Absstract of: CN119663366A
本申请公开了一种高性能MXene改性氧化物电解水电极及应用,通过溶剂热法和退火制备了一种负载在二维MXene材料上的高熵氧化物电极;其中氧化物中含有Fe、Co、Ni、Cu、Mn五种过渡金属,氧化物以纳米颗粒的形式存在MXene材料表面,并通过范德华力连接。电极同时在碱性和碱性盐水介质中展现出良好的电化学活性和稳定性。
Absstract of: CN119657173A
本发明公开了具有锌、钯双金属空位PdvFeCoNiZnv LDH高熵催化材料的制备方法及应用,将氯化钯分散于无水乙醇中得到溶液A;将六水氯化铁、六水合硝酸钴、六水合硝酸镍、六水合硝酸锌、氟化铵和尿素加入到去离子水中,再与溶液A混合均匀得到溶液B;将泡沫镍置于溶液B中水热反应得到负载PdFeCoNiZn LDH的泡沫镍;再置于碱性溶液中并加热反应得到具有丰富锌、钯双金属空位的纳米片自组装成的花状PdvFeCoNiZnv LDH高熵催化材料。本发明制备的高熵催化材料在电催化HER中展现出较快的传质速率和反应动力学,进而表现出优异的电催化活性和稳定性,能够用于电催化水裂解析氢催化剂。
Absstract of: CN119663363A
本发明公开了一种稀土元素钌基复合催化剂及其制备方法和应用。本发明的稀土元素钌基复合催化剂的制备方法包括如下步骤:(1)将稀土金属盐与钌源、导电碳材料和添加剂混合研磨,得到均匀的前体材料;(2)将前体材料置于微波反应器中,进行微波反应,制得所述的稀土元素钌基复合催化剂。本发明制备得到的稀土元素钌基复合催化剂作为电催化分解水析氧电极材料展现出了优异的活性和广阔的应用前景。
Absstract of: CN119663339A
本发明属于电解水制氢技术领域,具体涉及一种金属氧化物@聚四氟乙烯纳米复合材料、制备方法和应用,所述纳米复合材料包括聚四氟乙烯颗粒以及负载于聚四氟乙烯颗粒上的金属氧化物@聚四氟乙烯复合纳米颗粒网络,较高的比表面积、氧缺陷和氧化钌纳米颗粒@聚四氟乙烯薄层包覆结构,其集成了贵金属的高催化剂活性和PTFE的耐酸稳定性。该纳米复合材料采用一步煅烧湿混合原料制得,兼具良好的导电性、氧缺陷、贵金属的高催化剂活性以及PTFE的耐酸稳定性,在电解水和海水过程中能够表现出良好的催化活性、选择性和稳定性,在电催化产氢领域具有很高的应用前景。
Absstract of: CN119656984A
本发明公开了一种罐外装料水解制氢装置,包括盛水罐(1)和制氢反应罐(2),所述盛水罐(1)通过进水管(3)与制氢反应罐(2)连接,在所述制氢反应罐(2)上方设置有与制氢反应罐(2)连接的材料罐(4);在所述制氢反应罐(2)一侧设置有与制氢反应罐(2)通过管路A(5)连通的氢净化罐(6),在所述氢净化罐(6)上方设置有通过竖直管路(7)与氢净化罐(6)连接的缓冲气囊罐(11);所述竖直管路(7)通过带有开关阀(36)的水平管路(8)依次连接有过滤器(9)和干燥器(10)。本发明具有结构设计巧妙、实用可靠的优点,采用它能够快速且连续的进行氢气的生产,即产即用,安全性较高。
Absstract of: CN119660897A
本申请提供了一种膜电极反应装置,属于污水处理设备技术领域,包括:装置本体,所述装置本体设置有电解腔和连通所述电解腔的进水管和出水管;挡水部,所述挡水部正对所述进水管设置;导流部,所述导流部设置于所述电解腔内;BDD电极模组,位于所述挡水部和所述导流部之间。本申请的膜电极反应装置,通过设置挡水部,可以防止进水直接冲击BDD电极模组,避免因强度不足而破损的问题发生,同时设置有导流部,能够将气泡通过导流斜面引导至出水管排出。
Absstract of: CN119663332A
本发明公开了一种N杂原子修饰氧空位缺陷的电催化剂及其制备方法和应用,涉及催化剂的技术领域。本发明的制备方法包括以下步骤:将硝酸盐1、硝酸盐2、尿素以及氟化铵溶解于去离子水中,超声分散均匀后得到混合液A;将混合液A加入基底材料A中进行水热反应,反应后得到LDH自支撑材料;将LDH自支撑材料于真空干燥得到基底材料B;将次亚磷酸钠与尿素混合均匀得到氮源和磷源的混合物;将基底材料B与氮源和磷源的混合物在惰性气体下煅烧,得到N杂原子修饰氧空位缺陷的电催化剂。本发明通过水热耦合煅烧的方法,得到N杂原子氧空位缺陷的二维异质纳米片结构的高效电催化剂,并证实了该电催化剂在电化学水分解反应中具有潜在能力。
Absstract of: CN119657175A
