WO2024094454A2
A separator for alkaline hydrolysis comprising a porous layer, the porous layer comprising inorganic particles, characterized in that the inorganic particles have a fraction of primary particles having a diameter above 100 nm of lower than 3 % by number, as measured by Transmission Electron Microscopy (TEM).
Resumen de: CN120138724A
本发明涉及一种高耐久性碱性电解水制氢气复合隔膜及其制备方法,复合隔膜包括尼龙支撑网以及涂层浆料,涂层浆料由聚砜树脂、聚乙烯吡咯烷酮、阴离子交换树脂、自由基清除剂和有机溶剂组成;涂层浆料中,聚砜树脂的质量分数为5~15%,聚乙烯吡咯烷酮的质量分数为0.1~5%,阴离子交换树脂的质量分数为5~15%,自由基清除剂的质量分数为5~20%,有机溶剂的质量分数为30~60%;制备时先按照上述原料配制得到涂层浆料,然后将尼龙支撑网浸润涂层浆料中,接着用刮刀进行刮涂,将刮涂后的尼龙支撑网在空气中静置,进行预蒸发,之后置入醇的水溶液中进行相转化,制得产品。本发明制备方法简单;产品具有优异的化学和机械稳定性。
Resumen de: CN120138708A
本发明公开了一种自支撑钴@钴氧化物核‑壳纳米盘材料的制备方法,所述制备方法包括:(1)将基底材料浸泡在钴盐溶液中;(2)将浸泡后的基底材料进行煅烧,得到负载钴氧化物的基底材料;(3)将负载钴氧化物的基底材料在H2氛围下煅烧还原,得到钴@钴氧化物核‑壳纳米盘材料,记为Co@CoOX。本发明还公开了上述制备方法得到的钴@钴氧化物核‑壳纳米盘材料及其作为HER催化剂的应用。本发明通过简单的制备方法制备得到钴@钴氧化物核‑壳纳米盘材料;且该材料作为电催化剂应用在水解制氢气上表现出优异性能。
Resumen de: CN120138673A
本发明公开的模块化压力型碱性制氢电解槽,包括相对设置的左端板和右端板,左端板和右端板之间设置有若干紧密排列的电解模块,若干电解模块之间连接有第二紧固机构,左端板和右端板之间连接有第一紧固机构,左端板和右端板之间连接有支撑座。本发明将大方量电解槽由整体改为数个电解模块,每个模块均可单独运行或串联成为更大方量的电解槽,这种结构可以将极板、电极、隔膜等工件预先制成电解模块,确定电解槽使用参数后将若干电解模块组装成电解槽即可,使电解槽整装时间大幅降低,电解槽出现故障仅拆除故障模块即可,更利于根据生产现场需求更改电解槽制氢量,方便于改建或扩建。
Resumen de: AU2023383044A1
An electrolysis system 1 is provided with an electrolysis cell 2 and a mediator reduction tank 4. The electrolysis cell 2 comprises: an anode electrode 10 which electrochemically oxidizes a mediator reduction body M
Resumen de: WO2024094453A2
A separator for alkaline hydrolysis comprising a porous layer, the porous layer comprising zirconium oxide particles, characterized in that the zirconium oxide particles have a particle size of 70 nm or less, measured using the Debye-Scherrer equation on the (-111) reflection of a powder X-ray diffraction pattern of the zirconium oxide particles.
Resumen de: CN120138688A
本发明公开了一种电解水析氢用泡沫镍表面原位生长铜纳米颗粒构筑三维多孔自支撑电极及其制备方法。本发明泡沫镍表面原位生长铜纳米颗粒构筑三维多孔自支撑电极的制备方法,包括如下步骤:以泡沫镍为工作电极,以铜盐、氯盐、无机酸和去离子水组成的混合溶液为电解液,采用计时电量法进行电沉积,得到所述泡沫镍表面原位生长铜纳米颗粒构筑三维多孔自支撑电极。本发明通过以氢气泡为动态模板的一步电沉积法制备无需粘合剂的自支撑电极,无贵金属参与,可有效解决传统粉末状催化剂使用Nafion溶液等导电性较差的聚合物粘合剂而带来的阻断活性位点、降低电导率或抑制气体传输等问题。本发明所制备的电极具有优异的HER性能和良好的稳定性。
Resumen de: CN120138700A
本发明公开了一种金属单原子催化剂及其制备方法与应用,属于电催化技术领域;本发明通过在钙钛矿钴酸锶氧化物中掺杂金属元素并将钙钛矿钴酸锶氧化物置于高温高压环境下水热处理转化为羟基氧化钴,使得掺杂的金属元素从钙钛矿钴酸锶氧化物晶格中脱离出来并单分散锚定在所形成的层状羟基氧化钴表面,从而制得单原子催化剂;本发明解决了现有的单原子催化剂工艺复杂、成本高昂、金属单原子自发聚集的问题,制得的金属单原子催化剂具有高分散性和稳定性,可以实现单原子在特定活性位点的精准锚定,在电催化领域具有广阔的应用前景。
Resumen de: CN120138696A
本发明涉及纳米材料制备和应用技术领域,尤其涉及一种过渡金属硒化物催化剂及其制备方法与应用,包括:首先将金属镍盐、铁盐、尿素和氟化铵溶解在去离子水中,通过水热法合成镍铁层状氢氧化物纳米片前驱体;其次采用硒化反应制得铁掺杂硒化镍催化剂;利用铁掺杂策略调控硒化镍的电子结构,提高催化性能。制备的铁掺杂硒化镍催化剂用于析氢反应和硫离子氧化反应时具有良好的催化活性。在两电极硫离子氧化耦合制氢电解池中,仅需电压0.439V即可输出电流密度10mAcm‑2,实现高效节能制氢和硫离子氧化升级为高附加值单质硫产物的目标。本发明具有制备过程简单可控、原材料价格低廉和易于批量生产等优点,可作为高效的电解水制氢和硫离子氧化反应的催化剂。
Resumen de: CN120138679A
本申请提供一种电解水制氢膜电极及其制备方法、电解槽,属于电解水制氢技术领域,电解水制氢膜电极包括复合阳极层、阴离子交换膜和复合阴极层,其中,复合阳极层包括阳极基底层、第一气体扩散层和阳极催化层。阴离子交换膜,设置于复合阳极层具有阳极催化层的一侧,复合阴极层设置于阴离子交换膜背离复合阳极层的一侧,复合阴极层包括阴极基底层、第二气体扩散层和阴极催化层。本申请实施例提供的电解水制氢膜电极能够消除至少部分部件之间的界面电阻,使得离子传输和气体扩散更加顺畅,提高电解效率。
Resumen de: CN120138693A
本发明属于材料领域,公开了一种用于双功能碱性电解水锰掺杂硫化镍/多孔泡沫镍电极的制备方法。本发明通过两步电沉积的方式,首先对泡沫镍基底进行活化,然后在活化后的多孔泡沫镍基底上电沉积硫化镍并掺杂锰。本发明在多孔泡沫镍上生长的锰掺杂硫化镍纳米结构,构建了可用于双功能电解水的电极,该电极的多孔结构在高电流密度下,能够有效加速传质过程,同时促使反应产生的气泡快速逃逸。此外,硫化镍经过锰的掺杂,优化了电子结构,具有导电性增强、电化学活性面积增大、活性位点充分暴露和中间体吸附优化等特点。本发明的制备方法为实际水电解中高性能电极的制备提供了一种有效的策略。
Resumen de: CN120138709A
本发明涉及一种用于碱性氢气析出反应的掺杂型钕基复合电催化剂及其制备方法与应用。该催化剂以钕氧化物(Nd2O3)为基体材料,通过掺杂磷(P)和钌(Ru),优化了催化剂的电子结构,显著提高了其催化活性和稳定性。催化剂采用简单的水热法和低温磷化处理制备,具有均匀的连续平整的纳米层结构,有利于电子传输和反应活性位点的暴露。在1.0 M KOH电解液中,该催化剂表现出极低的过电位(11.8 mV)和优异的稳定性,显著优于商业Pt/C催化剂和未掺杂的钕氧化物催化剂。本发明的复合电催化剂不仅实现了高效、稳定的碱性氢气析出反应,还为设计高性能非贵金属催化剂提供了新的思路。
Resumen de: CN120143785A
本申请提供一种大规模制氢工厂的故障定位解决方法和系统、计算机可读存储介质,涉及制氢工厂技术领域。方法包括:S1:通过监测在线数据或提取关键特征,进行异常预警;S2:基于异常预警信号,进行故障定位;S3:识别出故障的部件,并进行部件分离;S4:使用故障算法辨识故障类型并定量;S5:进行故障溯源;S6:基于经济影响分析给出最优解决方案;S7:排查隐患。该方法和系统用以异常预警、目标定位、故障诊断并提出处理建议,以实现分析目标分流、算力高效分配。
Resumen de: CN120136734A
本发明提供一种三元有机共晶的制备及其在光催化中的应用。该三元有机共晶P‑TS‑TC的分子式为(Pyrene)0.1(TSB)0.9(TCNB),其中Pyrene为芘,TSB为反式‑1,2‑二苯乙烯,TCNB为1,2,4,5‑苯四乙腈。P‑TS‑TC的制备包括以下步骤:将芘、TSB和TCNB溶于乙腈溶剂中,乙腈溶剂自然挥发后即可得到橙黄色P‑TS‑TC单晶。本发明制备的三元共晶中存在电荷转移态(CT态),导致其光吸收范围相比于三种单体分子芘、TSB和TCNB均有明显红移。同时由于三种单体分子的能级呈梯度排列,能够有效促进P‑TS‑TC中的空穴转移,从而实现对共晶中CT态离域性的调控。相比于二元有机共晶P‑TC和TS‑TC,本发明制备的三元有机共晶P‑TS‑TC具有更长的载流子寿命和更高的光催化分解水制氢性能。
Resumen de: CN120138721A
本发明提供一种用于海水电解制氢的高稳定性复合隔膜及其制备方法,所述复合隔膜包括依次相连的增强层、多孔层及表面强化层;本发明通过采用增强层、多孔层及表面强化层这种结构设计及制备,得到具有高稳定性的海水电解用隔膜,而且该隔膜具有较低的面电阻和较高的强度;通过在表面强化层中添加有金属氧化物,在隔膜形成一层保护膜,有效减少海水对隔膜的腐蚀作用,并且由于金属氧化物的导电性,能够降低隔膜的电阻,提高电解效率;另一方面,通过控制表面强化层中微孔结构的大小,在不影响隔膜离子传导性能的情况下,有效将沉淀物阻隔在隔膜外,提高隔膜耐堵塞性,使隔膜实现在海水电解过程中的长期稳定工作。
Resumen de: CN120138713A
本发明公开一种Cu‑Co(OH)2/CeO2异质结电催化剂的制备方法及其应用,涉及电化学催化技术领域;所述催化剂的制备方法如下:以泡沫镍为工作电极,将其置于由钴盐、铈盐和铜盐按预定比例配制成的混合水溶液中,通过电沉积方法,制得Cu‑Co(OH)2/CeO2异质结电催化剂。其中异质组分间形成界面内建电场加速电子转移,CeO2作为电子受体优化空间电荷分布,促进高价钴的形成从而激活晶格氧,提升OER活性;Cu的掺杂进一步调控d带中心位置,增强中间体*OH的吸附,有利于快速填充晶格氧空位,大幅稳定活性组分结构。二者耦合实现协同优化*OH吸附能和LOM途径,有效提升OER活性和稳定性,大幅降低电解水阳极侧反应能耗,为设计工业非贵金属基OER电极提供思路。
Resumen de: CN120138687A
本发明属于催化剂技术领域,提供了一种木质素基过渡金属氢氧化物的电催化剂及其制备方法与应用。本发明提供的催化剂以木质素磺酸盐及过渡金属盐为原料,以导电材料为载体,通过水热合成实现过渡金属氢氧化物的合成并负载在导电材料上,制得木质素过渡金属氢氧化物的电催化剂。本发明通过木质素磺酸盐的磺酸基团及羧基等结构诱导高价金属活性物质生成,使其具备优异的催化活性和良好的复用性。
Resumen de: CN120138726A
本发明涉及一种用于电解制氢传质系统补水装置,补水系统单元包括膜组件、进、出液主管道、碱液进出泵和分流器,进液主管道输入端与碱液罐连接,进液主管道输出端通过分流器与各个膜组件连接,膜组件侧的碱液口通过第一出液主管道与碱液缓冲罐连接,碱液缓冲罐输出端通过第二出液主管道与碱液罐连接;海水循环单元包括具有海水进液口和海水溢流口的海水槽,膜组件设置在海水槽内;本发明通过巧妙的设计,能够在电解过程中实现对海水的直接淡化,无需额外消耗能量,从而显著降低了制氢过程的整体能耗。通过补水系统单元确保电解液能够高效的进行浓度转化,及时的为电解后的溶液进行补水。
Resumen de: CN120137678A
本发明公开了一种Pickering乳液及其在光催化制氢中的应用,属于Pickering乳液制备技术领域。本发明利用溶胶凝胶法以及水热法制备了具有亲水性质的氮铋共掺杂二氧化钛材料,又将氮铋共掺杂二氧化钛材料与具有疏水性质的羧基化多壁碳纳米管复合,得到的两亲性的氮铋共掺杂二氧化钛复合碳纳米管材料。以氮铋共掺杂二氧化钛复合碳纳米管作为乳化剂,蒸馏水作为水相,正辛醇为油相,利用高速匀浆均质,得到Pickering乳液。利用氮铋共掺杂二氧化钛复合碳纳米管稳定的Pickering乳液光催化产氢体系,与水相、辛醇油相、水‑辛醇非均相相比,其光催化性能显著提升。
Resumen de: CN120138684A
本发明公开了一种水电解制氢用抗逆电流电极,所述电极上设有催化剂涂层,所述催化剂的化学式为(Ni0.8Ti0.05Zr0.05MoxSb0.1‑x)O,其中,0<x<0.1。本发明以Ni为主要活性组分,保证高催化活性。通过引入Zr、Ti、Mo、Sb等多种元素进行高熵化设计,利用高熵效应提升材料的化学稳定性和机械性能。通过调节Mo和Sb的比例,优化电极的催化活性和抗逆向电流能力。
Resumen de: CN120138711A
本发明提供一种双金属磷化物及其制备方法和在电解海水中的应用,所述双金属磷化物的制备方法包括:S1,将镍盐、铁盐及二甲基咪唑加入溶剂中,搅拌,得到前驱液;将前驱液进行溶剂热反应,得到含镍铁的前驱体;其中,所述前驱液中,镍离子和铁离子的总摩尔数与二甲基咪唑的摩尔数之比为1:(0.25~0.75);S2,将含镍铁的前驱体与磷化试剂进行反应,得到双金属磷化物。所述双金属磷化物形貌为纳米片与纳米颗粒的复合体,所述复合体中,纳米颗粒负载在纳米片上。所述的双金属磷化物作为电解池的阳极材料,可以用于直接电解海水制氢。
Resumen de: CN120138663A
本发明公开了一种电解水制氢设备及其方法,涉及电解水制氢技术领域。一种电解水制氢设备包括外壳,所述外壳内部设置有电解槽,所述电解槽由阳极室和阴极室组成,且所述阳极室与阴极室通过隔膜分隔开;所述阳极室内设有阳极板,并通过阳极导电棒与电源正极相连;所述阴极室内设有阴极板,并通过阴极导电棒与电源负极相连。通过进水口向阳极室和阴极室内注入去离子水并确保充满整个空间,然后启动直流电源使电流通过电极板,在阳极产生氧气、阴极产生氢气;最后,产生的气体通过出气口及其连接的管道被收集到各自的气体收集罐中。本发明通过使用质子交换膜作为隔膜,仅允许质子通过而阻止气体分子,使得阳极产生的氧气和阴极产生的氢气被有效分离。
Resumen de: WO2025122112A1
The invention relates to a hydrogen sulfide separation system (A) and method for producing pure hydrogen (30) with high efficiency and environmental sustainability for the energy sector, while also converting sulfur (40) into economic value by producing sulfuric acid (60) The system includes a gasification unit (100) to convert liquid hydrogen sulfide (10) into gaseous hydrogen sulfide (20), an electrolyzer (200) equipped with a palladium-alloy membrane (290) to separate hydrogen (30) and sulfur (40) through electrolysis, and an oxidation unit (300) to oxidize sulfur (40) using hydrogen (30) and oxygen (50), resulting in sulfuric acid (60). The method enhances energy efficiency, reduces operating costs, and offers a sustainable solution for hydrogen production.
Resumen de: WO2025121289A1
Provided is a membrane electrode assembly capable of suppressing hydrogen crossover. The membrane electrode assembly is for solid macromolecule-type water electrolysis and comprises: an anode having a catalyst layer; a cathode having a catalyst layer; and a solid macromolecule electrolyte membrane disposed between the anode and the cathode. At least one of the catalyst layer in the anode and the catalyst layer in the cathode includes a fluorine-containing polymer having an ion exchange group, and having a unit having a cyclic ether structure.
Resumen de: WO2025119989A1
The invention concerns a method of electrolysing water using an electrolyser comprising an anode; a cathode and optionally a separator; wherein at least one of the cathode and the separator comprises a substrate and a coating, and the coating comprises 9.5 to 35 wt% chromium; 10 to 75 wt% cobalt; and 10 to 60 wt% of one or more further transition metals and/or one or more non-metallic elements selected from C, P, N and B.
Resumen de: KR20250085126A
본 발명은 수전해 수소발생반응용 Pt/LaNiO3 촉매에 관한 것으로서, 상세하게는, 수전해 시스템에서 수소발생반응(HER) 전극에 적용되는 신규 촉매로써 수전해시 동일 전압에서의 수소발생 반응성이 우수하며, 또한 과전압을 낮추는 효율, 촉매 안정성이 우수한 수전해 수소발생반응용 Pt/LaNiO3 촉매에 관한 것이다.
Resumen de: KR20250085499A
수전해 셀의 활성화 방법을 제공한다. 제공되는 수전해 셀의 활성화 방법은 ⅰ) 음극, 전해질막 및 양극을 포함하는 수전해 셀을 준비하는 셀 준비 단계, ⅱ) 수전해 셀에 증류수를 공급하여, 전해질막에 증류수를 흡수시키는 증류수 공급 단계, 및 ⅲ) 전해질막에 전압을 인가하여, 그 전위가 V1에서 V2로 증가한 후 V1으로 감소하는 사이클 또는 그 전위가 V2에서 V1으로 감소한 후 V2로 증가하는 사이클이 N회 반복되도록 하는 전위 증감 단계를 포함한다. V1은 0.01V 이상 1V 이하 범위로 제공되고, V2는 1.1V 이상 2.5V 이하 범위로 제공된다.
Resumen de: KR20250085401A
본 발명은 이퓨얼(e-fuel)을 제조하기 위한 시스템 및 방법에 관한 것으로, 본 발명에 따르면, 최근, 환경오염 문제가 날로 심각해지면서 기존의 석유나 가스 등의 연료를 대신하여 친환경 연료에 대한 요구가 높아짐에 따라 기존의 화석연료에 비해 이산화탄소 배출량을 크게 감소할 수 있는 친환경 연료로서 이퓨얼(E-Fuel)이 제시된 바 있으나, 전체적인 제조공정이 복잡하여 가격이 매우 높은 단점이 있었던 종래기술의 이퓨얼 제조시스템 및 방법들의 문제점을 해결하기 위해, 수소(H2)와 이산화탄소(CO2)를 이용하여 촉매반응을 통해 친환경적으로 이퓨얼을 생성할 수 있도록 구성됨으로써, 보다 친환경적으로 이퓨얼을 생산할 수 있는 동시에, 이퓨얼 제조시스템의 생산성을 높이고 전체적인 비용을 절감할 수 있도록 구성되는 수소와 이산화탄소를 이용한 이퓨얼 제조시스템 및 방법이 제공된다.
