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合金纳米团簇及其制备方法和应用

Resumen de: CN120058805A

本发明提供了合金纳米团簇及其制备方法和用途。该合金纳米团簇的分子式为Cu10Pt3X5Y6·Z，其中，X为炔配体，Y为氮膦配体，Z为阴离子。由此，该合金纳米团簇能够使Pt原子精确地掺杂在团簇的表面，提高该团簇的催化活性。此外，该合金纳米团簇中的Cu‑Cu键距离较短，具有优异的热力学稳定性和化学稳定性。

一种钌-羟基氧化铁镍负载的锶钽氮氧化物复合光催化剂及其制备方法

Resumen de: CN120054562A

本发明属于光催化剂合成的技术领域，具体公开了一种钌‑羟基氧化铁镍负载的锶钽氮氧化物复合光催化剂及其制备方法。所述复合光催化剂由负载金属Ru和NiFeLDH助催化剂的SrTaO2N组成。本申请以SrCl2和Ta2O5为前驱体，KOH为添加剂调控熔盐氮化SrTaO2N形成过程，采用浸渍还原法在SrTaO2N表面负载金属Ru析氢助催化剂，用光沉积法在SrTaO2N表面负载NiFeLDH析氧助催化剂。该方法工序简单、操作方便，所得SrTaO2N光催化剂具有良好结晶性和可见光吸收性能，金属Ru和NiFeLDH负载提升了光催化剂析氢析氧反应动力学性能，实现高效可见光催化全分解水，具有大规模工业化应用价值。

IRIDIUM-OXIDE-BASED CATALYST AND PREPARATION METHOD THEREFOR AND USE THEREOF, AND MEMBRANE ELECTRODE AND PREPARATION METHOD THEREFOR AND USE THEREOF

Resumen de: WO2025108003A1

Provided are an iridium-oxide-based catalyst and a preparation method therefor and the use thereof, and a membrane electrode and a preparation method therefor and the use thereof. The catalyst comprises an oxide of iridium, wherein the oxide of iridium comprises an oxide of iridium having vacancies, the vacancies comprising iridium vacancies or oxygen vacancies; and iridium oxide comprises metastable-phase iridium oxide. A hydrogen-oxygen flame method is used as the preparation method for the catalyst, and can respectively regulate and control vacancies and crystal phases. The catalyst has both high-activity defect vacancies and stable high-activity crystal phases, and has a low overpotential and a high oxygen evolution catalyzing activity when being applied to water electrolysis.

一种电解槽电流效率精准测量方法及实际产氢量标定方法

Resumen de: CN120060926A

本发明涉及碱性水制氢电解槽技术领域，具体涉及一种电解槽电流效率精准测量方法及实际产氢量标定方法，包括设置气体排水装置，将电解槽产生的氢气通入所述气体排水装置的水箱中进行氢气排水实验，通过氢气排水实验获取排水体积，得到通入所述气体排水装置中相应的氢气体积，并通过测量所述气体排水装置内氢气的压力数据和温度数据，将通入到所述气体排水装置中的氢气体积校正为标准压力和温度状态下的实际产氢量，并计算实际产氢量与理论产氢量之比，得到电解槽在设定电流密度工况下的电流效率。本发明可以精确测量电解槽电流效率，以及精确标定电解槽的实际产氢量。

一种La-Ce双掺杂Co3S4材料及其制备方法和应用

Resumen de: CN120060913A

本发明提供了一种La‑Ce双掺杂Co3S4材料及其制备方法和应用，属于电解水技术领域。本发明通过Co3S4中硫与钴构建高导电性和催化活性的硫化物结构，为析氧反应提供基础活性位点；利用镧和铈调整钴的d带中心，降低反应能垒，提高催化活性；铈的掺杂还可以增加氧空位，提高催化活性；镧和铈的离子半径较大，还可以维持结构稳定、优化界面电荷转移；特定的微观结构大幅度提高材料的比表面积，增加活性位点，进一步提高催化活性。

