Resumen de: ZA202403652B
The present invention provides a flower-shaped Bi2CrO6 oxygen-evolving photocatalyst and its preparation method, which belongs to the field of photocatalytic material preparation technology. The method uses bismuth nitrate and potassium chromate as raw materials and employs microwave heating to complete the reaction within a relatively low temperature (100oC) and a short time (2 hs). The preparation method of the present invention is mild, energy-efficient, and requires simple and fast experimental equipment. The obtained Bi2CrO6 photocatalyst samples have uniform size, large specific surface area, and abundant active sites. Additionally, due to the reduced thickness of the flakes, the migration distance of electrons and holes from the semiconductor interior to the surface is shortened, resulting in higher catalytic activity.
Resumen de: CN121428599A
本发明提供一种基于核壳异质结构介导的磁邻近效应电催化材料的制备方法,属于电催化材料制备技术领域。本发明通过静电纺丝技术将过渡金属Fe、W等元素锚定在纳米纤维载体上,并结合高温化学气相沉积法形成Fe7S8@WS2核壳结构催化剂材料。Fe7S8和WS2形成核壳结构后,可借助磁性材料与非磁性材料的界面耦合,诱导非磁性材料产生自旋极化的磁邻近效应(MPE),进而优化反应中间体的吸附与电子转移过程,使Fe7S8@WS2在电解水OER反应中50 mA/cm2的过电位仅为239 mV,在电催化领域显示出巨大的应用前景。
Resumen de: WO2025013883A1
This metal nonwoven fabric for a water electrolysis electrode contains a metal fiber. The metal fiber has: a core part including a first metal; and a coating part disposed on the surface of the core part and including a second metal and/or a compound of said metal. The first metal comprises one or more metal elements. The second metal and/or the compound of said metal comprises a metal composed of one or more metal elements and/or a compound including one or more metal elements. The second metal and/or the compound of said metal has catalytic activity and corrosion resistance in a water electrolysis reaction environment. A ratio M2/S of the sum M2 of the masses of the second metal present in the coating part and the metal element present as the compound of said metal to the geometric area S of the surface of the core part per unit mass of the metal nonwoven fabric is 0.01 g/m2 to 20.0 g/m2.
Resumen de: CN121430902A
本发明提出了一种应用于氨裂解制氢膜提纯系统的压力检测方法及系统;属于压力检测技术领域。所述方法包括:通过在金属膜上游和下游安装高精度压力传感器,实时采集膜两侧的压力数据;对采集到的压力数据进行预处理,获得多维时序压力数据集;基于预处理后的多维时序压力数据集,构建用于反映膜两侧压力变化特征的高维特征向量集,对高维特征向量集进行动态特征提取,得到多维特征矩阵;通过在金属膜上游和下游安装高精度压力传感器,能够实时、精准地采集膜两侧的压力数据。同时,对采集数据进行预处理形成多维时序压力数据集,从而实现更加精准的系统控制调节,实现制氢系统的最优化。
Resumen de: CN121428595A
本发明公开了一种表面氧化单原子纳米合金催化剂及其制备方法和应用,属于先进纳米能源材料与电催化技术领域。一种表面氧化单原子纳米合金催化剂,包括羟基化碳纳米管载体,负载于羟基化碳纳米管载体上的双金属纳米合金颗粒,双金属纳米合金颗粒中,非贵金属元素以单原子形式分散于贵金属纳米颗粒中,双金属纳米合金颗粒的尺寸为3‑4nm,且双金属纳米合金颗粒表面具有0.3‑0.6 nm厚的氧化层;贵金属的负载量为5‑15 wt%。本发明将钌与其他非贵金属元素合金化并锚定在碳材料基底上,可以大幅提升催化剂的导电性,而将合金颗粒尺寸精准控制在3‑4 nm范围内,可最大限度地暴露活性位点并兼顾结构稳定性。
Resumen de: CN121428581A