Resumen de: DE102023212354A1
Elektrolysesystem mit einem Stack (1), der einen Anodenraum (2) und einen Kathodenraum (3) aufweist und der dazu eingerichtet ist, Wasser elektrolytisch in Wasserstoff und Sauerstoff aufzuspalten, wobei der Kathodenraum (3) einen Einlass (9) und einen Auslass (10) aufweist. Dem Stack (1) ist ein Gas-Flüssig-Separator (11) zugeordnet, der über eine Ausleitung (12) mit dem Auslass (10) des Kathodenraums (3) verbunden ist und in dem Flüssigkeit von Gas getrennt wird, wobei der Gas-Flüssig-Separator einen Gasauslass (13) zum Abströmen des abgetrennten Gases aufweist. Der Gasauslass (13) mündet in einen zentralen Gas-Flüssig-Separator (25) zur Trennung von Flüssigkeit und Gas.
Resumen de: US2025186304A1
A hydrogen generation device includes a tubular tank and a top lid combined with the tank. An immersion tube in which a hydrogen generating agent package is stuffed is placed in the tank. The hydrogen generating agent package is submerged in water after water is poured in the tank to generate hydrogen, which is released through a tank opening of the tank. The hydrogen generating agent package accommodates hydrogen generating agent powders including calcium oxide and aluminum powders, both of which are mixed and wrapped with a nonwoven fabric, as well as a little catalytic sodium carbonate added inside. For inhibition of free radicals and promotion of metabolism, the hydrogen generation device is further provided with a connector and a hose for a skin-care instrument, a nasal mask, an eye shield or an ear cleaner through which hydrogen is supplied as required.
Resumen de: US2025187912A1
A catalyst includes a ruthenium metal loaded on a support, wherein the support has a chemical formula of AxB(1-x)Oy. A is an alkaline earth metal, B is aluminum, zinc, cerium, manganese, or a combination thereof, x is 0.05 to 0.50, and y is chemical stoichiometry. The catalyst may further include an auxiliary agent loaded on the support. The catalyst can be used to decompose gaseous ammonia.
Resumen de: US2025188621A1
Device for generating hydrogen gas and oxygen gas from water, comprising a case, which forms a hydrolysis chamber designed to contain an amount of water; electrode means that act as a cathode and an anode; and gas-separating means, disposed in the hydrolysis chamber between the cathode and the anode, which comprise a permeable membrane segment suitable for preventing the generated hydrogen gas and oxygen gas from passing through the permeable membrane segment and mixing together, the hydrolysis chamber being divided into a first portion that contains the cathode and a second portion that contains the anode, wherein the first and second chamber portions are in fluid communication with respective pipes for hydrogen gas and oxygen gas. Another object of the invention is a system for the same purpose, comprising at least one device as described above.
Resumen de: DE102023212440A1
Die Erfindung betrifft ein Offshore-Elektrolysesystem (100) umfassend eine Windkraftanlage (1) mit einem auf dem Meeresgrund verankerten Turm (19) und mit einer Elektrolyseanlage (5), wobei die Elektrolyseanlage (5) mit einer Versorgungsleitung (11) an die Windkraftanlage (1) angeschlossen ist, und wobei die Elektrolyseanlage (5) einen in einem Container (9) angeordneten Elektrolyseur (13) aufweist, wobei der Container (9) unterhalb des Meeresspiegels (25) angeordnet ist.Die Erfindung betrifft weiterhin ein Verfahren zum Betrieb eines entsprechenden Offshore-Elektrolysesystems. Dabei wird von einem unterhalb des Meeresspiegels (25) angeordneten Elektrolyseur (13) der Elektrolyseanlage (5) Wasser in Wasserstoff (H2) und Sauerstoff zerlegt, wobei der erzeugte Wasserstoff (H2) über eine Produktgasleitung (7) abtransportiert wird.
Resumen de: DE102023134698A1
Die Erfindung betrifft ein Verfahren zum Herstellen einer Elektrode (10) für die Verwendung bei der alkalischen Elektrolyse von Wasser, das Verfahren umfassend Bereitstellen eines metallischen Substrats (12), Bereitstellen eines Beschichtungswerkstoffes (26), umfassend ein Pulver (28) aus einem Katalysatormaterial (20) und nicht-metallische Partikel (24), und Beschichten zumindest eines Abschnitts des Substrats mit dem Beschichtungswerkstoff. Die Erfindung betrifft auch derart herstellte Elektroden.
Resumen de: US2025188632A1
An electrolytic method of loading hydrogen into a cathode includes placing the cathode and an anode in an electrochemical reaction vessel filled with a solvent, mixing a DC component and an AC component to produce an electrolytic current, and applying an electrolytic current to the cathode. The DC component includes cycling between: a first voltage applied to the cathode for a first period of time, a second voltage applied to the cathode for a second period of time, wherein the second voltage is higher than the first voltage, and wherein the second period of time is shorter than the first period of time. The peak sum of the voltages supplied by the DC component and AC component is higher than the dissociation voltage of the solvent. The AC component is selected based on a local minimum of a Nyquist plot to minimize energy loss while maintaining hydrogen transport.
Resumen de: US2025188620A1
A new energy hydrogen production system and a control method therefor. In the new energy hydrogen production system, a new energy input module supplies power to electrolytic cells by means of a power conversion module; and a control system of the new energy hydrogen production system is used for controlling, according to the power of the new energy input module, the power conversion module to work, such that among N electrolytic cells in an operation state, at least N-1 electrolytic cells work in a preset load range. The preset load range is a corresponding load range having the highest system efficiency in an electrolytic cell working range division result prestored in the control system.
Resumen de: US2025188628A1
An electrolysis cell for chlor-alkali or alkaline water electrolysis comprises two cell elements each defining an electrode chamber by providing a back wall and sidewalls of the electrode chambers, an electrode accommodated in each of the electrode chambers, and a sheet-like separator extending in a height direction and a width direction of the electrolysis cell, the separator being interposed in a joint between the two cell elements and providing a separating wall between the electrode chambers, wherein at least one of the electrodes is made from a sheet of metallic mesh, which is supported by a plurality of webs attached to the back wall of the respective electrode chamber, the webs extending in the height direction of the electrolysis cell, and wherein a plurality of ribs extending in the width direction of the electrolysis cell is carried by the webs, wherein the electrode is disposed on the plurality of ribs.
Resumen de: US2025188630A1
An oxynitride catalyst includes NiaMbNcOd, wherein M is Nb, Mn, or Co, a>0, b>0, c>0, d>0, and a+b+c+d=1. A hydrogen evolution device includes an anode and a cathode dipped in an electrolyte, and the anode includes the oxynitride catalyst. The oxynitride catalyst can be disposed on a support. The oxynitride catalyst may have a polyhedral structure.
Resumen de: US2025188633A1
The present invention relates to the generation of at least one electrolysis product, in particular to a hydropower-electrolysis system, a hydro power plant and a method for generating at least one electrolysis product. An electrolysis assembly includes a plurality of electrolysis cells configured to generate, upon provision of a direct electrical current, at least one electrolysis product from a supply medium. A hydropower assembly is electrically connected to the electrolysis assembly for operating the electrolysis cells of the electrolysis assembly based on electrical power generated by the hydropower assembly.
Resumen de: US2025188565A1
Improved processes and systems are disclosed for producing renewable hydrogen suitable for reducing metal ores, as well as for producing activated carbon. Some variations provide a process comprising: pyrolyzing biomass to generate a biogenic reagent comprising carbon and a pyrolysis off-gas; converting the pyrolysis off-gas to additional reducing gas and/or heat; reacting at least some of the biogenic reagent with a reactant to generate a reducing gas; and chemically reducing a metal oxide in the presence of the reducing gas. Some variations provide a process for producing renewable hydrogen by biomass pyrolysis to generate a biogenic reagent, conversion of the biogenic reagent to a reducing gas, and separation and recovery of hydrogen from the reducing gas. A reducing-gas composition for reducing a metal oxide is provided, comprising renewable hydrogen according to a hydrogen-isotope analysis. Reacted biogenic reagent may also be recovered as an activated carbon product. Many variations are disclosed.
Resumen de: US2025188631A1
An embodiment water electrolysis catalyst includes iridium oxide including a rutile phase and iridium-nickel oxide including a hexagonal phase. An embodiment method of preparing a water electrolysis catalyst includes preparing a mixture including an iridium precursor, a nickel precursor, and cysteamine hydrochloride, drying the mixture, grinding the dried mixture, and firing a ground product, wherein the water electrolysis catalyst includes iridium oxide including a rutile phase and iridium-nickel oxide including a hexagonal phase.
Resumen de: US2025188629A1
A power control device for a hydrogen production system according to one aspect includes: a power generation device that generates electric power by using renewable energy; a hydrogen production device that produces hydrogen by using electric power generated by the power generation device; and a connector that connects the power generation device and the hydrogen production device to an electric power system. The power control device determines a power command value to be supplied to the hydrogen production device based on electric power generated by the power generation device and electric power that reversely flows to the electric power system so that hydrogen is produced in a state where a reverse power flow to the electric power system continuously occurs.
Resumen de: AU2023397261A1
The invention relates to an electrolysis system (1) with a pressure electrolyzer (3) for generating hydrogen (H
Resumen de: DK202330343A1
Water electrolyser stack having a range of half-cell frames which each circumscribes one of an anolytic or a catholytic process chamber and which half-cell frames are arranged and aligned in an array between a proximal electric current injector/collector plate and a distal electric current injector/collector plate, and where each half-cell frame comprises an embedded furrow flow channel adapted to serve an electrolyte flow from a stack internal inflow manifold channel to a corresponding anolytic or catholytic reaction chamber and an embedded furrow flow channel adapted to serve an electrolyte and gas outflow from a corresponding anolytic or catholytic reaction chamber to a corresponding stack internal manifold channel wherein each of the embedded furrow flow channels comprise at least one fluid and/or gas trap section.
Resumen de: TW202409348A
An alkaline electrolyzer system comprising an electrochemical cell in proximity to a spacer frame is provided. The spacer frame contains a polymer composition that includes a polymer matrix that contains at least one polyarylene sulfide.
Resumen de: WO2025119096A1
The present disclosure relates to a method for preparing an oxygen evolution electrode, an oxygen evolution electrode and an electrolytic cell. The method (100) comprises: preparing a thin film on the surface of a conductive substrate by means of magnetron sputtering, wherein the thin film at least contains a catalyst substance serving as a catalyst in an oxygen evolution reaction and a soluble substance that can dissolve in an alkaline solution (102); and making the thin film come into contact with the alkaline solution, such that the soluble substance dissolves in the alkaline solution, so that a porous catalyst layer consisting of the catalyst substance is formed on the surface of the conductive substrate, and the conductive substrate and the porous catalyst layer form an oxygen evolution electrode (104). The method of the present disclosure can improve the catalytic activity and stability of an oxygen evolution electrode, and facilitates large-scale oxygen evolution electrode preparation, and can effectively reduce the production cost and the application cost.
Resumen de: WO2025118002A1
The invention relates to a method (1000) for operating an electrolysis system (10) which has at least one electrolyzer stack (100), with an air side (120) and a reactant side (130), and different operating situations. The method (1000) has the steps of detecting the operating situation of the electrolysis system (10) and controlling the electrolysis system (10) on the basis of the detected operating situation. In the method (1000), the operating situation of the electrolysis system (10) is determined to be a special operating situation if the detected operating situation deviates from a normal operation of the electrolysis system (10) for generating a synthesis gas from a reactant as intended. For the detected special operating situation, at least one electric heater (221, 222) is controlled so as to control the temperature of air which can be supplied to the air side (120) in order to control the temperature of the electrolyzer stack (100). Furthermore, for the special operating situation, a heating gas is guided to the reactant side (130), said heating gas having at least one protective gas. The invention also relates to a computer program product, to a control device (20) for carrying out the method (1000), and to an electrolysis system (10) comprising the control device (20).
Resumen de: CN117926298A
A system preferably includes a carbon dioxide reactor. A method for carbon dioxide reactor control preferably includes selecting a carbon dioxide reactor aspect based on a desired output composition, operating the carbon dioxide reactor under controlled process conditions to produce the desired output composition, and/or changing the process conditions to change the output composition.
Resumen de: EP4567079A1
Molybdenum carbide includes a Mo<sub>2</sub>C crystal structure, in which a content of carbon with respect to a total mass (100 mass%) of the molybdenum carbide is 6% or more.
Resumen de: WO2025116586A1
Disclosed are a catalyst electrode for ammonia water electrolysis and a manufacturing method thereof, the durability and catalytic activity of the catalyst electrode being improved by synthesizing platinum catalyst seeds through an ultrasonic treatment of a specific duration and inhibiting poisoning of a platinum catalyst by nickel hydroxide formed on the surface of a nickel support.
Resumen de: EP4566988A1
The invention relates to a process for the production of hydrogen gas (4) from ammonia, thereby obtaining an effluent gas (6) comprising hydrogen gas (4). Said process comprising the following steps:- providing an ammonia feedstock stream (8);- performing at least one electrical heating and conversion step, said step comprising:heating in at least one electric heater (12) the ammonia feedstock stream (8) so as to produce a heated gas stream (14); andperforming in at least one adiabatic reactor (16) an endothermic cracking reaction of the heated gas stream (14), said adiabatic reactor (16) comprising at least one catalyst bed (18) performing said endothermic cracking reaction of the ammonia feedstock stream (8) into said effluent gas (6).
Resumen de: KR20250084643A
본 발명은 수전해용 촉매 제조방법 및 수전해용 촉매에 관한 것으로서, 본 발명에 따른 수전해용 촉매 제조방법은, 탄소 소재를 준비하는 단계; 상기 탄소 소재 상에 니켈을 도금하는 단계; 상기 니켈에 금을 코팅하는 단계; 이리듐을 드롭캐스팅하는 단계; 및 열처리하는 단계;를 포함하고, 상기 니켈, 상기 금 및 상기 이리듐의 중량비는 1 : 12~16 : 2~4인 것을 포함한다.
Resumen de: EP4567159A2
There is disclosed an electrolyser (10, 20, 50) for operation at supercritical conditions, in which chambers (200, 210, 520) for retaining respective fluid reaction products are separated by a porous wall which permits a flow of electrolyte fluid therethrough and which inhibits a reverse flow of the respective reaction product. There is also disclosed a method of operating an electrolyser.
Resumen de: EP4567153A1
A method of electrolysing water, the method comprising:- providing an electrolyser comprising an anode; a cathode and optionally a separator;- contacting the cathode and/or the anode with an aqueous alkaline solution comprising water; and- electrolysing the water using a potential difference from the anode to the cathode,wherein at least one of the cathode and the separator comprises a substrate and a coating, wherein the coating comprises 9.5 to 35 wt% chromium; 10 to 75 wt% cobalt; and 10 to 60 wt% one or more further transition metals and/or one or more non-metallic elements selected from C, P, N and B, and wherein the coating catalyses hydrogen evolution at the cathode.
Resumen de: EP4566988A1
The invention relates to a process for the production of hydrogen gas (4) from ammonia, thereby obtaining an effluent gas (6) comprising hydrogen gas (4). Said process comprising the following steps:- providing an ammonia feedstock stream (8);- performing at least one electrical heating and conversion step, said step comprising:heating in at least one electric heater (12) the ammonia feedstock stream (8) so as to produce a heated gas stream (14); andperforming in at least one adiabatic reactor (16) an endothermic cracking reaction of the heated gas stream (14), said adiabatic reactor (16) comprising at least one catalyst bed (18) performing said endothermic cracking reaction of the ammonia feedstock stream (8) into said effluent gas (6).
Resumen de: EP4568049A1
Provided is an electrolyzer power control system that includes a reactive harmonic current reference generation stage. The reactive harmonic current reference generation stage selects a reactive power set point for reactive power drawn by a rectifier from a grid, determines a reactive power current reference based on the reactive power set point, aggregates the reactive power current reference with a reference current of harmonic currents that the rectifier injects in or draws from the grid, determines a reactive harmonic current reference that compensates for both the reactive power and the harmonic currents and outputs the reactive harmonic current reference. Switching signals that operate the rectifier are generated based on the reactive harmonic current reference.
Resumen de: CN119630834A
The invention relates to a method for heating a furnace comprising radiant tubes and capable of heat-treating a running steel product, comprising the following steps: i. Supplying H2 and O2 to at least one of said radiant tubes such that said H2 and said O2 combine into heat and steam; ii. Recovering said steam from said at least one of said radiant tubes; iii. Electrolyzing the steam to produce H2 and O2; iv. Supplying said H2 and O2 produced in step iii to at least one of said radiant tubes such that said H2 and O2 combine into heat and steam.
Resumen de: EP4567157A2
An electrolyzer system includes stacks of electrolyzer cells configured receive steam and air, and output a hydrogen product stream and an oxygen exhaust stream, and a first heat pump configured to extract heat from the oxygen exhaust stream to generate a first portion of the steam provided to the stacks.
Resumen de: CN119604469A
The present invention relates to a method for manufacturing an electrocatalyst for alkaline water electrolysis, said method comprising the steps of: (i) generating an aqueous electrolyte comprising suspended graphene and graphite nanoplatelets having lt in an electrochemical cell; the present invention relates to an electrolytic cell having a thickness of 100 nm, where the electrolytic cell comprises: a graphite negative electrode, (b) a graphite positive electrode, (c) an aqueous electrolyte comprising ions in a solvent, the ions comprising cations and anions, where the anions comprise sulfate anions; and wherein the method comprises the step of passing an electric current through the electrolysis cell to obtain exfoliated graphene and graphite nanosheet structures in the aqueous electrolyte in an amount greater than 5 g/l; (ii) forming an electroplating bath (2) comprising suspended graphene and graphite nanoplatelets in an amount greater than 2 g/l, said acidic electroplating bath comprising an aqueous solution of nickel sulfate and an electroplating solution comprising suspended graphene and graphite nanoplatelets in an amount greater than 5 g/l (thickness lt; 100 nm) of an aqueous electrolyte of step (i); and (iii) electrodepositing a combined layer of Ni or Ni alloy with graphene and graphite particles from the electroplating bath on a support to form an electrocatalyst.
Resumen de: US2025149602A1
A SOC stack system comprises one or more solid oxide cell stacks and multi-stream solid oxide cell stack heat exchanger(s).
Resumen de: AU2022322636A1
A highly crystalline mesoporous sulphur functionalized carbon nitride and a process for producing the same. The process including the steps of: providing a carbon nitride precursor material; mixing the carbon nitride precursor material with a metal salt to form a first mixture; and, thermally treating the first mixture to produce the crystalline carbon nitride.
Resumen de: AU2023338223A1
00049 An iridium-based catalyst and method of making the catalyst are described. The catalyst comprises a catalytic material comprising iridium oxide or a mixture of iridium and iridium oxide nanoplates. It may have a BET surface area of at least 50 m
Resumen de: EP4567158A1
Provided is a hydrogen production system (100) including: an electrolysis module (19) that supplies steam to a hydrogen electrode (11) including a metal component and produces hydrogen through steam electrolysis; a hydrogen storage facility (40) that stores the generated hydrogen; a steam supply unit (20) that supplies steam to the hydrogen electrode (11); a regulation unit (50) that regulates a supply amount of the hydrogen supplied from the hydrogen storage facility (40) to the hydrogen electrode (11) and a supply amount of the steam supplied from the steam supply unit (20) to the hydrogen electrode (11); and a control device (80) for controlling the regulation unit (50) to switch a heating medium supply state in which a heating medium is supplied from a heating medium supply unit (70) to the hydrogen electrode (11) to a steam supply state in which steam is supplied from the steam supply unit (20) to the hydrogen electrode (11), in response to the electrolysis module (19) exceeding a first switching temperature when activating the electrolysis module (19).
Resumen de: KR20250084527A
본 발명의 일 실시예는, 암모니아 공급부와, 제1 연결라인을 통해 상기 암모니아 공급부와 연결되고, 암모니아 분해반응을 통해 암모니아를 분해하고, 상기 암모니아 분해반응으로부터 생성된 수소, 질소 및 미반응 암모니아를 포함하는 반응생성물을 배출하는 분해반응부와, 상기 암모니아 공급부와 상기 분해반응부 사이에 배치되고, 상기 제1 연결라인을 통과하는 상기 암모니아를 승압하는 승압부와, 상기 암모니아 공급부와 상기 분해반응부 사이에 배치되며, 상기 제1 연결라인을 통과하는 상기 암모니아를 가열하는 가열부를 포함하는, 암모니아를 이용한 수소 제조 및 공급 장치를 제공한다.
