Resumen de: TW202513891A
The present disclosure relates to an electrode and a method for preparing the same. According to the present disclosure, an electrode for anion exchange membrane water electrolysis that can achieve improved electrochemical performance and also has excellent durability can be provided.
Resumen de: WO2025078381A1
The various embodiments of the present invention disclose a water electrolyser using alkaline medium, comprising: a first end plate and a second end plate and a plurality of cells stacked in-between the first and the second end plate. Each cell comprises an anode cell frame and a cathode cell frame, each cell frame further comprises a central opening, at least one inlet channel transversing through the cell frame, and at least one inlet pathway grooved in the cell frame for connecting the inlet channel to the central opening. The inlet pathway comprises an inlet orifice <b>characterized by</b> a minimum cross-sectional area in the inlet pathway. The cross-sectional area of the inlet channel in the stack is greater than the sum of the cross-sectional area of the plurality of inlet orifices in the stack by at least a predetermined factor, the predetermined factor being larger than 1 and smaller than or equal to 4.
Resumen de: WO2025053532A1
The present invention relates to a membrane electrode assembly manufacturing method comprising the steps of: (S1) forming a first catalyst layer on the other surface of a separation membrane having a first carrier film attached to one surface thereof; (S2) attaching a second carrier film to the other surface of the separation membrane on which the first catalyst layer is formed; (S3) removing the first carrier film attached to one surface of the separation membrane; and (S4) forming a second catalyst layer on one surface of the separation membrane from which the first carrier film is removed, wherein the second carrier film includes a first area corresponding to the first catalyst layer on the other surface of the separation membrane, and a second area, which is the remaining area that excludes the first area, and the second area of the second carrier film is coated with an adhesive on a surface facing the other surface of the separation membrane on which the first catalyst layer is formed.
Resumen de: CN119024088A
The invention provides a test system and method for evaluating an electrode for a hydrogen production electrolytic bath in a laboratory, and the test system at least comprises an electrode clamp which is used for clamping an electrode to be evaluated; the heat exchanger is connected to the electrode clamp, and electrolyte is preheated through the heat exchanger and then input into the electrode clamp; and a heating unit connected to the electrode holder to heat the electrode holder. According to the test system and method for the electrode for the hydrogen production electrolytic cell in the laboratory, the temperature of the electrode clamp and the electrolyte in the electrode clamp can be accurately controlled, the accuracy of the test result is improved, the energy consumption of the test system can be reduced, and the test efficiency is improved.
Resumen de: TW202508703A
The present disclosure relates to a method for preparing a nickel-based phosphide catalyst for oxygen evolution reaction in alkaline water electrolysis anode using sodium hypophosphite(NaH2PO2) substitution and pyrolysis.
Resumen de: TW202511178A
To provide: an ammonia-hydrogen mixed fuel production apparatus capable of stably obtaining hydrogen from ammonia even when there is a change in the required ratio of fuel; and a fuel supply system. An ammonia-hydrogen mixed fuel production apparatus 1010A comprises: an oxygen separation device 13 that separates oxygen (O2) 12 at a desired concentration from air 11; a reforming reactor 15 that converts ammonia (NH3) supplied from a raw material supply unit 14 into hydrogen (H2) by using the oxygen having the desired concentration from the oxygen separation device 13; and a gas component analyzer 17 that measures the concentration of one or both of hydrogen and ammonia in a reformed gas 16 from the reforming reactor 15.
Resumen de: WO2026048255A1
A water electrolysis cell and a water electrolysis system comprising: an ion exchange membrane; a cathode-side catalyst layer disposed on one side of the ion exchange membrane; an anode-side catalyst layer disposed on the other side of the ion exchange membrane; and a metal impurity removal layer disposed between the ion exchange membrane and the cathode-side catalyst layer and/or between the ion exchange membrane and the anode-side catalyst layer.
Resumen de: CN120004436A
The invention relates to the technical field of industrial solid waste comprehensive treatment, and discloses a water treatment method and system after secondary aluminum ash hydrogen production, and the method comprises the following steps: collecting hydrolysate after secondary aluminum ash hydrogen production to obtain high saline-alkaline ammonia nitrogen hydrolysate; carrying out ammonia-nitrogen separation on the high-salt-alkali ammonia-nitrogen hydrolysate to obtain a gas phase and a first-stage liquid phase; dissolving carbon dioxide in the first-stage liquid phase until a specified pH value is reached to obtain a second-stage liquid phase; dissolving carbon dioxide in the second-stage liquid phase until the specified pH value is reached to obtain a third-stage liquid phase; adding an extracting solvent into the third-stage liquid phase, dissolving carbon dioxide until the specified pH value is reached, and extracting and separating to obtain a fourth-stage liquid phase of an organic phase and a fourth-stage liquid phase of an inorganic phase; evaporating moisture of a fourth-stage liquid phase of the inorganic phase; and carrying out back extraction separation on the fourth-stage liquid phase of the organic phase to obtain an inorganic liquid phase and an organic liquid phase. By adopting the method, aluminum hydroxide and various valuable salts can be efficiently recovered, and the obtained product is rich and high in value.
Resumen de: WO2026048903A1
A titanium porous body according to the present invention comprises a powder sintered body and is formed in a sheet shape having a thickness of 200 μm or greater. In the titanium porous body, holes present in a cross-section extending along the thickness direction have an average aspect ratio of 3.2 or higher, the aspect ratio being calculated as a ratio of the thickness-direction length of a hole to the width-direction length of the hole, within a visual field measuring 200 μm × 200 μm in the cross-section.
Resumen de: AU2024328562A1
A reaction medium according to the present invention is characterized by having a chemical structure in which Mn is introduced into a composite iron oxide. It is preferable that this reaction medium is used in a method for producing hydrogen by thermally decomposing water. It is preferable that this reaction medium contains a composite metal oxide of Fe, Co, Ni, and Mn, contains a composite metal oxide of Fe, Ni, Mg, and Mn, or contains a composite metal oxide of Fe, Co, Mg, and Mn. A treatment method according to the present invention includes: a first step for thermally reducing the reaction medium; and a second step for bringing the thermally reduced reaction medium into contact with an object to be treated, thereby oxidizing the reaction medium and decomposing the object to be treated.
Resumen de: WO2026054154A1
According to one embodiment, a vehicle hydrogen generator having a hydrogen generation amount adjustment device may comprise a PEM water electrolysis stack for generating hydrogen by electrolyzing water, wherein the PEM water electrolysis stack includes: a water tank for storing water for generating hydrogen through electrolysis; an electrolysis cell for generating hydrogen by electrolyzing the water provided from the water tank; a water separator which removes moisture contained in the hydrogen provided from the electrolysis cell and which provides the removed moisture to the water tank; and a control unit electrically connected to the electrolysis cell and the water tank.
Resumen de: AU2026201235A1
WO 2021/16125 PCT/US2021/018596 The present invention provides a hydrodynamic pump, comprising: an upper hull enclosure adapted to float at a surface of a body of liquid; a liquid collecting chamber at least partially housed within the upper hull enclosure, the liquid collecting chamber adapted to confine liquid and gas at elevated pressure; a liquid pressurizing columnar conduit extending below the upper hull enclosure, the liquid pressurizing columnar conduit comprising an ingress orifice disposed outside the upper hull enclosure, an injection orifice opening into the liquid collecting chamber, and an interior wall defining a liquid pressurizing surface adapted to pressurize liquid in the liquid pressurizing columnar conduit when the hydrodynamic pump oscillates vertically in the body of liquid to inject liquid into the liquid collecting chamber; a first effluent conduit configured to drain liquid from the liquid collecting chamber and having an effluent port for discharging liquid from the first effluent conduit; and a first flow governor adapted to maintain a liquid pressure gradient between the liquid collecting chamber and the effluent port. WO 2021/16125 PCT/US2021/018596 eb e b
Resumen de: AU2026201234A1
WO 2021/168125 PCT/2021/018596 The present invention provides a wave engine, comprising: a buoy configured to rise and fall under an influence of a body of water; a hollow tube depending from the buoy and having a water ingress/egress mouth at a lower end and a water discharge spout at an upper end, and further comprising an interior including a wall defining a water accelerating surface adapted to eject water through the water discharge spout in response to an increasing hydrodynamic pressure within the interior of the hollow tube; a water collection reservoir in fluid communication with the water discharge spout; a first effluent conduit for diverting at least a portion of water collected in the water collection reservoir from the water collection reservoir; and a first electrical energy generator for converting an energy of a portion of water in the first effluent conduit into electrical energy. eb e b
Resumen de: AU2026201233A1
WO 2021/168125 PCT/US2021/018596 The present invention provide a method for manufacturing hydrogen, comprising: deploying a hydrodynamic pump to an ocean, the hydrodynamic pump including an inertial water tube comprising a constricting feature to pressurize ocean water, a pressurized fluid reservoir partially filled with ocean water transported from the ocean to the pressurized fluid reservoir via the inertial water tube, a turbine energized by a flow of pressurized ocean water exiting the pressurized fluid reservoir, an electrical generator coupled to the turbine, an electrolyzer, and a hydrogen tank; transmitting electrical energy from the electrical generator to the electrolyzer to generate hydrogen; and storing the hydrogen in the hydrogen tank. eb e b
Resumen de: US20260070025A1
Calcined or pyrolyzed metal compounds immobilized in membranes based on ionic liquids and/or eutectic solvents. The invention relates to new catalytic membranes synthesized from ionic liquids or deep eutectic solvents and oxidized or pyrolyzed immobilized metal compounds in the membranes. The use of these new catalytic membranes in oxidation/reduction reactions, for application in fuel cells and in water electrolyzers for hydrogen production, is described.
Resumen de: US20260074251A1
A fuel cell system including a fuel cell module having an anode inlet configured to receive an anode inlet stream including fuel and an anode outlet configured to output an anode exhaust stream including carbon dioxide and steam, a solid oxide electrolysis cell module configured to receive waste heat and a first portion of the anode exhaust stream from the solid oxide fuel cell module and output an electrolysis output stream including hydrogen and carbon monoxide, wherein at least a portion of the electrolysis output stream is redirected to become a component of the anode inlet stream of the fuel cell module, and a controller configured to operate the solid oxide electrolysis cell module at an endothermic current density
Resumen de: US20260070783A1
The disclosure relates to systems and methods for the production of hydrogen (H2) from ammonia (NH3) in a membrane reactor that include using ammonia as a sweep gas. Ammonia is converted to hydrogen and nitrogen (N2), and the hydrogen is separated from the nitrogen and unreacted ammonia by passing the hydrogen through a hydrogen-permeable membrane while using ammonia as a sweep gas. The ammonia sweep gas can be separated from the permeated hydrogen and continuously recycled.
Resumen de: US20260070826A1
A produced water stream in a GOSP is pretreated to remove total suspended solids, emulsified oil, total organic carbon, chemical organics and inorganics, and biodegradable matter. The pretreated produced water stream is further processed to remove hydrogen sulfide gas, which is split in an electrolysis cell to produce hydrogen, sulfur, and water. Following this, bromine gas is removed. The pretreated produced water stream, after the removal of hydrogen sulfide and bromine gas, is further treated using CO2 to produce several minerals. The pretreated produced water stream, after mineral production, is desalinated to produce fresh water and a reject stream. Several valuable chemicals are produced from the reject stream. This process recovers valuable minerals and chemicals from a produced water stream in a GOSP.
Resumen de: US20260071336A1
A system for producing hydrogen gas comprising: a heat exchanger module; the heat exchanger comprising: a warming module; and a boiler; a converter module; the converter module comprising a superheater, vaporizer, and/or compressor; an electrolyzer in communication with the converter module; and the electrolyzer in communication with the heat exchanger module. A method for producing hydrogen gas comprising: passing a working fluid into a heat exchanger module comprising warming module and a boiler to form a vapor-phase working fluid; passing the vapor-phase working fluid into a converter module comprising a superheater, vaporizer, and/or compressor to form a converted working fluid; passing the converted working fluid into an electrolyzer to form hot hydrogen gas and hot oxygen gas; passing the hot oxygen gas and/or hot hydrogen gas into the heat exchanger module.
Resumen de: US20260071342A1
There is provided a system comprising burning facility (101); a synthetic fuel production facility (102); a hydrogen production facility; and an oxygen production facility (114); wherein the oxygen production facility (114) is configured to feed the produced oxygen to the burning facility (101) for combustion of fuel at the burning facility (101) using the produced oxygen, and the burning facility (101) is configured to produce a CO2-rich flue gas based on the combustion of the fuel at the burning facility (101) using the produced oxygen, and the burning facility (101) is configured to feed the produced CO2-rich flue gas to the synthetic fuel production facility (102) for capturing the CO2 generated at the combustion in a fuel synthesis.
Resumen de: US20260071341A1
A hydrogen production system includes: an electrolysis module that supplies steam to a hydrogen electrode including a metal component and produces hydrogen through steam electrolysis; a hydrogen storage facility that stores generated hydrogen; a steam supply unit that supplies steam to the hydrogen electrode; a regulation unit that regulates a supply amount of the hydrogen supplied from the hydrogen storage facility to the hydrogen electrode and a supply amount of the steam supplied from the steam supply unit to the hydrogen electrode; and a control device for controlling the regulation unit to switch a heating medium supply state in which a heating medium is supplied from a heating medium supply unit to the hydrogen electrode to a steam supply state in which steam is supplied from the steam supply unit to the hydrogen electrode, in response to the electrolysis module exceeding a first switching temperature when activating the electrolysis module.
Resumen de: WO2026055325A1
A system for producing hydrogen gas comprising: a heat exchanger module; the heat exchanger comprising: a warming module; and a boiler; a converter module; the converter module comprising a superheater, vaporizer, and/or compressor; an electrolyzer in communication with the converter module; and the electrolyzer in communication with the heat exchanger module. A method for producing hydrogen gas comprising: passing a working fluid into a heat exchanger module comprising warming module and a boiler to form a vapor-phase working fluid; passing the vapor-phase working fluid into a converter module comprising a superheater, vaporizer, and/or compressor to form a converted working fluid; passing the converted working fluid into an electrolyzer to form hot hydrogen gas and hot oxygen gas; passing the hot oxygen gas and/or hot hydrogen gas into the heat exchanger module.
Resumen de: WO2026054606A1
The present invention relates to a porous water electrolysis separation membrane using a boron nitride compound. More specifically, the porous water electrolysis separation membrane comprises a porous polymer support and a boron nitride compound inserted into the inside of the porous polymer support or formed on a surface thereof. The water electrolysis separation membrane according to the present invention as described above exhibits excellent heat resistance and stability and has smaller pore sizes, thereby reducing the permeability of hydrogen and oxygen and achieving high hydrogen gas purity. In addition, with a reduced thickness, the water electrolysis separation membrane exhibits low sheet resistance and thus increases current density to improve electrolytic cell efficiency.
Resumen de: WO2026052657A1
The invention relates to an electrolysis system for electrolytically splitting water into hydrogen and oxygen, comprising an electrolytic cell (1) having an anode chamber (2) and a cathode chamber (3) that are separated from one another by a semipermeable barrier, and comprising an anode water circuit (4) which supplies the anode chamber (2) with water via an anode inlet (5) and which receives water from the anode chamber (2) via an anode outlet (6), wherein a gas-water separator (8) and a pump device (9) are disposed in the anode water circuit (4). The water from the cathode chamber (3) is received in a cathode water pathway (14) and fed into the anode water circuit (4), with a second gas-water separator (17) being disposed in the cathode water pathway (14) and an ion exchanger (10) for removing metal ions being disposed in the anode water circuit (4). A free-radical scavenger (20) is disposed in the cathode water pathway (14).
Resumen de: WO2026053829A1
Provided is a device capable of producing high purity hydrogen gas. Provided is a method capable of producing high purity hydrogen gas. This hydrogen gas production device comprises a cathode, an anode disposed facing one side of the cathode, and a solid electrolyte member disposed between the cathode and the anode, the hydrogen gas production device being provided with a hydrogen gas recovery passage disposed on the other side of the cathode.
Resumen de: WO2026052984A1
The present invention relates to a multipurpose generator for producing gaseous oxygen and hydrogen, water and electricity, comprising a spherical reactor with two external branches of operatively connected components, namely a warm air flow branch and a cold air flow branch. The warm air flow branch contains: a water inlet connected to a vaporiser associated with a water vapour fan device having a non-return valve that channels said flow to a water vapour intake pipe connected to a diffuser. The cold air flow branch comprises: a cold air mass inlet connected to a cold air circulation intake pipe associated with a cooler in turn coupled to a cold air fan having a non-return valve that channels said flow to a pipe connected to a fluid inlet diffuser distributing the cold air mass to the reactor. The invention also comprises two radially opposite electrical connectors.
Resumen de: WO2026051918A1
The aim of the present invention is to provide an alkaline water electrolysis membrane having good gas barrier property, which can maintain hydrophilicity during operation in long-term electrolysis, inhibit the reduction in ion permeability caused by bubble attachment, and improve the hydrogen production efficiency during the long-term operation of an alkaline electrolytic cell. The alkaline water electrolysis membrane is an electrolysis membrane capable of inhibiting the reduction of hydrophilicity thereof during long-term use and achieving a high production yield of hydrogen. The electrolysis membrane comprises: a porous support, and a porous resin containing a surfactant.
Resumen de: WO2026053545A1
This water splitting device produces hydrogen through irradiation with light and comprises: an electrolytic cell filled with an electrolyte solution and a water splitting cell immersed in the electrolyte solution. The water splitting cell has: a laminate in which an anode electrode, a hole transport layer, a perovskite battery layer, an electron transport layer, and a cathode electrode are stacked in this order; and an electrically insulating protective material that covers the outer periphery of the laminate. Two or more perovskite battery cells are connected in series in the perovskite battery layer.
Resumen de: US20260071333A1
The problem addressed by the invention is that of specifying a process for producing lithium hydroxide that is very energy-efficient. The process should in particular manage without using thermal energy. As a raw material, the process should be able to process Li-containing waters that arise when used lithium-ion batteries are digested. The LiOH produced by the process should be of sufficiently high purity that it can be used directly for the production of new LIBs. The process should achieve a high throughput and have a low space requirement so that it can be combined with existing processes for reprocessing used LIBs or for producing new LIBs to form a closed, continuous production cycle. The process according to the invention is an electrolytic membrane process that is operated using an LiSICon membrane. A particular aspect of the process is that the electrolysis is operated up to the precipitation limit of the lithium hydroxide.
Resumen de: WO2026050800A1
The invention provides a membrane electrode assembly for an electrochemical hydrogen compressor, the membrane electrode assembly comprising a proton exchange membrane arranged between an anode and a cathode, wherein the anode comprises an electrocatalyst for dihydrogen oxidation and the cathode comprises an electrocatalyst for proton reduction, and wherein the proton exchange membrane comprises a semicrystalline polymeric matrix comprising a hydrophilic polymer and particles of an inorganic metal compound dispersed in the semicrystalline polymeric matrix.
Resumen de: CN120835942A
An electrochemical cell stack (1) comprising a plurality of electrochemical cells (2) separated from one another by bipolar plates (5) wherein each electrochemical cell (2) consists of two half-cells (3, 4) having a membrane (6) as a common component, which membrane is held by a multi-piece support frame (7), according to the invention, the multi-part support frame (7) consists of two frame elements (16, 17) of different widths, each of which is stacked on one another from belonging to one half-cell (3, 4) and by inserting a plurality of layers of sheet devices (9) overlapping the membrane (6), on the inner side of each frame element (16, 17) facing the interior of the respective half-cell (3, 4), the frame elements (16, 17) are each provided with a seal (14, 15) which contacts the bipolar plate (5), and the two seals (14, 15) which are offset from each other due to different cross-sectional shapes of the frame elements (16, 17) each contact an outer layer (18, 20) of the sheet device (9).
Resumen de: AU2024265029A1
A system and method for transporting and distributing hydrogen, reducing the risk of hydrogen leakage, maintaining a record of provenance, and measuring and recording its purity level as it flows from source to destination to assure it complies with a predetermined range of values. The system includes a hydrogen delivery line made from metallic or non-metallic pipe that may be placed inside a safety pipe such that a channel is formed between an exterior of the hydrogen delivery line and an interior of the safety pipe. A sweeper gas or liquid may be injected into the channel to purge any hydrogen that might escape from the hydrogen delivery line, and one or more sensors may be used to detect and avoid the presence of an unacceptable level of hydrogen, or to stop the flow of hydrogen and remediate the problem well before a safety or environmental risk can occur.
Resumen de: EP4707429A1
The present application relates to the field of electrolysis hydrogen production technologies, and discloses a water electrolysis hydrogen production system and a method and an apparatus for controlling gas purity in a water electrolysis hydrogen production process, to implement separate control of flow rates at a hydrogen-side inlet and an oxygen-side inlet of an electrolyzer. The water electrolysis hydrogen production system includes an electrolyzer, a hydrogen gas-liquid separation unit, and an oxygen gas-liquid separation unit. A liquid outlet of the hydrogen gas-liquid separation unit is connected to a first pipeline, a liquid outlet of the oxygen gas-liquid separation unit is connected to a second pipeline, the first pipeline and the second pipeline converge and connect to one end of an alkali electrolyte return main pipeline, and the other end of the alkali electrolyte return main pipeline is connected to an oxygen-side pipeline and a hydrogen-side pipeline. The hydrogen-side pipeline is connected to a hydrogen-side alkali electrolyte flow channel inlet of the electrolyzer, and the oxygen-side pipeline is connected to an oxygen-side alkali electrolyte flow channel inlet of the electrolyzer. The hydrogen-side pipeline and the oxygen-side pipeline are respectively provided with a flow rate detection assembly and a flow rate regulation assembly. A hydrogen-side gas outlet of the electrolyzer is connected to the hydrogen gas-liquid separation unit, and an oxygen-side gas o
Resumen de: EP4707232A2
A hydrogen generation system with controlled water distribution is disclosed. The system comprises a reaction chamber containing a hydrogen-producing fuel, a liquid distribution mechanism, and a control system. The liquid distribution mechanism includes a rotating arm with liquid injection ports that move vertically through the fuel chamber. This allows for precise and efficient liquid delivery to unreacted fuel, optimizing hydrogen production. A proprietary fuel blend utilizes chemicals that store significant amounts of hydrogen in a solid-state form. A feature of the device is the arm's controlled vertical movement, achieved through a screw mechanism that adjusts the arm's height as it rotates, creating a spiral liquid distribution pattern. The control system regulates liquid injection rates, arm rotation speed, and vertical movement to optimize hydrogen production based on demand. The system can also operate at low pressures and be scaled to different sizes in a safer, more efficient, on-demand manner.
Resumen de: TW202436694A
A hydrogen generator with extractable filter includes a water tank, an electrolysis module configured in the water tank, a filtering device coupled to the water tank, a humidifying module vertically configured above the water tank, an integrated passageway module vertically configured above the humidifying module, and a condenser configured on the integrated passageway module. The electrolysis module is configured to electrolyze water contained in the water tank to generate gas comprising hydrogen. The humidifying module includes a humidifying chamber and a gas passage isolated from the humidifying chamber. The filtering device is disposed in the gas passage to receive and filter the gas comprising hydrogen generated by the electrolysis module. The condenser is configured to condense the gas comprising hydrogen outputted by the filtering device. The integrated passageway module includes a gas input channel for guiding the gas comprising hydrogen outputted from the condenser into the humidifying chamber.
Resumen de: US20260055516A1
A water electrolysis cell includes a membrane-electrode assembly, a frame body made of resin that is provided along a peripheral edge of the membrane-electrode assembly, and a first separator and a second separator that face each other through the membrane-electrode assembly and the frame body and are joined to each other by the frame body. An outer peripheral portion of the membrane-electrode assembly is extended to between a first face of the frame body and the first separator. A surface of the first face includes an antioxidant.
Resumen de: CN120659908A
A hydrogen generating battery includes a pair of input electrode plates, a pair of output electrode plates, an additional X-plate electrode positioned adjacent the pair of output electrode plates, and a plurality of intermediate electrode plates disposed between the pair of input electrode plates and the pair of output electrode plates. The plasma torch is spaced apart from and inductively coupled to the pair of input electrode plates. A pulsed DC voltage is applied to the plasma torch and the X-plate, while a lower pulsed DC voltage is applied to the pair of input and output electrode plates such that hydrogen gas is generated from the aqueous solution in which the battery is immersed.
Resumen de: US20260002270A1
An enclosure adapted for a hydrogen and oxygen generating apparatus arranged in a movable has an interior and an interior surface and an exterior surface whereby the hydrogen and oxygen generating apparatus comprises at least one electrolyser stack adapted for electrolysing water to hydrogen product gas and oxygen product gas and accompanying gas and electrolyte handling equipment. The exterior surface of the enclosure comprises at least a heat insulating, flexible polymer cover element which is attached to a metal frame.
Resumen de: JP2026038393A
【課題】アンモニアメタネーションにより効率よくメタン含有流体を製造する技術を提供する。【解決手段】アンモニアと二酸化炭素とを含有する原料流体からメタン含有流体を生成するにあたり、アンモニア分解活性、及びメタネーション活性を有する第一触媒が充填された第一反応器31に前記原料流体を供給し、アンモニアの分解、及びメタネーションを進行させて中間生成流体を得る。次いで、第一反応器31から流出した前記中間生成流体を冷却した後、メタネーション活性を有する第二触媒が充填された第二反応器32に供給してメタネーションを進行させ、メタン含有流体を得る。【選択図】図6
Resumen de: JP2026038451A
【課題】電解質膜の更なる劣化を抑制できる水電解システムを提供する。【解決手段】水素極と、酸素極と、水素極および酸素極の間に位置する電解質膜と、を有する水電解システムは、電解質膜の劣化状況を検出する劣化検出部と、水電解システムの起動時に、検出された前記劣化状況に応じて、水素極において発生する水素の圧力の上昇速度と圧力の上限値とのうち少なくとも一方を調整する水素調圧部と、を備える。【選択図】図1
Resumen de: WO2025048510A1
The present invention relates to a separator in which an anode catalyst layer is coated on one surface of a porous substrate, and an electrochemical cell comprising same, the separator allowing ions to smoothly move through pores of the porous substrate and exhibiting low overpotential due to having the anode catalyst layer coated on one surface thereof.
Resumen de: WO2026047670A1
The invention provides Pt 1-99- Ir1-99-Mo-99 aerogel useful as a bifunctional electrocatalyst in a unified regenerative fuel cell. Also provided is a unified regenerative fuel cell and a method of storing and producing energy with the aid of a liquid hydrogen carrier (LHC) as a fuel material in a unified regenerative fuel cell.
Resumen de: WO2026046825A1
The invention relates to a method for ammonia synthesis, comprising: providing hydrogen and nitrogen; supplying the hydrogen and the nitrogen to an ammonia synthesis circuit (20) comprising an ammonia converter (3) in which ammonia is catalytically synthesized, wherein a reactant gas mixture is supplied to the ammonia converter (4) and a product gas mixture is discharged from the ammonia converter (6); a circulator (1) which supplies a reactant gas mixture containing the hydrogen and the nitrogen to the ammonia converter (3); and a separator (11) in which ammonia is separated from a product gas mixture of the ammonia converter (4); wherein the ammonia synthesis circuit (20) is operated in a full-load operation in which a nominal flow rate of the hydrogen is provided to the ammonia synthesis circuit (20), and wherein the ammonia synthesis circuit (20) is either transferred from the full-load operation to a partial-load operation or from a partial-load operation to the full-load operation, wherein a flow rate of hydrogen is provided to the ammonia synthesis circuit (20) in the partial-load operation which is lower than the nominal flow rate, wherein, in the partial-load operation, a bypass gas flow branches off from the reactant gas mixture between the circulator (1) and the ammonia converter (4) and is supplied to the product gas mixture between the ammonia converter (4) and the separator (11).
Resumen de: WO2026046719A1
The invention relates to a method for catalytically producing methanol from biomass by means of electric current, wherein in a first stage, O2 and H2 are produced from water by electrolysis, wherein in a second stage, the biomass is converted into formic acid by means of an aqueous solution of a first catalyst in a first reaction vessel (R1), wherein the first catalyst reduced in the catalytic reaction is converted back into its initial state by oxidation, wherein for the oxidation thereof the oxygen produced in the first stage is introduced into the solution in the first reaction vessel (R1), wherein the solution with the formic acid resulting therein is transferred to a second reaction vessel (R2), wherein methanol is added to the solution during transfer into the second reaction vessel or in the second reaction vessel (R2), wherein the second reaction vessel (R2) is designed as a rectification column which optionally contains an acidic second catalyst which catalyses esterification of the methanol with the formic acid, wherein the second catalyst is present in solid form as a bed or in liquid form as an acid, wherein a reactive distillation is carried out in the second reaction vessel (R2) and the resulting methyl formate is transferred into a tank (T), wherein in a third stage, the methyl formate is evaporated from the tank (T) and is transferred to a third reaction vessel (R3) and there is hydrogenated with the H2 from the first stage by means of a third catalyst which c
Resumen de: WO2026048903A1
A titanium porous body according to the present invention comprises a powder sintered body and is formed in a sheet shape having a thickness of 200 μm or greater. In the titanium porous body, holes present in a cross-section extending along the thickness direction have an average aspect ratio of 3.2 or higher, the aspect ratio being calculated as a ratio of the thickness-direction length of a hole to the width-direction length of the hole, within a visual field measuring 200 μm × 200 μm in the cross-section.
Resumen de: WO2026048255A1
A water electrolysis cell and a water electrolysis system comprising: an ion exchange membrane; a cathode-side catalyst layer disposed on one side of the ion exchange membrane; an anode-side catalyst layer disposed on the other side of the ion exchange membrane; and a metal impurity removal layer disposed between the ion exchange membrane and the cathode-side catalyst layer and/or between the ion exchange membrane and the anode-side catalyst layer.
Resumen de: WO2026045952A1
An aluminum composite material for hydrogen production by hydrolysis, comprising an aluminum-based core and a composite layer formed on the surface of the aluminum-based core. The aluminum-based core comprises, by mass fraction: 90-95% of aluminum and the balance being a magnesium-sodium alloy. The composite layer comprises a carbon-based skeleton attached to the surface of the aluminum-based core and a titanium-iron oxide formed on the carbon-based skeleton. According to the composite material, the aluminum-based core can be prevented from reacting with oxygen to generate an aluminum oxide thin film, thereby increasing the hydrogen yield and hydrogen production rate of the aluminum composite material during hydrogen production. The present invention also relates to a preparation method for and a use of the aluminum composite material for hydrogen production by hydrolysis.
Resumen de: WO2026045877A1
The present application provides an electrolytic cell, an anode catalytic material, a preparation method therefor, and a use thereof. The anode catalytic material in the present application comprises: a substrate, which is an alloy comprising nickel and iron elements; and a nickel-rich oxide layer, which covers the surface of the substrate, wherein the nickel-rich oxide layer comprises nickel oxide and/or nickel hydroxide, and the mass content of nickel element in metal components of the nickel-rich oxide layer is greater than 70%. The anode catalytic material uses a nickel-iron alloy as a substrate, and the addition of iron element can effectively reduce the oxygen evolution overpotential of the substrate material; the nickel-rich oxide layer covering the surface of the substrate can passivate the substrate, and inhibit the dissolution of metal ions, preventing collapse of the skeleton structure of the alloy substrate, thereby maintaining mechanical stability; when the nickel-rich oxide layer is used as an anode, the thickness of the nickel-rich oxide layer does not increase significantly, thus not affecting the catalytic performance thereof; the nickel oxide and/or nickel hydroxide contained in the nickel-rich oxide layer and nickel iron hydroxide which may also be contained therein are also used as active components, thereby further ensuring the catalytic activity of the material.
Resumen de: US20260063035A1
A lunar regolith reduction reactor system includes a housing, a crucible, and a pair of electrodes. The housing includes a base structure and a cover structure detachably connected to the base structure, a gas input port to permit input of hydrogen gas into the housing, and a gas output port to permit outgassing of water vapor and gases. The crucible is designed to hold an amount of lunar regolith in the housing. The electrodes are disposed apart from one another and adjacent the crucible, wherein the electrodes are connectable to a power source to generate an electric arc to heat lunar regolith in the crucible and initiate a reduction reaction to separate oxygen gas and reduce separated material into a molten state.
Resumen de: US20260062823A1
A method of preparing bismuth vanadate particles is described. The bismuth vanadate particles prepared via ultrasonication and hydrothermal treatment exhibit controlled morphology (e.g., octahedral shape) and crystallinity (e.g., tetragonal crystal symmetry). A photoelectrode containing bismuth vanadate particles and a method of using the photoelectrode in a photoelectrochemical cell for water splitting is also provided.
Resumen de: US20260062816A1
A method of operating an electrolyzer system includes electrolyzing water into oxygen and inlet hydrogen using a polymer electrolyte cell (PEC) module including PECs, providing the inlet hydrogen to solid oxide electrolyzer cell (SOEC) modules that each include at least one SOEC stack, providing steam to the SOEC modules, and electrolyzing the steam to generate oxygen and a main product stream containing hydrogen.
Resumen de: US20260063069A1
A raw material fluid treatment plant is provided with a raw material reaction apparatus for reacting a raw material fluid to form a reaction gas. The raw material reaction apparatus includes preheaters and a reactor. The preheaters are heat exchangers that perform heat exchange between a second heat transfer medium and the raw material fluid to heat the raw material fluid. The reactor is a heat exchanger that performs heat exchange between a first heat transfer medium differing from the second heat transfer medium and the raw material fluid having been heated by the preheaters to heat and react the raw material fluid.
Resumen de: US20260066320A1
A method for generating power or producing hydrogen from a carbon source, the method including a chemical conversion step of making, in a chemical conversion unit, a mixture obtained by mixing a solution containing an intermediate medium with a carbon source to react at a temperature at which chemical exergy of the carbon source exceeds chemical exergy in a reduced state of the intermediate medium to reduce the intermediate medium while oxidizing the carbon source, an electrochemical conversion step of bringing the intermediate medium reduced at the chemical conversion step into contact with an anode of a battery structure in an electrochemical conversion unit including the battery structure, and bringing oxygen or air into contact with a cathode of the battery structure to generate power, or bringing water into contact to produce hydrogen, and a reuse step of returning a solution containing the intermediate medium after the electrochemical conversion step to the mixture, and an energy conversion system.
Resumen de: US20260063249A1
A system for compressing, storing and providing gas, in particular hydrogen, having a compressing device, a storage device, an expansion machine and a refrigeration machine, in particular an absorption-type refrigeration machine, wherein the system is configured to compress received gas by means of the compressing device, in particular in multiple stages, and to store the compressed gas in the storage device, wherein the system is configured to refrigerate the compressing device using the refrigeration machine and the expansion machine.
Resumen de: US20260062820A1
In a method for connecting a pair of electrolyser stacks with electrolyte, electric current and gas drain piping, each pair of stacks of the electrolyser: through interconnection endplates are supplied with alkaline electrolyte at elevated pressure by common electrolyte supply pipes and further, through the interconnection endplate drain off oxygen gas containing electrolyte, and hydrogen gas containing electrolyte, to common gas separation vessels for oxygen and hydrogen respectively, pull first electrically interconnected current injection electrodes adjacent to interconnection endplates to zero electrical potential through a zero potential conductor, and supply second current injection electrodes placed adjacent to distal endplates with electric current at potentials equally higher and lower respectively than the zero potential at the first electrodes.
Resumen de: AU2024337380A1
An electrolyzer stack in which gas passages (16C, 16D) and thin and long shunt-current reducing liquid passages (16A, 16B) are provided inside a gasket that is a combination of a first and a second gasket part (12A, 12B) for ease of assembly.
Resumen de: US20260066650A1
A plant network has an electrolysis plant, a power supply source, and a central supply line connected to a DC voltage output of the power supply source for feeding a direct current into the central supply line. The electrolysis plant is connected to a central DC network for a high voltage via the central supply line. The power supply source has a wind turbine as a power generator and a rectifier with a DC voltage output for the high voltage. An energy storage system can feed a direct current into the central supply line. A DC supply network controls three different DC voltage levels independently, namely, a first DC voltage for charging and discharging an electrical storage battery of the energy storage system, a DC-Bus high voltage on the central supply line, and a DC operating voltage of the electrolysis plant.
Resumen de: US20260055519A1
An electrolysis apparatus operation system includes an electrolysis apparatus, a control unit, a target state-of-health value input unit, and a control parameter calculating unit. The electrolysis apparatus has a plurality of electrolytic stacks in which a plurality of electrolytic cells that produce hydrogen by electrolyzing water are stacked. The control unit controls a controlled subject based on a control parameter that affects state-of-health of the controlled subject. The target state-of-health value input unit allows a system user to input a target state-of-health value that is a target value for state-of-health. The control parameter calculating unit calculates a control parameter of the controlled subject based on the target state-of-health value. The controlled subject is the electrolysis apparatus.
Resumen de: DE102024208419A1
Elektrolysesystem zur elektrolytischen Spaltung von Wasser in Wasserstoff und Sauerstoff, mit einer elektrolytischen Zelle (1), die einen Anodenraum (2) und einen Kathodenraum (3) aufweist, die voneinander durch eine semipermeable Barriere getrennt sind, und mit einem Anoden-Wasserkreislauf (4), der über einen Anodenzulauf (5) den Anodenraum (2) mit Wasser versorgt und der über einen Anodenablauf (6) Wasser aus dem Anodenraum (2) aufnimmt, wobei im Anoden-Wasserkreislauf (4) ein Gas-Wasser-Separator (8) und eine Pumpvorrichtung (9) angeordnet sind. Das Wasser aus dem Kathodenraum (3) wird in einem Kathoden-Wasserpfad (14) aufgenommen und in den Anoden-Wasserkreislauf (4) einspeist, wobei im Kathoden-Wasserpfad (14) ein zweiter Gas-Wasser-Separator (17) angeordnet ist und im Anoden-Wasserkreislauf (4) ein Ionentauscher (10) zum Entfernen von Metall-Ionen. Im Kathoden-Wasserpfad (14) ist ein Radikalfänger (20) angeordnet.
Resumen de: WO2026047273A1
An object of the invention is a solid oxide steam electrolysis system comprising a steam feed (1), a gas recycle device (10) that supplies hydrogen from feed-in line (51) to the steam feed (1), and flow rate of the hydrogen from the gas recycle device (10) is being configured to control the partial pressure of hydrogen in the inlet of the cathode compartment from fuel gas supply structure (22) of the solid oxide electrolysis stack structure (30). A first heat management system (20) is being configured to heat the steam-hydrogen gas mixture in line (21) to 400 - 900 °C and is being configured to supply the gas from fuel gas supply structure (22) to the cathode compartment of the solid oxide electrolysis stack structure (30) to reduce steam into hydrogen and oxygen ions by a first controlled current from a power source (70). In the system the hydrogen-steam mixture in product gas line (23) being fed to the first heat management system (20) transferring energy to the inlet gas mixture from line (21), and the hydrogen-steam mixture from the first heat management system (20) in fluid line (24) being fed through a second heat management system (40) where the gas mixture is partly condensing and producing two-phase hydrogen-water-steam mixture to line (41). The steam flow rate in fuel gas supply structure (22) to the cathode compartment of the solid oxide electrolysis stack structure (30) is being controlled based on the first controlled current of a power supply (70). The steam fl
Resumen de: WO2026050250A1
Methods of producing a product, such as methods that include irradiating a susceptor material with electromagnetic radiation, and contacting the susceptor material and a fluid to produce the product. The irradiating of the susceptor material may produce an electric current, a field, and/or generate heat, which can effect a chemical reaction of the fluid or a component thereof. Apparatuses and systems, which include a susceptor material disposed in a container.
Resumen de: WO2026047671A1
The invention provides a method of storing and producing energy with the aid of a liquid hydrogen carrier (LHC) as a fuel material in a unified regenerative fuel cell having bifunctional electrocatalyst on its oxygen electrode. A fuel cell system comprising the unified regenerative fuel cell and a fuel supply and regeneration installation for the LHC is also provided.
Resumen de: AU2024263112A1
The present invention relates to an electrode and in particular to an electrode suitable for gas evolution comprising a metal substrate and a catalytic coating. Such electrode can be used as an anode for the development of oxygen in electrolytic processes such as, for example, in the alkaline electrolysis of water.
Resumen de: GB2643827A
An energy storage system (60) comprises a high temperature electrolyser (70), and a battery pack (65) with cells (10) that comprise a ceramic electrolyte, means (75) to supply steam at above 400°C to the high temperature electrolyser (70), and means to carry a gas stream (77) containing hydrogen away from the high temperature electrolyser (70). The system (60) includes means (78, 82) to maintain the battery pack at an operating temperature above 170°C by use of heat from the high temperature electrolyser (70). The system (60) may be used in conjunction with a renewable energy source (62) of variable power output.
Resumen de: WO2024223362A1
The invention provides an electrochemical stack (1) comprising a plurality of electrochemical cells (2) oriented horizontally and arranged between a top plate (4) and a bottom plate (3) of the stack (1), wherein the top plate (4) and the bottom plate (3) are braced relative to one another by a bracing means (5). At least one connection for supplying gaseous and/or liquid media to or removing them from the electrochemical cells (2) is provided on the top plate (4). The top plate (4) has suspension means (17) configured to fasten the electrochemical stack (1) to a frame (15), wherein the bottom plate (3) is free-floating. The mounting assembly for mounting the electrochemical stack comprises a frame (15), on which the electrochemical stack (1) rests with its suspension means (17) such that the bottom plate (3) is free-floating and the electrochemical cells (2) are oriented horizontally.
Resumen de: CN121039328A
A solid-state oxide cell stack has at least one connection plate between the solid-state oxide cell stack and adjacent end plates, between two adjacent end plates, and/or between adjacent five solid-state oxide cell sub-stacks.
Resumen de: AU2024262986A1
The invention relates to the coating of cation exchange membranes with catalytically active substances. The catalytically actively coated cation exchange membranes are used in electrochemical cells, especially in fuel cells (proton exchange membrane fuel cells - PEMFC) or in electrolysers for water electrolysis (polymer electrolyte membrane water electrolysis - PEMWE). In order to counteract the disadvantages of conventional decal processes, an alterative process for coating cation exchange membranes was sought which enables the transfer of electrocatalysts without the need for high temperatures, high pressures and PFAS-based substrates. It was surprisingly found that catalyst layers which are treated, shortly before the transfer step, with a polymer-swelling solvent conducting the cations can be transferred far more easily.
Resumen de: MX2025012716A
An electrochemical device including: - at least one electrochemical cell, - two fluid lines, - a pre-heating unit for preheating at least one of the fluids before feeding the at least one fluid to the system, a load device for electrically oading the at least one electrochemical cell, - temperature sensors, - pressure sensors for detecting a pressure and/or a differential pressure, the device comprises a control management system. The control management system : - is configured to keep a temperature gradient between the inlet side and the exhaust side of at least one fluid line below a predefined system critical temperature gradient and/or to control a minimum temperature and/or a maximum temperature cross the electrochemical device compared with a pre-defined temperature reference; and/or - is configured to control the di f ferential pressure between the two fluid lines; and/or - is configured to control the pressure drop of at least one fluid line; and/or - is configured to control at least one maximum pressure and/or at least one minimum pressure of the fluid in the electrochemical device compared to a pre-defined pressure reference.
Resumen de: CN121013919A
The invention relates to a cell layer (200) for an electrolysis cell stack (60) of an electrolysis device group (51), in particular a water electrolysis device group (51), comprising a frame (250), in particular a cathode frame (250), in the main central region of which a transport structure (210) of the electrolysis cell stack (60) is accommodated, said frame (250) comprising at least one circumferentially open through-passage opening (256), in which the transport structure (210) of the electrolysis cell stack (60) is accommodated, the access through hole is used for electrolyzing an effluent product medium (56) of the cell stack (60); a fluid flow path (257) is arranged between the inner edge of the frame (250) and the outer edge of the transport structure (210) beside the product medium passage through-holes (256), the fluid flow path (257) leading to at least one of the product medium passage through-holes (256).
Resumen de: WO2024223472A1
A method for storing hydrogen in a reactor or a synthesis loop comprising the steps of (a) providing a gaseous stream of a reaction compound; (b) providing an excess of a hydrogen stream as required for stoichiometric molar ratio of reactants to hydrogen in the synthesis loop or reactor from an electrolysis unit; (c) storing the excess of hydrogen provided in step (b) by introducing at least an amount of the hydrogen stream into the gaseous stream of a reaction compound and to provide a mixed stream of hydrogen and gaseous reaction compound with at least 25 mol % excess hydrogen than what is required for a reaction of the reaction compound with hydrogen in the hydrogen stream; (d) introducing the mixed stream into the reactor or the synthesis loop; (e) withdrawing a mixed stream of gaseous reaction product and unreacted gaseous hydrogen and reaction compound from the reactor or the synthesis loop; (f) separating the reaction product from the unreacted gaseous hydrogen and reaction compound (g) recycling all or a part of unreacted amounts of hydrogen and reaction compound to the reactor or synthesis loop.
Resumen de: CN120813541A
The invention relates to a method for purifying an oxygen stream contaminated by water, hydrogen and possibly nitrogen, said method comprising contacting the oxygen stream to be purified with a zeolite-based adsorbent material comprising at least one metal in the form of a zero-valent metal, or in the oxidized or reduced form, and recovering the purified oxygen stream. The invention also relates to the use of a zeolite-based adsorbent material comprising at least one transition metal for purifying oxygen, and to the use of the oxygen thus purified in industrial processes.
Resumen de: AU2024220092A1
This disclosure relates to polymer electrolyte membranes, and in particular, to a composite membrane having at least two reinforcing layers comprising a microporous polymer structure and a surprisingly high resistance to piercing. This disclosure also relates to composite 5 membrane-assemblies and electrochemical devices comprising the composite membranes of the disclosure, and to methods of manufacture of the composite membranes. 21188108_1 (GHMatters) P120981.AU.1
Resumen de: WO2026040290A1
A hydrogen evolution electrocatalyst, a preparation method therefor, and the use thereof. The hydrogen evolution electrocatalyst comprises a nickel foam substrate, a Ni3S2 nanosheet layer and a graphdiyne coating layer; at least part of the outer surface of the nickel foam substrate is provided with the Ni3S2 nanosheet layer; nickel atoms in the Ni3S2 nanosheet layer come from the nickel foam substrate; at least part of the outer surface of the Ni3S2 nanosheet layer is provided with the graphdiyne coating layer. The hydrogen evolution electrocatalyst has the characteristic of high catalytic activity.
Resumen de: AU2024324493A1
A membrane-electrode assembly for a water electrolyser is provided. The membrane- electrode assembly comprises a polymer electrolyte membrane with a first face and a second face; an anode catalyst layer on the first face of the membrane, the anode catalyst layer comprising an oxygen evolution reaction catalyst; and a porous web of polymer fibres in contact with the anode catalyst layer, the polymer fibres comprising a conductive metal additive.
Resumen de: US20260055516A1
A water electrolysis cell includes a membrane-electrode assembly, a frame body made of resin that is provided along a peripheral edge of the membrane-electrode assembly, and a first separator and a second separator that face each other through the membrane-electrode assembly and the frame body and are joined to each other by the frame body. An outer peripheral portion of the membrane-electrode assembly is extended to between a first face of the frame body and the first separator. A surface of the first face includes an antioxidant.
Resumen de: US20260049408A1
An electrolysis system includes an electrolyzer stack and a contamination mitigation system. The electrolyzer stack includes an injection port fluidly connected with a cathode compartment of the electrolyzer stack. The contamination mitigation system is configured to remove ions from the electrolyzer stack to mitigate ion contamination in the electrolyzer stack. The contamination mitigation system includes a storage tank including formic acid therein and an injection line fluidly coupled between the storage tank and the injection port. The injection line is configured to direct the formic acid from the storage tank to the injection port for injection into the cathode compartment of the electrolyzer stack.
Resumen de: CN121593092A
本发明提供一种能够抑制电解质膜的进一步劣化的水电解系统。水电解系统具有氢极、氧极、以及位于氢极与氧极之间的电解质膜,并且进一步具备:劣化检测部,其检测电解质膜的劣化状况;以及氢调压部,在水电解系统启动时,氢调压部根据检测出的所述劣化状况,对在氢极中产生的氢的压力的上升速度和压力的上限值中的至少一方进行调整。
Resumen de: CN120787177A
The invention provides a ruthenium catalyst for ammonia decomposition reaction and a production method thereof. The ruthenium catalyst exhibits a conversion rate of almost 100% at a reaction temperature of 550 DEG C, even further exhibits a conversion rate of 93.6% or more at 500 DEG C, and also exhibits a conversion rate of about 60% or more at a low reaction temperature of 450 DEG C, so that the catalyst has excellent ammonia decomposition activity and low manufacturing cost, and can be used in the field of catalytic cracking. And therefore, the method is economical for ammonia decomposition processes even in large-scale decomposition processes at relatively low temperatures.
Resumen de: US20260048995A1
A method for manufacturing nano metal oxides and hydrogen includes the following steps: Step A, providing a first reactor, and placing a metal material, an alcohol compound, and a first catalyst in the first reactor and applying heating thereto for reacting to generate a metal alkoxide compound, while simultaneously generating a substantial amount of hydrogen; and Step B, providing a second reactor, and, after the metal material in the first reactor has fully reacted in Step A, transferring remaining solution in the first reactor into the second reactor, and adding a second catalyst and a controlled amount of water, and applying appropriate heating to generate nano metal oxide in powder form. As such, effects of significant reduction of production cost, enhancement of safety, widespread application of hydrogen fuel cells, extremely low carbon emissions, being defined as “green hydrogen”, and reduction of storage costs and risks can be achieved.
Resumen de: MA73371A1
A Solid Oxide Cell stack has at least one connection plate between the solid oxide cell stack and an adjacent end plate, two adjacent end plates and/or between adjacent solid oxide cell sub-stacks.
Resumen de: KR20240154110A
The present invention relates to a method for preparing a complex metal catalyst in the form of a tri-metal of ruthenium, yttrium, and potassium by using a thermally transformed delta-alumina support and to a method for preparing hydrogen through an ammonia cracking reaction using the same. An ammonia cracking catalyst according to the present invention adjusts the ratio of ruthenium/potassium + yttrium, along with a thermally transformed alumina support in a specific phase, even when using a low content of ruthenium metal, minimizes the contents of chlorine and nitrogen compounds, which are impurities in the catalyst, and localizes active metals in the catalyst, thereby achieving a very high ammonia conversion rate and hydrogen production efficiency even at low temperatures, compared with a catalyst having the same content of the ruthenium metal.
Resumen de: CN121574674A
本发明涉及质子交换膜电解槽装配技术领域,本发明公开了一种质子交换膜电解槽密封垫片装配用粘接剂及其制备方法,粘接剂包括质量分数如下的原料:原胶5%‑40%、乳化剂1%‑10%、增粘剂2%‑10%和溶剂40%‑90%组成。将原料在20℃‑50℃的环境下充分搅拌,搅拌混合均匀即得到本申请的粘接剂。本发明的粘接剂粘结强度高的同时粘性低、固化时间短,相较传统的粘结剂具有显著的优势;同时,使用方法操作简单、易于点胶,适配各种自动化操作过程,应用本申请的粘接剂能够解决低表面能橡胶和钛金属件难以固定的问题,提升密封垫片搭接效率和搭接稳定性。
Resumen de: CN121577725A
一种模拟阴离子交换膜水电解槽产生反向电流的方法及反向电流对电极影响的加速应力测试应用,它涉及电化学技术领域。产生反向电流的方法:在恒定电解状态下,停机瞬间施加0V,阳极电位会跨越平衡电位,出现‑1.0 V vs. RHE的瞬时反向极化信号,随后快速衰减并趋近于零,表明反向电流已被成功诱发。加速应力测试方法:在不同电流密度下分别运行,每个电流密度下运行后需要重新停机、再启动的操作,重复循环上述操作。本发明实现了对AEMWE阳极失效过程的实时追踪与定量评估,明确了阳极在反向电流条件下的活性衰减路径与惰性覆盖层形成过程,为波动工况下AEMWE电极可靠性评估提供了借鉴。
Resumen de: CN121571065A
本发明涉及新能源制氢技术领域,具体是一种动力装置废热供能的甲酸液相/汽相梯级制氢系统。该系统可充分利用氢燃料电池发动机等动力装置运行过程中的废热,加热甲酸制氢反应液,提高反应液温度进而强化甲酸分解制氢性能,甲酸所产氢气经纯化后进入氢动力装置,为氢动力装置提供氢气来源。
Resumen de: CN121575428A
本发明提供一种可稳定连续独立产生双气泡的双电极结构及制备方法,双电极结构包括外部绝缘管、电极线、内部绝缘管、导线和密封体;内部绝缘管中有第一电极线,外部绝缘管中设有第二电极线,第一电极线和第二电极线平行,第一电极线和第二电极线的第一端连接导线,第一电极线和第二电极线的第二端与外部绝缘管端面平齐并密封,第一端处外部绝缘管、导线以及内部绝缘管之间的间隙设置密封体;内部绝缘管的第一端和第一电极线的第一端均置于密封体中,两根电极线在外部绝缘管内绝缘;在电极表面产生微米级单气泡,防止电解液渗漏导致的短路或腐蚀,从根源上杜绝了电极表面多气泡的产生,保障了电极在同一时刻只产生单气泡,并延长了装置使用寿命。
Resumen de: CN121575439A
本发明属于催化材料技术领域,具体涉及一种珊瑚状铁钴镍铝钼高熵合金催化材料及其制备方法,以及该材料在碱水析氧反应中的应用。本发明通过精准调控电解液中铁、钴、镍、铝、钼五种元素的浓度比例,采用直流恒电流共沉积法,在洁净镍网表面直接生长出铁钴镍铝钼高熵合金珊瑚状结构(简称FeCoNiAlMo HEA)。制备的FeCoNiAlMo HEA催化电极具备较高的反应活性和快速的传质速率,而且表现出优异的稳定性,同时在大电流密度下展现出优异的催化效果;本发明通过组分和结构双重调控,解决传统高熵材料应用中需要粘结剂的使用导致传质受阻和稳定性不足的难题,为解决工业化电极大电流密度下性能较差的痛点提供了新的解决方案。
Resumen de: CN121575449A
本申请设计制氢技术领域,提供电解水制氢隔膜及其制备方法和电解水制氢装置。电解水制氢隔膜,包括基材层和多孔亲水层。其中,多孔亲水层设置于基材层的至少一侧表面,多孔亲水层中分散有多个改性无机颗粒,改性无机颗粒包括无机颗粒以及包覆于无机颗粒至少部分表面的改性材料。改性材料中含有的硅氧烷主链以及聚醚链段和烷基链段,不仅改善了无机颗粒与有机聚合物之间的相容性,而且实现了隔膜的高离子电导率、优异的气体阻隔性、良好的机械强度和长期运行稳定性。
Resumen de: CN121575423A
本发明涉及富氢水制备及氢氧混合供气技术领域,公开了一种可浸入式亲水性多孔钛PEM电解槽,包括阳极端板和阴极端板,阳极端板和阴极端板通过若干紧固螺丝和若干紧固螺母可拆卸连接;电解堆体,位于阳极端板和阴极端板之间,且电解堆体两端与阳极端板和阴极端板之间进行绝缘隔绝;电解堆体两端分别从阳极端板和阴极端板伸出,且分别与外部电源的正极和负极连接。本发明彻底省去传统PEM电解槽的密封结构、输气管道及外部水泵,不仅具备结构极致简化、成本低廉、氢气溶解效率高的优势,更通过明确的材料选型与工艺设计实现“富氢水制备‑氢氧混合供气”一体化,大幅提升高原户外使用的便捷性与实用性。
Resumen de: CN121575483A
本发明提供了一种钛酸锶单晶颗粒及其制备方法与应用。所述钛酸锶单晶颗粒的暴露晶面包括(100)晶面和(111)晶面;且所述钛酸锶单晶颗粒呈锥形多面体结构。本发明提供的钛酸锶单晶颗粒呈锥形多面体结构,暴露晶面只有(100)晶面和(111)晶面,且每个颗粒的(111)晶面暴露比例和面积更大,使得本发明提供的钛酸锶单晶颗粒具有更高的光量子利用率。
Resumen de: CN121575454A
本发明涉及电解水制氢技术领域,具体为一种具有低耗能干燥舱的电解水制氢设备,包括制备机构和循环机构,所述循环机构设在制备机构的左侧,所述制备机构包括储存组件、输送组件和电解组件,所述输送组件设在储存组件的顶部,所述电解组件设在储存组件的内侧,所述循环机构包括导流组件、干燥组件、冷却组件、散热组件、导热组件和回收组件,所述导流组件设在输送组件的左侧,所述干燥组件设在导流组件的内侧。本发明提供了一种具有低耗能干燥舱的电解水制氢设备,具有对含有水蒸气的氢气进行低能耗干燥除湿的结构,因此可以采用低能耗的方式为氢气中的水蒸气进行干燥除湿,提高了长期对氢气中水蒸气干燥除湿稳定性的优点。
Resumen de: CN121575447A
本发明公开了一种自支撑异质结构电催化析氧电极及其制备方法和应用,涉及电解水制氢技术领域。通过一种简单的两步水热方法直接在泡沫镍上生长一种新型的纳米棒(Ni3S2)负载高活性纳米簇(FeS/MoS2)异质结构的三维复合材料。第一步合成的短棒状Ni3S2有利于反应物(H2O、OH‑)的吸附和中间体(如O*、OOH*)的形成,而第二步合成的FeS/MoS2/Ni3S2@NF,其中FeS提供了大量的活性位点,MoS2优化了异质结构电子结构。FeS/MoS2/Ni3S2@NF具有较小的电荷转移电阻和优异的电催化性能。在1M KOH溶液中具有优异的OER性能,并保持了较长的工作寿命,在析氧电池中具有应用前景。
Resumen de: CN121574680A
本发明公开了一种具有催化水解离功能胶黏剂的制备方法及应用,属于新能源领域,一种具有催化水解离功能胶黏剂的制备方法,包括以下步骤:S1:将丙烯酸、丙烯酸甲酯、NN‑亚甲基双丙烯酸酰胺、乳化剂、以及纯水进行充分搅拌,升温至40‑60℃,搅拌时间为0.5‑2h,得单体溶液,S2:将引发剂溶解于纯水中得溶液A,且将金属离子化合物溶解于纯水中得溶液B,S3:采用缓慢连续滴加的方式向单体溶液中滴加溶液A和溶液B,滴加时间为0.5‑2h,升温至50‑75℃,反应1‑5h,得到具有催化水解离功能胶黏剂。本发明制得的胶黏剂通过内部活性催化粒子,显著降低了水分子解离的活化能垒,促进电解制氢过程中水的解离效率,进而提高制氢能效。
Resumen de: CN121571185A
本发明公开了一种用于光热氨分解制氢的MoN/Mo2C复合材料的制备方法及应用。该方法将以MoCl5·7H2O与尿素为原料,在氮气气氛中煅烧得到Mo2C,随后通过氨气和氦气的混合气体气氛条件下热得到MoN/Mo2C复合材料。该类复合材料在带有凸透镜聚焦的光源照射下有着优异的氨分解产氢效率。该催化剂在光照作用下不仅能够产生大量的热能,同时生成载流子能够有效地参与催化过程,极大程度地降低反应活化能,光热催化产氢效率远高于其在相同温度下未光照条件下的性能。该发明所涉及的催化剂合成方法简便易放大,光热催化氨分解制氢的方法具有条件温和,能耗低,效率高等特点,具有良好的应用前景。
Resumen de: CN121574352A
本发明公开了一种含有偶极诱导体的阴离子交换膜及其制备方法和应用,其属于高分子膜技术领域,其中,该阴离子交换膜含有刚性扭曲偶极诱导芳基单体Ar1和刚性扭曲芳基单体Ar2。本发明提供的阴离子交换膜具有良好的超高离子导电率和良好的尺寸稳定性,可以促进水电解的高效稳定进行,这是因为该阴离子交换膜的微孔结构能够有效地促进离子的传输,其中包含的全刚性聚合物主链可以限制阴离子交换膜的溶胀,可应用于碱性电解水。
Resumen de: CN121575431A
本发明涉及一种自支撑镧钼钴硼双功能全解水催化剂及其制备方法与应用,属于电催化材料技术领域。所述方法包括将镧盐、七钼酸铵与四水合乙酸钴按设定摩尔比溶于含硼酸与柠檬酸钠的水溶液中,再加入少量硫酸,加热形成均匀电解液;以泡沫镍为工作电极,在‑300至‑200mA cm‑2的电流密度和20-50℃条件下电沉积100-200分钟,得到负载于泡沫镍上的镧钼钴硼材料。该催化剂具备自支撑结构,无需粘结剂,制备过程简单、成本低且环境友好,在析氢反应与析氧反应中均表现出高催化活性与优异的稳定性,适用于高效全水分解系统。
Resumen de: CN121575436A
本发明涉及电催化剂技术领域,具体公开了一种双位点催化剂及其制备方法与应用,本发明提供一种电解水阳极催化剂制备方案,该方案采用温和的低温水热法及乙二醇原位热还原工艺,成功构建了催化位点‑质子传输位点的双位点协同体系,片状磷酸氧铌载体提供了较大的比表面积和优异的质子导电性,确保质子能够迅速传导至电解液中,避免了质子积累带来的负面效应,有效抑制了局部微环境酸化导致的金属铱溶解与脱落,维持催化剂的热力学稳定性,将金属铱纳米颗粒负载在片状磷酸氧铌载体上,金属铱作为反应活性位点,提供了高效的析出反应活性,磷酸氧铌载体作为质子导电位点,协同金属铱提高了反应效率,二者的协同作用显著提升了催化活性和稳定性。
Resumen de: CN121575443A
本发明公开了一种复合电极材料及其制备方法,属于电解水析氢催化剂合成技术领域。本发明的复合电极材料的制备方法,包括以下步骤:将煤质炭、导电剂和粘结剂配制成浆料,涂敷在电极基材上,然后以阶梯型递增电压进行电沉积,得到复合电极材料。本发明制备的复合电极材料具有较低的过电位,电催化性能良好,且具有优异的电催化稳定性。
Resumen de: CN121584591A
本发明公开考虑温度‑压力‑水影响的质子交换膜电解槽自适应调频控制方法,包括以下步骤:1)基于PEMEL动态运行特性,构建考虑温度、压力和含水量耦合效应的PEMEL动态模型,为调频控制策略设计提供精确的模型基础;2)剖析PEMEL在不同稳态运行点下的调频性能;3)剖析PEMEL的温度、压力、含水量对其最大制氢功率的影响机理;4)提出PEMEL在温度、压力、含水量影响下的调频功率补偿方法;5)基于模糊控制理论及PEMEL的运行点实时状态,设计PEMEL的虚拟惯量和一次调频参数自适应整定机制,研究PEMEL自适应调频策略。本发明通过考虑温度‑压力‑水影响的PEMEL自适应调频控制策略实现PEMEL调频性能的精准感知与动态优化控制。
Resumen de: AU2024321116A1
The present invention relates to a methanation method comprising providing an electrolyser system, the electrolyser system (20) comprising an electrolyser (10) that has at least one electrolyser cell (11), at least one fuel input (14) through which fuel enters the electrolyser (10) and at least one offgas output (46) from which offgas exits the electrolyser (10), the method further comprising supplying fuel to the at least one fuel inlet, the fuel comprising at least water and either or both carbon dioxide and carbon monoxide, operating the electrolyser system (20) by powering the electrolyser cell (11) with electricity to electrolyse the fuel in the at least one electrolyser cell (11) such that a part of the water splits into hydrogen and oxygen, wherein the electrolyser (10) is operated at a temperature at or in excess of 150 degrees C, and methanation occurs to the carbon dioxide and/or carbon monoxide in the electrolyser (10). The gas mixture can be released from the at least one offgas output (46) and then passed through a gas separation process to separate at least the methane from the gas mixture. The present invention also relates to an electrolyser system (20) configured to operate using the above method. The electrolyser system (20) comprises a fuel fluid flow path connecting a fuel inlet and a fuel outlet. The method may comprise providing to the fuel inlet a fuel gas containing water and a source of carbon selected from one or more of CO and CO2, operating the ele
Resumen de: CN121574362A
本发明涉及一种高温固相制备酰胺键桥连有机聚合物产氧光催化剂的方法,包括以下步骤:将芳香多元胺单体与芳香多元酰氯单体混合后进行高温处理,冷却,即得;高温处理的温度T满足T1≤T≤T2,高温处理的时间为10~60min,其中,T1为高于芳香多元酰氯单体的熔点且不低于260℃的温度,T2为比芳香多元胺单体的起始分解温度低20℃以上的温度。本发明采用一步高温固相法,通过将反应温度调控在T1与T2之间,利用芳香多元酰氯单体熔融自成溶剂的特性作为反应介质,使得氨基与酰氯基团直接、快速地缩合生成酰胺键,合成周期短;同时,该反应温度条件能够为分子链运动与有序排列提供充足能量,形成高结晶度的聚合物网络,从而表现出较好的光解水产氧性能。
Resumen de: CN121584757A
一种基于多状态协同调度的光伏制氢并网系统及方法,涉及新能源综合利用领域。解决现有因光伏发电的间歇性和波动性导致电解槽运行不稳定、能源综合利用率低及经济效益不佳等问题,所述系统包括光伏发电单元、储能单元、至少一个电解槽单元、储氢单元以及一个控制器。控制器实时监测光伏发电功率、储能单元充电状态和储氢单元储氢状态,并根据预设的多状态协同调度策略执行以下操作:依据光伏功率阈值分级启动电解槽单元;利用储能单元平滑光伏功率波动,为电解槽稳定供电;并且,基于储能单元达到上限或储氢单元达到上限这两个独立的触发条件,动态地将系统富余电能并网售卖。本发明还适用于集成光伏发电、电化学储能、电解水制氢领域。
Resumen de: CN121575432A
本发明属于电极技术领域,公开了一种具备电解水催化功能的钛基抗结垢阴极制备方法,步骤如下:在钛网基底表面构建微结构;在微结构上负载过渡金属催化剂;在具有催化功能的微结构材料表面涂覆惰性涂层。这种阴极表面的惰性涂层会阻碍电子与水分子接触,使仅未被惰性涂层覆盖的微结构尖端充当晶体的初始成核位点。当晶体生长至微米级时,其与微结构尖端的附着力会减弱。同时,电解水产生的气泡会沿惰性涂层生长,并在微结构尖端附近破裂,推动晶体自发脱落,避免沉淀在电极表面堆积。同时微结构上负载的金属阳离子如Ni2+、Co2+可以降低电解海水的过电位。这两种性质使得该阴极可以应用于海水中镁资源的提取。
Resumen de: CN121575437A
本发明公开了一种PdPtCu三元金属烯催化剂,所述催化剂的表面具有晶体、非晶、线缺陷、点缺陷和孔洞,所述PdPtCu三元金属烯由Pd、Pt和Cu三种元素合金化所构成,本发明具有活性和稳定性较高的特点。本申请还公开了PdPtCu三元金属烯催化剂的制备方法和应用。
Resumen de: CN121571061A
本发明涉及制氢设备技术领域,具体为一种结合等离子体与催化剂的氨裂解制氢装置,催化单元包括固定设置在底板上的支架,且其中一组支架上固定设置有控制器,控制器上固定设置有用于添加原料的存料器,底板上固定设置有转化器,存料器与转化器之间通过连接管连通,输料管二的另一端与转化器相连通,催化单元用于对氨气进行裂解反应,氨气通过转化器和输料管一输送至装置的反应罐内,设置在底板上的调节器能够保持氨气输送的稳定性和安全性,同时设置在输料管一上的结合器能够保持反应过程中氨气的稳定性,支撑框架上的混合器能够搅拌催化剂能够保持与溶液的充分接触,增加表面羟基数量,增强与活性组分的结合力。
Resumen de: CN121575440A
本发明属于电极材料技术领域,特别涉及一种双单晶CoS@CoSe2异质结电极及其制备方法和应用。所述异质结电极的结构为在碳布表面原位均匀生长单晶CoS纳米块,并于CoS纳米块表面外延生长单晶CoSe2纳米棒。所制备的双单晶CoS@CoSe2异质结电极在碱性OER测试中表现出卓越的性能。在1 M KOH电解液中,仅需115 mV的极低过电位即可驱动10 mA cm‑2的电流密度。
Resumen de: KR20260026808A
수소 생산 시스템이 제공된다. 본 발명의 일 측면에 따른 수소 생산 시스템은 물과 유기 연료를 이용하여 수소 혼합 유체를 생산하는 제1 수소생성기와, 상기 제1 수소생성기로 유입되는 상기 물과 상기 유기 연료를 가열하는 하나 이상의 히터를 포함하는 제1 수소생성부; 상기 제1 수소생성부에 상기 유기 연료를 공급하는 연료공급부; 상기 제1 수소생성부에 상기 물을 공급하는 물공급부; 및 상기 수소 혼합 유체로부터 수소 기체를 분리하는 흡착부;를 포함하되, 상기 제1 수소생성부는 상기 제1 수소생성기의 하류에 제1 열교환부를 더 포함하고, 상기 제1 수소생성기로 공급되는 상기 물은 상기 제1 열교환부를 경유하여 상기 수소 혼합 유체와 열교환한 후에 상기 제1 수소생성기로 공급될 수 있다.
Resumen de: CN120857975A
The invention discloses a catalyst for ammonia dehydrogenation, a preparation method thereof and a method for preparing hydrogen by using the catalyst. The disclosed catalyst for ammonia dehydrogenation comprises a clay, and an alkali metal and ruthenium impregnated in the clay.
Resumen de: WO2026041485A1
The present invention relates to a bipolar plate (100) for an electrolysis system (200), wherein the bipolar plate (100) comprises: - a main body (101) having a first side (103) and a second side (105) opposite the first side (103), wherein a plurality of channels (107) run at least on the first side (103) from a first end to a second end of the bipolar plate (100) opposite the first end, wherein guide paths (109) are formed between respective adjacent channels (107), and wherein respective channels (107) comprise a number of openings (111) which are configured to guide fluid flowing through the channels (107) into the guide paths (109).
Resumen de: AU2026200812A1
22418031_1 (GHMatters) P121123.AU.1 The present application relates to water electrolyzers, including water electrolyzers incorporating anion exchange membranes. The present applications also 5 relates to materials incorporated into water electrolyzers and approaches for manufacturing water electrolyzers, as well as methods of using water electrolyzers. eb e b
Resumen de: DE102024207916A1
Die vorgestellte Erfindung betrifft eine Bipolarplatte (100) für ein Elektrolysesystem (200),wobei die Bipolarplatte (100) umfasst:- einen Grundkörper (101) mit einer ersten Seite (103) und einer der ersten Seite (103) gegenüberliegenden zweiten Seite (105),wobei zumindest auf der ersten Seite (103) eine Vielzahl Kanäle (107) von einem ersten Ende zu einem dem ersten Ende gegenüberliegenden zweiten Ende der Bipolarplatte (100) verlaufen,wobei zwischen jeweiligen benachbarten Kanälen (107) Leitpfade (109) ausgebildet sind, undwobei jeweilige Kanäle (107) eine Anzahl Öffnungen (111) umfassen, die dazu konfiguriert sind, durch die Kanäle (107) strömendes Fluid in die Leitpfade (109) zu leiten.
Resumen de: DE102025110831A1
Eine Wasserelektrolysezelle beinhaltet eine Membran-Elektroden-Anordnung, einen Rahmenkörper aus Harz, der entlang einer Umfangskante der Membran-Elektroden-Anordnung bereitgestellt ist, und einen ersten Separator und einen zweiten Separator, die einander durch die Membran-Elektroden-Anordnung und den Rahmenkörper gegenüberliegen und durch den Rahmenkörper miteinander verbunden sind. Ein äußerer Umfangsabschnitt der Membran-Elektroden-Anordnung erstreckt sich bis zwischen einer ersten Fläche des Rahmenkörpers und den ersten Separator. Eine Oberfläche der ersten Fläche beinhaltet ein Antioxidationsmittel.
Resumen de: US20260055526A1
There are provided system for preparing lithium hydroxide from an aqueous composition comprising a lithium compound and use of the system thereof to prepare lithium hydroxide, the system comprising an electrochemical cell, a pH probe and at least one inlet for receiving acid or base for maintaining pH. For example, the lithium compound can be lithium sulphate and the aqueous composition can be at least substantially maintained at a pH having a value of about 2 to about 4.
Resumen de: WO2026042828A1
Problem To provide a water electrolysis method and a water electrolysis system with which water electrolysis can be highly efficiently performed under non-extreme pH conditions. Solution Provided is a water electrolysis method in a buffer solution having a pH of 7 to 12, wherein the buffer solution is composed of an electrolyte solution containing at least one cation species selected from the group consisting of alkali metal cations and at least one anion species selected from the group consisting of borates and carbonates, and the electrolyte solution contains 0.1 to 6.0 mol/kg of phosphate ions.
Resumen de: WO2026040290A1
A hydrogen evolution electrocatalyst, a preparation method therefor, and the use thereof. The hydrogen evolution electrocatalyst comprises a nickel foam substrate, a Ni3S2 nanosheet layer and a graphdiyne coating layer; at least part of the outer surface of the nickel foam substrate is provided with the Ni3S2 nanosheet layer; nickel atoms in the Ni3S2 nanosheet layer come from the nickel foam substrate; at least part of the outer surface of the Ni3S2 nanosheet layer is provided with the graphdiyne coating layer. The hydrogen evolution electrocatalyst has the characteristic of high catalytic activity.
Resumen de: WO2026039871A1
The present disclosure relates to hydrogen storage mediums comprising sodium borohydride, magnesium oxide, and magnesium which release hydrogen when contacted with a proton source. The present disclosure also relates to methods of producing hydrogen storage mediums.
Resumen de: KR20260026365A
본 발명에 따른 촉매 구조체 제조 방법은, 전도성 집전체를 준비하는 단계, 전이금속 및 칼코겐 원소를 포함하는 촉매층 소스를 준비하는 단계, 상기 전도성 집전체 상에 상기 촉매층 소스를 코팅하여 예비 촉매층을 포함하는 예비 촉매 구조체를 제조하는 단계, 및 상기 예비 촉매 구조체, 알칼리 금속 전극, 및 전해질을 이용한 전기화학적 양이온 주입 방법으로, 상기 예비 촉매 구조체의 상기 예비 촉매층을 촉매층으로 전환시켜 상기 촉매층을 포함하는 상기 촉매 구조체를 제조하는 단계를 포함하고, 전기화학적 양이온 주입 과정에서, 과전압의 방전에 의해 상기 촉매층의 결정 구조가 반도체 특징을 갖는 결정 구조에서 금속 특징을 갖는 결정 구조로 전환되는 것을 포함할 수 있다.
Resumen de: US20260054247A1
The invention relates to a device, stacked plate reactor and to a method for investigating chemical processes to be carried out simultaneously or almost at the same time on a large number of functional element variations of the process parameters.
Resumen de: US20260055524A1
Low-cost and earth abundant, Ni1-xMox alloy nanocrystals, with sizes ranging from 18-43 nm and varying Mo composition (0.0-11.4%), were produced by a colloidal chemistry method for alkaline HER reactions. For a water splitting current density of −10 mA/cm2, these alloys demonstrate over-potentials of −62 to −177 mV, which are comparable to commercial Pt-based electrocatalysts (−68 to −129 mV). The cubic Ni0.934Mo0.066 alloy nanocrystals exhibit the highest activity as alkaline HER electrocatalysts, outperforming commercial Pt/C (20 wt %) catalyst.
Resumen de: US20260055519A1
An electrolysis apparatus operation system includes an electrolysis apparatus, a control unit, a target state-of-health value input unit, and a control parameter calculating unit. The electrolysis apparatus has a plurality of electrolytic stacks in which a plurality of electrolytic cells that produce hydrogen by electrolyzing water are stacked. The control unit controls a controlled subject based on a control parameter that affects state-of-health of the controlled subject. The target state-of-health value input unit allows a system user to input a target state-of-health value that is a target value for state-of-health. The control parameter calculating unit calculates a control parameter of the controlled subject based on the target state-of-health value. The controlled subject is the electrolysis apparatus.
Resumen de: US20260055518A1
Herein discussed is a method of producing hydrogen comprising: (a) providing an electrochemical reactor having an anode, a cathode, and a membrane between the anode and the cathode, wherein the membrane is both electronically conducting and ionically conducting; (b) introducing a first stream to the anode, wherein the first stream comprises ammonia; (c) introducing an oxidant to the anode; and (d) introducing a second stream to the cathode, wherein the second stream comprises water and provides a reducing environment for the cathode; wherein hydrogen is generated from water electrochemically; wherein the first stream and the second stream are separated by the membrane; and wherein the oxidant and the second stream are separated by the membrane.
Resumen de: US20260055523A1
The technology generally concerns novel aerogels of mixed metal oxides and uses thereof as electrocatalysts.
Resumen de: US20260055522A1
Provided herein is a hydrogen gas production assembly includes a hydrogen gas production device, a container including an aqueous electrolyte solution, a storage container for storing produced hydrogen gas an input providing the aqueous electrolyte solution from the container to the hydrogen gas production device and an output for transferring produced hydrogen gas from the hydrogen gas production device to the storage container.
Resumen de: US20260055517A1
Microorganisms and bioprocesses are provided that convert gaseous C1 containing substrates, such as syngas, producer gas, and renewable H2 combined with CO2, into nutritional and other useful bioproducts.
Resumen de: US20260055516A1
A water electrolysis cell includes a membrane-electrode assembly, a frame body made of resin that is provided along a peripheral edge of the membrane-electrode assembly, and a first separator and a second separator that face each other through the membrane-electrode assembly and the frame body and are joined to each other by the frame body. An outer peripheral portion of the membrane-electrode assembly is extended to between a first face of the frame body and the first separator. A surface of the first face includes an antioxidant.
Resumen de: US20260054981A1
A method for hydrogen production may comprise: feeding a steam stream and a natural gas stream to a methane reforming unit to produce a gray hydrogen gas and CO2 stream; feeding the gray hydrogen and CO2 stream to a CO2 capture unit to produce blue hydrogen; feeding a water stream and electricity to an electrolyzer unit to produce a green hydrogen gas and oxygen; and collecting the blue hydrogen from the CO2 capture unit and the green hydrogen from the electrolyzer unit. A hydrogen production system may comprise: a methane reforming unit; a CO2 capture unit; and an electrolyzer.
Resumen de: AU2024327448A1
The present invention relates generally to the production of a desalinated, filtrated or other way treated water simultaneously with generation of renewal energy source, in particular hydrogen, using osmotic and/or gauge pressure driven filtration processes and systems. The co-generation of hydrogen 11 from water 8 produced during pressure driven water desalination/filtration processes, such as reverse osmosis, forward osmosis, pressure retarded osmosis or ultrafiltration. A small part of feed, raw saline solution and/or permeate involved in a desalination/filtration processes is subjected to electrolysis thereby splitting the water to produce hydrogen. This is achieved by the provision of novel RO type semi- permeable membranes and UF type membrane that incorporate electrodes 9, 10 within the membrane to allow splitting of the water via electrolysis.
Resumen de: DE102025133002A1
Ein Elektrolysevorrichtungsbetriebssystem beinhaltet eine Elektrolysevorrichtung, eine Steuereinheit, eine Zielgesundheitszustandswerteingabeeinheit und eine Steuerparameterberechnungseinheit. Die Elektrolysevorrichtung weist eine Vielzahl von Elektrolyse-Stacks auf, in denen eine Vielzahl von Elektrolysezellen, die Wasserstoff durch Elektrolyse von Wasser erzeugen, gestapelt sind. Die Steuereinheit steuert ein gesteuertes Objekt basierend auf einem Steuerparameter, der den Gesundheitszustand des gesteuerten Objekts beeinflusst. Die Zielgesundheitszustandswerteingabeeinheit ermöglicht es einem Systembenutzer, einen Zielgesundheitszustandswert einzugeben, der ein Zielwert für den Gesundheitszustand ist. Die Steuerparameterberechnungseinheit berechnet einen Steuerparameter des gesteuerten Objekts basierend auf dem Zielgesundheitszustandswert. Das gesteuerte Objekt ist die Elektrolysevorrichtung.
Resumen de: GB2643493A
A method for the production of hydrogen gas comprising (i) providing a DC electrical power supply, (ii) providing a plasma reactor with chamber 105, plasma torch 135 with a plasma cathode extending in to the chamber, a plasma anode extending into the chamber, and first and second spray systems which extend into the chamber, (iii) establishing a DC electric potential between the cathode and anode to generate and sustain a reaction zone about a plasma arc, (iv) providing a spray of hydrogen containing feedstock into the reaction zone from the first spray system whereby a mixture of gases comprising hydrogen gas is formed in the chamber by decomposition of the feedstock, and (v) providing a spray of water into adjacent to the reaction zone from the second spray system, wherein the water spray cools and dilutes the mixture of gases formed in step (iv). A plasma reactor comprising a chamber, plasma torch comprising a plasma cathode extending into the chamber and multi-functional device with plasma anode extending into the chamber, first spray anode with first annual passage surrounding the anode and providing a spray of hydrogen containing feedstock, and a second spray system with second annual passage surrounding the first passage and providing a spray of water.
Resumen de: WO2024165389A1
The present invention relates to a pyrogenic process for manufacturing metal oxides or metalloid oxides wherein a metal precursor and/or a metalloid precursor is introduced into a flame formed by burning a gas mixture comprising oxygen and hydrogen, wherein at least a part of the hydrogen has been obtained from electrolysis of water or an aqueous solution, using electrical energy, at least a part of which has been obtained from a renewable energy source, and wherein at least a part of the thermal energy of the flame is transferred to a first heat transmission medium by means of at least one exchanger, thereby heating the first heat transmission medium to a maximal temperature in the range between 80 and 150 °C.
Resumen de: CN120813538A
A process for catalytic cracking of ammonia, the process comprising: supplying an ammonia feed gas to one or more heated catalyst-containing reaction vessels disposed within an ammonia cracking reactor; and cracking ammonia in the ammonia feed gas in the one or more catalyst-containing reaction vessels to produce a hydrogen-containing stream wherein the ammonia feed gas is fed to the or each reaction vessel at a pressure of at least 10 bar wherein the or each reaction vessel is heated to a temperature of at least 500 DEG C, and wherein the or each of the reaction vessels has a wall comprising or consisting of an alloy selected to resist both nitriding and creep deformation without failure at said temperature and pressure over an operating period of at least 1000 hours, 5000 hours, 10,000 hours, 50,000 hours or 100,000 hours.
Resumen de: EP4700154A1
An electrolysis system includes an electrolyzer stack and a contamination mitigation system. The electrolyzer stack includes an injection port fluidly connected with a cathode compartment of the electrolyzer stack. The contamination mitigation system is configured to remove ions from the electrolyzer stack to mitigate ion contamination in the electrolyzer stack. The contamination mitigation system includes a storage tank including formic acid therein and an injection line fluidly coupled between the storage tank and the injection port. The injection line is configured to direct the formic acid from the storage tank to the injection port for injection into the cathode compartment of the electrolyzer stack.
Resumen de: EP4700159A1
Systems and methods are provided for water electrolysis. The system includes an electrolyte material configured for the exchange of anions, a first electrode including a nickel-cobalt-phosphorus-based compound, and a second electrode, wherein the first electrode and the second electrode are configured to exchange the anions through the electrolyte material.
