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水電解セル、及び水電解装置

NºPublicación:  JP2026147521A 17/09/2026
Solicitante: 
三菱重工業株式会社
JP_2026147521_A

Resumen de: JP2026147521A

【課題】イオン交換膜の損傷を適切に抑制することができる水電解セル、及び水電解システムを提供すること。【解決手段】本開示に係る水電解セルは、イオンを選択的に透過する性質を有するイオン交換膜と、イオン交換膜の一方側に配置される負極側触媒層と、イオン交換膜の他方の面側に配置される正極側触媒層と、イオン交換膜の一方の面と負極側触媒層の間と、イオン交換膜の他方の面と正極側触媒層の間との、少なくとも一方に設けられ、親水性を有する有機材料で構成される保護膜と、を備える。【選択図】図1

電解システム

NºPublicación:  JP2026147233A 17/09/2026
Solicitante: 
株式会社アイシン
JP_2026147233_A

Resumen de: JP2026147233A

0001 【課題】ヒートポンプの熱出力に誤差等が生じていても、電解セルに適正量の水蒸気を供給する。 【解決手段】電解システムは、水蒸気電解により水素を生成する電解セルを含む電解モジュールと、原料水から水蒸気を生成する水蒸気生成部と、水蒸気生成部で生成された水蒸気を電解モジュールに供給する蒸気供給ラインと、蒸気供給ラインから分岐して前記電解モジュールをバイパスするバイパスラインと、バイパスラインに設置される圧力調整弁と、を備える。 【選択図】図1

CONTINUOUS HYDROGEN ON-DEMAND SYSTEM

NºPublicación:  WO2026192980A1 17/09/2026
Solicitante: 
THE RESEARCH FOUNDATION FOR THE STATE UNIV OF NEW YORK [US]
THE RESEARCH FOUNDATION FOR THE STATE UNIVERSITY OF NEW YORK
WO_2026192980_A1

Resumen de: WO2026192980A1

A method for providing hydrogen on demand, as follows: providing an apparatus containing (i) a hydrogen storage unit configured to release hydrogen on demand for a period of up to 24 hours; (ii) a methanol reforming unit configured to steadily release hydrogen over a period of at least 24 hours, after a lead time for the methanol reforming process to pressurize a tank with hydrogen; and (iii) an electrical device operably connected to the hydrogen storage unit and methanol reforming unit and configured to switch operation of the hydrogen storage unit and methanol reforming unit to ensure that hydrogen is released without interruption by releasing hydrogen from the hydrogen storage unit only during said lead time of the methanol reforming process; and operating the apparatus to release hydrogen without interruption by releasing hydrogen from the hydrogen storage unit only during the lead time of the methanol reforming process.

METHOD OF CONVERTING BIOMASS INTO HYDROGEN AND BIOGENIC CARBON DIOXIDE

NºPublicación:  WO2026190457A1 17/09/2026
Solicitante: 
KI HYDROGEN LTD [GB]
KI HYDROGEN LTD
WO_2026190457_A1

Resumen de: WO2026190457A1

A method of continuously converting biomass into hydrogen and biogenic carbon dioxide is provided. The method comprises introducing biomass, water, an acid and an oxidised redox mediator into a first reactor; operating the first reactor to generate carbon dioxide and an anolyte solution comprising an oxidised biomass, a reduced redox mediator and H+ ions; removing carbon dioxide from the first reactor; introducing at least a portion of the anolyte solution into an anode side of an electrochemical reactor; introducing a catholyte solution comprising an acid and a catholyte redox mediator into a cathode side of the electrochemical reactor; operating the electrochemical reactor to generate hydrogen at the cathode by reducing H+ ions, and to regenerate the oxidised redox mediator at the anode by oxidising the reduced redox mediator; removing hydrogen from the electrochemical reactor; and recirculating the oxidised redox mediator from the electrochemical reactor to the first reactor.

ELECTROLYSIS SYSTEM

NºPublicación:  WO2026191168A1 17/09/2026
Solicitante: 
MITSUBISHI ELECTRIC CORP [JP]
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WO_2026191168_A1

Resumen de: WO2026191168A1

This electrolysis system comprises: an electrolysis device that generates a cathode off-gas containing hydrogen through electrolysis of a water raw material; a fuel synthesis reaction device that synthesizes fuel from hydrogen and a carbon oxide gas; a cathode regeneration heat exchanger that exchanges heat between the cathode off-gas and a cathode supply gas supplied to a cathode of the electrolysis device; a steam generator that converts the water into steam on the upstream side of the cathode regeneration heat exchanger; a heating medium circulation system in which a heating medium moves between the steam generator and the fuel synthesis reaction device; an auxiliary heating device that is provided on the upstream side of the steam generator in the heating medium circulation system and heats the heating medium; a heating medium pump that is provided on the downstream side of the steam generator in the heating medium circulation system; and a steam heating medium state estimation sensor that is provided in the steam generator and estimates a vaporization state of the water.