Resumen de: CN120119286A
本发明涉及一种氧连接的单原子‑氧化物过渡金属催化剂的制备方法,包括以下步骤:在氧化石墨烯溶液中加入钼源,然后再加入锆源搅拌,得到前驱体溶液,将前驱体溶液进行水热反应,得到反应产物;将反应产物干燥处理,之后采用化学气相沉积方法进行高温氮化,得到一种氧连接的单原子‑氧化物过渡金属催化剂。本发明利用四水合钼酸铵和四氯化锆作为金属前驱体,氨气为氮源,采用水热反应和化学气相沉积法合成一种氧连接的单原子‑氧化物过渡金属催化剂,本发明所制备的催化剂,在纯水和海水环境中,均表现出极为优异的电催化电解水效能,具有显著的高催化活性、可达到的大电流密度、极小的塔菲尔斜率,以及高度稳定性。
Resumen de: CN120115083A
本发明涉及制氢设备测试技术领域,具体的是一种便携式氢气发生器及其测试设备,本发明的氢气发生器包括主体部和支撑部,主体部由对接环和分别安装在对接环两端的料筒和水筒组成,料筒和水筒相背一端的外侧均开设有凹孔,支撑部包括承载座,承载座外侧固定设有U型杆,且U型杆对接环之间均转动安装,承载座顶部开设有沉槽,沉槽内部活动套设有卡凸,卡凸与沉槽之间连接有弹簧五,通过控制氢气发生器主体部的翻转来实现控制制氢反应的进行;本发明的测试设备包括基板,基板顶部设有回转检测机构,回转检测机构两端分别设有上料机构和分选机构,可以实现对待检测氢气发生器主体部周侧面的检测区域进行连续地全方位多位点检测。
Resumen de: CN120119280A
本发明公开了一种介孔氧化铱催化剂及其制备方法和应用,包括,含铱化合物、硝酸盐和尿素加水溶解,搅拌混合均匀得到混合液;混合液旋蒸干燥获得均匀的催化剂前驱体;前驱体在空气气氛下煅烧,得到氧化铱催化剂;所述含铱化合物包括但不限于氯铱酸、氯铱酸钾、三氯化铱中的一种或多种,所述硝酸盐包括但不限于硝酸钠、硝酸铵、硝酸钾中的一种或多种,所述混合液中尿素与含铱化合物的摩尔比为1~100:1、硝酸盐与含铱化合物的摩尔比为1~100:1;本发明制备的介孔氧化铱具有超高比表面积,有利于活性位点的暴露和优化了反应过程中的传质,有效降低质子交换膜电解水阳极催化剂的贵金属载量。
Resumen de: US2025186304A1
A hydrogen generation device includes a tubular tank and a top lid combined with the tank. An immersion tube in which a hydrogen generating agent package is stuffed is placed in the tank. The hydrogen generating agent package is submerged in water after water is poured in the tank to generate hydrogen, which is released through a tank opening of the tank. The hydrogen generating agent package accommodates hydrogen generating agent powders including calcium oxide and aluminum powders, both of which are mixed and wrapped with a nonwoven fabric, as well as a little catalytic sodium carbonate added inside. For inhibition of free radicals and promotion of metabolism, the hydrogen generation device is further provided with a connector and a hose for a skin-care instrument, a nasal mask, an eye shield or an ear cleaner through which hydrogen is supplied as required.
Resumen de: CN118374814A
The invention discloses a device for preparing arsine through double-anode electro-catalysis and application, the device comprises a cathode electrolytic bath and two anode electrolytic baths arranged on the two sides of the cathode electrolytic bath, the cathode electrolytic bath and the anode electrolytic baths are separated through diaphragms, and anode catalysts are tightly attached to the side faces, facing the anode electrolytic baths, of the diaphragms; a cathode electrode is inserted into the cathode electrolytic bath and is connected with the negative electrode of the power supply through a wire, and the two anode catalysts on the two opposite sides of the two diaphragms are connected in parallel through wires and are connected with the positive electrode of the power supply. According to the invention, a dual-channel anode electrolytic bath structure is designed, and the capacity of transferring protons by reaction is regulated and controlled by increasing the quantity of the anode electrolytic bath and the anode catalyst, so that the current density of the reaction is directly improved, on one hand, the oxygen generation rate of the anode is improved, and on the other hand, the generation of cathode arsine is accelerated.
Resumen de: CN120119267A
本发明提出一种高盐矿井水井下原位电解制氢系统及方法,涉及高盐矿井水处理与资源化利用技术领域,方法包括高盐矿井水的收集及处理、矿井水的水质分析与二次处理、高盐矿井水井下原位电解制氢、固体杂质脱盐及井下原位充填、高浓盐水回流循环电解和氢能存储与状态监测六个步骤,本发明能够满足井下复杂环境对系统小型化、防水、防尘、防腐蚀要求,实现高盐矿井水的井下原位电解制氢;同时,产生的固体杂质直接在井下废弃巷道、采空区进行原位充填,节省了杂质外排运输能耗,消除了杂质外排地表生态环境污染破坏风险;此外,根据矿井水的离子类型调整阴极和阳极材料,以确保电极具有良好的耐腐蚀性、导电性和稳定性,提高矿井水的电解制氢效率。
Resumen de: CN120119271A
本发明公开了一种制备系统,涉及燃气制备技术领域,包括氢气制备组件和氧气制备组件,氢气制备组件包括第一容器、阴极件和阳极件,阴极件和阳极件间隔设于第一容器。氧气制备组件包括第二容器和催化剂,第二容器与第一容器管路连通,催化剂位于第二容器,并用于催化第一容器反应制氢之后的溶液以制备氧气。第一容器制氢反应之后的电解液可排入第二容器,与第二容器中的催化剂混合之后可反应产生氧气,氧气可排出被收集。可见,本发明的氢气和氧气分别在不同的容器中制备得到,不会混合在一起,也不需要使用质子交换膜阻隔氢气和氧气,节省成本。
Resumen de: CN120119283A
本发明涉及一种碱性体系电解水阳极催化剂及其制备方法,是将泡沫镍浸渍在含有硫脲和氯化亚铁的水溶液中,70~100℃下反应,通过硫化及湿化学过程,在泡沫镍基底上形成富含硫化物‑氧化物纳米颗粒的混合层,制备得到的复合催化剂S‑NiFeOxHy/NF。本发明采用简便高效方法制备了S掺杂的NiFe(氧)氢氧化物自支撑阳极析氧反应催化剂,作为碱性体系电解水阳极催化剂,具有优良的电化学反应活性和稳定性。
Resumen de: CN120120358A
本发明涉及一种抗海浪晃动的海上平台电解水制氢设备稳定装置,主要包括制氢集装箱、弹簧阻尼器、压力传感器、调节轮和驱动装置。本发明制氢集装箱的4个底角固定在弹簧阻尼器上,弹簧阻尼器安装在海上平台上;弹簧阻尼器上装有压力传感器;通过弹簧阻尼器可减轻制氢集装箱的晃动;通过压力传感器感知制氢集装箱的姿态,并通过驱动装置控制调节轮的转速和转向,从而调整制氢集装箱的重心,使用于海上平台的电解水制氢设备保持稳定。
Resumen de: US2025001352A1
The present disclosure relates to a pressure swing adsorption apparatus for high purity hydrogen purification from ammonia decomposition and a hydrogen purification method using the same, and more specifically, the pressure swing adsorption apparatus includes a plurality of adsorption towers including a guard bed unit and a hydrogen purification unit, in which each adsorption tower is packed with different adsorbents, to purify high purity hydrogen from mixed hydrogen gas produced after ammonia decomposition, make it easy to replace the adsorbent for ammonia removal, minimize the likelihood that the lifetime of the adsorbent in the hydrogen purification unit is drastically reduced by trace amounts of ammonia, efficiently recover hydrogen of the guard bed unit, thereby maximizing the hydrogen recovery rate compared to a conventional pressure swing adsorption process including a pretreatment unit and a hydrogen purification unit, and respond to a large change in ammonia concentration in the raw material.
Resumen de: CN120119264A
本发明专利公开了一种电解液复合添加剂及其在电解水(海水)中的应用,属于电解水(海水)制氢技术领域;该电解液复合添加剂为含氧酸盐中的一种和苯甲酸钠的组合;复合添加剂中含氧酸盐在电解液中的浓度为5‑50mmol/L,苯甲酸钠在电解液中的浓度为0.1‑5.0mmol/L;在电解水(海水)制氢技术电解液中使用本发明的复合添加剂,可以起到提升电解水(海水)催化剂抗腐蚀性和稳定性的作用,有效抑制催化剂活性位点的损失和失活。该复合催化剂对电解水(海水)制氢领域中的镍基催化剂具有普适性。本发明对于电解水(海水)制氢技术的降本增效具有重大的意义,具有广阔的推广应用前景。
Resumen de: CN120119285A
本发明公开了一种用于直接电解海水制氢储能的具有氮掺杂硫化钴异质结构的析氧反应电催化剂及其制备方法,制备时以泡沫镍为基底,泡沫镍基底上形成自支撑氢氧化钴纳米片;将负载氢氧化钴纳米片的泡沫镍在硫化物溶液中浸泡,得到负载硫化钴的泡沫镍片;将负载硫化钴的泡沫镍片置于等离子辅助化学气相沉积系统中,用氮等离子体进行掺杂得到具有氮掺杂硫化钴异质结构的电催化剂。本发明的电催化剂中的分层异质结构具有大的比表面积、高的面负载量,掺杂的氮改善材料的导电性;在海水电解氧析出体系中,过电位较低,电流密度较大,具有优异的析氧反应催化活性;另外催化剂在海水电解环境中具有出色的稳定性和耐久性。
Resumen de: CN120119278A
本发明公开了一种利用绞合焊丝结合等离子喷丝工艺制备电解水Ni基合金电极涂层的方法、产品与应用,属于材料表面工程技术领域,包括以下步骤:将镍丝和铝丝绞合后得到绞合焊丝,利用等离子喷丝工艺于电极基体上制备Ni‑Al涂层,再将所述Ni‑Al涂层经热处理后去合金化,即得到所述电解水电极涂层。本发明还公开了上述制备方法制备得到的电解水镍基合金电极涂层及其在电解水中的应用。本发明有效解决了传统等离子喷涂粉末工艺存在的成本较高和存在安全隐患等问题。相较于现有技术,本发明中的丝材进料方式成本更低,为电极材料的制备提供了一种更为高效、安全的技术途径。
Resumen de: CN119243213A
The invention relates to the technical field of electro-catalysis hydrogen evolution, and discloses a preparation method and application of a double-gradient self-supporting hydrogen evolution electrode. The preparation method comprises the following steps: forming an oxygen-containing hydrophilic group on the surface of conductive carbon cloth to obtain pretreated carbon cloth; a metal organic framework composed of Co and dimethylimidazole grows on the surface of the pretreated carbon cloth in an in-situ self-growth mode, the metal organic framework forms triangular protrusions on the surface of the pretreated carbon cloth, roasting is conducted, and a geometric gradient electrode is obtained; and covering the surface of the geometric gradient electrode with a mask distributed with a plurality of through holes, applying a hydrophobic and aerophilic coating on the surface of the geometric gradient electrode through the through holes, and forming a plurality of hydrophobic and aerophilic areas on the surface of the geometric gradient electrode. By adopting the preparation method disclosed by the invention, the overpotential and the overpotential growth rate of the electrode under high current density can be effectively reduced.
Resumen de: US2025188631A1
An embodiment water electrolysis catalyst includes iridium oxide including a rutile phase and iridium-nickel oxide including a hexagonal phase. An embodiment method of preparing a water electrolysis catalyst includes preparing a mixture including an iridium precursor, a nickel precursor, and cysteamine hydrochloride, drying the mixture, grinding the dried mixture, and firing a ground product, wherein the water electrolysis catalyst includes iridium oxide including a rutile phase and iridium-nickel oxide including a hexagonal phase.
Resumen de: CN120119277A
本发明公开了一种高效稳定电镀析氢电极及其制备方法与应用,所述制备方法包括以下步骤:S1:准备导电基底材料,并对其进行预处理;S2:配制电镀液,包括溶剂、镍盐、次磷酸盐、缓冲剂以及络合剂;S3:以所述电镀液为电解液,以预处理后的导电基底材料为工作电极,进行三电极沉积,获得所述高效稳定电镀析氢电极。本发明制备的电极为无定形结构的磷酸盐材料,有着更大的催化界面以及更多的反应活性位点,且由于其开放的活性孔道形成渗透性通道,有利于离子或小分子的快速扩散;通过电化学参数协同作用能够使其具备在大电流密度下长时间稳定的能力。本发明制备方法操作简单,成本低廉,设备及工艺条件要求低,易于工业化大规模生产。
Resumen de: DE102023212354A1
Elektrolysesystem mit einem Stack (1), der einen Anodenraum (2) und einen Kathodenraum (3) aufweist und der dazu eingerichtet ist, Wasser elektrolytisch in Wasserstoff und Sauerstoff aufzuspalten, wobei der Kathodenraum (3) einen Einlass (9) und einen Auslass (10) aufweist. Dem Stack (1) ist ein Gas-Flüssig-Separator (11) zugeordnet, der über eine Ausleitung (12) mit dem Auslass (10) des Kathodenraums (3) verbunden ist und in dem Flüssigkeit von Gas getrennt wird, wobei der Gas-Flüssig-Separator einen Gasauslass (13) zum Abströmen des abgetrennten Gases aufweist. Der Gasauslass (13) mündet in einen zentralen Gas-Flüssig-Separator (25) zur Trennung von Flüssigkeit und Gas.
Resumen de: WO2025116600A1
Disclosed is a catalyst for a hydrogen evolution reaction or a hydrogen oxidation reaction, which can be used under alkaline conditions and has significantly improved kinetic properties compared to conventional commercially-available platinum catalysts. The present invention provides a catalyst for electrochemical hydrogen reactions under alkaline conditions, which has 2 to 20 ruthenium atoms supported in an ensemble form on the surface of a molybdenum carbide-carbon nanocomposite support, and a manufacturing method therefor, and a ruthenium-based catalyst electrode comprising the catalyst, which can be used as an electrode for anion exchange membrane-based water electrolysis cells and fuel cells.
Resumen de: KR20250084095A
신재생에너지 기반의 그린수소 생산 시스템 및 방법을 제공한다. 신재생에너지 기반의 그린수소 생산 시스템으로서, 전력계통; 재생에너지 기반의 전력을 생성하는 재생에너지 제공파츠; 및 상기 전력계통, 상기 재생에너지 제공파츠 중 적어도 어느 한 곳으로부터 전력을 공급받고, 기 설정된 고순도의 수소생산을 수행하는 수소 생산파츠를 포함한다.
Resumen de: CN120115163A
一种三功能非晶态/晶态Rh(OH)3/NiMoO4异质结电解水催化剂的制备方法及其应用,其具体步骤包括:以泡沫镍作为基底,硝酸镍作为镍源、钼酸钠作为钼源、尿素作为络合剂,加入水中形成混合溶液,通过水热法制备NiMoO4纳米花;再将三氯化作为铑源,使其溶解在水中形成溶液,并将NiMoO4浸入其中,在黑暗条件下静置12小时后干燥,即得催化剂。Rh(OH)3/NiMoO4在泡沫镍基底上生长均匀,材料的活性位点暴露较多,导电性能增强,三维纳米花结构使其与碱性电解液充分接触,在电解水过程中不易被腐蚀且更加稳定,并且铑和镍钼合金的协同效应改善了电解水反应动力学,对提高电解水性能具有重要作用。
Resumen de: CN120117655A
本发明提供了一种硫化铋/钨酸铋/三氧化钨光阳极及其制备方法和光电催化析氢的应用,首先通过化学浴沉积法在FTO基底上生长WO3纳米片,然后将Bi2WO6利用溶剂热法负载在WO3的表面制得Bi2WO6/WO3,之后通过阴离子交换法制得Bi2S3/Bi2WO6/WO3复合薄膜。该光阳极在碱性电解液中表现出高效的光电催化水解产氢性能,偏压辅助模拟太阳光照射下的光电催化水解产氢量达到330μmol/h以上,太阳能电池辅助户外太阳光照射下的光电催化水解产氢量达到260μmol/h以上。本发明通过原位生长形成Bi2WO6/WO3异质结构,并通过简单的阴离子交换法将Bi2WO6/WO3硫化,硫化铋/钨酸铋/三氧化钨三元异质结的协同作用发挥出优异的光电催化产氢性能,且在24h光电流响应测试中保持良好的稳定性。
Resumen de: WO2024058606A1
The present invention relates to a method for preparing a NiMo-MoO3-x porous nanorod catalyst on the basis of a metal-organic framework and a non-precious alloy catalyst prepared thereby. The method for preparing a non-precious alloy catalyst according to the present invention can produce an alloy catalyst retaining excellent HER performance close to that of a commercial platinum catalyst by forming porous nanorods with a wide surface area having a combination of an alloy and an oxide.
Resumen de: CN120119292A
本发明公开了一种基于滑模控制的碱液电解槽脉冲电流制氢电路及控制方法,该电路通过设计滑模控制器实现滑模控制方法,以为碱液电解槽提供脉冲电流进行电解制氢;该电路中,电压源的正极与开关管的集电极相连,电压源的负极与快恢复型二极管的正极、碱液电解槽的负极相连,开关管的发射极与电感的第一端、快恢复型二极管的负极相连,电感的第二端与碱液电解槽的正极相连;通过滑模控制器得到占空比,利用占空比和三角载波调制得到开关管基极上的控制信号,经过电感输出脉冲电流,并将其提供给碱液电解槽进行电解制氢。本发明能够显著降低输出电流纹波,提高电能质量,进而提升电解效率。
Resumen de: US2025187912A1
A catalyst includes a ruthenium metal loaded on a support, wherein the support has a chemical formula of AxB(1-x)Oy. A is an alkaline earth metal, B is aluminum, zinc, cerium, manganese, or a combination thereof, x is 0.05 to 0.50, and y is chemical stoichiometry. The catalyst may further include an auxiliary agent loaded on the support. The catalyst can be used to decompose gaseous ammonia.
Resumen de: CN120119282A
本发明涉及电解水催化剂技术领域,公开了一种复合催化剂及其制备方法、电解水析氢催化电极和电解水析氢的方法,所述制备方法包括:在载气的存在下,将含有S空位的过渡金属硫化物与非金属源进行焙烧;所述非金属源选自磷源、碳源、氮源和硒源中的至少一种;其中,沿载气流动方向,非金属源置于含有S空位的过渡金属硫化物的上游。该制备方法能够有效调节催化剂的电子结构,制得的催化剂具有较高的HER活性。
Resumen de: CN119013421A
The hydrocarbon feed stream is exposed to heat in the absence of oxygen to convert the hydrocarbon feed stream into a solid stream and a gas stream. The gas stream is separated into an off-gas stream and a first hydrogen stream. The carbon is separated from the solids stream to produce a carbon stream. The water stream is electrolyzed to produce an oxygen stream and a second hydrogen stream. Iron ore is reduced to produce iron by flowing hydrogen through the iron ore. The iron and a first portion of the carbon in the carbon stream are combined to produce steel. At least a portion of the oxygen in the oxygen stream and a second portion of the carbon in the carbon stream are combined to produce electrical energy and a carbon dioxide stream.