Resumen de: GB2700654A
An apparatus 1 for generating hydrogen includes a housing 10 containing a cylindrical first electrode 11 surrounding a part-conical or frusto-conical second electrode 12. Each of the first and second electrode is for submersion within water located within the housing. The first electrode may be an anode and the second electrode may be a cathode. The housing may be fabricated from or include glass or a glass body may be provided within the housing. The glass may be a borosilicate glass or heat tempered glass. The housing may be cylindrical or cuiboid. The distance between a lowermost portion of the housing and an uppermost portion of the housing may be at least three times greater than the height of the anode. The anode may be fabricated from a metal such as stainless steel which may have a protective coating. The anode may comprise a mesh, such as an unwelded mesh, for example with a mesh size of 149 to 841 µm. The cathode may be formed of stainless steel coated with a second metal. The surface of the cathode may be patterned or textured. The anode and cathode may be retained away from the walls of the housing. Figure 1
Resumen de: GB2700593A
A process for controlling an ammonia cracking plant comprising a fired ammonia cracking reactor 1, may comprise the steps of: decreasing a flow of ammonia feedstock 11 to the catalyst containing reaction tube inlets, and decreasing the heat output of a fuel combustion zone of the reactor. The obtained cracked gas from the outlet of the reaction tubes may be cooled 2, increased in pressure 3, and heated 4 before recirculating the cracked gas to the inlet of the reaction tubes and passing it through the reaction tubes. An ammonia plant in a turn down state may have operated said process. The process is intended to place the ammonia cracking plant into a turndown state which enables it to rapidly return to normal operation without wasting ammonia feedstock or hydrogen. A process may return the plant from turndown by increasing ammonia feedstock flow and heat output and obtaining cracked gas. Figure 2
Resumen de: EP4699691A1
Provided is a reduction device that can be manufactured inexpensively and easily, has a wide reaction field, can achieve a reduction reaction even with low energy light such as visible light, and has a long catalyst life. The reduction device of the present disclosure includes diamond particles. It is preferable to contain the diamond particles as a diamond particle dispersion liquid. The diamond particles preferably contain nanodiamond particles having a particle size of 1 µm or less. The diamond particles preferably include detonation nanodiamond particles.
Resumen de: EP4699693A1
A semiconductor catalyst is provided, which exhibits an effect of accelerating a reduction reaction by visible light irradiation and is excellent in durability. The semiconductor catalyst of the present disclosure includes thin film containing nitrogen-containing diamond particles in a plane direction and a height direction. The semiconductor catalyst can be produced by, for example, fixing, on a substrate having a positive or negative charge, nitrogen-containing diamond particles having a positive or negative charge, the positive or negative charge of the nitrogen-containing diamond particles being opposite to that of the substrate, and laminating, on the fixed nitrogen-containing diamond particles, nitrogen-containing diamond particles having a positive or negative charge, the positive or negative charge of the laminated nitrogen-containing diamond particles being opposite to that of the fixed nitrogen-containing diamond particles. The step of laminating is performed at least once after the step of fixing.
Resumen de: CN120835863A
A process for catalytic cracking of ammonia, the process comprising: supplying an ammonia feed gas to one or more heated catalyst-containing reaction vessels disposed within an ammonia cracking reactor; and cracking ammonia in the ammonia feed gas in the one or more catalyst-containing reaction vessels to produce a hydrogen-containing stream wherein the reaction vessel or each of the reaction vessels has a wall comprised of at least a first alloy and a second alloy wherein the first alloy is more resistant to nitriding than the second alloy, and the second alloy provides mechanical support for the first alloy, and wherein at least a portion of the wall adjacent the catalyst is comprised of the first alloy.
Resumen de: WO2024218486A1
Oxygen evolution catalyst materials are provided with a pyrochlore-type structure and with (i) calcium and / or sodium as A-site elements of the pyrochlore-type structure; (ii) iridium and / or ruthenium as first B-site elements of the pyrochlore-type structure; (iii) niobium and / or tantalum as second B-site elements of the pyrochlore-type structure; and (iv) a molar ratio of A-site elements: first and second B-site elements is in the range of and including 0.8: 1 to 1:1.
Resumen de: WO2024218273A1
A method for storing hydrogen in a plurality of subsea storages in a system. The system comprising an electrolyser source (100) for producing hydrogen at a source pressure; a downstream compressor (200) for compressing the hydrogen from the source pressure to a compressed higher pressure; and a plurality of storages (300) each for storing compressed hydrogen at the compressed higher pressure and each being subsea. The method comprising at least the steps of: producing hydrogen (1000) by the electrolyser source (100) at the source pressure; passing the hydrogen (2000) to the plurality of storages (300) through a bypass line (210) around the compressor (200); and storing the hydrogen (3000) in at least one of the plurality of storages (300) at a first pressure below the compressed higher pressure. A system for storing hydrogen in a plurality of subsea storages, the system comprising: an electrolyser source (100) for producing hydrogen at a source pressure; a downstream compressor (200) for compressing the hydrogen from the source pressure to a compressed higher pressure; a plurality of storages (300) each for storing compressed hydrogen at the compressed higher pressure and each being subsea; and a controller (400) for controlling the electrolyser source (100), the downstream compressor (200), and valves (310) to the plurality of storages (300). The controller (400) is configured for controlling the system in, at least, two alternative ways: A) passing the hydrogen, produced by
Resumen de: SE2350468A1
An electrode (200) for a proton exchange membrane water electrolyzer, the electrode (200) comprising a plurality of elongated nanostructures (220) arranged on a substrate (210). The elongated nanostructures (220) are attached to the substrate (210) at a respective first end and extend along a direction perpendicular to a plane of extension of the substrate (210). The plurality of elongated nanostructures (220) are coated with a conformal protective layer (230), and a catalyst layer (240) is arranged on the conformal protective layer. The catalyst layer (240) comprises a plurality of nanoparticles (241), the nanoparticles (241) forming a continuous coating on at least a part of the surface of the plurality of elongated nanostructures (220).
Resumen de: AU2024256387A1
The invention relates to a method (100) for producing hydrogen (103), wherein feed water is subjected to electrolysis (10) with a cathode gas (101) being obtained, wherein the cathode gas (101) contains hydrogen, oxygen and some of the feed water, wherein a process gas flow (102) is formed using at least some of the cathode gas (101), wherein the process gas flow (102) contains at least some of the hydrogen, oxygen and feed water contained in the cathode gas (101), and wherein, in the process gas flow (102), at least some of the oxygen is subjected to an oxidative catalytic reaction with some of the hydrogen to form oxidation water, and wherein at least some of the feed water and the oxidation water in the process gas flow (102) are removed from the process gas flow (1029 in a water removal process. The catalytic reaction and the water removal process are carried out using one or more process units (41, 42), wherein the one process unit (41, 42) or each of the plurality of process units (41, 42) has a first adsorptive drying bed (4a), by means of which at least some of the feed water is removed from the process gas flow (102), a catalytic bed (4b) which is arranged downstream of the first drying bed (4a) and by means of which the catalytic reaction is carried out, and a second adsorptive drying bed (4c) which is arranged downstream of the catalytic bed and by means of which at least some of the oxidation water is removed from the process gas flow (102). The invention also pro
Resumen de: WO2024217840A1
A method for producing green hydrogen by electrolysis in a hybrid power plant (10), which comprises at least: - a wind turbine (11 ) with a rotor (11.1), a drive-train and a generator; multiple photovoltaic modules (12), - an electrolysis unit (15) for producing hydrogen by electrical power generated by the wind turbine (11) and/or the photovoltaic modules (12), an internal electrical power grid interconnecting the generator, the photovoltaic modules (12) and the electrolysis unit (15) within the power plant (10) and - a control unit (16); wherein a) electrical energy is generated by using the photovoltaic modules (12) and/or wind turbines (11 ); b) cloud coverage and/or solar radiation is measured by at least one weather sensor (14) which is located in a windward position remote of the power plant (10) and which is connected to the control unit (16) via a data link; According to a first aspect of the invention the wind turbine (11) is used as kinetic energy storage and according to another aspect of the invention the wind turbine (11) is used as an energy absorber by increasing inertia of the rotor (11.1).
Resumen de: AU2024257970A1
Process for synthesis of ammonia wherein: ammonia make-up gas (7) containing hydrogen and nitrogen is reacted in an ammonia converter (15) under ammonia forming conditions thus obtaining an ammonia-containing effluent (8); a first hydrogen portion contained in the ammonia make-up gas (7) is produced by reforming a hydrocarbon source (1) in a reforming process (100); a second hydrogen portion (19) contained in the ammonia make-up gas (7) is produced separately from said reforming process (100), by using at least a renewable energy source (SE, WE); a part of said hydrogen (19) produced in step (c) is stored in a hydrogen storage (103); hydrogen (20) from said hydrogen storage (103) is used to fully or partially replace said second hydrogen portion (19) when said renewable energy source (SE, WE) is fully or partially unavailable. Said process comprising the steps of: assessing an expected flow rate of the hydrogen (19) produced in step (c); adjusting a flow rate of the hydrocarbon source (1) so that a flow rate of the first hydrogen portion in said ammonia make- up gas (7) is in a desired ratio with respect to said expected flow rate; detecting an actual amount, e.g., a filling level, of said hydrogen in said hydrogen storage (103); detecting an actual flow rate of hydrogen produced using the renewable energy source (SE, WE), and adjusting a flow rate of the hydrogen (20) from said hydrogen storage (103) depending on said actual amount detected in said hydrogen storage (103) and
Resumen de: CN120897885A
A method for reacting aluminum with water, the method comprising the steps of: adding aluminum metal to an aqueous solution comprising potassium hydroxide at a concentration between 0.1 M and 0.4 M and a surfactant; stirring the mixture of the previous step; and collecting the generated hydrogen. A composition for use in such a method for reacting aluminum with water, the composition comprising potassium hydroxide and a surfactant.
Resumen de: US20260028730A1
Conventional control schemes for electrolyzers focus on maximizing electrical efficiency, which describes the relationship between the electrical energy consumed and the gas produced by the electrolyzer. However, the cost associated with high electrical efficiency may be unnecessarily expensive. In one embodiment presented herein, a model is used to determine the cost (or profit) associated with a gas produced by the electrolyzer at each of a plurality of operating conditions. The control system can select the operating condition to use based on which operating condition is associated with the lowest cost (or highest profit), even though that operating condition may not be associated with the highest electrical efficiency.
Resumen de: CN121556089A
本发明提供了一种降低电解槽停机后高电位的方法,属于电解水制氢技术领域。本发明采用特定放置方式的电解槽进行产氢运行,所述电解槽的放置方式为侧式放置,即电解槽的膜电极朝向为竖直方向,使运行过程中产生的气体在浮力作用下上浮至总管口侧积聚,且气体积聚位置不位于膜电极的活性区,并结合两步吹扫方式,可显著加快气泡排出速度,大幅缩短吹扫时间,有效解决了大电流密度下电解槽停机后高电位问题。
Resumen de: CN121551024A
本发明提供了一种氧化铈负载的PtPdRhRuNi高熵合金团簇催化剂及其制备方法和应用,属于催化剂技术领域。该催化剂包括载体氧化铈和负载于所述载体上的PtPdRhRuNi高熵合金团簇。经测试,本发明提供的氧化铈负载的PtPdRhRuNi高熵合金团簇催化剂具有较好的循环稳定性;并且该催化剂在氨硼烷水解制氢反应中具有优异的催化性能。
Resumen de: CN121556058A
本发明提供一种高温蒸汽联用固体氧化物高温电解系统及控制方法,属于高温电解制氢技术领域。蒸汽依次通过氢侧换热器和氢侧补热器调节温度后送入电解堆高温箱;氮气和氢气依次通过氢侧换热器和氢侧补热器调节温度后送入电解堆高温箱;空气依次通过空侧换热器和空侧补热器调节温度后送入电解堆高温箱;电解堆高温箱中固体氧化物高温电解堆塔电解高温蒸汽后产生的氢气依次通过氢侧换热器、气体冷却器后,部分经氢气循环泵重新通过氢侧换热器和氢侧补热器调节温度后送入电解堆高温箱;电解堆高温箱中固体氧化物高温电解堆塔电解高温蒸汽后产生的其他气体通过空侧换热器送入空侧排放组件进行排放。采用模块化集成设计,温度分区布置,解决热应力问题。
Resumen de: CN121556083A
本发明提供了一种电氧化含氯电解质的催化剂及其制备方法和应用,所述催化剂包括原位生长在镍基底上的层状双氢氧化物‑稀土碱式碳酸盐异质结,所述镍基底为表面经过镍修饰的泡沫镍。本发明基于构建可区分Cl‑与OH‑的选择性吸附位点的策略,通过引入稀土碱式碳酸盐(RE(OH)CO3)实现对OH‑的优先吸附,从而显著增强材料在海水电解中的抗氯离子腐蚀能力。该异质结构不仅具有优于传统LDH的析氧反应活性,更在工业级电流密度下表现出卓越的结构稳定性与持续抗腐蚀性能,为推进海水电解技术的工业化应用提供了可行的材料解决方案。
Resumen de: CN121558979A
本发明涉及电解制氢安全领域,特别是一种电解制氢设备的监测装置,包括进气管构件,所述进气管构件包括外壳,外壳直接与制氢设备的氢气产物排出管道相连接,从管道中抽取少量氢气产物进行检测,所述外壳的内壁设置有监测管道,氢气产物会进入监测管道接受监测,所述监测管道的侧面设置有保温副管道,保温副管道为氢气产物保温,防止其快速降温生成冷凝水对监测传感器造成干扰或污染,所述保温副管道的一端设置有防护网,防护网与保温副管道固定连接,保温副管道与吸湿构件形成双重防潮防护:保温副管道有效延缓氢气产物的降温速度,抑制冷凝水生成,避免冷凝水附着在监测传感器表面影响其感应性能;吸湿构件进一步吸附氢气中残留的水分。
Resumen de: CN121556066A
本发明公开了一种复合物催化电极材料,包括:(CoNiFe)OOH纳米多孔结构以及吸附在(CoNiFe)OOH纳米多孔结构上的MoO42‑阴离子,通过MoO3/CoNiFe复合物前驱体经电化学氧化获得,其中,MoO42‑阴离子对(CoNiFe)OOH的阳离子催化位点进行锚定。本发明在碱性电解质条件下,由MoO3原位反应生成的MoO42‑阴离子吸附在(CoNiFe)OOH上,MoO42‑阴离子可以通过静电引力作用锚定(CoNiFe)OOH中的阳离子催化位点Co,Ni和Fe,降低金属阳离子在电解质溶液中的溶解,保证了电极的析氧催化稳定性。
Resumen de: CN121556063A
本发明实施例提供了一种电解槽塑料极框结构,包括:A极框,其包括两个能够对接形成框体结构的第一子极框,一个第一子极框的两端分别设有第一氢侧进液口和第一氢侧出气口,另一个第一子极框的两端分别设有第一氧侧进液口和第一氧侧出气口;B极框,其包括两个能够对接形成框体结构的第二子极框,一个第二子极框的中部区域分别设有第二氢侧进液口和第二氢侧出气口,另一个第二子极框的中部区域分别设有第二氧侧进液口和第二氧侧出气口;极板,其为平板结构且周侧设有密封槽,极板在周侧关于极板中心线对称的设有成对设置的极耳,在极耳中心的厚度方向开设有用以安装电阻丝的开孔,极板分别安装在A极框形成的框体结构内和B极框形成的框体结构内。
Resumen de: CN121556087A
本发明公开了一种羟基氧化铝基碱性电解水复合隔膜及其制备方法,属于隔膜制备技术领域,所述隔膜由聚砜、聚乙烯吡咯烷酮、季胺化聚乙烯醇、γ‑AlOOH粉末组成,通过γ‑AlOOH粉末的引入可以显著降低面电阻、增强阻气性、提高机械强度与尺寸稳定性、改善热稳定性与化学稳定性,通过季胺化改性可以显著增强隔膜的永久亲水性、提升隔膜离子传导效率。
Resumen de: CN121556080A
本发明公开一种稀土元素掺杂钌氧化物催化剂的制备方法及其应用,所述制备方法包括如下步骤:(1)将稀土金属盐、钌金属盐、盐酸多巴胺和Tris‑HCl缓冲剂溶于水中得到混合溶液,经原位聚合反应,固液分离、干燥后得到粉末前体;(2)将步骤(1)得到的粉末前体进行高温煅烧,得到稀土掺杂氧化钌催化剂。本发明通过将稀土金属盐与钌盐前体分散在原位构筑的多孔碳基底上,通过自牺牲模板法,在高温条件下氧化生成了稀土元素掺杂氧化钌纳米片。本发明方法具有高效且无污染的特点。本发明的稀土元素掺杂钌氧化物作为酸性电解水阳极反应的催化剂,展现出了优异的催化活性和广阔的应用前景。
Resumen de: CN121556079A
本发明属于纳米材料合成技术领域,涉及一种铁掺杂磷化钴空心纳米笼析氢催化剂及制备方法。该催化剂为Fe掺杂CoP纳米颗粒与氮掺杂碳的复合多孔材料,微观上包覆氮掺杂碳的Fe掺杂CoP纳米颗粒均匀负载于尺寸为200nm的十二面体多孔氮掺杂碳上。其制备方法包括三步:(1)六水合硝酸钴与2‑甲基咪唑在甲醇中室温反应,离心得ZIF‑67前驱体;(2)ZIF‑67与铁氰化钾在乙醇‑去离子水中油浴回流,离心干燥得CoFe‑PBAs前驱体;(3)CoFe‑PBAs在氩气保护下400℃退火2h,制得目标催化剂。该催化剂全pH范围析氢活性优异,酸性、碱性、中性体系中0.01Acm‑2过电位分别为61mV、133mV、188mV,质子交换膜电解槽实现1.0Acm‑2电流密度仅需1.91V,且200h运行电压衰减率低至0.1mVh‑1。本发明制备工艺简单、成本低,催化剂活性与稳定性突出,适用于工业绿氢制备场景。
Resumen de: CN121556056A
本发明公开了一种制氢模块用管路布置系统,包括制氢箱体组件,所述制氢箱体组件内设置有水箱系统,所述水箱系统上连接有进水系统、排水系统、水循环系统,所述水箱系统还连接有排氧气系统,所述水循环系统上连接有制氢系统,所述制氢系统与水箱系统连接,所述制氢系统上设置有氢气风冷系统,所述氢气风冷系统上连接有气液分离系统,所述气液分离系统上连接有排氢气控制系统、水箱系统。本发明的有益效果是,本技术方案的管路布置系统,布局合理,实用性较高,且运行稳定,运用此管路布置系统,实现了稳定制氢作业,有效提高了制氢作业的效率,同时方便对制氢过程进行灵活配置。
Resumen de: WO2025105885A1
A membrane-electrode assembly includes a first catalyst electrode, a polymer electrolyte membrane covering a side surface and an upper surface of the first catalyst electrode, and a second catalyst electrode disposed on the polymer electrolyte membrane, in which at least a portion of a corner area in which the side surface and the upper surface of the first catalyst electrode are connected has a curved shape.
Resumen de: CN121566547A
本发明涉及可再生能源风光发电、水电解制氢技术领域,具体涉及一种离网的风光互补制氢发电系统及方法:包括风力发电模块、光伏发电模块、碱性电解水模块、电力智能分配模块、储能模块和电力负载模块,风能发电模块和光伏发电模块共同作为电能来源,为碱性电解水模块及电力负载模块供电。在风光发电负荷充足时,碱性电解水模块以额定功率运行,同时将多余电能存储至储能模块;当风光发电负荷不足,无法满足碱性电解水模块的最低负荷需求时,储能模块为碱性电解水模块提供补充电能,确保其以最低负荷持续运行,同时向电力负载模块供电,通过电力智能分配模块动态调控风能、光伏、储能及负载之间的能量分配,实现高效能源管理。
Resumen de: CN121556082A
本发明属于电催化材料技术领域,公开了一种CeO2/NiCo2O4异质结析氧反应电催化剂及其制备方法。该电催化剂通过在NiCo2O4纳米片阵列表面构建由氮掺杂碳量子点与CeO2组成的复合保护层,利用吡啶氮捕获溶出钴离子、CeO2氧空位促进其再整合,实现界面动态自修复。所述氮掺杂碳量子点嵌入CeO2层中并与NiCo2O4直接接触,协同抑制钴流失并维持结构完整性。本发明通过构建具有动态离子捕获与自修复能力的CeO2/氮掺杂碳量子点复合界面层,成功解决了NiCo2O4基析氧反应电催化剂在强氧化性工况下因钴离子溶出导致的结构失稳与性能衰减问题,在绿色氢能电解水技术领域具有重要的应用价值与产业化前景。
Resumen de: US20260043158A1
An electrolytic cell and an anion-exchange conductive hollow fiber tube matrix thereof are disclosed. The anion-exchange conductive hollow fiber tube matrix includes a plurality of conductive hollow fiber tubes arranged adjacent to each other in a matrix. The conductive hollow fiber tubes each have a diffusion surface and two opposite ends defined as an inlet and an outlet. An anode and a cathode of the electrolytic cell are disposed adjacent to the diffusion surface. Water in an electrolysis tank flows into the conductive hollow fiber tubes from the inlet, water molecules enter the cathode from the diffusion surface and decompose to produce hydrogen and hydroxide ions, the hydrogen is discharged from the cathode, the hydroxide ions return to the conductive hollow fiber tubes from the diffusion surface and then enter the anode from the diffusion surface to produce oxygen, the oxygen is discharged from a surface of the anode.
Resumen de: US20260027556A1
A catalyst for decomposition of ammonia, and a method for decomposition of ammonia in which a decomposition reaction of ammonia is performed in the presence of the catalyst, the catalyst including a carrier, and catalytically active components supported on the carrier, where the catalytically active components include i) ruthenium (Ru) as first metal; ii) lanthanum (La) as second metal: and iii) one or more of aluminum (Al) and Cerium (Ce) as third metal, and the catalyst has a porosity of 25% or more. The catalyst exhibits very high ammonia conversion rates, has little pressure difference between the front end and back end of the reactor, has high catalyst strength, and catalyst layer temperature difference is very small.
Resumen de: CN121565302A
本发明公开了一种氮掺杂‑有机基团协同调控MXene非贵金属析氢电催化剂定向设计与筛选方法,其特征在于,该定向设计与筛选方法包括以下步骤:一、以氮掺杂Ti3C2O2 MXene为基底,选取有机基团进行修饰,构建吸附型协同模型;二、对步骤一中构建的吸附型协同模型的HER活性和位点可及性进行分析,筛选出最优的吸附型协同模型,得到MXene非贵金属析氢电催化剂。本发明的定向设计与筛选方法通过以氮掺杂Ti3C2O2 MXene为基底,选取有机基团进行修饰,构建吸附型协同模型,并结合HER活性和位点可及性两大指标共同筛选,有效缩短了研发周期,兼顾稳定性和活性位点密度,适用于电化学用催化剂的制备领域。
Resumen de: CN121556062A
本发明涉及质子交换膜电解水装置阳极催化剂领域,具体地公开了指一种适用于高电流密度酸性析氧反应的IrRu/TiOxNy纳米带阵列结构薄膜电极及其制备方法。本发明选择具有多孔结构和良好化学/机械稳定性的商用Ti毡作为基底,通过水热法在Ti毡上原位生长钛酸钠纳米带阵列,然后经过离子交换和热氮化处理分别制备得到氢钛酸纳米带阵列和TiOxNy纳米带阵列,最后利用湿化学还原法将IrRu纳米合金颗粒负载在TiOxNy纳米带阵列表面,获得具有纳米带阵列结构的IrRu/TiOxNy薄膜电极。本发明制备的IrRu/TiOxNy纳米带阵列结构薄膜电极,避免使用了粘结剂和导电添加剂,具有优异的高电流密度催化活性。
Resumen de: CN121550718A
本发明涉及电解水技术领域,具体为一种电解水用循环过滤装置,主要包括支撑架,支撑架顶面安装有电解槽和冷却箱,电解槽两端安装有出气管出液管和进液管,还包括:过滤机构,过滤机构设置在管道内部,振动机构,振动机构设置在管道内部,敲击机构,敲击机构设置在管道内部。通过电解槽中进行反应制氢时,外界的循环泵对电解槽中的液体进行循环,液体流动时,带动扇叶转动,扇叶带动转轴和转动条转动,转动条带动刮条和刷毛转动,刷毛和刮条对滤板侧面过滤下来的碳酸钾进行清除,碳酸钾不会堵塞滤板,提高液体从滤板处进入冷却箱再次到电解槽的效率,同时保证碳酸钾不会再次循环至电解槽中,对电极表面造成覆盖,进一步提高电解的效率。
Resumen de: CN121556070A
本发明提供了一种高熵尖晶石电极材料及其制备方法、固体氧化物电解池,上述高熵尖晶石电极材料具有尖晶石晶体结构,化学通式为RO4;其中,R由Mg、Mo、Sc、Co、Mn、Fe、Ni、Cu、Al、Zn、Cd、Cr以及In中的5种或5种以上元素组成,且R中各元素的化学计量系数xi均满足0.25≤xi≤1。本发明以5种及以上特定金属元素构建R组分,且各元素计量系数控制在合理区间,不仅能形成均匀致密的单相尖晶石晶体结构,更通过高熵混合效应降低体系吉布斯自由能,显著提升材料热力学稳定性,从而消除传统尖晶石材料在固体氧化物电解池中应用时存在的相分解问题,有利于固体氧化物电解池的稳定工作。
Resumen de: CN121557875A
本发明公开了一种碱性电解槽密封垫片厚度监测系统及监测方法,包括:图像采集设备,其安装在碱性电解槽的径向外侧;控制系统,其与图像采集设备电连接,包括图像预处理模块,其接收图像数据并对其进行去噪和增强处理;特征提取模块,其提取各极框、密封垫片的边缘特征,得到特征数据;角度畸变矫正模块,其根据拍摄角度误差对各密封垫片的特征数据进行矫正;厚度计算模块,其建立单位特征数据与实际尺寸之间的对应关系,并以此为依据计算各密封垫片的实际厚度数据;输出储存模块。本发明通过图像采集设备与控制系统的多个模块配合实现对各密封垫片厚度变化的实时、精确、自动化监测,解决了传统人工测量方式劳动强度大、误差大及不安全的问题。
Resumen de: CN121556091A
本发明提供一种PEM电解水产氢效率测试装置,包括:PEM电解腔以及排气端,所述PEM电解腔设有三组,其三组PEM电解腔规格相同,与现有技术相比,本发明具有如下的有益效果:通过进出水端向电解腔注入去离子水至规定液位,启动电源后,电解过程产生的氢氧气体经排气端分排收集,同时通过外置抽流泵实时监测底部沉淀水体,本发明还提供一种PEM电解水产氢效率测试装置的测试方法,本发明方法具有如下的有益效果:侧封板与内支撑杆构成的密封结构确保电解腔气密性,双极板阵列配合质子交换膜实现高效产氢,而侧测试罐内的氢气浓度传感器可精准监测气体纯度,外置抽流泵则有效排除气泡干扰,多腔并联设计不仅降低单次测试误差。
Resumen de: CN121556051A
本发明涉及核能、新能源与化工交叉技术领域,公开了一种基于核能的零碳系统,包括:淡水子系统;CO2捕集子系统从空气中捕集CO2气体;高温电解子系统接收从CO2捕集子系统传输的CO2气体以及从淡水子系统传输的水蒸气,以电解制取混合的合成气;核能子系统为淡水子系统供热和供电,使得淡水子系统产生水蒸气,且为CO2捕集子系统和高温电解子系统供电;化工原料合成子系统接收高温电解子系统传输的合成气,以制取化工原料。本申请直接利用核能子系统的热能和电能,将核能和化工生产有机结合,实现能源的多能互补和梯级利用,提高能源利用效率,扩大能量来源,降低碳排放,构建零碳系统。
Resumen de: CN121551755A
本发明公开了一种电解水氢氧焊割装置,涉及火焰焊割技术领域。该电解水氢氧焊割装置,包括反应组件、移动座、支撑组件,还包括:外壳,安装于支撑组件上,其内部设有用于氢气输送的内管,所述内管外侧设有套管,套管与内管之间的间隙形成氧气输送腔,且套管与外壳之间的间隙形成降温腔;接头,固定于外壳下端,其内设有与降温腔连通的环形腔,接头底部安装有出气嘴。通过同轴嵌套的内管、套管与外壳,隔离氢气输送、氧气输送及水雾,实现了燃料、助燃剂与冷却介质在输送阶段的完全物理分离,从根本上杜绝了可燃气体在管路内预混合的风险,将混合点严格限定在焊嘴外的安全区域,显著提升了设备使用时的安全水平。
Resumen de: CN121556050A
本发明公开了一种用于碱性电解水的改性电解液,包括:碱性电解质溶液以及添加在碱性电解质溶液中的钼酸盐、硒酸钠以及氢氧化锂,通过将钼酸盐、硒酸钠以及氢氧化锂加入到碱性电解质溶液中并对其进行搅拌溶解,以生成改性电解液。通过上述方式,本发明一种用于碱性电解水的改性电解液,能够在电极表面形成NiMo、NiMoSe等金属化合物,使电极的物质组成及表面形貌结构发生变化,暴露出更多的活性位点,提升电极的电解效率。
Resumen de: CN121556086A
本发明公开了一种IrxCo3‑xO4/Ir‑Co3O4异质结构电催化剂及其共沉积结合缺陷调控制备方法和应用,属于催化剂制备技术领域。包括:将含铱化合物和含钴化合物溶解于去离子水中配置成前驱体溶液,并在三电极体系中进行阴极共沉积处理;然后将样品煅烧,再经等离子体处理在材料中创造丰富的阴、阳离子空位,再次进行煅烧消除氧离子空位;将处理后的样品浸渍于IrCl3溶液中,蒸干溶剂后进行热处理,制得IrxCo3‑xO4/Ir‑Co3O4异质结构电催化剂。该异质结构催化剂能够有效改善Ir活性中心周围的电子结构,强化金属‑金属氧化物载体相互作用,抑制Ir活性中心原子过度氧化,极大地提升催化剂的活性及稳定性,因此能够有效解决现有技术中贵金属基催化剂活性低、质量活性不高及稳定性差的技术难题。
Resumen de: CN121556049A
本发明属于新能源制氢与生物质资源利用的技术领域,具体的涉及一种解耦电解水制氢的方法。该方法基于具有可逆氧化还原特性的过渡金属配合物,通过构建阳极侧“电化学-化学”反应的闭环通路解耦电解水,有效避免了传统电解水中高能耗的析氧过程,降低了系统运行电压和安全风险。在该方法体系中,过渡金属配合物作为氧化还原媒介,持续参与阴极水还原析氢和阳极氧化的电子转移过程,生成的高价态物种随后在电解液中被生物质还原,从而实现价态循环与持续电子传递;而生物质则同步实现了高价值转化。具有能耗低、安全性高、产物附加值高的优势,适用于分布式绿氢制备与生物质资源梯级利用。
Resumen de: CN121556068A
本发明适用于电解水制氢催化剂技术领域,提供了一种中熵普鲁士蓝类似物衍生硫化物催化剂及制备方法,包括以下步骤:将Ni(NO3)2·6H2O和C6H5Na3O7·2H2O溶解在去离子水中,磁力搅拌形成溶液A;将K3Co(CN)6和K3Fe(CN)6溶解在去离子水中,磁力搅拌形成溶液B;将溶液B加入到溶液A中,室温搅拌,得到混合溶液;将混合溶液水浴加热,搅拌;对混合溶液进行离心处理,分离得到沉淀,多次洗涤后再真空干燥过夜,得到FeCoNi‑PBA前驱体;将FeCoNi‑PBA前驱体与过量硫粉分别置于两个瓷舟内,放置于管式炉的下游和上游,在氩气气氛下,升温后,保温处理,得到中熵硫化物,命名为FeCoNi‑S。本发明制备得到具有丰富缺陷、高比表面积的双功能催化剂,实现高效、稳定的电解水制氢和制氧。
Resumen de: CN121556059A
本申请公开了一种电解制氢系统,电解制氢系统包括:ALK电解组件和AEM电解组件;ALK电解组件包括:ALK阳极反应区、ALK阴极反应区、ALK阳极气液分离罐和ALK阴极气液分离罐;ALK阳极反应区和ALK阳极气液分离罐连通,ALK阴极反应区和ALK阴极气液分离罐连通;AEM电解组件包括:AEM阳极反应区和AEM阳极气液分离罐;AEM阳极反应区和AEM阳极气液分离罐连通。在本技术方案中,能够实现ALK电解槽和AEM电解槽中的循环碱液可以相互补充,以避免电解液浓度失衡,提升制氢效率,保证电解制氢系统运行稳定性。
Resumen de: AU2024305585A1
The invention relates to an ion-conducting membrane (10) for an electrochemical device, said membrane comprising a layer of a material comprising: - 5% to 30% by weight of a polymer binder and - 70% to 95% by weight of a powdered ceramic, the powdered ceramic comprising ceramic doped with yttrium oxide and/or ceramic doped with cerium oxide. The invention can be used to produce a non-porous membrane for low-temperature electrolysis (0°C to 150°C).
Resumen de: CN121556074A
本发明提供了一种钌基电解水制氢电极材料的激光制备方法及其应用。所述方法将十二羰基三钌溶液喷到导电载体上,通过SEM发现十二羰基三钌的形貌为不规则的块状团聚体。再使用直接激光划线技术进行碳化处理。通过SEM,XRD等表征发现十二羰基三钌的形貌发生了剧烈的变化,从原来的不规则的块状团聚体转变为网络状的结构,形成了高活性的钌单质纳米颗粒,具有高效的催化活性。该方法将钌基化合物材料通过直接激光划线技术碳化处理成电极材料,具有良好的催化活性和稳定性,且本发明方法简单易行、成本低,可以批量生产。
Resumen de: CN121568290A
本发明公开了一种带状束氢离子源及系统,带状束氢离子源包括离子源基座、离子源弧室和水冷组件,所述水冷组件用于对离子源弧室进行冷却,所述离子源弧室包括弧室底板和弧室顶板,所述离子源弧室内设有灯丝以及相对布置的阴极组件和反射极组件,所述灯丝用于加热阴极组件以发射电子,所述阴极组件与反射极组件处于同一电位,所述弧室底板安装在离子源基座上,所述弧室顶板上开设有带状口。本发明具有氢气电离效率高、氢离子束稳定性好的优点。
Resumen de: CN121556081A
本发明公开了一种Cu/Cu2O/Bi2WO6三元Z型异质结光电催化材料及其制备方法和应用,制备方法包括:制备Bi2WO6粉末,并通过电沉积在碳纸表面得到一层均匀、垂直生长的Bi2WO6纳米片阵列,通过电沉积在附有Bi2WO6纳米片阵列的碳纸表面沉积Cu2O得到Cu2O/Bi2WO6薄膜;将沉积有Cu2O/Bi2WO6薄膜置于管式炉中在惰性气氛中,在150~300°C下退火处理,随后在空气中室温放置12~24 h,使其表面状态自然氧化达到稳定,获得Cu/Cu2O/Bi2WO6三元Z型异质结光电催化材料,本发明的Cu/Cu2O/Bi2WO6三元Z型异质结光电催化材料具有高效的光电转换效率、优异的稳定性和宽光谱响应特性,在其作为阴极和阳极的全解水体系中表现出优异的光电催化全解水效率。
Resumen de: WO2025028396A1
A method for producing hydrogen is provided in which ammonia can be highly efficiently decomposed even with low power consumption to produce hydrogen. This method for producing hydrogen includes a step in which an ammonia decomposition catalyst including a titanium oxide represented by general formula (1) or a titanium oxynitride represented by general formula (2) is brought into contact with ammonia while being irradiated with microwaves at low output. General formula (1): ATiO3-x (A is at least one member selected from the group consisting of Ba and Sr, and x is a number represented by 0.1≤x≤2.0.) General formula (2): ATiO3-xNy (A is at least one member selected from the group consisting of Ba and Sr, x is a number represented by 0.1≤x≤2.0, and y is a number represented by 0.1≤y≤1.0.)
Resumen de: CN121556067A
本发明属于电催化技术领域,具体涉及一种Ti网基底上负载锰钌氧化物复合电极材料及其制备方法和应用,所述制备方法主要为:将经过预处理后的Ti网基底置于含有锰盐、醋酸盐、硫酸盐的电解液中,对Ti网基底进行电沉积,接着放入马弗炉进行退火,得到Ti/MnOx;然后,将其放入钌盐溶液中进行数次浸泡和干燥,再放入马弗炉中退火,得到Ti/MnOx‑RuOy。本发明制备方法具有工艺简单方便,反应条件温和,成本经济的优势,所制得的复合电极材料,用作电解水阳极时具有优异的酸性OER性能和稳定性。
Resumen de: CN121551028A
本申请属于催化剂制备技术领域,具体涉及一种硫空位Co3O4/CdIn2S4‑Vs复合材料及其制备方法和应用。该方法将CdIn2S4纳米材料置于H2O2溶液中搅拌,洗涤,干燥,得到具有S空位的CdIn2S4‑Vs纳米材料;然后和Co3O4置于无水乙醇中,搅拌,洗涤,干燥,即得。本发明通过H2O2对CdIn2S4进行刻蚀,构建出具有表面硫空位的CIS‑Vs,其表面硫空位起到电子捕获阱的作用,促使CdIn2S4的光生电子快速转移,从而显著提高光生载流子分离效率。该复合材料的最佳光催化产氢速率达到10.378 mmol h‑1g‑1,是纯CdIn2S4的43倍,循环实验后性能仍能保持在93%。
Resumen de: CN121556084A
本发明提供了一种镍掺杂手性钴氧化物催化剂,化学式为L‑Co(3‑x)NixO4,制备方法:将还原剂、L‑半胱氨酸、柠檬酸钠、氯化钴、氯化镍与水混合搅拌,加入异丙醇并静置,得到镍掺杂手性钴氧化物催化剂。本发明还提供了包括BiVO4光阳极和镍掺杂手性钴氧化物催化剂的光电化学水分解用复合光阳极,镍掺杂手性钴氧化物催化剂负载在BiVO4光阳极表面,通过将L‑Co(3‑x)NixO4分散液与BiVO4光阳极混合热处理得到。本发明还提供了包括上述复合光阳极的光电化学水分解装置。本发明能够通过手性诱导的自旋选择效应实现自旋选择性电荷传输,降低了反应能垒,优化了OER路径,解决了现有技术高过电位和低光电流密度的问题,能够抑制H2O2副产物,稳定性强,无需外部磁场,为光电化学水分解提供了新思路。
Resumen de: CN121554752A
本发明公开了一种含不同配位模式金属节点的金属有机框架催化剂及其合成方法和应用。所述金属有机框架催化剂的合成方法包括如下步骤:S1,使三氮唑有机配体L与M1和M2金属源试剂进行水热反应得到母体框架,所述母体框架具有八面体位点和四面体位点,M1金属节点占据八面体位点中心,M2金属节点占据四面体位点中心;S2,采用醛基辅助修饰配体H配位取代四面体位点的M2‑Cl形成M2‑O。本发明的金属有机框架催化剂基于三氮唑有机配体与金属M构建的M‑TZ框架,具有结构明确、孔道可调、电子结构灵活等特点,在碱性及外加电压条件下可通过动态重构形成富含氧空位、键长优化和自适应活性位点的活性相,显著提升析氧反应活性和稳定性。
Resumen de: CN121556078A
本发明涉及一种卤离子掺杂的镍铁氢氧化物析氧催化剂及其制备方法,所述卤离子掺杂镍铁基氢氧化物结构特征为:卤素离子在镍铁基氢氧化物层板内配位,其原子数占总原子数的20~40%之间;镍与铁的原子数比为4:1~1:4之间;除镍和铁外,所添加的其他阳离子原子数占总原子数的0~20%之间;卤离子掺杂的镍铁基氢氧化物纳米片层交联生长,形成有序的中空阵列,其片层厚度为10~100 nm;晶系为三斜晶系,空间群为R‑3m。该催化剂亦可在泡沫镍、泡沫镍,镍网、不锈钢网、泡沫铁、铁网等载体上进行生长。大电流密度下,该催化剂具有较低的析氧过电位和塔菲尔斜率,具有优异的循环稳定性,在碱性电解槽中展现出不俗的应用潜力。
Resumen de: CN121556092A
本发明属于电解水制氢技术领域,公开一种集成汽水分离的PEM电解纯水制氢系统,包含原水预处理、超纯水精制、两级超纯水检测回流、PEM电解反应、集成式气液分离、氢气提纯及中央控制模块,系统通过集成多级气液分离单元与智能对比检测通道,实现气液高效分离与精准回流调控;两级超纯水检测回流模块保障水质并实现水资源循环利用;中央控制模块实现全系统自动化监测与联动控制。该系统可提升电解效率与氢气纯度,保障运行稳定安全,提高水资源利用率。
Resumen de: CN121556090A
本申请涉及一种制氢系统的电解液温度控制方法、装置和设备。制氢系统中包括:光伏单元、储能单元、电解槽单元、连接电解槽单元的电解液循环回路,以及目标DC‑DC变换器,目标DC‑DC变换器与电解液循环回路之间的距离小于预设距离,目标DC‑DC变换器包括:连接于光伏单元与储能单元之间的DC‑DC变换器,和/或,连接于储能单元与电解槽单元之间的DC‑DC变换器,方法包括:获取电解槽单元中的电解液实时温度;根据电解液实时温度所处的目标温度范围,确定与目标温度范围对应的目标工作模式;基于目标工作模式控制目标DC‑DC变换器工作。采用本方法能够优化能源利用效率。
Resumen de: CN121556069A
本发明提供了一种基于淬火工艺的镍钴铁碱性电解水催化剂,化学通式为NixCoyFezOx+y+z+1,其中0<x+y+z≤4,且0≤x≤2,0≤y≤1,0≤z≤1,制备方法包括:镍基材的前处理、制备前驱体溶液、浸渍‑煅烧‑淬火、重复浸渍‑煅烧‑淬火。还提供了应用,该基于淬火工艺的镍钴铁碱性电解水催化剂用于电解水催化。本发明通过多金属组份的协同形成金属‑氧强键合作用以及淬火处理诱导产生的大量氧空位和表面缺陷。不仅增加了活性位点数量,还优化了电子结构,促进了水分子的吸附与解离,有效防止了活性组分在长时间运行中的溶解和脱落。
Resumen de: CN121556088A
本发明公开了一种用于碱性水电解的复合隔膜及其制备方法和应用,属于复合膜技术领域。本发明中的复合隔膜采用高分子聚合物网格作为支撑层,可以提高复合隔膜的机械强度;另外,采用金属氧化物/层状双金属氢氧化物复合材料作为亲水无机填料,可以优化复合隔膜孔结构及增强复合隔膜的亲水性。本发明中所得复合隔膜较金属氧化物复合隔膜和层状双金属氢氧化物复合隔膜具有更优异的综合性能,应用在碱性水电解槽可达更好的电解性能。
Resumen de: CN121556057A
本发明公开一种模块化碱性电解槽,属于电解水制氢系统领域。包括电解小室、双极板、极框、端压板,极框上部开设有碱液出口,极框下部开设有碱液入口,在电解槽外围安装有n个输电板,n为不小于3的整数,所述的输电板焊接在极框外侧,极框与BOP的连接管道设有控制开关的阀门。所述的n个输电板为一个负极输电板和4个正极输电板或者一个正极输电板和4个负极输电板。本发明提供的模块化碱性电解槽,能够达到兼顾模块独立性、均衡运行、氢气和氧气纯度高的效果。
Resumen de: CN121556073A
本发明公开了一种三维多孔铂碳HER催化剂的制备方法,包括以下步骤:一、对Na3C6H5O7·2H2O、CH4N2O和NH4Cl混合溶液进行雾化干燥,得到前驱体粉末;二、前驱体粉末进行高温热解,得到热解产物;三、热解产物进行酸洗,得到三维多孔载体;四、三维多孔载体进行铂负载,得到固体粉末;五、固体粉末进行热还原,得到三维多孔铂碳HER催化剂。本发明成功制备出具有多级孔结构的三维多孔铂碳HER催化剂,其均匀分布的活性位点与丰富的孔径结构协同作用,显著改善了HER过程的传质效率和反应动力学,从而有效提升了电催化析氢性能,该制备方法工艺简便、产物纯度高且易于规模化制备,展现出良好的应用前景。
Resumen de: CN121551027A
本发明公开一种光催化制氢用Cs‑WO3‑X/Zn0.5Cd0.5S复合催化剂及其制备方法和应用,属于可见光谱响应的光催化材料制备技术领域。本发明将CsCl3、WCl6和CO(NH2)2溶解于乙醇进行水热反应得到Cs‑WO3‑x粉末;将CdCl2·2.5H2O、ZnCl2和Na2S·9H2O溶解于水中,然后加入Cs‑WO3‑x粉末室温搅拌,离心、洗涤、干燥得到Cs‑WO3‑X/Zn0.5Cd0.5S复合催化剂。本发明所制备的Cs‑WO3‑X/Zn0.5Cd0.5S复合异质结催化剂集合了单一Cs‑WO3‑X和单一Zn0.5Cd0.5S的优点,并且构建了异质结形成内建电场,异质结抑制了载流子复合,提高了光吸收率,提高了析氢产率。
Resumen de: CN121551048A
本发明提供了一种Co‑NC纳米立方体负载单金属Rh纳米催化剂的制备方法及在甲醇析氢中的应用,通过金属离子与有机配体结合制备了Co‑NC纳米立方体前驱体,再通过高温煅烧获得Co‑NC纳米立方体,随后使用还原剂硼氢化钠原位还原Rh3+金属离子,制备了Co‑NC纳米立方体负载单金属Rh催化剂,并将其应用在催化四羟基二硼与甲醇反应制氢中,其催化制氢中氢气转换频率值达到了161(L(H2)·gCat.‑1·h‑1)以上。本发明技术方案得到的纳米催化剂的优点为制备工艺简单,对四羟基二硼与甲醇反应制氢具有较高的选择性和催化活性,以及其在极低温度下仍保留较高催化活性。
Resumen de: CN121556054A
本发明涉及小型制氢机技术领域,具体为一种用于家庭治疗的小型制氢机,加工单元包括固定设置在所述外壳内的蓄水罐,所述外壳内固定设置有支撑板,所述支撑板上固定设置有电解器,所述加工单元用于对水进行电解反应处理,启动装置,通过设置净化腔室上的水泵使其能够提供一个稳定的吸力,并且水源能够被净化腔室内的除杂管进行净化除杂,处理过后的水源再通过长管输送至装置的蓄水罐中进行存储,并且通过设置在蓄水罐外壁上的催化剂罐对蓄水罐内的溶液进行进一步的除杂加工,再通过软管一输送至装置电解器中进行电解反应,保证电解过程的高效进行,设置在电解器内的转板能够对其内部溶液含量进行实时的检测,保证装置运作时的安全性。
Resumen de: WO2025095296A1
A solid oxide cell stack fastening apparatus, in which downward pressure applied to the solid oxide cell stack is uniform throughout, includes a housing which accommodates a solid oxide cell stack and includes a first coupling part on one side thereof, and a first block which includes a second coupling part and an elastic member in contact with the solid oxide cell stack. The first coupling part and the second coupling part each have screw threads coupled to each other.
Resumen de: CN121551047A
本发明公开了一种用于甲醛溶液重整制氢的光催化剂及其制备方法,属于催化剂制备与氢能技术交叉领域。所述光催化剂是具有不同Mn和Ni摩尔比的双金属结构材料,所述光催化剂分子式为MnxNiy/C3N4。其制备方法是通过加入不同比例的醋酸锰和氯化镍调节催化剂中Mn和Ni的投料比,将混合物在含C3N4的去离子水中均匀分散后,滴加硼氢化钠溶液并持续搅拌以获得前驱体,随后在氢气氛围中进行煅烧处理后得到。该光催化剂可同步实现甲醛降解与稳定产氢,其产氢速率可达134.53 mmol·h‑1·g‑1。本发明光催化剂在无牺牲剂的温和反应条件下展现出优异的光催化甲醛重整产氢性能,既能突破传统催化剂对牺牲剂的依赖性难题,又能通过甲醛的高效转化实现污染物降解与清洁能源制备的双重效益。
Resumen de: CN121556055A
本发明涉及低成本电解水制氢技术领域,具体为一种智能自适应宽负荷低电耗低成本电解水制氢设备,支撑单元包括固定设置在所述底板上的支撑杆,所述底板上固定设置有支撑台,且所述支撑台上固定设置有用于电解反应的反应罐,所述支撑杆上固定设置有定位架,同时控制台内的集成智能化运维系统,实时监测气体纯度与设备状态,精准动态管理系统热平衡、压力平衡和液位平衡,在装置使用过程中能够通过运料管进行各个原料的运输,设置在底板上的存储罐能够对反应过程中产生的氢气进行存储,设置在防护壳上的缓冲罐能够保证装置内的气压处于一个稳定的区间,保证反应过程的正常进行。
Resumen de: PL449572A1
Przedmiotem zgłoszenia jest elektrolizer do elektrolizy wody, z elektrodami ulokowanymi poziomo, które to elektrody są w pionie poprzecinane kanałami, gdzie stosunek pola przekroju poprzecznego pojedynczego kanału do jego długości wynosi co najwyżej 0,3 i mikroporowatego separatora, między tymi elektrodami, charakteryzujący się tym, że wspomniane elektrody (1, 2) i separator (4) je oddzielający są wypukłe w stronę dna elektrolizera i elektroda górna (1) jest ulokowana w objętości, której dotną ścianę stanowi separator (4) i obie strony: górną i dolną tej elektrody, łączą kanały do cyrkulacji elektrolitu (7, 7a) i poniżej dolnej strony kraju separatora (4) są również wykonane otwory cyrkulacyjne (13, 13a), a elektroda dolna (2) jest ulokowana poniżej tych otworów.
Resumen de: WO2024236080A1
There is provided a membrane electrode assembly (MEA) for an electrochemical devices, such as for fuel cells and electrolyzers, particularly for polymer electrolyte membrane (PEM) fuel cells, said membrane electrode assembly comprising a composite electrolyte membrane comprising a reinforced electrolyte layer comprising at least one porous support, the porous support being at least partially imbibed with a first ion exchange material; and a first electrode comprising a reinforced electrode layer comprising a porous support, the porous support being at least partially imbibed with a first catalyst and a second ion exchange material, wherein the composite electrolyte membrane is in contact with the first electrode. Also provided is a composite electrolyte membrane, which can be used in the manufacture of the membrane electrode assembly and a fuel cell and electrolyzer comprising such a membrane electrode assembly. A method for the manufacture of the membrane electrode assembly, and a membrane electrode assembly obtainable by such a method are also disclosed.
Resumen de: KR20260024959A
본 발명은 이리듐계 촉매를 포함하는 고분자 전해질막(Polymer Electrolyte Membrane: PEM) 수전해용 전극 촉매이며, 상기 이리듐계 촉매는 코어-셀(core-shell) 입자이며, 상기 코어는 이리듐 금속을 포함하며, 상기 쉘은 이리듐주석 복합산화물을 포함하는, PEM 수전해용 전극 촉매, 그 제조방법, 상기 전극 촉매를 포함하는 PEM 수전해용 전극, 및 이를 포함하는 PEM 수전해용 셀을 제공한다. 상기 PEM 수전해용 전극 촉매는 분산성 및 내구성이 향상된다. 이러한 전극 촉매를 포함한 전극은 산소 발생 반응 (oxygen evolution reaction: OER) 활성이 개선된다. 이러한 전극 촉매를 이용하여 형성된 PEM 수전해용 전극은 산소 발생 반응 (oxygen evolution reaction: OER) 활성이 개선된다. 이러한 전극을 이용하면 셀 성능이 개선된 PEM 수전해용 셀을 제조할 수 있다.
Resumen de: KR20260024382A
본 발명은 스테인레스 스틸 지지형 고체산화물 수전해전지 및 이의 제조방법에 관한 것으로, 본 발명에 따르면, 금속산화물 수전해전지의 제조시 스테인레스 스틸 다공성 지지체를 사용하여 고온에서의 열내구성이 뛰어나며 높은 수분 저항성을 나타내며, 양극(연료극)으로서 Ni, YSZ 및 페로브스카이트 산화물의 3가지 조성 혼합물을 사용함으로써 상기 페로브스카이트 산화물이 니켈(Ni) 입자 사이에 물리적 장벽 역할을 수행하고 전자전도성이 높고 융점이 니켈보다 높아 니켈과의 화학적 결합을 안정적으로 유지하여 니켈의 이동 및 조대화를 막고 전자전도를 향상시켜 고온에서도 니켈의 열화를 억제하여 수전해 전지 성능을 향상시킨다. 또한, 양극 제조시 기공형성제의 농도와 소성 온도를 조절하여 기공 크기 및 분포를 조절함으로써 전지 성능 향상을 더욱 증대시킬 수 있다. 또한, 상기 금속산화물 수전해전지는 슬러리를 테이프 캐스팅과 공소성을 통해 제조함으로써 제조가 용이하고, 연속 제조 공정이 가능하여 대량 생산이 가능하므로 종래 금속산화물 수전해전지를 대신하여 유용하게 사용될 수 있다.
Resumen de: KR20260024422A
본 발명은 전기화학적 활성 및 내구성이 우수한 수전해용 촉매 및 그 제조방법, 그를 포함하는 수전해 전지에 관한 것이다. 상기 수전해용 촉매 및 그를 포함하는 수전해 전지는 구조가 제어되어 있고, 알칼리성 및 산성 전해질에서 낮은 과전압에서 높은 전류밀도를 달성하기 때문에 전기화학적 활성이 우수하고, 향상된 내구성을 가지고, 그를 통해 수소의 생산에 대한 경제성과 효율성을 크게 향상시킬 수 있으며, 기존 촉매에 비해 전이금속 비율을 줄일 수 있어 그 제조비용을 줄일 수 있다. 또한, 상기 제조방법은 이온교환반응을 통해 구조를 제어할 수 있고, 상기와 같은 효과를 가지는 수전해용 촉매를 제공할 수 있으며, 제조과정에서 전이금속의 비율을 줄일 수 있어서 제조비용을 줄일 수 있다.
Resumen de: CN121359262A
The invention relates to a method for producing an assembly for an electrochemical cell, wherein the assembly comprises at least the following structural components: a first plate (10; 10 '), a proton exchange membrane (42), a first electrode (31) arranged between the first plate and the proton exchange membrane, and a first gas diffusion layer (21) arranged between the first plate and the first electrode, having the following steps: A) providing a substrate having only a part of the structural component, in particular the first plate and/or the first gas diffusion layer; b) assembling the components, wherein the assembling comprises the step of adding residual structural components; or the following steps: a) providing a substrate distinct from the structural component; b) assembling the components, wherein the assembling comprises adding structural components; wherein the bezel is formed by applying one or more layers of a molding material (70-72) to the provided substrate, the strength of the molding material being increased after said application, at least one layer of the molding material forming the bezel or at least one surrounding section of the bezel being applied prior to step B) or b). The invention also relates to an electrochemical cell, in particular a fuel cell or an electrolytic cell, to a cell stack having a cell of this type, and to a method and a facility for producing an assembly for a cell or a cell stack of this type.
Resumen de: KR20260024666A
본 발명은, 물을 다양한 목적으로 다양한 경로로 순환시킬 수 있는 다목적 펌프를 구비한 수전해 시스템에 관한 것이다. 상기 시스템은, 물탱크와 산소측 기액분리기를 연결하는 배관으로서 제1밸브, a합류점, 펌프, 이온교환기, b합류점, 제2밸브가 순서대로 배치된 제1배관과; b합류점과 물탱크를 연결하며 제3밸브가 배치된 제2배관과, 산소측 기액분리기와 a합류점을 연결하며 제4밸브가 배치된 제3배관과, 수소측 기액분리기와 a합류점을 연결하며 제5밸브가 배치된 제4배관을 포함한다. 여기서, 산소측 기액분리기의 수위가 제1 기준수위 미만이면, 제1 및 제2밸브를 개방하고 펌프를 동작시키고 제3, 제4 및 제5밸브를 폐쇄하고, 산소측 기액분리기 내의 물의 전기전도도가 제1 기준전도도 이상이면, 제2 및 제4밸브를 개방하고 펌프를 동작시키고 제1, 제3 및 제5밸브를 폐쇄하고, 물탱크 내의 물의 전기전도도가 제2 기준전도도 이상이면, 제1 및 제3밸브를 개방하고 펌프를 동작시키고 제2, 제4 및 제5밸브를 폐쇄하고, 수소측 기액분리기의 수위가 제2 기준수위 이상이면, 제2 및 제5밸브를 개방하고 펌프를 동작시키고 제1, 제3 및 제4밸브를 폐쇄하게 된다.
Resumen de: KR20260023453A
본 발명은 우수한 성능의 수전해 촉매를 제조할 수 있는 방법에 관한 것으로, 보다 구체적으로 본 발명은 니켈 전구체, 철 전구체 및 코발트 전구체를 포함하는 용액을 100℃ 이상 및 200℃ 이하의 온도에서 열처리하여 고형분을 수득하는 단계 및 상기 고형분을 동결건조하여 촉매 입자를 수득하는 단계를 포함하는 수전해 촉매의 제조방법에 관한 것이다.
Resumen de: KR20260024021A
본 발명은 수소 추출형 발전장비용 여과장치 및 그 제작방법에 관한 것으로서, 수소를 추출하여 전기를 생산하는 발전장비에서 미세 이물질의 포집 및 제거가 용이하게 이루어질 수 있게 되어 발전 효율을 향상시키는 효과를 나타낸다. 이를 실현하기 위한 본 발명은, 평탄면을 이루는 판상 구조를 이루는 가운데 다수의 타공(12)이 관통 형성된 타공판 본체(10)와; 상기 타공판 본체(10)의 저면에 스폿 용접에 의해 고정되는 매쉬망(20);을 포함하는 구성을 이루는 것을 특징으로 한다.
Resumen de: WO2026034682A1
Disclosed are an ammonia dehydrogenation catalyst with which hydrogen can be produced from ammonia in a high yield, and a method for producing hydrogen. The disclosed ammonia dehydrogenation catalyst includes nickel (Ni), lanthanide elements (M), and aluminum (Al).
Resumen de: US20260043150A1
A photocatalytic cell of the disclosure is installed in an inclined manner at an angle of 5° or more and 45° or less with respect to a horizontal plane. The photocatalytic cell includes: a translucent member; an electrolytic solution; a photocatalytic sheet including photocatalytic particles; an injection port through which the electrolytic solution is injected into an inside of the photocatalytic cell; a discharge port through which the electrolytic solution is discharged to an outside of the photocatalytic cell; and an exhaust port through which gas inside the photocatalytic cell is discharged, at least a part of the photocatalytic sheet is immersed in the electrolytic solution, a position of the exhaust port is higher than a position of the injection port, a gap between a surface of the translucent member and a surface of the photocatalytic sheet is 5 mm or more and 50 mm or less in width, and the injection port and the discharge port allow the electrolytic solution to flow from an upper part toward a lower part in the gap between the translucent member and the photocatalytic sheet.
Resumen de: KR20260022576A
본 발명의 일 실시예는 4차 암모늄화된 트립티센 첨가제를 포함하는 수전해용 음이온 교환막 및 이의 제조방법을 제공한다. 본 발명의 일 실시예에 따른 수전해용 음이온 교환막은 브롬화된 고분자 매트릭스 기지에 4차 암모늄화된 트립티센 첨가제를 도입하여 수전해 작동 온도 범위 내에서 추정된 수산화물 이온의 이온 전도성이 크게 향상되고 활성화에너지가 감소하여 수전해 전지의 성능을 개선하는 효과가 있다.
Resumen de: KR20260023671A
본 발명은, 배터리 방전을 이용한 수소 제조장치, 제조방법, 및 이를 이용한 탄화수소 연료 제조 시스템을 제공한다. 본 발명의 일실시예에 의하면, 상기 배터리 방전을 이용한 수소 제조장치는, 제1 방전대상 배터리 및 제2 방전대상 배터리가 전기적으로 연결되어 발생한 방전에 의하여 수전해가 이루어지는 방전 처리부; 상기 제1 방전대상 배터리가 상기 방전 처리부와 전기적으로 연결되도록 상기 제1 방전대상 배터리가 탑재되는 제1 배터리 탑재부; 상기 제2 방전대상 배터리가 상기 방전 처리부와 전기적으로 연결되도록 상기 제2 방전대상 배터리가 탑재되는 제2 배터리 탑재부; 및 상기 방전 처리부에서 상기 수전해에 의하여 발생한 수소 가스를 수용하는 수소 가스 수용부를 포함하고, 상기 제1 방전대상 배터리의 방전은, 상기 제2 방전대상 배터리에 의한 역전위 방전에 의하여 이루어질 수 있다.
Resumen de: KR20260023382A
본 발명의 일 실시예에 따른 플라즈마 버너는 내부 공간을 갖는 하우징, 및 상기 하우징 내부에 삽입되며 방전 전압으로 대전된 방전극을 포함하고, 상기 하우징은 상류측에 배치된 비방전 영역과 상기 비방전 영역의 하류에 연결되며 아크가 위치하는 방전 영역을 포함하며, 상기 방전극에는 연료가 이동하는 연료 통로와 상기 하우징 내부로 연료를 분사하는 연료 분사구가 형성될 수 있다.
Resumen de: KR20260022745A
본 발명은 전기화학적 활성 및 내구성이 우수한 수전해용 촉매 및 그 제조방법, 그를 포함하는 수전해 전지에 관한 것이다. 본 발명에 따른 수전해용 촉매 및 그를 포함하는 수전해 전지는 구조가 제어되어 있고, 알칼리성 전해질에서 낮은 과전압에서 높은 전류밀도를 달성하기 때문에 전기화학적 활성이 우수하고, 향상된 내구성을 가지며, 이를 통해 수소의 생산에 대한 경제성과 효율성을 크게 향상시킬 수 있다. 또한, 기존 촉매에 비해 전이금속 비율을 줄일 수 있고 특히 백금(Pt)을 전혀 사용하지 않아 그 제조비용을 크게 줄일 수 있다는 장점이 있다. 그리고, 본 발명에 따른 수전해용 촉매는 여러 조성의 입자로 구성될 수 있어서 원하는 목적에 따라 적당한 조성을 선택할 수 있다. 나아가, 본 발명에 따른 수전해용 촉매의 제조방법은 이온교환반응을 통해 구조를 제어할 수 있고, 상기와 같은 효과를 가지는 수전해용 촉매를 제공할 수 있으며, 제조과정에서 전이금속의 비율을 줄일 수 있고 백금(Pt)을 전혀 사용하지 않아 제조비용을 크게 줄일 수 있다.
Resumen de: DE102024207827A1
Die Erfindung betrifft eine Elektrolysevorrichtung (10) mit wenigstens einer Elektrolyseeinheit (12) zur Reduktion eines für die Elektrolyse vorgesehenen Mediums, insbesondere Wasser, mit einer Luftzuleitung (20) zur Zufuhr von Luft zur Elektrolyseeinheit (12), mit einer Abgasleitung (24) zur Ableitung von Anodenabgasen der Elektrolyseeinheit (12). Es wird vorgeschlagen, dass die Luftzuleitung (20) einen Verdichter (66) zur Druckerhöhung der Luft aufweist, die Abgasleitung (24) eine Turbine (74) aufweist, welche mechanisch mit dem Verdichter (66) gekoppelt ist.
Resumen de: JP2026027748A
【課題】燃焼器にNH3と酸化剤を供給してH2とN2に分解し、精製してH2を効率よく製造することが可能な燃焼式アンモニア分解装置および燃焼式アンモニア分解方法を提供する。【解決手段】アンモニアおよび酸化剤が供給される燃焼器11と、燃焼器11が設置される燃焼炉10と、燃焼炉10に接続された触媒槽20と、触媒槽20に接続され、アンモニアと水分を凝縮して分離する凝縮槽31と、凝縮槽31に接続され、吸着剤が充填された吸着塔33とを備え、燃焼炉10においては、燃焼器11にアンモニアおよび酸化剤を用いてアンモニア分解ガスを発生させ、触媒槽20においては、燃焼炉10から触媒槽20に導入されたアンモニア分解ガスに含まれる未反応アンモニアを分解し、触媒槽20が少なくとも2種類以上の触媒21,22により構成され、凝縮槽31ではアンモニアを水に溶解して吸着塔33に供給し、吸着塔33では水とアンモニアに分離する。【選択図】図1
Resumen de: WO2026037726A1
The invention relates to a method for operating an electrochemical system which comprises a plurality of electrochemical stacks (11; 12; 13; 21; 22; 23; 31; 32; 33) that are electrically and/or hydraulically interconnected. The following steps are carried out: - detecting at least one state parameter of each stack (11; 12; 13; 21; 22; 23; 31; 32; 33), - determining a degree of degradation of each stack (11; 12; 13; 21; 22; 23; 31; 32; 33) using the detected state parameters, - outputting a recommendation for replacing at least one stack (11; 12; 13; 21; 22; 23; 31; 32; 33) depending on the degree of degradation of the stack, wherein the recommendation comprises a degree-of-degradation range that the new stack (11; 12; 13; 21; 22; 23; 31; 32; 33) to be installed should have and a point in time at which the replacement should take place.
Resumen de: WO2026037594A1
The invention relates to an electrolysis device (10) having at least one electrolysis unit (12) for reducing a medium provided for the electrolysis, in particular water, an air supply line (20) for supplying air to the electrolysis unit (12), and an exhaust gas line (24) for discharging anode exhaust gases of the electrolysis unit (12). According to the invention, the air supply line (20) has a compressor (66) for increasing the pressure of the air, and the exhaust gas line (24) has a turbine (74) mechanically coupled to the compressor (66).
Resumen de: WO2026039480A1
A method for producing hydrogen including: performing electrolysis of a hydronium solution, the hydronium solution including: a molecule including hydrogen and oxygen; hydronium ions; hydroxide anions (OH-); a pH between -1.0 and 0.5; and a hydroxide anion OH- concentration of about 1% or less, wherein the hydronium solution is configured to maintain the same pH and the same hydroxide anion OH- concentration for at least six years. A method for producing hydrogen including: performing electrolysis of a hydronium solution, the hydronium solution including: a molecule including hydrogen and oxygen; hydronium ions; hydroxide anions (OH-); a pH between -1.0 and 0.5; and a hydroxide anion OH- concentration of about 1% or less, wherein the hydronium solution is configured to maintain the same pH and the same hydroxide anion OH-
Resumen de: WO2026039285A1
Provided are compositions comprising a catalytic oxide material having the atomic formula of M1xM2yM3zM4tM5uOv; and/or a catalytic alloy material having the atomic formula of M1xM2yM3zM4tM5u, where M1, M2, M3, M4 and M5 are selected from Ru, Ni, W, Nb, Mn, Fe, Ti, Ag, V, Co, and Mo. Further provided is the use of the catalytic oxide materials and/or the catalytic alloy materials in oxygen evolution reactions.
Resumen de: WO2026039286A1
Provided is a catalytic mixed metal oxide material that includes Ir, O, and which has the atomic formula of M1xM2yM3zIrtOu, or M1xM2yM3z(IrM4)tOu where between one and three elements labeled as M1 through M3 is selected from the group consisting of Ru, Sr, Fe, Co, Mn, Ni, Sb, Nb, W, and Sn and M4 is selected from Ru and Sr. Further provided is the use of the catalytic mixed metal oxide material in oxygen evolution reactions.
Resumen de: JP2026027770A
【課題】燃焼器にNH3と酸化剤を供給してH2とN2に分解し、精製してH2を効率よく製造することが可能な燃焼式アンモニア分解装置および燃焼式アンモニア分解方法を提供する。【解決手段】アンモニアおよび酸化剤が供給される燃焼器11と、燃焼器11が設置される燃焼炉10と、燃焼炉10に接続された触媒槽20と、触媒槽20に接続された吸着槽31とを備え、燃焼炉10においては、燃焼器11にアンモニアおよび酸化剤を用いてアンモニア分解ガスを発生させ、触媒槽20においては、燃焼炉10から触媒槽20に導入されたアンモニア分解ガスに含まれる未反応アンモニアを分解し、触媒槽20が少なくとも2種類以上の触媒21,22により構成され、吸着槽31においては、未反応アンモニアを吸着して回収する。【選択図】図1
Resumen de: US20260049370A1
The present invention concerns a metal material production configuration (1) and a method of direct reduction of a metal oxide material (5) holding a first thermal energy into a direct reduced metal material (16) by means of a metal material production configuration (1).The method comprises charging the metal oxide material (5), holding the first thermal energy, into a direct reduction facility (7); introducing a hydrogen, holding a second thermal energy, into the direct reduction facility (7).The invention involves reducing the metal oxide material (5) by using the first thermal energy of the metal oxide material (5) to heat or further heat the introduced hydrogen containing reducing agent (8) toward a required reaction temperature for providing a chemical reaction. A high-temperature exit gas (12) is removed from the direct reduction facility and fed to a high-temperature electrolysis unit (21) configured to produce the hydrogen.
Resumen de: US20260048995A1
A method for manufacturing nano metal oxides and hydrogen includes the following steps: Step A, providing a first reactor, and placing a metal material, an alcohol compound, and a first catalyst in the first reactor and applying heating thereto for reacting to generate a metal alkoxide compound, while simultaneously generating a substantial amount of hydrogen; and Step B, providing a second reactor, and, after the metal material in the first reactor has fully reacted in Step A, transferring remaining solution in the first reactor into the second reactor, and adding a second catalyst and a controlled amount of water, and applying appropriate heating to generate nano metal oxide in powder form. As such, effects of significant reduction of production cost, enhancement of safety, widespread application of hydrogen fuel cells, extremely low carbon emissions, being defined as “green hydrogen”, and reduction of storage costs and risks can be achieved.
Resumen de: AU2026200708A1
Abstract A separator for alkaline electrolysis (1) comprising a porous support (100) and a porous layer (200) provided on the porous support, characterized in that a lateral Bubble Point of the separator, measured according to the method described in the description, is at least 0.2 bar. Abstract an b s t r a c t a n
Resumen de: AU2024328340A1
Provided is an electrode exhibiting high oxygen generating electrode catalytic activity as compared with conventional electrodes using manganese-based oxide as an oxygen generating electrode catalyst.
Resumen de: WO2026038553A1
The present invention pertains to: an anion conductive film which includes a porous base material and an anion conductive polymer that is disposed, in addition to being provided inside of pores of the porous base material, on 70% or more of the area of at least one surface of the porous base material, and in which the anion conductive polymer has a constituent component (I) derived from a polyfunctional polymerizable monomer having a total of 2 or more of at least one atom selected from an oxygen atom, a sulfur atom, and a nitrogen atom at a structural part other than a polymerizable group, and the proportion of the constituent component (I) among all constituent components of the polymer is 50 mol% or more; a method for producing the anion conductive film; a membrane electrode assembly; a hydrogen production method; and a hydrogen production system.
Resumen de: WO2026037094A1
The present invention belongs to the technical field of electrochemical catalysis. Disclosed are the preparation and use of a nickel-foam-supported layered cobalt tungsten oxide catalyst for efficient water decomposition. In the present invention, nickel foam (NF) is selected as a substrate, on which two cobalt oxides having different morphologies successively grow by means of electrochemical deposition, wherein ComCo3O4 serves as a first layer and can tightly wrap around the NF, thereby preventing the NF from anodic corrosion and dissolution in a harsh acidic medium; AcCo3O4 serves as a second layer, and nanosheet-shaped Co3O4 has good OER activity itself; in addition, the large specific surface area also provides more growth sites for a tungsten oxide; and finally, the tungsten oxide is electrically deposited on the AcCo3O4. WxOy/AcCo3O4/ComCo3O4/NF prepared by using the above method has a low overpotential and good stability.
Resumen de: WO2026036170A1
This disclosure relates to a replaceable photocatalytic cartridge for use in a reactor, and a method for producing the replaceable photocatalytic cartridge. The replaceable photocatalytic cartridge being suitable for use within a reactor that photocatalytically splits water, such as a PWS reactor. In one embodiment, the photocatalytic cartridge comprises a container that contains a substrate that is coated with photocatalytic particles, wherein, in use, the photocatalytic cartridge is configured to be removably inserted into a receiving portion of the reactor such that the coated substrate is adapted to participate in a photocatalytic reaction with H2O and solar radiation within the reactor.
Resumen de: AU2024330634A1
The present invention refers to an electrolyser (1) for the production of hydrogen from an alkaline electrolyte. The electrolyser (1) comprises a first header (2) and a second header (3) between which a plurality of elementary cells (4) and a plurality of bipolar plates (5) are stacked. Each bipolar plate (5) separates two adjacent elementary cells. The electrolyser (1) further comprises a plurality of clamping elements (20) that mechanically connect said headers (2, 3). Each of the elementary cells (4) comprises a frame (6) defining a chamber (6A), having an anodic section and a cathodic section, in which an anodic electrode (7) and a cathodic electrode (8) are at least in part housed. Each of the elementary cells (4) further comprise a separator element (10) that separates the anodic section from the cathodic section. According to the invention, each of the frames (6) comprises first through holes (61) and each of the bipolar plates (5) comprises second through holes (51), wherein each of said first through holes (61) of one frame (6) is mutually aligned with a corresponding first through holes (61) of each of the another frames (6) and with one of said second through holes (51) of each bipolar plate (5), wherein each one of said clamping means (20) extends through said through holes (51, 61) mutually aligned.
Resumen de: AU2023460501A1
A composite separator and a preparation method therefor. The composite separator comprises a main film and an anti-contamination layer, which is arranged on one or both surfaces of the main film, wherein the anti-contamination layer comprises a first polymer, a charge agent and/or an anti-fouling agent. The composite separator can be applied to alkaline water electrolysis for hydrogen production and other electrolysis industries, and the anti-contamination layer of the composite separator can effectively prevent impurity species, especially metal ions fallen from a cathode catalyst, from being attached to the surface, which causes the sheet resistance to increase, thereby increasing the electrolytic energy consumption.
Resumen de: US20260049404A1
Disclosed are a photoelectric cell with a silicon carbide electrode (4) for photocatalytic production of hydrogen, and a manufacturing method therefor. The cell has on one side of the silicon carbide electrode (4) a window (2) the incidence of light (5) and on the other side of the silicon carbide electrode (4) an aqueous electrolyte (10) and a counter electrode (6). On the side of the silicon carbide electrode (4) facing the window, the cell is electrolyte-free. The silicon carbide electrode (4) is preferably produced by coating a substrate (3) with silicon carbide (4).
Resumen de: US20260049408A1
An electrolysis system includes an electrolyzer stack and a contamination mitigation system. The electrolyzer stack includes an injection port fluidly connected with a cathode compartment of the electrolyzer stack. The contamination mitigation system is configured to remove ions from the electrolyzer stack to mitigate ion contamination in the electrolyzer stack. The contamination mitigation system includes a storage tank including formic acid therein and an injection line fluidly coupled between the storage tank and the injection port. The injection line is configured to direct the formic acid from the storage tank to the injection port for injection into the cathode compartment of the electrolyzer stack.
Resumen de: US20260049405A1
A method of operating an electrolyzer cell system includes providing a steam inlet stream to a stack of electrolyzer cells, generating a main product stream containing hydrogen and steam, and an oxygen exhaust stream in the stack, and providing liquid water into the main product stream to cool the main product stream.
Resumen de: US20260049407A1
Provided is a carbon dioxide electrolysis device including: a carbon dioxide electrolysis cell including an anode, a cathode, an electrolyte, and a membrane disposed between the anode and the cathode. The carbon dioxide electrolysis device further includes; a supply line configured to supply gaseous carbon dioxide and water vapor to the cathode; and a discharge line configured to discharge, into the outside of the carbon dioxide electrolysis cell, the water vapor and a product produced by the electrolysis reaction of the gaseous carbon dioxide inside the carbon dioxide electrolysis cell, wherein the discharge line includes a condensation part configured to condense the water vapor discharged through the discharge line.
Resumen de: KR20240160080A
The present invention relates to a catalyst composite for a hydrogen production reaction having remarkably excellent catalytic activity and durability by an interaction effect between a porous carbon body doped with nitrogen of a high graphitic structure and a specific bonding type and a hydrogen active catalyst metal. More specifically, the present invention relates to a porous catalyst composite for a hydrogen production reaction, which comprises: a hydrogen active catalyst metal; and a porous three-dimensional net-type carbon support on which the hydrogen active catalyst metal is supported and containing nitrogen, wherein 30% or more of the total nitrogen contained in the porous three-dimensional net-type carbon support is nitrogen in a pyrrolic bond state.
Resumen de: KR20260021885A
본 발명은 물을 전기분해하는 방식으로 그린수소 제조를 위한 전기촉매에 관한 것으로서, 양극 산소 발생반응과 음극 산소 발생반응의 두가지 방식으로 수행하는 P-doped MnO2 전기촉매에 관한 것이다. 구체적으로 본 발명은 PMnO2 전기촉매는 합리적인 비용으로 가능한 열수반응과 CVD공법으로 합성되는 것으로, 먼저 MnO2 는 열수반응으로 전처리 과정을 거친 후에 CVD 퍼니스에서 MnO2 에 인(P)을 도핑한다.
Resumen de: TW202517835A
To provide iridium oxide suitable for proton exchange membrane-type water electrolysis, the iridium oxide having high initial activity and being excellent in stability during long-term operation. Provided is iridium oxide having a rutile structure, the iridium oxide being characterized by having: a crystallite size of 2.0 nm to 4.0 nm as calculated from a peak of a (110) plane of the rutile-structured iridium oxide determined by X-ray diffraction; and a BET specific surface area, measured by nitrogen adsorption measurement, of 70 m2/g to 120 m2/g.
Resumen de: AU2024303309A1
The present invention provides a method of controlling an electrolyser cell stack within a system having a fluid temperature control system, a current control system, a voltage monitoring system, monitoring/control systems for the temperatures of the fluid inlet and outlet, by controlling the current to a fixed value, calculating a temperature delta between the fluid inlet and outlet, and adjusting the fluid input temperature if the delta is greater than a threshold value. The present invention also provides a method of determining a stack operating condition is the temperature delta as measured above is lower than a threshold value. The present invention also provides a control device and computer program capable of executing the method as outlined above.
Resumen de: AU2024285985A1
A method of producing a hydrogen stream and an oxygen stream and passing the hydrogen stream and the oxygen stream to a reverse water-gas shift reactor is described, the method comprising: providing a water stream to an electrolysis system configured to form: a hydrogen stream at a first pressure, and an oxygen stream at a second pressure; passing the hydrogen stream, a carbon dioxide stream, and the oxygen stream to the reverse water-gas shift reactor, wherein the first pressure is lower than the second pressure.
Resumen de: AU2023443530A1
A method for forming a recombination layer includes, for example, an ionomer and a nanocrystal catalyst disposed in the ionomer. A method for forming the recombination layer may include, for example, providing an ionomer dispersion, providing a compound having a catalyst having a charge, adding the catalyst in the compound to the ionomer to form a mixture, reducing the catalyst in the compound to a metal catalyst in the ionomer, and forming the mixture with the metal catalyst into a recombination layer for a proton exchange membrane.
Resumen de: JP2026027768A
【課題】燃焼器にNH3と酸化剤を供給してH2とN2に分解し、精製してH2を効率よく製造することが可能な燃焼式アンモニア分解装置および燃焼式アンモニア分解方法を提供する。【解決手段】アンモニアおよび酸化剤が供給される燃焼器11と、燃焼器11が設置される燃焼炉10と、燃焼炉10に接続された触媒槽20とを備え、燃焼炉10においては、燃焼器11にアンモニアおよび酸化剤を用いてアンモニア分解ガスを発生させ、触媒槽20においては、燃焼炉10から触媒槽20に導入されたアンモニア分解ガスに含まれる残存アンモニアを分解し、触媒槽20が少なくとも2種類以上の触媒21,22により構成される。【選択図】図1
Resumen de: DE102024207773A1
Verfahren zum Betreiben einer elektrochemischen Anlage, die mehrere elektrochemische Stacks (11; 12; 13; 21; 22; 23; 31; 32; 33) umfasst, die elektrisch und/oder hydraulisch zusammengeschaltet sind. Dabei werden folgende Schritte durchgeführt:- Erfassen wenigstens eines Zustandsparameters jedes Stacks (11; 12; 13; 21; 22; 23; 31; 32; 33),- Bestimmen eines Degradationsgrads jedes Stacks (11; 12; 13; 21; 22; 23; 31; 32; 33) unter Verwendung der erfassten Zustandsparameter,- Ausgeben einer Empfehlung zum Austausch wenigstens eines Stacks (11; 12; 13; 21; 22; 23; 31; 32; 33) abhängig vom Degradationsgrad des Stacks, wobei die Empfehlung einen Degradationsgrad-Bereich umfasst, den der neu einzubauende Stack (11; 12; 13; 21; 22; 23; 31; 32; 33) aufweisen soll, und einen Zeitpunkt, zu dem der Austausch erfolgen sollte.
Resumen de: EP4696816A2
An electrolyzer stack is configured for high-speed manufacturing and assembly of a plurality of scalable electrolysis cells. Each cell comprises a plurality of water windows configured to maintain a pressure loss, temperature rise and/or oxygen outlet volume fraction below predetermined thresholds. Repeating components of the cells are configured based on a desired roll web width for production and a stack compression system is configured to enable a variable quantity and variable area of said repeating cells in a single stack. A high-speed manufacturing system is configured to produce scalable cells and assemble scalable stacks at rates in excess of 1,000 MW-class stacks per year.
Resumen de: WO2025002798A1
The invention relates to a reactor (2) for generating hydrogen and at least one other product from at least one reactant, the reactor comprising a tubular reactor vessel (4) which contains a catalyst (6) in the form of a ceramic bed. Improved corrosion resistance against a variety of media and thus an increased service life of the reactor (2) is achieved by forming the reactor vessel (4) from silicon-infiltrated silicon carbide (SiSiC).
Resumen de: AU2024304508A1
According to the invention, electrodes are arranged on two opposite surfaces of a separator. Each electrode consists of an open-pore metal structure, in particular a metal foam made of at least one of the chemical elements Ni, Al, Mo, Fe, Mn, Co, Zn, La, Ce, or an alloy of at least two of said chemical elements or an intermetallic compound of at least two of said chemical elements. A continuously decreasing catalytic activity is provided from the surface facing a separator or the respective other electrode of each electrochemical cell to the opposite surface of the respective electrode, and/or a continuously increasing porosity and/or pore size and/or a continuously decreasing specific surface area is provided from the surface facing a separator or the respective other electrode of each electrochemical cell to the opposite surface of the respective electrode.
Resumen de: WO2024214055A1
An electrolysis apparatus for the production of gaseous hydrogen and oxygen by water electrolysis is disclosed, with an electrolyzer (100) comprising a plurality of cells arranged next to each other to form a cell stack (116), wherein each cell includes an anode plate (122) and a cathode plate (124), and wherein the electrolyzer (100) further includes an anode end plate (118) and a cathode end plate (120) between which the cell stack (116) is clamped. The electrolyzer (100) has an active chamber (102) integrated therein, in which the electrolysis reaction of water contained in an electrolyte solution with which the electrolyzer (100) is fed takes place, a first liquid/gas phase separator (104) for separating oxygen gas from the electrolyte solution, and a second liquid/gas phase separator (106) for separating hydrogen gas from the electrolyte solution. The electrolyzer (100) also includes a plurality of sensors mounted on at least one of said anode and cathode end plates (118, 120) and configured to detect appropriate operating parameters of the first and second liquid/gas phase separator (104, 106).
Resumen de: CN121013926A
The invention relates to an electrochemical electrode structure comprising at least one electrode element and a support element. Each electrode element is a two-dimensionally extending conductive element having an open structure and has a first edge portion. The support element has an elastic region extending along the surface in a main extension plane of the elastic region. The elastic region is adapted to push the at least one electrode member away from the support element in a direction at least substantially perpendicular to a main plane of extension of the elastic region. The support element has a first tongue-shaped region arranged at an edge of the support element. A first edge portion of the at least one electrode element is curved around a first tongue-shaped region of the support element, thereby attaching the at least one electrode element to the support element. Furthermore, the invention relates to an electrochemical cell and a bipolar electrode assembly, each of which comprises such an electrode element, to an electrochemical cell arrangement having a plurality of such bipolar electrode assemblies, and to a method for attaching an electrode element to a support element of such an electrochemical electrode structure.
Resumen de: AU2023443530A1
A method for forming a recombination layer includes, for example, an ionomer and a nanocrystal catalyst disposed in the ionomer. A method for forming the recombination layer may include, for example, providing an ionomer dispersion, providing a compound having a catalyst having a charge, adding the catalyst in the compound to the ionomer to form a mixture, reducing the catalyst in the compound to a metal catalyst in the ionomer, and forming the mixture with the metal catalyst into a recombination layer for a proton exchange membrane.