METHODS FOR SELECTIVELY DEPOSITING NANO- OR MICROSCOPIC PLUGS IN MEMBRANES FOR ELECTROCHEMICAL APPLICATIONS

NºPublicación:  US20260275551A1 17/09/2026
Solicitante: 
UNIV COLUMBIA [US]
The Trustees of Columbia University in the City of New York
US_20260275551_A1

Resumen de: US20260275551A1

Crossover through submicron thick SiO2 membranes can be mitigated by selectively depositing oxide, e.g., carbon-containing silicon oxide (SiOxCy) “nanoplugs” into the pinholes and cracks of the membranes. Defect-containing membranes are contacted with a deposition solution including hydrolysable precursors, e.g., metal alkoxides like tetraethyl orthosilicate (TEOS), and a nanoplug directing agent, e.g., tetramethylammonium bromide (TMAB). Current is applied to the defect-containing membranes in pulses, including a shorter “on” phase where current is applied and a longer “off phase” where current is not applied. The SiOxCy nanoplugs are deposited to the structural defects during the “on” phase. The longer “off phase” enables reactants to diffuse back to the structural defects for deposition of additional nanoplugs during the next “on” phase, as well as prevent deposition of SiOxCy on non-defective regions. Treatment of plugged SiO2 membranes reduced H2 permeation rates by 5-6 orders of magnitude compared to unmodified SiO2 and 1-2 orders of magnitude compared to Nafion-117 membranes.

SOLID OXIDE ELECTROLYSIS CELL SYSTEM

NºPublicación:  WO2026191397A1 17/09/2026
Solicitante: 
HITACHI LTD [JP]
\u682A\u5F0F\u4F1A\u793E\u65E5\u7ACB\u88FD\u4F5C\u6240
WO_2026191397_A1

Resumen de: WO2026191397A1

In order to calculate the state of the inside of an SOCE without deteriorating airtightness between electrodes of the SOCE, a solid oxide electrolysis cell system according to the present invention comprises: an electrolysis cell unit that generates oxygen and hydrogen by electrolyzing water vapor using a solid oxide electrolysis cell; a voltage measurement unit that measures the voltage of the electrolysis cell unit; an impedance measurement unit that measures the impedance value of the electrolysis cell unit; a temperature calculation unit that calculates the cell temperature of the electrolysis cell unit on the basis of the impedance value of the electrolysis cell unit and the activation energy of a solid electrolyte unit of the electrolysis cell unit; a gas composition calculation unit that calculates the gas composition of the water vapor to be flowed into the electrolysis cell unit on the basis of the voltage and the cell temperature; and a gas control unit that controls the gas flow rate of the water vapor to be flowed into the electrolysis cell unit on the basis of the gas composition calculated by the gas composition calculation unit.

ELECTROLYSIS APPARATUS

NºPublicación:  US20260275556A1 17/09/2026
Solicitante: 
HYDEP S R L [IT]
HYDEP S.R.L.
US_20260275556_A1

Resumen de: US20260275556A1

An electrolysis apparatus for the production of gaseous hydrogen and oxygen by water electrolysis includes an electrolyzer having a plurality of cells arranged next to each other to form a cell stack. Each cell includes an anode and a cathode plate. The electrolyzer further includes anode and cathode end plates. The electrolyzer has an active chamber in which the electrolysis reaction of water contained in an electrolyte solution with which the electrolyzer is fed takes place, a first liquid/gas phase separator for separating oxygen gas from the electrolyte solution, and a second liquid/gas phase separator for separating hydrogen gas from the electrolyte solution. The electrolyzer also includes a plurality of sensors mounted on one of the anode and cathode end plates and configured to detect appropriate operating parameters of the first and second liquid/gas phase separator.