Resumen de: JP2025087142A
【課題】 水の分解効率が高く、耐久性に優れる水分解用光触媒固定部材およびその製造方法を提供する。【解決手段】 水分解用光触媒固定部材は、金属多孔質体と、該金属多孔質体に固定される複合めっき皮膜と、を備える。該複合めっき皮膜は、金属成分とめっき用光触媒粒子とを含むめっき液を用いためっき処理により形成され、該金属成分の金属を含む皮膜部と、該めっき処理において共析した該めっき用光触媒粒子を有する水分解用光触媒粒子と、を有する。水分解用光触媒固定部材の製造方法は、金属成分とめっき用光触媒粒子とを含むめっき液を調製するめっき液調製工程と、調製した該めっき液を用いて、金属多孔質体を電解めっき処理または無電解めっき処理することにより、該めっき用光触媒粒子を共析させるめっき処理工程と、を有する。【選択図】 なし
Resumen de: CN120119266A
本发明公开了一种氧化钌掺杂氧化钼/氢氧化镍全pH电解水催化剂的制备方法,本发明公开了一种氧化钌掺杂氧化钼/氢氧化镍全pH电解水催化剂的制备方法,属于催化材料制备技术领域。氧化钌掺杂氧化钼/氢氧化镍制备方法包括以下步骤:首先将钼盐与十二烷基苯磺酸钠水溶液混合后,置入泡沫镍基底;随后通过水热反应,接着在还原气氛中进行煅烧处理;最后将煅烧产物浸渍于RuCl3溶液,制得自支撑型异质结催化剂RuOx‑MoO3/Ni(OH)2。本发明通过过渡金属钼/镍基材料与贵金属氧化钌团簇的复合结构设计,有效解决了传统钌基催化剂活性低、稳定性差的技术瓶颈。所获催化剂在宽pH范围内均表现出优异的析氢反应(HER)活性及长期稳定性。
Resumen de: CN120115174A
本专利申请公开一种氮掺杂多孔碳担载RuCo Janus颗粒催化剂的制备方法及其应用,涉及新材料技术领域;该制备方法包括以下步骤:将钴金属盐和2‑甲基咪唑溶解在去离子水溶液中,离心分离,洗涤干燥后得到ZIF‑67前驱体。将所得的ZIF‑67前驱体置于保护气氛下,在700℃下煅烧2h反应得到Co/NC纳米材料。将钌盐水溶液加入到去离子水溶液中,通入气体除氧,加入煅烧后得到的Co/NC纳米材料,搅拌置换,离心分离,洗涤干燥后得到目标产物。本申请提供的纳米复合材料表现出优异的催化活性,具有比表面积大、孔隙率高、金属纳米颗粒尺寸小等特点。
Resumen de: CN120119273A
本申请涉及电解水制氢领域,公开了一种电解水用的电解槽气室及碱性电解槽,电解槽气室包括依次叠合的支撑网、阳极、阳极侧隔网、隔膜、阴极侧隔网、阴极、支撑网,所述阳极侧隔网、阴极侧隔网为带孔的孔板、带孔的网格或具备透气性的层,通过阴极侧隔网、阳极侧隔网分隔电极和隔膜,产生电极上气体排出的空隙,同时又保证了电极、支撑网等电解槽内部叠层的紧密性,使得本申请的电解水制氢的碱性电解槽同时兼具较低的接触电阻和气泡电阻,并且保证了所得气体的质量。
Resumen de: CN120117572A
本发明公开了一种碱性水电解制氢用纯化系统及其纯化控制方法,包括气液分离器、脱氧塔、氢气冷凝器、干燥塔、氢气冷却器和过滤器;所述气液分离器的出口与所述脱氧塔的进口密封连通,且将分离掉碱液后的氢气送入至脱氧塔中进行脱氧处理;所述脱氧塔的出口经氢气冷凝器与所述干燥塔的进口密封连通,且将脱氧后的氢气经氢气冷凝器排除多余水分后,再送入至干燥塔中进行干燥处理;所述干燥塔的出口经氢气冷却器与所述过滤器的进口密封连通,且将干燥后的氢气经氢气冷却器排除剩余水分后,再送入至过滤器进行过滤处理,并得到高纯度的氢气。本发明采用PID调节法来调节脱氧塔以及干燥塔温度,相具有稳定性,且更加准确,避免超调现象的发生。
Resumen de: CN120118261A
本发明提供一种基于不同长度模块单元构建的2D COFs材料及其制备方法与应用,该材料由BABE单体和均苯三甲醛或苯并1,2‑b:3,4‑b':5,6‑b'三噻吩‑2,5,8‑三醛反应制备得到。本发明2D COFs材料的制备方法包括将BABE单体、三角形醛基单体和有机溶剂加入派热克斯管,超声混合,得混合物;在混合物中加入催化剂,超声混合,将派热克斯管放入液氮浴中经过冷冻,解冻,循环脱气后,用火焰枪对派热克斯管封管;派热克斯管温度降到室温,放入烘箱加热晶化,加入浸泡溶剂,索提,真空干燥后,得2D COFs材料。采用本发明制备的2D COFs材料通过减小分子链的长度,缩短电子传输距离,抑制光生电子与空穴的复合,增强光催化性能,提高光催化效率。
Resumen de: WO2025116392A1
One embodiment of the present invention relates to a hydrogen production reactor for producing hydrogen by decomposing ammonia. The hydrogen production reactor comprises: a housing; at least one reaction tube provided inside the housing and having an inlet into which a reactant containing ammonia flows in: a heating unit for providing heat to the reaction tube; a preheating unit provided in the reaction tube and extending in one direction; and a catalyst layer positioned downstream of the preheating unit and extending in one direction, wherein the preheating unit is filled with an oxide containing magnesium oxide (MgO).
Resumen de: KR20250082175A
본 발명은 수전해용 촉매 및 이의 제조방법에 관한 것으로서, 산소발생반응(Oxygen Evolution Reaction, OER)의 활성이 증대된 수전해용 촉매 및 이의 제조방법에 관한 것이다.
Resumen de: KR20250082600A
본 개시는 수전해 평가 장치에 관한 것으로, 본 개시의 일 측면에 따른 수전해 평가 장치는 평가대상 수전해 장치에 물 또는 수용액을 공급하고, 상기 평가대상 수전해 장치로부터 배출되는 산소 배출물이 유입되는 제1 탱크; 상기 제1 탱크로부터 배출되는 산소 기체가 공급되는 제1 열교환기; 상기 제1 열교환기로부터 배출되는 배출물이 공급되는 제1 기액 분리기; 상기 평가대상 수전해 장치로부터 배출되는 수소 배출물이 유입되는 제2 열교환기; 및 상기 제2 열교환기로부터 배출되는 배출물이 공급되는 제2 기액 분리기;를 포함할 수 있다. 본 개시의 일 측면에 따른 수전해 평가 장치는 i) 열교환관의 표면에 핀이 배치되는 스파이럴 열교환기를 포함하고, ii) 상기 열교환기로부터 배출되는 배출물이 중력 방향으로 유입될 수 있도록 하는 기액분리관을 포함하는 기액분리기를 포함함으로써, 전기분해 후 잔존하는 미반응 물 또는 수용액을 최대한 감소시켜 전기분해 후 생성되는 수소(H2)와 산소(O2)의 양을 보다 정확하게 측정할 수 있고, 궁극적으로 수전해 장치의 성능을 보다 정밀하게 측정할 수 있다.
Resumen de: KR20250083003A
본 발명은 비대칭성 이온 채널 유닛을 포함하는 이온교환막에 관한 것으로, 상기 이온교환막은 점진적 공극 직경을 갖는 비대칭성 공유결합성 유기 골격 구조체(COF)으로 이루어진 이온 채널 유닛을 포함함에 따라, 이온전도도와 이온선택도가 모두 우수한 이온교환막을 제조할 수 있다.
Resumen de: PL450397A1
Przedmiotem zgłoszenia jest przedstawiony na rysunku układ do kompresji wodoru, który składa się z elektrolizera, sprężarki i zbiornika do magazynowania, przy czym sprężarka realizuje kompresję wodoru w dwóch fazach: — fazie I kompresji - do magazynowania wodoru w zbiornikach oraz — fazie II kompresji - do tankowania urządzeń wodorem. Wynalazek znajduje zastosowanie w tworzeniu stacji tankowania aut wodorowych, magazynowaniu energii oraz transporcie i logistyce.
Resumen de: KR20250082877A
본 명세서는 니켈 폼 지지체; 및 상기 니켈 폼 지지체 상에 구비된 코어-쉘 촉매 입자;를 포함하고, 상기 코어-쉘 촉매 입자의 코어부는 니켈 금속을 포함하고, 쉘부는 구리 산화물을 포함하는 암모니아 산화용 촉매 전극 및 이의 제조방법에 관한 것이다.
Resumen de: KR20250082014A
수전해 또는 연료전지에 사용되는 일체형 재생 연료전지가 개시된다. 본 발명의 일 실시예에 따른 일체형 재생 연료전지는, 수전해 또는 연료전지에 사용되는 것으로, 전기화학 반응이 발생되고, 일방향으로 연장된 길이를 갖는 원통형의 셀유니트와, 상기 셀유니트와 인접하고, 상기 셀유니트와 상기 일방향으로 나란히 연장되는 유로를 포함할 수 있다. 본 특허출원은 하기 기관의 지원사업의 도움으로 작성되었다. 과제관리(전문)기관명 인천테크노파크 연구사업명 2023년 미래자동차 부품 기술개발 지원사업 연구과제명 연료전지/수전해시스템에 동시 사용 가능한 차량용 MEA 개발 기여율 1/1 과제수행기관명 제로테크놀로지 연구기간 2023.05.01. ~ 2023.11.30.
Resumen de: AU2023402507A1
A method of recycling a waste catalyst coated membrane, wherein the waste catalyst coated membrane comprises a membrane including a membrane ionomer, a first catalyst layer disposed on one side of the membrane, the first catalyst layer comprising a first catalyst and a first catalyst layer ionomer, and a second catalyst layer disposed on an opposite side of the membrane, the second catalyst layer comprising a second catalyst and a second catalyst layer ionomer. The method is configured to recover the first and second catalyst layer ionomers in addition to the catalyst materials and membrane ionomer.
Resumen de: KR20250082094A
복수의 단위셀과 분리판이 적층된 구조로 이루어지며, 전해질 용액의 전기분해 반응으로 수소와 산소를 생산하는 수전해 스택; 상기 수전해 스택에 공급되는 상기 전해질 용액을 순환시키는 순환 펌프; 상기 수전해 스택으로부터 배출되는 가스와 전해질 용액의 혼합물로부터 가스와 전해질 용액을 분리하고, 상기 분리된 전해질 용액을 보관하는 제1 전해질 탱크; 및 상기 제1 전해질 탱크로부터 배출되는 전해질 용액을 가열하여 승온시키고, 상기 승온된 전해질 용액을 보관하는 제2 전해질 탱크;를 포함하는, 수전해 시스템이 개시된다.
Resumen de: JP2025086209A
【課題】メタン合成の際に用いる触媒の劣化を抑制しつつ、メタン製造システムを高効率で動作維持可能に制御することを可能とする。【解決手段】メタン製造方法は、供給された電気エネルギーを用いて水電解装置における水電解により水素を生成する工程と、生成された水素と、二酸化炭素とをメタン合成装置において反応させてメタンを製造し、メタンを製造する際に発生した反応熱を前記水電解装置に伝導させる工程と、前記メタン合成装置の温度が、予め設定された目標温度となるように前記水電解装置に供給する電気エネルギー量を調整する工程と、を備える。【選択図】図3
Resumen de: CN120099551A
本发明提供一种MnOx修饰的NiCoP纳米片阵列材料及其制备方法。本发明提供一种MnOx修饰的NiCoP纳米片阵列材料及其制备方法,包括以下步骤,将钴盐和2‑甲基咪唑溶于去离子水后,加入泡沫镍,室温反应得到Co‑MOF前驱体;然后将前驱体加入到镍源溶液中,室温静置得到NiCo‑LDH;将无水次磷酸钠和NiCo‑LDH共同置于氩气气氛中并加热,获得NiCoP纳米片阵列;最后将NiCoP纳米片阵列置于含有锰源的均匀溶液,通过电沉积,最后获得MnOx修饰的NiCoP纳米片阵列材料。纳米片阵列的三维结构可充分暴露活性位点,同时MnOx修饰可提高材料的导电性、调控电子结构,从而提高电解水本征活性。实践表明,该材料作为电解水电极材料应用时,表现出优异的过电位和稳定性。
Resumen de: JP2025086206A
【課題】メタン製造システムを高効率で動作維持可能に制御することを可能とする。【解決手段】メタン製造方法は、供給された電気エネルギーを用いて水電解装置における水電解により水素を生成する工程と、生成された水素と、二酸化炭素とをメタン合成装置において反応させてメタンを合成し、メタンを合成する際に発生した反応熱を前記水電解装置に伝導させる工程と、前記水電解装置から自己発熱によって発生する余剰熱量と前記メタン合成装置から前記水電解装置に伝導した熱エネルギー量の合計が、前記水電解装置における水電解反応において必要となる熱エネルギー量と等しくなるように前記水電解装置に供給する電気エネルギー量を調整する工程と、を備える。【選択図】図3
Resumen de: CN120094637A
本发明公开了一种硫化铟锌催化剂及其制备方法与应用,属于催化材料技术领域,通过加入十二烷基硫酸钠作为表面活性剂,通过一步水热法制备出超薄的具有面外压电性质的硫化铟锌,所得到的S‑Zn‑S‑In‑S‑In‑S的结构与现有技术中通过化学气相沉积法和热硒法制备得到的S‑Mo‑Se的Janus结构不同,但同样具有z方向不对称性。本发明的制备方法为一步水热法,能耗低且制备工艺得到了极大的简化。另外,本发明加入SDS可以有效增加ZnIn2S4的硫空位,优化ZnIn2S4(001)晶面的产氢势垒,激活(001)面为产氢活性位点,缩短载流子迁移途径,进而实现光‑压电协同催化。
Resumen de: CN120099564A
本发明提供了一种图灵催化剂及其制备方法与应用和膜电极反应器。该图灵催化剂的制备方法包括:通过使M靶材和N靶材共同溅射,在衬底表面沉积形成M‑N薄膜;其中,M为Ru、Os、Rh、Ir、Pd、Pt、Ag、Au中的一种或多种;其中,N为Zn、Si、Al、Pb中的一种或多种;将M‑N薄膜置于碱性溶液中进行蚀刻,得到图灵催化剂。根据本发明制备得到的图灵催化剂具有较高的质量活性和良好的稳定性,且其组成成分单一,能够解决现有技术中稀缺贵金属的回收性和可持续性受到阻碍的问题。
Resumen de: CN120099549A
本发明涉及水电解制氢技术领域,具体公开了一种避免电化学腐蚀的碱性水电解制氢系统及控制方法。碱性水电解制氢系统包括以下结构:电解槽、氢分离器、氧分离器、碱液循环泵、冷却器、纯水罐、稀碱罐、浓碱罐、纯水泵、过滤器1、过滤器2、控制阀1、控制阀2、控制阀3、控制阀4、控制阀5、控制阀6、控制阀7、控制阀8、控制阀9、流量计、温度计1、温度计2、KOH浓度监测仪、KOH微量分析仪、压力控制器1、压力控制器2、液位控制器1、液位控制器2、管线。本发明可解决碱性水电解电解槽的贵金属电极和多元合金电极在待机状态下的电化学腐蚀问题,延长电解槽寿命;可解决碱性水电解制氢系统碱液的在线监测和自动补碱问题。
Resumen de: CN120099555A
本发明公开了一种结合碳纳米管和硼化物介导的高效稳定的碱性析氢电催化剂及其制备方法与应用。所述电催化剂包括金属活性相、金属氧化物活性相、硼氧化物基体相、碳纳米管支撑和载体;所述碳纳米管支撑生长在载体上,所述金属活性相以纳米颗粒形式弥散分布于金属氧化物活性相和硼氧化物基体相表面,所述金属氧化物活性相和硼氧化物基体相混合分布,且均负载于生长有碳纳米管支撑的载体上。本发明基于同时优化本征活性、活性位点的密度和可及性以及电荷和物质传输特性,以硼化物和碳纳米管为媒介的高活性碱性析氢电催化剂的催化性能优于贵金属Pt催化剂,且具有优异的稳定性。
Resumen de: CN120101130A
本发明公开了一种基于氨分解分级燃烧的低NOx燃烧系统和方法,所述基于氨分解分级燃烧的低NOx燃烧系统包括氨储罐、氨分解装置、空气源和燃烧装置,燃烧装置包括一级燃烧区和二级燃烧区,氨分解装置的出口与一级燃烧区气体入口相连,空气源通过空气泵分别与一级燃烧区、二级燃烧区的气体入口相连,一级燃烧区为富燃区,二级燃烧区为贫燃区。通过利用该系统,液氨经减压后进入氨分解装置分解成氨气、氢气和氮气的混合气;混合气与空气混合成一次风后进入一级燃烧区进行燃烧,剩余空气由二次空气进口进入二级燃烧区进行燃烧。通过结合氨分解与富燃‑贫燃分级燃烧技术,实现氨的稳定燃烧,降低NOx排放和防止氨逃逸。
Resumen de: CN120097461A
本发明属于净水技术领域,公开了一种净水装置。该净水装置包括机壳、过滤组件、富氢杯和出水结构,过滤组件设置于所述机壳内,所述过滤组件用于过滤水;至少部分所述富氢杯外露于所述机壳,所述富氢杯上设置有出水口以及用于连通纯水源的进水口;所述出水口与所述出水结构连通,所述出水结构用于供水。至少部分富氢杯外露在机壳外,能够给用户直观体验,提高用户满意度;至少部分富氢杯外露,还能够在富氢杯故障时及时发现,有利于对富氢杯进行维护。
Resumen de: CN120097458A
本发明属于净水处理技术领域,公开了一种净水设备。净水设备包括机壳和富氢模块,所述富氢模块包括内腔以及设置于所述内腔内的电极,所述电极用于电离水产生氢离子,所述富氢模块包括与所述内腔连通的进水口和出水口,所述进水口用于通入液体,所述出水口用于向外供水;至少部分所述富氢模块由透明材料制成且位于所述机壳外,以使电离过程中产生的气泡由所述净水设备的外部可见。净水设备能够制备富氢水,以供用户使用;制氢过程中产生的气泡能够由净水设备外部看到,提高用户饮用富氢水的直观体验,从而满足用户使用需求。
Resumen de: CN120099554A
本发明涉及一种Ir‑Co3O4V(Co)纳米片电催化剂的制备方法及在PEMWE阳极中的应用。该催化剂通过简单的水热‑浸渍合成方法制备,其由许多小于100 nm的纳米片团聚在一起所组成,并且含有金属Co空位和Ir单原子及团簇,表现出超高的酸性水裂解活性和稳定性。将使用本发明制备得到的催化剂用于PEMWE阳极中,仅需要0.3mgIr/cm2,在1.65V‑1.7V即可达到1A/cm2的电流密度,并在500mA/cm2~1000mA/cm2下表现出超过3000小时的超长稳定性,在保证催化剂优异电解水性能和稳定性前提下,大大降低了贵金属的含量,实现电解水制绿氢技术的降本增效。
Resumen de: CN120094604A
本发明涉及氨分解制氢领域,公开了一种氨分解催化剂及其制备方法和一种氨分解制氢的方法。该催化剂包括载体和负载在载体表面的贵金属氧化物;所述载体包括惰性金属氢氧化物和第四周期过渡金属氧化物,其中,所述载体呈片状结构,所述第四周期过渡金属氧化物负载在所述片状结构的边缘。所述催化剂具有优异的氨分解反应催化活性,在低温(500℃)下,氨气转化率可达99%以上,是一种新型的高效氨分解制氢催化剂。
Resumen de: CN120097494A
本发明公开了一种富氢水制备装置及其制备方法,本发明涉及富氢水制备技术领域,包括制备箱,以及固定连接在制备箱下表面的底座;进水机构,该进水机构用于将水流灌入制备箱的内腔中,通过设置进水机构,可以将通过饮水机过滤和净化好之后的饮用水注入制备箱的内腔中,并在水流流动的过程中,可以将制备箱顶部漂浮的氢气重新带入制备箱的底部,进而在完成水流注入的过程中加快氢气的溶解速率的效果;搅动机构,该搅动机构用于在搅动的过程中将氢气排入水流之中,通过设置搅动机构,可以在工作的过程中,对制备箱内腔中的饮用水进行搅动,并在搅动的过程中,利用离心力的作用,在对饮用水搅动的过程中,达到使氢气充分溶解在水中的效果。
Resumen de: CN120099576A
本发明公开了一种制备合金颗粒负载的纳米片状Hf‑Ni2P‑Fe2P‑FeNi3/NF复合电催化材料的方法。通过优化制备工艺,实现了一步制备磷化物与合金的复合纳米材料。首先,采用传统的溶剂热方法合成了高价铪离子掺杂的NiFe‑LDH/NF前驱体(Hf‑NiFe‑LDH/NF)。然后,将Hf‑NiFe‑LDH/NF与一定量的次亚磷酸钠在氩氢混合气氛中进行化学气相热解反应,最终获得Hf‑Ni2P‑Fe2P‑FeNi3/NF纳米材料。该制备方法通过实验条件的筛选,确定了最佳反应物及反应条件,并通过简单易操作的一步化学气相热解实现了磷化物纳米片与合金颗粒互嵌的结构。整个制备过程操作简便、结构均匀性易于保证以及成本相对可控,对合成掺杂金属离子‑二元金属磷化物‑合金复合纳米结构具有一定的技术启示。
Resumen de: CN120099574A
本发明公开了一种铁钴镍粒子@碳核壳结构电催化剂及其制备方法和在电催化析氧反应中的应用,属于电催化技术领域。该电催化剂的制备方法包括:(1)将十六烷基三甲基溴化铵、九水硝酸铁、六水硝酸钴、四水合乙酸镍分散于油酸溶剂中并混合均匀,油浴加热并离心后得黑色粉末;(2)黑色粉末置于烘箱中干燥得到前驱体粉末;(3)将前驱体进行退火处理最后可获得核壳结构的该电催化剂。本发明制备的铁钴镍粒子@碳核壳结构作为一种高效的析氧催化剂具有优异的析氧性能。本发明制备的铁钴镍粒子@碳核壳结构电催化剂作为一种高效的析氧催化剂具有优异的析氧性能。
Resumen de: CN120105714A
本发明公开一种基于动态模型的碱性电解槽分钟级运行方法,该方法将电化学模型、三阶热力动态模型和三阶氧中氢动态模型集成到一个统一的优化框架中,以电解功率、碱液流量、冷却液流量和电解槽压力为控制量,以一分钟为调度间隔,通过多重打靶法将微分约束离散化后求解优化问题,优化目标综合考虑了电解功率跟踪精度、温度稳定性等多个方面。突破了传统15‑60分钟运行周期的局限,实现与风电系统分钟级互动响应,可有效解决可再生能源并网过程中的功率波动问题,在保证系统安全性的前提下最大化碱性电解槽的负载范围,对提升可再生能源消纳能力和电网运行稳定性具有重要的工程应用价值,本发明考虑了更精细的控制变量,可为系统运行提供更实际的建议。
Resumen de: CN120099570A
本发明公开了一种氮原子掺杂碳材料负载超细金属纳米簇催化剂及制备和应用,属于电解水制氢领域。本发明利用软模板制备了表面富含介孔和微孔结构的UIO‑66(Ce)作为前驱体,随后对其进行碳化,酸洗处理得到高比表面积的三维氮掺杂多孔碳球。该碳材料表面丰富的多级孔道结构可以有效限制金属活性中心在高温还原和HER反应过程中的聚集,提高了催化剂的长期稳定性。而极高的比表面积可以使其负载更多的金属活性中心以提高催化活性。实验表明,氮掺杂可以有效调控活性中心的电子结构,提高其催化活性和稳定性。
Resumen de: CN120099567A
本发明公开了基于真空互联的碳化钼催化剂及制备方法、应用,催化剂包括碳化钼薄层,以及至少在所述碳化钼薄层的表层形成的由氧化过程形成的氧化物MoxCyOz,其中x=1,y=0‑0.5,z=0‑3,氧化物至少选自钼碳氧物种和/或钼氧物种和/或积碳物种。在真空互联的前提下,实现了碳化钼碱性HER预催化剂的本征性能,并且通过可控的氧化工艺有效地提升了碳化钼催化材料的HER性能。
Resumen de: AU2023369983A1
The present invention relates to stack module with at least one Solid Oxide electrolysis stack that comprises a plurality of stacked Solid Oxide electrolysis cells, wherein the stack module comprises two gas inlet connections and two gas outlet connections. According to the invention, the at least one Solid Oxide electrolysis stack is encapsulated in a metal container, wherein the two gas inlet connections and the two gas outlet connections are attached to the metal container. The invention further relates to Solid Oxide Electrolyzer with at least one stack module and a method of exchanging a stack module of a Solid Oxide Electrolyzer.