Resumen de: AU2024249844A1
A method for thermal or thermochemical conversion of ammonia or methanol feedstocks into hydrogen (gas) in a related feedstock conversion facility (1000) is provided. The method comprises generating heated fluidic medium by at least one rotary apparatus (100), supplying a stream of thus generated heated fluidic medium into the feedstock conversion facility (1000), and operating said at least one rotary apparatus (100) and said feedstock conversion facility (1000) to carry out thermal or thermochemical conversion of the ammonia or methanol feedstocks into hydrogen at temperatures essentially equal to or exceeding about 500 degrees Celsius (°C). Facility (1000, 1000A) for production of hydrogen from ammonia or methanol feedstocks is further provided.
Resumen de: TW202511539A
The present disclosure provides hydrogen carrier fluid (HCF) compositions, comprising a leanliquid organic hydrogen carrier (lean-LOHC) component comprising at least one cyclohexyl-based compound having at least one unsaturated bond, optionally in combination with one or more C4-12 alkyl alcohol, or a rich-liquid organic hydrogen carrier (rich-LOHC) component comprising at least one cyclohexyl-based compound, optionally in combination with a C4-7 ketone, a C4-6lactone or a mixture thereof; and an electrolyte component. Also provided is the use of these HCF compositions for storage and release of hydrogen, in an electrochemical reactor system.
Resumen de: CN120958174A
The present invention relates to an electrochemical electrode structure comprising a current collector and at least one electrode element wherein the at least one electrode element is a two-dimensionally extending electrically conductive element having an open structure. In this electrochemical electrode structure, the at least one electrode element has at least one edge with a crimped rim, at which the strip portion of the electrode element is crimped away. Furthermore, the invention relates to an electrochemical cell comprising a first electrode, a second electrode and a separator wherein the first electrode or the second electrode or both electrodes are such an electrochemical electrode structure, and to a method for retrofitting a limited-gap electrochemical cell into a zero-gap electrochemical cell using such an electrochemical electrode structure.
Resumen de: EP4696815A1
Provided is a method of manufacturing an anion exchange membrane water electrolysis system exhibiting improved durability and efficiency, along with excellent water electrolysis performance.
Resumen de: CN121538669A
本发明属于高熵电极材料与电催化技术领域,具体涉及一种高熵磷硫化物自支撑电极材料及其制备方法和应用。所述电极材料包括导电基底和催化活性组分;所述催化活性组分为高熵磷硫化物,其由高熵普鲁士蓝类似物前驱体与磷源、硫源高温热处理制得;其中,所述高熵普鲁士蓝类似物前驱体的化学通式为M(Ⅱ)Fe(CN)6,M(Ⅱ)为Mn、Zn、Co、Fe、Ni、Cu中的至少三种;各M(Ⅱ)金属元素占全部M(Ⅱ)金属元素的摩尔百分比均为5%~35%。本发明高熵普鲁士蓝类似物前驱体与磷源、硫源高温热处理,将磷、硫元素成功引入高熵普鲁士蓝类似物骨架中。这种非金属元素掺杂能有效调节材料电子结构,显著降低析氧反应能垒,从而提升本征催化活性。
Resumen de: CN121538666A
本发明公开了一种用于可再生能源的AEM电解制氢系统及其动态控制方法,属于电解制氢技术领域,包括风光波动直连系统、动态响应控制中枢、AEM电解槽电堆以及气液分离纯化系统,通过“三阶变载策略”与“功率预测补偿”的结合,系统实现了冷启动时间小于30秒,功率在0‑100%范围内调节的响应时间小于5秒,完美适应可再生能源的秒级波动,显著提升了系统运行稳定性和寿命:优化的波浪形流场板和膜湿度闭环控制,共同确保了电堆内部反应环境的均匀和稳定,有效防止了变载工况下的膜电极损伤,显著延长了系统使用寿命,实现了与可再生能源的高效直连耦合。
Resumen de: CN121538660A
本发明公开了一种基于固体氧化物电解池电解重水制备高纯氘气的系统及方法。该系统包括重水加热装置、SOEC反应器、立式管式炉、氘气冷凝装置、外加电源和氘气存储罐。SOEC反应器位于立式管式炉中,固体氧化物电解池的两端连接外加电源。重水通过加热装置气化后直接输入到固体氧化物电解池的阴极,通过外加电压,将重水蒸汽电解为氘气,同时产生氧离子,氧离子通过电解质传输到阳极,在阳极氧化为氧气,实现重水电解制备高纯氘气的目的。该系统利用SOEC技术直接将重水蒸汽高温电解,经氘气干燥装置即可得到高纯氘气。该方法操作性强,安全风险低,易于规模化生产,解决了现有技术的重水除杂成本高,低温电解能耗高、效率低的问题。
Resumen de: CN121538674A
本发明公开了一种低铂碳载量的镍钼多酸‑高分子基自支撑电催化剂的制备方法和应用,涉及电催化剂技术领域。电催化剂的制备方法,包括以下步骤:称取配制电解质溶液的各原料;包括:硫酸镍、钼酸铵、氯铂酸、硼砂、聚乙烯醇以及壳聚糖;用去离子水分别将原料混合均匀得到镍钼多酸溶液、硼砂溶液和PVA‑CS溶液,得到目标电解质溶液并用碳纸浸泡;冷冻干燥;碳化;以处理后的碳纸作为工作电极,饱和甘汞电极作为参比电极,石墨电极作为辅助电极;采用循环伏安电沉积法在碳纸上电沉积铂制得电催化剂。本发明制备的电催化剂,能够降低成本、改善碱性溶液和碱性海水的反应动力学、降低过电位以及提高稳定性,使碱性海水电解过程更加经济和高效。
Resumen de: CN121535202A
本发明属于纳米材料制备与催化领域,公开了一种具有高孔隙率的核壳结构金属气凝胶及其制备方法。所述金属气凝胶包括如下成分:还原剂,Ru盐前驱体,配体;所述金属气凝胶中,还原剂、Ru盐前驱体、配体的摩尔比为(2‑4):1:1。本发明系统性调控反应物种类以及反应条件,通过一锅法合成具有高比表面积的单金属钌(Ru)气凝胶。随后通过调控马弗炉中的热处理时间和温度,精确调节核壳组分在气凝胶中的比例(Ru/RuO2),进而成功构建具有高孔隙率、Ru/RuO2核壳结构的金属气凝胶。实验结果表明,所制备的材料在全pH条件下均表现出优异的电催化析氢、析氧性能。本发明为设计具有核壳结构的金属气凝胶电催化剂提供了新策略。
Resumen de: CN121534765A
本发明属于氨硼烷水解析氢技术领域,公开一种Co‑Co3B界面双活性位点修饰的木质炭催化剂及其制备方法和应用。所述催化剂为核壳结构并且以BNC为壳,以Co‑Co3B异质结构为核;所述催化剂具有双活性位点:Co纳米颗粒和Co3B纳米颗粒,并且Co和Co3B之间存在界面结构;其中,所述BNC为氮化硼改性木质炭且具有多孔结构。本发明创造性地设计了Co‑Co3B界面双活性位点修饰的木质炭催化剂,BNC壳的存在不仅避免了催化剂失活还限制了金属颗粒的团聚,Co3B的引入增加了活性位点,与此同时,Co和Co3B之间还存在界面结构,优化了催化剂的电子结构和配位环境,降低了反应物分子的解离能垒,提高了催化活性,该催化剂在NH3BH3水解反应性能测试中,具有优异的催化性能,其产氢速率达到了10492mL·min‑1·gCo‑1。
Resumen de: CN121538657A
本申请提供一种用于制备不同氘丰度标气的装置,包括:进料单元,提供天然水,天然水包括氘水和氢水;电解制氢单元,电解天然水生成标气,标气包括氢气和氘气;水氢液相催化交换单元,包括在第一方向上依次连通的第一进料口、催化交换柱和第二进料口,第一进料口用于将标气传输至催化交换柱,第二进料口用于将天然水传输至催化交换柱;催化交换柱中氘气和氢水发生氢同位素交换反应,得到沿第一方向上氘丰度依次减小的标气;催化交换柱包括沿第一方向依次设置的至少两个出料口,任意两个出料口输出的标气的氘丰度不同。本申请的装置通过液相催化交换联合电解的方法,可以同时获得不同氘丰度的标气。
Resumen de: CN121534641A
本申请涉及氨分解制氢技术领域,具体提出了一种分区声场调控的液态金属氨分解反应器及其使用方法。反应器包括反应容器、设置在反应容器内的液态金属、设于反应容器底部区域并与液态金属连通的进气口,以及设于反应容器上部并与外部连通的出气口;反应容器底板的外侧设置有第一声场单元,反应容器外壁沿液态金属高度方向的上部区域设置有第二声场单元;第一声场单元为高频声振单元,第二声场单元为低频声振单元。本申请的底部高频声场使氨气气泡在生成阶段发生界面重构与分裂,上部低频声场使其在上浮阶段获得扰动与路径延长,从而提升液态金属体系的界面刷新效率,使气液界面在整个反应过程中保持一致活化水平,提高氨分解反应的整体反应速率。
Resumen de: CN121535023A
本发明公开了一种铝灰综合回收利用的方法,包括以下步骤:S1、对铝灰进行预处理;S2、向预处理后的铝灰中加入氢氧化钠溶液和添加剂,进行制氢反应,得到氢气、氨气及含氟铝酸钠溶液;S3、向含氟铝酸钠溶液中通入二氧化碳,进行反应,得到冰晶石和滤液;S4、向滤液中加入生石灰,进行反应,得到碳酸钙和氢氧化钠,将碳酸钙经高温烧结得到CaO和二氧化碳。本发明使用危废铝灰与添加剂、氢氧化钠混合反应来制氢,制得的氢气转化率高。本发明使用危废铝灰来制备冰晶石的方法具有成本低廉、反应条件温和、氟利用率高、环保无污染等优点,且制得的冰晶石产品纯度高、性能优良。本发明实现了无害化处理、减量化排放以及经济效益的最大化统一。
Resumen de: CN121534744A
本发明公开了一种硫锌镉固溶体负载二硫化钼光催化剂及其制备方法和应用,属于光催化产氢技术领域。所述光催化剂包括Cd0.7Zn0.3S固溶体及负载在表面的MoS2;光催化剂中,MoS2的含量为5~40wt%。本发明通过采用一步水热法在Cd0.7Zn0.3S表面构筑MoS2二维助催化层,促使二者形成紧密的界面接触与肖特基结,利用这种强界面耦合作用增强相互作用力,加速光生电荷转移,使其既具备高活性又兼顾低成本,能更充分地利用太阳能驱动光催化反应,大幅提升太阳能转化效率,为高效、稳定的光催化产氢技术提供了切实可行的解决途径,具有广阔的应用前景。
Resumen de: CN121541725A
本发明公开了一种集成电解水制氢与氢燃气轮机的能源系统,包括:富氧制备膜分离模块处理空气输出富氧气体,风光预测计算模块分析风速与光照数据生成电能产出曲线,电解功率分配模块据此向电解水制氢单元分配功率,富氧燃烧模拟模块计算燃烧场分布。耦合驱动控制模块采集氢气产量与燃烧效率数据,调节氢燃气轮机转速;参数监测反馈模块采集各模块参数并传输偏差值。同时,系统通过特定模型与算法优化富氧制备、功率分配、风光预测及燃烧模拟,风光预测计算、富氧燃烧模拟、耦合驱动控制模块还包含多个功能单元,运行时按六步启动各模块,该系统保障氢燃气轮机燃烧效率稳定,最终实现对高原缺氧环境下能源利用综合性能的显著提升。
Resumen de: CN121535538A
本发明公开了一种电解极板校正碾平装置,包括:底座;承载机构,用于承载极框,承载机构设于底座且包括多个承载组件;限位支撑机构,用于限位和支撑极框,限位支撑机构设于底座且包括沿周向间隔设置的多个限位支撑组件;下压机构,用于压着极框,下压机构设于底座;碾平机构,用于对极框焊缝进行碾平作业和平面度校正作业,碾平机构设于底座;上去毛刺机构,设于底座;下去毛刺机构,设于底座。本发明解决了极框加工和焊接过程中出现的变形、毛刺问题,通过将矫平、碾压、去毛刺集成于一体,可以将1.5‑2mm的焊高碾压到0.2‑0.5mm,使得焊缝内气孔被碾平,同时可以对极框的平面度进行校正,控制在1mm以内,极大地节约了人工成本和提高了产品质量。
Resumen de: CN121538667A
本发明公开了一种基于三电极体系的两步法电解水制氢的装置及其工艺,包括电源与两个以上串联的三电机电解池,单个三电机电解池包括电解液储罐,电解液储罐内设置有产氢催化电极、氢氧化镍电极与产氧催化电极,其中首个电解液储罐的氢氧化镍电极通过单刀双掷开关和电路分别与电源的正负极连通,其中一组电解液储罐的氢氧化镍电极与相邻另一组电解液储罐的产氢催化电极、产氧催化电极通过单刀双掷开关连通,尾部电解液储罐的产氢催化电极、产氧催化电极分别通过两组单刀双掷开关与电源的正负极连通。本发明的优点在于制氢纯度高、成本低,且易于串并联集成化和操作。
Resumen de: CN121538682A
本发明属于催化能源转化技术领域,具体为一种低铱掺杂氧化钌基酸性析氧催化剂及其制备方法。本发明催化剂制备包括,将可溶性钌金属前驱体盐与其他金属前驱体盐溶解混合于乙二醇,利用乙二醇的还原性将金属离子还原为低价态;再加入碳载体作为模板,控制金属颗粒粒径;随后经溶剂热反应、热解氧化得到催化剂;其中钌为基础金属,掺入金属包含过度金属与铂族贵金属。本发明制备工艺兼顾催化效率与催化剂的合成成本,具有高度的拓展性,材料成分具有高度的可选择性。制得的催化剂利用多元素协同调控有效优化钌在水氧化反应中的反应活性与稳定性,为电解水阳极催化剂降本增效提供了新的选择,具有较好的应用前景。
Resumen de: CN121534754A
本发明涉及制氢技术领域,具体是公开一种氨分解制氢催化剂及其制备方法,所述氨分解制氢催化剂包括载体和负载在载体上的钌基活性组分,其中,所述载体为液相沉积法制备的生物炭/二氧化钛复合载体,所述钌基活性组分为钌金属。本发明通过优化复合载体组分之间的相互作用与活性金属的分散度,协同解决活性、稳定性、成本和钌活性组分的分散度等问题,显著提升氨分解制氢的效率。
Resumen de: CN121538681A
本发明涉及电催化技术领域,且公开了一种析氢纳米颗粒催化剂制备方法。该析氢纳米颗粒催化剂制备方法,将含氮杂环有机物与镥源在溶剂中溶解后,经稀硝酸调节pH,在反应釜中结晶后再经研磨,超声处理,于管式炉中高温处理后,制得析氢纳米颗粒催化剂。本发明制备得到的析氢纳米颗粒催化剂具有良好的催化效率,且成本低,市场前景广阔。
Resumen de: CN121545608A
本申请公开了一种基于PEM电解水模块和EHC模块的耦合系统的水管理方法,涉及氢能技术领域。通过控制PEM电解水模块的最佳电流密度,调节进入EHC模块的水含量,使EHC模块始终运行在最佳水合状态,从而提高系统整体效率。该方法包括以下步骤:S1.建立PEM电解水模块的最佳电流密度与EHC模块的目标压比的关系模型JPEM‑r:S2.获取EHC模块的目标压比;S3.根据EHC模块的目标压比,通过JPEM‑r关系模型得到PEM电解水模块的最佳电流密度;S4.调节PEM电解水模块的实时电流密度至目标电流密度,实现对EHC系统的水管理。本申请同时公开了一种基于PEM电解水模块和EHC模块的耦合系统。本申请用于提升PEM电解水模块和EHC模块的耦合系统的性能。
Resumen de: CN121534743A
本发明公开了一种ZnCdS/NiO‑C异质结光催化剂的制备方法及应用,通过水热法合成ZCS粉末;以绿茶无水乙醇提取物为模板和碳源,通过热解法制备TOP‑Ni助催化剂;通过溶液自组装法将ZCS粉末与TOP‑Ni助催化剂复合,得到。本发明构建了高效的异质结界面,促进光生载流子的分离和转移,提高了光催化析氢的整体效率和可见光利用率,同时降低了光生电子‑空穴复合概率;利用绿茶无水乙醇提取物作为生物质模板诱导的助催化剂结构,提供了高比表面积和丰富的介孔通道,有利于增加活性位点并优化反应物/产物的传质过程,提升了表面反应动力学。
Resumen de: CN121537570A
本发明提供了一种光催化水凝胶的制备方法,属于光催化技术领域,旨在解决传统制氢高能耗污染、现有光催化水凝胶纯度低及性能不稳定的问题。方法先分步制备CPDT‑1、CPDT‑2Br‑SO3Na、PCT‑SO3Na、Fluo‑2Br‑SO3Na、PFT‑SO3Na、PCBT‑SO3Na、PFBT‑SO3Na七种前驱体,过程通过氮气吹扫防氧化、丙酮沉淀‑重结晶‑索氏提取纯化;再将四种活性前驱体分别与丙烯酸、季戊四醇三烯丙基醚、(2,4,6‑三甲基苯甲酰基)二苯基氧化膦混合,经365nm紫外光照射聚合,制得四种光催化水凝胶。该方法条件温和、操作可控,产物纯度高、光催化性能稳定,适用于氢能制取与水污染治理。
Resumen de: CN121538664A
本发明公开一种制氢行业碱液浓度自动测量与调节系统,涉及制氢技术领域,包括测量装置、回收装置、调节装置和PLC控制系统。测量装置通过碱液循环泵出口管道的减压阀、取样电磁阀连接密封耐压的测量容器,容器内的密度、温度、液位变送器实时传信至PLC;回收装置将测量容器内碱液经回收泵、电磁阀及止回阀抽回制氢系统分离器;调节装置通过补碱和补水装置精准补入浓碱与纯水,由PLC控制完成闭环调节。优点:该系统实现不停机带压测量,碱液回收再利用,自动化程度高且调节精准,提升生产效率、节能环保,保障制氢稳定。
Resumen de: CN121534738A
本发明属于光催化能源转化技术领域,具体为一种多孔蜂窝状CTF复合光催化剂及其制备方法和应用。本发明复合光催化剂由硫缺陷ZnIn2S4纳米片修饰处理得到;具体通过固相模板法构建吩噻嗪功能化三维有序大孔共价三嗪框架,并原位生长硫缺陷ZnIn2S4纳米片,形成三维有序大孔网络限域二维纳米片多级异质结构;得益于CTF‑PTZBN中吩噻嗪单元通过分子锚定作用诱导ZIS‑Sv定向生长,界面C‑S‑Zn/In键桥接形成稳定电子传输通道,随后骨架内建电场协同硫缺陷态构建电场驱动‑通道传输‑陷阱捕获三元载流子调控体系,实现光生电荷高效分离与定向迁移,成功减少光生载流子的复合。该二元复合材料表现出优秀的制氢以及苯乙烯选择性环氧化反应的性能。
Resumen de: CN121534788A
本发明公开了一种活化棉纤维素气凝胶负载Co‑B复合材料Co‑B/A‑CC,首先,采用溶剂交换法活化棉纤维素制得活化的棉纤维素A‑CC,然后,将A‑CC在LiCl/DMAc溶剂体系溶解得到活化棉纤维素溶液,再将CoSO4·7H2O置于活化棉纤维素溶液得到Co/A‑CC混合溶液,最后,将Co/A‑CC混合溶液注射到NaBH4水溶液中进行发泡即可得到。Co‑B/A‑CC的微观形貌为三维分层多孔框架结构,多级孔洞分布形态的尺寸涵盖微孔到宏孔;Co‑B纳米粒子作为活性物质。其制备方法包括以下步骤:1,棉纤维素A‑CC的活化;2,Co/A‑CC混合溶液的制备;3,Co‑B/A‑CC的制备。作为硼氢化钠水解制氢催化剂的应用时,在303K条件下最大产氢速率为3800‑4500mL·min‑1·g‑1,放氢量达到理论值的100%;8次回收/重复使用后,保留初始催化活性的71.7‑81.5%;活化能为Ea=45.3‑48.9kJ·mol‑1。
Resumen de: CN121538670A
本发明公开了一种煤基碳纤维负载磷化钴自支撑催化剂的制备方法及其在电解水制氢中的应用,属于电解水催化剂技术领域。该催化剂由煤基碳纤维载体和负载于其上的磷化钴活性组分组成;磷化钴活性组分由钴基层状氢氧化物与ZIF‑67的复合前驱体经磷化处理衍生得到。具体方法为:以静电纺丝法制备的煤基碳纤维为载体,在含有六水合硝酸钴和聚乙烯吡咯烷酮的水溶液中采用电沉积法在其表面生长钴基层状氢氧化物,再通过浸渍法原位生长ZIF‑67,形成钴基层状氢氧化物与ZIF‑67复合的前驱体结构,最后经磷化处理得到煤基碳纤维负载磷化钴自支撑催化剂。该催化剂具有亲水性、电解水催化活性和稳定性。
Resumen de: CN121537394A
本发明涉及一种自组装卟啉笼状化合物及其制备方法与应用,属于电催化水分解技术领域。一种自组装卟啉笼状化合物,其结构式如下所示。本发明通过对卟啉进行结构修饰,引入吸电子基团硝基(‑NO2),利用非贵金属锌(Zn)来调节催化剂的电子结构和表面活性位点,通过配位作用形成卟啉笼,并将其作为碱性析氧电催化剂进行应用。本发明所述自组装卟啉笼状化合物的分子结构清晰明确,制备过程中无需使用贵金属,大幅降低生产成本,对推动清洁能源技术发展具有重要意义。
Resumen de: CN121540853A
本发明公开了一种多通道电解槽产气质量测量系统及方法,包括电解槽巡检采样模块、气液处理模块、氮气供应模块、产气质量测量模块、回流模块;所述气液处理模块包括气液分离器,所述电解槽巡检采样模块包括若干电解槽,若干电解槽均通过采样管路连接到气液分离器的入口,气液分离器的底部出口通过出液管路连接到回流模块,所述氮气供应模块包括连接到气液分离器入口的氮气吹扫管路。本发明所述的多通道电解槽产气质量巡检测试方法,可实现在线切换不同电解槽产气质量巡检,可满足不同压力下的在线测试,提出了制氢系统尤其多台电解槽并机测试无法检测到单个电解槽的产气质量的解决方案。
Resumen de: CN121538675A
本申请属于电催化析氢技术领域,具体涉及一种金属型钴‑碳化钒异质结构复合材料及其制备方法和应用。该方法先将Zn(NO3)2·6H2O与Co(NO3)2·6H2O溶于甲醇中,然后加入2‑甲基咪唑甲醇溶液,搅拌均匀,继续加入含有MXene溶胶的甲醇/水混合液,搅拌反应,洗涤,干燥,得到前驱体,最后置于混合气氛中进行高温热解,冷却,得到所复合电催化材料。本发明采用MOF在二维V2C MXene表面原位组装,可有效控制前驱体的组成与结构,实现钴‑碳化钒异质结构在介孔碳片中的均匀分散,避免了传统金属纳米颗粒易团聚、分布不均等问题。此外,本发明合成工艺简便可控,无需复杂后处理或多步煅烧过程,适合规模化生产。
Resumen de: CN121538658A
本发明公开了一种氢气和有机酸的联产装置及方法,联产装置包括电解槽,电解槽内设置有析氢电极、氢氧化镍电极与有机物催化氧化电极,电解槽内加注有碱性电解液,析氢电极、氢氧化镍电极与有机物催化氧化电极底部均埋设于碱性电解液内,方法包含两个循环交替进行的阶段:产氢阶段,水在阴极析氢电极的电化学还原生成氢气,同时氢氧化电极被电化学氧化,生成NiOOH;有机物催化氧化阶段,有机醇在阳极有机物催化氧化电极发生电化学氧化生成相应的羧酸,以及NiOOH电化学还原生成Ni(OH)2。本发明的优点在于将具有增值效应的有机醇电氧化反应替代析氧反应,在阳极获得高价值的有机羧酸,进一步提升分步电解体系的经济效益。
Resumen de: CN121538668A
本发明公开了一种富含晶界的高熵金属硫化物多孔纳米管阵列催化剂及其制备方法和应用,属于催化剂领域。所述催化剂具有多孔纳米管阵列结构,包括一维多孔纳米管,所述多孔纳米管是由纳米粒子组装而成,若干所述多孔纳米管交错堆叠形成密集的多孔纳米管阵列;所述多孔纳米管尺寸为6~8μm,直径为40~80nm,且富含晶界微区结构。本发明的催化剂具有丰富的晶界结构,使得其能够提供更多高活性反应位点,同时高效催化析氧反应和硫氧化反应。
Resumen de: CN121536888A
本发明涉及纳米材料技术领域,具体地,涉及一种二维闪锌矿结构Zn1‑yCdySe纳米片及其制备方法和应用。所述制备方法包括以下步骤:1)在保护气存在的条件下,将一价铜源溶液与CuSe纳米片溶液反应,制得立方相Cu2‑xSe纳米片;2)将步骤1)中制得的立方相Cu2‑xSe纳米片分散于非极性溶剂与磷系助剂的混合液中得前驱体溶液,将金属盐溶于极性溶剂得金属盐溶液,将前驱体溶液与金属盐溶液混合反应;其中,所述金属盐溶液含锌源与镉源;0≤x≤1;0.05≤y≤0.3。该制备方法原料易得,反应温和,条件可控,适用于工业化大批量生产;同时,制得的纳米片催化性能优异,稳定性强,在光催化水分解领域展现出优异的催化性能。
Resumen de: CN121538683A
本发明涉及复合隔膜技术领域,具体涉及一种原位生成的碱性电解水隔膜及其制备方法。隔膜包括聚合物基体,所述聚合物基体由聚砜和/或聚醚砜构成;所述聚合物基体内部含有原位生成的层状双金属氢氧化物纳米颗粒;其制备方法包括首先将碱性前驱体加入有机极性溶剂中,将溶液pH值控制在8‑11,得到碱性极性溶液,再将聚砜或聚醚砜溶解于碱性极性溶液中,随后将金属盐前驱体加入到聚合物溶液中,使层状双金属氢氧化物在聚合物溶液中原位生成,搅拌使金属盐前驱体和聚合物搅拌混合,最终对聚合物溶液进行流延、相转化、后处理,随后固化成膜。本发明降低了隔膜的面电阻的同时还提升了复合隔膜的化学稳定性与长期运行稳定性,具有规模化生产的前景。
Resumen de: CN121538685A
本发明涉及材料测试分析技术领域,具体涉及一种水解制氢测试方法、设备及系统,通过获取若干工况下的电解槽工作电压,确定每个工况下的相对可控系数;根据每个工况下的相对可控系数和电解槽工作电压分析水解制氢反应的稳态变动趋势,确定每个工况下的运行稳态程度;通过每个工况下的运行稳态程度动态优化每个类型的运行参数值的调整步长,进而基于调整结果确定水解制氢测试对应的最优运行参数值组。本发明通过多工况数据收集全面了解系统行为,然后通过相对可控系数和运行稳态程度评估参数敏感性和系统稳定性,最后动态调整步长实现高效精确的寻优,其克服了固定步长方法的缺陷,能够快速、精确地确定最优运行参数值组。
Resumen de: CN121538677A
本发明公开了一种富含氧空位的Fe掺杂NiO电解水析氧催化剂及其制备方法与应用,包括:将镍基基底进行酸化预处理;将镍盐、铵盐和尿素溶解于溶剂中,加入预处理后的镍基基底进行水热反应,形成片状纳米阵列结构;将NiO前驱体进行退火处理,通入惰性气体以排空氧气,并在惰性气体保护下升温至退火温度后保温1~3h,在保温阶段开始时,切换为氩氢混合气保持10~30min,随后切换回惰性气体并持续至退火处理结束;将NiOx催化剂前体浸泡于铁源溶液中,经风干处理。本发明通过Fe掺杂与氧空位协同作用,在催化碱性环境中的电化学析氧反应中,表现出较好的催化活性和稳定性,具有很好的工业应用前景和商业价值。
Resumen de: CN121534764A
本发明涉及光催化制氢技术领域,具体公开了一种磺酸化氮化碳纳米片光催化剂,其是通过将含氮前驱体进行热处理后,得到氮化碳前驱体;再将与硫酸溶液混匀后微波处理,固液分离后得到磺酸化氮化碳纳米片光催化剂;本发明制备的磺酸化氮化碳纳米片光催化剂,具有更高的比表面积,更窄的带隙能量以及更大的光响应范围,并且具有更高的光催化产H2活性,应用前景广泛。
Resumen de: JP2023012629A
To provide a water decomposition device capable of easily collecting generated hydrogen, the whole device being easily and compactly configured.SOLUTION: A water decomposition device (1) comprises: an electrolytic cell (5) in which an electrolytic solution (3) is housed; an oxygen generation electrode (9) which is a photoelectrode including an n-type semiconductor layer (7) immersed in the electrolytic solution (3) in the electrolytic cell (5); and a hydrogen generation electrode (13) including a hydrogen storage alloy layer (11) immersed in the electrolytic solution (3) in the electrolytic cell (5).SELECTED DRAWING: Figure 1
Resumen de: US20260035242A1
A hydrogen generation system with controlled water distribution is disclosed. The system comprises a reaction chamber containing a hydrogen-producing fuel, a liquid distribution mechanism, and a control system. The liquid distribution mechanism includes a rotating arm with liquid injection ports that move vertically through the fuel chamber. This allows for precise and efficient liquid delivery to unreacted fuel, optimizing hydrogen production. A proprietary fuel blend utilizes chemicals that store significant amounts of hydrogen in a solid-state form. A feature of the device is the arm's controlled vertical movement, achieved through a screw mechanism that adjusts the arm's height as it rotates, creating a spiral liquid distribution pattern. The control system regulates liquid injection rates, arm rotation speed, and vertical movement to optimize hydrogen production based on demand. The system can also operate at low pressures and be scaled to different sizes in a safer, more efficient, on-demand manner.
Resumen de: JP2026025239A
【課題】無機化合物を含む不溶化補助剤を必要とせず、かつ簡便な方法で行える水素の製造方法を提供すること。【解決手段】本開示にかかる水素の製造方法は、アルミニウム合金をアルカリ溶液に反応させて水素を製造する方法であって、アルカリ溶液は、界面活性剤を含み、界面活性剤は、アルミニウム合金に含まれる不純物を不溶化する不溶化補助剤である。これにより、無機化合物を含む不溶化補助剤を必要とせず、かつ簡便な方法で行える水素の製造方法を提供することができる。【選択図】図1
Resumen de: CN121519091A
本发明公开一种双金属硫化物/三维多孔碳催化剂的制备方法和应用,涉及电解水催化剂技术领域,包括以下步骤:将三聚氰胺海绵进行清洗,得到清洁的三聚氰胺海绵;将金属盐1、金属盐2溶解于乙醇水溶液中,加入碱和苯胺单体,获得前驱体溶液;将所述清洁的三聚氰胺海绵完全浸泡在前驱体溶液中,经恒温水热反应后,依次进行洗涤、干燥,得到锚定双金属离子的三聚氰胺海绵;通入惰性气体保护,并进行高温硫化处理,得到嵌入双金属硫化物异质结构的三维多孔碳催化剂。所述催化剂包括均匀分散的双金属硫化物纳米颗粒和海绵状三维多孔碳载体,当应用于电催化分解水反应中,展现出优异的双功能催化活性和稳定性,具有广阔的应用前景。
Resumen de: KR20260021272A
본 발명은 전기 전도성 및 전기화학적 활성이 높으며, 동시에 내구성이 우수한 이종구조 촉매를 제조하는 방법, 이로부터 제조된 이종구조 촉매 및 이러한 이종구조 촉매를 포함하는 수전해 전극과 수전해 장치를 제공한다.
Resumen de: CN121513760A
本公开属于电能转化技术领域,提供了一种二氧化碳甲烷化反应器。该反应器包括电解单元和化学催化单元,二者均设置于支撑体上;电解单元包括若干固体氧化物电解池单元,用于电解二氧化碳和水产生一氧化碳和氢气;化学催化单元用于接收一氧化碳和氢气以及电解产生的废热,以进行化学催化反应,从而制备甲烷;支撑体为NiO与氧化锆基电解质、造孔剂的混合物,氧化锆基电解质选自YSZ、ScYSZ中的至少一种。本公开的反应器使得化学催化反应在常温下即可进行,无需高压。其将电解和化学催化相结合,实现了一体化制备,有效降低了反应的能耗,将可再生能源转化为易于储存和运输的甲烷,转化率高。
Resumen de: WO2025028379A1
Provided is an ammonia decomposition catalyst that has a high ammonia decomposition activity even at a low reaction temperature and a low reaction pressure, and has stable catalyst characteristics even when repeatedly used in reactions after being exposed to water or the atmosphere. A barium nitride according to the present invention is represented by general formula (1). (1): BaAN2-x (In general formula (1), A is at least one type of element selected from the group consisting of Si, Fe, Ni, Mo, and Zr, and x represents a numerical value represented by 0≤x<2.0.)
Resumen de: CN116439627A
The invention is applicable to the technical field of cleaning appliances, and discloses an integrated water tank capable of cleaning and separating, which comprises a clean water tank, a sewage tank and a water tank cover, the clean water tank contains and outputs clean water to a cleaning tool, the top wall is provided with a water outlet, and the inner wall of the bottom wall is connected with a water pumping joint; the sewage tank collects sewage output by the cleaning tool, the peripheral wall and the bottom wall of the sewage tank are closed, and only the top is open; the water tank cover can cover the clear water tank and the sewage tank from the top at the same time, a clear water outlet and a sewage inlet are formed in the water tank cover, the water tank cover is directly or indirectly connected with a water pumping pipe which is arranged in the clear water tank and communicated with the clear water outlet, and the other end of the water pumping pipe is communicated with a water pumping connector. The clean water tank and the sewage tank of the water tank can be detached independently, and the whole water tank is convenient to assemble and maintain; the clear water outlet and the sewage inlet arranged on the water tank cover are far away from the water tank electricity-taking interface, so that short circuit of the electricity-taking interface caused by water tank leakage can be avoided.
Resumen de: CN121519104A
本申请属于电催化材料技术领域,公开了一种钌钴双金属掺杂的二硫化钼析氢电催化材料的制备方法,包括以下步骤:制备离子液体并用其对碳布进行亲水性改性;一锅法制备Co掺杂且负载在改性碳布上的MoS2;对Co‑MoS2/MCC在管式炉中高温退火得到富含Mo空位的催化剂;采用还原成键技术向Co‑MoS2/MCC中引入Ru,最终得到钴钌双掺杂的CoRu‑MoS2/MCC。本申请在碳布上进行离子液体亲水性改性,再负载Co掺杂的MoS2,经高温退火造取富含Mo空位的催化剂,通过还原成键技术使Ru元素掺杂其中,形成钴钌双掺杂的MoS2复合材料,将MoS2的层状结构优势与Co、Ru的高电催化活性结合起来,从而提升材料的析氢电催化性能。
Resumen de: CN121513930A
本公开提供一种碳自掺杂氮缺陷催化剂的制备方法及碳自掺杂氮缺陷催化剂、制氢方法以及还原方法,涉及光催化剂技术领域,包括:将尿素和尿酸混合,经搅拌和煅烧处理后,得到碳自掺杂的g‑C3N4基底材料;对所述碳自掺杂的g‑C3N4基底材料在惰性气氛下进行煅烧,制得碳自掺杂氮缺陷催化剂。本公开能够提高碳自掺杂氮缺陷催化剂的光催化性能。
Resumen de: CN121513890A
本发明涉及氨分解制氢的技术领域,公开了一种基于二氧化铈反相催化剂进行氨分解制氢的方法,包括如下步骤:(1)将镍前驱体、钴前驱体、铁前驱体混合作为金属前驱体,将金属前驱体和二氧化铈粉末混合,得到A溶液;配制碱溶液作为B溶液;(2)将B溶液滴加至A溶液的同时进行搅拌,滴加完成后,经离心、干燥、有氧焙烧,得到反相催化剂;(3)将氨气与反相催化剂接触反应,温度为400~500℃,压力为0.01~1MPa,得到氢气。本发明通过多元金属组分设计、界面协同构筑与制备工艺优化,形成二氧化铈小颗粒锚定和高度分散在Ni‑Co‑Fe多元金属氧化物载体的反相催化剂,从而实现高效催化活性。
Resumen de: CN121516935A
本发明公开了一种低过电势高稳定性的NiFeCu氢氧化物的制备方法,属于电解水催化材料制备技术领域。所述低过电势高稳定性的NiFeCu氢氧化物的制备方法,包括如下步骤:将镍盐、铁盐、铜盐、聚乙烯吡咯烷酮和水混合,得到混合液;以导电基底作为阴极和阳极,在所述混合液中进行电沉积,形成所述NiFeCu氢氧化物。本发明采用“一锅”的电沉积法,在反应体系中加入PVP作为结构导向剂,将所有原料混合均匀后,通过控制电沉积的反应时间和电流密度,调节反应速率,从而控制催化材料的形貌,制备低过电势高稳定性的NiFeCu氢氧化物,适用于电解水制氢领域。
Resumen de: CN121521676A
本发明公开了一种用于电催化析氢材料的检测装置,本发明涉及电化学检测技术领域,包括底板,以及固定在其顶部的电解池,所述电解池的外表面固定安装有电源,所述电源的正负极均连接有导线,所述导线的端部固定安装有电极棒安装件,所述电解池顶部的两侧可拆卸安装有密封盖,所述电解池两侧分别安装有氧气收集机构与检测机构。该用于电催化析氢材料的检测装置,通过密封盖防止空气进入电解池影响实验结果,检测机构通过激光位移传感器实时检测位移件位置变化,进而计算产氢量和产氢速率,电极棒安装件稳固安装电极棒,提高了电极安装的稳定性,还能适应不同直径的电极棒,减少了接触电阻带来的测量误差,确保了实验数据的准确性。
Resumen de: CN121519090A
本发明提供了一种稀土掺杂的雷尼镍电极、制备方法及应用,步骤包括:对导电基材进行粗化处理;采用喷涂工艺,将复合粉末喷涂并沉积于所述导电基材上,得涂层导电基材;将所述涂层导电基材置于碱性溶液中进行活化处理,得所述稀土掺杂的雷尼镍电极;其中,所述复合粉末包括镍粉、铝粉、稀土组分的粉末。稀土组分的引入能够改善镍的电子结构,提高电极的导电性和催化活性,降低析氢过电位。喷涂工艺使不同粒径的粉末形成一层一层堆叠起来的致密且均匀的涂层,增强了耐腐蚀性和机械强度。本发明无需复杂的设备和高昂的成本,且稀土元素添加量较少,适合大规模工业化生产。
Resumen de: US20260043153A1
Systems and methods are provided for water electrolysis. The system includes an electrolyte material configured for the exchange of anions, a first electrode including a nickel-cobalt-phosphorus-based compound, and a second electrode, wherein the first electrode and the second electrode are configured to exchange the anions through the electrolyte material.
Resumen de: CN121519099A
本发明公开了一种P掺杂Bi4Si3O12‑Bi12SiO20异质结光电催化材料及其制备方法和应用,制备方法包括:取Bi(NO3)3·5H2O加入乙二醇中搅拌至溶解得到溶液A;取九水硅酸钠加入去离子水中,搅拌至溶解得到溶液B;将溶液B逐滴加入溶液A,搅拌至均匀得到混合溶液,加入磷酸钠,搅拌至均匀得到溶液C;调节溶液C的pH值至3~14,向溶液中加入CTAB,搅拌至均匀后填充进反应釜内衬中,置于水热烘箱中100~220 °C反应6~48 h,烘箱内温度降至室温后取出反应釜冷却,经过离心、洗涤、干燥得到粉体,即P掺杂Bi4Si3O12‑Bi12SiO20异质结光电催化材料,P掺杂Bi4Si3O12‑Bi12SiO20异质结的构建促使界面电荷转移,改善光生电荷分离,提高了长寿命电荷的产率,从而抑制了电荷重组,大幅度提高了光电催化水裂解的效率。
Resumen de: CN121519080A
本发明涉及电解水制氢技术领域,公开了一种电解水制氢用装置及方法,包括电解槽,电解槽包括槽体,槽体的两侧均安装有循环出液口和循环进液口;电解液循环单元,电解液循环单元包括安装在槽体上的净化罐;净化罐的内部设置有拦截机构,拦截机构包括设置于净化罐内部的旋转轴,旋转轴的两侧安装有拦截盘,且拦截盘之间设置有多组拦截板。本发明通过设置拦截盘和拦截板的旋转拦截机构,实现了对电解液中较大颗粒杂质的初步高效拦截过滤,并且在拦截机构转动时,可以利用流入的电解液对拦截板进行反冲洗,实现了连续、高效的自清洁功能,有效防止了过滤孔的堵塞,显著提高了电解水制氢装置的整体运行效率和稳定性。
Resumen de: AU2024291792A1
The disclosure concerns a process of carbon oxides-free hydrogen production is disclosed. The process comprises the following steps: - heating a gas stream of a reacting compound including hydrogen atoms in absence of oxidizing agents, to thermally decompose the reacting compound into smaller product compounds, including hydrogen molecules, obtaining a stream of decomposition product compounds; - separating hydrogen molecules from other product compounds of the stream of decomposition product compounds; - reacting a portion of the stream of separated hydrogen molecules with a stream of an oxidizing agent, in particular oxygen or air, to obtain combustion product compounds, including steam and heat, in a stream of combustion product compounds; - providing heat obtained in the previous step to the step of heating the reacting compound; and wherein the process can comprise a step of - recovering energy from the stream of decomposition product compounds and/or from the stream of combustion product compounds. Additionally, a system of hydrogen production is also disclosed, the system being configured to operate according to the above process.
Resumen de: WO2025012271A1
The invention relates to a plant for preparing H2 by catalytically decomposing NH3. The plant according to the invention can be operated in a start-up mode in order to heat apparatuses of the plant to an increased operating temperature using a heat-transfer medium, e.g. following interruption of a continuous operation of the plant due to maintenance work. After heating to the operating temperature, the plant according to the invention can be operated in a production mode for continuous production of H2. The invention also relates to a method for starting up a plant for preparing H2 by catalytically decomposing NH3.
Resumen de: CN121513919A
本发明公开了一种用于可见光光解水制氢的MXene修饰TiO2/Cd0.3Zn0.7S异质结复合光催化剂的制备方法。其包括通过氢氟酸蚀刻MAX相(Ti3AlC2)制备Ti3C2 MXene,利用水热氧化技术将TiO2纳米片原位生长并锚定在Ti3C2 MXene表面形成Ti3C2@TiO2复合材料,再通过油浴加热负载Cd0.3Zn0.7S纳米颗粒制得最终复合光催化剂。该制备方法简单、条件温和、成本低廉,无需添加表面活性剂或模板剂。所制备的复合光催化剂具有优异的光催化分解水产氢性能,析氢速率高达48.92 mmol·g‑1·h‑1,较纯Cd0.3Zn0.7S与Ti3C2@TiO2分别提升43.67倍与99.83倍,且循环稳定性良好,4次循环后活性保持95%以上,在420 nm处表观量子效率达74.6%。本发明为高效光催化体系提供了新思路,适用于太阳能转化及环境净化领域。
Resumen de: CN121518072A
本发明公开了一种聚苯硫醚隔膜‑聚四氟乙烯垫片粘接用环氧胶粘剂及其制备方法,属于碱性电解水制氢技术领域,一种聚苯硫醚隔膜‑聚四氟乙烯垫片用环氧胶粘剂,原料包括A组分和B两组分;其中,所述A组分包括环氧树脂、单官能团型苯环刚性结构稀释剂、硅烷交联改性纳米氧化锆粉末、聚苯硫醚微米级粉末、纳米碳化硅粉末、助剂;所述B组分为胺类固化剂。本发明制备的胶粘剂具有耐强碱、耐高温、对基材有高适配性和低VOC等多方面的优点。
Resumen de: CN121513905A
本发明涉及催化领域,特别是涉及一种整体式氨分解制氢催化剂及其制备方法和用途,所述整体式氨分解制氢催化剂包括蜂窝载体和活性涂层,所述活性涂层涂覆于所述蜂窝载体上;所述活性涂层包含钌、碱金属、复合金属氧化物以及碳材料;所述复合金属氧化物包覆碳材料;所述钌和碱金属负载在复合金属氧化物包覆的碳材料上。本发明所提供的整体式氨分解制氢催化剂具有较高的低温氨分解活性、较大的产氢速率和优异的长周期稳定性,且该催化剂技术制备工艺简单,能耗低,适合大规模生产应用。
Resumen de: CN121513696A
一种中微量元素耦合富氢水的复合供应装置及供应方法,复合供应装置包括原料供应单元、二阶混合单元和控制单元;原料供应单元包括供液机构、供氢机构和提供中微量元素的供料机构;二阶混合单元包括混粉设备和三相混合设备;混粉设备用于将供氢机构提供的氢气与供料机构提供的粉料混合,得到气载粉体;三相混合设备设置在混粉设备下游,用于将供液机构提供的液体与所述气载粉体混合均匀,得到中微量元素耦合富氢水;控制单元,用于调控中微量元素耦合富氢水中的中微量元素和/或氢气含量。本发明的复合供应装置及供应方法在确保氢气持续稳定供应的基础上,还能够为植物供应生长所需的中微量元素,实现了氢肥的协同供应。
Resumen de: CN121519108A
本发明公开了一种核壳结构二氧化钛载铱/氧化铱催化剂及其制备方法与应用,先将二氧化钛与前驱体水溶液混合经过水热反应得到水热产物,水热产物经洗涤、干燥后,再于特定气氛下煅烧后得到表面改性的二氧化钛载体;再将铱源与表面改性的二氧化钛载体于含有还原性物质的溶剂中,于避氧条件下加热反应后得到铱/改性二氧化钛中间体;将铱/改性二氧化钛中间体经酸洗和分段控温热处理得到二氧化钛载铱/氧化铱催化剂。本发明显著增强铱活性组分的分散度及其与载体的相互作用,制备工艺简单、成本可控、催化活性高且稳定性优异。
Resumen de: CN121519075A
本发明公开了一种制氢模块用新型结构的多功能水箱,包括箱体主体,箱体主体顶端设置有上盖组件,箱体主体底部设置有若干个辅助固定组件,箱体主体内设置有防浪组件,箱体主体前侧设置有呈上下布局的第一传感器、第二传感器、第三传感器,上盖组件上设置有鼓风机,上盖组件上位于鼓风机侧部设置有回水接口组件。本技术方案的水箱,结构设计巧妙,实用性较强,水箱强度高,且密封性好,具有一定的耐压能力,不会漏水漏气,具有水位监控,温度和电导率监控,自动进水和排水,以及气体排出等功能,运用此水箱结构,保证了制氢模块的正常工作,箱体内部的防浪板结构,有效防止了回水对内部水体的干扰,有效保证了制氢过程的稳定性和效率。
Resumen de: CN121519081A
本发明涉及一种再生烟气中CO2的转化方法及系统。本发明中将水送入电解水装置中进行电解,得到外部氧气和外部氢气;将所述外部氧气作为助燃气送入气体换热器与高温低压烟气换热后得到高温助燃气和低温低压烟气,将所述高温助燃气送入催化裂化再生器中进行再生烧焦,将所述低温低压烟气分为循环烟气和待转化烟气,将待转化烟气送入CO2电化学转化单元进行电化学转化反应,得到合成气和再生氧气。本发明充分提高了催化剂的再生效率、降低处理尾气中的CO2排放量,实现了处理装置的合理配置以及电解水副产氧气的高效利用,提高经济效益的同时达到了环境保护的目的。
Resumen de: CN121519103A
本发明涉及一种氮硫共掺杂碳包覆CoS2析氧电催化材料及其制备方法,属于电催化材料技术领域,包括以下步骤:取钴盐溶液与钴氰化钾溶液反应制得钴氰化钴前驱体;在惰性气氛下,对钴氰化钴前驱体进行高温热处理,得到中间产物;在惰性气氛下,以硫为硫源,对中间产物进行硫化处理,制得氮硫共掺杂碳包覆CoS2析氧电催化材料。本发明方法采用廉价的过渡金属化合物作为原料,具有制备工艺简单,容易控制,便于规模化生产等优势。采用本发明方法制得的氮硫共掺杂碳包覆CoS2析氧电催化材料在碱性条件下具有优异的析氧催化活性,且化学稳定性好。
Resumen de: FI20246009A1
The present disclosure relates to methods and arrangements for improving the operational flexibility of systems (200) comprising an electrolyzer (201) configured to produce hydrogen and one or more downstream hydrogen processing units (202a-d), wherein at least one of the one or more downstream hydrogen processing units has a hydrogen mass flow operating capacity more restricted than hydrogen mass flow operating capacity of the electrolyzer. The operational flexibility of the system is improved by feeding additional hydrogen from an additional hydrogen source (203) to the one or more downstream hydrogen processing units to compensate for the difference.
Resumen de: CN121519079A
本申请实施例公开一种基于三维正弦型曲线流道的流场板及质子交换膜水电解槽,流场板包括至少一条流道;流道包括若干依次排列且相互平行的流道段,相邻的流道段之间通过圆弧段交替首尾平滑连接;流道段由第一正弦型曲线流道和第二正弦型曲线流道交汇形成,在平行于流场表面的方向,第一正弦型曲线流道沿第一正弦型曲线延伸;在垂直于流场表面的方向,第二正弦型曲线流道沿第二正弦型曲线延伸,并在第一正弦型曲线流道的底面交汇形成间隔分布的凹坑,在第一正弦型曲线流道的侧面交汇形成间隔分布的侧洞。本申请实施例能够提升流体传输效率、优化气泡脱附与排放、改善温度均匀性,大幅度提升反应物的供给、产物的排出和系统的稳定性。
Resumen de: CN121513937A
本发明公开了一种碳载钼基复合物和层状双金属氢氧化物共修饰的光催化剂及其制法,属于光催化分解水产氢技术领域。所述光催化剂中,碳载钼基复合物为薄壁大/介孔中空氮掺杂碳管HNC负载的Mo2C/MoO2复合物,记为Mo‑C/O,利用Mo‑C/O作为助催化剂,限制了Mo2C/MoO2复合物的尺寸;层状双金属氢氧化物为笼状NiCo‑LDH复合物,Mo2C/MoO2和NiCo‑LDH共修饰ZnCdS;ZnCdS与Mo2C/MoO2构成肖特基结,NiCo‑LDH、ZnCdS间构成II型异质结,Mo2C/MoO2、ZnCdS和NiCo‑LDH间形成级联电子传输通道。本发明双异质结构之间的协同作用不但能够扩宽光响应范围,还能进一步增强光生载流子的分离效率,提高电荷迁移的驱动力,推动电子的定向迁移,提高反应动力学,进一步提高光催化析氢性能。
Resumen de: CN121519102A
基于钨球限域与原位转化策略构筑的酸性电解水多金属复合电催化剂及其制备方法和应用,它涉及多金属复合电催化剂的制法及应用。它是要解决现有的多金属电催化剂在酸性电解水中的催化活性、稳定性和可扩展性差的技术问题。本发明的催化剂是由W多酸团簇构筑的粒径为200~600nm球体,RuO2纳米晶与MnCO3镶嵌在球体表面并均匀分布在球体内部。制法:一、制备W球基底;二、制备W‑Mn‑Ru前驱体;三、制备W‑MnCO3/RuO2电催化剂。它在酸性OER和HER中,在电流密度为100 mA cm‑2时的电位分别为1.489 V和‑0.145 V,可用于在绿色能源转化和储存技领域。
Resumen de: CN121519891A
本发明涉及超基性岩石天然氢开发技术领域,是一种基于流速控制的水力激活超基性岩石自发断裂生氢方法,其利用水力压裂激活超基性岩层的水岩反应,通过水岩反应产生的矿物挤压和放热效应,使超基性岩层自发断裂,形成多级裂缝网络;之后注入含镍离子流体,所述含镍离子流体沿裂缝流动后进一步发生水岩反应,生成氢气。本发明提出的基于流速控制的水力激活超基性岩石自发断裂生氢方法,其通过精确控制含镍离子流体的注入速度,实现反应速率、裂缝扩展与氢气生成的动态平衡,流体注入速度与反应速率匹配,实现自发可控生氢。
Resumen de: CN121519093A
本发明涉及一种高稳定电解水催化剂及其制备方法和应用,属于电催化技术领域。催化剂,包括碳布,碳布上负载有四元合金,四元合金包括摩尔比为(1.2~1.8):(1.2~1.8):(0.7~0.9):(0.1~0.3)的镍、铁、镓和铂。碳布能够改善活性组分的分散性,并提升电子传导效率。四元合金的协同掺杂能够提升本征活性,抑制活性位点的团聚与溶解。在碱性环境下具备优秀的电化学性能,兼具高催化活性与长循环稳定性。
Resumen de: JP2026025107A
【課題】膜抵抗が充分に実用的なものでありながら、無機粒子の脱落を充分に抑制することができるアルカリ水電解用隔膜を提供する。【解決手段】多孔性支持体と、該多孔性支持体の片側又は両側の主面に設けられ、無機粒子及び有機樹脂を含む多孔膜と、を備えるアルカリ水電解用隔膜であって、更に、該多孔性支持体と該多孔膜とからなる本体層の片側又は両側の主面の少なくとも一部を覆う、中性又は塩基性の極性官能基を有する第1樹脂を含む被覆膜を備えることを特徴とするアルカリ水電解用隔膜。【選択図】なし
Resumen de: JP2026024144A
【課題】水電解効率を向上させる。【解決手段】水電解スタックは、互いに電気的に直列に接続され、水電解を行うアニオン交換膜型の複数のセルと、複数のセルに電解液を供給するための第1マニホールドと、複数のセルから電解液を排出するための第2マニホールドと、を有するマニホールド構造体と、を備え、第1マニホールドおよび第2マニホールドのうちの一方または両方の内壁面は、電解液よりも高い絶縁性を有する。【選択図】図1
Resumen de: JP2026024159A
【課題】多孔質構造を有するアルカリ水電解用隔膜において、き裂や打痕、摩耗などの軽度の欠陥が生じた場合に隔膜を補修する方法を提案する。【解決手段】高分子多孔質膜から成るアルカリ水電解用隔膜のガス遮断性を低下させる欠陥部分を溶着して当該欠陥部分の多孔質構造をバルク構造に変化させることにより、前記欠陥部分の前記ガス遮断性を回復させる。【選択図】図3
Resumen de: WO2026028789A1
This diaphragm for alkaline water electrolysis separates an anode chamber in which an anode of an alkaline water electrolysis tank is disposed and a cathode chamber in which a cathode is disposed, the diaphragm for alkaline water electrolysis comprising a polymer porous membrane integrally having a seal region, which is sandwiched by a tank-constituting member in the alkaline water electrolysis tank, and a separator region, which is disposed on the inner-peripheral side of the seal region. The separator region has an inter-electrode region that is smaller than the separator region and is sandwiched between the anode and the cathode, and a non-restraint region present between the seal region and the inter-electrode region. The polymer porous membrane has a frame-shaped bulk part that extends across the seal region, the non-restraint region, and the inter-electrode region.
Resumen de: CN121513870A
本发明涉及一种结构化氨分解催化剂及其制备方法和反应器,该结构化氨分解催化剂包括载体,该载体由电阻丝制成,其表面由内向外依次设有氧化铝晶须层和催化层,其两端分别通过导线与电源装置电性相连。该结构化氨分解催化剂的制备方法包括:1)氨分解催化剂粉末制备;2)催化浆料制备;3)载体预处理;4)催化层涂敷。从而,可防止在弯折变形时发生催化层的脱落,提升了使用的灵活性与拓展应用场景。同时,还可以直接在载体上施加电流而进行原位焦耳加热,极大的减少传热损失,提高能量利用率,并可降低床层压降,进一步降低能耗。
Resumen de: CN121517719A
本发明属于MOF材料领域,具体公开了一种用于光催化产生氢气的MOF材料及其制备方法和应用。所述MOF材料的分子式为Fe(anby)(SCN)2,晶体结构为有机配体与金属铁原子连接,桥联形成的规则二维网状结构;其中anby为9、10‑双(4‑吡啶基)蒽。本发明的配合物可在400nm的氙灯下,加入BIH、RuPS还有水和乙腈构建的光催化还原CO2体系中高效制氢。本发明促进了人工光合催化剂的发展,在新型能源应用和环境治理方面具有良好的发展前景。
Resumen de: CN121513927A
本发明公开了碱金属与碳共掺杂的聚合物碳氮化物光催化材料及其制备方法与应用。涉及光催化材料领域。碱金属与碳共掺杂的聚合物碳氮化物光催化材料的结构中包含碱金属‑N键和C=C双键,其中碱金属为Li、Na或K。本发明通过碱金属与碳共掺杂策略,在聚合物碳氮化物(PCN)中同步引入C=C双键和碱金属‑N键(如Li-N键、Na-N键或K-N键),从根本上提升了材料的光催化性能。
Resumen de: CN121519087A
本发明公开了一种基于时间序列分步化学转化的高性能雷尼镍网析氧电极,是通过分步化学浸渍法依序在基底雷尼镍网上先构筑界面稳定层,再生长催化功能层而获得;界面稳定层前驱液包含铈离子、镧离子、钇离子的至少一种;催化功能层前驱液包含主活性金属离子和协同调控元素离子,所述主活性金属离子包含镍离子和铁离子、或镍离子和亚铁离子,所述协同调控元素离子包含钴离子、锰离子、钒离子中的至少一种。本发明的雷尼镍网析氧电极具有界面稳定层与催化功能层紧密结合的梯度复合结构,在微观结构、宏观性能与长期稳定性方面都得到显著优化,且该制备工艺适用于工业大规模生产,为制约工业析氧电极发展的技术瓶颈提供了可行的解决方案。
Resumen de: CN121519106A
本发明提供了一种用于电解水制氢的氧化钼‑碳化钼复合催化剂及其制备方法,所述制备方法主要包括以下步骤:1)将钼酸铵和尿素经水热反应得到氧化钼纳米带;2)对氧化钼纳米带进行低温一次热碳化得到前驱体MoOx/C纳米带;3)将前驱体MoOx/C纳米带进行二次微波碳化和还原热处理即制备氧化钼‑碳化钼复合催化剂。本发明所制备的氧化钼‑碳化钼复合催化剂显著增加了催化活性位点,有效调节电子结构,进而展现卓越的电解水析氢性能。该方法具有工艺简单、成本低廉、可控性好等优势,适合大规模推广应用,在电解水制氢领域具备广阔的应用前景。
Resumen de: CN121513879A
本发明公开了一种碳基氨裂解制氢催化剂的制备方法及其应用,步骤如下:对纳米洋葱碳载体进行酸洗和钾盐溶液浸渍活化两级预处理,得到活化载体K‑CNO';采用均匀沉积沉淀法,将钴盐、镁盐、尿素与所述活化载体在水热条件下反应,经沉淀、过滤、洗涤、干燥和煅烧,制得最终催化剂CoxMg/K‑CNO'。本发明通过酸洗在CNOs表面引入含氧官能团,通过钾活化提升载体碱性和比表面积,并与活性组分Co及助剂MgO产生强协同效应,实现了Co基活性中心的高分散、强稳定性和丰富的表面碱性位点。该催化剂在氨分解制氢反应中表现出优异的低温催化活性和稳定性,在特定条件下氨转化率高达99.6%,且可在500℃下长期稳定运行。
Resumen de: CN121517656A
本发明公开了一种芘基共价有机框架材料的制备方法及其在光催化产氢反应中的应用,属于多相催化领域。本发明通过调控三苯胺数量,将具有不同含量的三苯胺单体整合到芘基共价有机框架(COF)骨架中,合成了一类新型芘基COFs光催化剂。本发明操作简单,反应条件温和,反应时间短,可重复性高,所得芘基COFs具有良好的光捕获能力和光生载流子分离特性,同时能够有效降低电子‑空穴复合,延长激发态寿命,从而提高光催化产氢的反应效率,具有潜在的应用前景。
Resumen de: CN121513761A
一种立式硅碳棒解水剂制氢装置,属于制氢技术领域,主要由料箱、解水剂料、供料管、电动阀、外管、反应管、落料板、硅碳棒、上盖、下盖、回收管、水箱、供水管、回收罐、蒸汽发生器、蒸汽管、电磁铁、压簧、氢气出口等组成,其特征是:料箱内装解水剂料,供料管上端接料箱中部串连两个电动阀下端接上盖进料口,反应管上端的上盖设有进料口和氢气出口内设落料板下端的下盖设有出料口和蒸汽进口,外管内置硅碳棒外设蒸汽发生器反应管从内通过。工作过程是:通电后,电磁铁振动,硅碳棒加热,解水剂料在重力和振动力作用下,由料箱内经电动阀进入反应管内,受热后与水蒸汽接触发生化学反应产生氢。氢气经氢气出口收集备用;剩余料经下盖出料口排出,由回收罐收集备用。优点有:1成本低于现有工业制氢;2无污染;3原料充足易得。
Resumen de: CN121519107A
本发明为一种电催化析氢用非晶镍/结晶二氧化钼材料的制备方法和应用。该方法包括以下步骤:将Mo系杂多酸放置于管式炉下游,固体气氛源放于管式炉上游,然后向管式炉内通入混合气体,升温到400‑700℃热解还原0.5‑5 h,得到非晶镍/结晶二氧化钼材料;Mo系杂多酸具体为钼酸镍NiMoO4、6‑钼镍酸四铵或9‑钼镍酸六铵;固体气氛源为尿素、三聚氰胺、氯化铵或双氰胺。本发明制备简单,催化剂组分可调,析氢反应活性高。
Resumen de: CN121521680A
本发明涉及碱性电解水制氢技术领域,公开了一种多参数融合的气液分离效果在线评估方法,包括以下步骤:在气液分离器回流碱液管道上实时采集碱液质量分数浓度、流体温度、实际混合密度和质量流量信号;根据实时采集的碱液质量分数浓度和流体温度,动态计算当前工况下无气泡纯碱液的理论密度;计算所述理论密度与实际混合密度的绝对偏差;对质量流量信号进行实时噪声水平分析;根据所述绝对偏差与预设密度偏差阈值的比较结果;输出分离结果判断结果并执行相应报警或联锁控制。本发明通过在控制单元中实时根据在线测量的碱液质量分数浓度和温度动态计算无气泡纯碱液的理论密度,实现了在浓度实时变化工况下的可靠分离结果评估。
Resumen de: WO2025012277A1
The invention relates to a method for the preparation of H2 from NH3. NH3 is introduced into a fixed-bed reactor at a gas temperature in the range from 550 to 850°C, in which fixed-bed reactor NH3 is decomposed on an NH3 decomposition catalyst partly into H2 and N2. The gas mixture obtained in this manner is discharged from the fixed-bed reactor at a gas temperature in the range from 300 to 700°C, is heated to a temperature in the range from 550 to 700°C and is then introduced into a tubular reactor in which further NH3 is decomposed on a nickel-based NH3 decomposition catalyst into H2 and N2. The gas mixture obtained in this manner is discharged from the tubular reactor at a gas temperature in the range from 550 to 750°C.
Resumen de: CN121519105A
本发明属于催化剂材料技术领域,具体涉及一种用于电解水制氢的双金属氮化物催化剂及其制备方法。所述方法为,将钒源、钛源溶于双氧水中,加入聚乙烯吡咯烷酮作为碳源,进行水热反应,得到前驱体,前驱体于氨气中进行氮化反应,即得所述双金属氮化物催化剂。所述催化剂为超薄二维多孔结构,可暴露丰富的催化活性位点,并且原位的碳基体复合提高了催化剂的稳定性。本发明可通过改变钒\钛比来调节双金属氮化物的电子结构,提高催化活性,从而表现出优异的电催化性能和良好的循环稳定性。本发明的制备方法操作简单、可控且适合规模化制备,在电解水产氢工业领域具有良好的应用前景。
Resumen de: CN121513943A
本发明涉及一种Co@BC‑PCN光热催化剂的制备方法和应用。本发明将三聚氰胺分散于一定浓度的磷酸水溶液中,然后进行水热处理使部分三聚氰胺水解为三聚氰酸,同时得到磷掺杂超分子前驱体;将此前驱体与废弃咖啡渣混合后,在氮气氛下焙烧得到由磷掺杂剥离的类石墨相氮化碳纳米片与咖啡渣生物炭组成的复合材料;进一步通过湿法浸渍‑原位还原制得Co@BC‑PCN光热催化剂。本发明通过三聚氰胺‑三聚氰酸热解自组装制备剥离的类石墨相氮化碳,结合磷掺杂和生物炭修饰来提高催化剂的比表面积,增强可见光吸收能力,减少光生载流子的复合,使得该催化剂在光热催化硼氢化钠水解产氢反应中有优异的催化性能。
Resumen de: JP2026024157A
【課題】アルカリ水電解用多孔質隔膜において膜の物理的強度を向上する。【解決手段】アルカリ水電解槽の陽極室と陰極室とを隔てるアルカリ水電解用隔膜は、アルカリ水電解槽において槽構成部材に挟み込まれるシール領域と、シール領域の内周側に配置されたセパレータ領域とを一体的に有する高分子多孔質膜を備える。セパレータ領域は、バルク構造の補強部を有する【選択図】図3
Resumen de: CN120569516A
The invention provides an electrolytic cell system (10). The electrolytic cell system comprises a heat storage unit (14) and an electrolytic cell (16). The heat storage unit (14) comprises at least one heat source feed inlet. The electrolytic cell (16) comprises at least one electrolytic cell cell (20), a steam inlet and at least one exhaust gas outlet. The exhaust outlet is connected to the heat source feed inlet to heat the heat storage unit (14). The heat storage unit (14) is configured to use its stored heat to generate steam for one of feeding into the steam inlet at a time and generating electricity or both feeding into the steam inlet at the same time and generating electricity. The invention also provides a system comprising an intermittent or variable power source (12) and an electrolytic cell system (10) as defined above. The intermittent or variable power source (12) may be configured to simultaneously or separately power the electrolysis cell (16) and heat the heat storage unit (14) via a heating element.
Resumen de: MX2025009259A
A hydrogen generation system includes: a direct current (DC) power supply providing a driver signal, a reactive circuit coupled to the power supply and configured to generate a pulse drive signal from the driver signal, at least one reaction chamber coupled to the reactive circuit and receiving the pulse drive signal wherein the chamber is configured to generate hydrogen from feedstock material utilizing the pulse drive signal, a gas analyzer coupled to the at least one reaction chamber and configured to detect the generated hydrogen, and a control unit coupled to the reactive circuit and to the gas analyzer and configured to control the reactive circuit based on the detected hydrogen. The reaction chamber includes a plurality of positively charged elements and a plurality of negatively charged elements. The elements are composed of non-dis similar metallic material.
Resumen de: WO2026028790A1
Disclosed is a diaphragm for alkaline water electrolysis, which separates an anode chamber and a cathode chamber of an alkaline water electrolysis cell. This diaphragm for alkaline water electrolysis is provided with a polymer porous film which integrally has a sealing region that is sandwiched by cell constituent members in the alkaline water electrolysis cell, an edge region that is disposed on the outer peripheral side of the sealing region, and a separator region that is disposed on the inner peripheral side of the sealing region. The sealing region has a shape surrounding the separator region, and has a bulk part for preventing permeation of an electrolyte solution through the pores of the polymer porous film.
Resumen de: CN121513942A
本发明公开了一种泡沫状磷掺杂氮化碳限域金属钴光热催化剂的制备方法和应用,属于光热催化材料制备与硼氢化物制氢领域。本发明制备方法通过盐酸与磷酸混酸溶液对三聚氰胺进行处理,再借助三聚氰胺‑三聚氰酸超分子前驱体自组装一步得到泡沫状磷掺杂类石墨相氮化碳,然后通过钴盐溶液浸渍,使Co2+在泡沫状氮化碳结构中限域吸附,最后通过NaBH4将其原位还原为金属钴,进而制得泡沫状磷掺杂类石墨相氮化碳限域钴光热催化剂。泡沫状结构有利于反应物分子的传输,限域钴为表面反应提供了更多的活性位点,磷掺杂后使氮化碳的禁带宽度降低,可增强可见光激发电子跃迁能力。
Resumen de: AU2024222987A1
A system, comprising: an electrolyzer having a plurality of electrolysis cells arranged in a cell stack, wherein the electrolysis cells are electrically connected in series and grouped into two or more cell groups, each cell group having an electrical contact at either end; an electrical circuit having one or more switches, each switch coupled between the electrical contacts of a respective one of the cell groups and configured to selectively disconnect the cell group from the cell stack by electrically bypassing the cell group via a lower resistance path, to thereby vary the number of active electrolysis cells in the cell stack; and a controller configured to determine the number of active electrolysis cells based on a variable amount of direct current (DC) electrical energy supplied to the cell stack by an electrical energy source, and to control the one or more switches based on the determination.
Resumen de: CN121513907A
本申请属于催化剂制备技术领域,具体涉及一种ZnIn2S4/CoAl2O4复合催化剂及其制备方法和应用。该方法先将Co(NO3)3·6H2O、Al(NO3)2·9H2O、尿素和NH4F分散于水中,搅拌,转移至反应釜中,然后置于恒温烘箱中进行反应,离心,洗涤,干燥,煅烧,最后分散于甘油和水的混合溶液中,加入ZnCl2、In(NO3)·4H2O和TAA,搅拌直至形成均匀溶液后,置于油浴中加热,洗涤,干燥,即得。本发明成功制备了一种II型异质结光催化剂,并实现了高效的光催化析氢性能。其中,CAO与ZIS的结合不仅有效抑制了ZIS的团聚现象,还显著增加了材料的比表面积,提供了更多的活性位点。
Resumen de: US20260008042A1
The present disclosure is directed to a processing solution composition comprising a metal salt, an acid, a solvent, and a non-metal reductant. The present disclosure is also directed to a method of impregnating a porous material by covering or coating the porous material with a processing solution comprising a metal salt, an acid, a solvent, and a non-metal reductant.
Resumen de: WO2024252801A1
Provided is a hydrogen gas production system capable of producing, with a high recovery rate, a hydrogen gas having a deuterium D content ratio equal to or higher than that in raw material water. A hydrogen gas production system 100 according to the present invention comprises: a first tank 10 that accommodates raw material water including heavy water; an electrolysis device 30 that electrolyzes the raw material water to generate a hydrogen gas; a reservoir 50 that stores the hydrogen gas; a liquid feed device 20 that feeds the raw material water from the first tank 10 to the electrolysis device 30; and a gas feed device 40 that feeds the hydrogen gas generated in the electrolysis device 30 to the reservoir 50. In the system 100, the liquid feed device 20 is controlled so as to replenish the raw material water from the first tank 10 to the electrolysis device 30 as the raw material water remaining in the electrolysis device 30 decreases, the gas feed device 40 is controlled so as to continuously feed the hydrogen gas generated in the electrolysis device 30 to the reservoir 50 before, during, and after the replenishment, and the reservoir 50 stores the hydrogen gas generated in the electrolysis device 30 before, during, and after the replenishment.
Resumen de: AU2024304508A1
According to the invention, electrodes are arranged on two opposite surfaces of a separator. Each electrode consists of an open-pore metal structure, in particular a metal foam made of at least one of the chemical elements Ni, Al, Mo, Fe, Mn, Co, Zn, La, Ce, or an alloy of at least two of said chemical elements or an intermetallic compound of at least two of said chemical elements. A continuously decreasing catalytic activity is provided from the surface facing a separator or the respective other electrode of each electrochemical cell to the opposite surface of the respective electrode, and/or a continuously increasing porosity and/or pore size and/or a continuously decreasing specific surface area is provided from the surface facing a separator or the respective other electrode of each electrochemical cell to the opposite surface of the respective electrode.
Resumen de: CN121519089A
本发明涉及光电催化材料领域,提供了一种铁电型异质结电极及其制备方法和在光电催化领域的应用,旨在双S型异质结中引入额外的内置电场,提高光生电荷的分离和利用效率。所述制备方法包括:制备TiO2纳米管阵列,在TiO2表面生成铁电体SrTiO3,形成SrTiO3/TiO2异质结,进一步在异质结表面生成g‑C3N4,形成g‑C3N4/SrTiO3/TiO2双S型异质结。所述电极将铁电体SrTiO3分布到TiO2和g‑C3N4之间,形成双S型三元异质结电极,铁电体的内置极化电场与异质结界面电场之间形成“多场耦合”效应,提高了光生电荷的分离和转移效率,同时保持了较强的氧化还原能力,有效提高光电催化性能。
Resumen de: DE102024122674A1
Es wird ein Verfahren zur Herstellung von Kohlenstoffmonoxid beschrieben. Das Verfahren umfasst die elektrochemische Desorption von Kohlenstoffdioxid und Sauerstoff aus einer ein Metallhydrogencarbonat enthaltenden Lösung und das Bilden von Kohlenstoffmonoxid aus dem Kohlenstoffdioxid. Das erzeugte Kohlenstoffmonoxid kann in einem Verfahren zur Bildung von Syngas verwendet werden.
Resumen de: WO2025051333A1
The invention relates to a plate-like element (10) of a cell stack (2) of an electrochemical system (1), having a first plate side (26), a second plate side (27), a plurality of openings (13, 21, 22, 23, 23') and a first structure (14) for forming a flow field for coolant and several further structures (14') for forming distributors for operating media on the first plate side (26). The structure (14) comprises a coolant conducting structure (15, 16) through which a first coolant path (15) and a second coolant path (16) arranged mirror-symmetrically thereto are formed, each of which have, starting from one of the openings (21), an elongate inflow portion (17), a centre portion (18) which starts from the inflow portion (17), fans out and describes at least one meandering bend (19), and an elongate outflow portion (20) which adjoins the centre potion (18) and is narrower than the centre portion (18). A longitudinal axis (30) of the inflow portion (17) of the first coolant path (15) matches a longitudinal axis (30) of the outflow portion (20) of the second coolant path (16), and a longitudinal axis (30') of the inflow portion (17) of the second coolant path (16) matches a longitudinal axis (30') of the outflow portion (20) of the first coolant path (15). The invention also relates to a cell stack (2) comprising a plurality of such plate-like elements (10) which are parallel to one another.
Resumen de: US20260043153A1
Systems and methods are provided for water electrolysis. The system includes an electrolyte material configured for the exchange of anions, a first electrode including a nickel-cobalt-phosphorus-based compound, and a second electrode, wherein the first electrode and the second electrode are configured to exchange the anions through the electrolyte material.
Resumen de: WO2026033097A1
The invention relates to the use of 3C-SiC microparticles having a carbon surface, for the solar-driven splitting of molecules.
Resumen de: WO2026033095A1
The invention relates to the use of doped 3C-SiC microparticles for the solar-driven splitting of molecules.
Resumen de: WO2026032903A1
The present invention relates to an electrode for the electrolysis of, in particular, alkaline water solutions. The electrode has a 3D-knitted metal structure in the form of a net. The metal is predominantly made of nickel. The invention also relates to a corresponding electrolysis cell and its use for the electrolysis of alkaline aqueous solutions.
Resumen de: WO2026033405A1
A process and a related plant for decomposing ammonia and synthesizing a hydrogen-rich process stream by a direct cooling performed downstream of the decomposition reactor with a stream consists of, or essentially consists of, nitrogen and/or ammonia, where the decomposition of ammonia takes place in a thermal or autothermal chemical reactor.
Resumen de: WO2026032632A1
The invention relates to a fluid transport component (1) for an electrolyser, having a gas diffusion layer (2) which comprises a metal and is porous, and having a porous transport layer (3) which comprises a carbon paper and/or a carbon nonwoven, characterised in that the gas diffusion layer (2) is integrally bonded and electrically conductively connected to the porous transport layer (3). The invention additionally relates to a method for producing a fluid transport component (1) for an electrolyser, having the following steps: a) providing a gas diffusion layer (2) which comprises a metal and is porous; b) providing a porous transport layer (3) which comprises a carbon paper and/or a carbon nonwoven; and c) integrally bonding and electrically conductively connecting the gas diffusion layer (2) to the porous transport layer (3).
Resumen de: WO2026032578A1
A method for producing carbon monoxide is specified. The method comprises electrochemical desorption of carbon dioxide and oxygen from a solution containing a metal hydrogen carbonate and forming carbon monoxide from the carbon dioxide. The carbon monoxide produced can be used in a method for forming syngas.
Resumen de: WO2026032563A1
A process (100) for producing a hydrogen product (20) from a feedstock stream (10), the process (100) comprising the following steps: - performing a combustion of a fuel gas (S11) to bring a heat input to the process (100) thereby generating a flue gas (52), - pre-heating the ammonia stream (S3), said preheating being realized in a first heat exchanger (4) arranged to heat the ammonia stream by heat exchange with the flue gas, - sending the pre-heated ammonia stream (12) to a vaporizer (5) and vaporizing (S4) said pre-heated ammonia stream, - sending the vaporized ammonia (14) from said vaporizer (5) as said feedstock stream (S6) and/or sending the vaporized ammonia from said vaporizer as said fuel to said combustion (S11).
Resumen de: WO2026032554A1
The invention relates to a catalyst system for cracking ammonia into hydrogen and nitrogen, comprising at least one tube having an axis extending centrally through the interior of the tube, wherein at least two coaxially arranged regions are formed in the tube in the form of a first region along the central axis and at least one further region surrounding the first region, and wherein the first region contains a first catalyst material and the at least one further region contains at least one further catalyst material, characterised in that a) the first catalyst material has at least one metal selected from the group consisting of noble metals and non-noble metals and b) the at least one further catalyst material has at least one non-noble metal. The first and the at least one further catalyst material are different.
Resumen de: WO2026032565A1
The invention relates to a process for producing a hydrogen product (3) from a feedstock stream (4), said process comprising the following steps: - providing an ammonia stream (8); - sending the ammonia stream (8) to a vaporizer (6) configured to receive said ammonia stream (8) and to vaporize said ammonia stream (8) so as to obtain a vaporized ammonia stream (10); and - controlling the temperature of the vaporized ammonia stream (10) by injecting a cooling medium (16) into the vaporized ammonia stream (10) thereby obtaining a temperature-controlled ammonia stream (18).
Resumen de: WO2026035873A1
Techniques for water electrolysis employing: a glass substrate layer; a transparent conductive oxide (TCO) layer including TCO electrical disconnects formed in the TCO; a photovoltaic (PV) layer including PV electrical disconnects formed in the PV layer, portions of the PV layer extending into the TCO electrical disconnects; a metal back contact (MBC) layer including MBC electrical disconnects formed in the MBC layer, portions of the MBC layer extending into the PV electrical disconnects; an insulating layer including insulating voids formed in the insulating layer to expose anode and cathode portions of the MBC layer, portions of the insulating layer extending into the MBC electrical disconnects; a metal conductor layer adjacent the insulating layer and including a metal conductor extending into insulating voids to form metal conductors electrically coupled to the exposed anode and cathode portions; catalyst coatings on the metal conductors electrically coupled to the anode and cathode portions.
Resumen de: US20260043149A1
The following disclosure relates to an electrochemical cell or system that is configured to operate with forced water flow on the cathode side of the cell and forced water flow on the anode side of the cell. The system may include at least one electrochemical cell having a cathode, an anode, and a membrane separating the cathode and the anode. The system has the forced water flow on the cathode side of the cell to be principally in opposite direction of the forced water flow on the anode side of the cell.
Resumen de: US20260043151A1
A method of operating an electrolyzer system includes providing steam to a stack of electrolyzer cells through a steam filter, electrolyzing the steam into a hydrogen product in the stack of electrolyzer cells, receiving data from one or more sensors indicating that the filter requires cleaning or replacement, and cleaning or replacing the steam filter in response to the receiving the data from the one or more sensors indicating that the steam filter requires cleaning or replacement.
Resumen de: US20260043160A1
This control device is for a hydrogen production facility and comprises: a plurality of electrolysis cells for electrolyzing water or steam; and a plurality of rectifiers for supplying DC power to each of the plurality of electrolysis cells. The control device is provided with: a degradation coefficient acquisition unit configured to acquire a plurality of degradation coefficients indicating the degrees of deterioration of the respective electrolysis cells, an individual necessary current calculation unit configured to calculate, on the basis of a total necessary current corresponding to a hydrogen generation volume required for the hydrogen production facility and the plurality of degradation coefficients, a plurality of individual necessary currents indicating necessary currents required for the electrolysis cells; and a control unit configured to control the respective rectifiers on the basis of the plurality of individual necessary currents.
Resumen de: US20260043159A1
A solid oxide electrolyzer cell (SOEC) includes a solid oxide electrolyte, a fuel-side electrode disposed on a fuel side of the electrolyte, and an air-side electrode disposed on an air side of the electrolyte. The air-side electrode includes a barrier layer disposed on the air side of the electrolyte and including a first doped ceria material, and a functional layer disposed on the barrier layer and including an electrically conductive material and a second doped ceria material.
Resumen de: JP2026022181A
【課題】本開示は、新たな直接空気電解法を提供することを目的とし、好ましくは、強塩基性や強酸性の溶液、及び、貴金属電極触媒を用いる必要がない、直接空気電解法を提供することを目的とする。【解決手段】アノードと、前記アノードに対向するカソードと、細孔を有する基材と、吸水性化合物と、を備え、前記基材は、前記アノードと前記カソードとの間に配置され、前記吸水性化合物は、前記基材の細孔中に存在する、電解セル。【選択図】なし
Resumen de: US20260043158A1
An electrolytic cell and an anion-exchange conductive hollow fiber tube matrix thereof are disclosed. The anion-exchange conductive hollow fiber tube matrix includes a plurality of conductive hollow fiber tubes arranged adjacent to each other in a matrix. The conductive hollow fiber tubes each have a diffusion surface and two opposite ends defined as an inlet and an outlet. An anode and a cathode of the electrolytic cell are disposed adjacent to the diffusion surface. Water in an electrolysis tank flows into the conductive hollow fiber tubes from the inlet, water molecules enter the cathode from the diffusion surface and decompose to produce hydrogen and hydroxide ions, the hydrogen is discharged from the cathode, the hydroxide ions return to the conductive hollow fiber tubes from the diffusion surface and then enter the anode from the diffusion surface to produce oxygen, the oxygen is discharged from a surface of the anode.
Resumen de: US20260043154A1
An alkaline water electrolysis apparatus includes: a separation membrane including a first main surface and a second main surface opposite to the first main surface; a first electrode including a third main surface and a fourth main surface opposite to the third main surface, the third main surface being provided to face the first main surface of the separation membrane; and a first bipolar plate including a fifth main surface, the fifth main surface being provided in contact with the fourth main surface of the first electrode, wherein the first electrode consists of a first metal porous body having a three-dimensional mesh structure.
Resumen de: US20260043150A1
A photocatalytic cell of the disclosure is installed in an inclined manner at an angle of 5° or more and 45° or less with respect to a horizontal plane. The photocatalytic cell includes: a translucent member; an electrolytic solution; a photocatalytic sheet including photocatalytic particles; an injection port through which the electrolytic solution is injected into an inside of the photocatalytic cell; a discharge port through which the electrolytic solution is discharged to an outside of the photocatalytic cell; and an exhaust port through which gas inside the photocatalytic cell is discharged, at least a part of the photocatalytic sheet is immersed in the electrolytic solution, a position of the exhaust port is higher than a position of the injection port, a gap between a surface of the translucent member and a surface of the photocatalytic sheet is 5 mm or more and 50 mm or less in width, and the injection port and the discharge port allow the electrolytic solution to flow from an upper part toward a lower part in the gap between the translucent member and the photocatalytic sheet.
Resumen de: US20260047229A1
Techniques for water electrolysis employing: a glass substrate layer; a transparent conductive oxide (TCO) layer including TCO electrical disconnects formed in the TCO; a photovoltaic (PV) layer including PV electrical disconnects formed in the PV layer, portions of the PV layer extending into the TCO electrical disconnects; a metal back contact (MBC) layer including MBC electrical disconnects formed in the MBC layer, portions of the MBC layer extending into the PV electrical disconnects; an insulating layer including insulating voids formed in the insulating layer to expose anode and cathode portions of the MBC layer, portions of the insulating layer extending into the MBC electrical disconnects; a metal conductor layer adjacent the insulating layer and including a metal conductor extending into insulating voids to form metal conductors electrically coupled to the exposed anode and cathode portions; catalyst coatings on the metal conductors electrically coupled to the anode and cathode portions.