SYSTEM AND METHOD FOR AMMONIA SYNTHESIS COUPLED WITH HYDROGEN PRODUCTION

NºPublicación:  EP4806839A1 16/09/2026
Solicitante: 
ENVISION ENERGY CO LTD [CN]
Envision Energy Co., Ltd.
EP_4806839_PA

Resumen de: EP4806839A1

0001 Provided are a system and method for ammonia synthesis coupled with hydrogen production. The system includes: a hydrogen production module, a hydrogen deoxygenation module, an adsorption module, and an ammonia synthesis module connected in sequence; and a nitrogen supply module, a regeneration module, and the adsorption module connected in sequence. When one of the regeneration module and the adsorption module includes a first adsorption tower, the other includes a second adsorption tower. A hydrogen purification module, the nitrogen supply module, and the ammonia synthesis module are all connectable and disconnectable to the first adsorption tower and the second adsorption tower. The nitrogen supply module supplies nitrogen, the regeneration module uses nitrogen to perform desorption regeneration in the first adsorption tower or the second adsorption tower and supplies nitrogen to the adsorption module. The hydrogen production module supplies hydrogen to be purified, and the hydrogen deoxygenation module purifies the hydrogen to be purified and then supplies it to the adsorption module. The adsorption module purifies hydrogen and nitrogen and then supplies them to the ammonia synthesis module, which is at least conducive to reducing energy consumption and system investment costs.

電解装置システムおよび電解装置システムを動作させるための方法

NºPublicación:  JP2026531374A 16/09/2026
Solicitante: 
ボルトグループリミテッド
JP_2026531374_A

Resumen de: WO2025043281A1

An electrolyser system (400) comprises at least one electrolyser (460) and has an operating energy requirement generated by an energy source (27). The energy source (27) includes waste heat generated by an industrial process whether involving combustion or an exothermic chemical reaction. The electrolyser system (400) further comprises a waste heat to power system (70) for recovering heat from the industrial process to produce electricity for supply to the at least one electrolyser (460); and a heat exchange system (407) for recovering heat from the industrial process and enabling transfer of said recovered heat to the at least one electrolyser (460) as thermal energy. The electrolyser system (400) has substantially higher energy efficiency and lower cost than an electrolyser system operated using an intermittent renewable energy source.

OPERATION METHOD FOR ELECTROLYSIS DEVICE, CONTROL DEVICE FOR ELECTROLYSIS DEVICE, AND ELECTROLYSIS SYSTEM

NºPublicación:  EP4807049A1 16/09/2026
Solicitante: 
MITSUBISHI HEAVY IND LTD [JP]
MITSUBISHI HEAVY INDUSTRIES, LTD.
EP_4807049_PA

Resumen de: EP4807049A1

Provided are an operation method of an electrolyzer, a controller of an electrolyzer, and an electrolysis system that can quickly reach a rated load. An operation method of an electrolyzer (100) including a temperature controller (30) configured to regulate a temperature of an electrolyte solution supplied to a cellstack (40), the cellstack (40) configured to electrolyze the electrolyte solution supplied via the temperature controller (30), and a gas-liquid separator (20) configured to separate a gas and a liquid from each other that are generated by the cellstack (40) includes: supplying hot water to the temperature controller (30) in a case of a stopped state where the electrolyzer (100) is stopped.

チタン酸ストロンチウム粒子、光触媒材、分散液、組成物、塗膜、基材

NºPublicación:  JP2026146518A 16/09/2026
Solicitante: 
住友大阪セメント株式会社
JP_2026146518_A

Resumen de: JP2026146518A

【課題】高い水分解活性を有し、光触媒を用いた太陽光照射による水分解に用いられる水分解用チタン酸ストロンチウム光触媒を提供する。【解決手段】粒子密度が4.0g・cm-3以上、比表面積が2m2・g-1以上25m2・g-1以下であり、イリジウムがドープされた、チタン酸ストロンチウム粒子。【選択図】なし

ELECTROLYSIS CELL SYSTEM AND METHOD FOR CONTROLLING SAME

NºPublicación:  EP4807048A1 16/09/2026
Solicitante: 
CERES POWER LTD [GB]
Ceres Power Limited
EP_4807048_PA

Resumen de: EP4807048A1

Provided is an electrolytic cell system comprising an electrolytic cell, a first supply line, a second supply line, a first pressure adjusting unit, a second pressure adjusting unit, and a controller. The electrolytic cell has a hydrogen electrode chamber and an oxygen electrode chamber. The first supply line supplies a feedstock gas containing water vapor to the hydrogen electrode chamber. The second supply line supplies compressed air to the oxygen electrode chamber. The first pressure adjusting unit is provided in the first supply line. The second pressure adjusting unit is provided in the second supply line. The controller adjusts a first pressure in the hydrogen electrode chamber and a second pressure in the oxygen electrode chamber by controlling the first pressure adjusting unit and the second pressure adjusting unit.