多孔石墨烯微流道结构的空间质子交换膜电解池

Resumen de: CN120060876A

本发明提出了多孔石墨烯微流道结构的空间质子交换膜电解池，属于太空能源、电解水制氢技术领域。解决了传统电解池流道阻力大，离子迁移受限，结构复杂占用空间大的问题。它包括双极板，两个所述双极板组合后内部形成空腔；质子交换膜，设置在两个所述双极板接触面之间，并将所述空腔分割成两个腔室，每个所述腔室中填充有多孔石墨烯结构并形成两个流道，生成的气体在相邻的所述多孔石墨烯结构之间骨架形成的孔隙中沿壁面流动。催化剂层，覆盖在质子交换膜的两侧，每侧的所述催化剂层均与同侧的多孔石墨烯结构相连。它主要用于提供气液流动通道。

硼修饰铱黑及其制备方法与电解水催化剂

Resumen de: CN120060904A

本发明提供了一种硼修饰铱黑及其制备方法与电解水催化剂。该硼修饰铱黑包括铱黑以及掺杂在铱黑中的硼；以硼修饰铱黑的摩尔量为100％计，硼修饰铱黑中硼元素的摩尔量为0.5％‑5％。该制备方法包括：将硼源、铱源和有机醇的混合物混合，形成反应体系，将反应体系蒸发干燥，洗涤干燥，得到所述硼修饰铱黑。本发明还提供了上述硼修饰铱黑制成的电解水催化剂。本发明提供的硼修饰铱黑具有较高的催化活性、导电性和抗腐蚀性。

一种三维自支撑多相异质结电催化剂及其制备方法和应用

Resumen de: CN120060886A

本发明提供了一种三维自支撑多相异质结电催化剂及其制备方法和应用，其中，所述三维自支撑多相异质结电催化剂包括导电基底和生长于所述导电基底上的CoMoS3.13/FeS2/Co3S4异质结纳米片，所述CoMoS3.13/FeS2/Co3S4异质结纳米片由CoMoS3.13、FeS2及Co3S4三组分组成。本发明提供的该三维自支撑多相异质结电催化剂在碱性条件下具有较好的电解水催化活性和循环稳定性。

一种氢氧化物-磷化物异质结析氧催化剂及其制备方法和在电解海水中的应用

Resumen de: CN120060947A

本发明提供一种氢氧化物‑磷化物异质结析氧催化剂及其制备方法和在电解海水中的应用，属于电解海水领域。为解决电解海水存在严重腐蚀情况，电解时导电性较弱，限制电子快速传递，导致催化效率低的问题。包括超声清洗载体材料；将铵盐、磷源和用于制备磷化物的金属源制备第一前驱体溶液；通过电化学沉积法在载体表面沉积金属磷化物；将用于制备氢氧化物的金属源制备第二前驱体溶液；通过电化学沉积法在金属磷化物表面生长层状金属氢氧化物，得到金属氢氧化物‑磷化物异质结催化剂；清洗干燥后得到层状金属氢氧化物/磷化物异质结析氧催化剂。本发明简单、高效、成本低廉，能够制备出更高效的析氧反应催化剂，对析氯反应具有良好抑制效果。

一种碳包覆钴基催化剂及其制备方法与在电解水中的应用

Resumen de: CN120060910A

本发明公开了一种碳包覆钴基催化剂及其制备方法与在电解水中的应用。本发明碳包覆钴基催化剂的制备方法，包括如下步骤：S1、将泡沫镍浸入由钼源、钴源、尿素、氟源和水组成的溶液中，加热进行水热反应，得到泡沫镍支撑的Mo‑Co LDH前驱体；S2、将步骤S1得到的产物在惰性气体保护下进行退火处理，得到泡沫镍支撑的Mo‑Co LDH纳米线阵列；S3、将步骤S2得到的产物加入2‑甲基咪唑溶液中，进行浸泡处理，以在泡沫镍支撑的Mo‑Co LDH纳米线阵列上负载金属有机框架材料ZIF‑67；S4、将步骤S3得到的产物与磷源共同在惰性气体保护下进行热解，以形成泡沫镍支撑的碳包覆钼掺杂磷化钴。本发明催化剂具有优异的析氢活性和稳定性，制备方法环保、安全、能耗低，适合大规模制备。