Resumen de: AU2026200498A1
A power generator is described that provides at least one of electrical and thermal power comprising (i) at least one reaction cell for reactions involving atomic hydrogen hydrogen products identifiable by unique analytical and spectroscopic signatures, (ii) a molten metal injection system comprising at least one pump such as an electromagnetic pump 5 that provides a molten metal stream to the reaction cell and at least one reservoir that receives the molten metal stream, and (iii) an ignition system comprising an electrical power source that provides low-voltage, high-current electrical energy to the at least one steam of molten metal to ignite a plasma to initiate rapid kinetics of the reaction and an energy gain. In some embodiments, the power generator may comprise: (v) a source of H2 and O2 supplied to the 10 plasma, (vi) a molten metal recovery system, and (vii) a power converter capable of (a) converting the high-power light output from a blackbody radiator of the cell into electricity using concentrator thermophotovoltaic cells or (b) converting the energetic plasma into electricity using a magnetohydrodynamic converter. an a n
Resumen de: AU2024357053A1
Provided is a control device including: a step in which a current command value regarding current to be applied to an electrolytic stack is determined; and a step in which pure-water adjustment amount command values for adjusting the pressure or/and flow rate of water to be supplied to the electrolytic stack are determined on the basis of the current command value. The control device further includes a step A in which, when the current command value is changed from a first current command value (current command value c1) to a second current command value (current command value c2), which is a different value, and the pure-water adjustment amount command value is changed from a first pure-water adjustment amount command value (pure-water adjustment amount command value w1) to a second pure-water adjustment amount command value (pure-water adjustment amount command value w2), which is a different value, measured values of the pressure or/and flow rate are caused to reach the second pure-water adjustment amount command value from the first pure-water adjustment amount command value before a measured value of current applied from a power converter to the electrolytic stack reaches the second current command value from the first current command value.
Resumen de: AU2024396946A1
According to exemplary embodiments of the present invention, a hydrogen production system is provided. The present invention comprises: a hydrogen generation unit configured to receive reduced iron from a reduced iron generation unit configured to generate reduced iron by reducing powdered iron ore in a reducing gas atmosphere, and to generate hydrogen from ammonia by bringing the reduced iron into contact with the ammonia; and a regeneration unit configured to receive the reduced iron from the hydrogen generation unit and to regenerate the reduced iron by reducing the reduced iron in a hydrogen gas atmosphere. According to other exemplary embodiments of the present invention, a method for producing hydrogen is provided.
Resumen de: AU2024398260A1
Provided according to exemplary embodiments of the present invention is an ammonia decomposition system capable of minimizing the generation of iron nitride, which is a by-product.
Resumen de: AU2024300028A1
The compression arrangement comprises a hydrogen compressor and a return circuit having an inlet, which is fluidly coupled with the discharge side of the centrifugal compressor, and an outlet, which is fluidly coupled with the suction side of the centrifugal compressor. A head-loss control valve is positioned in the return circuit. The head-loss control valve is adapted to generate a controlled head loss in the return circuit when the compressor operates at a flowrate below the surge control line.
Resumen de: WO2026033985A1
Provided is a hydrogen production system (40) which comprises: an exhaust heat reception unit (41) that receives exhaust heat generated by an external exhaust heat source (11); a water vapor generation unit (42) that generates water vapor by heating water by means of the exhaust heat received by the exhaust heat reception unit (41); a cell stack (43) that electrolyzes the water vapor generated by the water vapor generation unit (42) so as to generate hydrogen; and a replenishment unit (44) that, when the amount of exhaust heat is insufficient with respect to the amount necessary for generating the required amount of water vapor, replenishes water, water vapor, or the water vapor generation unit (42) with heat, or replenishes the cell stack (43) with water vapor from an external water vapor supply source (95).
Resumen de: WO2026035442A1
A system includes at least one electrochemical device including a proton exchange membrane situated between an anode and a cathode. An oxygen separator is fluidly connected to an inlet to the anode and a hydrogen separator is fluidly connected to an outlet from the cathode. A separator tank fluidly interconnects an outlet from the hydrogen separator to an inlet to the oxygen separator.
Resumen de: WO2026034682A1
Disclosed are an ammonia dehydrogenation catalyst with which hydrogen can be produced from ammonia in a high yield, and a method for producing hydrogen. The disclosed ammonia dehydrogenation catalyst includes nickel (Ni), lanthanide elements (M), and aluminum (Al).
Resumen de: WO2026034402A1
This electrolytic cell comprises an element provided with: an anode chamber provided with an anode; a cathode chamber provided with a cathode; a conductive partition wall provided between the anode chamber and the cathode chamber; and an outer frame that borders the conductive partition wall. The electrolytic cell is stacked with a gasket and a diaphragm interposed between cells. Sealing of an electrolytic solution is achieved by applying surface pressure between the gasket and the diaphragm and between the gasket and the outer frame. The contact ratio between the diaphragm and a first electrode, which is at least one of the anode and the cathode, is 15%-60%, and a region in which the local stress between the diaphragm and the first electrode is 0.1 MPa or more is 5% or less.
Resumen de: WO2025012271A1
The invention relates to a plant for preparing H2 by catalytically decomposing NH3. The plant according to the invention can be operated in a start-up mode in order to heat apparatuses of the plant to an increased operating temperature using a heat-transfer medium, e.g. following interruption of a continuous operation of the plant due to maintenance work. After heating to the operating temperature, the plant according to the invention can be operated in a production mode for continuous production of H2. The invention also relates to a method for starting up a plant for preparing H2 by catalytically decomposing NH3.
Resumen de: DE102024207534A1
Die Erfindung betrifft ein Fluidtransportbauteil (1) für einen Elektrolyseur, mit einer Gasdiffusionslage (2), die ein Metall aufweist und porös ist, und einer porösen Transportschicht (3), die ein Kohlenstoffpapier und/oder einen Kohlenstoffvlies aufweist, dadurch gekennzeichnet, dass die Gasdiffusionslage (2) stoffschlüssig und elektrisch leitfähig mit der porösen Transportschicht (3) verbunden ist. Zudem betrifft die Erfindung ein Verfahren zum Herstellen eines Fluidtransportbauteils (1) für einen Elektrolyseur, mit den Schritten: a) Bereitstellen einer Gasdiffusionslage (2), die ein Metall aufweist und porös ist; b) Bereitstellen einer porösen Transportschicht (3), die ein Kohlenstoffpapier und/oder einen Kohlenstoffvlies aufweist; und c) stoffschlüssiges und elektrisch leitfähiges Verbinden der Gasdiffusionslage (2) mit der porösen Transportschicht (3).
Resumen de: EP4691968A1
A process (100) for producing a hydrogen product (20) from a feedstock stream (10), the process (100) comprising the following steps:- performing a combustion of a fuel gas (S11) to bring a heat input to the process (100) thereby generating a flue gas (52),- pre-heating the ammonia stream (S3), said preheating being realized in a first heat exchanger (4) arranged to heat the ammonia stream by heat exchange with the flue gas,- sending the pre-heated ammonia stream (12) to a vaporizer (5) and vaporizing (S4) said pre-heated ammonia stream,- sending the vaporized ammonia (14) from said vaporizer (5) as said feedstock stream (S6) and/or sending the vaporized ammonia from said vaporizer as said fuel to said combustion (S11).
Resumen de: CN121359262A
The invention relates to a method for producing an assembly for an electrochemical cell, wherein the assembly comprises at least the following structural components: a first plate (10; 10 '), a proton exchange membrane (42), a first electrode (31) arranged between the first plate and the proton exchange membrane, and a first gas diffusion layer (21) arranged between the first plate and the first electrode, having the following steps: A) providing a substrate having only a part of the structural component, in particular the first plate and/or the first gas diffusion layer; b) assembling the components, wherein the assembling comprises the step of adding residual structural components; or the following steps: a) providing a substrate distinct from the structural component; b) assembling the components, wherein the assembling comprises adding structural components; wherein the bezel is formed by applying one or more layers of a molding material (70-72) to the provided substrate, the strength of the molding material being increased after said application, at least one layer of the molding material forming the bezel or at least one surrounding section of the bezel being applied prior to step B) or b). The invention also relates to an electrochemical cell, in particular a fuel cell or an electrolytic cell, to a cell stack having a cell of this type, and to a method and a facility for producing an assembly for a cell or a cell stack of this type.
Resumen de: EP4692422A1
The present invention relates to an electrode for the electrolysis of, in particular, alkaline water solutions. The electrode has a 3D-knitted metal structure in the form of a net. The metal is predominantly made of nickel. The invention also relates to a corresponding electrolysis cell and its use for the electrolysis of alkaline aqueous solutions.
Resumen de: EP4691967A1
Die Erfindung betrifft ein Katalysatorsystem zur Spaltung von Ammoniak in Wasserstoff und Stickstoff, umfassend mindestens Rohr mit einer zentral durch das innere des Rohrs verlaufenden Achse, wobei in dem Rohr mindestens zwei koaxial angeordnete Bereiche, in Form von einem ersten Bereich entlang der zentralen Achse und mindestens einem den ersten Bereich umgebenden weiteren Bereich, ausgebildet sind, und wobei der erste Bereich ein erstes Katalysatormaterial und der mindestens eine weitere Bereich mindestens ein weiteres Katalysatormaterial enthält, dadurch gekennzeichnet, dass a) das erste Katalysatormaterial mindestens ein Metall aufweist, das ausgewählt ist aus der Gruppe bestehend aus Edelmetallen und Nicht-Edelmetalle, und b) das mindestens eine weitere Katalysatormaterial mindestens ein Nicht-Edelmetall aufweist. Das erste und das mindestens eine weitere Katalysatormaterial sind verschieden.
Resumen de: CN120981421A
A hydrogen production system comprising: a first electrode having an electrocatalyst, a second electrode having an electron donor material comprising a plurality of active sites, the second electrode configured to release electrons from the active sites within a predetermined working potential range below a working potential triggering an oxygen evolution reaction; a first electrolyte in contact with the first and second electrodes, the electrolyte being a source of hydrogen protons; and a power source configured to provide the system with the predetermined operating potential range to release electrons from the second electrode and transfer electrons to the first electrode such that hydrogen protons combine with the electrons to produce hydrogen gas.
Resumen de: EP4692424A1
It is an object of the present invention to provide a steam electrolysis device and a steam electrolysis method, which have high energy efficiency. The present invention relates to: a steam electrolysis device, comprising an anode electrode chamber, a cathode electrode chamber, and an ion conductor disposed between these electrode chambers, wherein steam in an amount more than twice the amount of hydrogen generated is supplied to at least one selected from the anode electrode chamber and the cathode electrode chamber, and 50% or less of the supplied steam is electrolyzed; and a steam electrolysis method using the steam electrolysis device.
Resumen de: EP4691992A1
Provided is a method for producing a highly active oxygen carrier at low cost, and a method for producing hydrogen and an apparatus for producing hydrogen using the highly active oxygen carrier.SolutionA method for producing an oxygen carrier of the present invention is a method for producing an oxygen carrier formed of an activated iron titanate containing an alkali titanate and an iron oxide by calcining a mixture of iron titanate particles and an alkali component. The mixture of the iron titanate particles and the alkali component is prepared by any of: physically mixing the iron titanate particles and an alkaline compound; and spraying an aqueous solution of the alkaline compound to the iron titanate particles or impregnating the iron titanate particles with the aqueous solution of the alkaline compound and then drying the sprayed or impregnated iron titanate particles.
Resumen de: EP4693486A1
The invention relates to an electrocatalytic electrode comprising a coating film on an electrically conductive base substrate that includes a non-stoichiometric mixed oxide dispersed in the film, including a mixture of iron and vanadium, in a metal-organic matrix, the organic part of which includes the mixed oxide dispersed therein. The electrocatalytic electrode can be used for the production of molecular hydrogen.The invention also relates to a method for producing the electrocatalytic electrode and the use of the electrocatalytic electrode for the improved production of molecular hydrogen by means of at least water hydrolysis, alkaline water electrolysis, alkaline electrolysis via ion exchange, as a selective electrode and as an electrode for the oxidation of organic compounds in an aqueous solution.
Resumen de: CN120898031A
The present invention relates to a composition comprising from about 90% to about 99.99% by weight of one or more non-crosslinked fluorinated sulfonyl fluoride polymers and from about 0.01% to about 10% by weight of one or more noble metal catalysts, based on the total weight of the composition, wherein the one or more noble metal catalysts are uniformly distributed throughout the one or more non-crosslinked fluorinated sulfonyl fluoride polymers. Such compositions may be formed as cation exchange precursors, for example by extrusion, and, after treatment, form cation exchange membranes. The resulting films and membranes have a noble metal catalyst uniformly distributed throughout the layer of the catalyst-containing polymer.
Resumen de: CN120936755A
The present application relates to an electrolytic cell battery cell having a battery layer (1314) comprising an electrochemically active battery region (1350), the battery layer (1314) having a first side (1315a) and a second side (1315b). The cell defines a first fluid flow region (1360) for delivering fuel to the first side (1315a) of the cell layer (1314) and a second fluid flow region (1365) for discharging fluid from the second side (1315b) of the cell layer (1314). A cross-sectional area of the second fluid flow region (1365) is less than a cross-sectional area of the first fluid flow region (1360).
Resumen de: CN120752767A
A method of making a catalyst coated ion conducting membrane for use in an electrochemical device, such as a fuel cell or an electrolytic cell, is provided. The method includes providing an electrolyte membrane having a first face and a second face, the first face disposed opposite the second face. A first catalyst ink is deposited onto the first side of the electrolyte membrane to form a first wet catalyst layer, and then dried to form a first catalyst layer on the first surface of the electrolyte membrane. The first catalyst ink comprises a first ionically conductive polymer; a first electrocatalyst; and a first dispersant. Subsequently, a second catalyst ink is deposited onto a second face of the electrolyte membrane to form a second wet catalyst layer and dried to form a second catalyst layer. The second catalyst ink comprises a second ionically conductive polymer; a second electrocatalyst; and a second dispersant. Before depositing the second catalyst ink onto the second side of the electrolyte membrane, the first catalyst layer is subjected to a temperature A of 130 DEG C or more, and the second catalyst layer is subjected to a temperature B lower than the temperature A.
Resumen de: CN120882906A
A porous transport layer for an electrolytic cell or for a fuel cell, the porous transport layer comprising: a first non-woven layer having metal fibers, the first non-woven layer having metal fibers being arranged for contacting a proton exchange membrane, where the first non-woven layer having metal fibers comprises metal fibers having a first equivalent diameter, and the second non-woven layer having metal fibers having a second equivalent diameter; wherein the first non-woven layer having metal fibers has a first surface roughness and a first porosity,-a second non-woven layer having metal fibers wherein the second non-woven layer having metal fibers comprises metal fibers having a second equivalent diameter, wherein the second nonwoven layer having metal fibers has a second surface roughness and a second porosity wherein the first surface has a material ratio of less than 5% material at a height of 5 mu m and greater than 70% material at a depth of-5 mu m, the first equivalent diameter is less than the second equivalent diameter, the first surface roughness is at least 20% less than the second surface roughness, and the second surface roughness is at least 20% less than the second surface roughness. The first porosity is at least 10% less than the second porosity, such as in the range of 20% to 120%, for example, the first porosity is at least 10% less than the second porosity, such as in the range of 10% to 50%, and wherein the first nonwoven layer is metallurgically bo
Resumen de: CN121039917A
Systems and methods are provided for an electrolysis plant interconnecting a renewable energy source (22) and a power grid (20). The system includes a power source (22) and an electrolysis plant (30) including electrolysis equipment (32) connected to the power source (22) to energize the electrolysis equipment to respective operating conditions. The control system (40) is connected to the power source (22) and the power grid (20). Upon detection of a power failure or otherwise insufficient power supply of the renewable power source, the control system is configured to bring the electrolysis device to a corresponding standby condition. The electrolysis device is connected to an electrical grid to energize the electrolysis device to a standby condition. Optionally, a backup power supply (26) is connected to the control system such that the backup power supply is configured to energize the control system upon detecting that the renewable power source and the grid are simultaneously powered off or are simultaneously otherwise insufficient in power supply.
Resumen de: CN121013925A
The invention relates to a membrane electrode assembly (1) for a water electrolyser, comprising an anode (2), a cathode (3) and a hydrocarbon membrane (4) located between the anode (2) and the cathode (3), further comprising a first gas recombination layer (5) arranged between the anode (2) and the hydrocarbon membrane (4) wherein the first gas recombination layer (5) comprises a noble metal (6), a ceramic material (7) and a proton conducting polymer (8), and wherein the volume fraction of the proton-conducting polymer (8) is 24 to 84 vol%, in particular 35 to 75 vol%, and in particular 46 to 65 vol%, based on the total volume of the gas recombination layer (5).
Resumen de: CN120981610A
The invention relates to a membrane electrode assembly (1) for a water electrolyser, comprising an anode (2), a cathode (3) and a hydrocarbon membrane (4) located between the anode (2) and the cathode (3), further comprising a first gas recombination layer (5) arranged between the anode (2) and the hydrocarbon membrane (4), in which at least one adhesion layer (6) is arranged between the gas recombination layer (5) and the hydrocarbon membrane (4), wherein the adhesive layer (6) comprises at least one ceramic material (7) and a proton-conducting polymer (8).
Resumen de: CN120958177A
The invention relates to a membrane electrode assembly (1) having an anode (2), a cathode (3) and a hydrocarbon membrane (4) between the anode (2) and the cathode (3). The membrane electrode assembly (1) further comprises a protective layer (5) arranged between the anode (2) and the hydrocarbon membrane (4) and-or between the cathode (3) and the hydrocarbon membrane (4), where the protective layer (5) comprises at least one ceramic material (6) and a fluorine-containing ionomer (7), where the ceramic material (6) is dispersed in the fluorine-containing ionomer (7).
Resumen de: CN121013921A
The invention provides a porous transport layer for an electrolytic cell or for a fuel cell, the porous transport layer comprising:-a first non-woven layer having metal fibres, the first non-woven layer having metal fibres being arranged for contacting a proton exchange membrane, wherein the first non-woven layer having metal fibers comprises metal fibers having a first equivalent diameter, and wherein the first non-woven layer having metal fibers has a first surface roughness and a first porosity; -a second non-woven layer having metal fibers, where the second non-woven layer having metal fibers comprises metal fibers having a second equivalent diameter, where the second non-woven layer having metal fibers has a second surface roughness and a second porosity, where the first surface roughness is less than 10 mu m, and the second surface roughness is less than 10 mu m. The first equivalent diameter is less than the second equivalent diameter, the first surface roughness is at least 20% less than the second surface roughness, e.g. In the range of 20% to 120%, where the first porosity is at least 10% less than the second porosity, e.g. In the range of 10% to 50%, and where the first nonwoven layer is metallurgically bonded to the second nonwoven layer.
Resumen de: WO2024208792A1
A methanol plant and a process for the production of methanol is provided. A hydrogen recovery section receives off-gas stream from the methanol synthesis section and outputs a hydrogen-rich stream, which is recycled upstream the methanol synthesis section.
Resumen de: EP4691970A1
The invention relates to a process for producing a hydrogen product (3) from a feedstock stream (4), said process comprising the following steps:- providing an ammonia stream (8);- sending the ammonia stream (8) to a vaporizer (6) configured to receive said ammonia stream (8) and to vaporize said ammonia stream (8) so as to obtain a vaporized ammonia stream (10); and- controlling the temperature of the vaporized ammonia stream (10) by injecting a cooling medium (16) into the vaporized ammonia stream (10) thereby obtaining a temperature-controlled ammonia stream (18).
Resumen de: CN121285539A
The invention relates to a method for preparing methanol. The method comprises the following steps: (a) preparing a hydrogen raw material through electrolysis; (b) providing a carbon oxide feedstock during the electrolysis operation in step (a); (c) mixing at least part of the hydrogen feed and a carbon oxide source consisting of a carbon monoxide and/or carbon dioxide feed to obtain methanol syngas; (d) adjusting the molar content of hydrogen, carbon monoxide and/or carbon dioxide in step (c) to a modulus M of 1.9 to 2.2, said modulus M being (H2-CO2)/(CO2 + CO); (e) converting the methanol syngas to methanol in one or more boiling water reactors; during the electrolysis inoperation in step (a): (f) interrupting the conversion of methanol syngas by heat exchange with boiling water in one or more boiling water reactors, in which step (f) the one or more boiling water reactors are heated by one or more auxiliary heaters to maintain boiling of water in the one or more boiling water reactors.
Resumen de: WO2025002798A1
The invention relates to a reactor (2) for generating hydrogen and at least one other product from at least one reactant, the reactor comprising a tubular reactor vessel (4) which contains a catalyst (6) in the form of a ceramic bed. Improved corrosion resistance against a variety of media and thus an increased service life of the reactor (2) is achieved by forming the reactor vessel (4) from silicon-infiltrated silicon carbide (SiSiC).
Resumen de: KR20260020050A
본 발명은 우수한 성능을 지닌 광활성 재료용 복합체, 이를 포함하는 산소 발생 반응용 광전극, 및 이의 제조방법 등에 관한 것으로, 본 발명의 여러 구현예를 통하여 궁극적으로 우수한 성능으로 광전기화학적 물 분해를 통한 녹색 수소 생산을 달성할 수 있다.
Resumen de: US20260035242A1
A hydrogen generation system with controlled water distribution is disclosed. The system comprises a reaction chamber containing a hydrogen-producing fuel, a liquid distribution mechanism, and a control system. The liquid distribution mechanism includes a rotating arm with liquid injection ports that move vertically through the fuel chamber. This allows for precise and efficient liquid delivery to unreacted fuel, optimizing hydrogen production. A proprietary fuel blend utilizes chemicals that store significant amounts of hydrogen in a solid-state form. A feature of the device is the arm's controlled vertical movement, achieved through a screw mechanism that adjusts the arm's height as it rotates, creating a spiral liquid distribution pattern. The control system regulates liquid injection rates, arm rotation speed, and vertical movement to optimize hydrogen production based on demand. The system can also operate at low pressures and be scaled to different sizes in a safer, more efficient, on-demand manner.
Resumen de: JP2026021217A
【課題】水素の製造効率が良く、水酸化マグネシウムの産業廃棄物を産出しない、水から水素を製造する方法を提供する。【解決手段】水素化マグネシウムとクエン酸やグルコン酸などのハイドロオキシカルボン酸を水酸化マグネシウムの1.2モル比倍以上加えた塩化マグネシウム水溶液から製造したクロロマグネシウムプラズマで水から水素を製造する方法である。【選択図】なし
Resumen de: JP2026020879A
【課題】電極性能に関連する状態のばらつきが少ない水電解用電極を製造する観点から有利な水電解用電極の製造方法を提供する。【解決手段】水電解用電極の製造方法は、下記(I)及び(II)を含んでいる。(I)少なくとも1つの導電性基材21上に水電解用電極を形成させるための原料溶液L1を少なくとも1つの導電性基材21が配設された容器11を経由して循環させる。(II)容器11の内部における原料溶液L1の流れの向きを反転させる。【選択図】図1
Resumen de: AU2024303309A1
The present invention provides a method of controlling an electrolyser cell stack within a system having a fluid temperature control system, a current control system, a voltage monitoring system, monitoring/control systems for the temperatures of the fluid inlet and outlet, by controlling the current to a fixed value, calculating a temperature delta between the fluid inlet and outlet, and adjusting the fluid input temperature if the delta is greater than a threshold value. The present invention also provides a method of determining a stack operating condition is the temperature delta as measured above is lower than a threshold value. The present invention also provides a control device and computer program capable of executing the method as outlined above.
Resumen de: AU2023449815A1
A system and method of making hydrogen from water. A cylindrical reaction vessel is provided with an outer shell, a central shaft, and one or more concentric inner tubes separated by annular spaces. Water is delivered to the annular spaces by a water pump through an inlet defined in the reaction vessel. The water courses along a tortuous flow path. That path begins at an inner annular space around a central shaft. It ends at an outer annular space. The water emerges from the reaction vessel through an outlet associated with a manifold. A high-frequency vibratory stimulus is applied to the reaction vessel and water. Water molecules are dissociated into hydrogen molecules and oxygen atoms. These reaction products are delivered through the manifold along an effluent flow path to a receiving pressure vessel before deployment to a sub-assembly for harnessing clean energy.
Resumen de: CN121497514A
本发明公开了一种基于发动机尾气余热的等离子体氨分解制氢装置,包括发动机、液氨瓶、等离子体氨分解反应器、温度传感器、氢气罐及等离子体电源。发动机运行时,液氨经汽化器汽化为气态氨,一部分进入发动机燃烧,另一部分与发动机尾气换热后进入反应器。同时,温度传感器实时监测尾气温度并反馈至ECU,ECU根据尾气温度输出控制信号到等离子体电源。尾气温度高于700 K时,关闭等离子体电源,依靠热催化实现氨气分解;当尾气温度低于700 K时,触发等离子体电源并进入动态调节模式,采用分阶段上电策略,先低功率预放电保证放电稳定性,再根据需求逐步提升功率。反应器内氨气分解生成氢气和氮气,产物混合气部分储存,部分作为发动机燃料使用。
Resumen de: CN121490749A
本发明涉及光催化技术领域,具体涉及一种锶铋钒氧化物光催化剂及其制备方法与应用,光催化剂的化学式为Sr3.59Bi19.41V4O42,其晶体结构属于正交晶系,空间群为Immm,是一种由阳离子三重板层构成的独特层状结构;光催化剂通过熔盐法合成,在可见光下表现出光催化分解水产氧活性。本发明通过将SrO、Bi2O3和V₂O₅前驱体与熔盐介质混合研磨后,经程序升温煅烧合成目标产物;该方法所制备的催化剂具有高结晶度、缺陷少、形貌规整的特点,其光催化产氧性能显著优于传统固相法合成的同组分样品,可在波长≥420 nm的可见光照射下,以硝酸银、硝酸铁、氯化铁或者铁氰化钾水溶液为牺牲剂体系实现光催化分解水产氧。
Resumen de: JP2026020880A
【課題】少なくとも特定の箇所において電極性能に関連する状態のばらつきが少ない水電解用電極を製造する観点から有利な水電解用電極の製造方法を提供する。【解決手段】水電解用電極の製造方法は、下記(I)、(II)、及び(III)を含んでいる。(I)少なくとも1つの導電性基材21上に水電解用電極を形成させるための原料溶液L1を少なくとも1つの導電性基材21が配設された容器11を経由して循環させる。(II)原料溶液L1が少なくとも1つの流路14を通過する。(III)原料溶液L1の流れの下流における流路14の流路断面積が原料溶液L1の流れの上流における流路14の流路断面積よりも小さい状態で原料溶液L1の流れを生じさせる。【選択図】図1
Resumen de: JP2026020857A
【課題】Irを含有しなくても、十分な触媒性能および十分な耐久性を有する新規な水電解陽極触媒を提供する。【解決手段】第四周期以上第六周期以下の第IV、V、VI族元素および第二周期以上第六周期以下のXIV族元素からなる群から選択される少なくとも一種の元素、を含む炭化物、窒化物、およびホウ化物からなる群から選択される少なくとも一種の化合物、を含む水電解陽極触媒。【選択図】なし
Resumen de: JP2026020881A
【課題】従来よりも電極性能に関連する状態のばらつきが少ない水電解用電極を製造する観点から有利な水電解用電極の製造方法を提供する。【解決手段】水電解用電極の製造方法は、第1の設置状態及び第2の設置状態において少なくとも1つの導電性基材21上に水電解用電極を形成させるための原料溶液L1を少なくとも1つの導電性基材21が配置された容器11を経由して循環させる。第2の設置状態における少なくとも1つの導電性基材21の向きは、第1の設置状態における少なくとも1つの導電性基材21を、所定の直線を回転軸として半回転させたときの少なくとも1つの導電性基材21の向きと一致する。所定の直線は、少なくとも1つの導電性基材21の主面上の直線又は少なくとも1つの導電性基材の主面と交差する直線である。【選択図】図5
Resumen de: CN121496430A
本发明公开了一种兆瓦级大幅面AEM电解槽流场板,包括基板,所述基板的中央位置设有阳极进口、阳极出口一、阳极出口二,所述阳极出口一、阳极进口和阳极出口二依次呈直线排列,所述阳极出口一、阳极进口和阳极出口二形成的直线阵列位于所述基板的中央位置,所述阳极出口一、阳极进口和阳极出口二所形成的直线阵列将基板分为左基板和右基板,左右基板共设有四分区。本发明一种兆瓦级大幅面AEM电解槽流场板四分区结构,将大幅面流场进行划分,能够有效提升反应物的分布均匀性,提升活性面积利用率,减少局部过热的情况,同时通过分割为四个分区,大大减小单个流场的面积,有效解决电解槽压降较大的问题,可适用功率相对较小的泵体,降低能耗。
Resumen de: CN121493905A
本发明公开了一种通过氧化镍晶面调控吸附磷化氢制备电催化剂的方法,属于电催化材料制备技术领域;其包括:以镍源为原料,通过溶剂热法或水热法合成具有特定晶面暴露的形貌可控氧化镍颗粒,对氧化镍颗粒进行热处理得到前驱体,再将前驱体置于磷化氢氛围中进行磷化处理,最终制备得到含NixPy的电催化材料;其中,特定晶面包括(111)晶面和(110)晶面。本发明探究了不同形貌氧化镍对磷化氢吸附性能的差异,在实现高效脱除尾气中磷化氢的同时合成了电催化剂所形成的电催化剂材料,实现了环保治理与资源利用的双重目标。
Resumen de: CN121496474A
本发明公开了一种高韧性碱性电解水制氢复合隔膜及其制备方法,属于电解水制氢复合隔膜的技术领域,所述复合隔膜包括聚砜、软链段单体、催化剂、1wt%~5wt%致孔剂和基于硅烷偶联剂改性的无机纳米氧化物颗粒,所述聚砜与硅烷偶联剂改性的无机纳米氧化物颗粒的质量比为1:3~8;所述无机纳米氧化物颗粒为二氧化硅、二氧化钛、二氧化锆中的任意一种或者多种,且颗粒中位粒径为D50=0.2μm~1μm。本发明通过体系内接枝柔软链段构建互穿网络结构,从而显著提升隔膜的韧性,使其在液氮极端低温环境下仍能保持抗脆断性能,为隔膜在寒冷地区的应用提供了潜在解决方案,具有较好的实用性。
Resumen de: CN121496460A
本发明公开了一种硒掺杂二氧化钌及其制备方法与应用,通过将三氯化钌和亚硒酸钠溶解在醇类溶剂后置于油浴锅中反应,再将反应后的样品洗涤、负载、烘干、煅烧,最终成功制得了硒掺杂的二氧化钌。制得的二氧化钌呈现多孔簇状形貌,能够暴漏更多活性位点,利用硒掺杂调控电子转移,诱导反应机制转变提升了二氧化钌的活性和稳定性,将其作为催化剂用于电解水制氢时表现出了优异的析氧性能,在电催化领域具有应用前景。
Resumen de: CN121496439A
本申请提出一种在水基乳液中进行电沉积过程,制备催化电极的技术方法,属于催化电极制备技术领域,公开了催化电极及其制备方法。所述催化电极的制备方法具体包括:将二硫化钼分散液与聚乳酸的三氯甲烷溶液进行混合处理,得到皮克林乳液;将多孔金属基体在含有所述皮克林乳液电沉积液中进行电化学沉积处理,经过清洗干燥后,得到所述催化电极。该催化电极的制备方法简单可靠,易于工业实施,所制备的催化电极具有较高的催化活性,适合于电解水制氢、制氧等电化学装置中应用。
Resumen de: CN121496481A
本申请提供一种电解槽的停机方法、装置、设备、存储介质及程序产品。涉及电解制氢技术领域。该方法包括:确定与多个电解槽连接的分离装置的目标压力和多个电解槽的氢气生成速率,分离装置包括氧气分离装置和氢气分离装置;根据氢气生成速率,确定惰性气体待注入的第一总量;根据目标压力和惰性气体对应的注入压力,控制氧气分离装置和氢气分离装置的气体释放;在分离装置的当前压力达到注入压力时,控制多个电解槽停机;根据第一总量,向氧气分离装置和氢气分离装置注入惰性气体,提高了电解槽的停机的安全性。
Resumen de: CN121496477A
本申请公开了一种制氢系统及其温度控制方法、装置、存储介质与程序产品。该制氢系统的温度控制方法包括:获取预设时域内的电解槽的功率指令及设备属性参数;其中,预设时域包括连续的多个预设时段,功率指令包括与各预设时段对应的子功率指令;将各子功率指令输入优化温度控制模型,以最小化预设时域内电解槽温度与目标温度之间的偏差为目标,根据设备属性参数计算各预设时段对应的阀门开度指令;将预设时域内的阀门开度指令下发至制氢设备,以基于功率指令和阀门开度指令,控制制氢设备在预设时域内运行。本申请实施例的技术方案可减小电解槽温度与目标温度之间的偏差,提高制氢设备的产氢效率。
Resumen de: CN121496410A
本申请属于氢能源制备领域,具体公开了一种萃取辅助无膜电解水制氢方法及装置,包括:S1将电解液注入无膜电解槽内,S2执行电解制氢,S3收集析氢电极上析出的氢气,监测电解电压,在其上升幅度超过设定值时,中断制氢,S4将有机液相注入到电解液中,以促进有机液相萃取溴/碘单质,后将全部有机液相和部分电解液一起回收至第一容器中,S5重新开启外界电源以重启电解制氢,向第一容器中加入抗坏血酸,用于还原溴/碘单质,同时获得脱氢抗坏血酸,S6持续电解制氢同时,将第一容器的电解液重新回流至电解槽中。本发明同时提供了实现以上方法的装置。本发明方法解决了现有技术中无膜电解水制氢工艺连续循环性不足和制氢效率不足的问题。
Resumen de: CN121496456A
本发明涉及电催化剂合成领域,公开了一种中熵固溶体氧化物的制备方法:将固体无机锰盐、锡盐、铱盐和氯化钠进行研磨,混合后获得金属盐混合物;将金属盐混合物在空气中进行高能球磨处理,形成高度均质化的前驱体;将球磨后的前驱体进行热处理,获得含有氯化钠的固溶体氧化物催化剂;将含有氯化钠的固溶体氧化物催化剂进行水洗处理,获得中熵固溶体氧化物电催化剂。本发明还公开了上述制备得到催化剂及其在酸性溶液中电解水析氧反应和在质子交换膜PEM电解水制氢反应中的应用。该催化剂应用于PEM电解水制氢反应和电解水氧化反应中均展现出优异的电催化活性,且长期工作下仍具有较好稳定性。
Resumen de: CN121496443A
本发明公开了一种新型酸性电解水析氧反应电催化剂及其制备方法,所述电催化剂为一种以泡沫镍为基底的新型材料,该材料的制备方法是将预处理后的泡沫镍浸渍在RuCl3水溶液中,一定时间后取出再浸渍在高锰酸钾和盐酸多巴胺的氨水溶液中反应,最后在惰性气氛下焙烧制得。本发明提供了酸性电解水析氧反应电催化剂的方法,Ru在泡沫镍基底分散均匀,负载量低,在0.5M H2SO4酸性电解水析氧反应中,在10mA cm‑2电流密度下,过电位仅为174mv,稳定性超过44h。本发明解决了酸性电解质电解水制氢过程中OER催化剂活性较差、稳定性差、成本高的问题。
Resumen de: CN121496463A
本发明涉及析氢催化剂技术领域,尤其涉及一种基于缺陷工程的钌基碱性析氢催化剂及其制备方法。制备方法包括以下步骤:将钛源、无水乙醇、聚乙二醇200、硼酸的混合体系凝胶老化得到第一前驱体;所述第一前驱体于空气氛围、200~800℃下煅烧5~20h,得到第二前驱体;所述第二前驱体与钌盐和还原剂混合后洗涤干燥,得到所述催化剂。这种催化剂包括电子耦合的载体和Ru活性成分,所述载体为B替位取代Ti的TiO2载体。本发明通过B替位取代Ti,局部引入晶格应力和畸变,实现了快速的水解离,为Ru提供了更多、更强的锚定位点,增强了Ru与载体TiO2之间的电子耦合,至少从强水解能力、优化Ru的氢吸附能两个方面提高催化HER的活性。
Resumen de: CN121496455A
本发明公开了一种质子交换膜水电解池的阳极结构的制备方法,所述质子交换膜水电解池的阳极结构包括锗掺杂二氧化钌片状聚集体阳极催化剂,所述锗掺杂二氧化钌片状聚集体阳极催化剂的制备方法包括如下步骤:将固体无机钌盐、有机锗配合物和聚乙烯吡咯烷酮溶于溶剂中,室温搅拌,得到原液;获得的原液进行静电纺丝,干燥得到纳米纤维前驱体;对前驱体进行热处理,得到所述锗掺杂二氧化钌片状聚集体阳极催化剂。本发明还公开了上述制备得到催化剂及其在酸性溶液中,电解水析氧反应和在质子交换膜PEM电解水制氢反应中的应用。该催化剂应用于PEM电解水制氢反应和电解水氧化反应中均展现出优异的电催化活性,且长期工作下仍具有较好稳定性。
Resumen de: CN121496424A
本发明涉及氢气制备技术领域,公开了一种高效制氢空分一体化设备,包括用于存储电解液的蓄液组件和储气组件,蓄液组件内部设置有用于对电解液电解的电解模块,蓄液组件内部设置有用于对电解液充分搅拌的搅拌组件,蓄液组件一侧设置有用于放置储气组件并带动储气组件升降的顶升机构,磁力耦合传动组件有效减少了磨损,并使设备运行更加稳定,氢气通过氢气传输机构输送至储气组件进行储存,而空分过滤组件则进一步提纯氢气,去除氧气和氮气,确保氢气的高纯度,顶升机构和支撑组件提高了设备的操作灵活性和稳定性,该设备的设计有效地提高了氢气生产的效率和安全性,同时减少了设备的维护成本,并增强了其在中小型应用场景中的适应性。
Resumen de: TW202446996A
The present disclosure relates to an electrolysis cell comprising a porous transport layer which comprises at least one metallic support layer and at least one macroporous layer which comprises titanium particles deposited on the at least one support layer so that the titanium particles are at least partly covered with at least one conductive titanium suboxide surface layer.
Resumen de: CN121490828A
本发明公开了一种单原子‑钛氧簇协同催化剂及其制备方法与应用,该复合催化材料,包括:钛氧多核团簇结构单元;以及以单原子形式通过配位键锚定在所述钛氧多核团簇结构单元上的金属活性中心;其中,所述金属活性中心与钛氧多核团簇之间形成电子协同,增强光生电荷分离与传输。所述钛氧多核团簇为Ti6O6、Ti8O8、由NH2‑MIL‑125(Ti)热解衍生的钛氧簇单元、经有机配体修饰的MOF材料,或通过多羧酸配体调控尺寸的钛氧簇中的至少一种;所述金属活性中心选自Cu、Pt、Ru、Pd、Co中的至少一种。本发明能够实现催化剂的克级制造,具有良好的重复性与稳定性,并且实现钛氧簇与单金属原子的协同光催化水产氢。
Resumen de: CN121496483A
本发明提供了质子交换膜电解水制氢的智能调控方法、装置和系统,包括:在不增加上机前器件制备工艺和成本的前提下,实现改善使用寿命的目标;可在线实时进行状态监测,并利用监测数据研判状态,避免人为经验误判;可采集长时间PEMWE电解槽器件的电化学信息,助推其老化机制的解析;当面对外部环境变化时,可快速识别并进行响应,避免因无人值守等情况造成不必要的性能损失。
Resumen de: CN121496494A
本发明涉及分离技术领域,公开了一种碱性电解水制氢气液分离装置,包括保护外壳,所述保护外壳的内部固定连接有气相出口,所述气相出口的外部固定连接有法兰环,所述气相出口的底端固定连接有套筒,所述套筒的外部固定连接在保护外壳的内部,所述气相出口的内部固定连接有支撑板,所述支撑板的内部设置有泄压组件,所述泄压组件的外部滑动连接在气相出口的内部,所述泄压组件包括浮球,所述浮球的底端滑动连接在支撑板的内部,所述浮球的外部滑动连接在气相出口的内部。通过气相出口支撑支撑板进行固定,从而可以实现自动、智能地调整浮球的位置和密封方式的效果,极大地提升了装置在各种工况下的运行安全性和可靠性。
Resumen de: CN121499980A
一种基于高频阻抗分析的电解槽在线故障检测方法及系统。通过实验测定AEM电解槽液位的上限、安全工作温度对应的高频阻抗范围以及高频安全阻抗阈值范围;实时计算AEM电解槽的高频阻抗值,与安全工作温度对应的高频阻抗范围进行对比;当高频阻抗值处于安全工作温度对应的高频阻抗范围内,则判定AEM电解槽工作在安全环境中;否则,进入故障诊断流程;在故障诊断流程中,将高频阻抗值与高频安全阻抗阈值范围进行对比;区分上限对比结果与下限对比结果,判定AEM电解槽的故障类型并执行对应的处理措施。本申请方法实现了对AEM电解槽的实时监测、故障诊断和动态调控,确保电解槽的稳定、安全运行。
Resumen de: CN121496493A
本发明公开了一种制氢加氢自动化控制方法,它包括如下步骤:步骤S1、系统上电初始化,然后进行系统自检;步骤S2、根据不同的使用场景选择对应的氢气生产控制模式,进行制氢加氢操作,所述氢气生产控制模式包括电解制氢加氢模式、高压钢瓶加氢模式和制氢充固态储氢模式。本发明提供一种制氢加氢自动化控制方法及系统,从而提升制氢加氢一体机的可靠性、灵活性和多样性。
Resumen de: CN121490213A
本发明公开了一种高安全性家用智能氢氧治疗机及工作方法,该设备包括壳体、电解槽、气液分离装置、控制模块、电源模块以及集成的安全监测系统、闭环控制系统和人机交互系统;安全监测系统通过水流、差压、水质、水位、温度等多重传感器实时监控设备状态,确保运行安全;闭环控制系统根据电解槽实时电流、电压及输出差压反馈,精确调节电源功率,保证产气稳定可靠;人机互系统通过触摸显示屏和语音交互模块提供丰富的状态信息和直观的故障指导,本发明从根本上解决了现有家用氢氧治疗机在安全性、可靠性及交互体验方面不足的问题,特别适用于家庭保健环境。
Resumen de: CN121490747A
本发明涉及材料制备领域,具体为一种原位刻蚀生长嵌套式SrTiO3/TiO2异质结光催化材料的制备方法,解决了现有制备方法无法原位合成嵌套式SrTiO3/TiO2异质结构的问题。具体为将SrCl2·6H2O的水溶液与LiOH·H2O的水溶液混合,搅拌得到溶液A,将TiCl4加入1,2‑丙二醇的溶液中,搅拌得到溶液B;将溶液A和溶液B混合搅拌并水热反应一段时间,得到十八面体形状SrTiO3;盐酸水热刻蚀后,SrTiO3内部也会被部分刻蚀,并在其(001)晶面生长出锥形小颗粒,形成SrTiO3与TiO2内外嵌套结构;经过冷却、离心、清洗及干燥后,即可得到原位刻蚀生长嵌套式SrTiO3/TiO2异质结光催化材料。本发明在一般水热条件下即可进行,操作简单、成本低廉、具有较高的产率和纯度,且光催化活性较高,具备实际应用的潜力。
Resumen de: AU2024281599A1
A multi-tier integrated power-to-ammonia system includes a converter for generating ammonia and heat through a reaction involving a compressed mixture of hydrogen and nitrogen gases. The system includes a steam generator that can generate steam using the heat from the reaction, and a reversible solid-oxide system in fluid communication with the steam generator that can separate the steam into oxygen gas and hydrogen gas.
Resumen de: CN121496465A
本发明公开了一种Co2P/Fe2P异质结纳米片阵列材料及其制备方法和应用,属于电催化材料技术领域。本发明提供的制备方法包括:将预处理后的泡沫镍置于含钴盐、铁盐、尿素和氟化铵的前驱体溶液中,通过水热反应在其表面生长CoFe‑LDH纳米片阵列前驱体;随后在惰性气氛下进行低温磷化处理,将前驱体转化为Co2P/Fe2P异质结,最终得到生长于泡沫镍上的Co2P/Fe2P异质结纳米片阵列材料。该材料在碱性电解质中表现出优异的双功能电催化活性与稳定性,用于全水分解时仅需1.50V的低槽压即可驱动20 mA cm‑2的电流密度。本发明工艺简单、成本低廉,为高效、稳定的非贵金属水分解催化电极的制备提供了新方案。
Resumen de: CN121496447A
本发明公开了一种面向酸性电解水的钴基高密度单原子催化剂及其制备方法、应用,属于催化剂技术领域。所述的钴基高密度单原子催化剂包括:纳米四氧化三钴载体和负载在该载体上的单分散的铱单原子;所述铱单原子的负载量在6wt%以上,所述铱单原子的密度为4个/nm2以上。本发明公开了上述单原子催化剂在电催化分解水反应中的应用;通过提高单原子的利用率和负载密度,其在电催化分解水反应中具有高活性和高稳定性。此外,所述钴基高密度单原子催化剂合成便捷,成本低廉,在产业化应用中有巨大潜力。
Resumen de: CN121496491A
本发明涉及电解水制氢技术领域,尤其涉及一种制氢系统连通管控制方法,包括以下步骤:同步采集氢分离器和氧分离器的液位数据、氢气中的氧气浓度数据和氧气中的氢气浓度数据;基于采集的液位数据计算液位差,并对气体浓度数据进行信号预处理;将液位差和预处理后的气体浓度数据输入控制模型进行处理;通过控制模型将液位差与液位差阈值进行比对,将气体浓度数据与对应的气体浓度阈值进行比对。本发明中,通过引入气体纯度参数与液位差的多阈值耦合判断机制,进而根据超标等级触发分级控制指令,从而改善了传统方法大都采用单一液位平衡控制,由于缺乏对氢中氧和氧中氢扩散的主动阻断机制,从而造成气体纯度失控风险高的问题。
Resumen de: CN121497449A
本发明公开了一种电解制氢氧高压燃烧的热电联产储能系统及方法,涉及氢储能领域。电解槽制取高压氢气与氧气后,分别储存于氢/氧储罐中,系统可在氢/氧模式下运行,其中氧模式运行:氢气与来自氧储罐和氢/氧蒸压缩机的氧气蒸汽混合气在高压燃烧室内进行燃烧并生成过热水蒸气,随后进入膨胀透平做功;由于氧气过量,做功后的乏汽经气液分离器后分离成两股工质,即气体进入冷却器降温再经氢/氧蒸压缩机返回燃烧室,液体进入供热换热器后产生的排水经水泵加压后进入高温燃烧室,从而实现氢能的清洁利用与工质的循环再生。本发明可实现高发电效率和优良的环保性能,适用于需要稳定消纳波动性可再生能源以及需要电力与热力供应等地区。
Resumen de: CN121496490A
本发明公开了一种氢能系统碱性电解槽的安全故障预测方法,涉及电解槽安全预测技术领域,解决了现有技术中,析氢异常监测无法捕捉电解液浓度微小动态波动、未建立浓度变化与气泡动力学关联的问题,具体为安全故障预测方法全面覆盖析氢异常、热疲劳裂纹、绝缘性能劣化三大核心安全风险,通过多源传感器数据融合、特征参数精准提取、耦合关联模型构建和全生命周期监测,实现了安全故障的早期识别、精准定位和分级预警;为管理员提供可操作的干预策略,有效降低安全故障发生率,延长设备使用寿命,保障氢能系统稳定可靠运行。
Resumen de: CN121496425A
本申请实施例提供一种电解水制氢系统及其设备。该电解水制氢系统包括电解槽、气液分离装置、换热器、第一管路、第二管路、第三管路、控制器和第一温度传感器,其中:电解槽通过第一管路与气液分离装置连接,电解槽还通过第二管路与换热器连接;气液分离装置通过第三管路与换热器连接;第三管路上包括旁通的第四管路,第四管路与电解槽连接;第一温度传感器设于第一管路;换热器用于对气液分离装置输出的电解液进行降温;气液分离装置用于对电解槽输出的电解液进行气液分离;控制器用于基于第一温度传感器检测电解槽输出的电解液的第一温度,并在第一温度小于或等于第一阈值时,控制气液分离装置分离的电解液通过第四管路向电解槽传输。
Resumen de: CN121496444A
本申请涉及金属催化技术领域,具体涉及一种复合配位单原子催化剂及其制备方法和应用。本申请实施例催化剂包括载体和金属中心,载体包括辅助配位原子,至少两个辅助配位原子与金属中心耦合形成催化活性中心;其中,金属中心包括单原子金属中心,辅助配位原子包括C、N、P、S、Cr中的至少两种。该复合配位单原子催化剂通过金属中心和辅助配位原子间的协同作用降低H2O的解离能垒,提高H2O解离和质子产生速率,极大提高了复合配位单原子催化剂在碱性析氢反应中的催化效率。该复合配位单原子催化剂还通过辅助配位原子耦合锚定金属中心形成催化活性中心从而提高了复合配位单原子催化剂的稳定性和耐久性。
Resumen de: CN121496476A
本申请提供了一种电解槽的温度控制方法,根据当前周期内电解槽的工作电流值和上一周期内电解槽的工作电流值,确定当前周期和上一周期相比电解槽的入口温度理论变化值,进而结合上一周期的电解槽入口温度目标值,确定当前周期的电解槽入口温度目标值,再结合当前周期的电解槽入口温度实测值,调节冷水阀阀门开度。相比于常规的PID反馈调节系统,本方案根据每个周期内电流的变化量,在本周期内重新计算电解槽的入口温度目标值,然后使得冷却水流量阀的阀门开度快速变化,缩小电解槽入口碱液温度过程值与其目标值之间的误差,使电解槽出口碱液温度控制更加准确,保持温度在最佳产氢温度上,提高了制氢效率。
Resumen de: CN121490788A
本发明公开了一种S型异质结Bi12O17Cl2/CeO2光催化剂及其制备方法和应用。该制备方法包括:将CeO2粉末分散在水中得到悬浮液;将BiCl3溶解在乙醇中,滴加NaOH溶液至形成沉淀得到含BiOCl的混合液;将CeO2悬浮液加入含BiOCl的混合液中反应;离心、洗涤、干燥后煅烧,得到S型异质结Bi12O17Cl2/CeO2光催化剂。本发明的S型异质结Bi12O17Cl2/CeO2光催化剂具有优异的光催化性能,既可用于高效降解难降解的抗生素类污染物环丙沙星,也可用于光催化分解水产生氢气这一清洁能源,实现了环境污染治理和清洁能源生产的双重应用功能,为解决环境污染和能源短缺问题提供了一种有效的技术途径。
Resumen de: CN121496427A
本发明涉及综合能源技术领域的一种新能源储能制氢系统,包含用于提供电能的新能源发电单元,用于利用电能电解水制取氢气并在运行过程中产生废热的电解制氢单元,用于以热能形式存储能量的热储能单元,以及包括热力网和协调控制器的络热管理与协调控制子系统;热力网络将电解制氢单元的废热出口、热储能单元的热交换接口以及电解制氢单元的进料预热需求端流体连接;协调控制器能够实现热能在电解制氢单元与热储能单元之间的协同管理与优化利用;该系统通过智能化的热管理与协调控制,实现系统内热能的高效回收、储存与再利用,提升整体能效与经济性。
Resumen de: CN121496442A
本发明公开了一种基于飞秒激光诱导合成高熵析氧催化剂的方法及其在光电化学水分解中的应用,属于析氧催化剂技术领域。本发明方法包括如下步骤:(1)选取含有光电极半导体材料的光电极半导体基底;(2)将高熵金属元素材料负载于光电极半导体基底表面,形成复合基底;(3)将飞秒激光引导至复合基底表面,诱导表面重构,形成高熵金属氧化物‑半导体产物,得到高熵析氧催化剂。本工艺利用飞秒激光导表面重构,使高熵金属氧化物的紧密附着并形成特定结构,实现了高熵金属元素的均匀分布,具有具有步骤简捷、适用性广的优势。高熵析氧催化剂克服了现有技术存在的电荷分离弱、稳定性差等技术问题,在光电化学水分解具有广阔的应用前景。
Resumen de: CN121496482A
本发明提供了一种风光制氢智能控制系统,涉及电力技术领域,包括:能量输入模块,用于实时采集获取制氢功率预测序列;控制指令模块,用于利用最大消纳算法通过制氢功率预测序列,得到最大消纳电解槽状态预测表;利用最小动作算法通过制氢功率预测序列,得到最小动作电解槽状态预测表;通过最大消纳预期收益和最小动作预期收益得到性能指标;通过性能指标将最大消纳电解槽状态预测表或最小动作电解槽状态预测表作为目标电解槽状态预测表;能量转化存储模块,用于根据目标电解槽状态预测表控制氢气转化存储。本发明实现了在提高负荷分配效率的同时实现风光制氢统一调度机制。
Resumen de: CN121496453A
本发明公开了一种镍钒铁基自支撑电极及其制备方法与应用。本发明以偏钒酸钠和氯化镍分别作为钒源和镍源,在泡沫镍基底上通过水热反应合成了由片状结构组成的类球形前驱体,再以无水次磷酸钠和硝酸铁为磷源和铁源,通过磷化处理和浸泡处理最终形成NiO‑VO‑FeP@NF自支撑电极。本发明得到的电极无需添加粘合剂,简化了制备过程并降低了生产成本,而且催化材料与基底的结合紧密,防止了催化剂脱落,这种无缝接触为电荷地快速转移提供了条件,使得催化剂活性得到了明显改善。本发明得到的电极具有优异的析氧反应活性和稳定性,在高电流密度下,其析氧反应活性超越商业RuO2电极,显示出良好的产业化应用前景。
Resumen de: CN121496433A
本发明公开了一种制备高性能AEM电解水制氢膜电极的方法,分别制备AEM电解水制氢阳极和AEM电解水制氢膜阴极,然后将AEM电解水制氢阳极与AEM电解水制氢阴极置于阴离子交换膜两侧并封边,制得AEM电解水制氢膜电极,且制备阳极或阴极时,先将催化剂粉末于溶剂混合制备成催化剂预制浆料后,采用分批次加入阴离子交换树脂溶液后,并加入疏水性粘结剂,制得催化剂浆料,将该浆料涂于疏水改性的扩散层表面制得,最后在扩散层表面涂覆阴离子交换树脂溶液,并浸泡于有机溶剂,经冲洗即可。本发明制备的AEM电解水制氢膜电极能够实现减少氧气气泡滞留的基础上,提升稳定性的同时,提升膜电极的活性。
Resumen de: CN121496316A
本发明属于催化剂领域,具体涉及一种钼合金表面负载碳化钼的制备方法及其应用。其制备方法包括取钼合金置于密闭容器中进行加热;向所述密闭容器中通入甲烷,使所述钼合金在甲烷气氛中高温碳化,碳化完成后即得所述钼合金表面负载碳化钼。有益效果是:制备钼合金表面负载碳化钼的过程快速高效;具有优异的电化学性能,具有高电催化活性和稳定性;无需催化剂或有机溶剂,工艺简单环保;通过调节甲烷流量可精准控制钼合金片的碳化时间,可以满足工业化生产的需求。
Resumen de: CN121496466A
本发明公开了一种RE‑NiFeLDH双功能催化材料及其制备方法与应用。该催化剂包括镍铁水滑石(NiFeLDH)主体和插层于其层间的稀土元素(RE),同时具备析氢反应和析氧反应双功能催化活性。其制备方法为:将镍盐、铁盐、稀土盐、尿素和氟化铵溶于水中形成混合溶液,将预处理后的基材浸入混合溶液,在100~160℃下水热反应6~24小时,产物经抽滤、洗涤、烘干后获得催化剂。本发明通过稀土元素调控NiFeLDH的层间距和电子结构,增加比表面积、暴露更多活性位点,提升催化活性和电子传输效率;制备方法简单可控、成本低廉,催化剂在碱性电解液及模拟海水中均表现出优异的双功能催化性能,具有广阔的工程应用前景。
Resumen de: CN121493877A
本发明提供了一种MoS2(1‑x)Se2x纳米片阵列的方法及其制备方法。该制备方法包括如下步骤:将原料和衬底放置在密闭环境中,所述衬底位于所述原料的上方;其中所述原料为硫单质、硒单质、三氧化钼;在所述密闭环境中施加磁场,使所述原料置于所述磁场中;反应持续预定时间后,停止加载磁场;降温后则可得到原位生长的所述MoS2(1‑x)Se2x纳米片阵列,所述MoS2(1‑x)Se2x纳米片阵列位于所述衬底表面。与现有技术相比,本发明所使用的设备更为简单,反应时间显著缩短,制备效率高。
Resumen de: CN121493880A
本发明公开了一种含非界面Ni空位的NiS/NiSe2异质结的制备方法,包括前驱体制备、原位硒化处理步骤。本发明还公开一种含非界面Ni空位的NiS/NiSe2异质结,其采用如上所述的方法制备而成。
Resumen de: CN121490785A
ZIS/CdS/CQDs三元复合光催化剂的制备方法及应用,涉及光催化材料领域,要解决现有光催化产氢催化剂的光催化产氢的效率较低的问题。方法:一、将金属硫化物CdS加入到甲醇溶液中,然后依次加入二水合醋酸锌、四水合氯化铟和硫代乙酰胺,超声处理,加入Na2CO3,得到混合液;二、将混合液转置于反应釜中反应,冷却,洗涤,干燥,得到ZIS/CdS;三、将ZIS/CdS和CQDs粉末混合反应,冷却,洗涤,干燥,得到ZIS/CdS/CQDs。本发明中ZnInS与CdS复合,显著增强光催化活性。CQDs的宽光谱吸收能力可拓展复合材料的可见光响应范围,与CdS的窄带隙协同提升光捕获效率。本发明用于光催化产氢。
Resumen de: CN119491243A
The invention relates to the technical field of household appliances, and provides a hydrogen peroxide generating device and application thereof. The hydrogen peroxide generating device comprises a shell, a liquid inlet and a liquid outlet, the liquid inlet and the liquid outlet are formed in the shell, the liquid inlet is used for being connected with a water supply component, a cathode piece and an anode piece which are used for electrolyzing water to generate a hydrogen peroxide solution are arranged in the shell, and the liquid outlet is used for discharging the generated hydrogen peroxide solution. According to the hydrogen peroxide generating device provided by the invention, water entering the shell through the liquid inlet can be electrolyzed to generate the hydrogen peroxide solution, and the generated hydrogen peroxide solution is discharged through the liquid outlet; the hydrogen peroxide generating device can be applied to household appliances such as clothes washing equipment, clothes processing equipment, an air conditioner, a dehumidifier, a refrigerator and a dish washing machine, can play a good role in cleaning, odor removal, disinfection, sterilization and the like, reduces the use of detergent, and improves the use experience of a user.
Resumen de: CN121496492A
本申请公开了一种电解海水制氢系统健康状态检测方法、装置及设备,涉及设备状态检测领域,该方法包括:获取电解海水制氢系统的多模态数据集;根据多模态数据集对神经网络模型进行训练,得到预训练神经网络模型;神经网络模型包括多个单模态特征提取模块、特征融合模块、投影模块及预测模块;根据无标签多模态运行数据,采用自监督对比学习方法对预训练神经网络模型进行优化,得到优化后的预训练神经网络模型;根据电解海水制氢系统的实时多模态运行数据,采用优化后的预训练神经网络模型确定电解海水制氢系统的实时健康状态。本申请实现了在仅有少量标注数据甚至无异常样本条件下,对电解海水制氢系统全生命周期内健康状态的精准评估。
Resumen de: CN121491326A
本申请涉及无机材料合成技术领域,具体涉及一种具有纳米孪晶结构的铂纳米片及其合成方法、应用。该铂纳米片包括多个铂纳米晶粒;在铂纳米片的非边缘区域,孪晶畴内的晶格应变分布为:畴结构上部区域的面间角度小于无应变铂晶体面间角度的理想值,呈现压缩应变特征,畴结构下部区域的面间角度大于无应变铂晶体面间角度的理想值,呈现拉伸应变特征;在铂纳米片的边缘区域,畴结构上部区域的面间角度减小至65.6°,畴结构下部区域的面间角度增加至74.2°。该铂纳米片具有纳米孪晶结构,其孪晶畴内存在的晶格应变现象能够提高铂纳米片的吸附能力,进而显著增强铂纳米片的催化活性。
Resumen de: CN121496489A
本发明涉及氢能安全监测技术领域,具体地说,涉及一种基于光纤原位监测内部状态的电解槽。包括阴极端板和阳极端板,阳极端板位于阴极端板的一侧,阴极端板的侧壁固定连接有阴极垫片,阴极垫片远离阴极端板的一端固定连接有阴极极板,阴极极板的侧壁固定连接有阴极衬垫,阴极衬垫远离阴极极板的一端固定连接有阳极衬垫,阳极衬垫和阴极衬垫的内表面固定连接有膜电极,通过在阴极极板、阳极极板分别开设主沟槽、副沟槽,嵌入集成温度型和应变型FBG传感器的主光纤、副光纤,直接将监测点布置于反应核心区域贴近膜电极及流场,可实时捕捉流场方向上的温度梯度、机械应力变化等关键信息。
Resumen de: CN121496429A
本发明公开了一种中板、电极室组件及电解制氢装置,中板包括本体和循环板,所述本体由金属板一体冲压制备而成,所述本体表面周边冲压有截面为S型的环形密封槽道,所述环形密封槽道内侧的本体的两个表面上分别冲压有若干第一凸起和第二凸起;所述循环板倾斜设置并与第一凸起固定连接,所述循环板设置在环形密封槽道内且顶边与本体表面的间距小于底边与本体表面的间距;电极室组件运用上述中板组装而成,电解制氢装置则运用上述的电极室组件。本发明具有良好的密封效果,阴阳极室中板合二为一的冲压结构有效减少泄露点,降低外漏风险;而且减少点焊接工艺,降低内部接触电阻,从而降低电解槽能耗,上述结构配置合理,安装方便。
Resumen de: CN121490346A
本发明公开了一种用于肺功能训练的腹式呼吸训练装置,腹式呼吸训练装置通过定位板、储存气囊、气体发生装置、收集气囊、气泵、输出管道、发声器和控制组件的协同,使得使用者在吸气时腹部顶推储存气囊、控制组件随之动作并同步放大发声器音量,呼气时气囊回弹音量减弱,形成直观的听觉反馈,引导使用者自然采用腹式呼吸;同时气体发生装置按需向两个储存室供氧或供氢,气泵实现氢气循环,输出管道将氧气直接送达口鼻,既保证呼吸训练所需气体持续充足,又通过氢气回收避免浪费与风险,从而提升训练安全性、舒适性与有效性。
Resumen de: CN121496480A
本申请实施例提供一种启动方法、装置、电子设备、存储介质及程序产品。该方法包括:获取电解水制氢系统的多个电解槽的运行参数和效能参数;基于多个电解槽的运行参数,确定各电解槽是否达到启动条件;在存在电解槽未达到启动条件时,生成至少一个电解槽对应的告警提示信息,并停止启动;在多个电解槽达到启动条件时,获取电解水制氢系统的电源的可用功率容量,并结合电源的可用功率容量,启动电解水制氢系统的多个电解槽。在上述方法中,通过自动采集多个电解槽的运行参数与效能参数,基于运行参数自动判定各电解槽是否达到启动条件,无需人工逐台检查运行参数,大幅减少了大规模PEM电解水制氢系统在启动阶段的耗时。
Resumen de: CN121496478A
本发明公开了一种用于电解水制氢系统运行稳定性的控制方法,所述系统包括电解槽、电源、气液分离器、冷却器、循环泵以及检测与执行机构,包括以下步骤:S1:实时监测所述系统的运行状态参数,所述运行状态参数至少包括电解槽温度、电解槽压力、输入电流密度、氢侧与氧侧差压、循环碱液流量或去离子水电阻率;S2:基于所述运行状态参数,通过预设的系统稳定性评估模型。本发明克服了传统单回路控制的局限与干扰问题,使系统面对内外扰动时能整体做出前瞻、平稳且经济的协同响应,不仅在稳态运行时维持全局最优稳定性与能效,更在瞬态与异常工况下通过智能容错与运行点自适应迁移,显著提升系统的鲁棒性、安全性与全生命周期适应能力。
Resumen de: CN121496462A
本发明属于材料合成及电催化技术领域,具体涉及一种金属离子掺杂的镍磷化物催化剂及其制备方法和催化应用,将含有金属离子的盐、镍源、有机配体、溶剂充分混合后,加入载体,进行水热反应,得到金属离子掺杂的Ni‑有机配体前驱体;再将金属离子掺杂的Ni‑有机配体前驱体进行磷化处理,得到金属离子掺杂的镍磷化物。本发明材料的制备方法简单,制备的材料同时具有碱性氢析出反应(HER)和尿素氧化反应(UOR)催化活性,相较于传统Pt、Ru基催化剂而言,减少了Ru的用量,降低了成本,且拥有更高的HER和UOR活性和稳定性。通过HER耦合UOR产氢,从热力学上解决了全解水能耗高的问题,具有更高的工业应用价值。
Resumen de: CN121499362A
本发明提供一种用于碱性电解水制氢电极催化剂结合力与均匀性的测试方法,包括实验设备搭建和实验操作两个过程,其中,实验设备搭建包括制备测试溶液A、制备测试溶液B、制备防腐支撑板、制备样品和组装测试设备,然后,接通电源进行测试并记录数据。本发明提出了一种能够模拟电极失效的测试方法,相较于传统的测试方法,本发明的测试时间更短,测试方法更加灵活,尤其能够更加直观方便的反应催化剂与电极基材结合能力的强弱。相较于一般的测试方法,本方法具有更加灵活、快速、便捷、时间人力成本更低等特点。
Resumen de: CN121496440A
本发明属于电催化材料与电解制氢技术领域,具体涉及一种复合电催化剂及其制备方法与应用。本发明所述基于高铷高硅锂矿石基为载体的Ni单活性中心复合电催化剂的制备方法,通过对高铷高硅锂矿石进行预处理、酸蚀活化、锂化调控、Ni活性溶液配制、溶剂热负载、焙烧定型等步骤,实现Ni单活性中心在矿石载体上的均匀负载与高效活化。该催化剂应用于尿素电解制氢时,展现出低起始电位、低过电位、高稳定性的优势。
Resumen de: CN121496458A
本发明属于电催化二氧化碳还原反应技术领域,具体公开了Ni‑Co双单原子催化剂及其制备方法和应用,催化剂包括碳载体,原子级分散的Ni单原子,以Ni‑N4构型锚定于碳载体;原子级分散的Co单原子,以Co‑N4构型锚定于碳载体,催化剂中无金属‑金属键。本发明采用上述的Ni‑Co双单原子催化剂及其制备方法和应用,通过Ni‑N4和Co‑N4双活性位点分别独立调控CO2‑to‑CO转化和析氢反应(HER),实现CO/H2比例在0.3:1‑2.5:1范围内精确可调;利用Ni单原子位点调控界面水氢键网络刚性,平衡CO2和H2O的活化动力学,抑制工业级电流密度下的副反应。
Resumen de: CN121490765A
本发明适用于制氢技术领域,提供了一种MOF衍生多层碳材料催化剂的制备方法及其应用,所述催化剂以钴基MOF为前驱体,经高温焙烧后,再通过特定条件的DBD等离子体处理制得。DBD处理能有效减小催化剂粒径,增加活性位点暴露,提高钴物种分散度。将所得催化剂用于氨硼烷甲醇分解制氢反应,在温和条件下即可实现高效产氢,其催化活性与部分贵金属催化剂相当。本发明制备工艺简单、能耗低、环境友好,为非贵金属催化剂的开发及氨硼烷储氢材料的应用提供了新途径。
Resumen de: CN121496445A
本发明涉及电解水制氢的技术领域,提供一种PEM电解水的阳极催化剂浆料的制备方法及浆料及催化层,所述制备方法包括:S1、将阳极催化剂、第一离聚物、第一溶剂混合,分散,得到第一催化剂浆料;S2、将消氢催化剂、第二离聚物、第二溶剂混合,分散,得到第二催化剂浆料;所述消氢催化剂为碳载贵金属催化剂;S3、将第一催化剂浆料和第二催化剂浆料混合,进行均质化处理,得到阳极催化剂浆料。优点:通过消氢添加剂的添加、浆料制备工艺步骤等的配合设置,同时实现提高均匀性、改善传质和降低氧中氢的效果,提升了膜电极性能和安全性。
Resumen de: CN121496432A
本发明属于质子交换膜(PEM)电解水制氢技术领域,具体涉及一种PEM电解水制氢膜电极涂布方法。该方法包括:步骤1:涂布浆料动态预处理;步骤2:质子交换膜张力稳定输送;步骤3:双面同步狭缝涂布;步骤4:涂布过程第一次OCT在线检测;步骤5:三阶段梯度干燥固化;步骤6:干燥后进行第二次OCT实时检测与闭环调整;步骤7:涂布成品收卷。解决了传统涂布工艺“单面离散效率低、厚度不均、缺陷检测滞后、转运褶皱”等问题。
Resumen de: AU2024304508A1
According to the invention, electrodes are arranged on two opposite surfaces of a separator. Each electrode consists of an open-pore metal structure, in particular a metal foam made of at least one of the chemical elements Ni, Al, Mo, Fe, Mn, Co, Zn, La, Ce, or an alloy of at least two of said chemical elements or an intermetallic compound of at least two of said chemical elements. A continuously decreasing catalytic activity is provided from the surface facing a separator or the respective other electrode of each electrochemical cell to the opposite surface of the respective electrode, and/or a continuously increasing porosity and/or pore size and/or a continuously decreasing specific surface area is provided from the surface facing a separator or the respective other electrode of each electrochemical cell to the opposite surface of the respective electrode.
Resumen de: CN120882907A
A system and method for generating hydrogen from a liquid source comprising water is disclosed. The system comprises: a high fluid velocity electrolysis cell comprising an inlet and an outlet, the inlet of the high fluid velocity electrolysis cell being fluidly connected to a liquid source; and a gas fractionation system fluidly connected to the outlet of the high fluid velocity electrolysis cell.
Resumen de: KR20260018245A
본 발명의 일 태양에 따르면, 수전해 스택에 공급되는 전해액의 유량을 개별 제어하기 위한 수전해 시스템으로서, 복수의 수전해 스택, 상기 복수의 수전해 스택과 일대일 대응으로 연결되어 전해액을 공급하는 복수의 전해액 공급 펌프, 및 상기 복수의 수전해 스택으로부터 배출되는 수소 가스 또는 산소 가스의 온도와 상기 복수의 수전해 스택에 대하여 설정되는 타겟 온도를 참조하여 상기 복수의 전해액 공급 펌프의 유량을 개별 제어하는 유량 제어부를 포함하는 수전해 시스템이 제공된다.
Resumen de: KR20260018302A
산소발생반응용 전기 촉매를 개시한다. 어븀 산화물 나노 클러스터(nano cluster); 및 상기 어븀 산화물 나노 클러스터 상에 배치되어 상기 어븀 산화물 나노 클러스터와 이종계면을 형성하는 철 산화물 나노 입자를 포함한다.
Resumen de: CN121472892A
本发明属于火电乏汽利用技术领域,具体公开了一种耦合氢储能的火电乏汽制氢系统及方法,系统包括:火力发电单元、乏汽制氢单元和风光发电单元;火力发电单元的低压缸乏汽支路出口通过乏汽流量控制阀与增汽机的低压气入口连接,低压缸抽汽出口通过抽汽流量控制阀与增汽机的高压气入口连接,增汽机的气体出口与PEM电解池的原料入口连接;PEM电解池的供电端口与火力发电单元的发电机输出端以及风光发电单元分别连接;火力发电单元的低压缸乏汽进入PEM电解池作为电解原料,火力发电单元产生的部分电能和/或者部分风光电能进入PEM电解池作为电解能量,将电能、乏汽的化学能转化为氢气的化学能并储存,满足火电机组深度调峰的需求。
Resumen de: CN121472941A
本发明公开了一种应用于一体化电极材料的基体前处理工艺,属于电极材料制备技术领域。该工艺依次包括基体预处理、微蚀刻、粗糙镍沉积及绣花球阵列骨架电沉积,通过微蚀刻在镍基多孔基体表面构建微米级粗糙结构以提供更多形核位点;基于粗糙镍沉积在基体粗糙表面形成一层致密、非晶态的金属镍过渡层,实现与基体的强机械互锁,并兼备高耐蚀性与高导电性;最后利用电沉积在金属镍过渡层上生长出垂直取向的纳米线阵列骨架。本发明通过微蚀刻、粗糙镍沉积与电沉积三者协同作用,最终构建出从宏观基体到微观活性骨架的完整、稳定且高效的三维导电载体,从根本上提升了一体化电极材料与基体之间的结合力以及界面稳定性和传质能力。
Resumen de: CN121472932A
本发明公开了一种基于模拟工业碱性电解水的催化电极抗反向电流的测试方法,包括以下步骤:S10,将待测试催化电极固定安装于模拟碱性电解槽装置中;S20,配置28%‑32%的氢氧化钾溶液作为碱液,并通过水浴锅将碱液加热至85℃‑90℃;S30,将加热后的碱液注入模拟碱性电解槽装置中进行电解;S40,待碱液温度稳定在85℃左右后,通过电化学工作站对待测试催化电极进行活化,使待测试催化电极达到稳定状态;S50,采用电位测试阶跃法对稳定状态的催化电极进行抗反向电流测试。本发明的有益效果:能够模拟实际电解环境中的反向电流现象并测试催化电极的耐反向电流性能,以优化电解水制氢系统的稳定性和工作效率。
Resumen de: CN121472907A
本发明提供一种一体化析氧反应电极及其规模化制备方法和制备系统。该规模化制备方法包括以下步骤:提供导电基底;将导电基底置于循环流动状态的腐蚀液中,同时向腐蚀液中通入含氧气体,进行自发的电化学腐蚀,使得导电基底上原位形成层状双金属氢氧化物层。本发明借助腐蚀液的循环流动与含氧气体主动供给的协同策略,实现了高性能一体化析氧反应电极的高效、均匀、可控的规模化制备,其中循环流动消除了传质限制与浓度梯度,含氧气体为自发式电化学腐蚀提供了持续稳定的反应驱动力。该协同策略在宏观上保障了电极规模化制备的一致性,在微观上调控了活性组分,避免了剧烈扰动对局部高pH生长界面的破坏,为其放大至工业化生产规模奠定了基础。
Resumen de: CN121472919A
本发明属于电催化水分解技术领域,涉及一种自支撑Biy@CoOOH/NF复合材料及其制备方法与应用。本发明通过在泡沫镍载体上通过溶剂热法合成超薄Bix@Co‑MOF/NF前驱体;随后通过电化学处理诱导前驱体发生表面重构,将其转化为CoOOH载体并同步调控其中的氧空位浓度;获得自支撑Biy@CoOOH复合材料。本发明获得的复合材料呈现高活性比表面积,可实现铋物种尺寸的精确控制,进而实现对催化性能的连续调控。且表现出优异的析氧反应催化活性与长期稳定性,适用于高效电解水制氢系统。本发明避免了使用粘结剂所带来的性能衰减问题,为高性能自支撑电极的可控制备提供了普适、可靠的技术路线。
Resumen de: CN121473928A
本发明涉及一种集成电解池、氢燃机和燃煤电站的联合发电系统及方法,系统包括电解系统、氢燃气轮机发电系统和燃煤发电系统,电解系统包括质子交换膜电解池,质子交换膜电解池的电极与可再生能源发电系统电连接并利用可再生能源发电系统的电力电解水制氢,氢燃气轮机发电系统包括相互连接的燃烧室和氢燃气轮机,燃烧室与电解系统连接并通过电解产生的氢气燃烧产生蒸汽驱动氢燃气轮机发电;汽轮机组与氢燃气轮机发电系统连接,燃煤发电系统在升负荷时利用氢燃气轮机发电系统输出的蒸汽补充至汽轮机组。本发明在解决可再生能源发电电力消纳问题的基础上,协助燃煤机组升负荷,提高可再生能源的利用率,提升燃煤机组调峰的灵活性。
Resumen de: CN121471533A
本发明提出一种氨基基团修饰Ti基MOFs的制备方法与应用,其步骤为:将钛酸四丁酯添加到混合有机溶剂中,经搅拌和超声处理,得到混合溶剂;有机配体NH2‑BDC置于混合溶剂中得到配体Ⅰ,有机配体BDC置于混合溶剂中得到配体Ⅱ;将配体Ⅰ和配体Ⅱ分别进行搅拌和超声处理,至有机配体充分溶于混合溶液中,完成前置处理;配体Ⅰ与配体Ⅱ混合以n(NH2‑BDC)/n(BDC)计,n(NH2‑BDC)/n(BDC)为2~9:1~8,制备成NM(x)光催化剂。本发明解决现有方法制备的钛基MOFs存在配体分布不均、合成效率低,以及可见光利用率不足的问题。
Resumen de: CN121472923A
本发明公开了一种海绵状V2O5复合Fe插层石墨氮N‑V2O5@FeC及其制备方法与应用,通过球磨实现FeCl3/KCl与石墨粉的均匀混合,在250 ℃下热熔实现Fe插层石墨,从而得到高导电性的Fe插层石墨FeC。之后,在Fe插层石墨FeC中引入NH4VO3和三聚氰胺进行二次球磨,经两段式热处理成功制备出海绵状V2O5复合Fe插层石墨氮材料。本发明海绵状多孔结构大幅增加活性位点暴露,同时Fe插层诱导的石墨边缘缺陷和Fe‑O‑V键共同提升了V2O5复合材料的活性位点密度,从而增强了催化剂活性。其次,氮掺杂碳网络改善了电子传输性能,促使催化剂的电荷转移电阻降低至19.9 Ω。此外,Fe‑O‑V稳定结构和V‑O‑C键化学锚定的双重稳定机制,使材料在碱性条件下表现出良好的结构稳定性,并在OER中展现出优越的电化学性能。
Resumen de: CN121472888A
本申请提供一种制氢装置及制氢方法,涉及电解水制氢技术领域。其中,该装置中的空气压缩机、阳极换热器、SOEC电堆的阳极构成阳极回路,SOEC电堆的阴极、阴极换热器、混合器、分离器、氢气循环器构成阴极回路;气水换热器与蒸汽发生器和阳极换热器连接;聚光集热回路包括:聚光塔、一级换热器、热储罐、冷储罐、二级换热器、蒸汽发生器。该装置通过内部间接热耦合的聚光集热系统为SOEC回路供热,同时SOEC回路具有可进行深度余热回收的双回路,实现了把太阳辐照的短时波动与蒸汽生成彻底解耦,确保进入SOEC回路的蒸汽在温度与流量上均保持平稳;同时保留SOEC回路进行过热与微调的自由度,从而降低了固体氧化物电解池制氢过程中的控制难度,提高了设备稳定性。
Resumen de: CN121472917A
本发明提供了一种电解水制氢催化剂及其制备方法和应用。该催化剂包含式(1)所示的铱钌复合氧化物,RuxIr(1‑x)O2 (1),x=0.1~0.9。该催化剂在酸性电解液中表现出高的活性和长期稳定性,电流密度为10mA cm‑2时的过电位不超过220mV。
Resumen de: CN121472900A
本发明提供一种电解水制氢装置的极距优化型极框结构,第一极板和第二极板相对的表面上,在电极叠层区的侧边设置有凸起;所述凸起的上侧设有第一凹槽,所述凸起的下侧形成电极安装槽;所述第一极板和第二极板的凸起相对设置,相邻的凸起上侧与所述第一极板和第二极板共同围合形成密封垫圈安装空间;第一密封垫圈安装于所述密封垫圈安装空间内;所述第一阴极和第一阳极分别安装在所述第一极板和第二极板的电极安装槽中;所述第一隔膜设置在所述第一阴极和第一阳极之间,并延伸至所述第一凹槽与第一密封垫圈之间的位置。本发明消除电极边缘区域的极距突变现象,为电解反应提供均匀的电场分布基础。
Resumen de: CN121472905A
本发明属于电极技术领域,具体涉及一种基于氮掺杂石墨烯负载钼铁单原子电极及其制备方法和应用。本发明先在泡沫镍气相沉积氮掺杂石墨烯,并在其表面电沉积铁钼单原子,泡沫镍基底上锚定具有铁钼单原子的催化剂,作为电解水制氢阳极用于析氧(OER)反应。本发明的制备方法不仅避免了使用绝缘粘结剂,确保了优异的电子传输能力,而且三维多孔结构极大地促进了电解液浸润和氧气气泡的快速释放,结合了多元金属的协同电子效应、最大的原子利用效率以及理想的质量传输通道,为开发高效、低成本的电解水制氢阳极提供了极具应用潜力的解决方案。
Resumen de: CN121475958A
本发明涉及实验集气技术领域,本发明公开了一种铝颜料包覆层致密性的析氢测试装置及方法,包括铁架、反应瓶,所述反应瓶顶部封堵塞处固定连接有滴管,所述反应瓶的上方通过所述铁架固定连接有调浮集气组件,所述调浮集气组件由透明的环筒、透明的采集筒、顶气活塞、浮盒组成,所述浮盒的数量不少于1个,所述反应瓶、所述采集筒通过气管连通,所述环筒包围在所述采集筒的外部,所述顶气活塞密封滑动连接在所述采集筒的内部;采用非手触水的形式,利用浮力克服气封活塞摩擦力、活塞承受重力等对气体注入的阻碍问题,且经过调试后,即可进行多次且长期稳定运行,整体结构简单,成本低,符合实验应用需求。
Resumen de: CN121472897A
本发明公开一种基于纳米级梯度浆料分批次喷涂的PEM制氢膜电极及制备方法。本发明首先通过精确调控冰浴超声、超声波破碎及高压均质的工艺参数,制备出三种不同纳米级DLS粒径的催化剂浆料:第一IrOx浆料(5‑10 nm)、第二IrOx浆料(10‑15 nm)和第三IrOx/TiO2浆料(20‑40 nm);然后采用超声喷涂技术,按粒径由小到大的顺序,将三种浆料分批次依次喷涂于膜基底上,并精确控制各层铱负载量。本发明通过构建从致密到疏松的纳米级梯度催化层结构,有效增加了三相反应界面,降低了欧姆电阻与传质阻力,从而在显著降低贵金属用量的同时,大幅提升了膜电极的催化活性与析氧反应效率。
Resumen de: CN121472910A
本发明属于电解水制氢领域,具体提供了一种电解水制氢领域阳极表面的涂层、阳极及阳极的制备方法和应用。本发明所提供的电解水制氢阳极表面的涂层包括依次设置的底层、中间层和表层;所述底层含有Ni和Cr;所述中间层含有Ni、Mo和Zn;所述表层含有RuO2和IrO2。本发明所述的阳极涂层,通过独特的梯度复合设计,含有特定成分的多层结构,所述底层、中间层和表层三层之间相互配合,协同达到与基材结合力强、电化学性能优异、制氢效率显著提高的技术效果。同时,本发明还提供了含有所述特定梯度涂层结构的阳极,以及所述阳极的制备方法和在电解水制氢中的应用。
Resumen de: CN119491243A
The invention relates to the technical field of household appliances, and provides a hydrogen peroxide generating device and application thereof. The hydrogen peroxide generating device comprises a shell, a liquid inlet and a liquid outlet, the liquid inlet and the liquid outlet are formed in the shell, the liquid inlet is used for being connected with a water supply component, a cathode piece and an anode piece which are used for electrolyzing water to generate a hydrogen peroxide solution are arranged in the shell, and the liquid outlet is used for discharging the generated hydrogen peroxide solution. According to the hydrogen peroxide generating device provided by the invention, water entering the shell through the liquid inlet can be electrolyzed to generate the hydrogen peroxide solution, and the generated hydrogen peroxide solution is discharged through the liquid outlet; the hydrogen peroxide generating device can be applied to household appliances such as clothes washing equipment, clothes processing equipment, an air conditioner, a dehumidifier, a refrigerator and a dish washing machine, can play a good role in cleaning, odor removal, disinfection, sterilization and the like, reduces the use of detergent, and improves the use experience of a user.