Resumen de: US2025188630A1
An oxynitride catalyst includes NiaMbNcOd, wherein M is Nb, Mn, or Co, a>0, b>0, c>0, d>0, and a+b+c+d=1. A hydrogen evolution device includes an anode and a cathode dipped in an electrolyte, and the anode includes the oxynitride catalyst. The oxynitride catalyst can be disposed on a support. The oxynitride catalyst may have a polyhedral structure.
Resumen de: CN120099540A
本发明涉及再生气体生成装置技术领域,尤其是一种气体纯化设备使用的再生气体生成装置,包括PEM水电解模块和混合气体箱,所述混合气体箱的输入端连接有N2供给阀门和H2供给阀门,所述H2气体分离器的输出端与气体压缩泵相连接。通过H2供给阀门、PEM电解模块之间的配合,当压力降到设定的基准压力以下时,PEM电解模块会重新供电,并将氢气与氮气混合后供给P‑Gas储存容器,从而为气体净化装置的再生过程提供所需的再生气体,该装置通过水电解过程产生氢气并与外部供应的氮气混合,能够高效且连续地支持气体净化装置的再生需求,避免了传统的高压氢气储罐及外部气体供应的复杂性。
Resumen de: CN120099562A
本发明涉及催化剂技术领域,具体提出了一种用于工业水电解的低载量贵金属催化剂及其制备方法。该制备方法以薄层二维层状双氢氧化物(LDH)为基底材料,在一定温度和压力下水热反应负载贵金属(Ru,Rh,Pd,Ag,Ir,Pt,Au等),再经过水洗,除去杂质离子,烘干后得到目标产物,得到的电催化剂为超低载量贵金属负载的LDH,其中贵金属的负载量占比为0.1 wt%‑0.5 wt%,制备得到的电催化剂能够实现工业级电流密度的高效稳定水分解。所得电催化剂具有高催化活性和工业条件下的耐久性;而且制备工艺操作简单,重复性好,大幅降低贵金属的负载量。
Resumen de: CN120099602A
本发明属于新能源材料技术领域,公开了一种在室温下通过光辅助电沉积法合成的中高熵自支撑氧反应催化剂的制备方法及其应用。该方法通过将泡沫镍进行裁剪、清洗处理后,将其作为工作电极,在含有特定金属盐和还原剂的电解液中,利用三电极体系,在光照和恒定电压条件下进行电沉积,经洗涤干燥后得到催化剂。本发明解决了现有技术中析氧反应催化剂在电解海水过程中效率低、耐腐蚀性差的问题,提供了一种具有优异催化活性和抗腐蚀性能的中高熵自支撑氧反应催化剂,适用于电解海水制氢领域,同时实现提高电解效率和降低能耗的效果。
Resumen de: CN120099568A
本发明涉及一种纳米球状NiFe‑LDH@M@Cu析氧复合材料及其制备方法与应用,所述复合材料包括铜基底,所述铜基底上设置有金属功能层M,所述金属功能层M上设置有NiFe‑LDH活性层,所述NiFe‑LDH活性层包括纳米球状的NiFe‑LDH。所述金属功能层M包括防腐蚀功能层,所述防腐蚀功能层上还设置有催化结构层。本发明通过在预处理的铜基底上依次沉积金属功能层M、NiFe‑LDH活性层得到。其中,防腐蚀功能层可增强基材的耐腐蚀性,催化结构层可增加催化剂的活性表面并为催化层提供支撑,同时也能保留铜的高导电性,纳米球状的NiFe‑LDH具有较大的活性表面积。与现有技术相比,本发明制备的NiFe‑LDH@M@Cu具有低成本、高性能、结构稳定的优势,适用于工业条件上大规模应用。
Resumen de: CN120099573A
本发明公开了一种铁钴镍粒子/碳纳米复合材料催化剂及其制备方法和在电催化析氧反应中的应用,属于电催化技术领域。该催化剂的制备方法包括:(1)在聚乙烯吡咯烷酮溶液中加入九水硝酸铁、六水硝酸钴、四水合乙酸镍制备均匀分散的溶液;(2)将分散液置于烘箱中干燥得到前驱体粉末;(3)将前驱体进行退火处理最后可获得核壳结构的该催化剂。本发明制备的铁钴镍粒子/碳复合材料作为一种高效的析氧催化剂具有优异的析氧性能。本发明制备的铁钴镍粒子/碳纳米复合材料作为一种高效的析氧催化剂具有优异的析氧性能。
Resumen de: CN120099577A
本发明属于电催化材料技术领域,具体涉及一种Pt单原子负载非晶/结晶NiFe LDH电催化材料、制备方法与应用。本发明主要以导电泡沫镍为自支撑载体,通过恒压电沉积制备ac‑NiFe LDH前驱体,再通过循环伏安电沉积将Pt‑SAs负载到ac‑NiFe LDH上以获得Pt‑SAs/ac‑NiFe LDH电催化材料。本发明公开的制备工艺简易,能够高效利用贵金属材料并且降低成本,适合于工业化制备电催化剂,解决了目前其他合成技术复杂和成本高而不能满足电解碱性淡水和海水产氢的工业化生产问题。本发明合成的电催化剂在工业电流密度下具有远优于商业Pt/C的HER和、RuO2(+)||Pt/C(‑)的全电解水性能,具有工业化电化学水分解的应用潜力。
Resumen de: CN120094219A
本发明涉及一种氨分解产物分离纯化装置及方法,且涉及氨加工的技术领域;包括纯化釜,纯化釜内分为纯化区以及高温处理区;纯化装置设于纯化釜中的纯化区内,纯化装置包括安装框,安装框内沿高度方向滑动安装有吸附杂质的分子筛吸附板;纯化釜的高温处理区内还安装有对分子筛吸附板进行高速震动的清理部件;本发明能够解决现有技术中存在的以下问题:首先现有装置通过高温加热再生的方式来保证分子筛吸附板的吸附性能,但是在高温加热再生的过程中,一些杂质吸附在分子筛吸附板表面仅仅通过高温难以将其清理;其次,现有技术通过层层纯化的方式提高氢气纯化效果,但是会造成混合气体穿过分子筛吸附板的效率变慢,从而影响其提纯的效率。
Resumen de: CN120099579A
本发明涉及电催化材料领域,公开了一种多异质钴基硫化物电催化剂及其制备方法和应用。本发明的电催化剂是采用水热法结合高温煅烧热处理方法制备而成,其具体制备步骤为:采用水热反应将钴源、硫源按照比例混合制备二硫化钴,经过洗涤干燥后,置于管式炉中进行高温煅烧得到。该多异质钴基硫化物电催化剂在不同温度下处理所得样品表现出不同的晶体结构、不同的形貌特征,其结构为CoS2/Co3S4/CoS三相共存的多异质界面结构,采用本发明的多异质钴基硫化物电催化剂制备成电极材料,应用在电解水析氧的催化反应中,在电流密度为10 mA cm‑2时,该催化剂的过电势为230 mV,其表现出优异的电催化氧析出活性和耐久性。
Resumen de: CN120097460A
本发明属于净水技术领域,公开了一种净水机。该净水机包括机壳和富氢模块,富氢模块包括杯组件和富氢组件,所述杯组件底部设置有通孔;富氢组件可拆装设置于所述杯组件的底部,所述富氢组件包括反应腔以及设置于所述反应腔内的电极,所述通孔与所述反应腔连通,所述电极用于电离水产生氢离子,所述富氢组件设置于所述机壳外。杯组件和富氢组件可拆装连接,富氢组件设置于机壳外,以使富氢组件能够单独更换或维护,降低维护成本,提高用户的使用体验。净水机中富氢模块可以单独更换富氢组件,维护成本低;富氢模块位于机壳前侧,方便对富氢模块维护,提高用户使用体验。
Resumen de: CN120099583A
本发明公开了一种高性能过渡金属‑贵金属氧化物团簇异质结构析氧反应电催化剂及制备方法和应用,属于电化学催化技术领域。本发明的制备方法包括如下步骤:将贵金属氧化物与过渡金属羰基化合物混合后,在惰性气氛、100~400℃下进行热处理,即得;其中,贵金属氧化物包括二氧化铱或二氧化钌中的一种、两种或二者固溶体材料。本发明所提供的制备方法简单易控,容易规模化,同时制备而得的团簇异质结构析氧反应电催化剂具有优异的催化活性和稳定性,同时成本较低,可应用于电化学能量转换领域中,如作为质子交换膜电解水制氢的电催化剂。
Resumen de: CN120094610A
本发明涉及一种基于高真空射频等离子体改性Pt‑ZnIn2S4催化剂及其制备方法与应用。方法为:将贵金属铂盐原位负载在ZnIn2S4上,随后用高真空射频等离子体在一定氛围下对其进行表面改性,原位构建具有高度分散和高硫空位的Pt‑ZnIn2S4‑X催化剂。该原位刻蚀的改性方法,可有效避免其他改性方法如需添加酸、碱或是加入其它一些化学试剂避免催化剂而被二次污染或引入部分杂质,从而造成材料改性不均匀等不可控因素。此外,该等离子体处理是在超低大气压条件下进行的,可以有效地避免杂质对催化剂表面的污染和破坏,是一种具有广泛应用前景的制备具有高效废水产氢催化活性的Pt‑ZnIn2S4催化剂。
Resumen de: CN120099584A
本发明公开了一种PtRu纳米笼及其制备方法和应用,所述方法包括以下步骤:(1)将氯化钌和氯铂酸吸附到ZIF‑8上,形成PtRu@ZIF‑8复合材料;(2)在氢氩还原气氛下,对PtRu@ZIF‑8复合材料进行高温煅烧,使其还原为金属Ru和Pt,同时ZIF‑8分解产生的Zn与Ru和Pt形成金属间化合物,得到PtRuZn复合材料;(3)使用盐酸溶液选择性对PtRuZn复合材料进行刻蚀,去除Zn,从而得到具有笼状结构的PtRu纳米笼。本发明操作简便,能显著提升催化活性并大幅降低Pt用量。本发明材料适用于AEMWE,为开发低成本、高稳定性电解水制氢技术提供了新的解决方案。
Resumen de: CN120094608A
本发明公开了一种ZnO@ZnS@CuS三元纳米复合材料,制备方法和应用。上述ZnO@ZnS@CuS三元纳米复合材料,包括ZnO,通过硫化反应在ZnO上原位生长的ZnS层,以及原位生长在ZnS层上的CuS纳米颗粒。上述ZnO@ZnS@CuS三元纳米复合材料的制备方法,包括如下步骤:(1)将ZnO超声分散在水中,待分散均匀后,往其中加入硫代乙酰胺进行反应,反应后,离心、洗涤、干燥,得到ZnO@ZnS;(2)将ZnO@ZnS、硝酸铜和硫脲混合,反应后,离心、洗涤、干燥,得到ZnO@ZnS@CuS三元纳米复合材料。该复合材料作为光催化剂在光催化分解水制氢方面进行应用时,具有高的产氢能力和良好的循环稳定性。
Resumen de: CN120099566A
本申请具体公开了一种三维多孔泡沫镍钼合金材料制备方法及其应用,所述方法包括:S100、选取泡沫镍基体并进行清洗;S200、酸洗活化清洗后的泡沫镍基体;S300、对酸洗活化后的泡沫镍基体表面进行微观蚀刻;S400、对微观蚀刻后的泡沫镍基体进行电沉积,进而得到用于电解水制氢电极的三维多孔泡沫镍钼合金材料。本申请所制备得到的合金材料为三维多孔结构的镍钼合金材料,其主要成分为镍钼合金,因此,与现有制氢电极材料比较,镍钼材料的价格更低廉,三维多孔的结构使得该合金材料具有更高的孔隙率和比表面积,可使制氢电极有更多的析氢活性位点,催化活性更高,且镍钼合金结构稳定,能在碱性环境中长久保持催化活性。
Resumen de: CN120099569A
本发明公开了一种Ru‑CeO2/NC催化剂及制备方法和应用,属于电解水制氢领域。本发明通过软模板法、以及一步热解金属离子浸渍MOFs材料,制备得到了Ru‑CeO2/NC催化剂。该Ru‑CeO2/NC催化剂具有良好的导电性、稳定性和催化活性;电化学测试显示,本发明的Ru‑CeO2/NC催化剂在10 mA/cm²时仅需20 mV的过电势,远低于商业20wt% Pt/C催化剂的50 mV。
Resumen de: CN120099556A
本发明公开了一种p区金属掺杂的层状双金属氢氧化物电极及其制备方法与应用,所述p区金属掺杂的层状双金属氢氧化物电极包括金属基底和沉积于所述金属基底上的p区金属掺杂的层状双金属氢氧化物催化剂;所述p区金属掺杂的层状双金属氢氧化物催化剂包括p区金属和层状双金属氢氧化物;所述p区金属选自铝、镓、锡和铟中的一种或者几种。本发明通过简单、可控、温和的一步电沉积法,最短可在一分钟内完成,制备得到的p区金属掺杂的层状双金属氢氧化物电极尺寸、形状可调,作为OER阳极可满足实际应用中不同电解槽规格的需求并用于电解水制氢,能够提高整体电解水制氢的活性和稳定性,具有巨大的应用潜力。
Resumen de: CN120099578A
本发明属于催化剂技术领域,具体涉及一种在Cu MOF中内嵌棒状二氧化铈的CeO₂/CuO复合催化剂制备方法和应用。该CeO₂/CuO复合催化剂可用于水分解中析氢析氧催化反应。该制备方法在合成的过程中以N,N‑二甲基甲酰胺作为溶剂,引入了铜源、均苯三甲酸和聚乙烯吡咯烷酮K15‑19作为作为形貌调控剂和配位剂,并在合成的过程当中添加不同含量的二氧化铈纳米棒。通过适当的控制反应条件,Cu MOF原位均匀地生长并包裹在二氧化铈纳米棒周围,形成在Cu MOF中内嵌棒状二氧化铈并具有八面体形貌的材料,通过煅烧处理形成CeO₂/CuO复合催化剂。该制备方法得到形貌均一可控,具有超高分散度和良好两相接触的CeO₂/CuO复合催化剂,能够有效提高催化性能。同时,该方法具有制备简单、工艺可控、成本低廉等优点。
Resumen de: CN120098278A
本发明涉及光催化材料技术领域,尤其涉及一种锡聚七嗪酰亚胺及其制备方法与应用。所述锡聚七嗪酰亚胺的制备方法包括步骤:将氮化碳前驱体进行热聚合反应,得到聚合物氮化碳;将聚合物氮化碳在氯化盐熔盐作为熔盐模板的条件下进行热聚合反应,随后经过盐酸酸化,得到锡聚七嗪酰亚胺;其中所述氯化盐熔盐包括无水二氯化锡熔盐。通过本发明所述制备方法制备得到的锡聚七嗪酰亚胺具有高结晶性和宽光谱响应范围,大大拓宽了光催化材料的光吸收范围,有望实现高效的近红外光活性,可最大限度的利用太阳光,从而获得高的光催化分解水产氢活性。
Resumen de: CN120099565A
本发明公开了具有亲气梯度孔阵列结构的泡沫镍析氢电极构建方法;本发明所述的具有亲气梯度孔阵列结构的泡沫镍析氢电极,其工艺在于:一、电极预处理,先将泡沫镍表面构建4×4等间距梯度孔,然后将泡沫镍电极基底依次使用无水乙醇、盐酸、去离子水超声清洗;二、疏水涂层溶液的制备:首先取适量的正己烷至于烧杯中,再按比例往里加入聚二甲基硅氧烷(PDMS)和硅橡胶固化剂,随后进行超声震荡处理直至溶液充分混合,随后往混合液里添加疏水气相纳米SiO2颗粒,再超声振荡至均匀分散;三、将分散好的疏水涂层浆料均匀喷涂于泡沫镍梯度孔内部;四、使用两电极体系电沉积亲气处理后的泡沫镍制作析氢电极。
Resumen de: CN120099557A
本发明公开了一种半胱胺修饰的电解硫化氢催化材料及其制备方法与应用,所述制备方法包括以下步骤:S1:配制半胱胺溶液,并获取待修饰纳米材料,所述待修饰纳米材料为电解硫化氢催化材料;S2:将所述待修饰纳米材料浸泡在所述半胱胺溶液中,直至将半胱胺修饰到所述待修饰纳米材料表面;S3:取出修饰后的纳米材料,干燥后获得所述半胱胺修饰的电解硫化氢催化材料。本发明能够用半胱胺修饰电解硫化氢催化材料,形成具有优良界面传质性能的界面,加快传质速度,提高电解硫化氢的催化性能。
Resumen de: CN117285004A
The invention provides a ubiquitous light-gathering catalytic hydrogen production device and method and application. The ubiquitous light-gathering catalytic hydrogen production device comprises a hydrogen production unit, an artificial light-gathering light source unit and an electric power adjusting unit, the hydrogen production unit comprises a reaction tank and is used for preparing hydrogen and oxygen through artificial photocatalytic decomposition of water; the artificial condensation light source unit comprises a reflection assembly and a plurality of light-emitting assemblies, the light-emitting assemblies are used for emitting artificial light, and the reflection assembly is used for reflecting and gathering the artificial light into the reaction tank; the electric power adjusting unit is used for providing electric energy for the artificial condensation light source unit. According to the invention, electric power is converted into artificial light of a single wave band, artificial photocatalytic hydrogen production is carried out in a condensation mode, and the device is suitable for various electric power hydrogen production energy storage with fluctuation characteristics, especially hydrogen energy storage of low-price and negative-price electric power such as renewable energy power generation electric energy, valley electricity, abandoned electricity and the like.