本发明公开了一种电解水单元结构、PEM电解槽及组装方法,电解水单元结构包括:极板组件、膜电极组件和单元紧固组件,极板组件包括沿纵向相对设置的两块双极板膜电极组件夹装于两块双极板之间;多个单元紧固组件分布连接于两块双极板之间的四周,单元紧固组件用于在两块双极板相互压合于设定压紧状态时,将两块双极板之间的相对位置进行固定。本发明保证两块双极板与膜电极组件精准对位以及压装卸去外力后电解水单元结构的内部仍能保持相应的紧固力,防止在运输过程中内部组件错位,保证每个电解水单元结构受力一致性,以解决电解槽单室在组装时的复杂性导致单片之间以及各组件之间错位以及受力分布不均匀的问题。
Resumen de: CN121422984A
本发明公开一种光热催化水煤气转换反应用铁基催化剂及其制备方法和应用。该催化剂的结构中包含锌铁复合金属氧化物,以及负载在所述锌铁复合金属氧化物上的呈团簇状的贵金属颗粒。本发明的技术方案中首次实现了用此铁基催化剂光热催化水煤气转换反应,并在低温下具有较好的产氢活性。
Resumen de: CN121422989A
本发明涉及纳米催化剂技术领域,公开了富含硫空位的ZnxCd1‑xS纳米催化剂的制备方法与应用,包括富含硫空位的ZnxCd1‑xS纳米催化剂的制备方法,其特征在于,包括以下步骤:步骤S1、将镉盐、锌盐和硫脲在去离子水中混合得到混合溶液;步骤S2、将混合溶液置入反应釜中加热反应,冷却后收集反应产物,用去离子水对反应产物进行洗涤,将洗涤的反应产物干燥制备得到ZnxCd1‑xS纳米催化剂。本发明合成的ZnxCd1‑xS纳米催化剂分散均匀、尺寸均一、形貌规则,其中,随着反应温度的升高,所得ZnxCd1‑xS纳米催化剂的形貌由圆球状演变为表面粗糙的荔枝状的过渡态,进而生成形貌规则的松树状形貌。此外,所制备的催化剂富含一定硫空位,应用于光催化析氢领域性能提升显著。
Resumen de: CN121423009A
本发明属于光催化与新能源材料技术领域,具体涉及一种通用型基材光催化电子‑质子迁移通道材料及其制备与应用方法。本发明所述材料包括依次层叠的导电功能基材、质子迁移通道层和光催化异质结层,通过在导电功能基材表面引入电子传输路径与可连续导通的质子通道,实现光生电子向基材定向迁移,质子沿水膜或质子迁移通道层迁移,在阴极界面发生还原反应。本发明的材料体系可使用铝、钛、不锈钢、PI、FTO玻璃、碳纤维复合材料等广谱基材,并可通过不同构筑参数实现不同光催化应用。本发明体系具有光生载流子分离效率高、界面能带可调、可扩展至大面积涂覆等优点,是一种可用于光催化产氢、VOC降解、气体净化、自清洁表面的通用底层技术。
Resumen de: CN121428607A
本发明涉及工业过程控制技术领域,公开了一种碱性水制氢系统的智能优化控制方法,包括:控制器同步采集电解槽的实时电压、电流及温度数据;依据能斯特方程计算理论可逆电压并剔除欧姆压降,解析出表征气泡覆盖程度的气泡附加阻抗值;对气泡附加阻抗值的变化率进行微分处理生成流量前馈控制指令,结合基于温度偏差的反馈控制指令合成目标转速指令,驱动碱液循环泵调节流速;利用稳态窗口下的递推最小二乘法更新结构阻抗基准值,本发明通过构建气泡阻抗观测模型,实现对电解槽内部气泡状态的零延迟感知与解耦控制,消除单一温度反馈的滞后性,并解决执行器饱和与模型老化漂移问题。
Resumen de: CN121428571A
一种亚铁氰根/铁氰根循环辅助的低电耗解耦式电解水制氢及循环方法,属于电解水制氢领域。所述方法为:在阳极电解液储罐中加入亚铁氰化物溶液,并对阳极石墨毡进行预处理,使亚铁氰根在阳极发生氧化反应;在阳极电解液储罐中加入还原催化剂,并通过加热条件实现铁氰根向亚铁氰根的热催化再生,使再生后的亚铁氰根重新进入阳极室参与反应,从而在体系内构建铁氰根/亚铁氰根的闭环循环。本方法以铁氰根/亚铁氰根氧化还原电对为媒介,解耦电解水过程,实现析氢析氧反应的空间分离,显著降低氢气渗透引起的氧中氢含量升高风险。由于亚铁氰根氧化反应的理论电位远低于传统析氧反应,与阴极析氢半反应耦合可有效降低整体电解能耗。
Resumen de: CN120981608A
Disclosed is an electrolyte solution comprising an electrolyte, where the electrolyte is used in an amount ranging between 1 wt% and 10 wt% of the electrolyte solution; an ionic liquid, wherein the ionic liquid is used in an amount ranging between 1 wt% and 5 wt% of the electrolyte solution; and a solvent, wherein the solvent is used in an amount ranging between 75 wt% and 99 wt% of the electrolyte solution.
Resumen de: WO2026020196A1
An electrolytic process and an apparatus for producing solid carbon and gaseous oxygen from CO2. In one aspect the process comprises using a cathode that includes a solid, semi-solid or liquid metal containing a catalytically active material for CO2 reduction that includes less than or equal to 10 wt.% of at least one of copper or silver or gold. In another aspect the process comprises using a "spouted" bed electrolysis apparatus comprising a downwardly moving packed bed of cathode particles that include a catalyst, such as copper, for CO2 reduction and an upward flow of electrolyte.