Resumen de: CN121481107A
本发明涉及再生能源利用与绿色化工耦合技术领域,公开了可再生能源电解水制氢耦合绿色化工的运行方法及系统,运行方法包括:在每个运行周期初始,预设化工系统运行负荷,并在同一运行周期内保持预设的化工系统运行负荷不变;获取每个运行周期内风光发电的功率预测数据,根据功率预测数据以及电解水制氢综合电耗,计算电解水制氢产量预测值;实时采集储氢罐压力,并将储氢罐压力划分为多个区间,在每个区间内,根据储氢系统压力与电解水制氢产量预测值,通过不同修正系数确定化工系统运行周期内的耗氢速率。结合储氢情况及风、光电功率预测,设置下一时间周期内的化工稳定运行负荷,提升化工系统运行的稳定性,降低变负荷操作频率。
Resumen de: CN121471531A
本发明公开了一种钴基配位聚合物材料的制备方法及其光催化制氢应用。所述钴钙配位聚合物材料的化学式为CoCa(2‑sina)2,单斜晶系,空间群为C2/c,晶胞参数a=31.5440(12),b=5.5342(2),c=6.9592(3),α=90°,β=106.560(4)°,γ=90°,Z=4,晶胞体积V=1201.36(7) Å3。在光催化反应中,该晶体结构中的催化位点稳定存在,能够加快反应速率,在光敏剂和牺牲剂的存在下,该钴钙配位聚合物在可见光的照射下能表现出良好的制氢性能。
Resumen de: CN121472864A
本发明公开了一种自重构型析氧电极、制备方法及应用,该制备方法包括将镍基底作为工作电极,铂片作为对电极,饱和甘汞电极作为参比电极放置于NiCo2O4前驱体溶液中,对镍基底进行恒电位电沉积,得到表面具有Ni‑Co LDH前驱体的前驱体电极;将前驱体电极放入加热装置中加热并保温,然后取出前驱体电极进行冷却,得到具有尖晶石结构的NiCo2O4电极;将NiCo2O4电极依次放入九水合硝酸铁水溶液和氢氧化钠溶液中,使用连续离子层吸附反应法在NiCo2O4电极的表面负载α‑Fe2O3纳米颗粒,得到自重构型析氧电极。该自重构型析氧电极的制备方法在镍基底上构建由尖晶石结构的NiCo2O4和α‑Fe2O3组成的复合催化层,能适应功率波动。
Resumen de: CN121472921A
本发明公开了一种具有高抗电力波动性能的铁钴铝硫化物析氢催化剂及其制备方法和应用,涉及电催化全水分解技术领域,为解决现有技术中缺少高HER活性、耐受工业级电流密度、并在波动电力条件下保持稳定的催化剂。本发明技术要点包括:首先在载体表面通过电化学沉积尿素及铁、钴和铝的层状金属氢氧化物;再以层状金属氢氧化物为基体,通过水热原位硫化处理得到铁钴铝硫化物复合材料。本发明复合材料在制备电解制氢阴极材料中具有广泛的应用前景。
Resumen de: CN121467028A
本发明涉及一种热触发的电场催化氨低温分解制氢催化剂及其制备方法和用用,该催化剂包括载体、活性组分和导电材料添加剂,活性组分的负载量为催化剂总重量的0.1‑10%,导电材料添加剂的添加量为催化剂总重量的0%‑5%;其中,所述载体为铈锆固溶体;活性组分为Ru、Pd、Ag、Pt、Rh、Ir、Cr、Mn、Fe、Co、Ni、Cu中的一种或多种;导电材料添加剂为导电碳材料。与现有技术相比,本发明具有启用停止快速且稳定、长时间运行后氨转化率衰减小等优点。
Resumen de: WO2024231154A1
The present invention relates to a hydrogen gas production assembly comprised of a hydrogen gas production device, a container comprising an aqueous electrolyte solution, a storage container for storing produced hydrogen gas an input providing the aqueous electrolyte solution from the container to the hydrogen gas production device and an output for transferring produced hydrogen gas from the hydrogen gas production device to the storage container. The present invention further relates to methods for the production of hydrogen gas via the hydrogen gas production assembly.
Resumen de: CN121472927A
本发明属于电解水制氢催化材料技术领域,具体涉及一种析氧反应催化剂及其制备方法和应用。所述催化剂的化学通式为M‑M1M2 LDH,其中M1、M2分别为Fe、Co、Ni中的一种,且M1和M2不为同一元素,M为V、Cr、Mn、Co、Cu、Zn、Mo、Ce、Zr中的一种;采用溶胶‑凝胶法制备。本发明通过可控掺杂过渡金属元素优化层状双氢氧化物电子结构,合成粒径在5nm以下的过渡金属元素掺杂的层状双氢氧化物,用于析氧反应催化剂,具有良好的电催化活性。该材料制备工艺简单、成本低廉,为高效稳定电解水催化剂的开发和规模化生产提供了新策略。
Resumen de: CN121472889A
本发明涉及制氢设备技术领域,具体为基于非贵金属催化剂的光热电解耦合制氢装置:包括制氢底座,所述制氢底座的表面上设置有电解槽,所述制氢底座的表面上固定连接有总控制器,所述制氢底座的表面上固定连接有供电电源,所述供电电源的输出端固定连接有电源线,所述电源线的输入端固定连接有电极,所述电极固定连接在电解槽的外部,所述电解槽的表面上固定连接有排气管。本发明通过在关键管道设置第一电磁阀、第二电磁阀等多个电磁阀,并结合第一温度传感器等传感器实时监测温度,配合上总控制器控制,形成循环交流水道,针对电解槽内部温度,灵活调整水道水流方向,满足反应温度要求,显著提高制氢效率。
Resumen de: WO2024245759A1
The proposed invention concerns a process (100) for producing a cracked gas product comprising hydrogen from an endothermic cracking reaction of an ammonia feedstock stream, comprising the following steps: • In a secondary reactor, performing a secondary endothermic cracking conversion (104) of the remaining unconverted portion of ammonia into a hydrogen enriched fuel gas, • Redirecting the hydrogen enriched fuel gas to a fuel device (105), in particular comprising a burner, arranged to perform a combustion reaction (111) of said hydrogen enriched fuel gas, potentially with an additional fuel gas stream, • Heating the main endothermic cracking conversion (112) with heat provided by said combustion.
Resumen de: KR20260017874A
본 발명은 지지체; 및 상기 지지체 상에 형성된 미세다공성 고분자 복합체층;을 포함하고, 상기 미세다공성 고분자 복합체층은 미세다공성 고분자 및 이온성 액체를 포함하는, 수전해용 이온교환막 및 이의 제조 방법에 관한 것이다. 본 발명의 수전해용 이온교환막의 제조 방법은 제조 공정이 간단하기 때문에 모든 형태의 이온교환막에 적용이 가능하며, 손쉽게 강도 및 이온전도도를 개선할 수 있다.
Resumen de: CN121472920A
本发明公开了一种海水制氢催化剂制备方法及系统,属于海水制氢技术领域。方法包括基底预处理、梯度合金核层制备、三元渗透阻挡层制备、相变织构化处理和电场辅助表面改性。通过梯度磁场和超声波协同辅助电化学沉积技术制备原子排列有序的镍铁钴三元合金层,采用原子层沉积技术按钨层、钼层、铬层顺序制备三元渗透阻挡层,有效阻止氯离子侵蚀。系统包括基底预处理装置、梯度合金核层制备装置、三元渗透阻挡层制备装置、相变织构化处理装置和电场辅助表面改性装置。本发明制备的催化剂具有高催化活性、快反应动力学、大活性面积、低电荷转移电阻和强抗腐蚀稳定性,在海水电解环境中表现出优异的长期稳定性。
Resumen de: CN121472929A
本发明公开了一种非对称结构碱性电解水制氢隔膜及其制备方法和应用。该制备方法包括:(1)在支撑板上先涂覆第一层铸膜液,然后再放置隔网,随后再在隔网上涂覆第二层铸膜液,放卷后复合形成隔膜前驱体;(2)采用蒸汽诱导相分离法对隔网上表面涂覆的第二层铸膜液进行分相,之后再将隔膜前驱体浸入凝胶浴中进行凝固定型,最后经清洗、收卷,即得。本发明制得的隔膜具有非对称结构,一侧为致密孔,可以提升阻气;另一侧为相对开放的大孔结构,可以减小OH‑的传质阻力,有利于降低隔膜电阻,并降低电解能耗;且本发明采用两步法涂布制膜,可以在减少隔膜气泡缺陷的同时,提升效率,具有较好的应用前景。
Resumen de: CN121472928A
本发明属于电催化水分解技术领域,涉及一种内建电场与不对称桥氧键共同作用的Ta‑Co‑MOF‑P/NF复合材料的制备方法与应用。所述方法首先在泡沫镍载体上通过一步溶剂热合成双金属Ta‑Co‑MOF/NF前驱体,随后通过低温磷化处理在基底上构建Co‑MOF与CoP异质界面。得益于调控磷化程度构成的内建电场及适当Ta掺杂量形成的Co‑O‑Ta不对称桥氧键,共同改变了水分子构型以提高其水分解的活性。该催化剂能够增强与水分子间的相互作用力且自由水在表面水分子构型中所占比例提升,使活性氢物种更容易解离和释放,从而加快碱性HER反应动力学和传质过程。所述材料在碱性环境中表现出优异的HER催化活性和长期稳定性。
Resumen de: JP2026020096A
【課題】p型半導体とn型半導体とを組み合わせた接合体であって、効率よく酸化還元反応を起こす光触媒として使用できる接合体の提供。【解決手段】Cu系のp型酸化物半導体と、M1Fe2O4又はM2WO4(M1およびM2は、それぞれ独立して、金属元素)であるn型酸化物半導体とを接合した、接合体。【選択図】図2
Resumen de: CN121472926A
本发明公开了一种木质素多金属有序碳化界面四元电触媒,主要由FeNi合金纳米核、MoCx 渐变界面层、Ru超小金属簇和N/O/P 共掺杂木质素派生碳壳构成;MoCx 渐变界面层紧密包覆于 FeNi合金纳米核表面,Ru超小金属簇分布在MoCx 渐变界面层和N/O/P 共掺杂木质素派生碳壳之间,N/O/P 共掺杂木质素派生碳壳包围在最外层。据此,还建立了相应制备方法。本发明四元电触媒可以应用于高流密整体水分解,并用来制备电极或碱性整体水分解电解槽,为木质素等生物质资源在高流密电解水领域的高价值利用提供了一条新路径。
Resumen de: CN121472894A
本发明公开了一种PEM电解槽的集成式密封结构及PEM电解槽,包括极板组件、膜电极组件和集成式密封体,极板组件包括两块双极板,双极板的两侧表面均设置有至少一个环形密封槽;集成式密封体夹装于两块双极板之间,且沿膜电极组件的四周密封设置,集成式密封体的横截面包括扁平状的密封主体,密封主体的其中一侧表面设有至少一个第一线密封部和至少一个第一面密封部,另外一侧设有至少一个第二线密封部和至少一个第二面密封部,第一线密封部和第二线密封部分别与对应的环形密封槽密封抵接,第一面密封部和第二面密封部分别与两块双极板的表面密封抵接。本发明结合了线密封+面密封,增强了高压下的密封力,降低了装夹力,有效防止侧移风险。
Resumen de: WO2026027698A1
The invention comprises an electrochemical cell stack unit (10) consisting of electrochemical cells, which can be used, for example, as a fuel cell unit for electrochemically generating electrical energy from hydrogen and/or as an electrolysis cell unit for generating hydrogen and oxygen from electrical energy.
Resumen de: WO2026027570A1
The invention relates to a method of operating an electrolysis system having a plurality of stacks, each of which comprises a plurality of individual cells in a stacked arrangement, where each individual cell has an anode and a cathode that are separated by a membrane. According to the invention, by defining a lower power threshold (Pmid,low) and an upper power threshold (Pmid,high), an average power range in which the ageing rate (AR) of the membranes reaches a maximum is defined, and, in order to reduce membrane ageing, the available electrical power (P) is divided between one or more stacks so as to avoid operation of any individual stack in the average power range. The invention further relates to a control unit for executing steps of the method according to the invention.
Resumen de: WO2026027751A1
The installation (10), comprises a piece of equipment delimiting an electrolyte storage or/and circulation volume (200), the piece of equipment comprising a metal wall (202) having an inner surface (208) facing the electrolyte storage or/and circulation volume (200). The piece of equipment further comprises: - a polymer adhesive protection layer (220) applied on the inner surface (208) of the metal wall (202); - a polymeric liner (222) positioned between the polymer adhesive protection layer (220) and the electrolyte storage or/and circulation volume (200), the polymeric liner (222) having an electrolyte contact surface (232) delimiting the electrolyte storage or/and circulation volume (200).
Resumen de: WO2026027565A1
The present invention relates to an electrode, preferably a gas evolution electrode, comprising a substrate, a porous interlayer and a catalytic layer, wherein the porous interlayer comprises nickel and have a surface area of at least 0. 1 m2 /g measured by BET, wherein the catalytic layer comprises at least one catalytically active metal, wherein said porous interlayer has an inner porous surface and an outer surface, wherein the at least one catalytically active metal is a transition metal, a rare earth element or a combination thereof, wherein at least 80% of said at least one catalytically active metal is deposited on the outer surface of said porous interlayer measured by cross-sectional SEM EDAX image analysis, wherein at most 20% of said at least one catalytically active metal is deposited in the inner porous surface measured by cross-sectional SEM EDAX image analysis.
Resumen de: WO2026027476A1
A process for the synthesis of methanol (MeOH) comprising the following steps: (a) passing a water-containing stream (3) through an electrolysis unit (4) to produce a cathode-side stream (5) comprising hydrogen (H2) and an anode-side stream (6) comprising oxygen (O2); (b) heat-exchanging said cathode-side stream (5) and optionally said anode-side stream (6) in one or more indirect heat exchanger(s) (7, 8, 32, 33) to obtain a cathode-side heat-exchanged stream (9) and optionally an anode-side heat-exchanged stream (10); (c) condensing said cathode-side heat-exchanged stream (9) to separate a liquid condensate product (11) and a syngas (12); said cathode-side stream (5) and/or said syngas (12) comprise carbon dioxide and optional carbon monoxide added through a separate stream (2); (d) compressing said syngas (12) in a compressor (27, 28) and then feeding compressed syngas (13) to a MeOH synthesis loop (14) wherein catalytic conversion of said compressed syngas (13) into MeOH is carried out under methanol synthesis conditions, thus obtaining a crude methanol stream (15); (e) distilling said crude methanol stream (15) in one or more distillation column(s) (16, 17) to give a refined MeOH product (19, 22); (i) recycling as feed to the electrolysis unit (4) at least a portion of at least one of: (A) a portion (31) of said compressed syngas (13); and/or (B) a bottom water stream (20) of a distillation column (16, 17).
Resumen de: WO2026027472A1
A process or plant for the synthesis of methanol (MeOH). The process comprises: (a) passing a water-containing stream (3) through an electrolysis unit (4) to produce a cathode-side stream (5) comprising hydrogen (H2) and an anode-side stream (6) comprising oxygen (O2); (b) heat-exchanging said cathode-side stream (5) and optionally said anode-side stream (6) in one or more indirect heat exchanger(s) (7, 8, 32, 33) to obtain a cathode-side heat-exchanged stream (9) and optionally an anode-side heat-exchanged stream (10); (c) condensing said cathode-side heat-exchanged stream (9) to separate a liquid condensate product (11) and a syngas (12); said cathode-side stream (5) and/or said syngas (12) comprise carbon dioxide (CO2) and optional carbon monoxide (CO) added through a separate stream (2); (d) compressing said syngas (12) and then feeding compressed syngas (13) to a MeOH synthesis loop (14) wherein catalytic conversion of said compressed syngas (13) into MeOH is carried out under methanol synthesis conditions, thus obtaining a crude methanol stream (15); (e) distilling said crude methanol stream (15) in one or more distillation column(s) (16, 17) to give a refined MeOH product (22); wherein said one or more indirect heat exchanger(s) (7, 8, 32, 33) provide a heat input to said one or more distillation column(s) (16, 17), and/or to said MeOH synthesis loop (14), and/or to said electrolysis unit (4).
Resumen de: WO2026027165A1
A frame assembly (Fr.Ass) comprising a frame (TF) configured to be integrated in a stack of frames of an electrolyzer, the frame comprising a central opening (CentOp), a first through opening (In2, Out2), a top surface (Top) and a bottom surface (Bot) opposed to the top surface (Top), the frame further comprising an open channel (OpCh) on the bottom surface (Bot), the frame assembly comprising a bipolar plate (BP) formed from a polymer material, the bipolar plate being arranged so as to seal the open channel (OpChan), the bipolar plate being welded to the frame (TF).
Resumen de: WO2026027166A1
A frame assembly (Fr.Ass) comprising a frame (TF) configured to be integrated in a stack of frames of an electrolyzer, the frame comprising a central opening (CentOp), a first through opening (ln2, Out2), a top surface (Top) and a bottom surface (Bot) opposed to the top surface (Top), the frame further comprising an open channel (OpCh) on the bottom surface (Bot), the frame assembly comprising a bipolar plate (BP) formed from a polymer material, the bipolar plate being arranged so as to seal the open channel (OpChan), the bipolar plate being welded to the frame (TF).
Resumen de: DE102024207270A1
Die Erfindung betrifft ein Verfahren zum Betreiben eines Elektrolysesystems (1), umfassend einen Elektrolysestack (2) mit einer Anode (2.1) und einer Kathode (2.2) sowie einen Elektrolytkreislauf (3), über den der Anode (2.1) ein Elektrolyt, vorzugsweise Wasser oder eine wässrige Lösung, zugeführt wird, wobei in den Elektrolytkreislauf (3) eine Kühleinrichtung (4) integriert ist, mit deren Hilfe der Elektrolyt gekühlt wird, bevor er über den Elektrolytkreislauf (3) erneut der Anode (2.1) zugeführt wird. Das Verfahren zeichnet sich erfindungsgemäß durch folgende Schritte aus:a) Prognostizieren einer maximal verfügbaren Kühlleistung der Kühleinrichtung (4),b) Bestimmen der Elektrolyt-Temperatur im Elektrolytkreislauf (3) stromabwärts der Kühleinrichtung (4) und stromaufwärts einer temperaturkritischen Komponente (5), vorzugsweise eines Ionentauschers, die bzw. der in einem Nebenpfad (6) angeordnet ist, der stromabwärts der Kühleinrichtung (4) über ein Ventil (7) mit dem Elektrolytkreislauf (3) verbundenen ist, wobei die Elektrolyt-Temperatur anhand der in Schritt a) prognostizierten maximal verfügbaren Kühlleistung bestimmt wird,c) Vergleichen der in Schritt b) bestimmten Elektrolyt-Temperatur mit einem vorab definierten Maximalwert sowied) zumindest teilweises Schließen des Ventils (7), wenn der Vergleich in Schritt c) ergibt, dass der Maximalwert überschritten wird.Die Erfindung betrifft ferner ein Elektrolysesystem (1), das zur Durchführung des Verfah
Resumen de: DE102024207372A1
Die vorgestellte Erfindung betrifft eine Bipolarplatte (100) für ein Elektrolysesystem (300), wobei die Bipolarplatte (100) umfasst:- einen Grundkörper (101) mit einer ersten Seite (103) und einer der ersten Seite (103) gegenüberliegenden zweiten Seite (105),wobei zumindest auf der ersten Seite (103) eine Vielzahl Kanäle (107) von einem ersten Ende zu einem dem ersten Ende gegenüberliegenden zweiten Ende verlaufen,wobei zwischen jeweiligen benachbarten Kanälen (107) Leitpfade (109) ausgebildet sind,wobei die Leitpfade (109) an einem ersten Ende fluiddicht verschlossen und an einem gegenüberliegenden zweiten Ende offen sind, undwobei jeweilige Kanäle (107) eine Anzahl Öffnungen (113) umfassen, die ein Überströmen von durch die Leitpfade (109) strömendem Fluid in die Kanäle (107) ermöglichen.
Resumen de: DE102025128171A1
Die vorliegende Offenbarung betrifft eine Elektrolyseur-Batteriezelle, ein Herstellungsverfahren und eine Vorrichtung zum Erzeugen von Wasserstoffgas aus erneuerbarer Energie. Die Elektrolyseur-Batteriezelle umfasst eine Membranbaugruppe, die im zentralen Bereich der Elektrolyseur-Batteriezelle angeordnet ist; eine Anodenkomponente und eine Kathodenkomponente, die jeweils auf beiden Seiten der Membranbaugruppe angeordnet sind; wobei die Anodenkomponente eine Anodentransportstruktur umfasst, um Fluid innerhalb des Elektrolyseurs bei einer ersten Geschwindigkeit in der Anodentransportstruktur zu transportieren; wobei die Kathodenkomponente eine Kathodentransportstruktur umfasst, um Fluid innerhalb des Elektrolyseurs bei einer zweiten Geschwindigkeit in der Kathodentransportstruktur zu transportieren; wobei die Kathodentransportstruktur sich von der Anodentransportstruktur unterscheidet und der Durchschnittswert der zweiten Geschwindigkeit größer als der Durchschnittswert der ersten Geschwindigkeit ist. Die Lösung der vorliegenden Offenbarung verbessert die Transportrate des Fluids, unterstützt die Entladung der Gasprodukte auf der Kathodenseite und verhindert, dass die Gasprodukte auf der Kathodenseite die Katalysatorschicht bedecken, sodass die Reaktanten schnell die Elektrodenoberfläche erreichen können, wodurch die Reaktionsrate des elektrolysierten Wassers gewährleistet und die Leistung der Elektrolyseur-Batterie verbessert wird.
Resumen de: DE102024207257A1
Die Erfindung betrifft ein Verfahren zum Betreiben eines Elektrolysesystems mit mehreren Stacks, die jeweils eine Vielzahl an Einzelzellen in gestapelter Anordnung umfassen, wobei jede Einzelzelle eine Anode und eine Kathode aufweist, die durch eine Membran getrennt sind. Erfindungsgemäß wird durch Festlegen einer unteren Leistungsschwelle (Pmid,low) und einer oberen Leistungsschwelle (Pmid,high) ein mittlerer Leistungsbereich definiert, in dem die Alterungsrate (AR) der Membranen ein Maximum erreicht, und zur Verringerung der Membranalterung die verfügbare elektrische Leistung (P) so auf einen oder mehrere Stacks aufgeteilt wird, dass ein Betrieb eines einzelnen Stacks im mittleren Leistungsbereich vermieden wird.Die Erfindung betrifft ferner eine Steuereinheit zur Ausführung von Schritten des erfindungsgemäßen Verfahrens.
Resumen de: KR20260017211A
본 발명은 수소 첨가를 통해 배가스 및 바이오가스로부터 메탄 분리 및 나노탄소물질 제조방법, 이에 의하여 제조 가능한 탄소나노튜브 및 탄소 코팅된 실리콘 음극재에 관한 것으로, 더욱 상세하게는 (a) 배가스 또는 바이오가스, 또는 이들 모두에 포함된 혼합가스를 포집하고, 혼합가스에 포함된 불순물을 제거하는 단계; (b) 불순물이 제거된 혼합가스의 조성을 분석하여 소정량의 수소를 첨가하는 단계; (c) 수소가 첨가된 혼합가스를 제1 반응기에 투입하고, 상기 제1 반응기에 의하여 반응 후 생성물을 생성하는 단계; (d) 상기 제1 반응기에 의한 반응 후 생성물의 가스 분리를 통해 메탄을 분리하는 단계; (e) 상기 (d) 단계에서 분리된 메탄을 제2 반응기에 투입하여 나노탄소물질을 생성하는 단계; 및 (f) 상기 (c) 단계에서의 일부 생성물과, 상기 (d) 단계에서 메탄을 제외한 분리 가스 및 상기 (e) 단계에서의 제2 반응기에 의한 반응 후 생성된 가스를 선택적으로 재순환시키기 위한 단계;를 포함하여 이루어진다. 본 발명은 전북농기계·부품기술고도화 지원사업(IZ-24-0039)에 의한 위탁 연구를 통해 제안되었음을 밝힌다.
Resumen de: TW202511178A
To provide: an ammonia-hydrogen mixed fuel production apparatus capable of stably obtaining hydrogen from ammonia even when there is a change in the required ratio of fuel; and a fuel supply system. An ammonia-hydrogen mixed fuel production apparatus 1010A comprises: an oxygen separation device 13 that separates oxygen (O2) 12 at a desired concentration from air 11; a reforming reactor 15 that converts ammonia (NH3) supplied from a raw material supply unit 14 into hydrogen (H2) by using the oxygen having the desired concentration from the oxygen separation device 13; and a gas component analyzer 17 that measures the concentration of one or both of hydrogen and ammonia in a reformed gas 16 from the reforming reactor 15.
Resumen de: AU2025277771A1
Provided is a method for controlling a water electrolysis system with which operation states of a plurality of electrolysis stacks can be independently regulated highly responsively and highly efficiently. This method is for controlling a water electrolysis system which comprises: electrolysis stacks where water is electrolyzed to produce hydrogen and oxygen; a pure water feeder for feeding pure water to the electrolysis stacks; a first regulation part and a second regulation part, which are disposed between each electrolysis stack and the pure water feeder and are capable of regulating the operation state of the electrolysis stack; and an operation state regulation control unit which regulates the first regulation part and the second regulation part to regulate the operation states of the electrolysis stacks. The operation state regulation control unit, after receiving a command to change the operation state of an electrolysis stack, operates the first regulation part on the basis of the operation state and, when a predetermined requirement has been satisfied, operates the second regulation part simultaneously with the first regulation part on the basis of the operation state.
Resumen de: WO2026028988A1
This ion exchange membrane has a short side and a long side of 80 m or more. A membrane thickness deviation rate A, ion exchange capacity deviation rate B, and ion exchange group residual ratio C, which are calculated by a predetermined method, are within a specific numerical range.
Resumen de: US20260035321A1
A process of hydrogenating an unsaturated hydrocarbon is disclosed. The process comprises passing a hydrocarbon feed stream comprising toluene to a hydrogenation reactor. A hydrogen stream is passed to the hydrogenation reactor. In the hydrogenation reactor, the hydrocarbon feed stream is hydrogenated in the presence of hydrogen and a hydrogenation catalyst to produce a hydrogenated effluent stream comprising methylcyclohexane. The hydrogenated effluent stream is indirectly contacted with a water stream to produce a steam stream. The steam stream is taken from the hydrogenation reactor. In an electrolyzer, hydrogen is separated from the steam stream to produce the hydrogen stream which is passed to the hydrogenation reactor.
Resumen de: US20260039120A1
The invention relates to a method for operating a renewable power plant (100) comprising at least one wind turbine (101) and an electrolyzer system (110), the renewable power plant is connectable with a grid (190) via a circuit breaker (123) located at a point of common coupling (PCC), wherein the renewable power plant comprises an internal grid (191) connecting the at least one wind turbine and the electrolyzer system with the point of common coupling, wherein the method comprises detecting a low voltage at any of the at least one wind turbine, and electrically disconnecting the electrolyzer system from the internal grid in response to detecting the low voltage.
Resumen de: US20260035819A1
An electrolysis system includes an electrolyzer cell stack, a water tank, and a hydrogen management system. The electrolyzer cell stack uses water and electricity to produce a hydrogen product gas and an oxygen product gas including crossover hydrogen gas. The water tank is configured to receive a hydrogen tank stream including water and dissolved hydrogen gas and an oxygen tank stream including water and dissolved oxygen gas. In the water tank, the dissolved hydrogen gas and the dissolved oxygen gas exsolve from the water to form a gas mixture. The hydrogen management system is configured to control a concentration of the crossover hydrogen gas in at least a portion of the oxygen product gas to form a diluent for introduction into the water tank to decrease a hydrogen gas concentration in the gas mixture of the water tank.
Resumen de: US20260035816A1
A hydrogen production system including: a first renewable power source, a first electrolyser, and a single stage power converter having an input side and an output side, wherein the input side is connected to the first renewable power source and the output side is connected to the first electrolyser.
Resumen de: US20260035815A1
The present invention relates to a sealing layer for use in an electrolyzer, a separator plate therefor and an electrolyzer. The sealing layer has at least one sealing bead, which, when installed in the stack, in plan view of the sealing layer runs around the flow field of the separator plate in a self-contained manner and has an initial bead height H0 determined before the first compression in the stack, wherein after an initial one-time compression of the sealing layer under nominal compression in the assembled, ready-to-use state of the stack and subsequent disassembly of the stack, the self-contained sealing bead has a bead height H where H≤0.3 H0.
Resumen de: US20260035817A1
This control device for a hydrogen production apparatus is intended to be used for a hydrogen production apparatus including an electrolyzer for electrolyzing water and a rectifier for supplying a direct-current electric power to the electrolyzer, the control device being provided with: a voltage control unit which is configured so as to adjust an output voltage output from the rectifier to the electrolyzer in such a manner that the output voltage of the rectifier is coincident with a set voltage; and a voltage set unit which is configured so as to set the set voltage to a first voltage that is larger than a rated voltage for the electrolyzer in at least a portion of the period during the start-up of the hydrogen production apparatus.
Resumen de: US20260035240A1
Disclosed is a catalyst suitable for the catalytic oxidative cracking of a H2S-containing gas stream. The catalyst comprises at least one or more active metals selected from the group consisting of iron, cobalt, and nickel, supported by a carrier comprising ceria and alumina. The active metal is preferably in the form of its sulphide. Also disclosed is a method for the production of hydrogen from a H2S-containing gas stream, comprising subjecting the gas stream to catalytic oxidative cracking so as to form H2 and S2, using a catalyst in accordance with any one of the composition claims.
Resumen de: US20260035241A1
The present invention relates to a method and device for producing hydrogen by dissociating the water molecule through thermochemical reactions, using a small amount of active material. The thermochemical reactions are induced by solar energy with a moderate concentration of up to 50 suns, which can be achieved through linear or parabolic concentrators.
Resumen de: US20260035242A1
A hydrogen generation system with controlled water distribution is disclosed. The system comprises a reaction chamber containing a hydrogen-producing fuel, a liquid distribution mechanism, and a control system. The liquid distribution mechanism includes a rotating arm with liquid injection ports that move vertically through the fuel chamber. This allows for precise and efficient liquid delivery to unreacted fuel, optimizing hydrogen production. A proprietary fuel blend utilizes chemicals that store significant amounts of hydrogen in a solid-state form. A feature of the device is the arm's controlled vertical movement, achieved through a screw mechanism that adjusts the arm's height as it rotates, creating a spiral liquid distribution pattern. The control system regulates liquid injection rates, arm rotation speed, and vertical movement to optimize hydrogen production based on demand. The system can also operate at low pressures and be scaled to different sizes in a safer, more efficient, on-demand manner.
Resumen de: JP2026018134A
【課題】水素とホウ素からホウ化水素とそのシートを比較的簡単な方法で生成する製造方法を開発する。【解決手段】ホウ素微粒子21と、大気圧プラズマ発生装置27と、水素を含む作動気体を主たる要素とし、前記大気圧プラズマ発生装置27の前記作動気体として少なくとも水素を大気圧プラズマ発生装置27に供給し、大気圧プラズマを前記ホウ素微粒子21に照射することにより、ホウ化水素7とそのシートであるホウ化水素シート8を生成することを特徴とするホウ化水素とそのシートの製造方法である。また、好ましくは、前記作動気体にホウ素微粒子を加えることが望ましい。更に好ましくは、前記容器内に撹拌機と皿を加え、前記皿内に入れた前記ホウ素微粒子に前記大気圧プラズマを照射するように配置することが望ましい。【選択図】図2
Resumen de: JP2026017689A
【課題】各水電解装置の特性劣化を効果的に抑制する。【解決手段】制御システム50は、複数の水電解装置を含む水電解システムを制御する。制御システム50は、水電解システムにより使用されるべき電力を示す電力指令値が電力閾値を超過することを含む第1条件と、電力指令値の変化量が変化閾値を超過することを含む第2条件との少なくとも一方の成否に応じて、複数の水電解装置の各々の稼働または停止を決定する動作決定部61と、電力指令値と動作決定部61による決定結果とに応じて複数の水電解装置の各々に対する個別指令値を設定する指令値設定部62とを具備する。【選択図】図7
Resumen de: WO2026023164A1
This purification plant comprises: a temperature swing adsorption (TSA) tower in which unreacted ammonia is adsorbed to an adsorbent and removed from a decomposition gas and from which a resulting treated gas is discharged; a gas-purifying device that separately discharges product gas refined from the treated gas and off-gas; an off-gas heating device that heats the off-gas and supplies same to the TSA tower as regeneration gas for regenerating the adsorbent in the TSA tower; a combustion device that supplies, as a heat source for the off-gas heating device, a portion of a combustion gas resulting from combusting the regeneration gas discharged from the TSA tower; an off-gas flow path that circulates the off-gas through the combustion device; and a combustion-gas flow path that circulates the combustion gas through the off-gas heating device.
Resumen de: WO2026029709A1
The present disclosure broadly relates to a method of preparing a supported high-entropy oxide nanostructure The method may comprise the step of: irradiating, with a laser, a substrate coated with a hydrogel to form the high-entropy oxide nanostructure, wherein the hydrogel comprises at least five metal salts, a cross-linking agent, a carbonaceous substance and water to form a high-entropy oxide nanostructure. There is also disclosed herein a high- entropy oxide nanostructure produced by the method as well as the use of the high-entropy oxide nanostructure for forming hydrogen.
Resumen de: WO2026028848A1
In a hydrogen boiler (3), hydrogen gas and oxygen gas supplied from a water electrolysis device (2), which generates the hydrogen gas and the oxygen gas by electrolyzing water, are combusted in a combustion chamber of the hydrogen boiler (3), and a water pipe of the hydrogen boiler (3) is heated, thus generating water vapor.
Resumen de: WO2026030458A1
A process of hydrogenating an unsaturated hydrocarbon is disclosed. The process comprises passing a hydrocarbon feed stream comprising toluene to a hydrogenation reactor. A hydrogen stream is passed to the hydrogenation reactor. In the hydrogenation reactor, the hydrocarbon feed stream is hydrogenated in the presence of hydrogen and a hydrogenation catalyst to produce a hydrogenated effluent stream comprising methylcyclohexane. The hydrogenated effluent stream is indirectly contacted with a water stream to produce a steam stream. The steam stream is taken from the hydrogenation reactor. In an electrolyzer, hydrogen is separated from the steam stream to produce the hydrogen stream which is passed to the hydrogenation reactor.
Resumen de: WO2026029047A1
A method for promoting a formic acid synthesis reaction according to the present invention involves reacting carbon dioxide with hydrogen in an ionic liquid, wherein a substituent in a cation of the ionic liquid is at least an amino group or a carboxyl group.
Resumen de: WO2026028790A1
Disclosed is a diaphragm for alkaline water electrolysis, which separates an anode chamber and a cathode chamber of an alkaline water electrolysis cell. This diaphragm for alkaline water electrolysis is provided with a polymer porous film which integrally has a sealing region that is sandwiched by cell constituent members in the alkaline water electrolysis cell, an edge region that is disposed on the outer peripheral side of the sealing region, and a separator region that is disposed on the inner peripheral side of the sealing region. The sealing region has a shape surrounding the separator region, and has a bulk part for preventing permeation of an electrolyte solution through the pores of the polymer porous film.
Resumen de: WO2026028789A1
This diaphragm for alkaline water electrolysis separates an anode chamber in which an anode of an alkaline water electrolysis tank is disposed and a cathode chamber in which a cathode is disposed, the diaphragm for alkaline water electrolysis comprising a polymer porous membrane integrally having a seal region, which is sandwiched by a tank-constituting member in the alkaline water electrolysis tank, and a separator region, which is disposed on the inner-peripheral side of the seal region. The separator region has an inter-electrode region that is smaller than the separator region and is sandwiched between the anode and the cathode, and a non-restraint region present between the seal region and the inter-electrode region. The polymer porous membrane has a frame-shaped bulk part that extends across the seal region, the non-restraint region, and the inter-electrode region.
Resumen de: TW202511178A
To provide: an ammonia-hydrogen mixed fuel production apparatus capable of stably obtaining hydrogen from ammonia even when there is a change in the required ratio of fuel; and a fuel supply system. An ammonia-hydrogen mixed fuel production apparatus 1010A comprises: an oxygen separation device 13 that separates oxygen (O2) 12 at a desired concentration from air 11; a reforming reactor 15 that converts ammonia (NH3) supplied from a raw material supply unit 14 into hydrogen (H2) by using the oxygen having the desired concentration from the oxygen separation device 13; and a gas component analyzer 17 that measures the concentration of one or both of hydrogen and ammonia in a reformed gas 16 from the reforming reactor 15.
Resumen de: AU2024308720A1
The disclosure provides a method of producing hydrogen. The method comprises conducting a thermochemical reaction by contacting an active reagent and a basic aqueous solution, to thereby cause water from the basic aqueous solution to react with the active reagent and to produce hydrogen and a basic aqueous solution comprising an oxidised product. The method further comprises disposing the basic aqueous solution comprising the oxidised product in an electrochemical cell comprising an anode and a cathode, such that at least a portion of the cathode contacts the solution; and conducting an electrochemical reaction by applying a voltage across the anode and the cathode to produce hydrogen, oxygen and the active reagent. The active reagent comprises a metal or metal ion in a first oxidation state and the oxidised product comprises the metal or metal ion in a second oxidation state which is higher than the first oxidation state.
Resumen de: AU2024291792A1
The disclosure concerns a process of carbon oxides-free hydrogen production is disclosed. The process comprises the following steps: - heating a gas stream of a reacting compound including hydrogen atoms in absence of oxidizing agents, to thermally decompose the reacting compound into smaller product compounds, including hydrogen molecules, obtaining a stream of decomposition product compounds; - separating hydrogen molecules from other product compounds of the stream of decomposition product compounds; - reacting a portion of the stream of separated hydrogen molecules with a stream of an oxidizing agent, in particular oxygen or air, to obtain combustion product compounds, including steam and heat, in a stream of combustion product compounds; - providing heat obtained in the previous step to the step of heating the reacting compound; and wherein the process can comprise a step of - recovering energy from the stream of decomposition product compounds and/or from the stream of combustion product compounds. Additionally, a system of hydrogen production is also disclosed, the system being configured to operate according to the above process.
Resumen de: AU2024291778A1
A method of synthesizing aluminum oxide includes reacting a gallium and aluminum composite in a hydrogen evolution reaction with water to form an aluminum byproduct having at least one of aluminum hydroxide or aluminum oxyhydroxide. The method also includes removing the aluminum byproduct and calcinating the aluminum byproduct to form aluminum oxide.
Resumen de: EP4686717A1
A process or plant for the synthesis of methanol (MeOH). The process comprises:(a) passing a water-containing stream (3) through an electrolysis unit (4) to produce a cathode-side stream (5) comprising hydrogen (H<sub>2</sub>) and an anode-side stream (6) comprising oxygen (O<sub>2</sub>);(b) heat-exchanging said cathode-side stream (5) and optionally said anode-side stream (6) in one or more indirect heat exchanger(s) (7, 8, 32, 33) to obtain a cathode-side heat-exchanged stream (9) and optionally an anode-side heat-exchanged stream (10);(c) condensing said cathode-side heat-exchanged stream (9) to separate a liquid condensate product (11) and a syngas (12);said cathode-side stream (5) and/or said syngas (12) comprise carbon dioxide (CO<sub>2</sub>) and optional carbon monoxide (CO) added through a separate stream (2);(d) compressing said syngas (12) and then feeding compressed syngas (13) to a MeOH synthesis loop (14) wherein catalytic conversion of said compressed syngas (13) into MeOH is carried out under methanol synthesis conditions, thus obtaining a crude methanol stream (15);(e) distilling said crude methanol stream (15) in one or more distillation column(s) (16, 17) to give a refined MeOH product (22);wherein said one or more indirect heat exchanger(s) (7, 8, 32, 33) provide a heat input to said one or more distillation column(s) (16, 17), and/or to said MeOH synthesis loop (14), and/or to said electrolysis unit (4).
Resumen de: EP4686773A1
A frame assembly (Fr.Ass) comprising a frame (TF) configured to be integrated in a stack of frames of an electrolyzer, the frame comprising a central opening (CentOp), a first through opening (In<sub>2</sub>, Out<sub>2</sub>), a top surface (Top) and a bottom surface (Bot) opposed to the top surface (Top), the frame further comprising an open channel (OpCh) on the bottom surface (Bot), the frame assembly comprising a bipolar plate (BP) formed from a polymer material, the bipolar plate being arranged so as to seal the open channel (OpChan), the bipolar plate being welded to the frame (TF).
Resumen de: EP4686774A1
A frame assembly (Fr.Ass) comprising a frame (TF) configured to be integrated in a stack of frames of an electrolyzer, the frame comprising a central opening (CentOp), a first through opening (In<sub>2</sub> , Out<sub>2</sub> ), a top surface (Top) and a bottom surface (Bot) opposed to the top surface (Top), the frame further comprising an open channel (OpCh) on the bottom surface (Bot), the frame assembly comprising a bipolar plate (BP) formed from a polymer material, the bipolar plate being arranged so as to seal the open channel (OpChan), the bipolar plate being welded to the frame (TF).
Resumen de: EP4686772A1
The installation (10), comprises a piece of equipment delimiting an electrolyte storage or/and circulation volume (200), the piece of equipment comprising a metal wall (202) having an inner surface (208) facing the electrolyte storage or/and circulation volume (200).The piece of equipment further comprises:- a polymer adhesive protection layer (220) applied on the inner surface (208) of the metal wall (202) ;- a polymeric liner (222) positioned between the polymer adhesive protection layer (220) and the electrolyte storage or/and circulation volume (200), the polymeric liner (222) having an electrolyte contact surface (232) delimiting the electrolyte storage or/and circulation volume (200).
Resumen de: EP4686505A1
The present disclosure relates to a system suitable for photocatalysis comprising a semiconductor and selective contacts, the selective contacts being at least two, wherein the selective contacts are attached to the semiconductor; and the selective contacts comprise an electron transport layer and a hole transport layer. It also relates to a method to produce a system suitable for photocatalysis comprising the steps of: providing a sol-gel precursor of the semiconductor; dissolving the sol-gel precursor in a polar solvent; adding acid to the dissolution and stirring the dissolution to obtain a sol of the semiconductor; depositing the semiconductor in a suitable substrate; submitting the deposited semiconductor to a temperature of at least 300 °C for at least 1 hour to obtain a thin film of semiconductor; depositing on the semiconductor an electron transport layer and/or a hole transport layer. The present disclosure also relates to a method to obtain hydrogen from water or alcohol comprising the steps of contacting the system defined with water and/or alcohol, and irradiating the system as defined with light.
Resumen de: CN121241457A
The invention relates to a gas conduit arrangement (10) for conveying high-temperature gas between high-temperature fuel cell stacks (SOFC stacks). According to the invention, the gas conduit device (10) has a conduit body (11) made of a ceramic material in order to electrically insulate potentials at both axial ends of the conduit body (11).
Resumen de: JP2026017268A
【課題】従来よりも高い耐久性を発揮する観点から有利な新規の水電解用電極を提供する。【解決手段】水電解用電極1は、導電性基材10と、層状複水酸化物(LDH)層20とを備えている。LDH層20は、導電性基材10上に設けられている。LDH層20のクラック頻度は、0.18個/μm未満である。LDH層20のクラック頻度は、導電性基材10とLDH層20との間の単位界面長さ当たりのLDH層20におけるクラックの個数である。【選択図】図1
Resumen de: US2024401524A1
The present disclosure relates to a gas turbine plant that decomposes ammonia and supplies it as fuel to a combustor of a gas turbine. The gas turbine plant supplies sufficient heat to the ammonia in order to thermally decompose the ammonia effectively, and separates the residual ammonia present in the decomposition gas and supplies it to a combustor of the gas turbine.
Resumen de: JP2026017255A
【課題】触媒層における気液の入れ替わりを円滑化できる技術を提供する。【解決手段】膜・触媒層接合体は、電解質膜と、電解質膜の表面に形成された触媒層と、を備える。触媒層は、第1アイオノマー83および第2アイオノマー84を含む。第2アイオノマー84のEW値は、第1アイオノマー83のEW値よりも高い。このようにすれば、触媒層中に、第1アイオノマー83により比較的親水性が高くなる第1領域A1と、第2アイオノマー84により比較的親水性が低くなる第2領域A2とが形成される。これにより、触媒層において、気液の入れ替わりを円滑に行うことができる。【選択図】図4
Resumen de: JP2026017230A
【課題】水素発生の起動と停止を繰り返し行う場合でも、隔膜への触媒付着を抑え、長期にわたって安定運転可能なアルカリ水電解セルを提供する。【解決手段】隔膜1と、該隔膜1を隔てて配置された酸素発生陽極2及び水素発生陰極3とを具え、酸素発生陽極2と水素発生陰極3の少なくともいずれか一方の電極が、導電性基材2a,3aと、該導電性基材の表面上に配置された触媒層2b,2c,3b,3cとを含み、前記隔膜1と向かい合わせる面から蛍光X線分析法を用いて解析した触媒層2c,3cの金属原子濃度/導電性基材2a,3aの金属原子濃度比R1と、隔膜1と反対の面から蛍光X線分析法を用いて解析した触媒層2b,3bの金属原子濃度/導電性基材2a,3aの金属原子濃度比R2との比(R1/R2)の値が0以上1未満であることを特徴とする、アルカリ水電解セル10である。【選択図】図1
Resumen de: JP2026017267A
【課題】従来よりも高い耐久性を発揮する観点から有利な新規の水電解用電極を提供する。【解決手段】水電解用電極1は、導電性基材10と、層状複水酸化物(LDH)層20とを備えている。LDH層20は、導電性基材10上に設けられている。LDH層20の最小厚みt20は、540nm未満である。【選択図】図1
Resumen de: TW202503114A
Provided are a gas production method and a gas production apparatus that are capable of preventing the composition of generated gas in a gas phase part of each circulation tank from reaching a flammability limit to reduce a bad effect of a remaining dissolved gas in electrolyte on gas purity even when an electrolyte exchange is carried out between an anode side circulation tank and a cathode side circulation tank. In the gas production method of producing oxygen gas and hydrogen gas by electrolyzing electrolyte which is alkaline water by means of an electrolysis vessel, the electrolyte is depressurized when an electrolyte on the anode side and an electrolyte on the cathode side are exchanged.
Resumen de: WO2025012277A1
The invention relates to a method for the preparation of H2 from NH3. NH3 is introduced into a fixed-bed reactor at a gas temperature in the range from 550 to 850°C, in which fixed-bed reactor NH3 is decomposed on an NH3 decomposition catalyst partly into H2 and N2. The gas mixture obtained in this manner is discharged from the fixed-bed reactor at a gas temperature in the range from 300 to 700°C, is heated to a temperature in the range from 550 to 700°C and is then introduced into a tubular reactor in which further NH3 is decomposed on a nickel-based NH3 decomposition catalyst into H2 and N2. The gas mixture obtained in this manner is discharged from the tubular reactor at a gas temperature in the range from 550 to 750°C.
Resumen de: CN121451234A
本发明提供一种低铂‑镍铁氮复合自支撑电极,所述的低铂‑镍铁氮复合自支撑电极通过如下方法制备:以铂片作为阳极,镍片作为阴极,阳极与阴极间距为2~3 cm,以含有三氯化铁和三聚氰胺的盐酸水溶液为电解液,在恒定电压10~30 V、温度40~60 ℃的条件下,进行电化学阳极氧化和阴极电沉积耦合反应1~5 h,在阴极沉积得到所述低铂‑镍铁氮复合自支撑电极;该方法在控制低铂沉积量的同时,复合了镍、铁和氮元素,增加了自支撑催化剂的双功能性,避免了催化剂的团聚或脱落的问题,增强了催化活性,在工业化应用方面具有广阔的应用前景。
Resumen de: WO2026023125A1
This hydrogen production system comprises: a hydrogen compound member; a water supply member for supplying water to the hydrogen compound member; and a heat recovery device for recovering adsorption heat that is generated when hydrogen, which is generated by decomposing some of water into hydrogen and oxygen in the presence of the hydrogen compound member, is adsorbed to the hydrogen compound member. This hydrocarbon production system comprises: a hydrogen compound member; a water supply member for supplying water to the hydrogen compound member; a heat recovery device for recovering adsorption heat that is generated when hydrogen, which is generated by decomposing some of water into hydrogen and oxygen in the presence of the hydrogen compound member, is adsorbed to the hydrogen compound member; a heating device for heating the hydrogen compound member to which hydrogen is adsorbed; and a gas supply device for supplying a carbon dioxide-containing gas that contains carbon dioxide to the hydrogen compound member.
Resumen de: CN121451213A
本发明提供了一种电解制氢斥固阴极及其改性方法和应用,改性方法包括以下步骤:对HER电极进行预处理,去除HER电极表面的有机物和氧化层,得到预处理后的HER电极;将预处理后的HER电极浸渍在含有银离子的电镀液或化学镀液中进行电镀或者化学镀,使银颗粒沉积在HER电极的表面,得到改性的电解制氢斥固阴极。
Resumen de: CN120659909A
An electrochemical cell stack (1) comprising a plurality of cells (2) separated from one another by bipolar plates (5, 5 '), where each cell (2) is formed by two half-cells (3, 4) between which a membrane (6) surrounded by a support frame (7) is arranged, and where a porous transport layer (10, 11) is present in each half-cell (3, 4). The support frame (7) describes a step shape having two adjacent cross-sectional areas (12, 13), in which the edge (18) of the membrane (6) lies in a step (17) formed by the cross-sectional areas (12, 13) and the porous transport layer (10) of the half-cell (3) extends into the step (17), and in which the porous transport layer (10) of the half-cell (3) extends into the step (17). According to the invention, the support frame (7) comprises at least one sealing arrangement (15) injection molded onto the support frame (7) and comprising an electrically insulating sealing material, according to the invention, the sealing arrangement (15) comprises three sealing regions (19, 20, 21), each having at least one sealing lip (22, 22 '), in particular a first sealing region (19) and a second sealing region (20) and a third sealing region (21), which are assigned to narrower regions of the two cross-sectional regions (12, 13) facing the membrane (6), the first sealing region and the second sealing region each contact exactly one bipolar plate (5, 5 '), and the third sealing region is located on a side of the support frame (7) facing away from the step (17)
Resumen de: AU2023408768A1
A method of hydrogen production includes providing a solution and immersing a device in the solution. The device includes a substrate having a surface, an array of conductive projections supported by the substrate and extending outward from the surface of the substrate, and a plurality of catalyst nanoparticles disposed over the array of conductive projections. The solution includes dissolved sodium chloride (NaCl).
Resumen de: CN120677016A
Provided herein are water-reactive aluminum compositions comprising aluminum or an alloy thereof and an activating metal alloy (e.g., a non-eutectic activating metal alloy comprising bismuth, tin, indium, and gallium; or an activating metal alloy comprising bismuth, tin and indium). Some water-reactive aluminum compositions provided herein are free of gallium. Also provided herein are methods of activating aluminum to provide a water-reactive aluminum composition. Also provided are fuel mixtures comprising the water-reactive aluminum composition described herein and a water-reactive aluminum composition having an increased gallium content; and methods of providing hydrogen and/or steam using the water-reactive aluminum compositions described herein.
Resumen de: CN121446516A
本发明涉及制氢技术领域,公开一种氨分解制氢催化剂的制备方法及应用,包括以超细纳米为基础载体,通过并流共沉淀法引入助剂金属氧化物进行改性,再负载活性组分Ni和贵金属助剂制成。其制备方法关键在于:先采用回流法合成超细纳米悬浮液,再与助剂金属盐混合,通过并流共沉淀形成混合凝胶,经老化、洗涤、干燥、焙烧得到高比表面积、高热稳定性的催化剂载体,最后通过分步浸渍法负载活性金属组分。该催化剂在氨分解制氢反应中,尤其在450‑750℃、1‑3 MPa的加压条件下,表现出优异的低温活性、高氨转化率和长周期稳定性,适用于固定床反应器中的高效制氢过程。
Resumen de: CN121449911A
本发明提供的技术方案为,一种铁基金属有机框架催化剂的制备方法,制备凝胶状前体,所述凝胶状前体由含铁盐的溶液和含有机配体的溶液搅拌混合而成;(2)将铁源浸泡在制得的所述凝胶状前体中,采用微波加热法制得最终的催化剂。本发明的优点在于,通过金属铁与有机配体的定向配位构建稳定框架结构,在实现高比表面积,提供丰富且稳定的活性位点的同时,有效优化铁位点的电子结构,协同提升氧析出反应活性和催化剂稳定性。本发明的制备方法快速,绿色、温和环保,且可以放大规模生产。
Resumen de: CN116491864A
The invention is applicable to the technical field of cleaning appliances, and discloses a bottom cover assembly, which seals the bottom of an integrated water tank comprising a clear water tank and a sewage tank, and comprises: an electricity taking access device for connecting a water electrolysis module arranged in the clear water tank to an external power supply interface of the water tank; the upper surface of the bottom cover middle frame seals the clear water tank and/or the sewage tank, the lower surface of the bottom cover middle frame defines a wiring cavity used for connection of the electricity taking access device, the lower surface of the bottom cover middle frame is provided with a bearing ring rib used for supporting the weight of the integrated water tank, and the electricity taking access device is installed on the upper surface or the lower surface of the bottom cover middle frame. The invention further discloses the integrated water tank comprising the bottom cover assembly. The electricity taking access device arranged on the bottom cover assembly and used for taking electricity from the water electrolysis module is far away from the clear water outlet, so that the short circuit of the electricity taking access device caused by water leakage is avoided; the bottom cover assembly not only ensures complete insulation and isolation of the water tank and the electricity taking electrode of the water electrolysis module, but also ensures continuous maintainabi
Resumen de: CN121447048A
本发明提出了一种3D PtNi多枝纳米结构及其制备方法和应用,所述制备方法包括以下步骤:将19‑20mg 乙酰丙酮铂、25‑26mg乙酰丙酮镍、31‑32mg 十六烷基三甲基氯化铵和 90mg葡萄糖超声分散于20mL油胺中,得到溶液A,超声时间大于1.5h;将将溶液A在密闭条件下加热反应后,自然冷却至室温,得到溶液B;将溶液B离心得到中间产物,中间产物经洗涤后,在真空环境下干燥,得到3D PtNi多枝纳米结构。本发明的3D PtNi多枝纳米结构作为电催化剂具有优异的析氢性能,表现出超低过电位、超高质量活性、双电层电容以及稳定性。
Resumen de: CN121451211A
本发明属于电解水制氢技术领域,公开了一种阴离子交换膜电解水膜电极组件及其制备方法。该阴离子交换膜电解水膜电极组件包括阴离子交换膜、阳极气体扩散电极和阴极气体扩散电极,其中:阳极气体扩散电极包括阳极催化层和阳极气体扩散层,阴极气体扩散电极包括阴极催化层和阴极气体扩散层;阳极催化层包括第一阳极催化层和第二阳极催化层,第一阳极催化层和第二阳极催化层由内至外依次附着于阳极扩散层的表面,且第一阳极催化层的孔径大于第二阳极催化层的孔径。本发明通过设置第一阳极催化层和第二阳极催化层,形成了孔径梯度分布的阳极催化层结构,同时提高了该阴离子交换膜电解水膜电极组件的活性与稳定性。
Resumen de: DE102024207270A1
Die Erfindung betrifft ein Verfahren zum Betreiben eines Elektrolysesystems (1), umfassend einen Elektrolysestack (2) mit einer Anode (2.1) und einer Kathode (2.2) sowie einen Elektrolytkreislauf (3), über den der Anode (2.1) ein Elektrolyt, vorzugsweise Wasser oder eine wässrige Lösung, zugeführt wird, wobei in den Elektrolytkreislauf (3) eine Kühleinrichtung (4) integriert ist, mit deren Hilfe der Elektrolyt gekühlt wird, bevor er über den Elektrolytkreislauf (3) erneut der Anode (2.1) zugeführt wird. Das Verfahren zeichnet sich erfindungsgemäß durch folgende Schritte aus:a) Prognostizieren einer maximal verfügbaren Kühlleistung der Kühleinrichtung (4),b) Bestimmen der Elektrolyt-Temperatur im Elektrolytkreislauf (3) stromabwärts der Kühleinrichtung (4) und stromaufwärts einer temperaturkritischen Komponente (5), vorzugsweise eines Ionentauschers, die bzw. der in einem Nebenpfad (6) angeordnet ist, der stromabwärts der Kühleinrichtung (4) über ein Ventil (7) mit dem Elektrolytkreislauf (3) verbundenen ist, wobei die Elektrolyt-Temperatur anhand der in Schritt a) prognostizierten maximal verfügbaren Kühlleistung bestimmt wird,c) Vergleichen der in Schritt b) bestimmten Elektrolyt-Temperatur mit einem vorab definierten Maximalwert sowied) zumindest teilweises Schließen des Ventils (7), wenn der Vergleich in Schritt c) ergibt, dass der Maximalwert überschritten wird.Die Erfindung betrifft ferner ein Elektrolysesystem (1), das zur Durchführung des Verfah
Resumen de: CN121451200A
本发明涉及制氢电解槽技术领域,尤其涉及一种用于碱性水电解槽防气蚀监控系统,包括:气泡分割模块、监控标记模块、防气蚀分析模块、监控分析模块以及气蚀预警模块,气泡分割模块分割并拦截上升气泡,将气蚀作用从电解槽内壁转移至该可更换的分解网上;监控标记模块对分解网进行全域标记,并根据标记存在状态,确定各气蚀分析区域的气蚀均匀表征参量,确定气蚀分析区域的气蚀均匀类型;监控分析模块对应气蚀分析区域的监控分析方式,气蚀预警模块根据判定结果发出预警,本发明对气蚀稳定区域保持高效监测以优化资源,对波动区域则深入分析内应力分布以诊断根源;通过动态调整分解网水平位置,实现气蚀磨损的主动均衡化管理。
Resumen de: CN121451204A
本发明涉及一种提升合成气电解效率的鱼骨型流场固体氧化物电解槽几何结构及其工作方法,其特征在于:其中提升合成气电解效率的鱼骨型流场固体氧化物电解槽几何结构包括相对设置的呈现鱼骨型的阴极流场和阳极流场,以及阴阳流场之间的隔层,所述的阴极流场及阳极流场的对角线设计为中空流道,对角线中空流道对称分布直型流道。阴阳极流场的其余部分形成连接体。该流道结构设计合理,有利于改善反应气的传输效率和分布均匀性,提高电解槽的工作性能。
Resumen de: CN121451216A
本发明提供一种用于电解海水的耐氯腐蚀阴极及其制备方法和应用。所述制备方法包括如下步骤:S1、将钴盐、镍盐、形貌调控剂和结构导向剂按照摩尔比为(1~2.5):(1~2.5):(8~12):(6~10)溶解于溶剂中,搅拌形成第一溶液;S2、将钛网和第一溶液在100~150℃下进行水热反应,以在钛网上原位生长形貌为纳米针阵列的CoNi层状双氢氧化物;S3、将硒粉和还原剂按照摩尔比1:0.8~1.5溶解于溶剂中搅拌形成第二溶液;S4、将原位生长有CoNi层状双氢氧化物的钛网和第二溶液在150~190℃下进行水热反应,以在钛网上原位生长形貌为纳米针阵列的钴镍双金属硒化物,得到耐氯腐蚀阴极。
Resumen de: CN121451236A
本发明属于电解水制氢催化剂的技术领域,特别涉及一种导电MOF负载金属纳米颗粒复合材料及其制备方法和应用。所述导电MOF负载金属纳米颗粒复合材料,包括载体和该载体负载的金属纳米颗粒,所述载体为导电MOF,所述金属纳米颗粒为铂、钯、铁、铱、钌、钼和银中至少一种;其制备方法为将金属乙酰丙酮盐与导电MOF在醇溶液中直接搅拌处理,即可制得目标产物。该制备方法条件非常温和,在实现对所负载的金属离子还原的同时能够保持导电MOF材料的结构完整性,避免导电MOF发生部分碳化或金属节点还原的问题,有效保持金属/MOF界面的微观结构。该材料作为电解水析氢催化剂使用时,可获得优异的电解水析氢催化表现。
Resumen de: CN121451235A
本发明公开了一种钴铜基析氧电催化剂及其制备方法与应用,属于电催化水分解技术领域,将泡沫镍加入到含有钴源和铜源的水溶液中,在140℃进行水热反应,经过冷却、洗涤和干燥,得到CoCuOH/Co3O4复合材料,热处理,冷却后得到CuO/Co3O4复合材料,将其浸入植酸溶液中刻蚀5h,经过洗涤和干燥后获得Cu2O/Co3O4复合材料;通过硼氢化钠溶液进行还原处理,经过洗涤和干燥后得到钴铜基析氧电催化剂,本发明的钴铜基析氧电催化剂在析氧反应中于100 mA·cm‑2电流密度下可持续运行450小时以上,由其组装的全水分解电解槽在同等电流密度下可稳定运行超过560小时,展现出优异的耐久性与实际应用潜力。
Resumen de: CN121449016A
本发明公开了一种由氰基桥联高熵材料及其制备方法和应用。由氰基桥联的高熵材料的制备方法包括如下步骤:步骤1:将乙酸锰、乙酸钴、乙酸铜、乙酸锌溶解在超纯水中,加入PVP、柠檬酸钠制成A液;步骤2:将镍氰酸钾溶在超纯水里配成B液,待溶解后将B液倒进装有A液的容器中,待两者混合后通入氩气排出容器中的空气后密封,得到AB混合液;步骤3:将装有AB混合液的容器转移至水热反应釜中,于50‑80℃加热反应14‑18小时,然后洗涤、干燥得到由氰基桥联的高熵材料。本发明提供了所述的由氰基桥联的高熵材料作为光催化剂在可见光光催化分解水制氢中的应用,有效提高了光解水制氢的性能。
Resumen de: CN121451229A
本发明属于析氢电极技术领域,公开了一种高催化活性的析氢电极材料及其制备方法和应用,制备方法包括以下步骤:步骤1,清洗泡沫镍;步骤2,通过水热法在泡沫镍上制备钨铁铬共掺杂的羟基氟化钴/泡沫镍前驱体WFeCrCo(OH)F/NF;步骤3,将步骤2得到的WFeCrCo(OH)F/NF和次磷酸钠粉末分别放置在陶瓷舟的两个不同位置,次磷酸钠粉末位于管式炉的上游侧,在保护气体环境下保温,然后自然冷却到室温,得到钨铁铬共掺杂的磷化钴复合电极材料WFeCr‑CoP/NF。本发明通过钨、铁、铬三种元素的协同掺杂,提高了镍基析氢电极材料的催化活性。
Resumen de: CN121451205A
本发明公开了一种用于碱水电解的夹层供液器件及电解槽。所述夹层供液器件包括框架、夹层支撑条和下排进液孔,框架两侧分别与多孔隔膜贴合,形成供液夹层;夹层支撑条为多个平行排列、与框架上下边缘相接的波浪形分隔条,将供液夹层分隔成多个纵向供液通道;下排进液孔开设在框架下边框上,向上与各个纵向供液通道相接。所述夹层供液器件配套设有两块方形端板及双极板,构成完整的进液通道以及氢侧和氧侧的气液流出通道。本发明通过向供液夹层内泵入电解液,使得电解液均匀充满各个纵向供液通道,并向两侧的阴极和阳极表面渗透,实现水平方向全界面均匀供液。
Resumen de: CN121446548A
本发明属于新能源与光催化材料技术领域,具体涉及集吸湿、光解水制氢、储氢功能的TiO2/g‑C3N4/MOF复合结构及制备和应用。所述复合结构包括依次层叠的基材、TiO2底层、TiO2/g‑C3N4复合光催化中间层、TiO2保护/种子层与MOF吸湿储氢层;MOF吸湿储氢层吸附空气中水分形成MOF·H2O,光照下经TiO2保护/种子层的纳米通道将水分子传递至TiO2/g‑C3N4复合光催化中间层,触发H2生成,氢气被MOF多孔结构暂存或输出。该复合结构可构筑于金属、玻璃、陶瓷或工程塑料基材表面,并在相对湿度≥20%条件下运行,无需液态水或高压储氢瓶,适用于无人机机翼、车载平台与分布式固态制氢系统。
Resumen de: CN121451232A
本发明公开了一种镍合金电极及其制备方法和应用,该制备方法包括:将镍集流体置于电镀液中进行电镀,以在镍集流体表面形成镍合金层,其中,电镀液包括镍盐、钴盐、铬盐、亚铁盐和助剂,其中,镍盐在电镀液中的浓度为85~115g/L,钴盐在电镀液中的浓度为15~25g/L、铬盐在电镀液中的浓度5~15g/L,亚铁盐在电镀液中的浓度为3~7g/L,且镍合金层中镍与掺杂元素钴、铬、铁的原子比≥2.8,电镀液的pH值为3~5。采用特定配方的电镀液,通过电沉积法制备了Co、Cr、Fe元素掺杂的镍基合金层,实现了基底与催化层之间的原子级结合,不仅具有优异的界面结合强度,还表现出良好的耐久性。
Resumen de: CN121446360A
本发明涉及氢气泡水制备装置技术领域,具体是一种电解水生成纳米氢气泡水的装置及方法,包括机架,机架上从左往右依次固定有进水调节管、文丘里管、导流管和特斯拉阀,进水调节管、文丘里管、导流管和特斯拉阀内部连通以形成连续流路,进水调节管的一端设置有多个延伸至文丘里管入口处并共同围成可变出水口部的调节片,多个调节片通过第一驱动机构驱动能同步进行径向的扩张与收缩运动,以改变可变出水口部的截面积,本发明通过设置“动态文丘里效应初级破碎、联动机械搅拌二级破碎、高速剪切纳米化、特斯拉阀对撞均质”的完整的、逐级递进的处理工序,最终生成纳米氢气泡水中的氢气浓度显著提高,生成的气泡平均粒径更小,粒径分布范围更集中。
Resumen de: TW202507075A
Provided is a method of manufacturing an anion exchange membrane water electrolysis system exhibiting improved durability and efficiency, along with excellent water electrolysis performance.
Resumen de: CN121451202A
本发明公开了一种基于塔式聚光集热发电装置和压缩蒸汽制冷循环系统的SOEC电解水制氢系统,利用电解槽出口的高温气体预热进入电解槽的空气和氢气,加热纯水变为水蒸汽进行电解和带动发电机发电;所述塔式聚光集热发电系统产生的高温、热量和产生供给SOEC电解水系统电解槽进行电解制氢;所述压缩蒸汽制冷循环系统通过回收热量对进入SOEC电解水系统电解槽的纯水进行预热;将SOEC电解水系统、塔式聚光集热发电系统和压缩蒸汽制冷循环系统充分结合,使电解槽始终处于最佳运行温度从而提高电解效率,成功实现产氢、储热和发电三者的完美结合,降低新能源发电功率波动对整个系统的影响,从而提高整个系统运行的稳定性、可靠性和连续性。
Resumen de: CN121451221A
本发明公开了一种镍基析氧电极及其制备方法和应用,该镍基析氧电极的制备方法包括以下步骤:(1)将基体进行预处理;(2)将镍盐和氯盐溶于水中,超声混合后得到混合液;(3)将预处理后的基体置于混合液中进行脉冲电沉积,制备电催化剂;(4)将沉积有电催化剂的基体用水和有机溶剂进行清洗,干燥后即得镍基析氧电极。本发明中的镍基析氧电极的制备方法原料来源广泛,成本低廉,制备工艺操作简单,反应时间短,易于实现规模化放大,特别适用于碱性水电解制氢的工业生产中;且制得的镍基析氧电极在具有低的析氧过电位的同时,还能保证催化剂涂层与基体之间具有较强的结合力,提高电极的使用寿命。
Resumen de: CN121451244A
本发明涉及分离器技术领域,尤其是涉及一种用于碱性电解水制氢的多级旋流—重力复合式氢水分离器,包括内部具有封闭空腔体的分离罐,所述分离罐上设置有与空腔体连通的氢水混合液进口管、出气管和回流管,所述空腔体内由上而下依次设置有旋流区、过渡缓冲区和重力沉降区,所述旋流区用于使混合液旋流并分离气体与液体,所述过渡缓冲区用于减缓液体流动速度,并去除液体内残留的小气泡,使用时,通过分离罐的封闭空腔体内由上而下形成旋流区、过渡缓冲区和重力沉降区,输入重力沉降区内的混合液,实现气上液下,上升气体携带少量液体过渡缓冲区缓冲并去除液体内残留的小气泡,再进入旋流区内旋流并分离气体与液体。
Resumen de: CN121459968A
本发明公开了一种基于原位拉曼光谱‑分子动力学耦合模拟的光催化制氢界面反应动态调控方法,涉及光催化制氢技术领域。该方法先搭建含耐腐蚀透光反应池的原位拉曼系统,实时监测CdS光腐蚀引发的晶格应力变化、TiO2晶相转变等微观信息,捕捉·OH等中间体特征峰及O‑H键振动频率偏移;再结合光谱数据构建包含催化剂表面、吸附水分子的分子动力学模型,通过从头算模拟获取IrRu单原子位点对水取向的影响、M‑H键长演变等原子尺度机理;随后用数据融合算法关联光谱特征峰强度与模拟能量变化,锁定反应决速步;最终针对性调控,如构建异质结抑制CdS光腐蚀、调节层状催化剂层间距强化电荷分离,协同优化反应温度与氢气分压。
Resumen de: CN121451243A
本申请公开了一种电解水制氢系统的控制指令确定方法、系统及电子设备。其中,该方法包括:获取在当前数据采集周期内电解水制氢系统的可再生能源发电设备的第一发电量,电解水制氢系统的储能设备的第一荷电状态,以及电解水制氢系统的电解槽的第一运行参数和第一退化特征参数;基于第一运行参数和第一退化特征参数,确定电解槽的第一预测剩余寿命;基于第一发电量,第一荷电状态,以及第一预测剩余寿命,确定电解水制氢系统的预测控制指令,其中,预测控制指令中包括电解槽的目标运行电流和储能设备的目标充放电功率。本申请解决了相关技术中存在的电解水制氢系统的预测控制指令确定结果不准确的技术问题。
Resumen de: CN121451227A
本发明涉及一种碱性体系电解水阳极催化剂,是以泡沫镍为载体,于添加可溶性氯盐作为腐蚀剂的可溶性亚铁盐和可溶性镍盐混合电解质溶液中进行电沉积‑电腐蚀反应,原位生长镍铁层状双氢氧化物形成NiFe‑LDH/NF复合材料,再以复合材料于添加可溶性氯盐作为腐蚀剂的可溶性镁盐碱性水溶液中进行水热反应,掺杂金属镁构建的NiFeMg‑LDH/NF复合催化剂。本发明复合催化剂作为自支撑电极材料用于碱性体系水电解反应,具有良好的OER活性和稳定性,特别是高电流密度下的长期稳定性。
Resumen de: CN121446389A
本发明提出一种集成光照追寻与超声强化的柔性光催化制氢氧系统及方法,系统的驱动装置根据辐照度信息采集仪采集的太阳光照射强度信息驱动移动组件运动,移动组件带动调整菲涅尔透镜使其达到最佳光照角度;帕尔贴元件表面纳米颗粒催化剂接收来自菲涅尔透镜的太阳光,将水分解为氢气和氧气,超声换能器产生催化作用促进分解,产生的氢气由多孔氢气吸附材料吸附保存,帕尔贴元件两极产生温差从而产生电能。本发明利用太阳能作为能量来源制造氢气、氧气,提高太阳能的利用效率,能够解决目前渔业生产中的问题,并为未来海洋勘探、出海作业等提供生活保障。
Resumen de: CN121446384A
本发明提供了一种光催化制氢与高值化学品联产的系统与方法,属于光催化及绿色能源化工技术领域。所述系统和方法的核心在于利用双功能光催化剂,在光能驱动下,同步催化还原制氢与有机底物选择性氧化生成高值化学品,实现“氢化联产”。所述系统的运行模式包括利用光伏/风电转化的电能驱动特定波长LED光源的全天候模式,以及直接利用太阳光的户外模式。本发明有效解决了传统光催化制氢效率低、成本高的问题,通过联产高附加值化学品,显著提升了过程的经济性与可持续性。
Resumen de: CN121446434A
一种振动式硅碳棒解水剂制氢装置,属于制氢技术领域,主要由料箱、解水剂料、供料管、电动阀、外壳、制氢管、硅碳棒、水箱、供水管、回收罐、蒸汽发生器、电热圈、蒸汽管、振动电机、机架、弹簧、氢气出口、等组成,其特征是:料箱内装解水剂料,供料管上接料箱中部串连两个电动阀下接制氢管左端进料口,制氢管左端设有进料口和氢气出口右端设有出料口,外壳内通过制氢管硅碳棒放在制氢管下面,振动电机固定在机架上。工作过程是:解水剂料由料箱内经电动阀进入制氢管内,受热后与水蒸汽接触发生化学反应产生氢。优点有:1成本低于现有工业制氢;2无污染;3原料充足易得。
Resumen de: WO2026023894A1
The present invention relates to a separator which comprises a porous substrate and a mesh substrate laminated on one surface of the porous substrate, and which solves the problem of pinholes occurring in a conventional commercial separator by specifying the porosity of the porous substrate and also has high chemical/mechanical strength while maintaining the pore characteristics of the porous substrate and, simultaneously, can maintain a high level of electrolysis efficiency.
Resumen de: TW202508960A
Method and system for producing a hydrogen product from ammonia, comprising: optionally at least one pre-cracking reactor, such as an adiabatic pre-cracking reactor, arranged to receive an ammonia feed stream, thereby producing a partly converted ammonia feed stream comprising ammonia, hydrogen and nitrogen; an ammonia cracking reactor such as an electrically heated reactor. The reactor is arranged to receive the partly converted ammonia feed stream or the ammonia feed stream for producing an effluent gas stream comprising hydrogen and nitrogen and optionally also unconverted ammonia; and a hydrogen recovery unit arranged to receive the effluent gas stream for producing the hydrogen product and an off-gas stream comprising hydrogen, nitrogen and optionally unconverted ammonia.
Resumen de: MX2025014062A
A system and method of making hydrogen from water. A cylindrical reaction vessel is provided with an outer shell, a central shaft, and one or more concentric inner tubes separated by annular spaces. Water is delivered to the annular spaces by a water pump through an inlet defined in the reaction vessel. The water courses along a tortuous flow path. That path begins at an inner annular space around a central shaft. It ends at an outer annular space. The water emerges from the reaction vessel through an outlet associated with a manifold. A high-frequency vibratory stimulus is applied to the reaction vessel and water. Water molecules are dissociated into hydrogen molecules and oxygen atoms. These reaction products are delivered through the manifold along an effluent flow path to a receiving pressure vessel before deployment to a sub-assembly for harnessing clean energy.
Resumen de: CN121451226A
本发明涉及电催化剂制备技术领域,且公开了硼原子改性金属有机框架电催化剂的制备方法及其应用,包括以下步骤:步骤一、制备金属有机框架材料:将2‑甲基咪唑溶于溶剂中得到溶液A,将六水合硝酸钴或六水合硝酸锌溶于溶剂中得到溶液B,将溶液A滴入溶液B中,搅拌后离心,洗涤沉淀并干燥,得到ZIF‑67或ZIF‑8;步骤二、制备金属有机框架材料溶液:将上述金属有机框架材料溶于溶剂中,超声处理得到溶液C。该硼原子改性金属有机框架电催化剂的制备方法及其应用,制备方法简单高效、成本低廉易实现,所合成的电催化剂在OER反应中具有更低的过电位和电化学阻抗,提升了金属有机框架材料的电催化性能。
Resumen de: CN121451240A
本申请公开了一种用于制备碱性水电解复合隔膜的方法及复合隔膜,属于隔膜制备技术领域,所述制备碱性水电解复合隔膜方法中,包括步骤1):将聚苯硫醚编织网浸渍于乳白色铸膜液,浸渍预定第一时间后取出,生成浸渍后的聚苯硫醚编织网;步骤2):采用预设间距的刮刀刮涂浸渍后的聚苯硫醚编织网,生成液体湿膜;步骤3):将液体湿膜放入第一凝固浴中,在第一凝固条件下进行凝固,生成成形的白色薄膜;步骤4):将成形的白色薄膜放入第二凝固浴中,在第二凝固条件下进行凝固,生成碱性水电解复合隔膜。通过调节有机凝固浴的组分实现对隔膜内部微观结构的调控,且制备的复合隔膜具有面电阻低及机械性能优异的特点。
Resumen de: DE102025128171A1
Die vorliegende Offenbarung betrifft eine Elektrolyseur-Batteriezelle, ein Herstellungsverfahren und eine Vorrichtung zum Erzeugen von Wasserstoffgas aus erneuerbarer Energie. Die Elektrolyseur-Batteriezelle umfasst eine Membranbaugruppe, die im zentralen Bereich der Elektrolyseur-Batteriezelle angeordnet ist; eine Anodenkomponente und eine Kathodenkomponente, die jeweils auf beiden Seiten der Membranbaugruppe angeordnet sind; wobei die Anodenkomponente eine Anodentransportstruktur umfasst, um Fluid innerhalb des Elektrolyseurs bei einer ersten Geschwindigkeit in der Anodentransportstruktur zu transportieren; wobei die Kathodenkomponente eine Kathodentransportstruktur umfasst, um Fluid innerhalb des Elektrolyseurs bei einer zweiten Geschwindigkeit in der Kathodentransportstruktur zu transportieren; wobei die Kathodentransportstruktur sich von der Anodentransportstruktur unterscheidet und der Durchschnittswert der zweiten Geschwindigkeit größer als der Durchschnittswert der ersten Geschwindigkeit ist. Die Lösung der vorliegenden Offenbarung verbessert die Transportrate des Fluids, unterstützt die Entladung der Gasprodukte auf der Kathodenseite und verhindert, dass die Gasprodukte auf der Kathodenseite die Katalysatorschicht bedecken, sodass die Reaktanten schnell die Elektrodenoberfläche erreichen können, wodurch die Reaktionsrate des elektrolysierten Wassers gewährleistet und die Leistung der Elektrolyseur-Batterie verbessert wird.
Resumen de: CN121451239A
本发明公开了一种带有功能涂层的长寿命碱性电解水复合隔膜极其制备方法。本发明由基底材料和复合涂层构成,所述复合涂层包括内部复合层和外部功能涂层构成;所述基底材料包括表面改性的聚苯硫醚织物PPS;所述外部功能涂层包括含有磺酸基团的聚合物和含羟基的聚合物。本发明考虑对聚苯硫醚支撑织物表面进行强氧化处理,增加表面粗糙度,同时在表面引入‑COOH、‑OH、亚砜基等活性基团,降低网格布表面张力,增强涂布聚支撑织物与浆料的浸润速度和成型后支撑织物与涂层的结合力,从而增强复合隔膜的寿命。
Resumen de: CN121451209A
本发明涉及电解制氢技术领域,具体公开了一体化ALK矩形波纹电极流场,包括极板、密封圈、矩形波纹电极网、隔膜,所述矩形波纹电极网冲压扩张成型,还公开了一体化ALK矩形波纹电极流场的制备方法,包括以下步骤:S1、制备微孔矩形波纹电极网,S2、极板流道加工,S3、将密封圈置于极板与矩形波纹电极网的接触面边缘,利用极板的凹槽和密封圈本身弹性固定,S4、进行组合连接固定,形成所述一体化ALK矩形波纹电极流场,本发明形成的一体化ALK矩形波纹电极流场将流场与电极集成整体,显著降低接触电阻,提升结构稳定性,有效抑制电化学腐蚀风险,提升了机械性能,降低了成本。
Resumen de: CN121451215A
本发明提供了一种梯度孔NiFe LDH碱性电解水制氢电极及其制备方法与应用。采用非传统三电极体系,镍板作为牺牲阳极提供Ni源,不锈钢板作为自腐蚀电极提供Fe源,金属网(镍网或不锈钢网)作为阴极同时发生析氢反应和电沉积反应,利用梯度电流密度控制气泡密度并调节Ni、Fe的电沉积速率,以气泡形核‑生长‑脱附的动态行为作为“动态模板”,在阴极表面原位共沉积形成梯度分布的多孔结构NiFe LDH。本发明的梯度孔NiFe LDH碱性电解水制氢电极用于电解水制氢过程,析氢活性优异,且在工况环境下稳定运行超500h性能无衰减,满足其在碱性电解水制氢领域高性能、长寿命使用需求。
Resumen de: CN121451218A
本发明公开了一种高比表面积高熵氧化物催化剂及其制备方法和应用,属于电催化材料及其制备技术领域。所述高比表面积高熵氧化物催化剂化学式为(FeCoNiMnCr)O,比表面积为50~250 m2 g‑1,孔径为7~15nm,孔体积0.35~1.0cm3 g‑1,所述高比表面积高熵氧化物催化剂含有均匀分布的Fe、Co、Ni、Mn、Cr五种金属元素。本发明(FeCoNiMnCr)O高熵氧化物析氧催化剂,比表面积大,在电解水析氧反应过程中能提供更多的活性位点,氧气更容易析出,提高了催化剂的析氧催化活性,解决了现有技术中高熵氧化物的比表面积较低,电析氧反应时提供的活性位点数量不够的技术难题。
Resumen de: CN121451212A
本发明公开了一种粉网复合气体扩散层,其由钛粉和钛网骨架通过冶金结合制成,厚度为20µm~100µm、孔隙率为20%~50%、平均孔径为5µm~35µm、拉伸强度为200MPa~500MPa,本发明还公开了该粉网复合气体扩散层的制备方法,步骤一、将钛网骨架平铺后用钛粉进行填充,形成松装复合结构;步骤二、将步骤一中得到的松装复合结构进行真空压力烧结并随炉冷却,最终获得粉网复合气体扩散层。本发明公开的粉网复合气体扩散层具备超薄特性,可大幅度减少镀铂量,从而降低电解水制氢的成本,其中的钛网骨架能够有效增强气体扩散层的机械强度,避免了扩散层在装配操作过程中发生变形的问题。
Resumen de: CN121451230A
本发明属于催化剂技术领域,尤其涉及一种高熵氧化物复合镍铁层状双氢氧化物催化剂及其制备方法与应用。与现有技术相比,本发明提供的高熵氧化物复合镍铁层状双氢氧化物催化剂通过在镍铁层状双氢氧化物设置高熵氧化物保护层作为一种路易斯酸层,高熵氧化物层中的高价元素具有更强的亲电性,路易斯酸度更高,可通过氧化物的高熵化调控路易斯酸度,吸附OH‑抑制氯化学反应,同时还可通过Zn组分的溶出增加表面空位增加OH‑,从而可使催化剂在电解海水OER反应中排斥Cl‑,提高催化剂催化活性和耐久性。
Resumen de: US2024294395A1
A process for preparing metal oxide comprising (i) at least one metal chosen from nickel and cobalt and optionally (ii) at least one metal chosen from manganese, lithium and aluminum. The process comprising:reacting a metal sulfate comprising (i) at least one metal chosen from nickel and cobalt and optionally (ii) at least one metal chosen from manganese, lithium and aluminum with lithium hydroxide and optionally a chelating agent to obtain a solid comprising a metal hydroxide comprising (i) at least one metal chosen from nickel and cobalt and optionally (ii) at least one metal chosen from manganese, lithium and aluminum, and a liquid comprising lithium sulfate, the metal sulfate comprising (i) at least one metal chosen from nickel and cobalt and optionally (ii) at least one metal chosen from manganese, lithium and aluminum;separating the liquid and the solid from one another to obtain the metal hydroxide;submitting the liquid comprising lithium sulfate to an electromembrane process for converting the lithium sulfate into lithium hydroxide; andreusing at least a first portion of said lithium hydroxide obtained by the electromembrane process for reacting with the metal sulfate;reacting at least a second portion of said lithium hydroxide obtained by the electromembrane process with the obtained metal hydroxide to obtain a mixture of metal hydroxides; androasting said mixture of metal hydroxides to obtain the metal oxide.