本发明属于光催化纳米半导体材料合成技术领域,公开了一种Fe掺杂ZnIn2S4光催化剂及其制备方法与应用。本发明所述制备方法包括以下步骤:将锌源、铟源、硫源、亚铁源与水混合,进行水热反应,得到Fe掺杂ZnIn2S4光催化剂。Fe属于非贵金属,其掺杂含量属于微量;并且,水热法能够在合成条件相对温和、简单的情况下合成ZnIn2S4。本发明制得的非贵金属掺杂ZnIn2S4作为产氢的光催化剂,为解决能源短缺和环境污染提供了一种新方法,为合成绿色、经济、高效、普适性的光催化剂提供了其他可能。
Absstract of: CN119663351A
本发明属于电催化材料领域,具体涉及一种分级孔碳/晶相非晶双相金属磷化物复合电催化剂及其制备和应用,所述的制备方法步骤为:将包含熔盐、碳源、过渡金属源、磷源和助剂的混合原料预先在温度T1下进行第一段保温,随后升温至温度T2并进行第二段保温,得到前驱材料;将前驱材料进行急冷处理,制得所述的分级孔碳/晶相非晶双相金属磷化物复合电催化剂;所述的助剂为含有两个以上酸性基团的化合物;所述的酸性基团包括羧酸基、磷酸基中的至少一种;温度T1为200~450℃;温度T2为850~1200℃。本发明所述的材料兼顾优异的耐酸碱、HER、OER性能。
Absstract of: CN119663318A
本发明提供了一种气体扩散层、其制备方法及应用。该气体扩散层的制备方法包括:步骤S1,提供多孔镍毡,多孔镍毡的材料为镍纤维;步骤S2,将亲水改性剂、溶剂和氧化石墨烯混合,得到涂布液;步骤S3,将涂布液涂覆在多孔镍毡的一侧表面,经干燥处理后得到气体扩散层。采用多孔镍毡作为气体扩散层的基体材料,相较于传统的泡沫镍或镍网能够在提供孔道结构的同时提高基体的机械强度,从而能够发挥支撑催化层的作用,并且能够便于氢气的排出。亲水改性剂的引入能够提高气体扩散层的亲水性,从而提高阴极电化学反应效率。氧化石墨烯的表面含有大量的含氧官能团,将其引入涂布液并进行涂覆能够提高气体扩散层的导电性。
Absstract of: CN119663319A
本发明提供了一种电解槽极板组件及其制备方法,涉及电解槽技术领域,所述电解槽极板组件包括极板、密封件和扩散层,所述极板、所述密封件和所述扩散层连接为一体式结构,且所述扩散层位于所述密封件所围成的区域内,并覆盖所述极板的反应区域。这样,通过将极板、密封件和扩散层构造为一体式结构,使得密封件和扩散层定位牢固,从而可以有效降低密封件发生密封未对齐和扩散层发生错位装配的风险,同时,也使得电解槽极板组件整体为一体化部件,从而可以减少交换膜电解槽的零件数量,从而简化装配工艺。
Absstract of: CN119661589A
本申请提供一种化合物、其制备方法、质子交换膜及电解水制氢装置,该化合物中的阴离子为:通式a所示的结构与单缺位多金属氧簇的阴离子接枝后的结构,接枝为:通式a中的P与单缺位多金属氧簇的阴离子中空隙处氧原子接枝;通式a为#imgabs0#该种化合物的水溶性较差,所以在将该种化合物应用至质子交换膜中时,该种化合物可以比较稳定地保留在质子交换膜中,使得质子交换膜具有比较稳定的质子传导率。并且,由于该种化合物是由含有两个有机膦酸的原料a与单缺位多金属氧簇接枝得到的,所以该种化合物具有较高的酸性,使得质子交换膜具有较高的质子传导率。
Absstract of: CN119663356A
本发明涉及硫掺杂铁铝双金属材料技术领域,具体涉及一种富缺陷的S‑FeAl LDHet催化剂及其制备方法与应用;通过水热法合成了在泡沫镍基底上原位生长的非贵金属电催化剂S‑FeAl LDH,然后将催化剂S‑FeAl LDH在碱性条件下进行CV选择性刻蚀Al位点,对催化剂的形貌、电子结构进行调控,形成了富缺陷的S‑FeAl LDHet催化剂;本发明通过在OER的电化学窗口进行Al刻蚀,能够使催化剂形貌不发生任何变化,并且催化剂的机械强度也得到保留。电化学原位刻蚀Al构建缺陷的方法,能够通过CV曲线直观的得到催化性能。即通过CV刻蚀圈数来确定最佳的刻蚀量,确保活性位点完全的暴漏。同时也能够优化催化剂的导电性。
Absstract of: US2025092537A1
In this disclosure, a process of recycling acid, base and the salt reagents required in the Li recovery process is introduced. A membrane electrolysis cell which incorporates an oxygen depolarized cathode is implemented to generate the required chemicals onsite. The system can utilize a portion of the salar brine or other