一种负载助催化剂的Fe、Al共掺杂SrTiO3光催化剂及其制备方法和应用

Resumen de: CN120054529A

本发明属于光催化材料技术领域，具体涉及一种负载助催化剂的Fe、Al共掺杂SrTiO3光催化剂及其制备方法和应用。本发明将六水氯化铁研磨加入到Al‑SrTiO3的前驱体中，通过改变Fe源的摩尔比得到不同摩尔比例的Al‑SrTiO3‑x％Fe，然后加入Rh前驱体溶液、Cr前驱体溶液和Co前驱体溶液，300W氙灯下照射，得到负载助催化剂的Fe、Al共掺杂SrTiO3光催化剂。该光催化剂可以应用于光催化全解水领域。相较于现有的光催化剂，本发明光催化剂可控性良好，有利于进一步提升载流子的分离效率，复合材料用于光催化全解水有较高的产氢量和较好的稳定性。本发明绿色环保，方法简单，操作方便，材料制备成本低廉，具有广阔的应用市场前景。

一种基于NiCo-MOF/Ti3C2Tx衍生多相界面复合物及其在电催化析氢中的应用

Resumen de: CN120060892A

本发明提供了一种基于NiCo‑MOF/Ti3C2Tx衍生多相界面复合物的制备方法，专门用于电催化析氢。通过将金属有机框架与Ti3C2Tx MXene复合，利用MOF的高比表面积和可调节的结构特性，结合MXene的优异导电性和层间结构优势，本发明的复合材料展现出显著的电化学性能提升。合成过程中，采用尿素调控石墨化程度与形貌，使得NiCo金属单质均匀分散在Ti3C2Tx MXene载体上，进而优化了材料的导电性和电荷转移能力。所制备的NiCo/TiO2‑GH复合材料在碱性介质中表现出优异的催化性能和良好的稳定性。这是由于MXene的引入不仅提供了稳定的载体，还改善了催化剂的导电性和层间离子扩散性，与MOF的功能化金属中心协同作用，显著提升了析氢效率和材料稳定性。本发明的MOF衍生策略为构建高性能电催化材料提供了全新的思路。

Alloyed nanosheet catalysts for electrochemical water-splitting hydrogen generation

Resumen de: KR20250075817A

본 발명은 우수한 물분해 수소발생반응(Hydrogen evolution reaction, HER) 활성을 갖는 합금 나노시트 및 이의 제조방법에 관한 것이다. 보다 구체적으로, 본 발명은 전기화학적 물분해 반응 수소발생 촉매 활성을 갖는 텅스텐 나이오븀 디셀레나이드 (W1-xNbxSe2, 0 < x ≤ 1) 합금 나노시트 또는 텅스텐 나이오븀 바나듐 디셀레나이드(W1-(y+z)NbyVzSe2, 0 < y ≤ 1, 0 < z ≤ 1) 및 이들의 조성비를 정량적으로 조절 가능한 콜로이드 용액 반응 제조방법에 관한 것이다.