Resumen de: CN121451206A
本发明涉及催化剂技术领域,涉及一种电解水装置、催化剂及其应用。膜电极包括离子交换膜和设于离子交换膜的催化层,催化层包括催化剂,催化剂包括基体及设于基体表面的第一包覆层,基体包括内核及设于内核表面的第二包覆层;第一包覆层包括金属原子、金属单质、金属氧化物、金属合金中的至少一种,金属原子、金属单质、金属氧化物、金属合金中的金属元素包括第一贵金属元素和/或第一过渡金属元素;内核包括合金,合金至少包括M元素和N元素,M元素包括第二贵金属元素或非贵金属元素,N元素包括稀土金属元素或第二过渡金属元素,第一贵金属元素与第二贵金属元素不同;第二包覆层包括M金属。本申请的催化剂具有较好的稳定性和催化活性。
Resumen de: CN121446522A
本发明公开了一种压电极化诱导光生载流子转移的Z型异质结复合催化剂制备方法,利用多铁性BiFeO3和有利的可见光响应CdS纳米片构建了具有主动电子传输特性的Z型异质结构,不仅优化了光吸收能力和能带结构,还降低了界面电阻和光生载流子重组,BiFeO3颗粒与超薄CdS的结合不仅抑制了CdS纳米片的团聚,还有助于提高反应体系的比表面积。本发明利用多铁性BiFeO3和有利的可见光响应CdS纳米片构建了具有主动电子传输特性的Z型异质结构。该活性电子传输系统的构建促进了载流子的分离和传输,为提高光催化制氢反应活性提供了一种新的策略。
Resumen de: CN121451214A
本公开涉及一种PEM电解水膜电极及其制备方法和应用,该制备方法在阳极催化剂浆料中添加了羧甲基纤维素盐和碳纳米管,制得的PEM电解水膜电极具有铱负载量低、活性高、高电流密度下运行稳定的特点,且具有三维多孔道阵列结构,将其用于质子交换膜水电解(PEMWE)制氢时,膜电极的导电性和三相传质性能得到大幅度提高。
Resumen de: CN121451228A
本发明涉及用于电解水的催化剂技术领域,尤其涉及一种金属合金电催化剂及其制备方法,该金属合金电催化剂包括析氧催化剂和析氢催化剂,其中:析氧催化剂包括镍、钴、铜、铁四种元素,且镍、钴、铜、铁四种元素的摩尔比为1:1:1:1;析氢催化剂包括镍、钴、铜、钼四种元素,且镍、钴、铜、钼四种元素的摩尔比8.97:30.41:51.77:8.84。上述的析氢催化剂和析氧催化剂不含贵金属元素,成本低;其制备方法采用大气等离子喷涂技术,适用于工业化推广。
Resumen de: CN121451219A
本发明属于二维纳米材料电催化剂制备技术领域,具体涉及一种非晶态Sr‑CoOOHv超薄纳米片电催化剂及制备方法和应用。本发明通过水热法制备锶掺杂硒化钴纳米带作为基底,并在碱性电解水阳极析氧反应条件下发生原位电化学重构所得。本发明提供的富含钴空位的Sr‑CoOOHv超薄纳米片由于金属钴空位存在不仅能增强钴‑氧共价性活化晶格氧,同时也能提高羟基亲和力填充晶格氧,使得该催化剂在阴离子交换膜电解水制氢工业化应用中展示出优异的催化活性和耐久性。
Resumen de: CA3241482A1
An multi-stage electrolyzer cell is disclosed. The multi-stage electrolyzer cell comprises an anode, a cathode and at least one ion exchange membrane separating the anode and the cathode. The anode and cathode are exposed in the respective anode chamber and cathode chamber. At least one partition is arranged within at least one of the anode and cathode chambers, dividing the at least one chamber into a plurality of process stages. Each of the partitions comprises a feed port, allowing an electrolyte solution to transport sequentially through each of the plurality of process stages. Means are arranged to transport the electrolyte solution through each one of the plurality of process stages. A multi-stage electrolytic method is also disclosed.
Resumen de: KR20260014745A
본 발명은 개질 장치 및 이를 위한 운전 방법에 관한 것으로서, 상기 개질 장치가 암모니아를 저장하는 암모니아 탱크; 연료를 연소시켜 연소 가스를 생성하는 버너; 상기 버너에서 생성된 연소 가스가 통과하는 연소 가스 채널 및 상기 연소 가스 채널과 열 교환되게 형성되고 촉매로 상기 암모니아 탱크로부터 공급받는 암모니아를 수소와 질소로 개질하는 개질 채널을 갖는 개질기; 상기 개질기에서 생성된 수소와 질소를 분리시키는 압력 변동 흡착 장치; 상기 암모니아 탱크와 상기 개질 채널을 연통시키는 개질 채널 공급 경로; 상기 개질기와 상기 압력 변동 흡착 장치를 연통시키는 개질 채널 배출 경로; 질소를 저장하는 질소 탱크; 상기 질소 탱크와 상기 개질 채널 공급 경로를 연통시키는 합류 경로; 상기 개질 채널 공급 경로와 상기 합류 경로 사이 연통 지점에서 유동 방향 및 유량을 제어하는 제1 밸브; 상기 버너로 연료를 공급하는 연료 공급 경로; 상기 개질 채널 배출 경로와 상기 연료 공급 경로를 연통시키는 분기 경로; 및 상기 개질 채널 배출 경로와 상기 분기 경로 사이 연통 지점에서 유동 방향 및 유량을 제어하는 제2 밸브;를 포함함에 따라, 준비 기간을 단축할 수 있고, 안전 사고를 방지할 수 있다.
Resumen de: KR20260014927A
본 발명에 따른, 불활성가스와 압축공기를 주입하여 산소 가스 내 수소의 농도를 제어하는 수전해 시스템은, 물을 전기분해하여, 양극측에서 산소를 포함하는 전해산물을 배출하고, 음극측에서 수소를 포함하는 전해산물을 배출하는 수전해 스택; 상기 수전해 스택의 양극측 전해산물을 입력받아 물과 가스로 분리하고, 상기 분리된 물과 가스를 각각 배출하는 산소측 기액분리기; 제1밸브를 통해 상기 산소측 기액분리기에 소정의 불활성가스를 공급하도록 구성된 불활성가스 공급부; 제2밸브를 통해 상기 산소측 기액분리기에 압축공기를 공급하도록 구성된 압축공기 공급부; 및 상기 수전해 스택에서 전기분해가 수행되는 도중에, 상기 불활성가스 및 상기 압축공기 중 적어도 하나를 상기 산소측 기액분리기로 공급하기 위해 상기 제1밸브 및 상기 제2밸브 중 적어도 하나를 제어하는 제어부를 포함한다.
Resumen de: KR20260015099A
본 발명은 다공성 수송층, 음이온 교환막 및 기체 확산층이 순서대로 적층된 구조체를 준비하는 단계, 상기 기체 확산층으로는 수산화칼륨 수용액을 순환시키면서 상기 다공성 수송층으로는 촉매 전구체 용액을 순환시켜 다공성 수송층 상에 촉매층을 형성하는 단계 및 상기 수산화칼륨 수용액과 촉매 전구체 용액을 제거하고 상기 구조체를 세척하는 단계를 포함하는 막-전극 접합체의 제조방법을 제공한다.
Resumen de: CN121428588A
一种电解水制氢系统及冷启动控制方法,属于电解水制氢技术领域。一种电解水制氢系统,包括电解槽,还包括为所述电解槽提供电能的可调制氢电源,所述可调制氢电源用于向所述电解槽提供交、直流成分可调的电流,其中,直流分量数值大于等于交流分量的最大值,所述直流分量用于参与电解制氢的极化反应,所述交流分量用于对所述电解槽在冷启动过程中进行额外加热。本申请的电解水制氢系统通过特意增加制氢电源输出电流的交流分量占比和/或频率,即增加交流分量所产生的有功功率,使得更多的电源输出功率用于加热电解槽,从而在不改变制氢系统本身的工艺流程和不增加额外系统辅机部件的基础上,大幅提升制氢系统的升温启动性能。
Resumen de: CN121440800A
The embodiment of the invention relates to the technical field of photovoltaic hydrogen production, in particular to a light hydrogen storage system power regulation and control method, a light hydrogen storage system and a storage medium. Smooth filtering is performed on the output power of the photovoltaic module to obtain the photovoltaic power generation power, the charge target value of the PI control energy storage battery is determined according to the charge state value of the energy storage battery and the expected charge working interval, the charge difference value is determined according to the charge target value and the charge state value, and PI control is performed according to the charge difference value. The working power adjusting value of the electrolytic cell is determined, and the smooth and stable target working power value of the electrolytic cell is determined according to the photovoltaic power generation power and the working power adjusting value, so that the working power of the electrolytic cell can be smoothly and stably adjusted according to the target working power value of the electrolytic cell; the condition of large power fluctuation in the electrolytic cell power control process is reduced or avoided, and the service life of the electrolytic cell is prolonged.
Resumen de: AU2024305585A1
The invention relates to an ion-conducting membrane (10) for an electrochemical device, said membrane comprising a layer of a material comprising: - 5% to 30% by weight of a polymer binder and - 70% to 95% by weight of a powdered ceramic, the powdered ceramic comprising ceramic doped with yttrium oxide and/or ceramic doped with cerium oxide. The invention can be used to produce a non-porous membrane for low-temperature electrolysis (0°C to 150°C).
Resumen de: CN121127989A
The purpose of the present invention is to provide: Provided are: an electrolyte membrane for a solid polymer fuel cell, which has excellent proton conductivity; a membrane-electrode assembly comprising the electrolyte membrane for a solid polymer fuel cell; a solid polymer fuel cell comprising the membrane-electrode assembly; and an electrolyte membrane for a solid polymer fuel cell. Various methods for producing a membrane electrode assembly and a solid polymer fuel cell; and an electrolyte membrane for solid polymer water electrolysis. This electrolyte membrane for a solid polymer fuel cell contains a woody or herbaceous microfibrous cellulose, the average fiber width of the woody or herbaceous microfibrous cellulose being 50 nm or less, and the microfibrous cellulose having a phosphorus oxyacid group.
Resumen de: CN121430933A
本发明涉及碱性电解制氢安全防护技术领域,具体公开了一种碱性电解水制氢系统的泄漏防护方法及装置,包括首先获取关键点氢气传感信息与泄漏点氢气感应信息并生成第一泄露监控信息;再基于关键点信息确定泄漏率、泄漏加速度以生成动态风险评估结果,同时确定热点因子并结合动态风险评估结果生成第二泄露监控信息;最终基于双监控信息生成泄露防护结果。本发明解决传统防护依赖静态评估、单一监测导致的误报漏报、响应滞后问题,通过多源信息融合与动态分级控制,提升泄漏防护精准性与及时性,保障碱性电解制氢系统安全高效运行。
Resumen de: CN121428589A
The invention discloses a water electrolysis hydrogen production system, a cascade cold start control method, equipment and a medium, and belongs to the technical field of water electrolysis hydrogen production. The hydrogen production system comprises a plurality of electrolytic bath groups which are communicated with one another, a plurality of electrolytic baths are arranged in each electrolytic bath group, and a plurality of electrolytic bath groups in the plurality of electrolytic bath groups are provided with corresponding electrolyte storage tanks; at least one mixer is arranged between every two adjacent electrolytic cell groups, at least one control valve is arranged at an outlet of each electrolytic cell group, and the outlet of each electrolytic cell group is communicated with the at least one mixer through the control valve; and the control valve is used for controlling the self-circulation temperature rise of the electrolyte in the self electrolytic bath group or the temperature rise of the electrolyte mixed with the electrolyte in other electrolytic bath groups through the mixer. According to the cascade cold start method, the differentiated configuration method is adopted, configuration of the electrolyte storage tank is reduced, and cascade cold start can be achieved by efficiently utilizing waste heat through the method that cold electrolyte and hot electrolyte are mixed for direct heat exchange.
Resumen de: CN121428577A
本发明涉及一种碱性电解水制氢系统低负荷状态下控制氧中氢含量的系统和方法,该系统包括依次连接的电解水单元、气液分离单元、气体纯化单元、储氧缓冲单元、三通控制单元、补气流量控制单元和循环升压单元;所述循环升压单元连接至所述电解水单元,所述三通控制单元还连接有氧气副产品放空单元。本发明系统通过各单元之间的配合可有效降低电解水制氢系统内氧中氢含量,确保电解水制氢系统在较低负荷运行,拓宽了电解水制氢设备的负荷范围。
Resumen de: CN121428572A
The invention discloses a CO2-rich natural gas electro-thermal catalytic coupling reforming method. Methane and excessive carbon dioxide (CO2/CH4gt; the mixed gas obtained in the step (1) is introduced into a cathode of a solid oxide electrolytic tank, and series coupling of three reactions of methane dry reforming, reverse water vapor shift and water electrolysis on the cathode side can be realized by applying external current, so that high CH4 conversion rate, high CO2 conversion rate and high H2 selectivity are obtained. According to the method, the natural gas with high CO2 content is completely converted into the synthesis gas in one step in a single reactor, a high-energy-consumption separation process is avoided, the problems of low CO2 utilization rate, low H2 selectivity, complex process, greenhouse gas emission and the like of a traditional carbon-rich natural gas conversion technology are solved, and the method has the advantages of high efficiency, economy, environmental protection and the like and is suitable for industrial production. The method has a wide application prospect in the fields of conversion and utilization of natural gas and storage of renewable electric energy.
Resumen de: CN121423629A
本发明涉及催化材料技术领域,提供了一种粒径可控的PEM电解水制氢用铂黑催化剂的制备方法。本发明将铂前驱体、溴化物、水和醇混合,得到前驱体混合液;将前驱体混合液和碱溶液混合,得到碱性混合液;然后将碱性混合液在微波条件下进行还原反应,得到所述铂黑催化剂。本发明提供的方法能够实现对铂黑催化剂粒径的有效控制,所得铂黑催化剂粒径均匀,分散性好,活性高,并且操作简单,重复性好,能够实现均一批量化制备。实施例结果表明,将本发明制备的铂黑催化剂作为PEM电解槽膜电极阴极,采用商业氧化铱催化剂作为阳极,在60℃下,电流密度为2A cm‑2时电解电压仅需1.78V,远低于目前商用铂黑和铂碳催化剂。
Resumen de: CN121424582A
本发明属于隔膜技术领域,具体涉及一种纤维素及其衍生物掺杂型复合隔膜及制备方法和应用,制备方法包括以下步骤:将热塑性有机高分子聚合物、纤维素衍生物和金属氧化物纳米颗粒加入有机溶剂中,溶解后加入致孔剂,混匀后消泡处理,得到铸膜液,刮涂,得到液膜;将液膜置于相对湿度为30%~80%的湿空气氛围中进行预相转化,预相转化过程中,湿空气中的水蒸气渗透到液膜中,与液膜中的有机溶剂发生交换,得到湿膜;将湿膜浸入萃取剂中进行相转换,得到纤维素及其衍生物掺杂型复合隔膜。本发明的制备方法不仅能确保隔膜的安全运行,而且显著提升了隔膜的电解效率,在长时间运行的稳定性方面表现优异。
Resumen de: CN121422900A
本发明涉及一种加压氨分解器,解决现有的氨分解器容易造成炉胆变形损坏的问题。包括有反应腔体,反应腔体包括有桶状壳体、上盖、下盖、电加热系统以及测温装置,壳体内设有内套筒隔离件,内套筒隔离件外侧区域形成内套筒隔离腔,内套筒隔离件内侧形成催化反应腔,催化反应腔充装有催化剂。加压氨分解工况下,催化剂在被高温加热下发生个别烧结时,只是在内套筒隔离件壁面发生烧结,使内套筒隔离件壁面局部温度过高,但是内套筒隔离件只是一个内部件,不承压,即使局部损坏,也不影响设备正常使用。内套筒隔离件到壳体有一定距离,局部高温传导不到壳体上,不会损坏壳体,设备生产安全可靠,且整体结构简单,布局紧凑,制造方便。
Resumen de: CN121428598A
本发明涉及一种硼掺杂镍铁层状双氢氧化物电催化阳极及其制备方法和应用,属于电解水制氢技术领域。该硼掺杂镍铁层状双氢氧化物电催化阳极的制备方法,包括以下步骤:将镍盐、铁盐和尿素溶解于水中,得到反应液;将三维金属泡沫基底垂直浸入至反应液中,在密闭环境中进行水热反应,以使三维金属泡沫基底表面原位生长镍铁层状双氢氧化物纳米阵列,得到镍铁层状双氢氧化物电催化阳极;将获得的镍铁层状双氢氧化物电催化阳极浸入硼源溶液进行硼掺杂处理,得到硼掺杂镍铁层状双氢氧化物电催化阳极。该方法制备的电催化阳极在碱性海水中表现出优异的析氧反应活性,并在高电流密度下保持长期稳定性能,适用于高效耐腐蚀的海水电解制氢体系。
Resumen de: CN121422965A
本发明公开了一种缺陷调控的Cu2O光催化剂及其制备方法和应用,涉及光催化剂材料技术领域,制备方法包括以下步骤:将0.1g/L~5g/L的羧甲基纤维素溶于去离子水中,搅拌得到第一溶液;向第一溶液中加入五水硫酸铜,持续搅拌得到第二溶液;将氢氧化钠溶液加入到第二溶液中,持续搅拌得到第三溶液;将抗坏血酸溶液加入到第三溶液中,持续搅拌反应后处理得到Cu2O光催化剂。该制备方法解决了传统方法无法协同调控缺陷与形貌的难题,实现了通过控制高分子浓度来同步调控内部缺陷与材料尺寸的效果。
Resumen de: CN121422951A
本发明涉及一种有序介孔复合氧化物载体的制备方法及应用,涉及无机功能材料与多相催化技术领域。该载体由碱土金属氧化物、稀土金属氧化物和Al₂O₃组成,采用溶剂蒸发诱导自组装法制备。制备过程包括将模板剂、铝源、碱土金属和稀土金属的可溶盐溶于乙醇与稀硝酸的混合溶液,经蒸发自组装形成干凝胶,再经两段式控温焙烧:先在惰性气氛中低温热解,再在低氧浓度气氛中升至1000℃高温处理,最终得到有序介孔复合氧化物载体。该载体热稳定性优异,经历1000℃高温焙烧后仍能保持规整介孔结构、高比表面积和孔容。以其负载Ni、Co活性金属及Mo、W助剂制得的氨分解制氢催化剂,在低温条件下表现出高活性与优良的热稳定性,在200小时长周期运行中性能无衰减。
Resumen de: CN121428600A
本申请涉及一种海水全解水RuSe2‑MoSe2/NF异质结双功能催化剂及其制备方法和应用,属于电解海水电催化技术领域。本申请的双功能催化剂的制备方法,包括以下步骤:(1)将去离子水与无水乙醇混合,磁力搅拌,得到混合溶剂;然后向混合溶剂中加入硼氢化钠与硒粉,搅拌至完全分散,得到混合溶液;再向混合溶液中加入二水合钼酸钠与三氯化钌,通入高纯氮气,置换空气后继续磁力搅拌,得到深棕色前驱体混合液;(2)将预处理后的泡沫镍NF完全浸没于前驱体混合液中,进行水热反应,反应后冷却至室温,取出泡沫镍NF,先去离子水冲洗3~5次,然后用无水乙醇冲洗3~5次,烘干后即得。本申请所提供的双功能催化剂可同时高效催化海水中的析氢反应与析氧反应。
Resumen de: WO2024231574A1
The present invention relates to method for the synthesis of a transition metal catalyst consisting of electrodeposition on a substrate electrode from an electrolyte solution comprising at least one transition metal precursor, wherein the electrodeposition takes places at a deposition current density of 500 to 2000 mA/cm2. The present invention further relates to a transition metal catalyst <b>characterised in that</b> it is stable for at least 30 minutes at a current density of at least 400 mA/cm2 on the substrate electrode.
Resumen de: CN121428590A
本发明公开了一种金修饰的Cu3BiS3基半导体薄膜光电化学水分解光阴极及其制备方法,属于光电化学制氢领域。该光阴极由Mo导电衬底、Cu3BiS3吸收层、CdS缓冲层、TiO2保护层、Au纳米颗粒层及Pt析氢助催化剂依次组成。通过引入具局域表面等离激元效应的Au纳米颗粒,与Cu3BiS3吸收层、宽禁带TiO2及CdS缓冲层协同作用,显著扩大光吸收范围、增强光电流密度并提升光电转换效率,从而提高整体光解水产氢性能。该结构制备工艺简便、可规模化生产,Au用量极低、成本可控,具有优异的稳定性与环境友好性,在光电化学水分解制氢应用中具有广阔的商业化前景。
Resumen de: CN121426053A
本发明涉及制氢设备技术领域,公开了一种光热裂解制氢反应器,包括壳体、反应腔,壳体的前端设有透光板,反应腔内设有金属氧化物催化组件;壳体的侧面设有进水管,壳体的后端设有排气管;当反应腔内处于还原反应温度状态时,所述金属氧化物催化组件发生还原反应析出氧气并通过排气管排出氧气;当反应腔内处于氧化反应温度状态时,进水管处向反应腔内注入定量的水,水与还原反应后的金属氧化物催化组件发生氧化反应析出氢气并通过排气管排出氢气。通过该种装置分两步反应制氢,金属氧化物催化组件无消耗,可持续使用。
Resumen de: CN121428602A
本发明涉及析氢催化剂技术领域,尤其涉及一种钌基碱性析氢催化剂及其制备方法。制备方法包括以下步骤:锌源、非贵金属源、以及氮源在第一溶剂中混合后,离心干燥,得到第一前驱体;将所述第一前驱体于氢气和氩气的混合气氛、800~1100℃下煅烧0.5~3h,得到第二前驱体;将所述第二前驱体与钌源在第二溶剂中混合后,在100~200℃下加热除去上清液,得到第三前驱体;将所述第三前驱体于氢气和氩气的混合气氛、800~1000℃下煅烧0.5~3h,得到催化剂。本发明中通过调整制备步骤调控催化剂结构,从强水解能力、弱氢吸附能方面提高催化剂的性能,实现高效碱性HER催化。
Resumen de: CN121428571A
一种亚铁氰根/铁氰根循环辅助的低电耗解耦式电解水制氢及循环方法,属于电解水制氢领域。所述方法为:在阳极电解液储罐中加入亚铁氰化物溶液,并对阳极石墨毡进行预处理,使亚铁氰根在阳极发生氧化反应;在阳极电解液储罐中加入还原催化剂,并通过加热条件实现铁氰根向亚铁氰根的热催化再生,使再生后的亚铁氰根重新进入阳极室参与反应,从而在体系内构建铁氰根/亚铁氰根的闭环循环。本方法以铁氰根/亚铁氰根氧化还原电对为媒介,解耦电解水过程,实现析氢析氧反应的空间分离,显著降低氢气渗透引起的氧中氢含量升高风险。由于亚铁氰根氧化反应的理论电位远低于传统析氧反应,与阴极析氢半反应耦合可有效降低整体电解能耗。
Resumen de: CN121422994A
本发明公开了一种基于ZnIn2S4/CoP2的光催化分解水催化剂的制备方法,所述制备方法首先制备得到CoP2,再通过在CoP2加入Zn源、In源和S源,进一步转化得到ZnIn2S4/CoP2,从而得到基于ZnIn2S4/CoP2的催化剂;本发明所制备的ZnIn2S4/CoP2催化剂可以高效地进行光催化分解水产氢,并且制备方法简单,成本低,适用大面积推广应用。
Resumen de: CN121425469A
本发明公开了一种浮空器氢气发生器,该浮空器氢气发生器包括具有腔室的壳体、以及导热装置,导热装置包括隔板、导热体,隔板将腔室分隔成相互独立的加热隔室和氢气发生隔室,导热体被隔板分割成两部分,其中一部分位于加热隔室,另一部分位于氢气发生隔室,加热隔室内放置有热量发生物质,氢气发生隔室内放置有氢气发生物质,导热装置将热量发生物质在加热隔室内产生的热量导入至氢气发生隔室,氢气发生物质吸收热量后释放氢气。本发明公开的浮空器氢气发生器通过隔板将壳体内的腔室分割成独立的两个隔室,热量发生物质产生的热量通过导热装置导入至氢气发生隔室中,氢气发生物质受热而产生氢气,氢气形成的速度快,所适用的工况范围大。
Resumen de: CN121422377A
The invention provides an intelligent foot health repair system, and belongs to the technical field of foot disinfection and repair. An intelligent foot health repair system is characterized by comprising a gas generation system, a control system and a control system, the gas generation system comprises an ozone generator and a hydrogen generator, and the ozone generator and the hydrogen generator can respectively or simultaneously generate ozone and hydrogen; the gas mixing system can control and mix ozone and hydrogen to generate mixed gas with preset concentration; the gas conveying system can convey the mixed gas to a foot disinfection and repair area; and the control system can control the operation of the gas generation system, the gas mixing system and the gas conveying system and adjust the concentration and the conveying rate of the mixed gas. The device has the advantages that ozone and hydrogen are generated through electrolytic reaction with water, the ozone has the effects of sterilization, disinfection, inflammation diminishing and infection resistance, the hydrogen has the effects of oxidation reduction, aging resistance and cell repair, the gas mixing system controls and mixes the ozone and the hydrogen to generate mixed gas with preset concentration, the effect of treating dermatophytosis is achieved, and the device is suitable for popularization and application. Operation is convenient, and popularization and use of common people are facilitated.
Resumen de: CN121428196A
本发明属于碳中和技术领域,公开了一种协同高效且低碳的电解水与全氧高炉耦合的低碳钢化联产系统。包括电解水系统;全氧高炉系统,其鼓风气体入口与电解水系统的氧气出口连接,用于接收氧气以产生富含一氧化碳和二氧化碳的顶部循环煤气;煤气净化系统,其入口与全氧高炉系统的循环煤气出口连接;甲醇合成系统,其第一入口与电解水系统的氢气出口连接,第二入口与煤气净化系统的净化气出口连接,用于接收氢气和净化后的循环煤气以生成甲醇;循环气加热系统,设置于煤气净化系统与全氧高炉系统之间的循环气路中,用于加热返回高炉的循环煤气;烟气脱碳系统,其入口与循环气加热系统的燃烧烟气出口连接,用于将烟气中的二氧化碳输送至第二入口。
Resumen de: CN121428593A
本发明公开一种葫芦脲6衍生的S掺杂Ru2P/Ru双功能电催化剂及其制备方法和应用。属于HER催化剂技术领域。葫芦脲6衍生的S掺杂Ru2P/Ru双功能电催化剂,是以葫芦脲6作为载体,通过引入RuCl3,4,4’‑磺基二苯酚和六氯环三磷腈作为构筑单元,原位在葫芦脲6表面生长聚(环三磷腈‑co‑4,4’‑磺酰二酚)聚合物涂层,经热解后得到的双功能电催化剂Ru2P/Ru‑S‑CBC。本发明制备的电催化剂在碱性电解质中表现出优异的电催化HER和肼氧化活性,为HzOR反应代替析氧反应提供了前提,同时也实现了低能耗,高稳定的电化学制氢。
Resumen de: CN121428606A
一种电解制氢压力平衡控制装置、使用方法及电解制氢系统,属于电解制氢领域。电解制氢压力平衡控制装置包括舱体和柔性内管。舱体具有内部空间,在舱体上设有至少一个与内部空间连通的舱体管口,舱体管口可供第一气体进出内部空间;柔性内管设置于舱体内,其两端分别设有可供第二气体由舱体外部流入和流出柔性内管的内管入口和内管出口,柔性内管至少部分区段为由柔性材料制成的柔性可变体积段,该柔性可变体积段的内流道的最小横截面处的截面积不大于内管入口或内管出口中的内流道截面积较小者的1%;第一气体和第二气体的气压不同时,能够使柔性可变体积段发生形变,通过体积变化使柔性内管和舱体内的气体趋于平衡。
Resumen de: CN121428583A
一种低电导率PEM电解制氢系统及控制方法,属于电解水制氢技术领域。低电导率PEM电解制氢系统包括水电解单元以及与该水电解单元连接通过氧侧水循环回路连接的氧侧气液分离装置,还包括换热装置,接收所述氧侧气液分离装置中的水并对水降温;水处理装置,内部具有去离子树脂,所述水处理装置接收换热装置中的降温后的水并吸收水中的离子;水缓冲装置,接收并存储所述水处理装置处理后的水;控制装置,控制所述水缓冲装置中的水供应至所述氧侧水循环回路,以调节所述水电解单元内的水温。本发明延长了去离子树脂的寿命,减少能源消耗,且提高电解用原料水的质量。
Resumen de: US20260002270A1
An enclosure adapted for a hydrogen and oxygen generating apparatus arranged in a movable has an interior and an interior surface and an exterior surface whereby the hydrogen and oxygen generating apparatus comprises at least one electrolyser stack adapted for electrolysing water to hydrogen product gas and oxygen product gas and accompanying gas and electrolyte handling equipment. The exterior surface of the enclosure comprises at least a heat insulating, flexible polymer cover element which is attached to a metal frame.
Resumen de: MA66611A1
An innovative method for producing green hydrogen from seawater combines electromagnetic field-assisted electrolysis with renewable energy. This efficient approach reduces reliance on fossil fuels while improving the kinetics of chemical reactions through the use of a specific electromagnetic field. The saline residue is desalinated to produce fresh water, while the purified hydrogen is stored as a clean energy source, offering significant benefits for industry, transportation, and the environment.
Resumen de: CN121426181A
本发明提供了一种铁氧循环系统和自热耦合的铁基金属燃料储能装置,涉及储能领域,包括产铁阶段、铁分流阶段、氧化铁阶段;产铁阶段,通过输入系统的氢气经过还原反应将氧化铁还原为铁;铁分流阶段,将还原后的铁分为多个支路,多个支路;氧化铁阶段,将多个支路铁经过氧化反应产生氧化铁汇集后重新送入到产铁阶段,进入下一个循环。本发明采用上述的一种铁氧循环系统和自热耦合的铁基金属燃料储能装置,通过引入微型反应器,提高铁氧循环的能量储运效率,助力能源去碳化。
Resumen de: WO2025002651A1
The invention relates to an energy supply device (1) for an electrolyzer (10). The energy supply device (1) has an input circuit (2) and a transformer (3). The input circuit (2) is designed to be connected to an energy source (4) or an energy supply network. In order to improve the energy supply device (1), the input circuit (2) is additionally designed to provide at least two different electric potentials at contacts (5), and the converter (3) is electrically connected to at least one of the contacts (5) on the input side by means of a respective conductor (6). The energy supply device (1) is designed to change the contact (5) connected to the converter (3) by reconnecting at least one conductor (6) of the energy supply device (1). The invention additionally relates to an electrolysis device comprising such an energy supply device (1) and an electrolyzer (10) and to a method for controlling such an energy supply device (1) or such an electrolysis device (100), wherein the converter (3) is operated using a voltage level produced by the input circuit, and at least one conductor (6) of the energy supply device (1) is manually reconnected from a first contact of the contacts (5) to a second contact of the contacts (5) in order to change the voltage level.
Resumen de: ZA202403652B
The present invention provides a flower-shaped Bi2CrO6 oxygen-evolving photocatalyst and its preparation method, which belongs to the field of photocatalytic material preparation technology. The method uses bismuth nitrate and potassium chromate as raw materials and employs microwave heating to complete the reaction within a relatively low temperature (100oC) and a short time (2 hs). The preparation method of the present invention is mild, energy-efficient, and requires simple and fast experimental equipment. The obtained Bi2CrO6 photocatalyst samples have uniform size, large specific surface area, and abundant active sites. Additionally, due to the reduced thickness of the flakes, the migration distance of electrons and holes from the semiconductor interior to the surface is shortened, resulting in higher catalytic activity.
Resumen de: CN121428599A
本发明提供一种基于核壳异质结构介导的磁邻近效应电催化材料的制备方法,属于电催化材料制备技术领域。本发明通过静电纺丝技术将过渡金属Fe、W等元素锚定在纳米纤维载体上,并结合高温化学气相沉积法形成Fe7S8@WS2核壳结构催化剂材料。Fe7S8和WS2形成核壳结构后,可借助磁性材料与非磁性材料的界面耦合,诱导非磁性材料产生自旋极化的磁邻近效应(MPE),进而优化反应中间体的吸附与电子转移过程,使Fe7S8@WS2在电解水OER反应中50 mA/cm2的过电位仅为239 mV,在电催化领域显示出巨大的应用前景。
Resumen de: CN121422984A
本发明公开一种光热催化水煤气转换反应用铁基催化剂及其制备方法和应用。该催化剂的结构中包含锌铁复合金属氧化物,以及负载在所述锌铁复合金属氧化物上的呈团簇状的贵金属颗粒。本发明的技术方案中首次实现了用此铁基催化剂光热催化水煤气转换反应,并在低温下具有较好的产氢活性。
Resumen de: WO2025013883A1
This metal nonwoven fabric for a water electrolysis electrode contains a metal fiber. The metal fiber has: a core part including a first metal; and a coating part disposed on the surface of the core part and including a second metal and/or a compound of said metal. The first metal comprises one or more metal elements. The second metal and/or the compound of said metal comprises a metal composed of one or more metal elements and/or a compound including one or more metal elements. The second metal and/or the compound of said metal has catalytic activity and corrosion resistance in a water electrolysis reaction environment. A ratio M2/S of the sum M2 of the masses of the second metal present in the coating part and the metal element present as the compound of said metal to the geometric area S of the surface of the core part per unit mass of the metal nonwoven fabric is 0.01 g/m2 to 20.0 g/m2.
Resumen de: CN121430902A
本发明提出了一种应用于氨裂解制氢膜提纯系统的压力检测方法及系统;属于压力检测技术领域。所述方法包括:通过在金属膜上游和下游安装高精度压力传感器,实时采集膜两侧的压力数据;对采集到的压力数据进行预处理,获得多维时序压力数据集;基于预处理后的多维时序压力数据集,构建用于反映膜两侧压力变化特征的高维特征向量集,对高维特征向量集进行动态特征提取,得到多维特征矩阵;通过在金属膜上游和下游安装高精度压力传感器,能够实时、精准地采集膜两侧的压力数据。同时,对采集数据进行预处理形成多维时序压力数据集,从而实现更加精准的系统控制调节,实现制氢系统的最优化。
Resumen de: CN121428595A
本发明公开了一种表面氧化单原子纳米合金催化剂及其制备方法和应用,属于先进纳米能源材料与电催化技术领域。一种表面氧化单原子纳米合金催化剂,包括羟基化碳纳米管载体,负载于羟基化碳纳米管载体上的双金属纳米合金颗粒,双金属纳米合金颗粒中,非贵金属元素以单原子形式分散于贵金属纳米颗粒中,双金属纳米合金颗粒的尺寸为3‑4nm,且双金属纳米合金颗粒表面具有0.3‑0.6 nm厚的氧化层;贵金属的负载量为5‑15 wt%。本发明将钌与其他非贵金属元素合金化并锚定在碳材料基底上,可以大幅提升催化剂的导电性,而将合金颗粒尺寸精准控制在3‑4 nm范围内,可最大限度地暴露活性位点并兼顾结构稳定性。
Resumen de: CN121428581A
本发明公开了一种电解水单元结构、PEM电解槽及组装方法,电解水单元结构包括:极板组件、膜电极组件和单元紧固组件,极板组件包括沿纵向相对设置的两块双极板膜电极组件夹装于两块双极板之间;多个单元紧固组件分布连接于两块双极板之间的四周,单元紧固组件用于在两块双极板相互压合于设定压紧状态时,将两块双极板之间的相对位置进行固定。本发明保证两块双极板与膜电极组件精准对位以及压装卸去外力后电解水单元结构的内部仍能保持相应的紧固力,防止在运输过程中内部组件错位,保证每个电解水单元结构受力一致性,以解决电解槽单室在组装时的复杂性导致单片之间以及各组件之间错位以及受力分布不均匀的问题。
Resumen de: CN121422989A
本发明涉及纳米催化剂技术领域,公开了富含硫空位的ZnxCd1‑xS纳米催化剂的制备方法与应用,包括富含硫空位的ZnxCd1‑xS纳米催化剂的制备方法,其特征在于,包括以下步骤:步骤S1、将镉盐、锌盐和硫脲在去离子水中混合得到混合溶液;步骤S2、将混合溶液置入反应釜中加热反应,冷却后收集反应产物,用去离子水对反应产物进行洗涤,将洗涤的反应产物干燥制备得到ZnxCd1‑xS纳米催化剂。本发明合成的ZnxCd1‑xS纳米催化剂分散均匀、尺寸均一、形貌规则,其中,随着反应温度的升高,所得ZnxCd1‑xS纳米催化剂的形貌由圆球状演变为表面粗糙的荔枝状的过渡态,进而生成形貌规则的松树状形貌。此外,所制备的催化剂富含一定硫空位,应用于光催化析氢领域性能提升显著。
Resumen de: CN121423009A
本发明属于光催化与新能源材料技术领域,具体涉及一种通用型基材光催化电子‑质子迁移通道材料及其制备与应用方法。本发明所述材料包括依次层叠的导电功能基材、质子迁移通道层和光催化异质结层,通过在导电功能基材表面引入电子传输路径与可连续导通的质子通道,实现光生电子向基材定向迁移,质子沿水膜或质子迁移通道层迁移,在阴极界面发生还原反应。本发明的材料体系可使用铝、钛、不锈钢、PI、FTO玻璃、碳纤维复合材料等广谱基材,并可通过不同构筑参数实现不同光催化应用。本发明体系具有光生载流子分离效率高、界面能带可调、可扩展至大面积涂覆等优点,是一种可用于光催化产氢、VOC降解、气体净化、自清洁表面的通用底层技术。
Resumen de: CN121428607A
本发明涉及工业过程控制技术领域,公开了一种碱性水制氢系统的智能优化控制方法,包括:控制器同步采集电解槽的实时电压、电流及温度数据;依据能斯特方程计算理论可逆电压并剔除欧姆压降,解析出表征气泡覆盖程度的气泡附加阻抗值;对气泡附加阻抗值的变化率进行微分处理生成流量前馈控制指令,结合基于温度偏差的反馈控制指令合成目标转速指令,驱动碱液循环泵调节流速;利用稳态窗口下的递推最小二乘法更新结构阻抗基准值,本发明通过构建气泡阻抗观测模型,实现对电解槽内部气泡状态的零延迟感知与解耦控制,消除单一温度反馈的滞后性,并解决执行器饱和与模型老化漂移问题。
Resumen de: CN121428597A
本发明公开了一种磷化镍表面外延生长非晶镍钴铁层状双氢氧化物电极的制备和电解海水应用,属于电催化技术领域。该电极由表层NiCoFe‑LDH、中间层NiPx和底层Ni组成的多层结构,其制备方法为先用水热法对泡沫镍进行磷化合成NP电极,再对NP电极进行电沉积制备得到NP‑NCF电极。在OER过程中,中间层NiPx通过孔隙大量释放POxn‑到NiCoFe‑LDH层表面形成的富阴离子保护层,实现了电极对Cl‑的排斥。因此,NP‑NCF电极在碱性海水电解中显示出了优异的析氧选择性及稳定性。
Resumen de: CN121428585A
The invention discloses a performance recovery system and method of an electrolytic hydrogen production device and a cleaning solution, and belongs to the technical field of electrolytic hydrogen production. The performance recovery system comprises a cleaning unit which is externally connected to an electrolytic hydrogen production device and pumps cleaning liquid into the electrolytic hydrogen production device to clean an exchange membrane; the vibration unit is provided with a plurality of groups of electrically connected vibration assemblies, and the vibration assemblies are semi-soft polar bands, are fixed at fixed positions on the periphery of the electrolytic hydrogen production device, and are used for assisting the cleaning liquid in cleaning the exchange membrane; and the detection unit is electrically connected with the cleaning unit and the vibration unit, detects attenuation data and performance recovery data of the electrolytic hydrogen production device, and starts/stops the vibration assembly and the cleaning unit according to the attenuation data and the performance recovery data. On the basis that the device is not disassembled, impurities are selectively cleaned in a chemical and physical combined mode, main parts are not damaged, the performance of the device can be recovered, and the service life of the device is prolonged.
Resumen de: CN121428626A
本发明公开一种两步脉冲电沉积镍基三元金属电极的制备方法,主要包括以下步骤:对镍基基材预处理;在含有镍盐及两种不同过渡金属盐的混合盐溶液中,依次采用脉冲电流在预处理后的镍基基材上进行两步脉冲电沉积,并进行干燥,得到镍基三元金属电极。本发明的制备方法,电镀工艺沉积过渡金属层,其形成的负载催化层结构致密且兼具高耐磨性、强耐冲刷性,可大幅优化电极活性组分的负载状态与分散程度,能构建起致密耐磨、抗冲刷性能优异的负载催化层,对电极活性组分的负载量及分散均匀度有显著改善作用,所得镍基三元金属电极,具有丰富的活性位点,可显著提升电极导电性与电荷传输效率。本发明简单可控、成本低,性能稳定,适用于规模化生产。
Resumen de: CN121426183A
本发明公开一种片状羟基氧化钴及其制备方法。该片状羟基氧化钴的制备方法包括:将可溶性钴盐分散至水中配制成溶液A,将氧化剂和碱分散至水中配制成溶液B;将反应温度升至70~80℃,在第一搅拌转速下,向溶液A中通入溶液B,持续第一时间;在第二搅拌转速下,继续通入溶液B,持续第二时间;停止进料,在第三搅拌转速下,持续第三时间,得到反应液;反应液经固液分离、洗涤、干燥、破碎,得到片状羟基氧化钴。本发明通过控制氧化剂和沉淀剂的用量及搅拌速度,无需络合剂和分散剂,即可形成分散性好且具有独特片状结构的羟基氧化钴。本发明的制备方法简单、控制条件少、氧化剂使用后无残留、产物纯度高、可重复性强,适合工业大规模生产。
Resumen de: WO2025008254A1
An electrolysis system (1) having an electrolyzer (2) designed to convert electrical energy to chemical energy, and having power electronics (4) for supply of the electrolyzer (2) with the required electrical power. The power electronics (4) comprise circuit components (7) and a rectifier (8). Also present is a busbar (14) for electrical connection of the power electronics (4) to the electrolyzer (2). The power electronics (4) comprise multiple strings (5), where each string (5) has circuit components (7) and a rectifier (8), and each string (5) is mounted in a housing (10). The electrolysis system (1) has a carrier frame (15) with multiple slots (16), where each slot (16) is designed to accommodate one of the housings (10) in an assembly position, such that the strings (5) are connectable to the busbar (14) in the assembly position.
Resumen de: WO2026022489A1
An oxygen evolution reaction (OER) catalyst material is provided. The OER catalyst material comprises an iridium-containing compound on a particulate catalyst support and has the following characteristics: a BET surface area in the range of and including 35 to 55 m2/g; an iridium content in the range of and including 25 to 45 wt% with the proviso that if the BET surface area is greater than 45 m2/g the iridium content is at least 35 wt%; a Tmax in the temperature-programmed reduction profile of the OER catalyst material of less than 135 °C.
Resumen de: WO2026023125A1
This hydrogen production system comprises: a hydrogen compound member; a water supply member for supplying water to the hydrogen compound member; and a heat recovery device for recovering adsorption heat that is generated when hydrogen, which is generated by decomposing some of water into hydrogen and oxygen in the presence of the hydrogen compound member, is adsorbed to the hydrogen compound member. This hydrocarbon production system comprises: a hydrogen compound member; a water supply member for supplying water to the hydrogen compound member; a heat recovery device for recovering adsorption heat that is generated when hydrogen, which is generated by decomposing some of water into hydrogen and oxygen in the presence of the hydrogen compound member, is adsorbed to the hydrogen compound member; a heating device for heating the hydrogen compound member to which hydrogen is adsorbed; and a gas supply device for supplying a carbon dioxide-containing gas that contains carbon dioxide to the hydrogen compound member.
Resumen de: WO2026021999A1
The present invention relates to a water electrolysis device comprising a plurality of nanopillars. Each nanopillar has a vertical extension in relation to a plane of extension of a substrate supporting the nanopillars. Further, each nanopillar comprises a plurality of quantum dot segments of InxGa1-xN alloy, wherein each quantum dot segment is interposed along the vertical extension between barrier segments of GaN, wherein each quantum dot segment has a thickness of less than or equal to 20 nm along the vertical extension. Moreover, each nanopillar comprises a p-side portion constituting a photoanode and an n-side portion constituting a photocathode, wherein the photoanode comprises at least one quantum dot segment and the photocathode comprises at least one quantum dot segment, wherein the photoanode and the photocathode are separated by a depletion portion comprising GaN. A system for water electrolysis comprising such a water electrolysis device is also presented.
Resumen de: WO2026021830A1
Electrolysis system and method to operate said system notwithstanding occurrence of an adverse operational event are provided. Disclosed embodiments feature bypass circuitry configured to dynamically and quickly adapt the electrolysis system during occurrences of such adverse operational events and effectively inhibit the possibility of having to shut down the entire electrolysis system.
Resumen de: DE102024206988A1
Elektrochemische Anlage mit einem elektrochemischen Stack (1), in dem ein erster Reaktionsraum (2) und ein zweiter Reaktionsraum (3) ausgebildet sind, die durch eine semipermeable Barriere (4) voneinander getrennt sind und zwischen denen eine elektrische Potentialdifferenz angelegt werden kann. Zumindest einer der Reaktionsräume (2; 3) ist während des Betriebs mit Wasser befüllt und mit einer Ablaufleitung (10) verbunden, über die Wasser bzw. die wässrige Lösung abfließen kann. Die Innenseite (110) der Ablaufleitung (10) ist hydrophilisiert und weist einen Benetzungswinkel (α) von 0° bis 90° auf.
Resumen de: WO2026024816A1
A continuous method includes passing a steam feed stream and one or more of a recycled tail gas stream and a methane-rich feed stream to an anode of an electrolyzer containing a cathode, the anode and an electrolyte inserted between the cathode and the anode, thereby producing an anode effluent including syngas, and passing the anode effluent including syngas to the reactor unit, thereby producing a chemical product or a fuel-based product.
Resumen de: WO2026022486A1
Described herein includes a method for the production of hydrogen gas, the method comprising: (i) providing a DC electrical power supply; (ii) providing a plasma reactor (100) comprising: (a) a plasma chamber (105), (b) a plasma torch (135) comprising a first plasma electrode extending into the plasma chamber, (c) a second plasma electrode extending into the plasma chamber, and (d) first and second spray systems, each extending into the plasma chamber; (iii) establishing a DC electric potential between the first plasma electrode and the second plasma electrode to generate and sustain a reaction zone about a plasma arc therebetween; (iv) providing a spray of a hydrogen-containing feedstock into the reaction zone from the first spray system, whereby a mixture of gases comprising hydrogen gas is formed in the plasma chamber by decomposition of the hydrogen-containing feedstock; and (v) providing a spray of water into the plasma chamber adjacent to the reaction zone from the second spray system, whereby the spray of water cools and dilutes the mixture of gases formed in step (iv).
Resumen de: WO2026023164A1
This purification plant comprises: a temperature swing adsorption (TSA) tower in which unreacted ammonia is adsorbed to an adsorbent and removed from a decomposition gas and from which a resulting treated gas is discharged; a gas-purifying device that separately discharges product gas refined from the treated gas and off-gas; an off-gas heating device that heats the off-gas and supplies same to the TSA tower as regeneration gas for regenerating the adsorbent in the TSA tower; a combustion device that supplies, as a heat source for the off-gas heating device, a portion of a combustion gas resulting from combusting the regeneration gas discharged from the TSA tower; an off-gas flow path that circulates the off-gas through the combustion device; and a combustion-gas flow path that circulates the combustion gas through the off-gas heating device.
Resumen de: WO2026022833A1
The present invention relates to a frame for an electrolyser cell and electrolyser cell comprising such a frame. Said frame (10) for an electrolyser cell comprises: a base part (34) with a central opening (42) configured to serve as active chamber of the electrolyser cell, said base part (34) being made of reinforced polymeric material with reinforcing fibres and/or mineral filler in a percentage greater than 10%; a cover part (36) coupled with the base part (34), said cover part (36) being made of polymeric material or rubber without reinforcing fibres or mineral filler, or with a percentage of reinforcing fibres or mineral filler not exceeding 10%; and a plurality of sealing gaskets (38, 40) arranged between the base part (34) and the cover part (36).
Resumen de: WO2026020744A1
A gas supply system for an LNG dual-fuel main engine, and an LNG dual-fuel powered ship. The gas supply system comprises an LNG supply unit (10), a dual-fuel main engine (20), an electrolytic hydrogen production unit (30), an exhaust gas recirculation unit (40), and a cold and heat circulation unit (50). The LNG supply unit (10) comprises an LNG storage tank (11), a submersible pump (12), an LNG heat exchanger (13) and a buffer tank (14). The electrolytic hydrogen production unit (30) comprises a pure water unit (31), a pure water heat exchanger (32), an electrolytic cell (33), a hydrogen storage tank (34), and an oxygen storage tank (35). The exhaust gas recirculation unit (40) comprises a flue gas heat exchanger (41). The cold and heat circulation unit (50) comprises an expansion water tank (51) and a circulation pump (52).
Resumen de: WO2026020196A1
An electrolytic process and an apparatus for producing solid carbon and gaseous oxygen from CO2. In one aspect the process comprises using a cathode that includes a solid, semi-solid or liquid metal containing a catalytically active material for CO2 reduction that includes less than or equal to 10 wt.% of at least one of copper or silver or gold. In another aspect the process comprises using a "spouted" bed electrolysis apparatus comprising a downwardly moving packed bed of cathode particles that include a catalyst, such as copper, for CO2 reduction and an upward flow of electrolyte.
Resumen de: US20260031366A1
A process for producing an ion-conducting membrane comprising a recombination catalyst-containing membrane layer. The membrane layer if fabricated from an ink comprising a stabilised dispersion of recombination catalyst nanoparticles. Also provided are ion-conducting membranes for electrochemical devices, such as fuel cells or water electrolysers, with a recombination catalyst-containing membrane layer comprising dispersed recombination catalyst nanoparticles, a nanoparticle stabilising agent, and an ion-conducting polymer.
Resumen de: US20260031377A1
The present invention relates to a method of supplying electricity to an electrical load including steps of providing an alkaline solution, reacting the alkaline solution with silicon so as to produce hydrogen. processing the hydrogen in a fuel cell to generate electricity, and supplying the electricity from an output of the fuel cell to the electrical load via a suitable electrical interfacing module.
Resumen de: US20260028949A1
The present invention relates, in general, to systems and methods for generating hydrogen from ammonia on-board vehicles, where the produced hydrogen is used as a fuel source for an internal combustion engine. The invention provides an expansion valve configured to maintain ammonia in a gaseous state prior to introduction into a cracking system that comprises a heat-exchange cracking unit and electric cracking unit coupled in series which enables reliable hydrogen generation under varying engine operating conditions.
Resumen de: US20260028934A1
An energy supply system includes an electrolysis system to perform electrolysis on a first source of water, and break the water into hydrogen and oxygen components. The hydrogen and oxygen components are supplied to a power generation system. The power generation system includes a combustor receiving the hydrogen and oxygen components and is operable to combust the hydrogen and oxygen components. The combustor also receives a source of steam. Products of combustion downstream of the combustor pass over a top turbine rotor, driving the top turbine rotor to rotate. A first generator generates electricity from the rotation of the top turbine rotor.
Resumen de: US20260029198A1
A method for heating a furnace including radiant tubes and being able to thermally treat a running steel strip including the steps of: i. supplying at least one of the radiant tubes with H2 and O2 such that the H2 and the O2 get combined into heat and steam, ii. recovering the steam from the at least one of the radiant tubes, iii. electrolysing the steam to produce H2 and O2, and iv. supplying at least one of the radiant tubes with the H2 and O2 produced in step iii, such that they get combined into heat and steam.
Resumen de: US20260028733A1
An electrochemical apparatus includes a cell stack, a power conversion apparatus, a control unit, and a heating tank. The power conversion apparatus is electrically connected to the cell stack. The control unit controls the power conversion apparatus. The heating tank includes a housing space housing the cell stack and heats the cell stack. The cell stack produces hydrogen by electrolyzing water using supplied power, or generates power through an electrochemical reaction between hydrogen and an oxidizing agent. The power conversion apparatus is disposed outside the heating tank, further toward a lower side than the cell stack is. The power conversion apparatus and the cell stack are electrically connected by a conductor that passes through a wall portion of the heating tank. The power conversion apparatus is disposed such that at least a portion thereof overlaps the heating tank when viewed in a vertical direction.
Resumen de: US20260028739A1
An electrolysis system includes an electrolyzer stack, a water source, and a cathode-side purging system. The electrolyzer stack has an anode side and a cathode side. The water source is fluidically coupled to an inlet of the anode side of the electrolyzer stack. The cathode-side purging system is fluidically coupled to a first and second outlet of the cathode side.
Resumen de: US20260028730A1
Conventional control schemes for electrolyzers focus on maximizing electrical efficiency, which describes the relationship between the electrical energy consumed and the gas produced by the electrolyzer. However, the cost associated with high electrical efficiency may be unnecessarily expensive. In one embodiment presented herein, a model is used to determine the cost (or profit) associated with a gas produced by the electrolyzer at each of a plurality of operating conditions. The control system can select the operating condition to use based on which operating condition is associated with the lowest cost (or highest profit), even though that operating condition may not be associated with the highest electrical efficiency.
Resumen de: US20260028738A1
A continuous method includes passing a steam feed stream and one or more of a recycled tail gas stream and a methane-rich feed stream to an anode of an electrolyzer containing a cathode, the anode and an electrolyte inserted between the cathode and the anode, thereby producing an anode effluent including syngas, and passing the anode effluent including syngas to the reactor unit, thereby producing a chemical product or a fuel-based product.
Resumen de: US20260028737A1
A continuous method includes passing a first steam feed stream to a cathode of an electrolyzer including the cathode, an anode and an electrolyte inserted between the cathode and the anode, thereby producing a cathode effluent including hydrogen, passing a second steam feed stream and one or more of a recycled tail gas stream from a reactor unit and a methane-rich feed stream to the anode of the electrolyzer, wherein the one or more of the recycled tail gas stream and the methane-rich feed stream are utilized as fuel for producing the cathode effluent including hydrogen, and passing the cathode effluent including g hydrogen and a carbon dioxide feed stream to the reactor unit, thereby producing a chemical product or a fuel-based product.
Resumen de: US20260028728A1
The present application relates generally to methods and systems for accelerating the evaporation of brine pond water. In one embodiment the application pertains to an integrated process for producing hydrogen wherein waste heat evaporates the brine water. The process comprises producing hydrogen and heat from water using an electrolyzer and then heating a heat transfer fluid with the heat from the electrolyzer. The heated heat transfer fluid is pumped to a heat exchanger where it heats a brine solution from the brine pond to increase its evaporation.
Resumen de: US20260028734A1
A method for use in controlling operation of a hydrogen production plant includes determining a maximum available amount of energy of a predetermined energy category in a current time interval; determining a target minimum amount of the energy of the predetermined energy category to be used for hydrogen production in the current time interval; and determining hydrogen setpoints for the current time interval using the maximum available amount and the target minimum amount as constraints.
Resumen de: US20260028543A1
Methods and systems of the present disclosure can function to capture flue gas and convert the flue gas to a synthesis gas, which can be further processed to other components such as liquid fuels. Aspects of the present disclosure provide for a process designed to capture flue gas from large scale (i.e. ̃GW), fossil based power plants in a 24/7 continuous operation. In addition, the method and system can convert the flue gas to a synthesis gas (mainly carbon monoxide and hydrogen), which will be processed into high quality liquid fuels, like diesel.
Resumen de: US20260027556A1
A catalyst for decomposition of ammonia, and a method for decomposition of ammonia in which a decomposition reaction of ammonia is performed in the presence of the catalyst, the catalyst including a carrier, and catalytically active components supported on the carrier, where the catalytically active components include i) ruthenium (Ru) as first metal; ii) lanthanum (La) as second metal: and iii) one or more of aluminum (Al) and Cerium (Ce) as third metal, and the catalyst has a porosity of 25% or more. The catalyst exhibits very high ammonia conversion rates, has little pressure difference between the front end and back end of the reactor, has high catalyst strength, and catalyst layer temperature difference is very small.
Resumen de: AU2026200145A1
MAGNETOHYDRODYNAMIC HYDROGEN ELECTRICAL POWER GENERATOR A power generator is described that provides at least one of electrical and thermal power comprising (i) at least one reaction cell for reactions involving atomic hydrogen hydrogen products identifiable by unique analytical and spectroscopic signatures, (ii) a molten metal injection system comprising at least one pump such as an electromagnetic pump that provides a molten metal stream to the reaction cell and at least one reservoir that receives 5 the molten metal stream, and (iii) an ignition system comprising an electrical power source that provides low-voltage, high-current electrical energy to the at least one steam of molten metal to ignite a plasma to initiate rapid kinetics of the reaction and an energy gain. In some embodiments, the power generator may comprise: (v) a source of H2 and O2 supplied to the plasma, (vi) a molten metal recovery system, and (vii) a power converter capable of (a) 10 converting the high-power light output from a blackbody radiator of the cell into electricity using concentrator thermophotovoltaic cells or (b) converting the energetic plasma into electricity using a magnetohydrodynamic converter. MAGNETOHYDRODYNAMIC HYDROGEN ELECTRICAL POWER GENERATOR an a n
Resumen de: AU2024321116A1
The present invention relates to a methanation method comprising providing an electrolyser system, the electrolyser system (20) comprising an electrolyser (10) that has at least one electrolyser cell (11), at least one fuel input (14) through which fuel enters the electrolyser (10) and at least one offgas output (46) from which offgas exits the electrolyser (10), the method further comprising supplying fuel to the at least one fuel inlet, the fuel comprising at least water and either or both carbon dioxide and carbon monoxide, operating the electrolyser system (20) by powering the electrolyser cell (11) with electricity to electrolyse the fuel in the at least one electrolyser cell (11) such that a part of the water splits into hydrogen and oxygen, wherein the electrolyser (10) is operated at a temperature at or in excess of 150 degrees C, and methanation occurs to the carbon dioxide and/or carbon monoxide in the electrolyser (10). The gas mixture can be released from the at least one offgas output (46) and then passed through a gas separation process to separate at least the methane from the gas mixture. The present invention also relates to an electrolyser system (20) configured to operate using the above method. The electrolyser system (20) comprises a fuel fluid flow path connecting a fuel inlet and a fuel outlet. The method may comprise providing to the fuel inlet a fuel gas containing water and a source of carbon selected from one or more of CO and CO2, operating the ele
Resumen de: AU2024299452A1
A control method and apparatus for a hydrogen production system. The method comprises: for each electrolytic cell, performing evaluation to obtain energy efficiencies of the electrolytic cell under load currents; for each electrolytic cell, converting the energy efficiencies of the electrolytic cell under the load currents into an energy efficiency value of the electrolytic cell; and ranking the electrolytic cells in descending order according to the energy efficiency values of the electrolytic cells, and performing power distribution on the electrolytic cells on the basis of the ranking. In the present solution, current efficiencies corresponding to load currents are obtained on the basis of bypass currents under the load currents, energy efficiencies corresponding to the load currents are obtained on the basis of the current efficiencies and voltage efficiencies, the energy efficiencies are converted into energy efficiency values, and power distribution is performed on electrolytic cells on the basis of the energy efficiency values, thereby achieving the purpose of controlling the power distribution for electrolytic cells in a hydrogen production system on the basis of accurate energy efficiencies of the electrolytic cells.
Resumen de: AU2024293794A1
The present invention is directed to a method and plant for controlling a dynamic operation in a Power-to-X plant via a DCS (distributed control system). Said plant comprises one or more electrolyzers for converting water into hydrogen and said plant can produce one or more of ammonia, methanol, ethanol, DME, methane or synthetic fuels such as gasoline or jet fuel.
Resumen de: AU2024298608A1
An electrolyzer (1) for electrolyzing saline water comprising: a housing (10) extending along a longitudinal direction (X-X) between a first end portion (11) and an opposed second end portion (12) and having a feed fluid inlet (13) and a product fluid outlet (14); two or more electrolytic cells (20) connected fluidically between the feed fluid inlet (13) and the product fluid outlet (14) and configured to electrolyze saline water entering the housing (10) to produce an electrolyzed fluid comprising hydrogen, hypochlorite and saline water; each electrolytic cell (20) comprising an anode (21) and a cathode (22); the housing (10) comprises: an inner wall (30) extending from the first end portion (11) towards the second end portion (12) along the longitudinal direction (X-X) and dividing at least a portion of the housing (10) in an inlet channel (15) and an outlet channel (16) respectively associated to the feed fluid inlet (13) and to the product fluid outlet (14); a diverting channel (40) at the second end portion (12) configured to divert the electrolyzed fluid from the inlet channel (15) to the outlet channel (16), the two or more electrolytic cells (20) being arranged along the inlet channel (15), the outlet channel (16) and the diverting channel (40)
Resumen de: WO2026018801A1
Problem To provide a nickel-plated metal material for water electrolysis capable of suppressing damage to a diaphragm while maintaining a suitable gas generation surface area. Solution This nickel-plated metal material comprises: a sheet-shaped metal base material having a plurality of opening parts; and a roughened nickel layer provided on at least one surface of the metal base material. ΔRzjis on a surface on the roughened nickel layer side is 4.0 μm or less, and a developed area ratio Sdr on the surface on the roughened nickel layer side is 15.0% or more. The ΔRzjis represents the difference between the ten-point average roughness Rzjis1 of the end portion of the opening part and the ten-point average roughness Rzjis2 of the center portion between the two adjacent opening parts.
Resumen de: JP2026013794A
【課題】本発明が解決しようとする課題は、全ての水電解装置を短時間で起動するように制御可能な水電解装置の制御装置、水素製造装置、および水電解装置の制御方法を提供することである。【解決手段】上記課題を達成するために、複数の水電解装置の温度上昇曲線を作成可能な導出部と、温度上昇曲線を比較して、温度上昇曲線の補正をすべきか判定可能な判定部と、この判定に基づき、水電解装置を加熱可能な加熱器の出力および水電解装置の電解電圧の少なくとも一方を調整可能な調整部と、を含むことを特徴とする。【選択図】図1
Resumen de: WO2026018535A1
This water electrolysis system comprises: one or more water electrolysis stacks; a water line for supplying water to each water electrolysis stack; an oxygen line for discharging an oxygen gas that is generated in each water electrolysis stack and surplus water; a hydrogen line for discharging a hydrogen gas that is generated in each water electrolysis stack and surplus water; an insulation pipe for electrically insulating the water electrolysis stacks from the pipes of the water line, the oxygen line, and the hydrogen line; and a DC power supply for supplying DC power so as to drive the water electrolysis stacks. During the operation of this water electrolysis system, water is supplied to a part in which the hydrogen gas and surplus water are mixed in the water electrolysis stacks or the hydrogen line on the upstream side of the insulation pipe of the hydrogen line.
Resumen de: JP2026014024A
【課題】高い分離係数αを有する重水分離用触媒および重水分離装置を提供する。【解決手段】この重水分離用触媒は、γ-FeOOHを含む。重水分離装置1は、アニオン交換膜4と、その両側にそれぞれ設けられたアノード触媒層6およびカソード触媒層8とを有し、カソード触媒層8の材料として前記触媒を用いることにより、同位体効果によりH2Oの分解が重水素または三重水素を含むHODやHOTの分解よりも優先的に生じることを示す分離係数αを10以上に高めることが可能である。【選択図】図1
Resumen de: CN120981608A
Disclosed is an electrolyte solution comprising an electrolyte, where the electrolyte is used in an amount ranging between 1 wt% and 10 wt% of the electrolyte solution; an ionic liquid, wherein the ionic liquid is used in an amount ranging between 1 wt% and 5 wt% of the electrolyte solution; and a solvent, wherein the solvent is used in an amount ranging between 75 wt% and 99 wt% of the electrolyte solution.
Resumen de: CN121039323A
A method of generating hydrogen and oxygen from a liquid feed stream by an integrated system of forward osmosis and electrolysis is disclosed wherein the method comprises the steps of feeding water into an electrolyte solution by means of forward osmosis and applying a voltage across the electrolyte solution to generate hydrogen and oxygen, characterized in that the electrolyte solution comprises an electrolyte, an ionic liquid and a solvent wherein the electrolyte is used in an amount ranging from 1 wt% to 10 wt% of the electrolyte solution and wherein the ionic liquid is used in an amount ranging from 1 wt% to 5 wt% of the electrolyte solution, and wherein the solvent is used in an amount ranging between 75 wt% and 99 wt% of the electrolyte solution.
Resumen de: CN120917183A
An electrode for water electrolysis under alkaline conditions, comprising: a nickel metal substrate; a ceramic material having a perovskite-type structure comprising an oxide of at least one metal selected from lanthanide series elements including lanthanum, cerium and praseodymium, the ceramic material forming a coating on the nickel metal substrate; the metal nanoparticles are embedded within the ceramic material. The metal nanoparticles facing the alkaline solution have electrochemical activity, while the metal nanoparticles facing the metal substrate form anchor points between the metal substrate and the ceramic material.
Resumen de: AU2024213038A1
An electrolyser system and method of electrode manufacture. The electrolyser system may comprise a first vessel in communication with an electrolyser stack, a power supply, an electrode, a separator, a membrane, and a second vessel in communication with the electrolyser stack. The electrode may comprise a catalytic material and a micro- porous and/or nano-porous structure. The method of electrode manufacture may comprise providing a substrate, contacting the substrate with an acidic solution, applying an electric current to the substrate, simultaneously depositing a main material and supporting material comprising a scarifying material onto the substrate, and leaching the scarifying material.
Resumen de: WO2026024621A1
An integrated blue-green ammonia process that avoids the need for air separation is disclosed. Water electrolysis, to produce hydrogen, produces oxygen as a co-product. Natural gas (methane) is reacted in a reformer with steam and air to create a mixture composed primarily of hydrogen, steam, nitrogen and carbon dioxide. The oxygen from electrolysis drives this process, either directly inside an autothermal reformer, or indirectly by oxycombustion in the furnace of a steam methane reformer. The steam is removed by cooling the gas, the carbon dioxide is removed, leaving a purified stream comprising hydrogen and nitrogen. This stream can be combined with additional hydrogen from the electrolyzer to yield a 3:1 mixture of hydrogen and nitrogen for the Haber-Bosch process to make ammonia. The disclosed blue-green process is two-fold less expensive than the conventional green ammonia process and emits about half as much greenhouse gas as the conventional blue ammonia process.
Resumen de: WO2026023894A1
The present invention relates to a separator which comprises a porous substrate and a mesh substrate laminated on one surface of the porous substrate, and which solves the problem of pinholes occurring in a conventional commercial separator by specifying the porosity of the porous substrate and also has high chemical/mechanical strength while maintaining the pore characteristics of the porous substrate and, simultaneously, can maintain a high level of electrolysis efficiency.
Resumen de: WO2026022299A1
The invention discloses a gas generator for a working tool, comprising an electrolysis cell (150), an electrolyte, a first electrode and a second electrode, said first electrode and said second electrode are separated by at least one electrically non-conductive separator. Further, the at least one electrically non-conductive separator is connected to a wick and the first electrode is connected to a first busbar and the second electrode is connected to a second busbar. A working tool (591), comprising such gas generator is also disclosed.
Resumen de: EP4685273A1
The present disclosure provides a membrane electrode for hydrogen production by alkaline water electrolysis, a preparation method therefor, and an electrolytic cell. According to the method provided by the present disclosure, a membrane electrode with catalyst layers uniformly and firmly adhered to the surfaces of a membrane can be obtained via a direct coating and hot pressing. The membrane electrode is endowed with good stability, and the obtained membrane electrode exhibits a significantly reduced overpotential for water electrolysis. The method comprises the following steps: directly applying a catalyst slurry (catalyst slurries) onto both sides of a membrane, followed by drying and hot pressing the catalyst slurry (catalyst slurries) to form catalyst layers on each surface of the membrane to obtain the membrane electrode. The membrane is selected from a porous membrane or an alkaline anion exchange membrane; the catalyst slurry comprises a binder solution and a catalyst, wherein the binder solution is one or more selected from a perfluorosulfonic acid resin solution and a perfluorosulfonic acid ionomer dispersion, and the mass concentration of the binder solution is 5% to 30%; and the mass ratio of the binder solution to the catalyst is 1:1 to 4:1.
Resumen de: WO2024193977A1
The invention relates to an offshore hydrogen production system (100, 200), comprising a plurality of offshore hydrogen production wind turbines (102, 202, 240), in each case comprising a wind turbine (106, 206) and a micro-electrolysis system (104, 204), at least one first central offshore treatment structure (108, 208), comprising at least one water treatment plant (110, 210) designed to treat water for hydrogen production, and at least one interconnected medium network (118, 218) arranged between the plurality of offshore hydrogen production wind turbines (102, 202, 240) and the first central offshore treatment structure (108, 208). The interconnected medium network (118, 218) comprises at least one water supply network (120, 220) designed to supply the micro-electrolysis systems (104, 204) with the treated water.
Resumen de: EP4685272A2
L'invention se rapporte à une Cellule électrochimique (CEC) comprenant une première électrode (A0) de forme cylindrique et une deuxième électrode (C1) de forme cylindrique, la première électrode (A0) et la deuxième électrode (C1) partageant un même axe de révolution, le diamètre de la première électrode étant supérieur au diamètre de la deuxième électrode, de sorte que le volume (V) défini entre la face interne de la première électrode et la face externe de la deuxième électrode puisse recevoir un électrolyte, la cellule (CEC) comprenant des moyens d'obturation (D2, D3, CFo) de la base supérieure et de la base inférieure de la cellule assurant l'étanchéité de l'électrolyte, la cellule (CEC) comprenant de plus des moyens de production d'un champ magnétique (B), ledit champ magnétique étant perpendiculaire au champ électrique produit entre la première électrode (A0) et la deuxième électrode (C1).
Resumen de: EP4685269A2
The present disclosure relates to an electrolyzer cell. A ring-shaped skeleton is provided between a first sealing ring and a second sealing ring of a sealing gasket, which is able to support the sealing gasket well, avoiding problems such as not fitting in place and excessive compression deformation of the sealing gasket. In addition, in the present disclosure, the sealing gasket, the ring-shaped skeleton, a bipolar plate, nickel meshes are combined to form the electrolyzer cell, which can effectively improve the assembly efficiency, the assembly precision and the sealing of an alkaline water electrolyzer. The electrolyzer cell has a reasonably designed structure, is suitable for long-term use in working environments with alternating pressure and temperature changes, has a long service life, and can be reused.
Resumen de: JP2026013294A
【課題】急激な水素の生成を抑制できる水素発生装置を提供する。【解決手段】水素発生装置は、下部に設けられた収容部に反応液と反応して水素ガスを発生させる水素生成燃料体が収容される密閉容器と、密閉容器の上部に設けられ、反応液を貯留する反応液タンクと、収容部の上部に配置され、反応液を分散して水素生成燃料体へ供給する受け皿と、反応液タンクと受け皿との間を上下移動可能に配置された可動板と、反応液タンクの底部に設けられ、反応液タンクに貯留した反応液を密閉容器内に落下させる流出口と、可動板に取り付けられ、可動板の上下移動で流出口を開閉する止水弁と、収容部内で発生し、受け皿と可動板との間に流出した水素ガスを外部に排出する水素排出部と、を有する。【選択図】図1
Resumen de: EP4684865A2
A system includes a first chamber, a second chamber, an ultraviolet light source and a microwave source. The first chamber includes an inlet. The second chamber is adjacent the first chamber and includes an outlet and a waveguide. The ultraviolet light source resides within the waveguide of the second chamber. Related apparatus, systems, techniques and articles are also described.
Resumen de: EP4685268A1
The invention discloses a gas generator for a working tool, comprising an electrolysis cell (150), an electrolyte, a first electrode and a second electrode, said first electrode and said second electrode are separated by at least one electrically non-conductive separator. Further, the at least one electrically non-conductive separator is connected to a wick and the first electrode is connected to a first busbar and the second electrode is connected to a second busbar.A working tool (591), comprising such gas generator is also described.
Resumen de: EP4686026A1
Electrolysis system and method to operate said system notwithstanding occurrence of an adverse operational event are provided. Disclosed embodiments feature bypass circuitry configured to dynamically and quickly adapt the electrolysis system during occurrences of such adverse operational events and effectively inhibit the possibility of having to shut down the entire electrolysis system.
Resumen de: EP4685890A1
The present invention relates to a water electrolysis device comprising a plurality of nanopillars. Each nanopillar has a vertical extension in relation to a plane of extension of a substrate supporting the nanopillars. Further, each nanopillar comprises a plurality of quantum dot segments of In<sub>x</sub>Ga<sub>1-x</sub>N alloy, wherein each quantum dot segment is interposed along the vertical extension between barrier segments of GaN, wherein each quantum dot segment has a thickness of less than or equal to 20 nm along the vertical extension. Moreover, each nanopillar comprises a p-side portion constituting a photoanode and an n-side portion constituting a photocathode, wherein the photoanode comprises at least one quantum dot segment and the photocathode comprises at least one quantum dot segment, wherein the photoanode and the photocathode are separated by a depletion portion comprising GaN. A system for water electrolysis comprising such a water electrolysis device is also presented.
Resumen de: EP4685271A2
An electrolysis system includes an electrolyzer stack, a water source, and a cathode-side purging system. The electrolyzer stack has an anode side and a cathode side. The water source is fluidically coupled to an inlet of the anode side of the electrolyzer stack. The cathode-side purging system is fluidically coupled to a first and second outlet of the cathode side.
Resumen de: CN121407144A
本发明公开了一种双功能中空氮掺杂碳纳米盒负载钌‑二氧化钌纳米催化剂及其制备方法和应用,涉及电催化技术领域。本发明采用ZIF‑8、乙酰丙酮钌和NaBr作为原料,惰性气氛下煅烧得中空氮掺杂碳纳米盒负载钌纳米催化剂,将其置于空气气氛下煅烧,得中空氮掺杂碳纳米盒负载钌‑二氧化钌纳米催化剂。其中,通过空气煅烧处理,既能烧掉中空氮掺杂碳纳米盒负载钌纳米催化剂表面的衍生碳层,使活性物质得以暴露,从而提高催化活性;又能将单质Ru部分氧化为RuO2以形成Ru‑RuO2异质结,提高稳定性和HER性能。本发明制得的双功能中空氮掺杂碳纳米盒负载钌‑二氧化钌纳米催化剂具有优异的HER和OER活性,可用于电催化全解水。
Resumen de: AU2023390125A1
Catalyst ink formulas for the preparation of CCMs are described. The catalyst ink formulas comprise a catalyst, an ionomer, a solvent, and a porogen soluble in the solvent. The catalyst ink formula may also comprise an additive, such as an electron conductive polymer. The anode catalyst coating layer or both the anode and the cathode catalyst coating layers prepared from the catalyst ink formula comprises uniformly distributed nanopores that allow easy gas removal and uniform water feed distribution, which will avoid or reduce the direct energy losses for the electrolyzers. Catalyst coated membranes and methods of making a catalyst coated membranes are also described.
Resumen de: CN121407126A
本发明提供一种碱性电解水制氢电极的表面处理方法,包括:第一蚀刻工序:将喷砂后的镍基材与第一蚀刻液接触,得到镍基材I;第二蚀刻工序:将镍基材I与第二蚀刻液接触,得到镍基材II;第一蚀刻液中含有硝酸、柠檬酸和过氧化氢,硝酸、柠檬酸和过氧化氢的用量质量比为1:0.1‑2:0.05‑1;第二蚀刻液中含有草酸、磷酸和醋酸,草酸、磷酸和醋酸的用量质量比为1:0.1‑1:0.1‑1。本发明将喷砂后的镍基材通过两次蚀刻处理,通过粗蚀刻快速刻蚀基材表面,形成较大的微观结构,然后通过细蚀刻,进一步细化前述形成的微观结构,使表面更加细腻均匀,不但能够显著增加涂层与基材的机械咬合力,还能减少涂层中的缺陷。
Resumen de: CN121407142A
本发明一种基于多钼酸基金属有机框架的MoP@C电催化剂的制备方法及其应用,属于电催化材料技术领域,MoP@C电催化剂的制备方法包括以下步骤:S1.有机配体btpe的合成,S2.多钼酸基金属有机框架CUST‑698晶体的合成,S3.MoP@C电催化剂的原位合成,MoP@C电催化剂应用于电催化析氢电极,MoP@C电催化剂或者应用MoP@C电催化剂的电催化析氢电极,在酸性或碱性电解质中的析氢反应(HER)中应用,本发明通过N2吸脱附测试证实,MoP@C电催化剂具有由微孔和介孔构成的多级孔道系统,有利于电解质的渗透和氢气气泡的脱附,并暴露了大量的活性位点,具有高析氢活性,SEM和TEM图像显示,MoP@C电催化剂的结构有效防止了团聚,确保了活性位点的充分利用和快速的物质传输,具有良好的稳定性。
Resumen de: CN121407134A
本发明涉及催化剂技术领域,发明公开了一种自支撑多尺度多孔CoNiZn合金全解水产氢催化剂及其制备方法,在泡沫CoNi合金表面通过电镀锌、退火和腐蚀锌原位构筑多尺度多孔CoNiZn合金;泡沫CoNi合金作为基底载体的同时为多尺度多孔CoNiZn合金的原位构筑提供金属来源。多尺度多孔CoNiZn合金可以产生丰富的高活性位点,基底与合金层间的无缝一体化结合以及三维连续贯通的多尺度孔结构可以提供高效的电解水传质效率,同时还能显著提高催化剂在碱性溶液中的长期催化稳定性与耐腐蚀能力。该催化剂在碱性介质中均展现出优异的析氢、析氧以及全水分解电催化活性和稳定性,同时具有制备工艺经济、简便高效,适合大量制备的特点。
Resumen de: CN121409598A
本申请涉及制氢装备测试技术领域,公开了一种用于测试电解槽密封垫片的装置及测试方法。装置包括:电解槽,包括传感模块,用于测量电解槽的以下信息:表面温度、内部压力、拉杆轴力和电解槽形变位移;打压系统用于调节电解槽的内部压力;循环系统用于抽取电解槽的循环介质并调整循环介质的状态后输送回电解槽;控制系统用于控制打压系统和循环系统的工作,不断获取传感模块测量的表面温度、内部压力、拉杆轴力和电解槽形变位移,并将拉杆形变位移为电解槽的密封垫片的性能参数,对获取的密封垫片的性能参数、表面温度、内部压力、拉杆轴力进行曲线拟合,得到密封垫片的性能曲线。获取了电解槽密封垫片的性能曲线,实现了对电解槽密封垫片的测试。
Resumen de: CN121411536A
本发明提供了一种碱性电解槽温度复合控制方法、系统、介质及设备,包括:建立包含电解制氢系统内满足预设要求的关键工艺设备的全流程动态仿真模型;通过全流程动态仿真模型分析获得以电流为输入、前馈补偿量为输出的前馈控制器;基于所述前馈补偿量以使在电流I变化下电解槽温度稳定在设定值;构建前馈‑串级复合控制系统;基于前馈‑串级复合控制系统完成对电解槽温度的闭环控制。本发明将基于全流程动态仿真设计的前馈控制器与串级控制相结合,实现了对宽幅电流波动的精准超前补偿,有效克服了单一串级控制的响应滞后问题,显著提升了电解槽温度控制的动态响应速度与抗干扰能力。
Resumen de: CN121405145A
本发明公开一种ZnxNi1‑xCo2O4异质结催化剂的制备方法,属于电催化材料制备技术领域。该方法包括以下步骤:(1)配制前驱体溶液:称取镍盐、钴盐和锌盐,搅拌溶解于去离子水中,配制成金属盐混合溶液;(2)共沉淀反应:向金属盐混合溶液中滴加碱液,调节溶液pH值至碱性,并持续搅拌反应;反应完成后静置,然后离心分离并用去离子水洗涤至中性,得到中间产物;(3)煅烧成型:将中间产物在烘箱内干燥,然后置于空气氛围中升温煅烧,煅烧完成后再进行研磨,得到粉末状ZnxNi1‑xCo2O4催化剂。本发明所制得ZnxNi1‑xCo2O4异质结催化剂成本低,而且其活性和稳定性等明显优于市面现有催化剂。
Resumen de: CN121407143A
本发明涉及析氢催化剂技术领域,尤其涉及一种界面强耦合的钌基碱性析氢催化剂及其制备方法。制备方法包括以下步骤:将酸洗后干燥的二氧化钛、钌盐和还原剂混合后干燥,得到前驱体;将前驱体在氨气氛围下煅烧,得到催化剂。这种催化剂包括TiO2载体和Ru活性成分,所述TiO2载体和Ru活性成分之间具有强耦合界面Ru‑N‑Ti结构。本发明通过在Ru与TiO2界面构建强耦合界面Ru‑N‑Ti结构,不仅实现了电子从Ti向Ru的再分布,增强了Ti的路易斯酸性,促进了H2O的吸附和H‑OH键的断裂,实现了快速的水解离、质子的充足供应;同时Ru实现富电子态,优化了Ru的氢吸附能;从强水解能力、弱氢吸附能两个方面共同提升碱性析氢催化性能。
Resumen de: CN121407141A
本发明提供了一种碱性电解槽析氢电极及其制备方法,涉及析氢材料制备技术领域。一种碱性电解槽析氢电极的梯度电镀的方法,包括以下步骤:采用两电极电镀法,以镍基金属载体作为阴极,将阴极置于电镀液中,于3.0~4V进行第一次电镀;再于5.0~7.5V进行第二次电镀后于8.0~12V进行第三次电镀得到析氢电极;通过分阶段施加递增电压,诱导不同电位窗口下金属离子的选择性还原,实现从内到外由“富镍结合层”向“Ni‑Fe‑Mo过渡层”再至“富钼催化层”的梯度演化,增强了镀层与基底的相容性与界面结合强度,同时在外层富集高活性Mo组分,在保证长期稳定性的同时显著降低析氢过电位,为碱性电解水制氢电极提供解决方案。
Resumen de: CN121407125A
本公开涉及一种负载型含铱催化剂及其制备方法和应用,该方法包括:将铱源、二氧化钛载体、醇原料和还原剂接触,并在加热的条件下进行反应;所述还原剂包括抗坏血酸和碳原子数为1‑6的羧酸中的一种或几种;所述醇原料包括碳原子数为1‑6的饱和醇中的一种或几种。本公开的制备方法无需焙烧,同时避免使用硼氢化钠等还原剂,并且将其用作质子交换膜电解水制氢的阳极催化剂时,具有催化活性高的优点。
Resumen de: CN121407118A
本发明公开了一种电极支撑件、极板组件、电解槽,属于电解设备技术领域,旨在解决现有电极支撑结构回弹性差、无法维持零极距导致能耗高的问题。本发明支撑件最小单元横截面为椭圆形,椭圆形截面具有各向异性力学特性,沿其短轴方向受压时能够发生均匀可控的弹性变形,且在卸载后可实现完全弹性恢复,多个螺旋条通过肋带焊接连接形成网状支撑件,并可裁剪适配电极形状。本发明支撑件能够在电解槽运行中始终维持电极间的零极距,显著降低电解能耗,同时具备优异的抗疲劳特性,支持多次复用,有效延长了电解槽使用寿命并降低了维护成本。
Resumen de: CN121407129A
本发明属于但不限于无机材料合成技术领域,公开了一种四氧化三钴负载纳米级无定形氧化铱电解水催化材料及其制备方法;配置CoCl2·6H2O、IrOx·xH2O、NaNO3混合溶液;对混合溶液进行超声处理,磁力搅拌;在烘箱特定温度干燥,得到固体粉末;此固体粉末在空气氛围下进行煅烧处理,自然冷却至室温,高温下CoCl2·6H2O和IrOx·xH2O与NaNO3发生反应并生成负载纳米级催化活性组分;通过离心收集所得产物,并用超纯水和乙醇多次洗涤,干燥后得到纳米级负载的IrOx/Co3O4催化剂。本发明制备的催化材料既降低了Ir的负载量,又提高了IrOx电解水析氧反应的催化性能和稳定性。
Resumen de: CN121407139A
本发明公开了一种四元非贵金属基碱性电解水析氢反应电催化剂及其制备方法,所述电催化剂为具有核壳结构的电催化剂,其化学式为Cu(OH)2/NiMoW。本发明制备方法是将泡沫铜阳极氧化为氢氧化铜(Cu(OH)2)纳米线,再将Cu(OH)2纳米线上浸入含有Ni、Mo、W三种元素的金属盐溶液进行电沉积而制得。本发明解决了工业级电流密度下电解水过程中过电位较大、稳定性差的问题,同时该设计提高了催化剂的结构稳定性。该材料兼具低成本及高碱性析氢活性,有望应用于工业化安培级电流密度下电解水制氢,具有较高的应用价值。同时制备方法简单、易操作,为大规模电解水制氢提供了技术可行性。
Resumen de: CN121407151A
本发明涉及水电解制氢系统排污技术领域,具体公开了一种水电解制氢系统用排污控制系统,包括氧气分离器、氢气分离器组、第一冷却器、第二冷却器、若干个控制阀、传感组件以及控制单元,氢气分离器组为氢气分离器、第一气液分离器、第二气液分离器、第一干燥气液分离器和第二干燥气液分离器,氢气分离器通过管道与氧气分离器连接,第一冷却器通过第一冷却管道与氧气分离器连接,第一冷却器通过管道连接有第三气液分离器,第三气液分离器连接有第一排污管道,第二冷却器通过第二冷却管道与氢气分离器连接。本发明的控制单元的联锁设定以及控制方法,确保了共用同一排污管道出口排污的多个分离器能够在同一时间段内只对一个分离器进行排污。
Resumen de: CN121401708A
本公开涉及一种海上制氢设备的技术领域,尤其涉及一种海上漂浮平台的气液分离装置,包括两个分离组件,两个分离组件相连通;每个分离组件均包括第一立式分离器和第二立式分离器,第二立式分离器的顶部通过法兰连接于第一立式分离器的底部;法兰的直径尺寸小于第一立式分离器以及第二立式分离器的直径尺寸;保证在无规则剧烈晃动时第一立式分离器的碱液中气体难以进入第二立式分离器,第二立式分离器的气体可进入第一立式分离器第一立式分离器液面不稳时难以影响第二立式分离器的碱液。缓冲结构设置于第一立式分离器,以减小第一立式分离器中碱液的扰动;和/或设置于第二立式分离器,用于减小第二立式分离器中碱液的扰动,提高安全性和稳定性。
Resumen de: CN121407150A
本发明公开一种纳米Mg(OH)2‑PPS织物复合隔膜的制备方法,将PPS织物中引入自由基,再经酸处理,在隔膜界面引入含氧亲水官能团,得到亲水的PPS织物隔膜。随后,利用原位生长法,使Mg(OH)2生长在亲水型PPS织物隔膜的纤维表面,赋予复合膜高气密性、低膜阻,以及提高隔膜的耐碱性和电解稳定性。本发明制备的复合膜表现出超亲水性,水滴可在1s内完全被吸收,在实际电解生产中进行500h的测试后,复合隔膜的各项性能保持稳定,表现出优异的长期稳定性和电解性能。
Resumen de: CN121407101A
本发明公开一种基于氟掺杂的三金属NiFeMn‑MOF催化剂及其制备方法与应用。本发明将镍源、铁源、锰源、有机配体和碱溶于去离子水中,搅拌混合均匀,得到混合溶液;所述镍源中镍离子:铁源中铁离子:锰源中锰离子的摩尔比为(1~3):(5~6):(1~4);将泡沫镍置于混合溶液后,水热反应,得到三金属NiFeMn‑MOF催化剂;将三金属NiFeMn‑MOF催化剂和氟源分别放于惰性气体流的下游和上游,烧制处理,得到基于氟掺杂的三金属NiFeMn‑MOF催化剂;所述氟源和三金属NiFeMn‑MOF催化剂的质量比为(300~400):40。本发明制备的催化剂用于电催化析氧,具有高效的催化活性和良好的稳定性。
Resumen de: CN121402108A
本发明属于纳米材料技术领域,具体涉及一种Ru/TiO2@Ti2C复合材料的制备及其作为原位构筑富氢环境光催化剂的应用,以TiO2、RuCl3为原料,在还原剂作用下经化学还原法将Ru定向沉积于TiO2上,制备获得Ru/TiO2纳米材料;其次在室温条件下对Ti2AlC进行刻蚀,得到Ti2C粉末;最后将Ru/TiO2纳米材料与Ti2C粉末在氩气氛围下进行球磨制得Ru/TiO2@Ti2C复合材料。本发明所储存的氢来自水,且以固体储氢的形式储存,避免了光催化产生的氢气在后续储运环节中的高能耗问题,减少了气态氢这一中间环节,更为重要的是利用氢溢流效应来构建富氢环境,并且将H*直接转移到储氢材料的表面。
Resumen de: CN121407137A
本发明属于电解水制氢能源转换技术领域,具体涉及一种氧化钼‑镍钼基化合物电解水制氢催化剂材料及其制备方法。所述方法包括:采用静电纺丝技术结合预氧化处理制备氧化钼纳米纤维基底;通过双温区钼蒸气掺杂技术在基底中引入混合价态与氧空位缺陷;利用氩‑氢低温等离子体对掺杂后的基底进行轰击处理以活化表面;通过浸泡结晶法在活化后的基底上原位生长镍钼基化合物,并经还原性热处理得到最终催化剂材料。该材料具有独特的三维分级结构,比表面积大,活性位点丰富。将其应用于电解水析氢反应时,在碱性条件下表现出优异的催化活性和稳定性,能够显著降低析氢过电位和电解能耗,且制备工艺可控,原料成本低,具有良好的应用前景。
Resumen de: KR20260013001A
수전해 시스템의 수소생산 효율 향상을 위해 코발트(Co) 및 니켈(Ni)을 포함하는 코어; 상기 코어 표면에 코팅된 코발트니켈인산화물 나노층; 및 상기 나노층의 결정구조 내에 증착 및 고정화된 백금(Pt) 단원자를 포함하는 것을 특징으로 하는, 코어-쉘 헤테로 구조를 갖는 하이브리드 수전해 촉매 합성 기술을 제공한다.