ELECTROCHEMICAL CELL ASSEMBLY

NºPublicación:  EP4805996A1 16/09/2026
Solicitante: 
CERES POWER LTD [GB]
BOSCH GMBH ROBERT [DE]
Ceres Power Limited
Robert Bosch Gesellschaft mit Beschr\u00E4nkter Haftung
TW_202520535_A

Resumen de: TW202520535A

The invention relates to an electrochemical cell assembly (10), comprising a first end plate (12), a second end plate and a stack (16) of cell units (18), wherein each cell unit defines an external perimeter, a housing (42) surrounding the stack to define or enclose a fluid volume (48), at least one electrically insulating member (98) being located between the housing and the external perimeters of the cell units and a positioning device (100) for the at least one electrically insulating member, comprising at least one positioning member (106) protruding from either the housing or one of the end plates into the fluid volume, wherein the at least one positioning member has a positioning surface interacting with the electrically insulating member for positioning the electrically insulating member relative to the housing and/or the end plates. The invention also relates to methods of manufacturing an electrochemical cell assembly.

IRIDIUM-BASED NANOWIRE AND PREPARATION METHOD THEREFOR, AND IRIDIUM-BASED CATALYST CONTAINING SAME AND PREPARATION METHOD THEREFOR

NºPublicación:  EP4807047A1 16/09/2026
Solicitante: 
CHINA PETROLEUM & CHEM CORP [CN]
SINOPEC SHANGAI RESEARCH INST OF PETROCHEMICAL TECHNOLOGY CO LTD [CN]
China Petroleum & Chemical Corporation
Sinopec (Shangai) Research Institute of Petrochemical Technology Co., Ltd.
EP_4807047_PA

Resumen de: EP4807047A1

0001 This invention discloses an iridium-based nanowire comprising a twin crystal composed of iridium and at least one transition metal selected from iron, cobalt, and nickel, preferably, the diameter d of the nanowire is 0.5 to 6 nm, and more preferably, the grain size of the twin crystal is (0.8-1.1)·d nm. This invention also relates to an iridium-based catalyst comprising the iridium-based nanowire and preparation methods of the iridium-based nanowire and the iridium-based catalyst. The catalyst of this invention has the advantages of large electrochemical active surface area, high catalytic activity for oxygen evolution reaction, and good stability.

A METHOD AND A CONTROL ARRANGEMENT FOR CONTROLLING A RENEWABLE POWER PLANT

NºPublicación:  EP4806031A1 16/09/2026
Solicitante: 
VESTAS WIND SYS AS [DK]
VESTAS WIND SYSTEMS A/S
WO_2025098577_PA

Resumen de: WO2025098577A1

A method and a control arrangement for controlling a renewable power plant (100) connected to a power grid (116) are presented. The method comprises: - determining (210) a dynamic policy (DP) based on: -- a current state (Scur) of the renewable power plant (100), -- a prediction (Ppred) of a future power production of more than one renewable electric power generating units (103) comprised in the renewable power plant, and -- a risk (λ) for instability at a connection (115) to the power grid (116); - determining (220) one or more power-to-gas reference points (RPP2G) based on: -- an available power (Pav) provided by the more than one renewable electric power generating units (103), and -- the determined dynamic policy (DP); and - providing (230) the determined one or more power-to-gas reference points (RPP2G) to at least one power-to-gas unit (120).

一种PEM电解槽阴极保护系统及方法

NºPublicación:  CN122751217A 15/09/2026
Solicitante: 
重庆大学
CN_122751217_PA

Resumen de: CN122751217A

本发明涉及质子交换膜电解水制氢技术领域,尤其涉及一种PEM电解槽阴极保护系统及方法,包括至少一台PEM电解槽、氢水一级分离罐、阴极水循环保护回路和阳极回路;阳极回路与PEM电解槽的阳极出口和阳极进口连接,阴极水循环保护回路包括阴极进水管路和阴极回水管路;阴极回水管路均与PEM电解槽的阴极出口和氢水一级分离罐连接;阴极回水管路上设置有阴极回水三通球阀;阴极进水管路均与PEM电解槽的阴极进口和氢水一级分离罐连接;阴极进水管路上设置有阴极进水三通球阀、止回阀、水泵、Y型过滤器和气动球阀,解决了现有技术中氮气消耗高、难以适配多工况、保护效果差且改造成本高的技术问题。