Salt and hydrogen production system using seawater

Resumen de: KR20250075808A

본 발명은 바닷물을 이용한 소금과 수소의 생산시스템에 관한 것으로, 원수(바닷물 또는 해변염지하수)에 포함된 부유물, 실트, 금속, 플라스틱을 차압에 의해 셀프클리닝필터에의한 여과, 마이크로 플라스틱, 미생물, 유기성 물질을 제거하는 정밀 및 한외여과막 및 역삼투막분리에 의한 1가의 나트륨 및 칼륨, 2가의 칼슘 및 마그네슘, 3가이온의 알루미늄 등의 금속성 양이온과 염소이온, 황산이온, 질산이온,인산이온, 탄산이온등의 음이온을 제거하여 농축수는 농축수저장조로 보내고 역삼투분리막을 통과한 물은 투과수저장조로 보내는 전처리부와; 농축수저장조로부터 공급되는 농축수를 돔하우스로 공급하여 열에 의해 수분을 증발시켜 응축수저장조로 공급하고, 수분이 증발하여 생산되는 고체소금과 액체소금을 생산하는 소금생산부와; 응축수저장조에 저장된 물을 수처리장치를 통해 총용해성고형물질이 설정 ppm 이하로 걸러진 순수한 물을 전기분해장치로 공급하여 전기분해에 의해 수소를 생산하는 수소생산부;를 포함하는 것을 특징으로 하며, 전처리하여 얻어지는 바닷물을 열에 의해 고체소금과 소금물을 생산하고, 소금물은 재처리를 통해 기능성 액체소금을 생산하며, 액체소금에 특정 첨가제를 투입하여 기�

Quantum dot-coated photoelectrode and Method of preparing the same

Resumen de: KR20250076382A

태양광 수소생산용 광전극 및 이의 제조방법을 제공한다. 상기 광전극은 양자점이 코팅된 금속산화물 필름을 포함하는 광전극으로, 상기 양자점에 의해 광전극의 광흡수 파장 범위가 넓어진 광전기화학적 수소생산용 금속산화물 기반의 광전극이다. 또한, 상기 광전극은 연속 이온층 흡착 및 반응법(Successive Ionic Layer Adsorption and Reaction)에 의해 양자점이 균일하게 코팅되어 광전기화학적 수소생산 성능이 향상될 수 있다.

PtZn Intermetallic compound PtZn catalyst for ammonia oxidation reaction and its manufacturing method

Resumen de: KR20250076184A

본 발명의 일실시예는 암모니아 산화 반응에서의 피독 문제를 개선하고 내구성을 향상시킨 암모니아 산화 반응용 금속간 화합물 PtZn 촉매 및 그 제조방법을 제공한다.

Cathode for alkaline water electrolysis comprising catalyst-supporting gas diffusion layer and manufacturing method thereof

Resumen de: KR20250076122A

본 발명은 알칼리 수전해 스택에서 단위전지를 구성하는 전극 중 음극 및 그의 제조 방법에 관한 것으로, 지지체를 배제한 묶음 전극을 포함하고, 묶음 전극은 촉매 슬러리가 직접적으로 담지 된 가스확산층으로 구성되어, 촉매 슬러리를 지지체에 담지하지 않아 묶음 전극의 두께를 0.5 내지 3 mm로 감소시키는 것을 특징으로 한다. 기존의 촉매 담지 기술에 비해 간편하고 경제적으로 전극을 제조하는 기술로써 전도성 고분자를 바인더로 사용하여 촉매 담지 가스확산층을 포함하는 알칼리 수전해용 음극 및 그의 제조 방법에 관한 것이다.

Célula para formar un electrolizador, electrolizador que comprende tal célula, método para fabricar y operar un electrolizador

Resumen de: AU2023374771A1

Cell for forming an electrolyser comprising at least one diaphragm or membrane having a first side and a second side opposite the first side, a first cell plate, arranged on the first side of the diaphragm, provided with a first electrode, provided with an inlet channel for supplying or draining electrolyte to or from the electrode, provided with a first discharge channel for discharging oxygen from the electrode, at least one second cell plate, arranged on the second side of the diaphragm, provided with a second electrode and provided with a second discharge channel for discharging hydrogen from the electrode wherein the at least one first and second cell plate are made of a polymer material.

CELL FRAME FOR PRESSURIZED ELECTROLYSER CELL STACK AND ELECTROLYSER CELL STACK COMPRISING A NUMBER OF SUCH CELL FRAMES

Resumen de: AU2023381476A1

A cell frame adapted for use in a pressurised electrolyser cell stack is provided. From an inner circumferential rim of the cell frame, a circumferential radial shelf with inwardly tapering thickness is provided, such that an annular space between a circumferential radial shelf and a neighbouring circumferential radial shelf is provided when cell frames are stacked in alignment with each other, and that outwardly of the circumferential radial shelf, a mobility link is provided which connects the radial shelf to the remaining cell frame.