Resumen de: KR20260012987A
이온교환막 수전해 시스템의 수소생산 효율 향상을 위해 MXene표면에 고촉매활성의 루텐늄-인화 루템늄을 고밀도로 고정화한 고효율, 고내구성의 이종구조 하이브리드 수전해 촉매 합성 기술을 제공한다.
Resumen de: KR20260012903A
본 발명은 지르코늄(Zr)이 도핑된 코발트 탄산염 수산화물Zr-Co(CH) 전구체를 열수 방법을 사용하여 탄소섬유에 성장시켜 제1 나노와이어를 준비하는 단계; 상기 제1 나노와이어를 이리듐 이온(Ir3+) 용액에 함침하여 코발트 결정구조네 이리듐원자를 통합하는 단계; 및 인산화 및 환원 공정을 통하여, 제2 나노와이어를 준비하는 단계를 포함하는 음이온 교환막 수전해용 촉매의 제조방법을 제공한다. 상기 제조방법에 의하여 제조된 촉매는 OER 및 HER 반응에 모두 적용될 수 있는 촉매로서, 전자 전달 성능 향상 및 전기화학적 표면적 향상을 통하여 음이온 교환막 수전해 시스템의 효율을 개선할 수 있다.
Resumen de: KR20260012438A
그린 수소 생산 시스템 및 상기 시스템을 활용한 그린 수소 생산 방법을 제공한다. 상기 그린 수소 생산 시스템은 수전해 시스템, 폐기물 소각로 및 하이브리드 에너지 저장 시스템을 포함하는 시스템으로, 상기 폐기물 소각로에서 배출된 고온 연소가스를 고온 열원으로 사용하여 에너지 효율이 우수하고, 상기 하이브리드 에너지 저장 시스템에 의해 일정량의 전력이 지속적으로 공급되어 지속적인 수소 생산이 가능한 그린 수소 생산 시스템을 제공할 수 있다. 상기 그린 수소 생산 시스템을 활용한 수소 생산 방법은 탄소의 배출없이 생산된 고순도의 수소를 제공할 수 있다.
Resumen de: KR20260012491A
본 발명에 따른 물 순환 모드의 제어가 가능한 수전해 시스템은, 수전해 스택, 산소측 기액분리기, 수소측 기액분리기, 제어부를 포함한다. 산소측리턴배관은, 상기 산소측 기액분리기 내의 물을 상기 수전해 스택으로 리턴하기 위한 배관으로서, 상기 산소측 기액분리기로부터 상기 수전해 스택에 이르는 물의 흐름방향을 따라 제1밸브와 제1펌프가 배치된다. 수소측리턴배관은, 상기 수소측 기액분리기 내의 물을 상기 수전해 스택으로 리턴하기 위한 배관으로서, 상기 수소측 기액분리기로부터 상기 수전해 스택에 이르는 물의 흐름방향을 따라 제2밸브와 제2펌프가 배치된다. 제1연결배관은, 상기 산소측 기액분리기 내에 수용된 물과 상기 수소측 기액분리기 내에 수용된 물을 연결하도록 구성된다. 제2연결배관은, 상기 산소측리턴배관 중 상기 제1밸브와 상기 제1펌프의 사이와 상기 수소측리턴배관 중 상기 제2밸브와 상기 제2펌프의 사이를 서로 연결하도록 구성되되, 제3밸브와 제4밸브가 배치된다. 제3연결배관은, 상기 제2연결배관의 상기 제3밸브와 상기 제4밸브의 사이와 상기 제1연결배관을 연결한다. 제어부는, 상기 수전해 스택의 동작상태에 따라 상기 제1 내지 제4밸브 중 적어도 하나의 개폐 및 개폐량을 제어한다.
Resumen de: CN121407153A
本发明公开了基于氢气纯度与析氢过电位的协同优化制氢系统及方法。基于氢气纯度与析氢过电位的协同优化制氢系统,包括:电解槽、氢气纯度检测装置、电源、电参数检测装置、第一辅助参数检测装置和第二辅助参数检测装置。基于氢气纯度与析氢过电位的协同优化制氢方法,实时采集数据并通过精准计算,实时掌握析氢过电位的大小和变化趋势,以便实时协同优化调整。本方案通过实时检测氢气纯度,实时计算析氢过电位,协同优化调整电源的参数,就能满足工业级、车载级、电子级不同场景的纯度要求,让整个制氢系统的成本降低;当纯度或过电位出现异常时,电源能快速做出调整,而且能减少电极的腐蚀损耗,让电极的使用寿命延长,每年的维护成本降低。
Resumen de: WO2025005555A1
Disclosed are an ammonia partial oxidation-based hydrogen extraction catalyst, a manufacturing method therefor, and a hydrogen extraction method using the catalyst. The ammonia partial oxidation-based hydrogen extraction catalyst comprises: a support; and ruthenium (Ru) loaded on the support. The hydrogen extraction method using the catalyst allows the temperature inside a reactor to be maintained at a high temperature without an external heat source and has a long reaction time, thereby solving the existing problem of thermal efficiency reduction and enabling a high ammonia conversion rate to be obtained.
Resumen de: CN121401628A
本发明公开了一种紧凑空间电解水制氢系统的多维安全防护集成布局方法,属于氢能安全技术与危险环境设备布局技术领域;本发明制氢系统集成于集装箱撬体内,所述集装箱撬体内的安全防护布局包括:氢气探测子系统、火焰探测子系统及气体灭火子系统;所述氢气探测子系统的氢气探测器布设位置为制氢模块设备正上方、管道阀门组上方及集装箱内最高点;所述火焰探测子系统的火焰探测器布设位置为探测视角覆盖设备区并形成重叠监视区;所述气体灭火子系统灭火喷嘴的灭火剂覆盖范围与所述氢气探测器和火焰探测器的监测区域在空间上相关联并被其覆盖,本发明实现了安全防护的立体化、无盲区和系统化目的。
Resumen de: CN121407117A
本申请公开了一种模块化电解水制氢装置,涉及电解水制氢领域,其包括用于提供原料的供给单元、用于电解原料的电解单元、用于存储电解产物的存储单元和用于供电的电控单元,还包括板体组件,本申请通过第二板体在滑道内滑动,使得第一插座、第一插头之间断开连接,再旋转偏心轮使得限位凸起移出限位凹槽并解除对插块的定位,接着推动第一管体、第三管体收缩,同时,随着插块移出插槽,弹性件借助自身弹力依次推动限位板、第三杆体、密封块移动并关闭第二通道、密封槽之间的连通状态,完成对固定管和第一管体的密封,待拆卸完成后,移动第三板体,将不同的模块单独拆卸即可,管路复杂程度较低且拆卸较为快捷,提高了维护工作的便捷性。
Resumen de: CN121402113A
本发明公开了一种具有氧掺杂和氮空位的双缺陷g‑C3N4光催化剂及其制备方法,属于光催化材料技术领域,其包括以下步骤:(1)将原始g‑C3N4粉末预压成片,得到样品,然后装入高压装置的样品腔中;(2)将装有样品的高压装置置于压机中,施加压力至5.0‑6.0 GPa,然后在5.0‑6.0 GPa压力下,将温度升至200‑500 °C,并在200‑500 °C下保温保压10‑120分钟;(3)保温结束后,停止加热,将样品随炉冷却至室温,卸去压力,取出样品;(4)将取出的样品进行水洗、烘干和研磨,得到具有氧掺杂和氮空位的双缺陷g‑C3N4光催化剂。本发明在单一高温高压工艺中,同步实现了g‑C3N4的氧元素掺杂和氮空位缺陷的构建,两种缺陷位点能产生协同效应,更有效地调控光催化剂的电子结构,促进光生载流子的分离和迁移。
Resumen de: CN121407116A
本发明提供了一种制氢智能循环系统,涉及制氢系统技术领域,储液分离模块与工况适配模块连接,储液分离模块的两个输入端分别接入外部设备提供的去离子水和电解槽,用于接收并分离电解槽输出的气液混合物形成电解液循环回路;工况适配模块中换热器与储液分离模块连接,换热器并联有三条支路,第一支路设置第一自动阀,第二支路设置第二自动阀和去离子器,第三支路设置第三自动阀和加热器,电解槽出口输出氢气;控制模块通过控制阀的工作状态以实现冷启动工作模式、常态工作模式和去离子工作模块。上述系统构建了支持多模式切换及独立温控路径的智能循环系统架构,解决了传统系统冷启动慢、热管理粗放、水质调控被动等问题。
Resumen de: CN121401961A
本发明公开了一种无人机用水解镁毡供氢机构,包括固定于无人机上的水箱(1)和外壳(2),外壳(2)内设有制氢模块(3),水箱(1)侧面设有输水管(4),输水管(4)上端与外壳(2)相连,外壳(2)上方设有出氢口(5);所述制氢模块(3)包括两块端板(31),两块端板(31)之间设有多根并排分布的螺杆(32),螺杆(32)两端设有位于端板(31)外侧的锁紧螺母(33),螺杆(32)上套设有多个位于两块端板(31)之间的制氢单元(34)。本发明利用镁毡与水反应现场产生氢气,直接供给无人机的氢燃料电池,不仅供氢响应快速,而且安全可靠,还可以提升无人机的续航里程。
Resumen de: US2023287587A1
The present application relates to water electrolyzers, including water electrolyzers incorporating anion exchange membranes. The present applications also relates to materials incorporated into water electrolyzers and approaches for manufacturing water electrolyzers, as well as methods of using water electrolyzers.
Resumen de: JP2025004799A
To provide a configuration capable of grasping the recovery amount by a recovery container 14 for recovering a composition containing a by-product generated during hydrogen generation.SOLUTION: A hydrogen generation part 12 generates hydrogen by reacting a hydrogen carrier with a liquid containing water. A body part 10 has a hydrogen generation part 12. The recovery container 14 is attachable to and detachable from the body part 10 and recovers a composition containing a by-product generated together with hydrogen in the hydrogen generation part 12. A detection part 13 detects the recovery amount of the composition recovered from the hydrogen generation part 12 by the recovery container 14. A memory 17 is provided in the recovery container 14 and stores information related to the recovery amount.SELECTED DRAWING: Figure 1
Resumen de: CN121407128A
本发明属于电极材料技术领域,尤其涉及一种泡沫镍上原位重构γ相氢氧化氧镍催化剂及其制备与应用。制备方法包括:将泡沫镍浸没于0.5~5.0g/L的钼酸铵溶液中超声处理,随后将两者一并置于30~60℃稳定温场中反应得到泡沫镍负载钼酸镍前驱体;将所述前驱体用超纯水超声清洗,再于惰性气体氛围下干燥;将干燥后的前驱体固定为工作电极,KOH为电解液,Pt片为对电极、Ag/AgCl电极为参比电极组成三电极体系,联通电化学工作站后,在1.0~3.0VvsRHE区间循环伏安扫描,完成原位重构,得到目标催化剂。本发明中制备催化剂在碱性电解水析氧反应中活性优异,可有效降低体系能耗,且电子转移效率高、活性位点丰富。
Resumen de: CN121407122A
本申请提供一种水电解膜电极及其制备方法、电解槽。水电解膜电极包括依次层叠设置的阳极多孔传输层、阳极催化层、阴离子交换膜、阴极催化层和阴极多孔传输层;阴极催化层包括层叠设置的第三子催化层和第四子催化层,第三子催化层位于第四子催化层朝向阴离子交换膜的一侧;其中,第一子催化层的接触角大于第二子催化层的接触角,第三子催化层的接触角小于第四子催化层的接触角。通过分别在阳极催化层与阴极催化层中设置分层结构,能够在水电解膜电极中构建指向阳极多孔传输层和阴极多孔传输层的定向气液传输通道,能够确保反应物和产物的快速传输,极大抑制了大电流下的浓差极化,从而确保水电解膜电极在大电流密度下运行时具有理想的表现。
Resumen de: CN121407149A
本申请提供一种膜电极及其制备方法、电解槽,属于电解水制氢技术领域,膜电极包括阳极催化扩散层、阴离子交换膜、导电聚合物层和阴极催化扩散层。阳极催化扩散层包括多孔金属扩散层和形成于多孔金属扩散层其中一侧的阳极催化层,阴离子交换膜设置于阳极催化扩散层中具有阳极催化层的一侧,导电聚合物设置于阴离子交换膜背离阳极催化扩散层的一侧,阴极催化扩散层包括阴极气体扩散层和设置于阴极气体扩散层其中一侧的阴极催化层,阴极催化层位于导电聚合物层和阴极气体扩散层之间。本申请实施例提供的膜电极能够提高膜电极的动态响应性能,提升在波动性电源下快速功率调节能力与耐久性,延长使用寿命。
Resumen de: CN121407130A
本发明涉及电催化领域,具体是NiFe基LDH催化剂及其制备方法和应用。本发明提供的制备方法,创新性地在不需要外加pH调节剂条件下,运用简单的一步水热法制备得到NiFe基LDH催化剂,通过向NiFe LDH中引入金属M,诱导NiFe LDH金属间的电荷共享,降低反应能垒、稳定活性位点、促进碱性OER反应动力学的同时增强了催化剂的运行中长期稳定性,不仅实现了催化剂在AEMWE器件中低电解槽电压条件下的大电流,而且实现了大电流下的长期稳定运行,在500 mA/cm2的大电流下进行AEMWE电解水达4750 h仍然未见明显衰减,极大提升了AEMWE电解水技术的商业应用前景。
Resumen de: CN121405966A
本发明提出一种双功能配体构筑Ti基MOFs及其应用。所述Ti基MOFs由功能配体(OH)2‑BDC和NH2‑BDC共同构筑的形貌为扁平饼状且表面明显粗糙的纳米材料;其X射线衍射峰2θ=6.9°、9.8°、11.8°和18.1°,最低的带隙为1.95eV,在波长为530~800nm范围内具光吸收能力。本发明制备的双配体Ti基MOFs材料,能够同时整合2个功能基团的优势,在保持框架高稳定性的同时,实现高效的可见光催化析氢性能。
Resumen de: CN121407124A
本发明为一种基于两性离子聚合物粘结剂的电解水制氢复合电极的制备方法。该方法两性离子聚合物聚甲基丙烯酸磺基甜菜碱替代传统的离子型粘结剂Nafion,通过其独特的电中性水合层结构优化电极‑电解液界面,不仅强化了气泡的快速脱附行为,也促进了反应离子的高效传输;并利用喷涂工艺,于调控PSBMA粘结剂与催化剂之间的质量比例。本发明旨在克服现有Nafion粘结剂成本高、传质不足、界面稳定性差的缺陷,提供一种以PSBMA为粘结剂的复合电极及其制备方法,所提供的复合电极制备工艺简单、成本可控,具备良好的推广应用前景。
Resumen de: CN121402158A
本发明公开了一种高稳定性氨分解制氢催化剂及制备方法与应用,属于新能源储氢及氨氢储能技术领域。所述高稳定性氨分解制氢催化剂包括活性组分、助剂和载体,其中,活性组分为RuOx,x=2~3,且占所述高稳定性氨分解制氢催化剂质量的0.5~10%;助剂包括CaOy、MgOy、BaOy和SrOy中的一种或几种,y=1~2,且占所述高稳定性氨分解制氢催化剂质量的1~10%;载体包括介孔SiO2、介孔Al2O3、介孔TiO2和介孔ZrO2中的一种或几种,且占所述高稳定性氨分解制氢催化剂质量的85~98.5%。本发明提供了一种热稳定性优异以及贵金属Ru利用率高的氨分解制氢催化剂。
Resumen de: CN121407133A
本发明公开了一种Ni‑Ru/CF催化剂电极及其制备方法,包括泡沫铜基底以及在其表面通过电沉积负载的Ni‑Ru双金属催化活性组分,所述泡沫铜设有三维多孔结构,根所述电沉积的参数为恒电压为‑1V,时间为180s,本发明的Ru离子浓度设定为0.02M/L,沉积电压为‑1.0V,使催化剂形成均匀纳米花结构,提供高导电网络,致密纳米颗粒减少晶界电阻,加速电子从泡沫铜基底向催化剂表面传递;Ni‑Ru双金属协同优化反应动力学,降低反应能垒;电压精准控制,避免气泡覆盖电极,保障离子扩散通道畅通。
Resumen de: CN121402634A
本公开提供了一种镍基粉末、碱性电解水制氢电极及制备方法,涉及表面处理技术领域。该镍基粉末的制备方法包括:将铝粉依次通过SnCl2‑HCl溶液和PdCl2溶液进行敏化和活化处理;将活化后的铝粉加入目标溶液中,并进行水浴加热反应;其中,目标溶液包括硫酸镍、柠檬酸钠、柠檬酸、次磷酸钠和硫脲;对水浴加热后的产物进行真空抽滤、洗涤和干燥处理,以获得中间镍基粉末;将中间镍基粉末、镍粉原料、湿磨介质和成型剂置于球磨机中进行湿磨混合,以得到混合料浆;通过喷雾造粒的方式将混合料浆转化为球形团聚粉体,并对球形团聚粉体进行烧结,经冷却和过筛,以获得镍基粉末。本公开可以有效抑制因镍基涂层氧化而造成碱性电解水制氢电极性能劣化的问题。
Resumen de: CN121407115A
本发明属于质子交换膜电解水制氢领域,为了解决现有技术中多孔传输层存在的气液传质性能和机械性能不能兼顾问题,减少电解槽制造装配工艺,降低制造成本,平衡质子交换膜电解槽多孔传输层的传质和机械性能,公开了一种质子交换膜电解槽中的对称双斜孔多孔传输层。该多孔传输层在电极板流道对应位置均匀设置多个一定倾斜角度的贯通孔;所述贯通孔第一端与电极板流道连通,第二端与催化层连通,相邻的两个所述的贯穿孔对称倾斜设置,在第二端形成重合部分。该结构能够在保证气液传输性能不降低的情况下,提升多孔传输层的机械性能,结构简单、生产成本低,可以显著提升质子交换膜电解槽长周期运行的安全性,具有良好的市场前景。
Resumen de: CN121402103A
本发明公开了一种基于CdS/Co9S8既可分解水产氢又可氧化苯甲醇制备苯甲醛的可见光催化剂的制备方法,所述制备方法首先制备得到Co9S8,再通过加入Cd源和S源,进一步转化为CdS/Co9S8,本发明所制备的CdS/Co9S8催化剂可以高效地在可见光下催化水分解产氢和氧化苯甲醇制备苯甲醛,且制备方法简单,成本低,适用大面积推广应用。
Resumen de: CN121407132A
本发明提供一种低铂催化剂和制备方法及其在电解水产氢的应用。将一定比例的三聚氰胺和三聚氰酸分散在无水乙醇中,加入过渡金属前驱体溶液继续搅拌,升温继续反应并清洗过滤、干燥、研磨得到第一固体粉末;将第一固体粉末置于惰性气体下进行碳化处理,得到第二固体粉末;将第二固体粉末分散在溶解有贵金属前驱体的去离子水中,搅拌进行反应并清洗过滤、干燥后得到低铂催化剂。催化剂中Pt的含量为0.1‑10wt%。本发明制备的低铂催化剂具有优异的析氢性能,可有效地降低贵金属的使用量,提高贵金属的利用效率;该制备方法制备程序简单、成本较低,可实现批量制备,具有优异的市场价值和经济价值。
Resumen de: CN121407127A
本发明属于电极材料技术领域,具体涉及一种碳纳米管复合镍黄铁矿电极材料及其制备方法和应用。本发明提供了一种碳纳米管复合镍黄铁矿电极材料的制备方法,包括以下步骤:将可溶性铁盐、镍盐,硫脲,N,N‑二甲基甲酰胺(DMF)和乙二醇(EG)混合,得到混合溶液,再加入碳纳米管均匀分散;将所得混合物进行水热反应,得到所述碳纳米管复合镍黄铁矿电极材料。按照本发明提供的制备方法制备得到的碳纳米管复合镍黄铁矿电极材料,具有较大的比表面积和较高电导率,能够提供更多的活性位点,利于活性材料与电解液的充分接触,便于电子和离子的快速转移,从而提升了电催化剂的析氧性能。本发明提供的制备方法较为简单,适于大规模量产。
Resumen de: US20260028739A1
An electrolysis system includes an electrolyzer stack, a water source, and a cathode-side purging system. The electrolyzer stack has an anode side and a cathode side. The water source is fluidically coupled to an inlet of the anode side of the electrolyzer stack. The cathode-side purging system is fluidically coupled to a first and second outlet of the cathode side.
Resumen de: CN121407145A
本发明涉及催化材料领域,公开了一种镍钴功能化金属有机框架催化剂的制备方法及其应用。该制备方法包括:1)制备MOF‑808;2)将MOF‑808置于极性溶剂中加热回流活化,分离,真空活化,分散于扩散疏水溶剂中;将溶有镍盐和钴盐的亲水溶剂滴加至扩散疏水溶剂中扩散掺杂,交换反应后离心洗涤干燥,得镍钴功能化金属有机框架催化剂。本发明方法可避免在镍钴掺杂过程中破坏MOF的多孔有序框架结构;将本发明方法制得的镍钴功能化金属有机框架催化剂应用于光电催化水分解反应中时,可抑制活性组分溶出,从而具有优异的催化效率和稳定性。
Resumen de: WO2026019015A1
One embodiment of the present invention provides an anion-exchange membrane water electrolysis system incorporating a reference electrode, and a method for producing same. The anion-exchange membrane water electrolysis system incorporating a reference electrode according to one embodiment of the present invention places the reference electrode not between reduction (cathode) and oxidation (anode) electrodes but outside of a membrane electrode assembly, thereby allowing overvoltage of each electrode to be measured without degrading system performance.
Resumen de: TW202446996A
The present disclosure relates to an electrolysis cell comprising a porous transport layer which comprises at least one metallic support layer and at least one macroporous layer which comprises titanium particles deposited on the at least one support layer so that the titanium particles are at least partly covered with at least one conductive titanium suboxide surface layer.
Resumen de: AU2024312824A1
Proton exchange membranes are described. The proton exchange membranes comprise a reinforced membrane, a continuous nonporous hydrogen recombination catalyst coating layer comprising a mixture of hydrogen recombination catalyst and a proton conducting ionomer, and a continuous nonporous cross-linked polyelectrolyte multilayer coating comprising alternating layers of a polycation polymer and a polyanion polymer. Catalyst coated membranes incorporating the proton exchange membranes and methods of making the proton exchange membranes are also described.
Resumen de: KR20260012074A
본원 발명은 양성자 교환막용 강화막 및 이의 제조방법에 대한 것으로, 보다 구체적으로는 다공성 폴리올레핀 지지체; 및 상기 지지체 상에 형성된 블록형 탄화수소계 이오노머층을 포함하는 것을 특징으로 하는 양성자 교환막용 강화막 및 이의 제조방법에 대한 것이다. 본원 발명에 따른 양성자 교환막용 강화막은 다공성 지지체의 구속 응력으로 인해 향상된 기계적 특성과 치수 안전성을 가지는 장점이 있다.
Resumen de: CN121380482A
The invention discloses a solar-driven green hydrogen preparation and methanol conversion coupled hydrogen metallurgy integrated system and an operation method. The system comprises a photovoltaic power generation system, a water electrolysis hydrogen production system, a reducing gas preparation system, a hydrogen metallurgy system, a top gas treatment system and a methanol conversion system. Photovoltaic power generation supplies power to hydrogen production through water electrolysis; when solar energy is sufficient, part of hydrogen generated by electrolyzing water enters the reducing gas preparation system, is mixed with circulating top gas, is heated and then is introduced into the hydrogen metallurgy system, and iron ore is reduced into direct reduction iron in the shaft furnace; treating the reacted furnace top gas, partially circulating, and partially combusting to heat the reducing gas; the captured carbon dioxide and hydrogen prepared by electrolyzed water are synthesized into methanol to be stored; when solar energy is insufficient, methanol is cracked to generate hydrogen and carbon monoxide as supplementary reducing gas to maintain stable operation of the system; according to the invention, the carbon emission of the metallurgical process can be greatly reduced, and the high-quality collaborative development of renewable energy sources and high-carbon industries is promoted.
Resumen de: CN121381067A
本发明公开了一种IrO2负载的SST纳米颗粒及其制备方法和应用,所述IrO2负载SST纳米颗粒是采用溶胶凝胶法和高温热冲击方法合成的。通过将Sn、Sb共掺杂入TiO2的晶体结构中,显著提升TiO2的导电性,且保持载体的晶体结构,实现IrO2的均匀负载。此外,多余的电子能够给予Ir原子,从而抑制Ir的溶解,这能够在提升贵金属IrO2催化效果的同时降低Ir载量。三电极测试结果显示IrO2/SST在析氧反应(OER)中只需要233 mV的过电位即可达到10 mA cm2,塔菲尔斜率只有43.6mVdec1。质量活性(MA)在1.53V vs RHE时可达到498 mA mgIr‑1。
Resumen de: CN121381034A
本发明涉及电解海水制氢催化剂技术领域,具体涉及一种用于安培级大电流电解海水的异质MoOx/CoFe‑LDH催化剂及其制备方法和应用,该制备方法制备方法,通过在泡沫镍片上引入具有高价态的MoOx作为纳米阵列基底,再通过电沉积在纳米阵列基底表面原位覆盖CoFe‑LDH层,构建CoFe‑LDH与MoOx的异质结构作为抗氯层,制得异质MoOx/CoFe‑LDH催化剂。所制得的异质MoOx/CoFe‑LDH催化剂具有优异的电催化活性、导电性和耐腐蚀性优点,提升海水电解体系在大电流条件下的使用寿命和电解性能,实现安培级大电流稳定海水析氧。该催化剂可直接作为工作电极使用,工艺简便,在海水电解制氢析氧反应中具有很好的应用前景。
Resumen de: CN121381015A
本发明属于电解技术领域,具体涉及一种具有高强度的电极片及其制备方法与应用。本发明的电极片,包括n层基底层、n‑1层树脂碳层、第一微孔层和第二微孔层;电极片自上而下依次为:第一微孔层、第一基底层、第一树脂碳层、第二基底层、第二树脂碳层、…、第n‑1基底层、第n‑1树脂碳层、第n基底层及第二微孔层,其中n的数值为3‑10。本发明通过在基底层内部以及基底层之间填充树脂碳,通过巧妙的设计将多张碳纸形成适用于具有高强度高导电、高透气的电解合成双氧水用碳纸,同时,在通过对其设计双侧涂覆致密微孔层后,在保证氧扩散能力的前提下,进一步提高电极片的防水性,从而适用于电解合成双氧水。
Resumen de: CN121380987A
The invention discloses a system and a method for dehydrogenation of methyl cyclohexane by using a fuel cell. The system comprises an electrochemical dehydrogenation power generation unit which takes a solid oxide fuel cell as a reactor and is used for performing an electrochemical dehydrogenation reaction on methylcyclohexane to generate a dehydrogenation product containing toluene and simultaneously generating electric energy; the electrochemical hydrogenation unit takes a proton exchange membrane electrolytic tank as a reactor and is used for carrying out electrochemical hydrogenation reaction on toluene and hydrogen to generate methylcyclohexane; and in the material circulation loop, toluene generated by the electrochemical dehydrogenation power generation unit is at least partially conveyed to the electrochemical hydrogenation unit to serve as a reactant, and methylcyclohexane generated by the electrochemical hydrogenation unit is at least partially conveyed to the electrochemical dehydrogenation power generation unit to serve as a reactant. The electrochemical reaction path is used for replacing traditional thermocatalysis, the reaction efficiency is improved, the energy consumption is reduced, and the system is a green and efficient energy comprehensive utilization system.
Resumen de: CN121395415A
The invention discloses a wind-hydrogen mixing system energy storage capacity configuration method considering dynamic efficiency and heat balance of an electrolytic cell. Integrating an electrolytic cell dynamic efficiency model, a heat balance link model, a storage battery operation model, a fuel cell operation model, a hydrogen storage tank energy balance model, a wind power output power model and a capacity configuration objective function, and establishing a wind-hydrogen hybrid system energy storage capacity configuration model considering the electrolytic cell dynamic efficiency and heat balance; and solving the energy storage capacity configuration model of the wind-hydrogen hybrid system by using a distributed robust method to obtain a capacity configuration scheme. According to the method, through the synergistic effect of dynamic efficiency modeling and a heat balance system, the total cost of the system is reduced compared with that of a traditional method. The redundant capacity of the electrolytic cell and the fuel cell is reduced, and the capacity of the hydrogen storage tank is reasonably configured, so that the optimal balance between the investment cost and the operation risk is realized on the premise of guaranteeing the reliability of the system.
Resumen de: CN121381008A
The invention discloses a green electricity hybrid electrolytic cell hydrogen production system and an optimal configuration and multi-scale control method, and belongs to the field of water electrolysis hydrogen production. The programmable dynamic power supply is used for providing working voltage for the electrolysis array and superposing a specific alternating current or pulse electric signal for the working voltage of one or more specified electrolysis units in the electrolysis array according to a control instruction; the pulsating fluid driving unit is used for providing composite electrolyte supply consisting of steady-state basic flow and pulsating flow for each electrolysis unit according to the control instruction; the multi-mode sensing network is used for collecting internal operation state data of the electrolysis array; and the collaborative scheduling controller is a decision-making and control center of the system, generates a control instruction and sends the control instruction to related units so as to realize closed-loop optimization control of the system. According to the invention, the problems of low overall energy conversion efficiency of the system, unstable operation and accelerated attenuation of the service life of equipment caused by violent fluctuation and uncertainty of green power input power are solved.
Resumen de: JP2022191624A
To provide a silver ion water formation kit which makes it easy to know a replacement timing of a silver ion water generator.SOLUTION: A silver ion water generating kit 100 has a silver ion water generator 20 which generates silver ion water and a housing case 10 which houses the silver ion water generator 20. The housing case 10 has an opening (open hole) 15 through which fluid (water 200) enters and exits. In the housing case 10, solubility particles (e.g., vitamin agent) 25 that dissolve in the fluid (water 200) are arranged together with the silver ion water generator 20.SELECTED DRAWING: Figure 1
Resumen de: JP2025039684A
To provide means for solving the problem on radioactive contamination by applying hydrogen water to applications that are different from an application of removing a radioactive substance from soil and that appropriately exhibit functions of hydrogen water with unique properties.SOLUTION: In a method for reducing an amount of radioactivity in liquid containing a radioactive substance by dissolving hydrogen in the liquid, hydrogen may be dissolved in the liquid by mixing a substance containing a radioactive substance with hydrogen water containing hydrogen of 1.0 ppm or more.SELECTED DRAWING: None
Resumen de: JP2026011586A
【課題】成膜性及びアルカリ耐久性に優れたポリマー、及びそれを用いた電解質膜を提供する。【解決手段】下記式(1)で表される繰り返し単位を有するポリマー。TIFF2026011586000020.tif51170(式(1)中、Arは芳香族基であり、R1及びR2は、それぞれ独立に、イオン交換基又はハロゲノ基で置換されたC1-C12の直鎖、分岐又は環状のアルキル基を表し、R3及びR4は、それぞれ独立に、C1-C6の直鎖、分岐又は環状のアルキル基を表し、Xはカウンターアニオンを表す。)【選択図】なし
Resumen de: JP2026011984A
【課題】水または電解水を電気分解して得た水素を水中に溶存させ、効率よく二酸化炭素と結合させ炭化水素を含む水として、静電気などで容易に爆発することのない安全な水素エネルギー利用装置を提供する。【解決手段】半球状の水または炭酸水・炭酸を含む電解水が入る耐油性、耐薬品、耐酸性、耐アルカリ性の樹脂容器内に、電解水と電極、振動装置を設け、振動および撹拌させながら電気分解を行うことで、電解水中に水素を溶存させナノバブルおよびマイクロバブルで保存する。このとき、高圧炭酸水を添加し振動を与え、電解水中の水素や酸素から成るナノバブルおよびマイクロバブルを崩壊させる。その結果、水素原子と二酸化炭素を効率よく結合させ炭化水素を得ることができる。【選択図】図1
Resumen de: CN121381018A
本发明公开了一种低铱载量复合析氧催化剂及其制备方法和应用,属于电解制氢技术领域。制备方法为:(1)将MOF金属源、有机配体、反应溶剂、分散剂和调制剂混合反应得到粉末混合物;(2)煅烧所得粉末混合物,得到催化剂前驱体载体;(3)对催化剂前驱体载体进行酸处理,干燥后得到多孔金属氧化物粉末;(4)制备双金属前驱体粉末;(4)将两种粉末与碱性固体试剂及无机物盐混合,煅烧后得到低铱载量复合析氧催化剂。本发明的复合材料通过表面阴离子掺杂与稀土金属修饰的协同作用,有效调控氧化铱的电子结构,增强氧中间体的吸附行为,从而在极低铱负载条件下,显著提升在酸性介质中的析氧反应活性和电化学稳定性。
Resumen de: CN121381076A
本发明公开了一种非对称结构碱性水电解复合隔膜的制备方法,属于碱性水电解制氢复合隔膜领域。所述制备方法,包括如下步骤:1)将树脂、溶剂、添加剂以及亲水纳米粒子均匀混合,得到均相溶液;2)对PPS滤网进行热处理定型、表面粗糙化改性;3)在底膜表面刮涂浆料A,一次预固化后完全贴合处理过的PPS滤网,随后在PPS滤网上侧狭缝挤出涂覆浆料B,二次预固化处理,得到湿膜;4)将预固化后的湿膜置入凝固浴中相分离固化,置换萃取溶剂并洗涤干净后去除浮水。所制备的膜具有疏松层和致密层构成的非对称结构,与商用Zirfon PERL隔膜相比,所制备的隔膜具有更低面电阻和更高的泡点压力,并且具备更高的强度以及耐折性能。
Resumen de: CN121378629A
本发明涉及一种共价有机框架(COF)纳米颗粒的制备方法。该方法采用聚乙烯吡咯烷酮作为位阻稳定剂,调控成核与生长行为,获得均匀分散的纳米级COF胶体,解决传统工艺制备颗粒尺寸偏大、激子利用率低的问题。所述纳米COF材料在光吸收与电荷分离方面表现较优,可有效抑制激子复合,提升载流子生成与传输效率。该材料适用于光催化析氢等反应,并在同类条件下体现出稳定可重复的性能,适合于规模化应用的进一步开发。
Resumen de: CN121381019A
本发明公开了一种多孔传输层的制备方法,包括如下步骤:1)将含钛金属的粉末颗粒与有机溶剂混合均匀,获得混合浆料;2)将步骤1)得到的混合浆料涂覆于钛基材料表面,干燥后,得到预制气水传输层;3)将步骤2)得到的预制气水传输层进行真空烧结,冷却,得到多孔传输层。本申请的多孔传输层,仅采用含钛金属的粉末颗粒和有机溶剂的浆料体系,涂覆至钛基材料后,通过在中低温(500‑900℃)的真空条件下(≤10‑3Pa)烧结制备,可确保钛颗粒间形成烧结颈的同时,保持涂层微孔结构完整性和与钛基材料间的结合强度;相对于现有钛烧结温度≥1000℃,不仅可显著降低烧结能耗,还可避免过度烧结引起的钛颗粒涂层孔隙率降低等问题。
Resumen de: CN121380996A
本发明属于电解水制氢领域,提供一种质子交换膜电解槽极板的新型交指流道结构,包括极板主体和极板上设置的入口流道与出口流道;入口流道包括入口主流道、多个入口次流道和入口支流道;出口流道包括出口主流道、多个出口次流道和出口支流道;入口支流道与出口支流道相互平行并依次交替设置,形成交指型结构;所述入口支流道和出口支流道互相平行,并依次交替均布在所述质子交换膜电解槽极板上,形成交指型结构。该流道结构提升了流道内流体分布的均匀性,进一步降低电解过程中的压力损失与阻抗损失,从而提升了电解槽的整体性能。
Resumen de: CN121381044A
本发明涉及纳米压电析氢催化剂电催化产氢技术领域,公开了一种三异质结型高敏压电析氢催化剂的合成方法,采用水热‑煅烧‑静电自组装耦合的方法,制备得到目标催化剂;该方法先通过水热合成出硫化钼/硫化镉的异质结构前驱体,使其具有优异的析氢性能及导电性,接着将前驱体进行煅烧,破坏材料对称结构产生晶格畸变,使得压电性能增强,最后通过调控表面电荷状态,利用正负电荷间的静电吸引作用,将其与钨酸铋进行定向自组装,形成稳定的异质界面,从而合成目标催化剂;并应用于压电催化产氢系统,通过超声进行压电析氢反应产氢;本发明制备催化剂在压电催化制氢中具有优良的析氢性能及稳定性,析氢过电位明显下降,产氢量显著增加。
Resumen de: CN121381081A
本发明公开了一种电解槽气液比例监控系统与方法,系统主要包括:安装于电解槽本体的可视化监控模块、气液比例检测模块及调控执行模块,各模块与数据处理单元电连接。可视化监控模块用于实时采集电解槽内气泡的形态、数量、运动轨迹及分布图像;气液比例检测模块用于检测电解槽内电解液液位及生成气体的实时流量;数据处理单元用于对气泡图像进行分析,并且计算气液比例;调控执行模块调节电解槽的进液量或电解电流,以维持预设气液比例范围。本发明实现了对电解过程中气泡生成、分布及变化的实时观察与分析,对电解槽内气液状态的精准调控,有效提升电解反应的稳定性和效率,降低因气液比例失衡导致的能耗增加或设备损坏风险,适用于水电解、氯碱工业等各类电解工艺场景。
Resumen de: CN121395348A
The invention discloses a multi-energy collaborative optimization method for an offshore wind plant cluster collection system, and the method comprises the steps: building a corresponding energy storage equipment model, a hydrogen load matching strategy, a hydrogen energy income model, and a wind power-controllable load collaborative model through the fusion of multi-energy equipment, and taking a multi-energy coupling model as a new optimization variable. Constructing a collaborative optimization mechanism for the collection system, wherein the collaborative optimization mechanism comprises a power collaborative distribution mechanism and an equipment capacity and collection system matching mechanism; taking the comprehensive benefit of the power transmission line as an optimization target of the collection system, establishing a collection system constraint and a multi-energy equipment constraint, and forming an optimization target system; and finally, based on the optimization target system, solving the optimal collaborative topology of the collection system by adopting an improved genetic algorithm based on a dynamic variable weight minimum spanning tree. An offshore wind power cluster collection system is combined with multi-energy equipment, the optimal collaborative topology of the system is solved, and the wind curtailment cost is further reduced and the comprehensive benefits of the system are improved by stabilizing residual fluctuation through energy storage and ab
Resumen de: CN121381062A
本发明公开了一种非贵金属Ni基析氧催化剂的制备方法及应用。本发明所提供的催化剂包括硒化镍纳米颗粒和负载于所述硒化镍纳米颗粒表面的石墨烯量子点;其中,所述石墨烯量子点和所述硒化镍纳米颗粒的质量比为(1~8):50。本发明通过简单的水热反应便可在硒化镍表面负载石墨烯量子点,不但制备方法简便,而且制得的催化剂在降低成本的同时能够大幅度的降低析氧反应的过电位,在阴离子交换膜电解槽中具有较高的电化学性能和稳定性,具有广阔的应用前景。
Resumen de: CN121385502A
本发明涉及制氢系统的电性能测试技术领域,公开了一种PEM电解水制氢过程中的关键参数监测及预警方法。该方法包括:向电解槽注入复合激励信号,其振幅与实时工作电流密度、平均温度相关;采集多维度运行参数,对电压响应信号进行时频域联合处理得到时频谱图;基于时频谱图提取实时谐波失真特征向量及阻抗变化量,计算与基准向量的频谱偏移量,结合频段能量比判定故障倾向类型及区域;拼接特征向量经轻量化人工智能模型推理输出故障概率分布,执行分级预警。本发明通过多信号激励与多维参数融合分析,提升故障识别的及时性与准确性,实现电解槽运行状态的精准监测与分级预警,保障制氢过程稳定可靠。
Resumen de: CN121373468A
本发明属于电解水制氢技术领域,公开了一种AEMWE电解槽用共晶高熵合金基气体扩散层及制备方法,该方法采用气雾化法制备成分为AlFeCoCrNi2.1的共晶高熵合金球形粉末;通过SLM工艺在优化参数下建立具有三维仿晶格超结构的模型;采用选区激光熔化技术,将共晶高熵合金球形粉末根据所述模型一体化成形为气体扩散层构件后进行热处理和电化学脱合金处理,以在表面形成三维双连续纳米多孔结构。本发明将新颖的高熵合金、先进的SLM增材制造技术、结构设计理念以及系统的后处理工艺相结合,成功地创造出性能优异、结构可控、制备可靠的新型EHEA基气体扩散层,推动了高性能电解水装置的发展,为产业化应用奠定了坚实的基础。
Resumen de: CN121381032A
本发明属于水电解制氢技术领域,具体涉及一种用于PEM膜电极的铱合金催化剂及其制备方法。制备方法包括:将氯铱酸、非贵过渡金属或镧系元素的可溶性盐、熔盐研磨混合均匀,在空气气氛下煅烧,经冷却、水洗后得到铱合金催化剂。本发明显著缩短了合成周期,且能够获得性能优异且稳定的PEM阳极催化材料。
Resumen de: JP2025004800A
To provide a configuration that can suppress a rise in the pressure inside a storage container 1 for storing a hydrogen carrier or a by-product, even if keeping storage containers 1 in a manner of stacking them in the vertical direction or lay out them in the horizontal direction or the front-rear direction.SOLUTION: A pair of plane parts 16 are provided on two opposite outer wall surfaces of a storage container 1 in at least either of the vertical direction, the horizontal direction, and the front-rear direction in an installation state of the storage container 1. A recessed portion 15 is formed in a portion of at least one 16 of the pair of plane parts 16, and is formed so as to be recessed inward from another portions 16a of the plane part 16, and such that at least a part of the recessed portion is in communication with the outside of the plane part 16 in a direction along the plane part 16. A relief valve 11 is provided in the recessed portion 15, and automatically opens when the pressure inside a storage part 14 for storing a hydrogen carrier exceeds a predetermined value to release a gas inside the storage part 14 to the outside.SELECTED DRAWING: Figure 2
Resumen de: CN121381016A
本发明公开了一种用于海水电解的高稳定性NiMoW多孔块体电极材料的制备方法,属于电催化材料技术领域。该方法以镍、钼、钨粉末为原料,采用高能湿式球磨法进行充分混合与合金化处理,随后通过真空烧结工艺获得NiMoW电极材料。所制得的电极具有不规则的多级孔隙分布,显著提升了在海水电解条件下的电化学催化活性和稳定性。实验结果表明,该电极在1 M KOH+1 M NaCl溶液中表现出较低的氢析出过电位,在100 mA/cm²电流密度下的过电位不超过290mV,适用于高效率海水电解制氢系统。
Resumen de: CN121395525A
The invention provides an intelligent regulation and control system for photoelectric flexible hydrogen production. The system puts forward a multi-energy flow cooperative control concept in a breakthrough manner, constructs a multi-time scale and multi-space granularity source, network, load, storage and use cooperative optimization control model, carries out unified scheduling on new energy power generation power, electrolysis power, hydrogen storage pressure and hydrogen transmission flow, and ensures electric power balance and hydrogen balance. The system also fully considers the dynamic coupling characteristics of each process, avoids the problems of supply and demand imbalance and frequent adjustment of traditional single-process control, and realizes intelligent hydrogen production operation with high efficiency, low energy consumption and low cost.
Resumen de: CN121381048A
本发明提供了一种嵌层锂/碳化钨纳米线复合材料及其制备方法与应用。所述嵌层锂/碳化钨纳米线复合材料的结构是:锂离子嵌入碳化钨纳米线的内部晶格中。其制备方法是:首先在基底表面通过水热反应生长氧化钨纳米线前驱体;随后采用乙二胺作为碳化剂,将氧化钨纳米线转化为碳化钨纳米线结构;最后,将所得碳化钨纳米线置于含有六氟磷酸锂的电解液中,利用电化学锂调谐技术实现锂离子的嵌入,从而获得嵌层锂/碳化钨纳米线复合结构材料。本发明制备方法工艺流程简洁,安全性高,操作方便且成本低廉;所制备的复合结构在电催化性能方面表现优异,具有潜在的广泛应用价值。
Resumen de: CN121372295A
本发明适用于氨裂解制氢技术领域,提供了一种基于仿生结构的氨裂解制氢膜反应器,包括绝热外壳和设置于其内部的仿生反应器模块;所述仿生反应器模块包括主进气管道、中心管道以及多级反应支管,各级反应支管呈Y形分形拓扑结构,其内设有催化剂载体,并在分叉处连接有内置氢气选择性分离膜的氢气分离管道;反应支管外设有加热模块,分叉处布置有温度传感器、压力传感器及氢气浓度传感器。该装置通过仿生分形结构强化传热与反应,实现了反应‑分离一体化与过程智能调控,具有氨转化效率高、氢气回收率高、结构紧凑及运行稳定可靠等优点。
Resumen de: CN121381011A
本发明公开了一种自适应电极配置优化方法及系统,其特征在于,包括以下步骤:1)将泡沫镍预处理;2)备Ru3+、Cu2+的第一溶液;3)将预处理后的泡沫镍多次浸泡在第一溶液中干燥煅烧,形成中间体1;4)将中间体1浸泡在Cu2+、Fe3+的第二溶液中;5)称取一定质量的尿素加入到第二溶液中,充分搅拌混合均匀,将其移入反应釜中,水热反应后,洗涤除杂,然后干燥整夜,形成中间体2;6)将中间体2置于马弗炉中,高温煅烧,得到自适应电极。本发明提出的分级多金属复合体系,兼具高分散活性位点、强基底结合力及可调电子结构特性,满足析氧/析氢双功能催化的自适应需求。
Resumen de: CN121381050A
本发明涉及一种基于微区原电池的物相均一镍铁基析氧反应催化剂的制备方法。本发明将镍基金属基底放入铁盐溶液中浸泡,在镍基金属基底的表面生成羟基氧化铁,构筑微区原电池;再将铁盐溶液浸泡过的镍基金属基底置于包括螯合剂、镍盐、铁盐的混合溶液中,加热反应后取出干燥处理,即得物相均一镍铁基析氧反应催化剂。本发明利用三价铁盐水解在镍基金属基底上原位生成羟基氧化铁纳米颗粒,构建微区原电池体系,通过螯合剂精准调控三价铁离子水解速率,同步实现镍基底刻蚀与NiFe氢氧化物催化剂生成,合成物相均一、活性高、稳定性强的析氧反应(OER)催化剂,为高效电解水制氢提供低成本、绿色制备方案。
Resumen de: CN121381033A
本发明公开了一种铱合金电解水催化剂及制备方法,将介孔碳载体与改性剂分散于第一溶剂中,混合并干燥,得到复合碳材料;在预设惰性气体气氛下,对所述复合碳材料进行第一热处理,冷却后得到改性碳材料;基于所述改性碳材料和铱合金前驱体溶液,得到所述铱合金电解水催化剂。本发明采用改性剂对介孔碳载体进行改性后,再负载铱合金,基于介孔碳空间限域效应耦合杂原子锚定效应的双效协同机制,能够有效提升铱合金电解水催化剂的电化学活性面积和催化活性,并降低制备成本。
Resumen de: CN121381007A
本发明涉及碱性水制氢电解槽技术领域,具体涉及一种外围紧固的碱性水制氢电解槽,所述碱性水制氢电解槽包括由极板、中间极板、端极板、端压板、垫片、拉紧螺栓、碟簧、紧固螺母所组合而成,在碱性水制氢电解槽的本体外围增加设置有用于限制电解槽本体弯曲或扭曲变形从而保持电解槽本体平直度的刚性紧固加强结构。本发明通过对原有的电解槽增加外围刚性紧固加强结构,使电解槽在使用过程中因热胀冷缩产生的位移被强制限定在稳定的区域内,从而可以有效防止槽体发生弯曲、扭曲或错位,确保电解槽在整个运行过程中保持较高的平直度和结构完整性,由此提高了电解槽运行的可靠性。
Resumen de: CN121372431A
本发明实施例公开了一种金属镍/晶态金属氧化物析氢催化剂、制备方法及应用,所述制备方法包括:将镍网的表面进行粗糙化处理得到第一中间产物;将镍铝合金喷涂于第一中间产物表面,并采用碱刻蚀的方式得到表面含有金属镍的镍网;将形成金属氧化物的前驱体盐溶解在溶剂中作为前驱体溶液,将表面含有金属镍的镍网放置在前驱体溶液中,通过水热合成的方式在金属镍表面生长金属氧化物,经过洗涤干燥后得到第二中间产物;将第二中间产物在惰性气体的气氛下进行热处理,再经过洗涤干燥后得到金属镍/晶态金属氧化物析氢催化剂。通过本发明实施例,可以解决现有催化剂催化活性差、稳定性低的问题。
Resumen de: CN121372464A
本发明提供了一种光热蒸发‑光催化产氢的系统,利用本发明提供的光热蒸发‑光催化产氢复合材料能够实现海水淡化的同时进行产氢,其中碳化木(表面碳化处理的木材)能够实现光热转化,蒸发海水获得水蒸气;水蒸气作为反应原料在光催化产氢催化剂表面参与产氢反应。本发明提供的光热蒸发‑光催化产氢复合材料不仅仅能够拓宽光谱吸收,将太阳光光谱的吸收波长扩展到了可见光和近红外区域;同时还减小了界面反应电阻,并优化了电子‑空穴的分离和转移,从而提高了光能利用率,进而提升了氢气的产量。
Resumen de: CN121382148A
The invention relates to the technical field of new energy development and energy storage, and discloses a coupling system based on deep ground dry hot rock stratum hydrogen storage and geothermal energy development and a working method thereof.The coupling system comprises a ground surface subsystem, a shaft subsystem and a dry hot rock reservoir; the earth surface subsystem comprises a hydrogen production unit, a hydrogen compression and injection module, a power generation combined heat and power supply unit, a gas separation and purification module and a central control system; the gas separation and purification module is connected with a power grid; the shaft subsystem comprises underground extraction equipment, a shaft conveying system and a ground wellhead device; the shaft conveying system comprises an injection well and a production well, the hot dry rock reservoir comprises a plurality of artificial fracture networks which are communicated with one another, and monitoring modules are installed in the artificial fracture networks. Large-scale hydrogen storage and hot dry rock development are combined, hydrogen storage and efficient geothermal extraction and conversion are synchronously achieved by means of the space, the high-temperature environment and the sealing performance of a hot dry rock reservoir, and the development problem of a hydrogen storage and enhanced geothermal system is solved.
Resumen de: CN121381064A
本发明涉及一种基于裂纹诱导自钝化机制的镍钼阳极电极及其制备方法,该方法包括如下步骤:步骤一、将基底浸入A溶液中1min~25min后取出;步骤二、再将经过步骤一处理后的基底浸入B溶液中浸泡10min,得到前驱体;步骤三、将前驱体放入焦耳超快加热装置中,在空气或惰性气氛下,以大于等于100℃/min加热速率加热到380℃~450℃,并保温一定时间,冷却,得到镍钼阳极电极。该方法通过短时化学浸泡对泡沫镍三维骨架无结构性破坏,完美保留其原有的高孔隙率与互连网络,比表面积损失率降低。制备出的镍钼阳极电极利用裂纹边缘的自钝化效应与厚层的组分储备功能,将Mo溶解速率降低一个数量级,能实现低电流密度下千小时级稳定运行。
Resumen de: CN121383092A
The invention relates to the technical field of hydrogen energy preparation, in particular to hydrogen storage equipment for a hydrogen production and hydrogenation all-in-one machine, which comprises a machine body, a hydrogen production machine module and a hydrogen storage module, the hydrogen storage module is fixed in the machine body, and the hydrogen storage module is composed of a plurality of gas storage tanks; the hydrogenation module is arranged at the top of the hydrogen storage module, the hydrogenation module is a filling pump, and the inlet end of the hydrogenation module is connected with the hydrogen storage module; the dynamic design that a rotating frame carries a multi-fan-shaped filter screen body is adopted in a filtering air inlet assembly of the hydrogen production machine module, efficient anti-blocking and continuous air inlet in the catkin season are achieved in combination with a brush disc cleaning structure of a cleaning assembly, the rotating frame drives a vertical rod to rotate through a driving motor, the filter screen body is driven to do circular motion through bevel gear transmission, and the filter screen body does circular motion; and meanwhile, the transverse rotating rod drives the brush disc to brush and sweep the surface of the filter screen in real time, it is guaranteed that holes are smooth, the air pump assembly stably sucks sufficient air so that the whole filling and storing equipment can normally operate, water electrolysis hy
Resumen de: CN121380978A
本发明涉及催化剂技术领域,具体公开了一种非贵金属液体溶胶催化剂,该催化剂通过三氟乙酰丙酮、环氧氯丙烷与特定离聚物PiperION‑A5的协同作用,实现了催化剂性能的显著提升,SAXS测试显示出了微观结构的独特优势,其利用TFA强吸电子能力带来的优异封端效应,成功将减小了初级粒子的平均粒径,并大幅减少聚集体占比,特定的离聚物通过分子间相互作用构建了离聚物‑催化剂桥联网络,这种桥联方式能够显著控制催化剂在浆料中的粒径大小、分散状态,这种显著优化的粒径控制和高度分散状态,使活性位点得以充分暴露,让本发明的催化剂表现出卓越的析氧反应(OER)催化性能,并在AEMWE工况测试中展现出明显的稳定性优势。
Resumen de: CN121381059A
本发明公开了一种具有制备方法简单性能高,可稳定电解水制氢的电极材料同时公开了其衍生物用于制备净化废水光催化剂的制作方法,所述电催化剂的制备主要方法为利用稀盐酸刻蚀镍金属基底后,同时与铋源和钼酸盐一并溶于反应釜中进行水热合成,得到水热产物,将所得材料高温煅烧得到样品前驱体和部分副产物,最后重复一次反应得到具有高活性电极和相关副产物衍生物,将两个副产物混合高温煅烧研磨后得到第二段产物。本发明所制备的催化剂引入铋源作为添加剂,通过一步水热‑腐蚀‑生长法在NF基底上构建了NiMoO4/Fe2(MoO4)3复合薄膜层活性相,通过限域效应诱导活性相与NF骨架形成强界面结合,这不仅提高电子转移速率还通过降低活性相价带位置显著提升电极性能。制备流程操作简单,催化剂形貌可控,衍生副产物产生了更高的经济效益。
Resumen de: CN121381060A
本发明属于电催化材料技术领域,公开了一种NiCo2S4‑MoS2电化学催化剂及其制备方法和在碱性析氧反应中的应用,该电化学催化剂是将Ni的前驱体、Co的前驱体、络合剂和CH4N2S混合在100~250℃反应,经清洗和真空干燥处理得到NiCo2S4;将Na2MoO4·2H2O、CH4N2S和还原剂加入去离子水制得混合溶液;再将混合溶液和NiCo2S4混合经超声,在120~250℃水热反应,经离心、洗净和干燥处理制得。本发明的电化学催化剂具有优异的电催化性能,仅需265~272 mV的过电位就可达到10 mA cm‑2的电流密度,在1 A的大电流下持续工作160 h,可应用在碱性析氧反应领域。
Resumen de: CN121381054A
本发明公开了一种Co2P/RuP4@C复合电催化剂的制备方法,步骤如下:S1. 将有机膦酸BHMTPMPA、硝酸钴和尿素混合,溶于乙醇与水的混合溶液中,搅拌均匀;S2. 将上述混合溶液置于反应釜中,在140℃下反应24 h,冷却干燥后得到前驱体有机膦酸钴;S3. 将前驱体与不同体积的0.1M RuCl3·3H2O溶液混合,搅拌、洗涤、干燥;S4. 将上述产物与NaH2PO2·H2O在氮气气氛下进行高温磷化处理,得到Co2P/RuP4@C复合材料。该工艺简单、条件温和、重复性好。通过简单调控RuCl3溶液的加入量,即可有效调控催化性能,这种可控性对于工业化生产至关重要。该催化剂具有介孔与大孔并存的多级孔道结构,能提供较高比表面积和丰富活性位点的同时,还能缓解传质限制并促进气体释放,电催化析氢和析氧性能优异。
Resumen de: WO2024262442A1
A water electrolysis electrode 1 comprises a conductive substrate 10 and a layered double hydroxide layer 20. The conductive substrate 10 contains Ni. The layered double hydroxide layer 20 is provided on a surface of the conductive substrate 10. The layered double hydroxide layer 20 contains Ni. In an XRD pattern of the grazing incidence X-ray diffraction of the water electrolysis electrode 1, the ratio P003/P111 of the intensity P003 of the diffraction peak of the (003) plane of the layered double hydroxide to the intensity P111 of the diffraction peak of the (111) plane of Ni is 0.025 or less.
Resumen de: CN121381052A
本申请一实施例公开了一种La掺杂两相异质结催化剂,所述催化剂包括前驱体和非晶包覆层,所述非晶包覆层包裹所述前驱体的至少部分,所述前驱体为晶体相的La掺杂的Ni3S2,所述非晶包覆层为FeOOH。本申请具有良好的析氧性能。本发明还公开了La掺杂两相异质结催化剂的制备方法与应用。
Resumen de: CN121381005A
本发明公开一种电解水制氢电解槽用极框及电解槽,属于水电解制氢领域。所述的电解水制氢电解槽用极框,中下部开设有碱液入口、第一碱液分散口、第二碱液分散口,极框中上部开设有氢侧气液口、氧侧气液口,极框的一面设有阳极台阶,另一面设有阴极台阶和隔膜台阶,所述的第一碱液分散口、氢侧气液口内分别嵌有第一衬套,第二碱液分散口、氧侧气液口内分别嵌有第二衬套,碱液入口内嵌有第三衬套,第一衬套、第二衬套、第三衬套均呈中空筒状,分别与极框上对应的开口形状相匹配。本发明提供的极框,能够达到避免短路、提高电解效率的效果。
Resumen de: CN121381009A
本发明涉及能量转换技术领域,具体为一种光热耦合增强电解水的方法及装置。该方法以具有高光热转换能力和高催化电解水性能的单壁碳纳米管复合膜作为电解水的双功能一体化膜电极,设计调控膜电极为上层疏水的光热转换层,下层为亲水的负载了高活性催化电解水活性成分的亲水电解水层。层间通过单壁碳纳米管网络连接,使膜电极具有高热/电传输效率和优异的力学性能。亲疏水层设计使一体化膜电极可漂浮在电解质表面,通过光热耦合提高电解水效率。该方法可通过设计扁平状的电解池以提升光热增强电解水的效率,特别是在光照充足、低气温的极端环境中,具有良好应用前景。
Resumen de: CN121381049A
本发明公开了一种Fe3O4‑CoFe2O4/MoS2复合析氧电催化剂的制备与应用,属于催化技术领域。本发明采用简单的溶剂热方式将MoS2复合到NF支撑的Fe3O4‑CoFe2O4中,以制备高效的阳极析氧电催化剂。本发明制备的催化剂兼具高效电子传输通道与稳定活性界面的复合体系,在碱性条件下展现出优异的催化活性和长久的稳定性,因而具有大规模应用的潜力。
Resumen de: CN121381075A
The invention discloses a preparation method of a functional composite diaphragm, and relates to the technical field of hydrogen production through water electrolysis. The preparation method comprises the following steps: preparation of a membrane casting solution: mixing a polymer and a solvent, heating and dispersing to prepare a uniform polymer solution; the method comprises the following steps: mixing zirconium oxide, a coupling agent and a solvent, and performing ultrasonic dispersion to obtain an inorganic material dispersion liquid containing the coupling agent; under a stirring condition, adding the dispersion liquid into the polymer solution, and continuously stirring to obtain a uniform membrane casting solution; base membrane forming: coating a polyphenylene sulfide supporting net with the membrane casting solution, standing at room temperature, and drying in a drying oven to obtain a composite base membrane; and surface modification: sequentially dipping the composite base membrane in a first organic alkali solution and a second organic alkali solution, washing with a solvent after each dipping, and obtaining the functional composite diaphragm after washing.
Resumen de: CN121381080A
本发明涉及电解水制氢技术领域,公开了一种碱性电解水制氢阵列自适应优化运行方法和装置,本发明通过实时获取并分析各电解槽的运行参数,系统能够动态生成精确的健康状态值,实现了对电解槽性能衰减的实时感知与量化评估;在此基础上,结合风光预测功率与系统需求所确定的总功率,以及基于安全运行边界确定的阵列目标工况,系统能够依据各电解槽的健康度进行前瞻性的运行状态调配。这不仅将运维模式从“故障后被动处理”转变为“衰退前预见性维护”,还有效规避了非健康槽的过载运行风险,同时优化了健康槽的负载分配,从而在保障系统安全稳定、延长电解槽整体寿命的同时,显著提升了制氢阵列的运行效率与经济性。
Resumen de: CN121381002A
本发明提供了一种仿生叶脉式PEM电解池极板及方法,涉及PEM电解水制氢技术领域,电解池极板包括极板、主脉通道、侧脉通道、毛细脉通道、进水管和出水管,通过主脉通道、侧脉通道和毛细脉通道的平滑过渡、分级传输结构设计,使主脉通道承担主流体输送,侧脉通道实现二次分流,毛细脉通道延伸至极板全域,有效面积利用率≥95%,从原理上适配流体运动规律,降低转向阻力与涡流损耗,提升有效面积利用率,同时仿生分级结构使最大静压损失较传统蛇形流道降低40%以上,达到了低阻力的目的,流体在成对的极板中相对形成的闭合流道内的流速分布均匀,解决了现有流道结构存在流道阻力大、传质均匀性差、有效面积利用率低的技术问题。
Resumen de: CN121381037A
本发明公开了一种基于Ce‑FeCo‑LDH/NF的电催化分解水催化剂的制备方法,所述制备方法以泡沫镍(NF)为基底,通过原位生长得到Ce‑FeCo‑LDH/NF,本发明所制备的Ce‑FeCo‑LDH/NF催化剂可以高效地进行电催化分解水反应并且制备方法简单,成本低,适用大面积推广应用。
Resumen de: CN121380626A
The invention relates to the technical field of 3D printing, in particular to a crack-free alloy for achieving double homogenization through 3D printing and a preparation method and application of the crack-free alloy. The method comprises the steps that a metal salt precursor and a photosensitive resin solution are prepared; uniformly mixing the metal salt precursor with the photosensitive resin solution to form resin ink; a 3D printing structure is obtained based on resin ink and by means of the digital light processing 3D printing technology; sequentially sintering the 3D printing structure according to a preset temperature gradient to obtain a metal oxide; the metal oxide is treated for 4-8 h at the temperature of 800-1200 DEG C, mixed gas of hydrogen and argon is introduced, heat preservation is conducted for 5-10 h at the temperature of 400-800 DEG C, and the crack-free alloy is obtained. According to the method, the cracking phenomenon in the sintering process is reduced, and the sintered alloy structure is smooth and flat in surface and compact in microstructure.
Resumen de: CN121381053A
本发明提供一种316L不锈钢基NiFe催化剂、其制备方法及用途,所述316L不锈钢基NiFe催化剂的制备方法包括以下步骤:配置硝酸镍、硝酸铁和草酸的混合水溶液;将洁净的316L不锈钢基底浸入含有硝酸镍、硝酸铁和草酸的混合水溶液中;维持体系在60‑90℃常压条件下反应6‑12小时;反应结束后,取出产品,经去离子水、乙醇超声洗涤后,25‑80℃真空干燥,得到316L不锈钢基NiFe催化剂。本发明通过一步低温常压浸渍法在316L不锈钢基底上原位生长高性能NiFe(C2O4)2(OH)催化剂,该催化剂适用于工业级绿氢制备系统的阳极析氧反应。
Resumen de: CN121381077A
本发明公开一种碱水电解制氢隔膜及其制备方法,属于隔膜制备技术领域。包括以下步骤:将聚砜与聚苯并咪唑溶解于N,N‑二甲基乙酰胺中,在室温下搅拌、消泡,得到均相铸膜液;将所得铸膜液均匀倾倒于洁净干燥玻璃板前端,刮涂,形成液态膜;液态膜在空气中暴露后,转移至异丙醇与去离子水的混合凝固浴中发生相转化,剥离固化隔膜,依次经去离子水浸泡除残余溶剂、30wt%的KOH溶液离子溶剂化,得到西瓜皮仿生多孔复合膜,即碱水电解制氢隔膜。本发明通过创新设计制备工艺与结构,突破现有碱性电解制氢隔膜“高离子传导性与高耐久性难以兼顾”的技术瓶颈,在结构性能、电化学效能、环境适应性及长期服役稳定性等方面展现多维度优势。
Resumen de: WO2024262443A1
This electrode 1 for water electrolysis comprises a conductive base material 10 and a layered double hydroxide layer 20. The catalyst layer 20 is provided on the surface of the conductive base material 10. The layered double hydroxide layer 20 comprises a roughness layer 20r. With respect to the layered double hydroxide layer 20, the ratio Ptr of the thickness t20r of the roughness layer 20r to the thickness t20 of the layered double hydroxide layer 20 is 4.8% or more.
Resumen de: WO2024223362A1
The invention provides an electrochemical stack (1) comprising a plurality of electrochemical cells (2) oriented horizontally and arranged between a top plate (4) and a bottom plate (3) of the stack (1), wherein the top plate (4) and the bottom plate (3) are braced relative to one another by a bracing means (5). At least one connection for supplying gaseous and/or liquid media to or removing them from the electrochemical cells (2) is provided on the top plate (4). The top plate (4) has suspension means (17) configured to fasten the electrochemical stack (1) to a frame (15), wherein the bottom plate (3) is free-floating. The mounting assembly for mounting the electrochemical stack comprises a frame (15), on which the electrochemical stack (1) rests with its suspension means (17) such that the bottom plate (3) is free-floating and the electrochemical cells (2) are oriented horizontally.
Resumen de: CN121372384A
本发明公开了一种具有近红外光响应的多形貌钛酸锶光催化剂及其制备方法与产氢应用,通过水热法合成不同形貌的钛酸锶前驱体,将钛酸锶前驱体在保护性气氛下进行热处理,实现表面碳化,得到具有近红外光响应的多形貌钛酸锶光催化剂。本发明通过选择不同钛源与反应条件,可定向合成介孔微球、立方相、树枝状等多种形貌的钛酸锶,满足了不同应用场景对催化剂结构的需求。表面碳化处理在SrTiO3表面引入了缺陷和新的能级,使其光响应范围成功拓展至近红外区,能高效利用近红外光进行光解水制氢,具有广阔的应用前景。
Resumen de: CN121381071A
本发明提供一种NiFePS/Co‑ZIF‑67电催化剂及制备方法和应用,所述NiFePS/Co‑ZIF‑67电催化剂是原位生长于泡沫镍上的Co‑ZIF‑67纳米片堆叠NiFePS纳米球的三维复合纳米结构。所述NiFePS/Co‑ZIF‑67电催化剂被用作双功能电催化剂全解水时展现优异的双功能全解水性能,在HER、OER、全解水的条件下,具备良好的催化稳定性。
Resumen de: CN121380977A
本申请公开了一种耐高压差及抗波动运行的碱性电解水制氢系统,包括氢分离器、氧分离器,氢分离器和氧分离器之间设有电解槽;所述碱性电解水制氢系统还包括碱液循环单元,碱液循环单元包括相互独立的氢侧循环回路和氧侧循环回路,氢侧循环回路连接氢分离器和电解槽,氧侧循环回路连接氧分离器和电解槽。具有以下优点:以解决传统系统压差容忍度低、负载响应能力不足的问题,显著提升系统在波动工况下的运行稳定性和安全性。
Resumen de: CN121381039A
本发明提供一种铂‑镍基氧化物‑碳化钨复合自支撑电极,以钨片与铂片并联作为阳极,以镍片作为阴极,阳极与阴极间距为2~3cm,以盐酸水溶液为电解液,在恒定电压15~25V、温度40~60℃的条件下进行电化学阳极氧化和阴极电沉积耦合反应3~5h,在阴极沉积得到所述的铂‑镍基氧化物‑碳化钨复合自支撑电极的前驱体,将前驱体置于氢气与甲烷的混合气体氛围下,在500~800℃温度下进行高温还原碳化反应0.5~5h,得到铂‑镍基氧化物‑碳化钨复合自支撑电极;本发明制备工艺简单、操作安全,铂负载量低,经济效益高,易于通过控制电化学反应条件和烧炉条件来实现催化剂结构、组成和粒径的调控,从而提高复合自支撑电极的电催化活性和稳定性,具有广阔的工业化应用前景。
Resumen de: CN121372429A
本发明属于AEMWE催化应用领域,具体涉及一种Ni/NiO@RE2O3/C纳米催化剂及其百克级制备方法和应用。本发明提供的Ni/NiO@RE2O3/C纳米催化剂的百克级制备方法包括将乙酰丙酮镍和稀土醋酸盐以及碳载体于溶剂中超声分散均匀,再将所得分散液加热搅拌至蒸干后研磨,之后将研磨物于含氢气体中煅烧,以使得乙酰丙酮镍转变成Ni和NiO,且稀土醋酸盐转变为稀土氧化物。采用该方法可以实现Ni/NiO@RE2O3/C纳米催化剂的百克级规模制备,且所得Ni/NiO@RE2O3/C纳米催化剂可以显著提升碱性HER产氢效率,在AEMWE的MEA上展现出优异的电催化性能。
Resumen de: CN121382357A
The invention discloses an electricity-heat-hydrogen comprehensive energy system based on thermochemical energy storage, which is characterized in that an outlet of a thermodynamic cycle system is communicated with an inlet of a steam turbine, a steam extraction opening of the steam turbine is communicated with a shell side inlet of a thermochemical reactor, a shell side outlet of the thermochemical reactor is communicated with an inlet of a solid oxide electrolytic tank, and a shell side outlet of the solid oxide electrolytic tank is communicated with a shell side outlet of the steam turbine; a hydrogen outlet of the solid oxide electrolytic tank is communicated with an inlet of the hydrogen storage tank, an oxygen outlet of the solid oxide electrolytic tank is communicated with an inlet of the oxygen storage tank, an outlet of the hydrogen storage tank is communicated with an inlet of the combustion chamber, an outlet of the oxygen storage tank is communicated with an inlet of the combustion chamber, and an outlet of the combustion chamber is communicated with an inlet of the steam turbine. By means of the system, a unit can better absorb new energy for power generation, and stable operation of a power grid is kept.
Resumen de: CN121398905A
In the present invention, there is provided a nanoparticle comprising a plasmon metal and a catalytic metal, characterized in that: both the plasmon metal and the catalytic metal exist on the surface of the nanoparticle; wherein the nanoparticles comprise from 0.1 wt% to 5 wt% of the catalytic metal; and wherein the catalytic metal is capable of catalyzing a hydrogen evolution reaction. The invention also relates to a preparation method and application of the nanoparticles.
Resumen de: CN121381035A
本发明公开了一种PtNiCo纳米颗粒负载的碳纤维自支撑高效析氢催化材料,采用静电纺丝、滴定和焦耳热冲击技术制备得到,将PtNiCo纳米颗粒均匀分散到高导电性的NiCo/CNFs上,这两者之间的界面电荷重分配诱导的电子金属‑载体相互作用,优化了合金部位的氢解吸动力学,引发了氢溢出效应,从而促进了氢的析出。本发明制备的催化材料在减少贵金属的同时也能显著催化性能提升,在碱性电解质中具有优异的HER的催化活性,以及具有良好的稳定性和耐久性。
Resumen de: CN117050116A
The invention relates to the technical field of catalysis of tetraazacyclo nickel complexes, and particularly discloses a nickel complex based on 1, 4, 7, 10-tetraazacyclo dodecane and application of the nickel complex in catalytic hydrogen production. According to the invention, a mononuclear nickel complex Ni (cyen) Cl Cl, a binuclear nickel complex Ni (cyen) Cl2Ni (cyen) Cl and a tetranuclear nickel complex Ni (cyen) (SCN) 3Ni2 (SCN) 3Ni (cyen) are synthesized; under the condition that the overpotential (OP) is 837.6 mV, NiL1, Ni2L2 and Ni4L3 electro-catalyze hydrogen evolution of neutral water at the turnover frequencies (TOF) of 956.44, 1989.45 and 2675.25 mol per mole of catalyst per hour (mol H2/mol catalyst/h) respectively. The result shows that Ni4L3 has higher H2 generation activity than Ni2L2 and NiL1. Electrochemical testing and analysis are carried out on the catalyst, and the hydrogen production catalysis mechanism of the catalyst is researched.
Resumen de: CN121372493A
本发明涉及一种Pt@TpBTTBpy‑COF复合材料的制备及其光催化全解水性能应用。本发明的目的是为了解决普通的二组分COFs光催化剂存在的光生电子‑空穴复合,太阳光利用率低等问题,因此提供了三个单体构成的三组分COFs材料的制备方法:首先将含有Pt NPs的正丁醇溶液,1,3,5‑三醛基间苯三酚,苯并1,2‑B:3,4‑B':5,6‑B'三噻吩‑2,5,8‑三醛,5,5‑二氨基‑2,2‑联吡啶与邻二氯苯、正丁醇和醋酸混合均匀,超声处理后,在液氮浴中进行三次冻融循环脱气,密封后于120℃中加热72h,过滤并用四氢呋喃洗涤数次,干燥得到Pt@TpBTTBpy‑COF材料。本发明的制备过程简单有效,单体和溶剂比例恰到好处;且本发明提供的光催化剂能够有效提高太阳光利用率,增强光催化全解水的效率和稳定性。实验表明该复合材料具有优异的光催化全解水性能,在可见光照射下全解水产氢速率可达到286.4μmol·h‑1·g‑1,产氧速率可达到143.2μmol·h‑1·g‑1。
Resumen de: CN121376907A
本发明涉及一种紫叶李叶提取物在抑制活泼金属粉尘遇水产氢中的应用,属于湿式除尘系统金属制氢爆炸防治领域。本发明以可再生植物资源紫叶李叶为原料,通过简易水基萃取工艺开发出高效、无毒、低成本的工业级氢气惰化剂,其能够有效抑制湿式除尘系统中活泼金属粉尘的遇水产氢行为,防止系统中因氢气积聚而产生气体爆炸。本发明提供的紫叶李叶提取物作为湿式除尘系统氢气爆炸惰化剂具有经济性、环保性和可降解性的特点。
Resumen de: CN121381022A
本发明公开一种手性过渡金属氢氧化物自旋催化剂及其制备方法和应用,属于无机非金属能源材料技术领域。制备方法包括将过渡金属元素源和手性诱导剂溶于去离子水中,搅拌后缓慢加入碱液调节pH值,得浸渍液;将预处理的载体浸入浸渍液中,进行水热反应,冷却至室温,取出载体,依次用去离子水和无水乙醇洗涤,干燥,得手性过渡金属氢氧化物自旋催化剂。本发明提供的手性过渡金属氢氧化物自旋催化剂作为电极材料在电催化氧析出反应中的应用。本发明提供的手性过渡金属氢氧化物自旋催化剂具有优异的自旋选择性和高电催化析氧活性,对开发高效电解水制氢催化剂、提升清洁能源转化效率意义重大。
Resumen de: CN121395470A
The invention discloses an electrochemical energy storage collaborative storage method, device and equipment for an integrated energy system, and relates to the technical field of energy collaborative control, and the method comprises the steps: obtaining a parameter value of a measurement parameter for switching electrochemical energy storage to hydrogen production operation; identifying the parameter type of the acquired measurement parameter, wherein the parameter type comprises the residual electric quantity generated by electrochemical energy storage, the net income of transmitting the residual electric quantity from an electric quantity production place to an electric quantity supply place for selling, and the hydrogen production efficiency of converting the residual electric quantity into hydrogen; in combination with the three parameter types mentioned above, when the obtained parameter values meet the triggering conditions of one and/or multiple parameter types of the three parameter types, electrochemical energy storage is switched into hydrogen production operation, so that the specific parameter values can be obtained, and the hydrogen production efficiency can be improved. The specific numerical value of the parameter value of the measurement parameter is determined, so that the electrochemical energy storage operation is switched into the hydrogen production operation under different specific triggering conditions.
Resumen de: CN121381063A
本发明公开了一种过渡金属催化剂及其制备方法与应用,所述过渡金属催化剂具有纳米花结构,制作方法为:先配置铁盐、镍盐、尿素混合溶液,通过水热反应形成铁镍氢氧化物Fe‑Ni(OH)2,所述镍盐、铁盐的摩尔比为5~25:1,所述镍盐、尿素的摩尔比例为1.4~3.5:1;然后以Fe‑Ni(OH)2为原料,含磷化合物或磷粉作为磷源,通过化学气相沉积法,制备Fe‑NiP过渡金属催化剂,Fe‑NiP过渡金属催化剂过电位降低。本发明还进一步用气相沉积法引入硫源,在催化剂表面实现S掺杂,制备得到Fe,S‑NiP催化剂。这种方法引入的硫元素,不仅能够优化催化性能,还能够避免硫元素毒害磷化物、腐蚀基底,提升催化稳定性,本发明制得的催化剂在电催化制氢应用中具有广泛的工业应用前景。
Resumen de: CN121381027A
本申请公开了一种氢氧化钴电极,所述氢氧化钴电极为泡沫镍负载的氢氧化钴,所述氢氧化钴为非晶相氢氧化钴,所述氢氧化钴的微观结构为纳米针。本申请所得电极具有催化活性较高和反应动力学较强的特点。本申请还公开了氢氧化钴电极的制备方法与应用。
Resumen de: JP2026011065A
【課題】高収率で高純度の水素の分離回収が可能であり、膜劣化の問題が生じず長期間の使用が可能である、水素の分離回収装置を提供する。【手段】プロトン伝導体からなる筒状体、アンモニア分解手段、および、水素ポンプを備え、アンモニア分解手段は、プロトン伝導体からなる筒状体の外部空間を通るアンモニアを、水素と窒素に分解する電極を備え、水素ポンプは、水素を前記プロトン伝導体からなる筒状体の内部空間に通過させる電極を備える、水素の分離回収装置。【選択図】図1
Resumen de: CN121372246A
The invention discloses a system and a method for preparing green alcohol by coupling green hydrogen with green carbon. The system comprises an electrolytic hydrogen production device, an oxygen-enriched combustion and carbon capture device, a synthesis gas preparation device, a methanol synthesis device and a methanol rectification device, the electrolytic hydrogen production device is used for producing hydrogen and oxygen by electrolyzing water; the synthesis gas preparation device is used for producing synthesis gas through biomass gasification; the oxygen-enriched combustion and carbon capture device is used for producing carbon dioxide through oxygen-enriched combustion, flue gas recirculation and flue gas carbon capture; the methanol synthesis device is connected with the electrolytic hydrogen production device, the oxygen-enriched combustion and carbon capture device and the synthesis gas preparation device to produce crude methanol; and the methanol rectification device is connected with the methanol synthesis device to produce refined methanol. According to the invention, a low-carbon and high-efficiency renewable energy system can be constructed, and the large-scale development and utilization efficiency of wind and light resources can be effectively improved.