Resumen de: US2025179655A1
A system (1) for generating hydrogen gas comprises a reaction vessel (101) containing an aqueous solution (102) and a cathode (105) and an anode (107) each positioned at least partly in the reaction vessel (101). The system (1) comprises first and second ultrasonic transducers (215-220) which emit ultrasonic waves in the direction of the cathode (105) and the anode (107) respectively. Each ultrasonic transducer (215-220) is driven by a respective transducer driver (202) to optimise the operation of the system (1) for generating hydrogen gas by sonoelectrolysis.
Resumen de: WO2025113866A1
The invention relates to a process (100) for the production of hydrogen from ammonia comprising the following steps: - providing a water feed stream to a water electrolyzer (101); - performing a water electrolysis (102) of the water feed stream in the electrolyzer, producing an oxygen product stream and an electrolysis hydrogen stream; - providing an ammonia feed stream to an ammonia cracking reactor (103); - providing an oxidant stream (105) and performing a combustion reaction (106) with said oxidant stream, thereby generating heat; - in the ammonia cracking reactor, performing an endothermic reaction of ammonia cracking (104) of the ammonia feed stream with said generated heat; characterized in that the oxidant stream comprises at least a portion of the oxygen product stream produced by the water electrolysis of the water feed stream.
Resumen de: US2025179658A1
In a method of producing metal borohydride, M(BH4)n, from metal metaborate, M(BO2)n, in which M is a metal, such as a metallic metal, an alkali metal, an alkaline earth metal, a transition metal or a chemical compound behaving as a metal, and n is a valence value of the metal, metal borohydride is formed through a reaction of metal hydride, MHn, with trimethyl borate, B(OMe)3, and metal trimethyl borate is formed through a reaction of boric acid, H3BO3, with methanol, MeOH, under removal of water, H2O. An electrochemical cell is used for the conversion of metal metaborate and water, H2O, to boric acid, in the electrochemical cell. The electrochemical cell has an anodic half-cell and a cathodic half-cell separated by a cation exchange membrane, and a solvent and water is provided to both the anodic half-cell and the cathodic half-cell. Metal metaborate is provided to the anodic half-cell, where acid ions, H+, and electrons, e−, are generated at the anode from electrolysis of water, and H reacts with metal metaborate and water. The cation exchange membrane passes metal ions, Mn+, from the anodic half-cell to the cathodic half-cell, and metal hydroxide, M(OH)n, is formed in the cathodic half-cell.
Resumen de: US2025179656A1
A method for controlling a hydrogen generation system includes controlling the potentials of an electrode for oxygen generation and an electrode for hydrogen generation included in an electrolyzer so that the potential change is smaller in the electrode for oxygen generation or the electrode for hydrogen generation having a larger deterioration rate than in the electrode having a smaller deterioration rate.
Resumen de: US2025179653A1
A system (1) for generating hydrogen gas comprises a reaction vessel (101) containing an aqueous solution (102) and a cathode (105) and an anode (107) each positioned at least partly in the reaction vessel (101). The system (1) comprises first and second ultrasonic transducers (215-220) which emit ultrasonic waves in the direction of the cathode (105) and the anode (107) respectively. Each ultrasonic transducer (215-220) is driven by a respective transducer driver (202) to optimise the operation of the system (1) for generating hydrogen gas by sonoelectrolysis.
Resumen de: US2025179666A1
Embodiments include a method for operating an electrolysis system. Aspects include supplying service water to a water treatment system and purifying and deionizing the service water in the water treatment system to create deionized water and ion-containing wastewater. Aspects also include supplying the deionized water from the water treatment system to an electrolyzer and supplying the ion-containing wastewater from the water treatment system to a cooling device. A waste heat generated by the electrolyzer is dissipated by the cooling device.
Resumen de: US2025179660A1
A method for controlling an organic hydride generation system includes controlling potentials in an anode electrode and a cathode electrode such that a potential change in an electrode having a higher deterioration rate among the anode electrode and the cathode electrode included in an electrolytic bath is smaller than a potential change in an electrode having a lower deterioration rate.
Resumen de: US2025179651A1
Disclosed is a method for operating an electrolysis plant for producing hydrogen and oxygen as product gases, wherein the oxygen product gas, which additionally contains hydrogen as a foreign gas, is fed from an electrolyser to a downstream gas separator, wherein when a predefined limit value for the hydrogen concentration in the oxygen product gas is exceeded, an inert gas (L) is fed to the gas separator such that the hydrogen concentration in the oxygen product gas is lowered. The invention further relates to a corresponding electrolysis plant.
Resumen de: US2025179010A1
Provide are a urea production method and a urea production apparatus in which hydrogen and oxygen are produced by electrolysis of water in an electrolysis unit, nitrogen is separated and recovered from air in an air separation unit, ammonia is synthesized in an ammonia synthesis unit using hydrogen from the electrolysis unit and nitrogen from the air separation unit as raw materials, carbon dioxide is produced by combusting a fuel in an oxycombustion unit while using at least the oxygen from the electrolysis unit, and urea is synthesized in a urea synthesis unit by using the carbon dioxide and the ammonia as raw materials.
Resumen de: US2025177939A1
Method for controlling an ammonia synthesis converter or a methanol synthesis converter during intermittent availability of a renewable power-dependent hydrogen feed, wherein under a limited or no availability of power the converter effluent is recycled back to the inlet of said converter in a loop, and heated to keep said converter in a hot stand-by mode wherein the temperature in the reaction space remains within a target range.
Resumen de: US2025179674A1
A system (1) for generating hydrogen gas comprises a reaction vessel (101) containing an aqueous solution (102) and a cathode (105) and an anode (107) each positioned at least partly in the reaction vessel (101). The system (1) comprises first and second ultrasonic transducers (215-220) which emit ultrasonic waves in the direction of the cathode (105) and the anode (107) respectively. Each ultrasonic transducer (215-220) is driven by a respective transducer driver (202) to optimise the operation of the system (1) for generating hydrogen gas by sonoelectrolysis.
Resumen de: US2025179977A1
This invention is about a hydrogen-generating device, with low energy consumption and high electrode durability, for diesel cycle engines. The hydrogen-generating device includes an electrolysis cell made of aluminum, containing heat exchanger fins on the outside, an electrolytic solution, two electrodes; a hydrogen transport system to be injected into the engine's air intake system; electronic module for direct voltage control, used in electrolysis, of the electrode polarity alternation time, of the volume of hydrogen in a mixture of constant hydrogen/oxygen composition to be injected into the engine in a variable manner, thus injecting a quantity of up to 10% of the hydrogen:oxygen mixture, in the ratio of 65:35, per liter of diesel consumed, in a volume/volume ratio.
Resumen de: US2025179675A1
A system (1) for generating hydrogen gas comprises a reaction vessel (101) containing an aqueous solution (102) and a cathode (105) and an anode (107) each positioned at least partly in the reaction vessel (101). The system (1) comprises first and second ultrasonic transducers (215-220) which emit ultrasonic waves in the direction of the cathode (105) and the anode (107) respectively. Each ultrasonic transducer (215-220) is driven by a respective transducer driver (202) to optimise the operation of the system (1) for generating hydrogen gas by sonoelectrolysis.
Resumen de: US2025179670A1
The invention relates to a method for operating an electrolyzer (10) for the production of hydrogen and oxygen, comprising a membrane (22), which is permeable to OH ions and separates an anode chamber (14) from a cathode chamber (16), said method comprising at least the following method steps:a) temporary dry operation of the cathode chamber (16),b) temporary diffusion of water molecules through the membrane (22) from the anode chamber (14) into the cathode chamber (16),c) variation of a differential pressure (42) between the cathode chamber (16) and the anode chamber (14) by means of a restrictor valve (46), andd) adjustment of the moistening/wetting of the cathode chamber (16) by adjusting a defined differential pressure (42).
Resumen de: US2025179673A1
A system (1) for generating hydrogen gas comprises a reaction vessel (101) containing an aqueous solution (102) and a cathode (105) and an anode (107) each positioned at least partly in the reaction vessel (101). The system (1) comprises first and second ultrasonic transducers (215-220) which emit ultrasonic waves in the direction of the cathode (105) and the anode (107) respectively. Each ultrasonic transducer (215-220) is driven by a respective transducer driver (202) to optimise the operation of the system (1) for generating hydrogen gas by sonoelectrolysis.
Resumen de: US2025179985A1
A system and method by which energy from ocean waves is converted into hydrogen, and that hydrogen is used to manifest electrical and mechanical energies by an energy consuming device. A portion of the generated electrical power is communicated to water electrolyzers which produce oxygen and hydrogen from water as gases. At least a portion of the generated hydrogen gas is transferred to a transportation ship via a hose-carrying, remotely operated (or otherwise unmanned) vehicle, and subsequently transferred to an energy-consuming module or infrastructure, where a portion of the hydrogen is consumed in order to manifest a generation of electrical energy, a mechanical motion, and/or a chemical reaction.
Resumen de: WO2025114716A1
A water-electrolyser anode for a proton exchange membrane (PEM) water electrolyser comprises: a transition metal oxychalcogenide catalyst having the formula ABxOy, wherein A is a transition metal and B is a chalcogenide, and wherein 0 < x < 2 and 0 < y < 2. Also provided are a proton exchange membrane (PEM) water electrolyser, a method of water electrolysis, use of a transition metal oxychalcogenide as a catalyst in an oxygen evolution reaction under acidic conditions, and a method of manufacturing an anode for an electrolyser.
Resumen de: US2025179671A1
A pressure control system for pressure control of at least two pressurized fluid systems comprises a duct for each fluid system having an inlet connectable to the respective fluid system and an outlet, a pressure control valve arranged within each of the ducts to control the fluid flow from the inlet to the outlet of the duct, wherein the pressure control valves are pilot-operated pressure relief valves having an inlet port for a pilot gas to affect a cracking pressure of the pressure control valves, wherein the pressure control system further comprises a common pilot gas buffer system, which is connected to each of the inlet ports of the pressure control valves for a simultaneous pressure control of the fluid systems.
Resumen de: US2025179672A1
A system (1) for generating hydrogen gas comprises a reaction vessel (101) containing an aqueous solution (102) and a cathode (105) and an anode (107) each positioned at least partly in the reaction vessel (101). The system (1) comprises first and second ultrasonic transducers (215-220) which emit ultrasonic waves in the direction of the cathode (105) and the anode (107) respectively. Each ultrasonic transducer (215-220) is driven by a respective transducer driver (202) to optimise the operation of the system (1) for generating hydrogen gas by sonoelectrolysis.
Resumen de: US2025179941A1
A thermal energy storage system with fluid flow insulation, the system including heated thermal storage blocks positioned within a housing, and a method for operating the thermal energy storage system, including providing a flow of fluid into the housing, the fluid convectively extracting heat from a top region, a side region and a bottom region of the thermal energy storage system, to generate heated fluid that insulates the thermal storage blocks from the housing and a foundation of the thermal energy storage system.
Resumen de: US2025179942A1
An apparatus includes one or more thermal storage blocks that define a radiation chamber and a fluid flow slot positioned above the radiation chamber to define a fluid pathway in a first direction. The apparatus includes a heater element positioned adjacent to the radiation chamber in a second, different direction, wherein the radiation chamber is open on at least one side to the heater element. The apparatus includes a fluid movement system configured to direct a stream of fluid through the fluid pathway in the first direction.
Resumen de: US2025179901A1
A method of producing hydrogen and sequestering carbon or sulfur includes generating a fluid including at least one of water, steam, hydrogen sulfide, carbon dioxide and heat as a byproduct of a surface facility and injecting the fluid into a subsurface formation. The subsurface formation can include a porous rock, in various forms of porosity such as intragranular, intergranular, fracture porosity. The method can further include heating the fluid to stimulate an exothermic reaction of the fluid with components of the subsurface rock formation and produce a hydrogen reaction product and one or more of sulfur minerals from the hydrogen sulfide or carbon minerals from the carbon dioxide. The fluid can be heated to between about 25° C. and about 500° C. The method can also include extracting the hydrogen produced from the reaction of the fluid with the subsurface rock formation and mineralizing sulfur or carbon in the porous rock.
Resumen de: AU2023396734A1
The present invention relates to an ammonia decomposition catalyst and a method for producing same and, more specifically, to an ammonia decomposition catalyst containing alumina (Al
Resumen de: WO2025114700A1
A process for preparing an oxygen evolution reaction (OER) catalyst comprises an oxygenated iridium component supported on a particulate solid support, which process comprising the steps of: (i) forming an aqueous mixture comprising a particulate solid support and a solution of a halide-free metal iridate; (ii) reducing the pH of the aqueous mixture to ≤ 5.0 to precipitate an oxygenated iridium component onto the particulate solid support; and (iii) isolating the product of step (ii).
Resumen de: JP2025085515A
【課題】高い効率で水素を発生させることができる鉄基粉末を提供する。【解決手段】Cu-Kα線を用いたX線回折の回折ピークの内、α-Fe結晶の(110)回折面に相当する回折強度曲線の半価幅が0.03°以上0.60°以下の範囲である水素製造用鉄基粉末。【選択図】なし
Resumen de: JP2025085516A
【課題】高い効率で水素を発生させることができる鉄基粉末を提供する。【解決手段】X線回折の回折ピークの内、α-Fe結晶の(110)回折面に相当する回折強度曲線から求められる格子面間隔が2.000Å以上2.100Å以下の範囲である水素製造用鉄基粉末。【選択図】なし
Resumen de: WO2025116392A1
One embodiment of the present invention relates to a hydrogen production reactor for producing hydrogen by decomposing ammonia. The hydrogen production reactor comprises: a housing; at least one reaction tube provided inside the housing and having an inlet into which a reactant containing ammonia flows in: a heating unit for providing heat to the reaction tube; a preheating unit provided in the reaction tube and extending in one direction; and a catalyst layer positioned downstream of the preheating unit and extending in one direction, wherein the preheating unit is filled with an oxide containing magnesium oxide (MgO).
Resumen de: WO2025116600A1
Disclosed is a catalyst for a hydrogen evolution reaction or a hydrogen oxidation reaction, which can be used under alkaline conditions and has significantly improved kinetic properties compared to conventional commercially-available platinum catalysts. The present invention provides a catalyst for electrochemical hydrogen reactions under alkaline conditions, which has 2 to 20 ruthenium atoms supported in an ensemble form on the surface of a molybdenum carbide-carbon nanocomposite support, and a manufacturing method therefor, and a ruthenium-based catalyst electrode comprising the catalyst, which can be used as an electrode for anion exchange membrane-based water electrolysis cells and fuel cells.
Resumen de: WO2025116572A1
The present invention relates to an electrode for water electrolysis for hydrogen production and a manufacturing method therefor. The manufacturing method according to the present invention achieves a simpler process compared with an existing iridium (IrO2) electrode manufacturing process, uses low thermal energy, shortens the time required for, especially, heat curing, facilitates the thickness adjustment of a coating layer, and can manufacture an electrode for water electrolysis at relatively low facility costs and manufacturing costs, and requires less time, labor, and energy to perform steps of the process. In addition, the electrode for water electrolysis obtained by the manufacturing method according to the present invention not only possesses generally required electrochemical stability and chemical resistance, but also exhibits high discharge efficiency of generated bubbles while preventing defects due to voids in an actual hydrogen manufacturing process.
Resumen de: KR20250080797A
본 발명은 수소 제조를 위한 수전해용 전극 및 이의 제조방법에 관한 것으로, 본 발명에 따른 제조방법은 기존 이리듐(IrO2) 전극 제조 공정에 비하여 공정이 단순하며, 사용되는 열에너지가 낮고, 특히 열경화에 소요되는 시간을 단축할 수 있고, 코팅층 두께 조절이 용이할 뿐 아니라, 비교적 적은 설비 비용 및 제조 비용으로 수전해용 전극을 제조할 수 있으며, 공정의 단계를 수행하는데 적은 시간, 노동력, 에너지를 요하는 장점이 있다. 또한, 본 발명에 따른 제조방법으로 제조되는 수전해용 전극은 통상적으로 요구되는 전기화학적 안정성, 내화학성을 구비할 뿐 아니라, 실제 수소 제조 과정에서 보이드로 인한 결함을 방지하면서 생성되는 기포의 배출 효율 또한 높다는 장점을 갖는다.
Resumen de: KR20250080012A
본 발명은 가역 고체산화물전지 시스템에 관한 것으로, 연료전지 모드에서 연료를 이용하여 전력을 생산하고, 수전해전지 모드에서 전력을 이용하여 수소를 생산하는 고체산화물전지와, 상기 고체산화물전지의 연료전지 모드에서 상기 고체산화물전지의 반응 후 가스의 열을 축열하고, 수전해전지 모드에서 축열된 열을 이용하여 상기 고체산화물전지에 공급되는 가스를 가열하는 열풍로형 열저장부를 포함할 수 있다.
Resumen de: WO2025116571A1
The present disclosure relates to a manufacturing method for a separator for water electrolysis having a superhydrophobic coating layer. The manufacturing method of the present disclosure not only has high efficiency of manufacturing the separator, but also can reduce manufacturing costs and ultimately product sales costs, and thus has excellent industrial utility value. In addition, the superhydrophobic separator according to the present disclosure has high efficiency of separating hydrogen and oxygen generated in a water electrolysis process, can stably maintain hydrogen purity, and has excellent performance in preventing oxygen from being mixed into hydrogen gas, and thus can fundamentally block the risk of explosion (fire).
Resumen de: WO2025116024A1
Provided is a catalyst for hydrogen generation comprising a mixture of tungsten carbide and cobalt, the catalyst for hydrogen generation being characterized in that the absolute value of the cathode current per mg of the catalyst is 0.10 mA/mg or more when the catalyst for hydrogen generation is loaded on a glassy carbon electrode and subjected to potential scanning at -1.2 V with respect to a silver/silver chloride reference electrode under nitrogen bubbling in a 1 mol/L sodium hydroxide aqueous solution.
Resumen de: WO2025111640A1
A polymer electrolyte membrane (PEM) electrolyser or fuel cell system for the extraction of hydrogen, the electrolyser or fuel cell system comprising first and second end plate assemblies provided at longitudinal and opposed ends of the electrolyser or fuel cell system with an electrolyser stack positioned between the first and second end plate assemblies; the electrolyser stack comprising a plurality of electrolyser cells wherein each cell comprises bi-polar contact plates separated by a catalyst-coated membrane or catalyst coated electrodes and wherein the electrolyser stack is located between a pair of current collectors; wherein each of said current collectors is arranged adjacent said first and second end plate assemblies respectively with a compression arrangement being located at each end of the fuel cell stack to apply a compressive force on each of the current collectors thereby clamping the plurality of bi-polar contact plates and the plurality of catalyst-coated membranes and/or catalyst coated electrodes therebetween to apply uniform pressure across the bi-polar contact plates, wherein the compression arrangement is further configured to be adjustable to vary contact pressure between the plurality of bi-polar contact plates.
Resumen de: WO2025116586A1
Disclosed are a catalyst electrode for ammonia water electrolysis and a manufacturing method thereof, the durability and catalytic activity of the catalyst electrode being improved by synthesizing platinum catalyst seeds through an ultrasonic treatment of a specific duration and inhibiting poisoning of a platinum catalyst by nickel hydroxide formed on the surface of a nickel support.