ASU Electrolyser System

Resumen de: US2025171922A1

An air separation system includes an air separation unit and at least one solid oxide electrolyser cell, the air separation unit including a source gas infeed, the at least one solid oxide electrolyser cell including an anode, a cathode and an electrolyte, a steam input and an oxygen rich gas output, where the oxygen rich gas output connects to the source gas infeed of the air separation unit.

HYDROGEN PRODUCTION SYSTEM, AND THERMAL MANAGEMENT METHOD AND APPARATUS THEREFOR

Resumen de: US2025171911A1

The present application relates to a hydrogen production system, and a thermal management method and apparatus therefor. The hydrogen production system includes: at least two electrolytic cells; and a post-treatment device, the at least two electrolytic cells sharing the post-treatment device, and the post-treatment device including first electrolyte inflow branch pipes and second electrolyte inflow branch pipes, wherein the first electrolyte inflow branch pipes share a single cooling apparatus and are used for guiding a cold electrolyte into a corresponding electrolytic cell, and the second electrolyte inflow branch pipes are bypass branch pipes of the cooling apparatus and are used for guiding a hot electrolyte into a corresponding electrolytic cell. Compared with the prior art, embodiments of the present invention implement accurate control on the temperature of each electrolytic cell and improve system efficiency.

SYSTEMS AND METHODS FOR PRODUCING HYDROGEN GAS

Resumen de: US2025171920A1

An electrolyzer system comprises one or more electrolyzer cells each comprising a first half cell with a first electrode and a second half cell with a second electrode and a controller to control a current applied through the one or more electrolyzer cells, wherein the controller is configured to dynamically set the current density within a current density range of from about 150 mA/cm2 to about 3000 mA/cm2, and wherein the controller is configured to set the current density to a first value when a first condition is met and to a second value when a second condition is met.

SEAWATER NON-DESALINATION IN-SITU DIRECT ELECTROLYSIS HYDROGEN PRODUCTION METHOD, APPARATUS, AND SYSTEM

Resumen de: US2025171910A1

This invention discloses a method, device, and system for the direct electrolysis of seawater without desalination for hydrogen production. By immersing the direct electrolysis device for hydrogen production from seawater without desalination directly into seawater, driven by the pressure difference at the interface between seawater and the self-driven electrolyte, seawater continuously enters the device through the solution mass transfer layer. The self-driven electrolyte induces the water to enter the electrolyte solution, while the hydrophobic action of the solution mass transfer layer effectively blocks non-water impurities in the solution. During electrolysis, the water in the self-driven electrolyte is consumed to produce hydrogen and oxygen, inducing the regeneration of the electrolyte, maintaining the pressure difference at the interface, and achieving a self-circulating excitation drive without additional energy consumption.

SYSTEM AND METHOD FOR PRODUCING HYDROGEN

Resumen de: US2025171921A1

The present invention relates to a system and method for producing hydrogen gas. The system comprises at least one gas transport vessel which is arranged to transport at least hydrogen up through water by buoyancy, a heat transfer unit connected to an electrolysis unit and arranged to transfer at least a portion of the waste heat from the electrolysis unit to the hydrogen gas that is to be transported by the gas transport vessel.

A Separator for Alkaline Water Electrolysis

Nº publicación: US2025171918A1 29/05/2025

Solicitante:

AGFA GEVAERT NV [BE]
Agfa-Gevaert NV

Resumen de: US2025171918A1

A separator for alkaline electrolysis (1) comprising a porous support (10), a first porous layer (20b) provided on one side of the porous support and a second porous layer (30b) provided on the other side of the porous support, wherein the first and the second porous layer are partially impregnated into the porous support and each have an overlay thickness d1 and d2 respectively, said overlay thickness being defined as the part of each porous layer which is not impregnated into the porous support, characterized in that a) d1 is smaller than the overlay thickness of the second porous layer (d2), and b) d1 is at least 20 μm.