一种用于绿氢精制的可再生脱氧剂及其制备方法

NºPublicación:  CN122748574A 15/09/2026
Solicitante: 
淮安华海新材料有限公司
CN_122748574_A

Resumen de: CN122748574A

0001 本发明涉及气体净化技术领域,尤其涉及一种用于绿氢精制的可再生脱氧剂及其制备方法。本发明采用的技术方案是:一种用于绿氢精制的可再生脱氧剂,其特征在于,以重量份计,所述脱氧剂由以下组分组成:氧化锰(以MnO<2>计):25~40份;氧化铜(以CuO计):18~30份;氧化锌(以ZnO计):5~20份;载体以100重量份计。本发明的优点是:利用各组分的协同效应,在不大幅增加制备复杂度的情况下,同时实现了高脱氧容量、优异循环稳定性及高机械强度。

一种CoP/NiFe-LDH异质结构电催化剂及其制备方法与应用

NºPublicación:  CN122751253A 15/09/2026
Solicitante: 
西北师范大学
CN_122751253_PA

Resumen de: CN122751253A

本发明公开了一种CoP/NiFe‑LDH异质结构电催化剂及其制备方法与应用,属于电催化材料领域。该催化剂通过水热、磷化和电沉积三步原位生长策略,在泡沫镍上构筑由晶相CoP纳米线骨架与低结晶度NiFe‑LDH纳米片组成的“纳米线‑纳米片”分级异质结构。两者间的功函数差驱动界面电子由NiFe‑LDH向CoP迁移,构建了稳定的内建电场,不仅加速界面电荷传输,更诱导析氧反应路径由传统吸附演化机制(AEM)向晶格氧参与机制(LOM)转变,突破了中间体的标度关系限制。本发明催化剂在1 M KOH电解液中,于100 mA·cm‑2下过电位仅191 mV,在1 A•cm‑2工业级电流密度下过电位为239 mV,且在1 A·cm‑2下连续运行600 h后电流保持率仍达92%。本发明为工业电解水制氢提供了一种兼具优异催化活性与超长稳定性的非贵金属电催化剂。

一种基于NiMo基合金的电解水析氢电极及制备方法

NºPublicación:  CN122751238A 15/09/2026
Solicitante: 
南开大学中国大唐集团科技创新有限公司
CN_122751238_PA

Resumen de: CN122751238A

本发明涉及一种基于NiMo基合金的电解水析氢电极及制备方法,通过对NiMo基合金材料或表面具有NiMo基合金镀层的导电基底进行酸清洗,再经过氧化热处理和还原热处理,在电极表面原位构筑NiMo基复合析氢催化层,从而提高其析氢反应活性和稳定性;制备得到的基于NiMo基合金的电解水析氢电极直接能够用作碱性电解水和阴离子交换膜电解水中的阴极,用于析氢反应,不需要额外加入聚合物粘结剂、导电炭黑或独立集流体。本方法避免了复杂前驱体合成和粉体催化剂涂覆过程,既能够保证电解水析氢电极的高效催化性能,又降低了制备成本和工艺复杂度,具有较佳推广应用前景。

一种Bi2MoO6/r-WO3异质结光阳极材料及其制备方法

NºPublicación:  CN122751250A 15/09/2026
Solicitante: 
湖北师范大学
CN_122751250_PA

Resumen de: CN122751250A

0001 本发明公开了一种Bi<2>MoO<6>/r‑WO<3>异质结光阳极材料及其制备方法,属于光电催化材料技术领域。光电化学水分解是太阳能向清洁能源转化的有效途径,但空白WO<3>光阳极因小极化子效应导致体相电导率低、载流子复合严重。本发明提供以下方案:通过两步水热结合退火在FTO基底上制备WO<3>光阳极,经电化学还原引入氧空位得到r‑WO<3>,再经溶剂热原位生长Bi<2>MoO<6>纳米片,构筑Type‑Ⅱ型二维/二维异质结。氧空位可降低极化子跳跃活化能,异质结可加速界面电荷分离,二者协同增效,提升了空白WO<3>光阳极的光电化学水分解性能。本发明方法温和可控,所得光阳极具有良好的体相电荷传输性能和界面电荷分离效率,可应用于光电化学水分解制氢领域。