Resumen de: KR20250081605A
암모니아 수전해용 촉매 전극에 있어, 백금 등 귀금속 기반 촉매로서 귀금속의 사용량을 최소화하면서도 기존 귀금속 촉매에 비해 우수한 성능의 암모니아 수전해 촉매 전극과 이를 효과적으로 제조할 수 있는 방법이 개시된다. 본 발명은 금속 구조체 상에 층상 이중 수산화물(Layered Double Hydroxide, LDH)이 형성된 지지체 표면에 활성 금속 촉매가 전착(electrodeposition)된 암모니아 수전해용 촉매 전극 및 이의 제조방법을 제공한다.
Resumen de: KR20250080331A
본 발명의 일실시예는 전기분해용 전극촉매의 제조 방법 및 이를 이용한 수계 내 총 유기탄소의 저감 방법에 관한 것이다.
Resumen de: KR20250080796A
본 발명은 초소수성 코팅층이 형성된 수전해용 분리막의 제조방법에 관한 것으로, 본 발명의 제조방법은 분리막의 제조 효율이 높을 뿐 아니라 제조 비용 및 궁극적으로 제품 판매 원가를 절감할 수 있으므로 산업적 효용가치가 매우 우수하다. 또한, 본 발명에 따른 초소수성 분리막은 수전해 공정에서 발생하는 수소 및 산소의 분리 효율이 높고, 수소 순도를 안정적으로 유지할 수 있으며, 수소 가스로의 산소 혼입 방지 성능이 탁월하여 폭발(화재) 위험을 원천적으로 차단할 수 있는 장점이 있다.
Resumen de: KR20250079969A
본 발명은 물분해용 비스무스 바나데이트 광전극 박막 제조방법 및 상기 전극의 몰리브덴 도핑 방법에 관한 것이다. 본 발명의 몰리브덴(Mo) 도핑된 BiVO4를 포함하는 비스무스 바나데이트 박막은 BiVO4 타겟과 MoO3 타겟을 이용하여 스퍼터링 방법으로 기판상에 동시에 증착하여 제조되며, 이렇게 몰리브덴 도핑된 비스무스 바나데이트 박막은 전기화학적 특성, 안정성 및 장기간 사용 가능성이 향상되고, 간단한 방법으로 최적의 몰리브덴 도핑 농도를 파악하여 결정 가능하다.
Resumen de: DE102023211891A1
Die vorliegende Anmeldung betrifft Verfahren sowie eine Anlage (10) zur Aufbereitung eines Sauerstoffgases, welches mittels Elektrolyse von Wasser und/oder Wasserdampf erzeugt und als Oxidationsmittel in einer hüttentechnischen Einrichtung (1) eingesetzt wird, wobei das mittels der Elektrolyse erzeugte Sauerstoffgas wenigstens einem Trocknungsschritt unterzogen wird, über welchen die in dem Sauerstoffgas enthaltenen Begleitgase Wasserstoff und Wasser, vorzugsweise quantitativ, entfernt werden
Resumen de: WO2025114702A1
There is provided a an apparatus for the photolysis of a target material. The apparatus comprises a chamber arranged to receive a target material, at least one emitter arranged to emit an electromagnetic radiation signal at or towards the target material in use, an electromagnetic field generator configured to generate an electromagnetic field within the chamber in use, and a controller. The controller is configured to control the electromagnetic field generator to generate an electromagnetic field in the presence of the target material, such that the electromagnetic radiation signal emitted by the at least one emitter is incident upon the target material in the presence of the generated electromagnetic field.
Resumen de: US2025179663A1
A production unit for the production of hydrogen or ammonia by electrolytic decomposition of water, with an electrolysis unit supplied with electrical energy by a photovoltaic unit and connected on the media side to a water storage tank and on the output side to a hydrogen tank, is intended to enable a particularly reliable and fluctuation-insensitive use of a regenerative energy source. For this purpose, the production unit is designed for floating operation and comprises a balloon envelope forming a buoyant body which can be filled with a buoyancy gas and which is provided with a support structure for the water storage unit, the electrolysis unit, the photovoltaic unit and the hydrogen storage unit.
Resumen de: US2025179654A1
A system (1) for generating hydrogen gas comprises a reaction vessel (101) containing an aqueous solution (102) and a cathode (105) and an anode (107) each positioned at least partly in the reaction vessel (101). The system (1) comprises first and second ultrasonic transducers (215-220) which emit ultrasonic waves in the direction of the cathode (105) and the anode (107) respectively. Each ultrasonic transducer (215-220) is driven by a respective transducer driver (202) to optimise the operation of the system (1) for generating hydrogen gas by sonoelectrolysis.
Resumen de: WO2025114571A1
An electrolysis device configured to produce hydrogen gas from water, the electrolysis device comprising a container (4), the container accommodating an aqueous alkaline solution (5), a cathodic electrode (1), and an anodic electrode (2), an electrical current being selectively applied between the cathodic electrode and the anodic electrode, wherein the cathodic electrode and possibly the anodic electrode, is made of a nickel alloy, with a nickel base alloyed with at least one element chosen among chromium, molybdenum, cobalt and iron, wherein the cathodic electrode and the anodic electrode are manufactured by an additive manufacturing process, from respective first and second mixed metallic powder compounds, wherein the cathodic and anodic electrodes exhibit an outer surface comprising a plurality of first surface patterns (6,7).
Resumen de: WO2025114080A1
The invention relates to a process (100) for producing a synthesis product (6), in which gaseous hydrogen (3) is provided by electrolysis (10) of water (1) and is subjected to a reaction (30) with one or more gaseous reactants (4) to form the synthesis product (6), wherein during a first process mode, the hydrogen (3) and the one or more reactants (4) are mixed to obtain a gaseous reaction mixture (5) and the gaseous reaction mixture (5), or a part thereof, is stored under pressure in a storage unit (20), and wherein during a second process mode the gaseous reaction mixture (5), or a part thereof, stored under pressure in the first process mode is taken from the storage unit (20) and fed to the reaction (30) to form the synthesis product (6). The invention also relates to a corresponding plant.
Resumen de: US2025179652A1
A system (1) for generating hydrogen gas comprises a reaction vessel (101) containing an aqueous solution (102) and a cathode (105) and an anode (107) each positioned at least partly in the reaction vessel (101). The system (1) comprises first and second ultrasonic transducers (215-220) which emit ultrasonic waves in the direction of the cathode (105) and the anode (107) respectively. Each ultrasonic transducer (215-220) is driven by a respective transducer driver (202) to optimise the operation of the system (1) for generating hydrogen gas by sonoelectrolysis.
Resumen de: AU2023379422A1
Abstract An multi-stage electrolyzer cell is disclosed. The multi-stage electrolyzer cell comprises an anode, a cathode and at least one ion exchange membrane separating the anode and the 5 cathode. The anode and cathode are exposed in the respective anode chamber and cathode chamber. At least one partition is arranged within at least one of the anode and cathode chambers, dividing the at least one chamber into a plurality of process stages. Each of the partitions comprises a feed port, allowing an electrolyte solution to transport sequentially through each of the plurality of process stages. Means are arranged to 10 transport the electrolyte solution through each one of the plurality of process stages. A multi-stage electrolytic method is also disclosed.
Resumen de: EP4563350A1
An electrolysis device configured to produce hydrogen gas from water, the electrolysis device comprising a container (4), the container accommodating an aqueous alkaline solution (5), a cathodic electrode (1), and an anodic electrode (2), an electrical current being selectively applied between the cathodic electrode and the anodic electrode, wherein the cathodic electrode and possibly the anodic electrode, is made of a nickel alloy, with a nickel base alloyed with at least one element chosen among chromium, molybdenum, cobalt and iron, wherein the cathodic electrode and the anodic electrode are manufactured by an additive manufacturing process, from respective first and second mixed metallic powder compounds, wherein the cathodic and anodic electrodes exhibit an outer surface comprising a plurality of first surface patterns (6,7).
Resumen de: EP4563725A1
Es wird ein Verfahren (100) zur Herstellung eines Syntheseprodukts (6) vorgeschlagen, bei dem gasförmiger Wasserstoff (3) durch Elektrolyse (10) von Wasser (1) bereitgestellt und mit einem oder mehreren gasförmigen Reaktionspartnern (4) einer Umsetzung (30) zu dem Syntheseprodukt (6) unterworfen wird, wobei während eines ersten Verfahrensmodus der Wasserstoff (3) und der eine oder die mehreren Reaktionspartner (4) unter Erhalt eines Reaktionsgemischs (5) vermischt werden und das Reaktionsgemisch (5) oder ein Teil hiervon in einer Speichereinheit (20) druckgespeichert wird, und wobei während eines zweiten Verfahrensmodus das in dem ersten Verfahrensmodus druckgespeicherte Reaktionsgemisch (5) oder ein Teil hiervon aus der Speichereinheit (20) entnommen und der Umsetzung (30) zu dem Syntheseprodukt (6) zugeführt wird. Eine entsprechende Anlage wird ebenfalls vorgeschlagen.
Resumen de: EP4563523A1
The invention relates to a process (100) for the production of hydrogen from ammonia comprising the following steps:- providing a water feed stream to a water electrolyzer (101);- performing a water electrolysis (102) of the water feed stream in the electrolyzer, producing an oxygen product stream and an electrolysis hydrogen stream;- providing an ammonia feed stream to an ammonia cracking reactor (103);- providing an oxidant stream (105) and performing a combustion reaction (106) with said oxidant stream, thereby generating heat;- in the ammonia cracking reactor, performing an endothermic reaction of ammonia cracking (104) of the ammonia feed stream with said generated heat;characterized in that the oxidant stream comprises at least a portion of the oxygen product stream produced by the water electrolysis of the water feed stream.
Resumen de: AU2023359996A1
The invention relates to an electrolysis system (1) for generating hydrogen and oxygen as product gases, comprising an electrolysis module (3) and a process unit (5), wherein the process unit (5) has a reactant line (7) for supplying process water and a product line (9), each of which is connected to the electrolysis module (3), and the process unit (5) is equipped with a thermally insulating insulation device (11), comprising a thermal insulating material (17), such that a slow cooling of the process water is produced during a standstill operation.
Resumen de: AU2023359866A1
The invention relates to a plant network (100) comprising an electrolysis plant (1, 1A, IB), a power supply source (3) with a DC voltage output (7) and a central supply line (5), wherein the central supply line (5) is connected to the DC voltage output (7) of the power supply source (3), so that a direct current can be fed into the central supply line (5) and a central DC network designed for a high voltage is provided to which the electrolysis plant (1, 1A, IB) is connected via the central supply line (5). The power supply source (3) aass a power generator comprises a wind turbine (19) to which a rectifier (13A) with a DC voltage output (7) is connected, wherein the DC voltage output (7) is designed for the high voltage, and wherein a controllable energy storage system (17) is connected to the central supply line (5) which is designed in such a way, that a direct current can be fed into the central supply line (5) by means of the energy storage system (17) as required or can be discharged from the central supply line (5) and fed into the energy storage system (17). A DC supply network is implemented in the plant network (100) that enables application and control of three different DC voltage levels independently, with a first DC voltage provided as a storage battery voltage for charging and discharging an electrical storage battery of the energy storage system (17), with a second DC voltage provided as DC- Bus high voltage on the central supply line (5), and with a third DC
Resumen de: WO2024023030A2
A method of electrolysing hydrogen bromide comprising the steps i) synthesizing sulfuric acid such that hydrogen bromide is produced, ii) providing an electrolytic cell comprising an anode, a cathode, and a membrane sandwiched between the anode and the cathode, iii) feeding a first composition comprising hydrogen bromide and water to the anode, iv) feeding a second composition comprising hydrogen bromide and water to the cathode, and v) operating the electrolytic cell to produce hydrogen at the cathode.
Resumen de: WO2024023030A2
A method of electrolysing hydrogen bromide comprising the steps i) synthesizing sulfuric acid such that hydrogen bromide is produced, ii) providing an electrolytic cell comprising an anode, a cathode, and a membrane sandwiched between the anode and the cathode, iii) feeding a first composition comprising hydrogen bromide and water to the anode, iv) feeding a second composition comprising hydrogen bromide and water to the cathode, and v) operating the electrolytic cell to produce hydrogen at the cathode.
Resumen de: CN119604644A
A process for producing hydrogen and/or bromine by electrolyzing hydrogen bromide in the electrolysis of hydrogen bromide using a fluoropolymer membrane having a glass transition temperature Tg > = 110 DEG C, wherein the hydrogen bromide is derived from the bromination of hydrocarbons.
Resumen de: EP4563727A2
A method of operating an electrolyzer system includes providing steam from a steam source through a system steam conduit to module steam conduits located in respective electrolyzer modules, controlling a flow rate of the steam through the system steam conduit using a system mass flow controller located on the system steam conduit, providing portions of the steam to the module steam conduits and providing steam in the module steam conduits to respective stacks of electrolyzer cells located in respective hotboxes in the respective electrolyzer modules, and operating the stacks to generate a hydrogen product stream and an oxygen exhaust stream.
Resumen de: CN119604644A
A process for producing hydrogen and/or bromine by electrolyzing hydrogen bromide in the electrolysis of hydrogen bromide using a fluoropolymer membrane having a glass transition temperature Tg > = 110 DEG C, wherein the hydrogen bromide is derived from the bromination of hydrocarbons.
Resumen de: US2025171388A1
The disclosure provides a process for producing methanol and hydrogen from methane. The process of the disclosure comprises the steps of: •a) providing a gaseous feed stream comprising methane: •b) reacting said gaseous feed stream with at least one halogen reactant •under reaction conditions effective to produce an effluent stream comprising methyl halide, hydrogen halide •optionally poly halogenated alkanes •and optionally unreacted methane: •c) recovering said an effluent stream •d) reacting the recovered effluent stream with water and at least one organic base under reaction conditions effective to produce an aqueous solution of hydrogen halide •and a methanol stream comprising methanol (MeOH) and dimethyl ether (DME) and/or optionally unreacted methane, and, c) decomposing by means of electrolysis said aqueous solution of hydrogen halide under conditions effective to produce a gaseous hydrogen stream and a stream comprising halogen reactant.
Resumen de: US2025171388A1
The disclosure provides a process for producing methanol and hydrogen from methane. The process of the disclosure comprises the steps of: •a) providing a gaseous feed stream comprising methane: •b) reacting said gaseous feed stream with at least one halogen reactant •under reaction conditions effective to produce an effluent stream comprising methyl halide, hydrogen halide •optionally poly halogenated alkanes •and optionally unreacted methane: •c) recovering said an effluent stream •d) reacting the recovered effluent stream with water and at least one organic base under reaction conditions effective to produce an aqueous solution of hydrogen halide •and a methanol stream comprising methanol (MeOH) and dimethyl ether (DME) and/or optionally unreacted methane, and, c) decomposing by means of electrolysis said aqueous solution of hydrogen halide under conditions effective to produce a gaseous hydrogen stream and a stream comprising halogen reactant.
Resumen de: CN119698495A
A process for the production of hydrogen comprising the steps of: a) providing a starting mixture comprising bromine, water and a sulfur-containing compound, b) reacting the starting mixture provided in step a) to produce a reaction mixture effluent comprising sulfuric acid and hydrogen bromide, c) separating the reaction mixture effluent obtained in step b) into one or more hydrogen bromide-enriched compositions and one or more sulfuric acid-enriched compositions, where at least one hydrogen bromide-enriched composition contains up to 1,000 ppm sulfuric acid, where step c) comprises at least two distillation steps, d) separating the reaction mixture effluent obtained in step c) containing up to 1,000 ppm sulfuric acid, at least a portion of the at least one hydrogen bromide-enriched composition comprising at least one hydrogen bromide-enriched composition comprising at least 50,000 ppm sulfuric acid and at least 50,000 ppm sulfuric acid is subjected to electrolysis to obtain hydrogen and a bromine-containing composition wherein the electrolysis cell is operated at an operating temperature of at least 70 DEG C, and e) recycling at least a portion of the bromine-containing composition obtained in step d) back to step a).
Resumen de: EP4563524A1
The present invention relates to a method and device for producing hydrogen by dissociating the water molecule through thermochemical reactions, using a small amount of active material. The thermochemical reactions are induced by solar energy with a moderate concentration of up to 50 suns, which can be achieved through linear or parabolic concentrators.
Resumen de: EP4563494A1
The present invention provides a container and a hydrogen production system. The container includes a bottom base, an upper cover, a first side plate, and a driving device. The first side plate is arranged between the bottom base and the upper cover, and is connected to the bottom base and the upper cover separately; and the driving device is connected to the first side plate and is configured to drive the first side plate to rotate relative to the bottom base, and the first side plate drives the upper cover to move, to switch the container from a closed state to an open state. The container in the present invention can implement hoisting of a device, so that a process in which the device is placed in the container is simplified, and the design efficiency of the hydrogen production system is improved. In addition, it is convenient for personnel to enter the container for device overhaul and maintenance, thereby effectively resolving the problem of inconvenient maintenance on the device after the device is placed in the container.
Resumen de: EP4564633A1
Disclosed in the present application are a power system and a frequency modulation control method therefor. The method comprises: first, determining whether the current power grid frequency of a power system falls within a preset allowable frequency deviation range; if not, performing calculation according to the current power grid frequency and a power grid rated frequency to obtain an input current change value of a hydrogen production power generation unit in the power system; on the basis of the size relationship between the input current change value and limit values thereof and the size relationship between the changed input current value and limit values thereof, determining a target input current of the hydrogen production power generation unit; and finally, adjusting an input current of the hydrogen production power generation unit according to the target input current, so as to allow the power grid frequency of the power system to fall within the preset allowable frequency deviation range. Therefore, by means of the relationship between system power consumption and frequency fluctuation, the present application can guide input current setting for the hydrogen production power generation unit on the basis of a measured system frequency to achieve frequency modulation control of the power system, thus solving the problem of frequency fluctuation of power grid systems caused by randomness and fluctuation of renewable energy power generation.
Resumen de: DK202330316A1
An alkaline electrolyzer comprising a stack (17) of electrolytic cells (1) is used for producing hydrogen gas (8). Each of the cathode compartments (5) comprises a cathode gas outlet (23A) into a cathode electrolyte return conduit (22A), the downstream end (41) of which is connected to a hydrogen purifier (33) configured for providing purified hydrogen gas by removing oxygen from the gas received from the cathode electrolyte return conduit (22A). A cathode gas recirculation system (38) connects a downstream end of the hydrogen purifier (32,33) to an upstream end (40) of the cathode electrolyte return conduit (22A) for supplying purified hydrogen gas to the cathode electrolyte return conduit (22A). Alternatively, or in addition, each of the anode compartments (6) comprises an anode gas outlet (23B) into an anode electrolyte return conduit (22B), the downstream end (41) of which is connected to an oxygen purifier (33), configured for providing purified oxygen gas by removing hydrogen from the gas coming from the anode electrolyte return conduit (22B). An anode gas recirculation system (38) connects a downstream end (41) of the oxygen purifier (33) to an upstream end (40) of the anode electrolyte return conduit (22B) for supplying purified oxygen gas to the anode electrolyte return conduit (22B). By recirculating purified gases through the electrolyte return conduits, the electrolyzer can operated at part load, for example below 10% of the nominal load.