Resumen de: CN121380673A
The invention belongs to the field of titanium alloy materials, particularly relates to a hydrogen embrittlement-resistant beta-type titanium alloy and application thereof, and is expected to be applied to the fields of deep sea engineering, hydrogen energy and the like which bear extreme hydrogen environments. The hydrogen embrittlement-resistant beta-type titanium alloy comprises the following elements in percentage by mass: 8-28% of one or a mixture of Mo and V, 0-5% of one or a mixture of more than two of Al, Cr, Fe, Sn and Zr, and the balance of titanium, wherein the total mass fraction of the Mo and the V is 8-28%, and the total mass fraction of the Al, the Cr, the Fe, the Sn and the Zr is 0-5%. The alloy is metastable beta titanium alloy or beta single-phase titanium alloy, has high hydrogen solid solubility and inhibits brittle hydride transformation, main alloying elements are Mo and V elements, high corrosion resistance and hydrogen permeation resistance of the material are guaranteed, and other alloy elements are combined to optimize the comprehensive mechanical property of the alloy. The hydrogen embrittlement resistant beta-type titanium alloy material is reasonable in design, the preparation method is simple and controllable, and large-scale industrial application is facilitated.
Resumen de: CN121381047A
本发明提供一种Ru‑NiCoP/NF自支撑电极及其制备方法和应用。所述Ru‑NiCoP/NF自支撑电极以泡沫镍为基体,以负载在泡沫镍上的钌掺杂的磷化镍钴为活性组份,钌掺杂的磷化镍钴是具有海胆状形貌的三维复合纳米结构,钌掺杂的磷化镍钴中Ru包含Ru3+和Ru0两种价态,Ni以Ni2+的价态存在,Co包含Co2+和Co3+两种价态。所述Ru‑NiCoP/NF自支撑电极,在析氢反应与析氧反应过程中具有良好的催化活性,可用于电解水。
Resumen de: CN121373806A
本发明公开了一种用于低压环境下高活性超亲水疏气电极及其制备方法和应用,涉及电催化领域。制备方法包括以下步骤:取镍纤维毡清洗、干燥后,组装三电极系统,采用循环伏安法进行线性扫描,清洗、干燥得前驱体;采用飞秒激光加工设备进行扫描刻蚀,扫描间距为25‑300μm,形成周期性的纳米级和/或微米级结构,制备得到电极。本申请通过飞秒激光诱导亲水微纳米物理结构,进行表面重构,并通过优化扫描间距寻求高效传质和高活性位点的平衡,提高了OER反应催化活性以及高电流密度下的稳定性。具有制备工艺简便、机械强度高、传质效率优等显著优势,有利于电解水制氢设备在高海拔低气压的极端环境中稳定运行。
Resumen de: CN121381014A
本发明公开一种一体式双极板的制备方法及PEM电解槽结构,涉及电解水制氢的技术领域,该方法包括:对金属钛粉进行连续轧制处理,形成具有孔隙率和机械强度的多孔钛板生胚;依次在多孔钛板生胚上叠加铺设钛网、致密钛板以及钛网,形成复合叠层结构;钛网包括编织网、拉伸网和冲孔网,铺设层数为一层或多层;对复合叠层结构进行升温加压烧结,得到一体式双极板。本发明克服了现有的PEM电解槽结构在装配过程中存在的接触电阻大、电子传输效率低、组件错配率高等缺陷,显著提升了PEM电解槽的装配效率和电子传输效率。
Resumen de: CN121381125A
本发明公开了一种光电磁场耦合制备四氧化三钴的方法,包括如下步骤:1)在三电极体系中,引入钴源溶液,在光照和外加磁场条件下,在半导体光催化材料上电沉积,生长氢氧化钴材料;2)将所得复合材料进行退火处理,得四氧化三钴纳米片材料。本发明采用光电磁场耦合的方法在半导体光阳极材料表面生长四氧化三钴助催化剂,所得四氧化三钴材料在半导体材料表面分布均匀、尺寸可调,并有利于在四氧化三钴内部形成定向电子转移路径,催化性能优异;所需沉积电压较小,沉积时间短,可大规模制备;将所得四氧化三钴材料用作助催化剂,在中性电解液甚至海水中,仍可表现出较优异的光电催化水分解性能,适用性广。
Resumen de: CN121372244A
本发明涉及水下制氢技术领域,尤其涉及一种水下制氢系统,包括料舱和反应釜,料舱的出料口与反应釜的进料口连通,反应釜设置有进水口和排渣口,料舱的内腔设置有推料机构,料舱上设置有用于储存氢气和驱动推料机构运动的中间舱,中间舱设置有出气口,反应釜的出气口通过气体输送管与中间舱的进气口连通。本发明能够将反应后的氢气储存在中间舱中,同时推料机构能够利用中间舱中储存的氢气,利用氢气的压力作为动力,将料舱中的活性铝推送到反应釜中,而且,将反应釜排渣口的控制阀关闭后,也能够使反应釜内部的压力升高,利用内外压差将反应釜中的渣液从排渣口排出,整个过程无需外接额外动力源即可自动送料和排渣,有效节约了能源。
Resumen de: CN121380990A
本发明公开了一种基于金属锑的解耦水电解制氢装置及其应用,属于制氢技术领域。该装置,包括析氢电极、析氧电极、Sb/C电极、电解液、电解槽和外部电源;其中,析氢电极用于产氢,析氧电极用于产氧,Sb/C电极用于解耦,所述析氢电极、析氧电极、Sb/C电极位于同一电解槽中。本发明利用金属锑作为可逆的固态氧化还原介质,有效实现了析氢反应(HER)与析氧反应(OER)的时间与空间解耦。相比传统水电解体系,本发明可实现无膜条件下的分步制氢,大幅提高能量转化效率,同时降低系统复杂度与整体电解成本。
Resumen de: CN121381024A
本发明涉及PEM电解水制氢系统的高效集成组件领域,公开了一种用于PEM交换膜电解水制氢系统的高效集成组件,集成组件中的阳极电极单元包括钌基高熵金属氧化物电催化剂,钌基高熵金属氧化物电催化剂包括钌、锡、锰、铬和钽元素;钌基高熵金属氧化物电催化剂的制备方法:将固体无机钌盐、锡盐、锰盐、铬盐、钽盐和氯化钠进行研磨获得金属盐混合物;再进行球磨获得高熵金属氧化物前驱体;将前驱体进行热处理和水洗处理,获得钌基高熵金属氧化物电催化剂。本发明还公开了上述电催化剂在酸性溶液中电解水析氧反应和在PEM质子交换膜电解水制氢反应中的应用,展现出优异的电催化活性。
Resumen de: CN121381017A
本发明属于光电化学技术领域,具体涉及一种用于水分解的Mxene/Fe:CuO光电极薄膜及其制备方法。本发明采用两步电沉积法制备Mxene/Fe:CuO光电极薄膜,首先将CuCl2·2H2O和KCl溶于去离子水中再加入少量的FeCl3·6H2O制备成电沉积液,随后使用电化学工作站进行电沉积,随后在马弗炉中空气气氛下退火,得到Fe:CuO光电极薄膜,在Fe:CuO薄膜基础上再次电沉积负载Mxene得到Mxene/Fe:CuO光电极薄膜。本发明采用Fe掺杂以及表面负载Mxene的方法来改善CuO光电极薄膜的光电催化活性,显著提高了CuO光电极薄膜的分解水能力。
Resumen de: CN121377560A
本发明属于光电化学技术领域,提供了一种高性能Ce和Ag共掺杂的ZnIn2S4光电极薄膜及其制备方法和应用。采用水热法,首先将Ce(NO3)36H2O和AgNO3分别融于去离子水中制备成溶液,然后将CH4N2S、ZnCl2和InCl3加入到去离子水与无水乙醇的混合溶液中制备成前驱体溶液,并在反应釜中提前放置清洗完毕的FTO导电玻璃,将溶液置于反应釜中在烘箱中加热,得到产物Ce‑Ag:ZnIn2S4。最后在马弗炉中空气气氛下高温煅烧,得到Ce‑Ag:ZnIn2S4光电极薄膜。本发明采用Ce和Ag共掺杂的方式来改善ZnIn2S4光电极薄膜的光电催化活性,显著提高ZnIn2S4光电极薄膜的PEC性能。
Resumen de: CN121372421A
本发明公开了一种用于光热催化甲醇水蒸气制氢的三元金属氧化物及其制备方法与应用。其制备方法为:首先,通过共沉淀法制备含有具有特定比例的铜镍铟三元金属作为前驱体,然后在高温下采用空烧的方式对三元前驱体进行氧化处理,得到铜镍铟三元金属氧化物材料CuO‑NiO‑In2O3。该方法制备所得的CuO‑NiO‑In2O3材料具有优异的光热催化甲醇水蒸气制取氢气活性,在较低的温度下发挥出较高的产氢速率,并取得了很高的二氧化碳选择性,同时在加较低太阳光的条件下,产氢速率有了质的提高,可以实现低温加低太阳光强驱动的甲醇水蒸气制氢气的高效率转化。
Resumen de: CN121381055A
本发明属于材料化学技术领域,公开了一种高效析氢复合电极材料及其制备方法和应用,制备方法包括以下步骤:包括以下步骤:步骤1,清洗活化泡沫镍;步骤2,采用恒电流电沉积法,在泡沫镍的三维骨道上原位沉积W‑V基非晶前驱体薄膜,得到W‑V基非晶前驱体;步骤3将步骤2得到的所述W‑V基非晶前驱体浸入水热反应溶液进行水热反应,洗涤后得到钨钒铁铬钴共掺杂的氢氧化物FeCrCoFWV(OH)F/NF前驱体;步骤4,将FeCrCoFWV(OH)F/NF前驱体与固态磷源NaH2PO2·H2O共同置于管式炉中,在保护气氛下程序升温热处理进行磷化反应,得到钨钒铁铬钴共掺杂的磷化钴镍基复合电极材料FeCrCoWV/NF。本发明的氢复合电极材料成本低、催化活性高,易于规模化生产。
Resumen de: CN121378623A
本发明属于电解水制氢用高性能阴离子交换膜技术领域,具体公开了一种自交联型聚(芳基哌啶)阴离子交换膜材料及其制备方法和应用。聚(芳基哌啶)聚合物选为不含醚键主链,环状哌啶鎓选为阳离子基团可以有效提高膜材料的化学稳定性,其次通过在聚合物结构单元中引入弯曲构象的间三联苯单体,提高膜材料内部的自由体积,有利于离子传输,再引入自交联网络进一步促进离子传导高速通道的形成,同时限制了膜的过度溶胀,从而提高膜的离子传导率和机械稳定性。所制备的阴离子交换膜可应用于电解水制氢中。
Resumen de: CN121381045A
本发明公开了一种用于全pH环境电催化制氢的Ni2P@CoCH/CFP异质结纳米材料及制备方法。本发明所述材料以六水合硝酸钴、六水合硝酸镍、尿素、氟化铵、碳纤维纸(CF P)为原料,通过以下步骤制备:1)水热法制备Co(CO3)0.5(OH)0.11H2O/CFP(简称CoCH/C FP)前驱体:一次水热在碳纤维纸(CFP)上垂直生长出Co(CO3)0.5(OH)0.11H2O纳米针阵列(简称CoCH),得到CoCH/CFP前驱体;2)水热法制备Ni‑LDHs@CoCH/CFP前驱体:二次水热在CoCH纳米针上生长Ni‑LDHs纳米片,得到Ni‑LDHs@CoCH/CFP前驱体;3)热处理法制备Ni2P@CoCH/CFP异质结纳米材料:在氩气的保护下将Ni‑LDHs@CoCH/CFP前驱体进行低温磷化,得到Ni2P@CoCH/CFP异质结纳米材料。本发明制备的纳米材料可用于全pH环境下电解水制氢,并且能在工业安培级电流密度下稳定制氢100h。
Resumen de: WO2025008146A1
The present invention relates to a method for producing hydrogen and magnetite from water and iron in the presence of an iron(II) salt catalyst. The invention also relates to the use of the iron obtained as an indirect hydrogen store.
Resumen de: WO2024262045A1
The water electrolysis cell electrode 1 comprises a conductive substrate 10, a first layer 11, and a second layer 12. The conductive substrate 10 includes a transition metal. The first layer 11 is disposed on the conductive substrate 10 and includes two or more transition metals and oxygen. The second layer 12 is disposed on the first layer 11 and includes a layered double hydroxide (LDH) that has two or more transition metals. The first layer 11 is disposed between the conductive substrate 10 and the second layer 12 in the thickness direction of the first layer 11. The first layer 11 includes a first transition metal and a second transition metal, wherein the first transition metal is the same kind as the transition metal included in the conductive substrate 10, and the second transition metal is the same kind as the transition metal included in the second layer 12 and is different from the first transition metal. The concentration of the first transition metal in the first layer 11 is higher than the concentration of the first transition metal in the second layer 12.
Resumen de: CN121381066A
本发明属于电催化材料技术领域,更具体的说是涉及一种钒掺杂磷化钴异质复合材料的制备方法及应用。首先通过浸渍法在碳布上生长ZIF‑67前驱体,得到ZIF‑67/CC;再将ZIF‑67/CC浸泡于偏钒酸钠溶液中进行刻蚀,形成Co3V2O8/CC中间体;最后通过低温气相磷化处理,得到钒掺杂磷化钴异质复合材料,该材料在碱性的条件下具有优异的电催化析氧性能和良好的全水分解性能,并表现出优异的导电性和良好的稳定性,可作为电催化析氧反应的优良催化剂,具有一定的实际应用潜力,制备方法简单,流程短,便于商业推广。
Resumen de: CN121395250A
The embodiment of the invention relates to the technical field of photovoltaic hydrogen production, in particular to a light hydrogen storage system power control method, a light hydrogen storage system and a storage medium. According to the embodiment of the invention, the output power of the photovoltaic module is subjected to smooth filtering to obtain the photovoltaic power generation power, and the working power regulation value of the electrolytic cell is determined according to the charge state value of the energy storage battery and the expected charge interval; therefore, the smooth and stable target working power value of the electrolytic cell is determined according to the photovoltaic power generation power and the working power adjustment value, the working power of the electrolytic cell can be smoothly and stably adjusted according to the target working power value of the electrolytic cell, and the situation that power fluctuation is large in the electrolytic cell power control process is reduced or avoided. The service life of the electrolytic bath is prolonged, a high-performance super capacitor and an energy storage battery do not need to be configured, the system cost and complexity are reduced, and the system operation efficiency is improved.
Resumen de: CN121380991A
本发明提供一种集装箱式固体氧化物高温电解装置。包括集装箱箱体,所述集装箱箱体内部通过隔断划分为工艺设备区及控制辅助区;所述工艺设备区内设置有两台高温电解模块、连通各高温电解模块的辅助管路、氢气安全系统以及设置在集装箱箱体上的对外管路接口;所述控制辅助区内设置有配电柜、纯水机、制氢电源柜以及就地控制台;所述就地控制台内置控制系统,用于监控高温电解模块的运行状态,并根据用户用氢需求与外部电价信号,动态调整各高温电解模块的运行模式与工作点。本发明可根据用户用氢需求及峰谷电价,动态调整高温电解模块运行状态及工作点,具有模块化设计、操作灵活、工作可靠,易于安装扩展、效率高等特点。
Resumen de: CN121381056A
本发明公开了一种大电流高稳定电解水镍基磷化物自支撑电极及其制备方法与应用。本发明一种泡沫镍@Fe‑MoNiP自支撑电极的制备方法,包括如下步骤:S1、采用以碳棒为对电极、泡沫镍为工作电极的两电极体系,以经预热的包含镍盐、磷源、钼源的水溶液为电沉积液,进行脉冲电流沉积,得到泡沫镍@MoNiP;S2、将所述泡沫镍@MoNiP浸渍在包含铁盐的溶液中,经干燥得到泡沫镍@Fe‑MoNiP自支撑电极。本发明仅需一步电沉积法,金属配比可精确调控,钼和铁元素优化磷化镍的氢结合能,并生成最佳OER活性相,从而实现活性位点催化性能的大大提高,大大提高了在大电流密度下材料的电解水稳定性。
Resumen de: CN121372191A
本发明涉及可再生能源规模制备技术领域,尤其涉及了一种阶梯进样光催化分解水制氢进样装置,包括光催化进样器、进样器中空隔层、端口催化剂磁吸器皿、内腔,端口催化剂磁吸器皿内部设置磁力转子,光催化剂进样器外部包裹进样器外层聚光套,光催化剂进样器内部设置进样器中空隔层,中空隔层与内腔之间设置钢化玻璃,阶梯双轨道为侧壁横开的双轨道,内部设有缓压端口。本发明用于光催化制氢进样系统,在光催化剂进样器内设阶梯双轨道,增大光催化剂通过进样器进入反应器速率,降低了催化剂损耗,促使进样器内腔与催化剂磁吸器皿之间出现压力差,将光催化剂在进样阶段均匀分散,提高光催化剂利用效率,节省运行费用,减少进样器损耗。
Resumen de: CN121381043A
本发明公开了一种莫特肖特基异质结电催化材料及其制备方法和用途,该莫特肖特基异质结电催化材料的分子式为Co/VN@DDC,制备方法为:制备钴钒金属有机框架,记为CoV‑MOF;将所述CoV‑MOF与三聚氰胺混匀后,在惰性气氛中,以程序升温的方式进行退火,得到所述莫特肖特基异质结电催化材料。本发明的有益效果在于:通过利用莫特‑肖特基界面,大大增加了活性位点的可用性,并提高了氢吸附能力。由此产生的Co/VN@DDC异质结在各种pH值条件下都表现出卓越的HER性能,证明了其作为pH值通用型HER催化剂的潜力。
Resumen de: CN121380976A
本发明公开了一种氧化镍负载铂的析氢催化剂的制备方法,属于催化材料技术领域。制备方法的主要步骤为,称取四水合乙酸镍与石墨各0.2 g,研磨均匀,随后转移至马弗炉中,在空气氛围450~750℃煅烧1~3 h,得到前驱体A,称取4~18 mg前驱体A,置于一定量的浓度为0.2~1.5 mmol L‑1的H2PtCl6溶液中,超声30~60 min,随后,在反应釜中160~200℃下加热5~10 h完成水热反应,冷却至室温后,进行抽滤、干燥,即得到所制备的催化剂。本发明所制备的催化剂具有与商业Pt/C相当的催化效果,且铂的使用量较商业Pt/C显著降低,具有商业应用前景。
Resumen de: CN121381003A
本发明涉及碱性水电解制氢装置技术领域,具体公开了一种压扁电极与集流体的整体焊接结构及其制备工艺,其中,压扁电极与集流体的整体焊接结构包括集流体基板、乳突阵列、压扁电极以及焊接层。本发明显著降低了界面电阻,提升了能效,直接降低了制氢成本;增强了结构稳定性与运行可靠性,延长了设备寿命;优化了电流分布,提升了反应效率与一致性;工艺兼容性好,易于实现规模化生产;实现了“结构”与“功能”的统一。
Resumen de: CN121381074A
本发明公开了一种聚芳烷基阴离子交换膜及其制备方法与应用,属于电解水制氢技术领域,本发明在主链中引入高度疏水的全氟烷基侧链和亲水的脲基侧链,利用亲疏水热力学不相容性构建离子传输通道,而离子通道的形成便于传输氢氧根离子。引入的脲基间形成的氢键网络也促进了离子的高效传输,从而提高电导率。在机械性能上,一方面较低的离子交换容量(IEC)可以抑制过度溶胀,提升湿态下机械性能;另一方面脲基引入构建的氢键,增强了聚合物分子链间的相互作用力,提高链间缠结性,从而赋予阴离子交换膜更好的机械性能。本发明有效解决了现有用于阴离子交换膜水电解池中阴离子交换膜高离子电导率和湿态下机械性能之间的相互制约效应。
Resumen de: CN121381030A
本发明公开了一种钼酸镍/云母复合材料及其制备方法和应用,属于电解水催化剂技术领域。包括钼酸镍和云母,所述钼酸镍负载在云母上。其制备方法包括将云母粉预处理;称取云母粉、镍粉和钼粉混合后进行球磨,干燥,得前驱体;将前驱体研磨筛分,然后进行煅烧。本发明首次将钼酸镍与云母进行复合,利用云母的层状结构和优异化学稳定性,为钼酸镍提供了稳定的支撑基底,有效抑制了活性组分的团聚与脱落,所制备的复合材料具有催化活性高、机械强度好、结构稳定及成本低廉等优点,是一种析氧反应过电位低、本征活性高、运行稳定性好的新型电催化剂,可直接作为电极材料用于电解水析氧反应,具有很高的使用价值和广阔的应用前景。
Resumen de: CN121381078A
本公开涉及一种集成设计的ALK‑PEM混联系统以及运行方法,该运行方法本公开根据制氢单元接受到电网单元的实时电功率,灵活的调节PEM电解槽阵列和ALK电解槽阵列的运行状态,以使制氢单元在实时电功率较低的情况下利用PEM电解槽阵列低负荷运行;PEM电解槽阵列和ALK电解槽阵列共同作用,不仅能够降低制氢功率运行范围的下限,还能够提升该混联系统在低负荷运行时的系统能效。并且,在PEM电解槽阵列运行时,使PEM电解槽阵列出口的换热后的冷却水为所述ALK电解槽阵列预热能维持ALK电解槽阵列中电解液的温度,进而能够在实时电功率出现波动时,及时的响应,提高制氢单元消纳波动性出力的能力。
Resumen de: CN121380999A
一种PEM电解槽测试系统,涉及质子交换膜电解水技术领域,包括电解槽、补水及循环水模块、产气预处理及分析模块、氮气吹扫模块、冷凝模块、数据采集模块、控制模块和供电模块。所述补水及循环水模块设置有补水缓冲支路,用于在补水时削弱低温水对循环水温的扰动;所述产气预处理及分析模块包括平行的氢气处理系统和氧气处理系统,氢气处理系统中设置有露点仪,用于检测产出氢气的露点。本发明通过补水缓冲支路设计,有效稳定了进入电解槽的水温;通过集成露点仪,扩展了对电解槽产出气体干燥度的检测能力;系统整体构架优化,提升了测试精度与能效,降低了运行成本。
Resumen de: CN121381058A
本发明公开了一种用于制氢电解槽的电极材料及其制备方法,涉及制氢技术领域,包括以下步骤:将镍盐、四氧化三铁、乙二醇和十二烷基硫醇混合搅拌均匀;加入氨水,混合均匀后进行水热反应,洗涤、干燥,得到镍/四氧化三铁;将镍/四氧化三铁、粘结剂加入溶剂中搅拌4~6小时,喷雾干燥,得到改性镍/四氧化三铁;在惰性气氛下,将改性镍/四氧化三铁进行热处理,得到电极材料。本发明制备的电极材料具有高活性,有效提升了制氢的效率。
Resumen de: CN121377134A
本发明涉及一种高熵氧化物及其制备方法和应用,其化学式为:(NiaCobCucMgdMneAf)Fe2O4,A元素为Ga元素,组成六元高熵氧化物,相比传统的尖晶石,能够在热化学循环中制备出纯度更高的氢气,从而减少分离纯化氢气的费用。通过甲烷能够显著降低反应温度,能够在800℃下得到超过传统镍铁尖晶石的产率和纯度。本发明采用六元氧载体保障氢气产率和纯度的稳定性。
Resumen de: CN121378555A
本发明公开了一种交联型聚苯乙烯阴离子交换膜及其制备方法和应用。所述交联型聚苯乙烯阴离子交换膜的制备包括如下步骤:先以苯乙烯、对氯甲基苯乙烯为单体,在引发剂的作用下,通过本体聚合获得共聚物;然后将共聚物和1,4‑二氮杂双环2.2.2辛烷制成铸膜液进行浇铸成膜,再将所得膜浸入三甲胺水溶液中完全季铵化,最后在KOH水溶液中处理得到交联型聚苯乙烯阴离子交换膜。本发明提供了所述交联型聚苯乙烯阴离子交换膜在碱性电解水中的应用。本发明阴离子交换膜合成过程简单,试剂廉价易得,能极大地平衡传统阴离子交换膜OH‑电导率和尺寸稳定性之间的矛盾,同时具有高碱性稳定性,在碱性电解水中表现出优秀的电解性能。
Resumen de: CN120882907A
A system and method for generating hydrogen from a liquid source comprising water is disclosed. The system comprises: a high fluid velocity electrolysis cell comprising an inlet and an outlet, the inlet of the high fluid velocity electrolysis cell being fluidly connected to a liquid source; and a gas fractionation system fluidly connected to the outlet of the high fluid velocity electrolysis cell.
Resumen de: AU2024257970A1
Process for synthesis of ammonia wherein: ammonia make-up gas (7) containing hydrogen and nitrogen is reacted in an ammonia converter (15) under ammonia forming conditions thus obtaining an ammonia-containing effluent (8); a first hydrogen portion contained in the ammonia make-up gas (7) is produced by reforming a hydrocarbon source (1) in a reforming process (100); a second hydrogen portion (19) contained in the ammonia make-up gas (7) is produced separately from said reforming process (100), by using at least a renewable energy source (SE, WE); a part of said hydrogen (19) produced in step (c) is stored in a hydrogen storage (103); hydrogen (20) from said hydrogen storage (103) is used to fully or partially replace said second hydrogen portion (19) when said renewable energy source (SE, WE) is fully or partially unavailable. Said process comprising the steps of: assessing an expected flow rate of the hydrogen (19) produced in step (c); adjusting a flow rate of the hydrocarbon source (1) so that a flow rate of the first hydrogen portion in said ammonia make- up gas (7) is in a desired ratio with respect to said expected flow rate; detecting an actual amount, e.g., a filling level, of said hydrogen in said hydrogen storage (103); detecting an actual flow rate of hydrogen produced using the renewable energy source (SE, WE), and adjusting a flow rate of the hydrogen (20) from said hydrogen storage (103) depending on said actual amount detected in said hydrogen storage (103) and
Resumen de: TW202513457A
A hydrogen production device (10) has a reactor (12) for producing hydrogen by thermally decomposing a hydrocarbon gas, which is a raw material gas, using a catalyst (14), which is fine metal particles, and a fluidized bed of catalyst is formed inside the reactor by introducing raw material gas from the lower part. The reactor is configured to provide an activated catalyst.
Resumen de: WO2026019103A1
An ammonia decomposition system according to one embodiment of the present invention comprises: a decomposition device for decomposing ammonia, which comprises a heating member for heating a catalytic reactor and the catalytic reactor containing a decomposition catalyst; a plasma reforming device disposed upstream of the decomposition device so as to reform ammonia; and a reformed gas supply pipe for connecting the plasma reforming device and the decomposition device, and supplying the reformed gas generated in the plasma reforming device to the catalytic reactor and/or the heating member, wherein the plasma reforming device can pyrolyze ammonia by using plasma.
Resumen de: US20260022476A1
A vanadium oxide-based electrode for electrochemical water splitting that includes metallic substrate and a layer of particles of a vanadium oxide composite at least partially covering a surface of the metallic substrate. The particles of the vanadium oxide composite are in the form of nanobeads having an average particle size of 50 to 400 nm. A method of making the electrode.
Resumen de: KR20260010855A
본 발명의 용융도금법 기반 수전해용 레이니 Ni 촉매 제조 방법은 Ni 플레이트(Plate)를 준비하는 단계, 상기 Ni 플레이트를 용융 도금욕에 침지하여 도금하는 단계, 상기 용융 도금된 Ni 플레이트를 합금화 열처리하는 단계 및 상기 합금화 열처리된 Ni 플레이트를 화학적으로 리칭(leaching)하여 표면에 다공성 구조의 Ni 촉매층을 형성하는 단계를 포함할 수 있다.
Resumen de: AU2026200050A1
21680504_1 (GHMatters) P123644.AU 6/01/26 The invention relates to a method for configuring a plant for the production of green ammonia using renewable energies for the production of hydrogen. an a n
Resumen de: AU2024324493A1
A membrane-electrode assembly for a water electrolyser is provided. The membrane- electrode assembly comprises a polymer electrolyte membrane with a first face and a second face; an anode catalyst layer on the first face of the membrane, the anode catalyst layer comprising an oxygen evolution reaction catalyst; and a porous web of polymer fibres in contact with the anode catalyst layer, the polymer fibres comprising a conductive metal additive.
Resumen de: AU2023449815A1
A system and method of making hydrogen from water. A cylindrical reaction vessel is provided with an outer shell, a central shaft, and one or more concentric inner tubes separated by annular spaces. Water is delivered to the annular spaces by a water pump through an inlet defined in the reaction vessel. The water courses along a tortuous flow path. That path begins at an inner annular space around a central shaft. It ends at an outer annular space. The water emerges from the reaction vessel through an outlet associated with a manifold. A high-frequency vibratory stimulus is applied to the reaction vessel and water. Water molecules are dissociated into hydrogen molecules and oxygen atoms. These reaction products are delivered through the manifold along an effluent flow path to a receiving pressure vessel before deployment to a sub-assembly for harnessing clean energy.
Resumen de: US20260022480A1
An electrode including a transparent substrate and a layer of a perovskite-based nanocomposite (PTNC) material at least partially covering a surface of the transparent substrate. The PTNC material includes gold (Au) nanoparticles, graphitic carbon nitride (g-C3N4) nanoparticles, and perovskite-based nanoparticles through synergistic interaction. A method of making the electrode is described.
Resumen de: US20260022704A1
A hydrogen production plant, to produce hydrogen having a compressing assembly, for increasing the pressure of the hydrogen. The compressing assembly has at least one barrel compressor and at least one integrally geared centrifugal compressor. Also disclosed are methods of compressing hydrogen.
Resumen de: US20260022482A1
An estimation system for estimating current efficiency of an electrolyser comprises a data processing system (105) for computing heat loss of the electrolyser based on specific heat capacity of electrolyte, a flow rate of the electrolyte in a cathode side of the electrolyser, a flow rate of the electrolyte in an anode side, a temperature difference (T1c-T0c) between electrolyte circulation outlet and inlet of the cathode side, and a temperature difference (T1a-T0a) between electrolyte circulation outlet and inlet of the anode side. The current efficiency is estimated based on a difference between electric power supplied to the electrolyser and the computed estimate of the heat loss, and on a product of thermoneutral voltage of electrolysis cells of the electrolyser and electric current supplied to the electrolyser.
Resumen de: US20260022481A1
Composite anion exchange membranes are described. The composite anion exchange membranes comprise an anion exchange polymer containing a hydrogen recombination catalyst dispersed in the anion exchange polymer. The anion exchange membrane may also include a radical scavenger. The anion exchange polymer comprises a plurality of repeating units of formula (I)Catalyst coated membranes and membrane electrode assemblies made using the composite anion exchange membranes are also described.
Resumen de: US20260022478A1
Discloses are an electrocatalyst for a water electrolysis and a method of preparing the same, which includes a support made of a MXene having a two-dimensional structure; and a transition metal compound located on and heterogeneously bonded to the support, thereby increasing electrochemical activity by improving the operation stability and increasing the surface area compared to conventional commercial catalysts.
Resumen de: US20260022475A1
An ammonia electrolysis cell according to one embodiment of the present invention includes an end plate, a collector plate, a separator plate, a porous transport layer support gasket, a porous transport layer electrode, and a membrane, wherein the collector plate is connected to a power source, the power source may be characterized in that it cross-applies a working voltage and a rest voltage of 0.2 V or less. Thus, the present invention can effectively remove* NHx and OH− that poison the oxidation electrode, thereby significantly increasing the efficiency of hydrogen production, and can provide a bulk storage and transportation device for utilizing hydrogen as an energy medium.
Resumen de: US20260022471A1
A water electrolysis system including a container; a plurality of microcells located inside the container; the microcells are centered around a central axis of the container; a first bracket located on a first side of the microcells; a second bracket located on a second side of the microcells; a plurality of magnets mounted on the first and the second brackets, the magnets are placed in parallel to the microcells; a liquid inside the container. The first and the second brackets are adapted to be connected to a motor. The first and the second brackets rotate during the electrolysis process. The magnets on the first bracket produce a first magnetic field and the magnets on the second bracket produce a second magnetic field; and the first and the second magnetic fields have opposite polarity.
Resumen de: US20260022477A1
A vanadium oxide-based electrode for electrochemical water splitting that includes metallic substrate and a layer of particles of a vanadium oxide composite at least partially covering a surface of the metallic substrate. The particles of the vanadium oxide composite are in the form of nanobeads having an average particle size of 50 to 400 nm. A method of making the electrode.
Resumen de: US20260022472A1
An example electrochemical system includes: a cathode including a first electrocatalyst configured to catalyze a reduction reaction of carbon dioxide to produce water; an anode including a second electrocatalyst comprising ruthenium doped iridium oxide, the second electrocatalyst configured to catalyze an oxygen evolution reaction to produce diatomic oxygen from the water; an electrolyte connecting the cathode and the anode; and an electricity source configured to apply an electrical current across the cathode and the anode to catalyze the reduction and oxygen evolution reactions.
Resumen de: US20260022470A1
A method for producing hydrogen by means of water electrolysis, in which a direct electrolysis current is fed to one or more electrolysis units at least in a first operating mode, wherein the direct electrolysis current is supplied from a mains current using a current conversion arrangement, wherein the mains current is an alternating current, wherein the current conversion arrangement, comprises one or more first synchronous electric machines which are operable as motors and one or more second synchronous electric machines which are operable as generators, wherein the one or more first synchronous electric machines is/are operated using the mains current, wherein the one or more second synchronous electric machines is/are driven using the one or more first synchronous electric machines, and wherein the direct electrolysis current is supplied using the one or more second synchronous electric machines. The present invention also relates to a corresponding plant.
Resumen de: US20260024783A1
This disclosure relates to electrolyzer composite membranes, and in particular, to a composite membrane having at least two reinforcing layers comprising a microporous polymer structure and a surprisingly high resistance to piercing. The electrolyzer composite membranes have as recombination catalyst configured to be disposed closer to an anode than to a cathode in a membrane-electrode assembly (MEA). The disclosure also relates to membrane-electrode assemblies and electrolyzers comprising the membranes, and to method of manufacture of the membranes.
Resumen de: WO2025021544A1
The invention relates to a cell frame (100) configured to be integrated in an electrolyzer. The frame is forming a closed shape having an inner contour (InnCont) that defines an opening (Op) extending in an extension plane (ExtP1). The inner contour is presenting at least two steps (St1, St2, St3, St4, St5, St6) each comprising a first surface (S1) perpendicular to the extension plane and a second surface (S2) parallel to the extension plane. The respective second surfaces of two (St1, St3, St5) of the steps is configured to support two respective bipolar plates (BP-1, BP-21, BP-22).
Resumen de: WO2026019647A1
Composite anion exchange membranes are described. The composite anion exchange membranes comprise an anion exchange polymer containing a hydrogen recombination catalyst dispersed in the anion exchange polymer. The anion exchange membrane may also include a radical scavenger. The anion exchange polymer comprises a plurality of repeating units of formula (I). Catalyst coated membranes and membrane electrode assemblies made using the composite anion exchange membranes are also described.
Resumen de: WO2026019103A1
An ammonia decomposition system according to one embodiment of the present invention comprises: a decomposition device for decomposing ammonia, which comprises a heating member for heating a catalytic reactor and the catalytic reactor containing a decomposition catalyst; a plasma reforming device disposed upstream of the decomposition device so as to reform ammonia; and a reformed gas supply pipe for connecting the plasma reforming device and the decomposition device, and supplying the reformed gas generated in the plasma reforming device to the catalytic reactor and/or the heating member, wherein the plasma reforming device can pyrolyze ammonia by using plasma.
Resumen de: WO2026017387A1
The invention relates to an electrolysis system for hydrogen production, comprising: A DC Power source, in particular with a fluctuating power revenue, comprising: a positive power bar; and a negative power bar; A plurality of electrolyser modules, each electrolyser module comprising: A plurality of electrolyser cells; At least a first common liquid input connection; At least one common positive electric pole; At least one common negative electric pole; A liquid circuit for supplying an electrolyte to the liquid input connection of each of said electrolyser modules, connecting the electrolyser modules hydraulically; A controllable electric circuit, configured for selectively connecting and disconnecting one of: the positive electric pole of at least one of the electrolyser modules; or the negative electric pole of said at least of the electrolyser modules; to or from the respective positive or negative power bar; characterised in that the controllable electric circuit is further configured for selectively connecting and disconnecting the other of: the positive electric pole of said at least one of the electrolyser modules; and the negative electric pole of said at least one of the electrolyser modules; to or from the respective positive power bar or the respective negative power bar.
Resumen de: WO2026018801A1
Problem To provide a nickel-plated metal material for water electrolysis capable of suppressing damage to a diaphragm while maintaining a suitable gas generation surface area. Solution This nickel-plated metal material comprises: a sheet-shaped metal base material having a plurality of opening parts; and a roughened nickel layer provided on at least one surface of the metal base material. ΔRzjis on a surface on the roughened nickel layer side is 4.0 μm or less, and a developed area ratio Sdr on the surface on the roughened nickel layer side is 15.0% or more. The ΔRzjis represents the difference between the ten-point average roughness Rzjis1 of the end portion of the opening part and the ten-point average roughness Rzjis2 of the center portion between the two adjacent opening parts.
Resumen de: WO2026019015A1
One embodiment of the present invention provides an anion-exchange membrane water electrolysis system incorporating a reference electrode, and a method for producing same. The anion-exchange membrane water electrolysis system incorporating a reference electrode according to one embodiment of the present invention places the reference electrode not between reduction (cathode) and oxidation (anode) electrodes but outside of a membrane electrode assembly, thereby allowing overvoltage of each electrode to be measured without degrading system performance.
Resumen de: WO2026018874A1
An ion exchange membrane comprising: a sulfonic-acid-type membrane body containing a polymer having a sulfonic-acid group; and a reinforcement material disposed in the sulfonic-acid-type membrane body, wherein the surface roughness R1 of a first surface of the sulfonic-acid-type membrane body is lower than the surface roughness R2 of a second surface of the sulfonic-acid-type membrane body.
Resumen de: WO2026018535A1
This water electrolysis system comprises: one or more water electrolysis stacks; a water line for supplying water to each water electrolysis stack; an oxygen line for discharging an oxygen gas that is generated in each water electrolysis stack and surplus water; a hydrogen line for discharging a hydrogen gas that is generated in each water electrolysis stack and surplus water; an insulation pipe for electrically insulating the water electrolysis stacks from the pipes of the water line, the oxygen line, and the hydrogen line; and a DC power supply for supplying DC power so as to drive the water electrolysis stacks. During the operation of this water electrolysis system, water is supplied to a part in which the hydrogen gas and surplus water are mixed in the water electrolysis stacks or the hydrogen line on the upstream side of the insulation pipe of the hydrogen line.
Resumen de: WO2026018390A1
The present disclosure provides a means by which resource efficiency in hydrocarbon production can be improved. Disclosed is a method for producing hydrocarbons, wherein: a CO2 hydrate and an alkali metal ion concentrated aqueous solution are obtained from a CO2-containing gas and an alkali metal ion-containing aqueous solution; the CO2 hydrate is decomposed to obtain CO2 and water (a); the alkali metal ion concentrated aqueous solution is introduced into the anode chamber of an electrolytic cell provided with a diaphragm, water for recovery is introduced into the cathode chamber, and H2 and an alkali metal hydroxide aqueous solution are obtained by electrolysis; and the CO2 and the H2 are reacted to obtain a hydrocarbon and water (b).
Resumen de: WO2026017234A1
A system for producing hydrogen gas by reacting a metal selected from a group consisting of silicon, aluminum, magnesium, calcium, lithium, potassium and sodium and water, comprises a reaction chamber, a water supply device, configured for supplying water to the reaction chamber, a metal supply device, configured for supplying metal to the reaction chamber, a hydrogen collection arrangement, configured for collecting hydrogen gas from the reaction chamber and supplying said hydrogen gas via a main output channel to an application hydrogen consumer, and a controller, configured to control at least one of the water supply device, the metal supply device and the hydrogen collection arrangement. A water harvesting device is configured for harvesting water from air, and comprises an adsorbent, a water release device, configured to causing water to be released from the adsorbent, and a water collection device, configured to collect water released from the adsorbent, wherein the water collection device is connected to supply water to the reaction chamber. The disclosure provides a system and methods for producing hydrogen gas by reacting metal and water. The disclosure further provides a vehicle comprising said system and a portable device comprising said system.
Resumen de: WO2026016601A1
A hydrogen generation device, comprising a water tank, two electrolysis modules, a condenser, and a first humidifier, wherein the water tank has an accommodating space to accommodate electrolyzed water; the two electrolysis modules are located outside the water tank and are connected in series to each other, and each electrolysis module is configured to receive and electrolyze the electrolyzed water from the water tank to generate and output a hydrogen-containing gas to the water tank; the condenser is arranged above the water tank, and the condenser is configured to receive and condense the hydrogen-containing gas from the water tank and output the condensed hydrogen-containing gas; and the first humidifier is coupled to the condenser and has a first humidification chamber to accommodate makeup water, and the first humidifier is configured to receive the condensed hydrogen-containing gas from the condenser into the makeup water to filter and humidify the condensed hydrogen-containing gas.
Resumen de: EP4681815A1
Disclosed are a catalyst for the dehydrogenation of ammonia, a manufacturing method therefor, and a method for producing hydrogen using same. The disclosed catalyst for the dehydrogenation of ammonia comprises clay and an alkali metal and ruthenium impregnated in the clay.
Resumen de: AU2024312898A1
Composite proton exchange membranes are described. The composite protonexchange membranes comprise three layers including a proton exchange membrane layer, a continuous nonporous organic-inorganic composite coating layer, and a continuous nonporous cross-linked polyelectrolyte multilayer coating. Catalyst coated membranes incorporating the composite proton exchange membranes and methods of making the composite proton exchange membranes are also described.
Resumen de: EP4682297A1
A ceramic reversible cell including any one or more selected from the group consisting of a perovskite-type metal oxide, a hydrate of the perovskite-type metal oxide and a hydride of the perovskite-type metal oxide, in which the any one or more selected from the group consisting of the perovskite-type metal oxide, the hydrate of the perovskite-type metal oxide, and the hydride of the perovskite-type metal oxide include A (A being any one or more selected from the group consisting of Ba, Sr and Ca), B (B being any one or more selected from the group consisting of Zr, Sn, Ce, Ti and Hf), and M (M being any one or more selected from the group consisting of In, Fe, Cr and Mn) as main metal atoms, and satisfy the predetermined formula and include hydride ions when brought into an equilibrium state by contact with dry hydrogen having a water content of 20 ppm or less in a volume ratio at 500°C to 900°C.
Resumen de: CN120981607A
A selective membrane is described that includes a porous polymer membrane and a selective material on at least one outer surface. A selective material comprising a composite material of an ion exchange polymer and zirconia particles (ZrO2) distributed throughout the ion exchange polymer may be applied as a liquid by a spray method. Selective membranes made by the methods described herein are suitable for alkaline water electrolysis applications.
Resumen de: CN121013979A
The invention relates to an electrolysis device, to a method for measuring the concentration of a gas component in an electrolysis device, to a computer program product, to the use of a measurer and to a simulation program product. The electrolysis device (10) comprises a separation membrane (16) for generating hydrogen (13) and oxygen (15) from water. The electrolysis device (10) has a first line (12) for discharging hydrogen (15) in the hydrogen fluid (17), in the region of which a measuring device (20) for detecting impurities (18), for example oxygen impurities, in the hydrogen fluid (17) is arranged. According to the invention, the measuring device (20) is designed to detect an acoustic characteristic variable in the hydrogen fluid (17). The invention also relates to a method (100) which can be used for determining the concentration (32) of the impurity (18) in the electrolysis device (10). The invention further relates to a computer program product (45) which can be used to carry out such a method (100) and to a simulation program product (60) which can be used to simulate the operating behavior of such an electrolysis device (10). The invention further relates to the use of a measuring device (20) in an electrolysis device (10), said measuring device being designed to measure the velocity (42) of sound in a mixed gas (11).
Resumen de: CN120476490A
The present invention provides a reinforced ion conducting membrane comprising: (a) a reinforcement layer comprising a porous polymer structure; and (b) a polymer ion conducting membrane material impregnated within the porous polymer structure; wherein the porous polymer structure comprises a polymer backbone based on a nitrogen-containing heterocyclic ring, and the polymer ion-conducting membrane material has a transition temperature T alpha in the range of from 60 DEG C to 80 DEG C and including end values.
Resumen de: CN120936421A
A method for generating and treating a two-phase effluent from one or more pressurized electrolysis cell stacks adapted to electrolyze water into hydrogen and oxygen, whereby a pump supplies a cathodic electrolysis fluid stream from a first gas-liquid gravity separator vessel to the electrolysis cell stack, whereby another pump supplies an anode electrolysis fluid flow from a second gas-liquid gravity separator vessel to the electrolysis cell stack, and whereby at least one cyclone gas-liquid separator receives a combined effluent from the cathode electrolysis chamber and/or receives a combined effluent from the anode electrolysis chamber, these combined effluents are respectively located within respective gas-liquid gravity separator containers, whereby further, the at least one cyclonic gas-liquid separator separates the gas from the liquid within the gas-liquid gravity separator container along a substantially horizontal cyclonic axis of rotation. An electrolytic cell system is also provided.
Resumen de: CN120882908A
The invention relates to an electrolysis cell system (10) comprising at least one electrolysis cell (20) comprising at least one steam inlet (41) and at least one exhaust gas outlet (38; 39), and a turbocharger (62) for compressing the exhaust gas from the electrolysis cell (20). The turbocharger (62) comprises a driving fluid inlet, a driving fluid outlet, a compressed fluid inlet, a compressed fluid outlet, a compressor (13) and a turbine (12). The turbine (12) is configured to drive the compressor (13). A driving fluid outlet of the turbocharger (62) is fluidly connected to at least one steam inlet (41) of the electrolysis cell (20). At least one exhaust gas outlet (38; 39) is fluidly connected to a compressed fluid inlet of the turbocharger (62). The system (10) may further include a steam source in fluid connection with the drive fluid inlet of the turbocharger (62) to power the turbine (12) using pressurized steam.
Resumen de: MX2022009657A
A power generator is described that provides at least one of electrical and thermal power comprising (i) at least one reaction cell for reactions involving atomic hydrogen hydrogen products identifiable by unique analytical and spectroscopic signatures, (ii) a molten metal injection system comprising at least one pump such as an electromagnetic pump that provides a molten metal stream to the reaction cell and at least one reservoir that receives the molten metal stream, and (iii) an ignition system comprising an electrical power source that provides low-voltage, high-current electrical energy to the at least one steam of molten metal to ignite a plasma to initiate rapid kinetics of the reaction and an energy gain. In some embodiments, the power generator may comprise: (v) a source of H<sub>2</sub> and O<sub>2</sub> supplied to the plasma, (vi) a molten metal recovery system, and (vii) a power converter capable of (a) converting the high-power light output from a blackbody radiator of the cell into electricity using concentrator thermophotovoltaic cells or (b) converting the energetic plasma into electricity using a magnetohydrodynamic converter.
Resumen de: JP2026009582A
【課題】 水素の生成を確実に効率良く行うことができる水素生成装置を提供する。【解決手段】 アルカリ性の反応液が貯留される反応槽10と、金属材料を含む原料を反応槽10に連続的に供給する原料供給装置20と、原料供給装置20の作動を制御する制御装置とを備え、反応槽10において金属材料と反応液とを反応させることにより水素を生成する装置1であって、反応槽10から排出される水素の流量を測定する流量測定部33を更に備え、制御装置は、流量測定部33の測定に基づき、反応槽10への原料の供給を制御する。【選択図】 図1
Resumen de: WO2024132577A1
A process for producing a synthesis gas product comprising hydrogen by an endothermic reaction of a feedstock, said process comprising the following steps: - Supplying a first fuel gas comprising at least 20% of ammonia at a first flow rate into a combustion chamber, - Supplying a second fuel gas comprising at least 10% of hydrogen at a second flow rate into the combustion chamber, at least a first portion of one of the fuel gas being delivered separately from the other fuel gas into the combustion chamber, - Supplying an oxidizing gas stream, - Performing a combustion of the supplied first fuel gas and the supplied second fuel gas with the supplied oxidizing gas stream in the combustion chamber to provide heat to the endothermic reaction.
Resumen de: WO2024132587A1
A process for producing a synthesis gas product by an endothermic reaction of a feedstock stream, said process comprising the following steps: - Providing an ammonia fuel stream, - Performing a first combustion in which the ammonia fuel stream is partially burned, generating heat and a combustion flue gas stream comprising an unburned portion of ammonia fuel stream being not burned, - Providing heat from the first combustion and from the combustion flue gas stream to the endothermic reaction, thereby obtaining a cooled flue gas stream, - Performing a second combustion of the cooled flue gas stream in which the unburned portion of ammonia fuel stream is burned, - Providing heat from the second combustion to the endothermic reaction.
Resumen de: AU2024240321A1
An electrochemical system includes a counter electrode and a working electrode spaced from the counter electrode. The working electrode includes a substrate, an array of conductive projections supported by the substrate and extending outwardly from the substrate, each conductive projection of the array of conductive projections having a semiconductor composition, and including a surface, the surface including nitrogen, and an oxynitride layer disposed on the surface. The counter electrode and the working electrode are arranged in a two-electrode configuration.
Resumen de: EP4682296A1
A solid oxide-type electrolysis cell system includes: a solid oxide-type electrolysis cell; a combustion unit configured to combust a fuel electrode off-gas from a fuel electrode of the solid oxide-type electrolysis cell; a case that has a heat insulating property and houses the solid oxide-type electrolysis cell and the combustion unit; a water and steam supply unit configured to supply water or steam to a fuel supply line connected to the fuel electrode; a preheating unit provided in the case and configured to preheat water or steam flowing through the fuel supply line by combustion heat of the combustion unit; a condensation unit provided outside the case and configured to condense steam contained in the fuel electrode off-gas from the fuel electrode; and a combustion reflux line configured to reflux a part of the fuel electrode off-gas having passed through the condensation unit by driving a pump and to supply the part of the fuel electrode off-gas to the combustion unit.
Resumen de: EP4682295A1
A solid oxide electrolysis cell system includes: a solid oxide electrolysis cell; a heat storage unit configured to store exhaust heat from outside of the system; a steam generation unit provided in a fuel supply line extending from a water source to a fuel electrode of the solid oxide electrolysis cell and configured to generate steam by using the heat stored in the heat storage unit; and a heat exchange unit provided downstream of the steam generation unit in the fuel supply line and configured to heat, by using the exhaust heat from the solid oxide electrolysis cell, the steam.
Resumen de: CN120957794A
The present invention relates to the technical field of electrolysis and, in particular, to a degassing device for an electrolysis plant for producing dihydro (H2) and dioxygen (O2) by electrolyzing water. According to the invention, the apparatus comprises a degassing device (1, 101) comprising a degassing chamber (14, 114), the degassing chamber (14, 114) is provided with an opening for a gas-liquid mixture supply pipe (11, 111), an opening for a liquid discharge pipe (12, 112) arranged below the level of the gas-liquid interface (15, 115) of the degassing chamber (14, 114), and an opening for a gas discharge pipe (13, 113) arranged above the level of the gas-liquid interface (15, 115) of the degassing chamber (14, 114). Furthermore, a static mixer (21, 121) is inserted into the gas-liquid mixture supply tube (11, 111).
Resumen de: AU2024236667A1
The present disclosure is directed to a geothermal hydrogen production and compression system, wherein the system comprises an impure water intake to receive water from a impure water source, at least one geothermal well having a well inlet to receive the impure water from the impure water intake in to the geothermal well and one or more well outlets adapted to return heated impure water from the geothermal well, one or more well outlets being adapted to direct the heated impure water from the geothermal well through a steam engine providing a mechanical output, a purification plant comprising one or more purification chambers for separating impurities from the heated impure water expelled from the steam engine to produce at least some fresh water, one or more discharge outlets to discharge one or more products of the purification plant wherein the fresh water is directed to an electrolyser for electrolysis to produce hydrogen gas, where the hydrogen gas is passed through a hydrogen compressor coupled to the mechanical output and pressurised in a storage apparatus.
Resumen de: CN121360464A
本发明涉及氢气纯化的技术领域,尤其涉及一种多干燥器交替选择性氢气纯化系统,包括:除杂组件,包括气水分离部件、与气水分离部件相连的脱氧件以及与脱氧件相连的氢气冷却件;干燥组件,所述干燥组件设置有若干组,每组所述干燥组件包括与氢气冷却件相连的再生冷却件以及与再生冷却件相连的干燥部件;切换组件,所述切换组件设置在氢气冷却件与多组干燥组件之间,利用多组干燥箱体所形成的不同工作状态,从而对氢气的纯化进行不同层级的操作,增加氢气纯化的效率和纯化成品率。
Resumen de: CN121362996A
本发明涉及电催化材料技术领域,尤其是CeFe@C/NF自支撑电催化材料、制备方法及应用,包括将铁盐、对苯二甲酸和苯甲酸溶解在N,N‑二甲基甲酰胺、乙醇和水的混合溶液中,然后进行第一次水热反应,煅烧,得到Fe基MOF前驱体MIL‑53(Fe)的衍生物粉末;将Fe基MOF前驱体MIL‑53(Fe)的衍生物粉末、硝酸铈六水化合物和聚乙烯吡咯烷酮加入到乙醇、乙二醇和水的混合溶液中,混合均匀,得到混合溶液;将泡沫镍放入混合溶液中进行第二次水热反应,得到CeFe@C/NF自支撑电催化材料。该方法通过采用一元羧酸苯甲酸作为结构调控剂获得显微结构和晶体结构可控的超薄纳米片状Fe基MOF前驱体MIL‑53(Fe)纳米片,将其煅烧后并与CeO2原位负载,解决了现有技术中存在的电催化剂制作成本高,过电势较高和催化活性较低问题。
Resumen de: WO2025051333A1
The invention relates to a plate-like element (10) of a cell stack (2) of an electrochemical system (1), having a first plate side (26), a second plate side (27), a plurality of openings (13, 21, 22, 23, 23') and a first structure (14) for forming a flow field for coolant and several further structures (14') for forming distributors for operating media on the first plate side (26). The structure (14) comprises a coolant conducting structure (15, 16) through which a first coolant path (15) and a second coolant path (16) arranged mirror-symmetrically thereto are formed, each of which have, starting from one of the openings (21), an elongate inflow portion (17), a centre portion (18) which starts from the inflow portion (17), fans out and describes at least one meandering bend (19), and an elongate outflow portion (20) which adjoins the centre potion (18) and is narrower than the centre portion (18). A longitudinal axis (30) of the inflow portion (17) of the first coolant path (15) matches a longitudinal axis (30) of the outflow portion (20) of the second coolant path (16), and a longitudinal axis (30') of the inflow portion (17) of the second coolant path (16) matches a longitudinal axis (30') of the outflow portion (20) of the first coolant path (15). The invention also relates to a cell stack (2) comprising a plurality of such plate-like elements (10) which are parallel to one another.
Resumen de: CN121367208A
The invention discloses a hydrogen production system flexibility improving method based on multi-source cooperation and self-adaptive regulation and control, and belongs to the technical field of new energy. The method is executed by taking a digital twinborn body as a global decision center, and comprises the following steps: acquiring predicted data of wind-solar power generation power, a real-time frequency deviation signal of a power grid and an operation state of each electrolytic cell in a hydrogen production system; based on the prediction data and the frequency deviation signal of the wind-solar power generation power, a global optimization scheduling instruction is generated by taking improvement of the flexibility and the economy of the system as a target; according to the global optimization scheduling instruction, cooperatively controlling dynamic reconfiguration of the electrolytic cell and applying virtual synchronous generator (VSG) control to a hydrogen production load; and actual operation data after cooperative control are collected and fed back to the equipment fatigue loss analysis model and the wind and light output prediction model for dynamic correction of fatigue damage evaluation and power prediction in the next period. According to the method, the operation cost of the system is effectively reduced, and meanwhile the flexibility of the new energy hydrogen production system is greatly improved.
Resumen de: CN121363003A
The invention provides a state control method for a mixed type electrolytic cell array and computer equipment, and the method comprises the steps: obtaining the real-time wind power in a wind power hydrogen production system and the running state of electrolytic cells in a plurality of electrolytic cell arrays in the wind power hydrogen production system, and obtaining the running state of the electrolytic cells in the plurality of electrolytic cell arrays according to the real-time wind power; the number of required electrolytic cells corresponding to all the electrolytic cell arrays is obtained, the electrolytic cells in all the electrolytic cell arrays are grouped according to the running states of the electrolytic cells in all the electrolytic cell arrays, and multiple electrolytic cell sets corresponding to all the electrolytic cell arrays are obtained and comprise the first electrolytic cell set in the production state, the second electrolytic cell set in the production state and the third electrolytic cell set in the production state; and according to the number of the required electrolytic cells and the number of the electrolytic cells of the first electrolytic cell group, the operation states of the electrolytic cells in part of the electrolytic cell groups are controlled and switched. Therefore, the running state of the electrolytic cell can be adaptively adjusted according to dynamic changes of wind power, and the wind energy utilization rate and the hydrogen produ
Resumen de: CN121362990A
本发明属于水电解制氢催化剂技术领域,涉及一种金属单原子析氢催化剂及其制备方法,催化剂中包括大量的金属单原子以及少量金属团簇,金属在催化剂中处于氧化状态,催化剂中存在晶态PMA;催化剂中C60与PMA结构共存;制备方法包括:将乙酰丙酮金属络合物、磷钼酸与富勒烯分别溶于4A型分子筛的甲苯溶液中,并分别依序混合并磁力搅拌后洗涤、离心获得金属单原子析氢催化剂;本发明金属单原子析氢催化剂具有优秀的HER性能,室温合成策略实现了高负载量、高分散的金属单原子桥接C60与PMA的PMA‑M‑C60催化剂,且催化成本更低。
Resumen de: WO2024132579A1
A process for producing a synthesis gas product comprising hydrogen from an endothermic cracking reaction of an ammonia feedstock stream, comprising the following steps: - Providing an ammonia feedstock stream, - Performing a catalytic conversion by catalytically converting the ammonia feedstock stream by cracking endothermically said ammonia feedstock stream into a synthesis gas product comprising hydrogen, - Performing heat exchanges step by performing heat exchanges between the synthesis gas product and the catalytic conversion of the ammonia feedstock stream, said heat exchanges step comprising the following steps: • Discharging the synthesis gas product in a synthesis gas product circulation duct, said duct being arranged for the heat exchanges between the discharged synthesis gas product and the catalytic conversion of the ammonia feedstock stream, • Recovering heat from the discharged synthesis gas product, • Directing the recovered heat to the catalytic conversion of the ammonia feedstock stream.
Resumen de: CN121366919A
The invention discloses a composite modified anti-pollution proton exchange membrane and a preparation method thereof, belongs to the technical field of proton exchange membranes, and is suitable for hydrogen fuel cells, microbial fuel cells and water electrolysis hydrogen production equipment. In order to solve the problems that an existing proton exchange membrane is single in anti-pollution dimension, high in cost depending on precious metal and insufficient in acid resistance and mechanical performance, a three-layer functional structure is adopted and comprises a free radical pollution resisting outer layer, a composite pollution resisting middle layer and a water retention enhancing inner layer, a precious metal-free composite modifier is matched, and key process parameters such as pretreatment and functional liquid preparation are defined. The membrane realizes cooperation of pollution resistance, high conductivity, acid resistance and mechanical properties, and is suitable for multi-scene application.
Resumen de: CN121362976A
本发明属于电解水技术领域,具体涉及一种用于提升电解水耦合氕氘分离分离比的电解液添加剂及电解液。所述电解液添加剂选自:有机添加剂或无机添加剂中的一种或几种;所述有机添加剂选自羧基类有机物、胺基类有机物、酰胺类有机物中的一种或几种;所述无机添加剂选自钠盐、钾盐、锂盐中的一种或多种。本发明首次在保持电极析氢活性的同时,实现氕氘分离分离比的进一步提升,普适性应用于所有碱性电解水/电解海水材料氕氘分离比的提升,所述有机或无机添加剂能将氕氘分离比从原有的5.4最高提升至11.3。
Resumen de: CN121362980A
本申请公开了一种反应区域均压的电解槽端板结构,涉及水电解制氢领域,其包括两个端压板、设置在两个端压板之间用于电解制氢的电解组件,两个所述端压板上穿设有紧固螺栓,其中一个所述端压板上设置有若干抑制端压板弯曲变形的均压电动螺栓,在另一所述端压板上设置有与均压电动螺栓对应的压力传感器,所述均压电动螺栓的一侧设置有支撑架,所述支撑架上设置有用于调节均压电动螺栓松紧度的松紧组件,所述支撑架上设置有驱动松紧组件移动的驱动机构,所述支撑架上还设置有用于控制驱动机构驱使松紧组件移动并拧转均压电动螺栓的PLC控制器。本申请自动调节受力不均的端压板,抑制端压板弯曲变形,解决电极与隔膜因端板变形导致的接触不紧密问题。
Resumen de: CN121362991A
The invention relates to a preparation method and application of a Turing-shaped high-entropy alloy catalyst under an interlayer confinement range, and belongs to the technical field of catalyst preparation and electro-catalysis. According to the method, materials are ingeniously taken, commercialized crystalline flake graphite which is low in cost and resistant to acid and alkali corrosion is particularly selected to be combined with aniline to assist metal salt cation coordination, and simple mixing and sufficient intercalation are conducted firstly. And finally, performing in-situ pyrolysis on the metal salt ions confined between the carbon layers through low-temperature heat treatment, and promoting the formation of a Turing structure pattern with uniform size and uniform distribution by virtue of a confinement diffusion-reaction mechanism, so as to successfully obtain the Turing-shaped high-entropy alloy catalyst. In a performance test, the catalyst shows excellent three-function electro-catalysis HER/ORR/OER activity and stability under an alkaline medium. Furthermore, an oxygen electricity-hydrogen electricity sustainable energy system based on self-driving of the metal-air battery is constructed by virtue of the excellent multifunctional catalytic performance of the catalyst.
Resumen de: CN121362998A
本发明公开了一种氢氧化镍/无定形黑磷电极电催化水分解装置,属于电化学技术领域。本发明通过构建黑磷基过渡金属氧化物界面电子传输工程,设计了一种无定形黑磷与β‑氢氧化镍复合的高效OER催化体系,具有制备方法简便、界面调控精准等优点。相比于单一的β‑氢氧化镍催化剂,黑磷的引入显著增强了复合材料的电子传输能力和结构稳定性,从而提升了催化活性与稳定性。相比于晶态黑磷,无定形黑磷由于具有更高的载流子迁移率,进一步增强了界面电荷转移,促进了活性位点的动态维持,确保了反应过程的持续高效性。本发明所搭建的电催化水分解装置,在光照条件下能够高效地促进水分子的分解,为构建太阳能驱动水分解体系提供了可行性。
Resumen de: WO2024262445A1
An electrode 1 for water electrolysis comprises a conductive substrate 10 and a layered double hydroxide (LDH) layer 20. The layered double hydroxide layer 20 is provided to a surface of the conductive substrate 10. The effective film thickness of the layered double hydroxide layer 20 is 250 nm or more and less than 4,000 nm. The layered double hydroxide layer 20 may contain a layered double hydroxide 20a. The effective film thickness of the layered double hydroxide layer 20 may be 3,470 nm or less.
Resumen de: CN121362986A
本发明公开了一种低成本高活性电解水催化电极材料制备方法及其应用,所述制备方法包括:以泡沫镍为基体,依次进行超声波酸洗活化、化学镀和热处理,其中,化学镀液包含硫酸镍、水合肼、络合剂和稳定剂。本发明通过化学镀在三维泡沫镍基体上原位还原沉积金属镍,形成了与基体具有同源性强结合力的催化镀层,有效解决了传统喷涂雷尼镍催化剂易脱落的问题,因此,本发明所制备的电解水催化电极兼具高催化活性和高镀层结合力,而且,本发明制备工艺环保、成本低廉,在电解水制氢领域具有广阔的应用前景。
Resumen de: CN121363837A
The invention relates to an efficient ammonia hydrogen production system coupled with a heat storage device and an implementation method thereof, and the system comprises an ammonia hydrogen production system used for providing hydrogen for a hydrogenation system; the hydrogenation system is connected with the ammonia hydrogen production system and is used for compressing hydrogen and filling the hydrogen to a user; and the refrigerating system is respectively connected with the ammonia hydrogen production system and the hydrogenation system and is used for cooling the hydrogen in the filling process and preventing the hydrogen from overtemperature in the filling process. The hydrogen production cost can be reduced, the system stability and safety are improved, and efficient conversion and storage of energy are achieved.
Resumen de: CN121362335A
本发明公开了一种缺陷NH2‑Ni‑MOF、制备方法及应用,属于压电光催化制氢领域。该方法是首先通过溶剂热法合成前驱体NH2‑Ni‑MOF,让卖家将NH2‑Ni‑MOF材料与研磨球一同放入球磨机中,进行研磨,得到缺陷NH2‑Ni‑MOF;所述的研磨球为5个直径为10 mm的大球与15个直径为5 mm的小球的混合。本发明采用特定比例大小磨球混合研磨制得的D3‑NH2‑Ni‑MOF,实现了高能冲击与高频研磨的协同效应,成功引入了最大浓度的晶格缺陷。该缺陷结构能有效促进光生载流子的分离与迁移,并增强材料在超声作用下的压电极化效应,从而显著提升压电协同光催化性能。在太阳光照及超声振动共同作用下,将D3‑NH2‑Ni‑MOF催化剂分散于甲醇水溶液中,可实现高效且稳定的水分解产氢活性。
Resumen de: CN121360589A
一种具有原子级共格界面的CdS/TiO2异质结复合光催化剂的制备方法,属于光催化领域。特别是涉及通过溶剂热法‑原位水热法制备所述光催化剂的方法,属于催化化学与环境能源技术领域。本发明通过引入十二胺DDA作为界面调控剂,并精确控制水热合成工艺参数,成功地在商业化TiO2表面原位生长出与其晶格高度匹配的CdS纳米晶,从而形成原子级连续的共格界面。该共格界面结构能显著降低界面电荷转移电阻,极大促进光生电子‑空穴对的高效分离与迁移,从而大幅提升了光催化产氢性能。本发明的催化剂在无助催化剂条件下的析氢速率达到18.44 mmol·g‑1·h‑1,是传统非共格界面异质结的2.25倍,具有优异的循环稳定性。
Resumen de: CN121360593A
本发明涉及一种Janus型异质结材料及其在光催化水分解中的计算方法和应用,属于异质结材料技术领域。该材料上层为1T相GeSe单层,下层为1T相SnSSe单层,根据界面原子排列分为GeSe/SSnSe和GeSe/SeSnS两种构型。通过VESTA与VASP软件进行建模与仿真计算,结果表明该材料具备直接Z型异质结特性,能有效促进光生载流子分离并拓宽光吸收范围,显著提升光催化氧化还原能力与太阳能‑氢能转化效率,为开发高效光催化剂提供了新策略。
Resumen de: CN121362978A
The invention relates to the technical field of water electrolysis equipment, in particular to a photovoltaic water electrolysis hydrogen production system which comprises a skid-mounted shell, and a photovoltaic power generation unit, a water electrolysis unit, a gas storage unit, a power supply and heat supply unit and a central controller are arranged in the skid-mounted shell; the water electrolysis unit comprises an electrolysis assembly, an airflow purification assembly, a vibration energy storage assembly, a temperature monitoring assembly and an air bag sealing assembly; the gas storage unit is used for storing oxygen and hydrogen electrolyzed by the water electrolysis unit; and the power supply and heat supply unit is used for converting the hydrogen in the gas storage unit into electric energy. The photovoltaic power generation module, the water electrolysis module, the solid-state gas storage module, the hydrogen fuel cell module and the waste heat heat supply module are assembled in a modularized mode, photovoltaic power generation, power supply and electrolysis of water into hydrogen and oxygen for storage can be independently completed, the hydrogen fuel cell is used, hydrogen is converted into electric power, meanwhile, working waste heat of the electrolytic cell and the fuel cell is absorbed, and energy is saved. And combined supply of hydrogen, oxygen, heat and electricity is carried out.
Resumen de: CN121362995A
本申请属于光电极材料制备领域,具体涉及一种CoNiOOH修饰Sr掺杂BiVO4光电极及其制备方法。光电极,包括:导电基底;设置在导电基底上的Sr掺杂BiVO4层;以及设置在Sr掺杂BiVO4层上的CoNiOOH层。制备方法,包括以下步骤:a)在导电基底上通过电沉积方法制备BiOI电极;b)将含有锶源和钒源的溶液施加到所述BiOI电极上,并进行热处理,以形成Sr掺杂BiVO4光电极;c)将所述Sr掺杂BiVO4光电极浸入含有钴源和镍源的溶液中,进行原位生长处理,以在所述Sr掺杂BiVO4光电极表面形成CoNiOOH层,最后得到Sr:BiVO4/CoNiOOH光电极。
Resumen de: CN121362902A
本发明提供了一种多尺度电化学微电偶结构的产氢合金及其制备方法,该产氢合金包括铝基体、纳米级阴极相与微米级阴极网络;纳米级阴极相为分布于铝基体中的金属间化合物;微米级阴极网络为沿铝基体晶界连续分布的Ga‑In‑Sn共晶合金;铝基体为阳极相;铝基体与纳米级阴极相和微米级阴极网络构成多尺度微电偶结构。通过纳米级阴极相与微米级阴极网络的协同作用,纳米级活性位点负责快速“点火”,启动反应,微米级连续网络则作为“主干道”,负责维持反应的深度和广度,这种多尺度微电偶结构的协同效应,使得作为阳极的铝基体利用率显著提高,接近铝完全反应的理论值。
Resumen de: CN121363001A
本申请提出了一种基于电解槽多状态协同和动态优化的制氢控制方法。该方法通过将电解槽分组并实时监测光伏发电功率,自动诊断和分配每台电解槽的状态,实现了电解槽负荷与光伏发电功率的精准匹配。系统采用聚合和分散两种动态调整模式,灵活应对不同天气条件下的光伏发电特性。同时,引入分段计价策略和季节性运行模式,优化经济效益。这种方法提高了新能源利用效率,增强了系统灵活性和稳定性,延长了设备寿命,降低了运维成本。它为大规模绿氢生产提供了技术支持,有助于推动绿氢产业发展。
Resumen de: CN121366513A
The invention relates to a hydrogen energy teaching practical training system, which comprises a water electrolysis module, a fuel cell, an electric appliance, a power supply module and a control module, and is characterized in that the water electrolysis module comprises a water tank, an electrolytic cell and a gas-liquid separator, the fuel cell is connected with the electric appliance, and the water tank is provided with a first water outlet and a water oxygen recovery port; a first water outlet of the water tank is communicated with a water inlet of the electrolytic cell, the electrolytic cell is provided with a first hydrogen outlet and an oxygen outlet, the gas-liquid separator is provided with a hydrogen inlet, a second hydrogen outlet and a second water outlet, the first hydrogen outlet is communicated with the hydrogen inlet, and the second hydrogen outlet is communicated with the second water outlet. The second hydrogen outlet is connected with the fuel cell so as to convey hydrogen into the fuel cell, and the second water outlet, the oxygen outlet and the water-oxygen recovery port are connected through a three-way pipe fitting. By adopting the technical scheme, the hydrogen energy teaching practical training system provided by the invention prepares hydrogen through water electrolysis, is high in safety, can show a complete closed loop of hydrogen energy from production to application, and enhances the continuity and practicability of teaching.
Resumen de: CN121361843A
本发明公开了一种NiS/CdS异质结材料及其制备方法和应用。按摩尔比CdS:Ni:S=1:(0.5~1.5):(0.5~1.5)将暴露(001)晶面的六方相CdS、可溶性镍源和可溶性硫源分散在乙二醇中,于180±10℃恒温反应,得到NiS/CdS异质结材料。该制备方法在单一温和体系中仅通过时间调控,在六方相CdS暴露的(001)晶面上原位实现NiS的相变‑形貌协同调控:首次实现NiS从非晶‑NiS→α‑NiS(六方相)→β‑NiS(菱方相)的梯度相变,并伴随多维形貌演化(量子点→无定形态→晶面暴露型→块状→长杆型)。特别是,反应时间为18~24h时该制备方法成功制备出α‑NiS与β‑NiS双晶相共存的NiS/CdS异质结材料。此外,该制备方法可以制备出NiS沿CdS纳米线轴向延伸的纳米线型NiS/CdS异质结材料,为推动纳米线型NiS/CdS异质结材料从概念走向实用化奠定了基础。
Resumen de: CN121362983A
本发明提供一种合金材料CePdAl在电解制氢的阴极中和/或在储氢材料中的用途。本发明提供了一种电解制氢的方法,其包括以下步骤:(1)将合金材料CePdAl制备成电解制氢的阴极;(2)提供电解液和阳极;(3)向所述阴极、电解液和阳极中通电,以电解制氢。本发明还提供了一种储氢的方法。本发明发现合金材料CePdAl可以作为电解制氢的阴极,在制氢的同时还可以储氢。
Resumen de: WO2024262441A1
This electrode 1 for water electrolysis comprises a conductive base material 10 and a layered double hydroxide layer 20. The layered double hydroxide layer is provided on the surface of the conductive base material 10. The extinction coefficient k800 of the layered double hydroxide layer 20 at the wavelength of 800 nm is 0.08 or more.
Resumen de: CN121362985A
本发明属于电解水技术领域,具体涉及一种电解水制氢耦合氕氘分离的方法。所述方法包括:使用含有铁基催化剂的材料用作析氢反应电极,所述铁基催化剂包含铁元素。本发明发现,采用含铁元素物质作为析氢反应电极用于电解水/海水制氢耦合氕氘分离副产重水,具有优异的性能,分离比可达6以上。铁基催化剂在析氢反应中多为heyrovsky机理,对氕氘吸附选择性强,更容易吸附结合氕生成氢气,从而将氘富集在电解液中,在产氢同时副产重水。
Resumen de: AU2024312642A1
The present invention relates to an electrolysis system comprising a tank adapted to contain water or an aqueous solution, an electrolytic array comprising electrically conductive plates, a temperature-resistant cathode proximal to, but spaced apart from, a cathodic end of the electrolytic array, a tank anode proximal to, but spaced apart from, an opposing anodic end of the electrolytic array, wherein the cathodic and anodic ends of the electrolytic array are electrically connected to a negative and positive terminal, respectively, of a first power supply adapted to provide direct-current (DC) power thereto, the temperature-resistant cathode and the tank anode are electrically connected to a negative and positive terminal, respectively, of a second power supply adapted to provide DC power thereto and at least the temperature-resistant cathode is adapted to generate a plasma arc within the water or aqueous solution between an end thereof and a closest plate of the electrolytic array.
Resumen de: CN121360529A
本申请实施例提供了一种储氢反应器以及储放氢的方法。所述储氢反应器包括:反应容器,以及,设置在反应容器上的进料系统;所述反应容器包括功能上耦合的自热反应区和储氢反应区;所述自热反应区设置有铁粉,所述储氢反应区设置有储氢材料;所述进料系统用于向所述自热反应区输入水和气相氧化剂;所述水、气相氧化剂以及铁粉发生放热反应,放热产生的热量将水气化为高温水蒸气,所述高温水蒸气与储氢材料发生水解反应,产生氢气,同时释放热量。该设计不仅极大地简化了系统结构、实现了装置的轻量化与紧凑化,还利用反应热将水瞬间气化,高温气态水携带大量热量且更均匀的与储氢材料反应,从而显著提升了储氢材料的水解反应速率与放氢效率。
Resumen de: CN121362989A
本发明公开了一种低载量贵金属铂镍催化剂的制备方法及其在天然海水制氢中的应用,属于贵金属纳米催化材料制备技术领域。该催化剂以泡沫镍为载体,放入氯铂酸钾溶液中进行水热反应,得到所述的低载量贵金属铂镍催化剂。组装流动型电解池,以得到的低载量贵金属铂镍催化剂作为流动型电解池的阴极,以NiFe‑LDH作为流动型电解池的阳极,阴极以天然海水为电解液,阳极以氢氧化钾溶液为电解液,进行电催化反应。本发明提出的镍基催化剂的合成策略具有操作简便、成本低廉、环境友好等优势,所采用的原料易得且符合绿色化学原则,具备规模化生产的可行性,在清洁能源转化等领域具有广阔的应用前景。
Resumen de: CN121362984A
本发明属于催化剂技术领域,尤其涉及一种高熵合金催化剂及其原子级制造方法与应用。与现有技术相比,本发明在支撑体表面沉积FeCoNiCrM高熵合金薄膜作为高熵合金催化剂,其中掺入Cr与M,当M包括V时,Cr与V作为牺牲掺杂剂,当M包括Cu时,Cu与其他元素构成多元活性中心,使高熵合金各组分协同整合诱导催化剂配位环境的电子调制,显著提高了析氧反应效率,并且在反应过程中,可控制性浸出Cr与M组分,生成富含氧空位的结构,同时通过熵稳定保持结构完整性,从而使高熵合金催化剂展现出卓越的碱性电解水析氧反应催化性能及出色的稳定性。
Resumen de: CN121361835A
本发明属于光催化析氢技术领域,更具体的说是涉及一种溶剂热法合成硒化锌/硫化钼铜光催化剂的方法。本发明先合成必需的氧化亚铜,再以氧化亚铜为模板合成硫化钼铜,最后硫化钼铜作为助催化剂用于合成硒化锌/硫化钼铜异质结光催化剂。相比于纯硒化锌,硒化锌/硫化钼铜光催化剂有更丰富的析氢活性位点和较低的析氢过电位;并且硒化锌/硫化钼铜光催化剂的载流子分离效率也明显优于纯硒化锌,所以硫化钼铜的引入可以显著提升硒化锌的光催化析氢活性。实验结果表明,硒化锌/1wt%硫化钼铜展现出最佳的产氢性能,其平均产氢速率是纯硒化锌的4.14倍。
Resumen de: CN121362993A
本发明提供了一种具有内建电场复合电催化材料及其制备方法,属于电化学能源材料技术领域,该制备方法包括以下步骤:将镍网浸泡于盐酸溶液中超声处理后使用去离子水和乙醇冲洗,干燥后得到预处理的镍网;将预处理后的镍网浸泡于由硝酸镍、硝酸钴、尿素和氟化铵溶解于去离子水得到的水热溶液中,使用水热法在镍网表面生长均匀的镍钴氢氧化物纳米片阵列结构;再将得到的镍钴纳米片阵列结构置于含有氯铂酸的氢氧化钾溶液中,通过简单的循环伏安法在纳米片表面均匀沉积铂纳米颗粒,干燥后得到该具有内建电场复合电催化材料。本发明的制备方法合成周期短,合成过程工序简单、操作方便、重复性可靠,非常适合于规模化工业生产。
Resumen de: CN121362982A
本发明公开了一种铱钌双原子/海绵镍复合材料及其制备方法和碱性电催化析氢中的应用。上述的制备方法包括称取醋酸镍和量取水合肼、氯铱酸、三氯化钌水溶液溶解于去离子水配置混合溶液并置于高压反应釜中进行水热反应得到铱钌双原子/海绵镍复合材料电催化剂。本发明制得的铱钌双原子/海绵镍复合材料相较于原始的海绵镍电催化剂具有更好的碱性电催化析氢性能;其优点在于氯铱酸的酸性会使得部分Ni原子溶出产生Ni空位,从而提供铱钌双原子形核位点。复合材料可以协同催化碱性析氢,其机制为镍位点提供碱性H2O的裂解位点,获得活性氢物种,进一步通过铱钌双原子实现氢质子的快速脱附,从而获得更优异的碱性电催化析氢性能。
Resumen de: CN121362981A
本发明涉及膜电极技术领域,特别涉及一种电解水装置、膜电极及其制备方法,电解水装置包括膜电极,膜电极包括离子交换膜和设于离子交换膜至少一侧的催化层,催化层包括至少两层活性层;定义相邻的两活性层为第一活性层和第二活性层;第一活性层设于离子交换膜,第二活性层设于第一活性层背离离子交换膜的一侧,第一活性层中的第一催化剂的体积平均粒径D50小于第二活性层中的第二催化剂的体积平均粒径D50。本申请通过设计梯度催化剂颗粒的分布,提高气泡的排出效率,降低催化剂层的物质传输阻力,优化水电解性能以及降低能耗。
Resumen de: KR20260009676A
경사형 도핑 영역을 갖는 광전기화학 전극의 제조방법 및 이에 의해 제조된 광전기화학 전극이 제공된다. 상기 광전기화학 전극의 제조방법은 P형 실리콘(p-Si) 기판의 표면에 나노 다공성 구조 도입으로 표면 결함 개선과, 광 흡수를 높일 수 있고, 상기 나노 다공성 구조에 경사형 고농도 인(P) 도핑영역을 형성함으로써 캐리어 재결합의 정밀한 제어를 통해 이를 적용한 광전기화학 전지의 성능을 향상시킬 수 있다.
Resumen de: KR20260009420A
본 발명은 가연성의 폐기물을 이용한 바이오디젤 및 합성 연료의 생산 방법 및 그 시스템에 관한 것으로서, 보다 구체적으로, 본 발명은 가연성의 폐기물을 소각과 열분해를 병합하여 열분해의 흡열반응에 필요한 열을 소각의 발열반응에서 얻는 열을 사용함으로써, 열분해의 흡열반응에 필요한 열을 별도로 공급하지 않고, 열분해를 실행한다. 이를 위해 소각 장치를 건류장치로 구비하고, 건류장치의 소각은 마이크로웨이브 플라즈마 토치(Microwave Plasma Torch)의 3,000~5,000℃의 화염으로 하며, 건류장치에서 가연성의 폐기물이 열분해 된 건류 가스는 냉각장치로 응축시켜 열분해 오일을 얻고, 이 열분해 오일을 전이에스테르화 반응시킨 후, 고속분리하여 바이오디젤을 생산한다. 또한, 응축되지 않은 미응축 저분자 가스는 스팀 보일러(Steam Boiler)에서 연소시켜 수증기를 생산하고, 수중기의 열을 이용하여 펠티어 소자(Peltier Module)를 통해 전기를 생산하며. 펠티어 소자를 통해 생산된 전기를 수전해 스택에 공급하여 물을 전기 분해함으로써, 그린수소(H2)를 생산한다. 스팀 보일러(Steam Boiler)에서 최종 연소 후, 배출되는 배기가스는 건류장치에 화염을 발생시키는 마이크로웨이브 플라즈마 토치(Microwave Plasma Torch)의 스월가스(Swirl ga
Resumen de: CN121360601A
本申请提供了一种分子筛限域氨裂解制氢催化剂及其制备方法,利用活性组分、碱源、有机配体、模板剂、硅源及铝源将活性组分铆钉在分子筛内部,通过还原气氛焙烧调控活性组分团簇颗粒大小,增加活性组分之间的相互作用,从而有效降低氨裂解制氢催化反应温度。
Nº publicación: JP2026008252A 19/01/2026
Solicitante:
株式会社日立製作所
Resumen de: JP2026008252A
【課題】水の電解にともなって水電解セル内に発生した気泡に起因する電解質膜での水枯れをただちに検出し、水電解セルの電解効率の低下や電解質膜の劣化を従来と比べてより確実に防止することができる水電解システムを提供する。【解決手段】水電解システム100Aは、水電解セル200の電圧を、予め設定されたサンプリング時間間隔で断続的に計測する電圧計測部102と、電圧同士の差分をサンプリング時間間隔で除した電圧勾配値に基づいて水電解セル200の水枯れを判定する水枯れ判定部104と、水枯れの判定により、水供給装置106から水電解セル200への給水流速の増加と、電源装置50から水電解セル200に通電する電流値の低減とを行って水電解セル200の電圧を低減させる水枯れ解消部105と、を備える。【選択図】図1