lithium-containing brine or solid waste to generate hydrochloric or sulfuric acid, sodium hydroxide and carbonate salts. Simultaneous generation of acid and base allows for taking advantage of both chemicals during the conventional Li recovery from brines and mineral rocks. The desalinated water can also be used for the washing steps on the recovery process or returned into the evaporation ponds. The method also can be used for the direct conversion of lithium salts to the high value LiOH product. The method does not produce any solid effluent which makes it easy-to-adopt for use in existing industrial Li recovery plants.
Absstract of: KR20250039098A
본 발명은, 제조 방법이 간단하고, 바인더를 사용하지 않아 성능 저하의 우려가 없고, 금속 원소 비율을 용이하게 조절할 수 있는 층상이중수산화물, 그 제조 방법, 이를 포함하는 전극을 제공한다. 본 발명의 일실시예에 따른 층상이중수산화물의 제조방법은, 결정질 프러시안 블루 유사체를 형성하는 단계; 상기 결정질 프러시안 블루 유사체를 열처리하여, 비정질 프러시안 블루 유사체를 형성하는 단계; 및 상기 비정질 프러시안 블루 유사체를 전기화학적 산화환원처리하여, 층상이중수산화물을 형성하는 단계를 포함한다.
Absstract of: US2025091976A1
A method of producing formaldehyde, the method comprising: generating electrolytic hydrogen from the electrolysis of water; providing a feedstock gas stream comprising the electrolytic hydrogen and one or both of carbon monoxide and carbon dioxide; converting at least a portion of the feedstock gas to methanol; converting at least a portion of the methanol to formaldehyde and hydrogen; separately recovering at least some of the formaldehyde and at least some of the hydrogen; and recycling at least some of the recovered hydrogen to the feedstock gas stream.
Absstract of: US2025091862A1
A plant, such as a hydrocarbon plant, is provided, which has a syngas stage for syngas generation and a synthesis stage where the syngas is synthesized to produce syngas derived product, such as hydrocarbon product. The plant makes effective use of various streams; in particular, CO2 and H2. The plant does not comprise an external feed of hydrocarbons. A method for producing a product stream, such as a hydrocarbon product stream is also provided.