Resumen de: CN120917183A
An electrode for water electrolysis under alkaline conditions, comprising: a nickel metal substrate; a ceramic material having a perovskite-type structure comprising an oxide of at least one metal selected from lanthanide series elements including lanthanum, cerium and praseodymium, the ceramic material forming a coating on the nickel metal substrate; the metal nanoparticles are embedded within the ceramic material. The metal nanoparticles facing the alkaline solution have electrochemical activity, while the metal nanoparticles facing the metal substrate form anchor points between the metal substrate and the ceramic material.
Resumen de: AU2024213038A1
An electrolyser system and method of electrode manufacture. The electrolyser system may comprise a first vessel in communication with an electrolyser stack, a power supply, an electrode, a separator, a membrane, and a second vessel in communication with the electrolyser stack. The electrode may comprise a catalytic material and a micro- porous and/or nano-porous structure. The method of electrode manufacture may comprise providing a substrate, contacting the substrate with an acidic solution, applying an electric current to the substrate, simultaneously depositing a main material and supporting material comprising a scarifying material onto the substrate, and leaching the scarifying material.
Resumen de: JP2026014024A
【課題】高い分離係数αを有する重水分離用触媒および重水分離装置を提供する。【解決手段】この重水分離用触媒は、γ-FeOOHを含む。重水分離装置1は、アニオン交換膜4と、その両側にそれぞれ設けられたアノード触媒層6およびカソード触媒層8とを有し、カソード触媒層8の材料として前記触媒を用いることにより、同位体効果によりH2Oの分解が重水素または三重水素を含むHODやHOTの分解よりも優先的に生じることを示す分離係数αを10以上に高めることが可能である。【選択図】図1
Resumen de: AU2024321116A1
The present invention relates to a methanation method comprising providing an electrolyser system, the electrolyser system (20) comprising an electrolyser (10) that has at least one electrolyser cell (11), at least one fuel input (14) through which fuel enters the electrolyser (10) and at least one offgas output (46) from which offgas exits the electrolyser (10), the method further comprising supplying fuel to the at least one fuel inlet, the fuel comprising at least water and either or both carbon dioxide and carbon monoxide, operating the electrolyser system (20) by powering the electrolyser cell (11) with electricity to electrolyse the fuel in the at least one electrolyser cell (11) such that a part of the water splits into hydrogen and oxygen, wherein the electrolyser (10) is operated at a temperature at or in excess of 150 degrees C, and methanation occurs to the carbon dioxide and/or carbon monoxide in the electrolyser (10). The gas mixture can be released from the at least one offgas output (46) and then passed through a gas separation process to separate at least the methane from the gas mixture. The present invention also relates to an electrolyser system (20) configured to operate using the above method. The electrolyser system (20) comprises a fuel fluid flow path connecting a fuel inlet and a fuel outlet. The method may comprise providing to the fuel inlet a fuel gas containing water and a source of carbon selected from one or more of CO and CO2, operating the ele
Resumen de: AU2024299452A1
A control method and apparatus for a hydrogen production system. The method comprises: for each electrolytic cell, performing evaluation to obtain energy efficiencies of the electrolytic cell under load currents; for each electrolytic cell, converting the energy efficiencies of the electrolytic cell under the load currents into an energy efficiency value of the electrolytic cell; and ranking the electrolytic cells in descending order according to the energy efficiency values of the electrolytic cells, and performing power distribution on the electrolytic cells on the basis of the ranking. In the present solution, current efficiencies corresponding to load currents are obtained on the basis of bypass currents under the load currents, energy efficiencies corresponding to the load currents are obtained on the basis of the current efficiencies and voltage efficiencies, the energy efficiencies are converted into energy efficiency values, and power distribution is performed on electrolytic cells on the basis of the energy efficiency values, thereby achieving the purpose of controlling the power distribution for electrolytic cells in a hydrogen production system on the basis of accurate energy efficiencies of the electrolytic cells.
Resumen de: AU2024293794A1
The present invention is directed to a method and plant for controlling a dynamic operation in a Power-to-X plant via a DCS (distributed control system). Said plant comprises one or more electrolyzers for converting water into hydrogen and said plant can produce one or more of ammonia, methanol, ethanol, DME, methane or synthetic fuels such as gasoline or jet fuel.