一种镍基钌电催化材料及其制备方法和应用

NºPublicación:  CN122751242A 15/09/2026
Solicitante: 
桂林理工大学
CN_122751242_PA

Resumen de: CN122751242A

本发明涉及电催化材料及新能源技术领域,具体涉及一种镍基钌电催化材料及其制备方法和应用:该催化材料的表达式为NiRux,其中x为Ru与Ni的原子百分比,x为0.5至5。其制备方法包括:将镍源、钌源和碱溶于多元醇溶剂中,所述多元醇优选1,2‑丁二醇;加热至160‑180℃反应1‑2小时;产物经乙醇和丙酮洗涤后干燥,即得。本发明通过优化溶剂种类、贵金属种子、钌含量及合成工艺,成功制备出钌高分散于镍表面的催化材料。该材料在碱性析氢反应中表现出优异的电催化活性,且稳定性好、贵金属用量低。该合成方法简便、绿色、易于放大,可广泛应用于阴离子交换膜水电解制氢领域。

一种阻断阳极侵蚀的碱性海水电解制氢电解液及其应用

NºPublicación:  CN122751210A 15/09/2026
Solicitante: 
西安交通大学
CN_122751210_PA

Resumen de: CN122751210A

本发明属于碱性电解海水制氢技术领域,具体涉及一种阻断阳极侵蚀的碱性海水电解制氢电解液及其应用。所述海水电解制氢电解液,由海水、碱性电解质和含氧阴离子添加剂混合制成。其中,所述碱性电解质为氢氧化钠。所述含氧阴离子添加剂选自磷酸盐、碳酸盐、硫酸盐和硝酸盐中的任一种或几种。所述碱性电解质的终浓度为0.1mol/L~2.5mol/L。所述含氧阴离子添加剂的终浓度为0.015mol/L~3mol/L。本发明的海水电解制氢电解液在250h内的电解电压波动幅度仅为0.5V。且在500mA/cm2的大电流密度下仍能维持250h以上的稳定运行。本发明的海水电解制氢电解液能保护阳极金属不被腐蚀和保护阳极表面的催化剂的活性。

盐穴造腔系统及方法

NºPublicación:  CN122751975A 15/09/2026
Solicitante: 
国家石油天然气管网集团有限公司国家管网集团北方管道有限责任公司国家管网集团北方管道有限责任公司天津输油气分公司
CN_122751975_PA

Resumen de: CN122751975A

0001 本申请提供一种盐穴造腔系统及方法,涉及水溶造腔技术领域,用于通过电解卤水的方式提高盐穴的排卤效率。该盐穴造腔系统包括:至少一个注液管道,注液管道用于向盐穴内注水,在盐穴中形成卤水;至少两个排气管道,每个排气管道内包括一种极性的电解电极,至少两个排气管道中至少包括一个内部设置有阳极的排气管道和一个内部设置有阴极的排气管道,排气管道用于输送电解电极电解卤水产生的气体;在每个排气管道内,电解电极设置的位置高于排气管道靠近盐穴一侧的端口,排气管道远离盐穴的一侧设置有阀门,在阀门关闭时排气管道内的气体压力上升,排气管道内的液面下降直至排气管道内的电解电极与卤水分离。

一种碳笼限域的Zn掺杂CoS2纳米纤维海水电解催化剂及其应用

Nº publicación: CN122751226A 15/09/2026

Solicitante:

温州大学新材料与产业技术研究院

CN_122751226_PA

Resumen de: CN122751226A

0001 本发明提供一种碳笼限域的Zn掺杂CoS<2>纳米纤维海水电解催化剂及其应用,本发明采用ZnCo‑ZIF前驱体与静电纺丝相结合的方法,将金属有机骨架均匀引入聚合物纳米纤维体系中,经预氧化、碳化和硫化后形成碳笼限域的Zn掺杂硫钴化合物催化剂。所得材料保持了连续的一维纤维网络结构和三维开放骨架,以及多孔纤维网络和丰富的开放通道结构,该结构能够增加电解过程中催化剂与电解液的接触面积,促进活性位点暴露,并有利于析氧过程中气泡的快速脱附,从而提升催化反应效率;碳层与氮掺杂碳骨架共同构成耐腐蚀保护层,可在碱性海水电解环境下有效削弱Cl<‑>对催化剂表面的不利吸附与腐蚀作用,同时保持快速的电子传输通道,使催化剂兼具高活性与高稳定性。

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