Absstract of: US2025092532A1
A process of producing hydrogen from air comprising: contacting a hygroscopic liquid with a source of air to absorb a water content from said source of air into the hygroscopic liquid; and electrolytically converting the water absorbed in the hygroscopic liquid into hydrogen and oxygen.
Absstract of: US2025092531A1
The invention generally concerns processes for the production of hydrogen gas.
Absstract of: US2025092543A1
An oxygen evolution reduction electrocatalyst includes a pyrochlore compound with the chemical formula Sm2Ru2xM2-2xO7, where M is selected from the group consisting of Ir, Sc, Fe, Cu, Pd, Cr, and Rh, and x is less than 1.0 and greater than or equal to 0.5. Also, a water electrolysis cell includes an anode, a cathode, an electrolyte, and the oxygen evolution reduction electrocatalyst.
Absstract of: US2025092545A1
A plasmonic substrate includes a base, a metallic film on the base, and a semiconducting photocatalyst on the metallic film. A method for producing a plasmonic substrate includes depositing a first metal layer having a thickness ranging from 10 to 200 nm and having a first metal through a physical vapor deposition technique onto a base, depositing a second metal layer having a second metal through a physical vapor deposition technique onto the first metal layer forming a multilayered metal template, immersing the multilayered metal template into a solution having a salt or complex of the second metal for a period of time forming a metallic film, and depositing a semiconducting photocatalyst on the metallic film. A method of catalyzing hydrogen production includes immersing a plasmonic substrate in a photocatalytic solution, exposing the plasmonic substrate to light, and generating hydrogen at a surface of the semiconducting photocatalyst.
Absstract of: US2025092546A1
A preparation method for a one-dimensional Ni12P5/Ni2P polycrystalline heterostructure catalyst used for high-efficiency water oxidation is provided. In particular, nickel foam is used as a conductive carrier and a nickel source, sodium phosphite is used as a phosphorus source, and the one-dimensional polycrystalline heterostructure catalyst is synthesized therefrom by means of a two-step hydrothermal-phosphorization method. The combination of the one-dimensional heterostructure and the nickel foam conductive carrier is beneficial for charge transfer and the release of bubbles on the surface of an electrode/electrolyte. The prepared Ni12P5/Ni2P/NF catalyst has a relatively low electrocatalytic water oxidation overpotential and long-term stability in an alkaline solution. After the Ni12P5/Ni2P/NF is loaded with monatomic Ir, the water oxidation overpotential can be further reduced.
Absstract of: US2025092544A1
Method for preparing a doped metal phosphorus trichalcogenide (dMPT) comprising: (a) contacting a first metal salt, an optional base and a fluorine salt under hydrothermal conditions thereby growing a first metal precursor on a conductive substrate; (b) contacting the first metal precursor with an aqueous solution of a second metal salt thereby forming a doped metal precursor; and (c) contacting the doped metal precursor, phosphorus, and sulfur thereby forming a mixture; and heating the mixture; a dMPT, and a method for producing hydrogen gas using the same.
Absstract of: US2025092541A1
A sulfur-modified carbon material contains conductive carbon black and sulfur elements distributed therein. The total sulfur content in the sulfur-modified carbon material is equal to or more than 1.2 times, preferably equal to or more than 1.5 times, the surface sulfur content. A process for preparing the sulfur-modified carbon material includes an impregnation step to impregnate the conductive carbon black with a solution containing sulfur at 10-80° C. for 1-5 h, and a drying step.
Nº publicación: US2025092542A1 20/03/2025
Applicant:
UNIV KING FAHD PET & MINERALS [SA]
KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS
Absstract of: US2025092542A1
An electrode includes a metallic substrate and a layer of cobalt (Co) and cadmium (Cd) doped bimetallic metal-organic framework (BMMOF11) material at least partially covering a surface of the metallic substrate. The BMMOF11 material contains irregular shaped microcrystalline structures with pointed edges, and the irregular shaped microcrystalline structures are in the form of sheets that are stacked on top of one another. A method of making the electrode, and a method of electrochemical water splitting.