Resumen de: AU2024298608A1
An electrolyzer (1) for electrolyzing saline water comprising: a housing (10) extending along a longitudinal direction (X-X) between a first end portion (11) and an opposed second end portion (12) and having a feed fluid inlet (13) and a product fluid outlet (14); two or more electrolytic cells (20) connected fluidically between the feed fluid inlet (13) and the product fluid outlet (14) and configured to electrolyze saline water entering the housing (10) to produce an electrolyzed fluid comprising hydrogen, hypochlorite and saline water; each electrolytic cell (20) comprising an anode (21) and a cathode (22); the housing (10) comprises: an inner wall (30) extending from the first end portion (11) towards the second end portion (12) along the longitudinal direction (X-X) and dividing at least a portion of the housing (10) in an inlet channel (15) and an outlet channel (16) respectively associated to the feed fluid inlet (13) and to the product fluid outlet (14); a diverting channel (40) at the second end portion (12) configured to divert the electrolyzed fluid from the inlet channel (15) to the outlet channel (16), the two or more electrolytic cells (20) being arranged along the inlet channel (15), the outlet channel (16) and the diverting channel (40)
Resumen de: WO2026024621A1
An integrated blue-green ammonia process that avoids the need for air separation is disclosed. Water electrolysis, to produce hydrogen, produces oxygen as a co-product. Natural gas (methane) is reacted in a reformer with steam and air to create a mixture composed primarily of hydrogen, steam, nitrogen and carbon dioxide. The oxygen from electrolysis drives this process, either directly inside an autothermal reformer, or indirectly by oxycombustion in the furnace of a steam methane reformer. The steam is removed by cooling the gas, the carbon dioxide is removed, leaving a purified stream comprising hydrogen and nitrogen. This stream can be combined with additional hydrogen from the electrolyzer to yield a 3:1 mixture of hydrogen and nitrogen for the Haber-Bosch process to make ammonia. The disclosed blue-green process is two-fold less expensive than the conventional green ammonia process and emits about half as much greenhouse gas as the conventional blue ammonia process.
Resumen de: WO2026023125A1
This hydrogen production system comprises: a hydrogen compound member; a water supply member for supplying water to the hydrogen compound member; and a heat recovery device for recovering adsorption heat that is generated when hydrogen, which is generated by decomposing some of water into hydrogen and oxygen in the presence of the hydrogen compound member, is adsorbed to the hydrogen compound member. This hydrocarbon production system comprises: a hydrogen compound member; a water supply member for supplying water to the hydrogen compound member; a heat recovery device for recovering adsorption heat that is generated when hydrogen, which is generated by decomposing some of water into hydrogen and oxygen in the presence of the hydrogen compound member, is adsorbed to the hydrogen compound member; a heating device for heating the hydrogen compound member to which hydrogen is adsorbed; and a gas supply device for supplying a carbon dioxide-containing gas that contains carbon dioxide to the hydrogen compound member.
Resumen de: DE102024206988A1
Elektrochemische Anlage mit einem elektrochemischen Stack (1), in dem ein erster Reaktionsraum (2) und ein zweiter Reaktionsraum (3) ausgebildet sind, die durch eine semipermeable Barriere (4) voneinander getrennt sind und zwischen denen eine elektrische Potentialdifferenz angelegt werden kann. Zumindest einer der Reaktionsräume (2; 3) ist während des Betriebs mit Wasser befüllt und mit einer Ablaufleitung (10) verbunden, über die Wasser bzw. die wässrige Lösung abfließen kann. Die Innenseite (110) der Ablaufleitung (10) ist hydrophilisiert und weist einen Benetzungswinkel (α) von 0° bis 90° auf.
Resumen de: WO2026024816A1
A continuous method includes passing a steam feed stream and one or more of a recycled tail gas stream and a methane-rich feed stream to an anode of an electrolyzer containing a cathode, the anode and an electrolyte inserted between the cathode and the anode, thereby producing an anode effluent including syngas, and passing the anode effluent including syngas to the reactor unit, thereby producing a chemical product or a fuel-based product.
Nº publicación: WO2026022486A1 29/01/2026
Solicitante:
TETRONICS TECH LIMITED [GB]
TETRONICS TECHNOLOGIES LIMITED
Resumen de: WO2026022486A1
Described herein includes a method for the production of hydrogen gas, the method comprising: (i) providing a DC electrical power supply; (ii) providing a plasma reactor (100) comprising: (a) a plasma chamber (105), (b) a plasma torch (135) comprising a first plasma electrode extending into the plasma chamber, (c) a second plasma electrode extending into the plasma chamber, and (d) first and second spray systems, each extending into the plasma chamber; (iii) establishing a DC electric potential between the first plasma electrode and the second plasma electrode to generate and sustain a reaction zone about a plasma arc therebetween; (iv) providing a spray of a hydrogen-containing feedstock into the reaction zone from the first spray system, whereby a mixture of gases comprising hydrogen gas is formed in the plasma chamber by decomposition of the hydrogen-containing feedstock; and (v) providing a spray of water into the plasma chamber adjacent to the reaction zone from the second spray system, whereby the spray of water cools and dilutes the mixture of gases formed in step (iv).