Resumen de: CN120082913A
本发明公开了硫掺杂镍钴铁层状双氢氧化物纳米片阵列催化剂及其制备方法和应用,首先对镍泡沫进行表面改性,在其表面生长分布均匀的NiCo LDH纳米片阵列,然后将其浸泡在含有铁离子和硫代硫酸钠的溶液中,得到S‑NiCoFe LDH纳米片阵列,制备出镍钴基自支撑OER电催化剂。这种电极材料的优势在于:三维多孔自支撑电极,无需有机粘合剂和支撑电极;原料为非贵金属,价格便宜,来源广泛。得到的镍钴基自支撑电极材料在1mol/LKOH中表现出良好的OER性能,该催化剂在100mA/cm2的过电位为283mV,进行48h稳定性测试后,催化剂性能没有明显衰减。
Resumen de: CN120082919A
本发明公开了一种钼镍合金‑氧化镍自支撑催化剂及其制备方法与应用,其制备方法包括将镍金属基片加入含Mo盐和尿素的混合溶液中进行溶剂热反应,镍基体的溶出提供Ni源并与Mo盐反应,在镍基体原位生长钼镍氧纳米片组成的纳米花瓣。而后将前驱体置于还原性气氛下进行保温反应,即得所述钼镍合金‑氧化镍自支撑复合析氢催化剂。该自支撑结构无需添加粘结剂有助于提升催化剂大电流循环稳定性,原位析出的方式极大的增加了MoNi4合金颗粒在NiO纳米片基体表面的分散度,提升了催化剂的导电性,并获得高的表面积和丰富的高活性的MoNi4‑NiO复合界面,同时异质界面的强电子耦合作用优化了MoNi4合金表面的氢吸附能和NiO表面的水解离活性,显著提升复合催化剂的碱性析氢活性。
Resumen de: CN120082921A
本申请提出一种g‑C3N4修饰的GaN纳米柱光电极材料、光阴极、光电化学电池及其制备方法和应用,在GaN纳米柱表面使用g‑C3N4进行修饰,不但拓宽了光电极材料的吸收光谱范围;g‑C3N4与GaN纳米柱形成了Z型异质结构,有效钝化纳米柱的表面态,有效地将GaN纳米柱导带中的电子转移到二维纳米片g‑C3N4的价带上,从而增加光电流密度,大大提升光电转换效率;为解决GaN纳米柱表面电荷复合带来的效率损失提供了有效的解决方案。且在用于光电化学电池在水分解制氢应用时,使用g‑C3N修饰GaN纳米柱还能够防止GaN纳米柱在电解质中的光电腐蚀,且g‑C3N4作为无金属电催化剂适用于可持续水分解系统,进一步增强了光电极的稳定性,改善了器件的整体光电性能。
Resumen de: CN120082892A
本发明公开了一种用于酸洗的清洗剂、电解装置以及酸洗方法。清洗剂包含螯合剂,能有效去除电解装置组件表面因腐蚀而产生的金属沉积物,提高酸洗的效率和质量,从而提高整体的氢气生产性能。本发明的电解装置集成了反应堆、氢气气液分离器、氧气气液分离器和清洁组件,其中,所述清洁组件连接所述反应堆、所述氢气气液分离器和/或所述氧气气液分离器,用于存储所述的用于酸洗的清洗剂,并在酸洗时为所述电解装置提供所述清洗剂,以能够高效地进行酸洗操作,提高生产效率。本发明的酸洗方法通过监测清洗剂中金属离子的浓度,既能够确保清洗剂在有效范围内使用,又能及时结束酸洗过程,避免过度消耗清洗剂、节约酸洗时间,同时确保酸洗效果。
Resumen de: CN120082924A
本发明属于催化电解水技术领域,涉及电解水的催化剂,涉及一种异质界面丰富的二硫化钌/铁镍硫化物/碳复合材料及其制备方法与其在催化电解水制氢中的应用。所述复合材料为纳米颗粒,包括金属硫化物以及负载所述金属硫化物的碳基质;所述金属硫化物由RuS2和(FeNi)S1.03形成异质结构,所述异质结构为晶体结构且晶粒尺寸为5~50 nm,两种晶粒的界面为异质界面。本发明通过液相螯合共沉淀法,先分散阳离子并得到均匀的前驱体沉淀物,再通过同步高温煅烧从而更好地构建丰富的异质结构。本发明提供的复合材料可同时高效催化析氢和析氧反应,并且在实验室电解池和商业AEM电解槽的应用中展现出良好的工业应用前景。
Resumen de: CN120079369A
本发明属于光催化材料技术领域,具体涉及一种K掺杂SrTiO3光催化剂及其制备方法和应用。本发明采用熔融盐介质,高温固相法制备SrTiO3,低温煅烧梯度掺杂K原子,原位分步光沉积法加载助催化剂,其可以应用于光催化全解水领域。相较于现有的光催化剂,本发明低温煅烧K掺杂SrTiO3光催化剂稳定性强,形成从表面到体相的浓度梯度,导致能带弯曲和梯度带隙结构,形成内建电场,驱动光生电子向表面迁移,空穴向体相扩散,显著提升电荷分离效率。低温掺杂过程减缓晶格应力积累,避免因K掺杂导致的晶格坍塌或缺陷聚集,确保梯度分布的稳定性。催化剂材料制备成本低,试剂无毒且产量高,符合目前所倡导的绿色环保理念,且具有广阔的应用市场。
Resumen de: CN120082920A
本发明公开了一种Ni/Ni(OH)2异质结纳米电催化剂的制备方法及其在制氢中的应用,所述方法为:制备低共熔溶剂;然后加入镍盐加热搅拌使镍盐充分溶解且无晶体析出;加入咪唑添加剂,搅拌均匀得到电解液;将电解液加入电解槽进行电沉积,阴极表面逐渐沉积形成均匀且紧密的Ni/Ni(OH)2异质结层;将阴极电极进行清洗、干燥、活化得到所述催化剂。本发明通过向氯化胆碱‑乙二醇低共熔溶剂体系中引入咪唑,采用电沉积技术,一次性实现了镍与氢氧化镍的同步沉积和界面结合,获得了Ni/Ni(OH)2异质结,避免了传统方法中的繁琐多步工艺,并且提高了催化剂催化析氢反应的高效性和长期稳定性,具有较好的可重复性和工业化潜力。
Resumen de: CN120082931A
本发明公开了一种PEM电解水制氢补水系统的控制方法,获取电解槽运行参数、水箱液位计示数和水箱温度、压力示数,计算出预测液位值和液位差值,得到水箱液位计示数的均方根误差;将预测液位值与补水液位范围进行比较,生成补水控制信号;将均方根误差与预设定值比较,生成一类故障判断信号;将液位差值与预设定故障液位范围比较,生成二类故障判断信号;根据补水控制信号,控制纯水机开关或打开排水;根据一类故障判断信号,发出故障提示或进行预测液位值修正;根据二类故障判断信号,发出异常提示、停机检查和/或正常运行。可见,本发明能够识别系统性偏差并及时诊断系统故障,避免潜在损害,有效优化补水过程,提升整体安全性和可靠性。
Resumen de: CN120082918A
本发明公开了一种自支撑氮化钼/硫化镍复合催化剂及其制备方法与应用。其制备方法包括运用溶剂热法,把碳布置于含有Mo盐与硫脲的混合溶液里,进行溶剂热处理,得到碳布上生长的自支撑MoS2纳米片,而后在乙酸镍溶液中浸渍,形成Ni离子插层的MoS2前驱物,干燥后于氨气气氛下氮化获得碳布上生长的二维Mo5N6/Ni3S2自支撑复合催化剂。此种原位耦合界面显著增强界面电子结构作用,从而优化吸附氢的吸脱附,获得增强的析氢动力学,同时自支撑的二维纳米片结构助于暴露大量的催化活性位点,从而获得优异析氢性能;且涉及的制备方法较简单,操作方便,适合推广应用。
Resumen de: CN120082355A
本发明公开了CPB/ZIFs复合材料、制备方法及应用,首先通过调节锌盐与2‑MIM的摩尔比以及添加不同浓度的活性剂,合成六角星状ZIF;然后,采用热注入法合成CsPbBr3钙钛矿量子点(CPB);最后,通过使用正己烷作为溶剂,先溶解CPB,再加入ZIF,通过超声波和磁力搅拌的方法形成复合物,二者之间形成Pb‑N键。该制备方法方便分别调控CPB和ZIF的性质,以及能够准确控制活性物质比例。此外,通过在正己烷中进行混合,形成了有利于载流子传输的Pb‑N键,表现出良好的稳定性和高电荷传输效率。制备的样品在光电化学测试中表现出高的光电流密度和良好的稳定性,显著优于纯CPB量子点和其他形貌的ZIFs复合材料,展示了其在光电催化水分解、光电化学传感和CO2还原等应用中的潜力。
Resumen de: CN120082915A
本发明公开了一种用于酸性析氧反应的电催化剂及其制备方法和应用,属于电解水技术领域。本发明的用于酸性析氧反应的电催化剂的制备方法,包括以下步骤:在导电基底上原位生长过渡金属氧化物,得到过渡金属氧化物载体;对所述过渡金属氧化物载体进行等离子体处理后置于贵金属盐溶液中进行阳离子交换反应,得到电催化剂。本发明制备的电催化剂在0.5M H2SO4溶液中进行电解水反应时具有极低的起始过电位(187mV),在连续酸性电解水4500h过程中无明显的性能衰减,表现出很高的操作稳定性,在取代商业RuO2/IrO2催化剂以及降低电极制备成本和酸性电解水方面具有很大的应用潜力。
Resumen de: CN120082907A
本发明公开了一种同步提升析氢析氧性能的镍基催化剂的制备方法,包括预处理、恒电位活化、煅烧等多个步骤。通过上述方式,本发明一种同步提升析氢析氧性能的镍基催化剂的制备方法,通过对镍网基底进行恒电位活化并在活化电解液中掺杂其他金属,来调节镍网表面活性位点的电子结构,改变镍网表面的纳米结构,从而同步提升了其镍基催化剂的析氢析氧性能,有效降低了电极催化剂的成本,同时提高了镍基催化剂自身结构的稳定性,避免催化剂涂层在强碱环境中脱落,以提高析氢析氧性能的稳定性,进一步促进电解水制氢技术的可持续发展。
Resumen de: CN120082930A
本发明公开了一种PEM电解水制氢集成式散热系统及其控制方法,其中散热系统包括电解槽和散热装置,散热装置包括第一水泵、第二水泵、散热器和板式换热器;其中控制方法主要是获取电解槽的散热需求,利用散热系统模型,建立散热需求、第一水泵转速、第二水泵转速、散热器转速和板式换热器参数的动态关系,使散热需求与散热能力相匹配,再根据第一水泵实际转速、第二水泵实际转速、散热器实际转速和板式换热器实际参数,得到散热装置的辅机功耗;在辅机功耗为最小值时,输出辅机功耗和散热装置的运行参数。可见,本发明有效地改善了换热效率,通过正向设置散热装置的运行参数,实现了散热系统的最佳配置,有效地降低了运行功耗。
Resumen de: CN120082929A
本发明公开了一种PEM电解槽模拟装置、方法及制氢系统的控制方法,其中模拟装置包括壳体、水箱和参数检测单元,壳体内设置有反应水回路、调温模组、水消耗模组、气体调节模组和负载;反应水回路与水箱连通;调温模组调节壳体内反应水和气体的温度;水消耗模组与反应水回路连通;气体调节模组调节气体参数;负载与电源电连接;参数检测单元检测水箱液位、反应水温度和/或气体参数;调温模组、水消耗模组、气体调节模组和参数检测单元分别与PEM电解水制氢系统通信连接。可见,本发明通过控制模拟装置相关功能来模拟电解槽运行过程中的相关性能,去调试系统零部件选型、阈值选择是否正确,控制逻辑是否合理,有效缩短研发周期,降低成本。
Resumen de: CN120082896A
本发明公开了一种电化学合成高纯磷酸二氢钾的低能耗方法,属于生产化合物的电解工艺技术领域。本方法包括如下步骤:电解液环境中,氯化钾、磷酸在恒电流作用下进行电解,分别于阳极生成钾离子与氯气,于阴极生成磷酸二氢根与氢气,得到磷酸二氢钾,回收目标产物。本发明采用廉价的磷酸与氯化钾为原料,通过绿色电能的输入,以高的法拉第效率进行电解来一步得到高纯的磷酸二氢钾。与传统磷酸二氢钾的合成方法相比,本方法污染小,原子利用率高,对装置腐蚀性弱,副产物具高附加值,符合绿色合成、安全生产的要求,具有良好的工业化应用前景。
Resumen de: CN120082904A
本发明公开了一种电解室及其制作方法,包括在两个端板上各自设有安装槽;两个端板之间密封夹紧有电解用隔膜,电解用隔膜同时盖设在两个安装槽的槽口处;具有凸起的乳突板嵌装在安装槽中,乳突板与外部电源电连接;电极板嵌装在安装槽中,电极板位于乳突板和电解用隔膜之间,凸起与电极板的板面抵接并电性导通;一个端板的板面上设有环形凸起,另一个端板的板面上设有环形凹槽,环形凸起能嵌装并固定在环形凹槽中;安装槽和电解用隔膜均限位在环形凹槽围成的区域内。本发明结构简单可靠,电解过程稳定,通过设置环形凸起和环形凹槽,该设计能提高两个端板固接的密封性;同时环形凸起与环形凹槽还能起到定位的作用,两个端板固接时能准确对位。
Resumen de: CN120082914A
本发明提供了一种钌团簇烯催化剂的制备方法、钌团簇烯催化剂及其应用,涉及碳载催化剂的技术领域。所述钌团簇烯催化剂的制备方法包括:(1)将有机贵金属钌源、碱金属的无机盐和碳载体混合,经研磨,得到混合物;(2)将步骤(1)得到的混合物进行煅烧,再经洗涤和干燥,得到所述钌团簇烯催化剂。本发明所述钌团簇烯催化剂的制备方法具有绿色、简洁的特点,并能够实现催化剂的大规模合成。在析氢反应中,所得到的催化剂表现出优于商业铂碳和商业钌碳的电催化活性;在阴离子膜碱性电解槽中,催化剂还展示了超过现有膜电极组件的优异器件活性,并在大电流密度下保持超长时间的稳定性。
Resumen de: CN120079408A
本发明公开了一种氯氧化铋基异质结光催化剂及其制备方法和应用,属于光催化技术领域。本发明将氯氧化铋与硫铟锌复合,在去除水体中抗生素污染物的同时,将抗生素作为空穴牺牲剂实现高效产氢。本发明获得的氯氧化铋基异质结光催化剂,光生载流子的分离和传输效率高、光催化活性好、稳定性良好,能够有效去除水体中的抗生素污染物,同时还可以将抗生素污染物作为空穴牺牲剂实现高效产氢,实现环保去污和获得新能源的双重效果,符合绿色环保理念。本发明的制备方法操作简单、成本低廉,应用前景广阔。
Resumen de: CN120082911A
本发明属于催化剂领域,尤其涉及一种镍基导电凝胶催化剂及其制备方法和应用。本发明提供的镍基导电凝胶催化剂由NiOOH粉末、石墨烯凝胶粉末、造孔剂、固化剂和溶剂的混合料经过固化成型和除造孔剂制成。本发明通过使用造孔剂,能够在镍基催化剂内部形成均匀致密的多孔结构,增加催化剂的比表面积,提高反应活性和物质传递效率;同时,通过添加石墨烯凝胶粉末,可以提高镍基催化剂的导电性能,增强电子传导和催化反应速率;而且,本发明催化剂中的导电凝胶与NiOOH紧密结合,这种紧密结合的形式在促进电子传导、提高催化反应速率的同时,还能增强催化剂的物化稳定性,使催化剂表现出更优的耐腐蚀性能和机械强度。
Resumen de: CN120079443A
本发明提供一种CdS/TFPT‑DHTH‑COF复合光催化剂及其制造方法。根据本发明的方法包括将1,3,5‑三(4‑甲酰基苯基)三嗪和2,5‑二(3‑羟丙氧基)间苯二酰腙(DHTH)在均三甲苯、二氧六环及冰醋酸混合形成三嗪基共价有机框架化合物(TFPT‑DHTH‑COF),然后加入二水合醋酸镉(Cadmium acetate dihydrate),二甲基甲酰胺溶剂和硫脲,使得硫化镉晶体(Cadmium sulfide crystal)在三嗪基共价有机框架化合物表面生长,从而获得共价有机框架/硫化镉复合光催化剂(CdS/TFPT‑DHTH‑COF)。
Resumen de: AU2023359866A1
The invention relates to a plant network (100) comprising an electrolysis plant (1, 1A, IB), a power supply source (3) with a DC voltage output (7) and a central supply line (5), wherein the central supply line (5) is connected to the DC voltage output (7) of the power supply source (3), so that a direct current can be fed into the central supply line (5) and a central DC network designed for a high voltage is provided to which the electrolysis plant (1, 1A, IB) is connected via the central supply line (5). The power supply source (3) aass a power generator comprises a wind turbine (19) to which a rectifier (13A) with a DC voltage output (7) is connected, wherein the DC voltage output (7) is designed for the high voltage, and wherein a controllable energy storage system (17) is connected to the central supply line (5) which is designed in such a way, that a direct current can be fed into the central supply line (5) by means of the energy storage system (17) as required or can be discharged from the central supply line (5) and fed into the energy storage system (17). A DC supply network is implemented in the plant network (100) that enables application and control of three different DC voltage levels independently, with a first DC voltage provided as a storage battery voltage for charging and discharging an electrical storage battery of the energy storage system (17), with a second DC voltage provided as DC- Bus high voltage on the central supply line (5), and with a third DC
Resumen de: AU2023402507A1
A method of recycling a waste catalyst coated membrane, wherein the waste catalyst coated membrane comprises a membrane including a membrane ionomer, a first catalyst layer disposed on one side of the membrane, the first catalyst layer comprising a first catalyst and a first catalyst layer ionomer, and a second catalyst layer disposed on an opposite side of the membrane, the second catalyst layer comprising a second catalyst and a second catalyst layer ionomer. The method is configured to recover the first and second catalyst layer ionomers in addition to the catalyst materials and membrane ionomer.
Resumen de: CN120079416A
本发明属于电池和电解水的电极催化剂技术领域,公开了一种ZnS/Co异质结复合氮硫掺杂碳材料及其制备方法与应用,将ZnS纳米球与ZIF‑67按质量比为1:1~1:30混合均匀,在600~1000℃煅烧即得。制得复合材料由均匀分散于氮硫掺杂碳基体中的硫化锌/钴纳米颗粒异质结构组成,其中,细小的硫化锌纳米颗粒包覆于大尺寸的钴纳米颗粒表面,形成核壳异质结构;所述硫化锌纳米颗粒的直径为2~5 nm,钴纳米颗粒有两种尺寸,大尺寸为20~100 nm,小尺寸为2~10 nm;氮硫掺杂碳为类十二面体结构,其直径为200~500 nm。将该复合材料用作液态可充电锌空气电池的正极催化剂时,充放电性能具有明显优势;用作AEM电解水阳极催化剂时,性能优于商业铂碳和二氧化钌,且稳定运行超过600小时。
Resumen de: CN120079208A
本发明公开了一种电解水制氢高效自动干燥装置及其使用方法,包括筒体,所述筒体顶部设有封盖、气水过滤器,所述筒体内侧底部设有排水组件;所述筒体底部设有排水口,所述筒体的两侧设有进气口及出气口,所述排水组件包括压块、刮水组件,所述压块底部设有密封组件,所述排水口下方设有安装管,所述筒体外部安装有支撑组件;本发明通过气水过滤膜和冷凝管的双重过滤,能够高效去除气体中的水分,确保干燥效果;排水组件和移动排水管的设计实现了自动排水功能,减少操作复杂性;刮水组件的设置可以大大减少筒体内壁上残留的水汽,且底部移动排水管的设置可以进一步减少筒体底部残留的液体,确保筒体内部干燥,保证输出的气体质量。
Resumen de: CN120081346A
本申请涉及电催化剂催化能源转化领域,具体公开了一种富氧空位铬离子掺杂磷酸镍纳米花及其制备方法与应用。该制备方法包括以下步骤:S1、将六水合硝酸镍、九水合硝酸铬、尿素、酒石酸钠和聚乙二醇溶于水中,然后进行加热反应;S2、将步骤S1制得的铬离子掺杂氢氧化镍纳米花与次亚磷酸钠混合并均匀分散于水中,然后经过冷冻干燥和密封煅烧;S3、将步骤S2制得的铬离子掺杂磷酸镍纳米花在通入惰性放电气体的条件下进行等离子体反应,得到富氧空位铬离子掺杂磷酸镍纳米花。该富氧空位铬离子掺杂磷酸镍纳米花具有较高的导电性和表面活性,能够降低过电位,促进水分解反应的动力学过程,减少能量损耗,提升电解水制氢的效率。
Nº publicación: CN120082923A 03/06/2025
Solicitante:
辽宁大学
Resumen de: CN120082923A
本发明涉及一种高性能的Ge、Zr‑Fe2O3光阳极及其制备方法和应用。通过在Fe2O3中引入Ge和Zr元素,采用水热法制备了具有优异光电化学性能的Ge,Zr‑Fe2O3光阳极薄膜。Ge掺杂提高了Fe2O3的导电性,Zr掺杂改善了其结晶性和抗腐蚀性,二者协同作用显著提高了Fe2O3在水分解反应中的光电化学效率及稳定性。所制备的Ge,Zr‑Fe2O3光阳极材料,适用于太阳能水分解光电化学反应,且制备成本低、环保,具有广泛的工业化应用前景。